CN1140987A - High lathering and high depositing shampoos with mild surfactant system - Google Patents
High lathering and high depositing shampoos with mild surfactant system Download PDFInfo
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- CN1140987A CN1140987A CN 94194746 CN94194746A CN1140987A CN 1140987 A CN1140987 A CN 1140987A CN 94194746 CN94194746 CN 94194746 CN 94194746 A CN94194746 A CN 94194746A CN 1140987 A CN1140987 A CN 1140987A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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Abstract
Provided is a mild, high lathering shampoo composition with high deposition of functional materials, the shampoo composition comprising: (a) from about 5 % to about 40 %, by weight, surfactant system comprising: (i) from 80 % to about 99 %, by weight of the surfactant system, anionic surfactants which are alkyl ethoxylated sulfates and alkyl sulfates in a ratio between about 1:1 and 1:0; and (ii) from about 1 % to 20 %, by weight of the surfactant system, polyhydroxy fatty acid amide surfactants; (b) from about 0.05 % to about 25 %, by weight, functional materials; and (c) from about 35 % to about 95 %, by weight, water.
Description
Technical field
The present invention relates to a kind of shampoo Compositions, contain in the said composition just like conditioner, the functional substance of setting agent or dandruff removing agent and so on, especially it should be noted that, the present invention relates to a kind of soft shampoo Compositions, said composition has high spumescence, and makes the functional substance have high deposition property.Background technology of the present invention
Can must can be cleaned hair and dandruff by the shampoo Compositions that people accept, and to user security.But the advantage of preferred shampoo is not only simple cleaning and safety.For example, it is suitable adopting soft surfactant system in the shampoo, thereby makes shampoo have nonirritant, and to the scalp gentleness.
Other advantage that the multiple functional substance of adding has except that cleaning shampoo in shampoo also is suitable.This class functional substance comprises as conditioner, setting agent, dandruff removing agent and analog thereof.Preferred shampoo must make the deposition properties of functional substance on hair and scalp good, to such an extent as to these materials can provide their expection benefit.For example, conditioner must be able to be deposited on the hair effectively in the use of shampoo, to such an extent as to thereby conditioner is not rinsed the good conditioning performance can be provided.Similarly, dandruff removing agent must be deposited on the scalp effectively, thereby good anti-dandruff performance can be provided.
Another important parameters is a foam in the shampoo Compositions.Consumer connects high foam and effective cleaning usually, therefore would rather be reluctant to use the shampoo of low bubble property with the shampoo of height bubble property from aesthetic view point.
General soft shampoo prescription uses high-load nonionic in the presence of anion surfactant, cation and amphoteric surfactant are to obtain good soft property.But the foam volume of these prescriptions is starkly lower than the foam volume of the anion surfactant type shampoo prescription of normal sight.
Advantage of the present invention is to find that the shampoo that contains the specific surfactant system can not only provide suitable soft property, and high bubble property and functional substance's high deposition property can be provided.This surfactant system is to be combined with specific amount and ratio by specific anion surfactant and polyhydroxy fatty acid amide surfactant.Below with the present invention is described in further detail.
Unless add explanation in addition, all percent and ratios are all calculated by weight.Unless add explanation in addition, each component all is to be basis with the effective content, does not therefore comprise carrier or by-product, and these carriers or by-product can be included in the commercially available material.
Summary of the present invention
The invention provides a kind of soft, high foaming shampoo Compositions, contain the functional substance of high deposition properties in the said composition, the compositions of this shampoo comprises:
(a) about 5% surfactant system to about 40% (weight).This surfactant system comprises: (i) about 80% of surfactant system weight to about 99% anion surfactant, these anion surfactants are that the sulfate and the alkyl sulfate of alkyl ethoxylated combines in about 1: 1 to 1: 0 ratio; And (ii) about polyhydroxy fatty acid amide surfactant of 1% to 20% of surfactant system weight;
(b) functional substance of about 0.05% to 25% (weight); And
(c) water of about 35% to 95% (weight).
The advantage of shampoo Compositions of the present invention has provided soft property, the reasonable combination of high bubble property and functional substance's's (as conditioner, setting agent or dandruff removing agent) high deposition property.
