CN114133632B - 矿用耐寒轮胎胎面胶及其制备方法 - Google Patents
矿用耐寒轮胎胎面胶及其制备方法 Download PDFInfo
- Publication number
- CN114133632B CN114133632B CN202111535053.XA CN202111535053A CN114133632B CN 114133632 B CN114133632 B CN 114133632B CN 202111535053 A CN202111535053 A CN 202111535053A CN 114133632 B CN114133632 B CN 114133632B
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- Prior art keywords
- parts
- carbon black
- rubber
- agent
- butadiene rubber
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 68
- 239000005060 rubber Substances 0.000 title claims abstract description 66
- 238000005065 mining Methods 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000006229 carbon black Substances 0.000 claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- 229920005989 resin Polymers 0.000 claims abstract description 37
- 239000011347 resin Substances 0.000 claims abstract description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 27
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 25
- RTGQGAXEHFZMBG-UHFFFAOYSA-N 2-(2-nonanoyloxyethoxy)ethyl nonanoate Chemical compound CCCCCCCCC(=O)OCCOCCOC(=O)CCCCCCCC RTGQGAXEHFZMBG-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 19
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 16
- 229920003235 aromatic polyamide Polymers 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 16
- 229920001194 natural rubber Polymers 0.000 claims abstract description 16
- 239000004760 aramid Substances 0.000 claims abstract description 15
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 14
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 14
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 14
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 14
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 14
- 239000003549 soybean oil Substances 0.000 claims abstract description 14
- 239000008117 stearic acid Substances 0.000 claims abstract description 14
- 239000011593 sulfur Substances 0.000 claims abstract description 14
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 14
- 239000011787 zinc oxide Substances 0.000 claims abstract description 14
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims description 23
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 16
- 238000003825 pressing Methods 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 12
- 238000007599 discharging Methods 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 9
- 238000007670 refining Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 235000014692 zinc oxide Nutrition 0.000 claims description 4
- 235000006708 antioxidants Nutrition 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 claims 8
- 239000002174 Styrene-butadiene Substances 0.000 claims 8
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 claims 8
- 238000005520 cutting process Methods 0.000 abstract description 8
- 239000003981 vehicle Substances 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 11
- 230000008901 benefit Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- PBRIXADXGMHVMW-UHFFFAOYSA-N formaldehyde;4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound O=C.CC(C)(C)CC(C)(C)C1=CC=C(O)C=C1 PBRIXADXGMHVMW-UHFFFAOYSA-N 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- -1 polycyclic hydrocarbon Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000010058 rubber compounding Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical class C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- MSOUPGALSMOJRB-UHFFFAOYSA-N [Ni].C=CC=C Chemical compound [Ni].C=CC=C MSOUPGALSMOJRB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical compound O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111535053.XA CN114133632B (zh) | 2021-12-15 | 2021-12-15 | 矿用耐寒轮胎胎面胶及其制备方法 |
Applications Claiming Priority (1)
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---|---|---|---|
CN202111535053.XA CN114133632B (zh) | 2021-12-15 | 2021-12-15 | 矿用耐寒轮胎胎面胶及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN114133632A CN114133632A (zh) | 2022-03-04 |
CN114133632B true CN114133632B (zh) | 2023-05-09 |
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Family Applications (1)
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CN202111535053.XA Active CN114133632B (zh) | 2021-12-15 | 2021-12-15 | 矿用耐寒轮胎胎面胶及其制备方法 |
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CN (1) | CN114133632B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114425823A (zh) * | 2022-04-07 | 2022-05-03 | 山东万达宝通轮胎有限公司 | 一种橡胶混炼方法、混炼胶及应用 |
CN115627014A (zh) * | 2022-11-07 | 2023-01-20 | 中策橡胶集团股份有限公司 | 一种耐切割的矿山胎胎面胶组合物、制备方法、应用和轮胎 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6090889A (en) * | 1997-04-25 | 2000-07-18 | The Goodyear Tire & Rubber Company | Rubbery polymer with improved properties |
CN103214703B (zh) * | 2013-04-09 | 2015-02-18 | 徐州徐轮橡胶有限公司 | 一种耐寒水田轮胎 |
CN107973950B (zh) * | 2017-12-11 | 2020-01-21 | 泰凯英(青岛)专用轮胎技术研究开发有限公司 | 环保型井下用途工程轮胎胎面橡胶组合物及其制备方法 |
CN112566791B (zh) * | 2018-08-09 | 2022-12-06 | 株式会社普利司通 | 轮胎 |
CN112812388A (zh) * | 2020-12-30 | 2021-05-18 | 山东兴鸿源轮胎有限公司 | 耐低温和高抗湿滑的雪地胎胎面胶及其制备方法 |
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2021
- 2021-12-15 CN CN202111535053.XA patent/CN114133632B/zh active Active
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Address after: 266061, 9th and 10th floors, Building 2, No. 6 Keyuan Jingsan Road, Laoshan District, Qingdao City, Shandong Province Patentee after: Taikaiying (Qingdao) special tire technology research and Development Co.,Ltd. Country or region after: China Address before: 266000 room 1901, building 2, Tianbao international business center, 61 Haier Road, Laoshan District, Qingdao City, Shandong Province Patentee before: Taikaiying (Qingdao) special tire technology research and Development Co.,Ltd. Country or region before: China |