Detailed description surfactant system of the present invention
Shampoo Compositions of the present invention contains a kind of specific surfactant system.People have found that this surfactant system has as to the scalp gentleness, the reasonable combination of advantages such as high bubble property and functional substance's's (conditioner, setting agent, dandruff removing agent etc.) high deposition property.This shampoo contains the surfactant system of about 5%～40% (weight), preferred about 7% to 35% weight, preferred 12% to 20% weight that is about.This surfactant system comprises: (i) about anion surfactant of 80% to 99% of surfactant system weight, this anion surfactant are that the sulfate and the alkyl sulfate of alkyl ethoxylated forms by about 1: 1 to 1: 0 mixed; And the (ii) polyhydroxy fatty acid amide surfactant of about 1%-20% of surfactant system weight.Alkyl ethoxy sulfate and alkyl sulfate surfactant
As mentioned above, the surfactant system of shampoo Compositions of the present invention comprises about 80% to 99% the anion surfactant of surfactant system weight, preferably about 85% to 95% weight, this anion surfactant are to be combined according to about 1: 1 to 1: 0 ratio by alkyl ethoxylated sulfate (" AES) and alkyl sulfate (" AS ").(AES: AS) be at least about 1: 1, this anion surfactant also can be 100%AES and do not have AS (be AES: AS is 1: 0) to the ratio of alkyl ethoxy sulfate and alkyl sulfate simultaneously.The ratio of preferred AES and AS is about 1: 1 to 10: 1, and the ratio of preferred AES and AS is about 2: 1 to 10: 1, and the ratio of most preferred AES to AS is about 2: 1 to 6: 1.
The structural formula of alkyl ethoxy sulfate and alkyl sulfate is respectively (I) RO (C
2H
4O) xSO
3M reaches (II) ROSO
3M, wherein R is that carbon number is approximately 9 to 18 alkyl or alkenyl, and X is 1 to 12, and M is hydrion or cation such as the ammonium salt that forms soluble-salt, alkanolamine such as triethanolamine, monovalent metal such as sodium ion (Na
+) and potassium ion (K
+), or multivalent metal cation such as magnesium ion (Mg
2+) or calcium ion (Ca
2+).The selection of the cation M of this anion surfactant should make this anion surfactant be water solublity.Dissolubility depends on the mixture and the selected cation of specific anion surfactant.As the mixture and the cation that help to determine suitable anion surfactant, it is about 15 ℃ or lower that the selection of anion surfactant should make the Krafft temperature of this surfactant, preferred temperature is about below 10 ℃ or 10 ℃, preferred temperature is about below 0 ℃ or 0 ℃, and preferably this anion surfactant is soluble in this shampoo Compositions simultaneously.The cation of preferably using among the present invention is ammonium ion (NH
4 +), sodium ion (Na
+) and/or magnesium ion (Mg
2+).
Ordinary circumstance, alkyl ethoxylated sulfate are to be that the condensation product of about monohydric alcohol of 9 to 18 is made with oxirane and carbon number.This monohydric alcohol can be from fat, as Oleum Cocois, and palm-kernel oil, or obtain in the Adeps Bovis seu Bubali, or synthetic.This monohydric alcohol is preferably with about 1 to 10, more preferably with about 1 to 4, most preferably with the reacting ethylene oxide of about 2 to 3.5 mol ratios, for example with gained, every mol of alcohol has the molecule mixture of average 3 moles oxirane, carries out sulphation and neutralization.
Suitable alkyl ethoxylated sulfate is comprising Cortex cocois radicis alkyl triethylene glycol ether sulfate, tallow alkyl triethylene glycol ether sulfate, tallow alkyl hexaoxyethylene sulfate, and the sodium salt and the ammonium salt of lauryl triethylene glycol ether sulfate.Preferred alkyl ethoxylated sulfate is the sodium salt and the ammonium salt of lauryl triethylene glycol ether sulfate, also is called " laureth-3 sodium sulfate " and " laureth-3 ammonium sulfate " or " lauryl (EO)
3Sodium sulfate " and " lauryl (EO)
3Ammonium sulfate ".
Alkyl sulfate generally is by long carbochain alcohol sulphation and neutralization and make, and these alcohol can be natural, perhaps can be synthetic alcohol.The industrial process of alkyl sulfate is made in many suitable being used to, and concerning those are proficient in the people in surfactant field, is known.
Suitable alkyl sulfate is comprising lauryl sulfate, the Cortex cocois radicis alkylsurfuric acid and vitriolic sodium salt of tallow alkyl and ammonium salt.Being preferred for of the present invention is the sodium salt and the ammonium salt of lauryl sulfate.
Polyhydroxy fatty acid amide surfactant
The surfactant system of shampoo Compositions of the present invention also comprises about 1%-20% (surfactants based weight), is preferably about 5% polyhydroxy fatty acid amide surfactant to about 15% (weight).It has been found that the anion surfactant of stipulating among the present invention and the amount of polyhydroxy fatty acid amide surfactant not only make shampoo have soft property, also have high bubble property and functional substance's high deposition property simultaneously.
This polyhydroxy fatty acid amide surfactant comprises the chemical compound with following array structure:
Wherein: R
1Be H, C
1-C
4Alkyl, 2-hydroxyethyl, 2-hydroxypropyl or its mixture, preferably C
1-C
4Alkyl, more preferably C
1Alkyl (being methyl); R
2Be C
5-C
31Alkyl, the C of straight chain preferably
7-C
19Alkyl or alkenyl, the more preferably C of straight chain
9-C
17Alkyl or alkenyl, the most preferably C of straight chain
11-C
16Alkyl or alkenyl, perhaps its mixture; Z is a kind of polyhydroxy alkyl, and this group contains at least three linear hydrocarbyl chains of directly linking the hydroxyl on the chain, or the derivant of a kind of its alkoxide (being preferably ethoxylation or propoxylation).Preferably, Z derives from a kind of reducing sugar in reduction amination; More preferably, Z is a kind of glycosyl.Suitable reducing sugar comprises glucose, fructose, maltose, lactose, galactose, mannose and xylose.The corn syrup of the corn syrup of high-load glucose, the corn syrup of high content fructose and high-load maltose also can be as above-named single sugar as raw material, and Z also can be the mixture by a kind of saccharic composition of these syrup generations.It should be understood that this wants to get rid of other proper raw material anything but.Z preferably is selected from-CH
2-(CHOH)
n-CH
2OH ,-CH (CH
2OH)-(CHOH)
N-1-CH
2OH and-CH
2-(CHOH)
2(CHOR ') (CHOH)-CH
2OH, wherein n is the integer of from 3 to 5 (comprising 3 and 5), R ' is H or a kind of ring-type or aliphatic monosaccharide, with and oxyalkylated derivant, the glycosyl of n=4 most preferably, especially-CH
2-(CHOH)
4-CH
2OH.R
1Can be, as N-methyl, N-ethyl, N-propyl group, N-isopropyl, N-butyl, N-2-hydroxyethyl or N-2-hydroxypropyl.R
2-CO-N＜can be, for example, coconut monoethanolamide, stearmide, oils and fats amide, lauramide, myristamide, decyl amide, palmitamide or Adeps Bovis seu Bubali amide.Z can be, for example, and 1-deoxyglucose base, 2-deoxidation fructosyl, 1-deoxidation malt-base, 1-deoxidation lactose base, 1-deoxy-galactose base, 1-deoxymannose base or 1-deoxidation maltotriose glycosyl.
The method of producing polyhydroxy fatty acid amide is known in present technique.Usually, their method for making is that a kind of alkylamine and a kind of reducing sugar are formed the corresponding N-alkyl polyhydroxy amine by reduction amination, then with this N-alkyl polyhydroxy amine and a kind of fatty acid ester or triglyceride by condensation/amidation process formation N-alkyl, N-polyhydroxy fatty acid product.Produce and contain the polyhydrony fatty acid method for compositions and have been disclosed in, for example by Th-omas Hedley ﹠amp; Co.Ltd is in the british patent specification 809 of bulletin on February 18 nineteen fifty-nine, 060, the United States Patent (USP) that belongs to E.R.Wilson 2 of nineteen sixty December bulletin on the 20th, 965, the United States Patent (USP) that belongs to Piggott 2,703 of 25, bulletins of 576,1934 on Decembers, 798 (Anthony M.Schwartz), the present invention is incorporated herein by reference above-mentioned each patent.
At a preparation N-alkyl or N-hydroxy alkyl, in the method for N-deoxyglucose base fatty acid amide, wherein the glycosyl component derives from glucose, N-alkyl or N-hydroxy alkyl degree of functionality are the N-methyl, the N-ethyl, the N-propyl group, the N-butyl, N-ethoxy or N-hydroxypropyl, the method for making of this product is with N-alkyl or N-hydroxyalkyl-glucamine and a kind ofly is selected from fatty methyl ester, the fatty ester of fat ethyl ester and fat triglyceride reacts in the presence of a kind of catalyst and forms, and this catalyst is selected from lithium phosphate, sodium phosphate, potassium phosphate, tetrasodium pyrophosphate, pentapotassium tripolyphosphate, Lithium hydrate, sodium hydroxide, potassium hydroxide, calcium hydroxide, lithium carbonate, sodium carbonate, potassium carbonate, disodium tartrate, di-potassium tartrate, potassium sodium tartrate, trisodium citrate, potassium citrate, alkali formula sodium silicate, alkali formula potassium silicate, alkali formula sodium aluminosilicate, alkali formula potassium aluminosilicate and composition thereof.Catalyst consumption is preferably about 0.5% (mole) to about 50% (mole), more preferably be about 2.0% (mole) to 10% (mole), (based on the molal quantity of N-alkyl or N-hydroxyalkyl-glucosamine).This reaction was preferably generally reacted about 20 to 90 minutes down at about 138 ℃ to about 170 ℃.When in the reactant mixture with triglyceride during as the fatty acid ester source, about 1% consisting of phase-transferring agent to about 10% (weight) (weight based on the entire reaction mixture is calculated) is preferably used in reaction, this consisting of phase-transferring agent is selected from the many ethoxylates of saturated aliphatic alcohol, alkoxyl poly glucoside (alkylopolyglucoside), line style glucamide surfactant with and composition thereof.
Preferably, this course of reaction is carried out as follows:
(a) fatty acid ester is preheated to about 138 ℃ to about 170 ℃;
(b) N-alkyl or N-hydroxyalkyl glucosamine are joined in the fatty acid ester of heat, and be blended into the required degree of a kind of liquid/liquid two-phase mixture of formation;
(c) with catalyst mix in reactant mixture; And
(d) in the response time of regulation, stir.
Simultaneously preferably, when fatty acid ester is triglyceride, the preformed line style N-alkyl of about 2% to 20% (based on weight of reactant) or N-hydroxyalkyl, N-line style glucityl fatty acid amide product are added in the reactant mixture as consisting of phase-transferring agent.This has activated reaction, has therefore improved response speed.
The polyhydroxy that uses among the present invention " fatty acid " amide material provides such benefit for the shampoo formulatory: promptly shampoo can all or basically by natural, callable, non-petrochemical material be made into, and can be degraded.They show hypotoxicity to aquatile simultaneously.
Must recognize, in the preparation polyhydroxy fatty acid amide, also can produce a certain amount of nonvolatile by-product such as acyl amine and ring-type polyhydroxy fatty acid amide in this process.These content of by-products are according to specific reactant and preparation condition and different.Preferably, the form that adds the polyhydroxy fatty acid amide in the shampoo Compositions of the present invention should make to contain in the polyhydroxy fatty acid amide and be lower than approximately 10%, be preferably lower than about 4% ring-type polyhydroxy fatty acid amide.The advantage of above-mentioned this method for optimizing is that they can produce the quite low by-product of content, comprise this cyclic amide by-product.Alternative surfactant
Except the surfactant of " surfactant system " of formation above-mentioned shampoo Compositions of the present invention, shampoo of the present invention also can comprise the surfactant that is used for shampoo that other present technique field personnel know, as other anionic, non-ionic, cationic, zwitterionic and/or amphoteric surfactant.Preferred shampoo comprise be no more than about 15%, most preferred about 10% the optional surfactant that is no more than.Be suitable for various surfactants in the shampoo and be described in detail in the 6th hurdle of the United States Patent (USP) of announcing on July 9th, 1,992 5,120,532 that belongs to people such as Wells, the 35th row is to the 14th hurdle, the 17th row (the present invention introduces this patent as a reference).(as described in people's such as Wells patent, some cationic surfactant also can be used as conditioner; In this case, the present invention comprises them in " conditioner " scope that is discussed below, and is not included in " optional surfactant ".) conditioner
As mentioned above, contain the functional substance of about 0.05% to 25% (weight) in the shampoo Compositions of the present invention, preferably contain about 0.1% to 10% (weight).
The functional substance can comprise one or more conditioners that present technique field personnel know, the preferred consumption of this conditioner is about 0.05% to about 8% of a shampoo Compositions weight, more preferably about 0.2% to about 5% (weight), most preferably is about 0.2% to about 4% (weight).Preferred conditioner comprises cationic material (cationic surface active agent and cation type polymer), hydrocarbon ils, and the blend of silicone oil and silica gel material.
The cationic surface active agent that is preferably used as conditioner of the present invention is quaternary amine or amino-compound, this amino-compound has a N-substituent group that contains one or more non-ionic hydrophilic group at least, these hydrophilic groups be selected from alkoxyl, polyoxyalkylene, alkylamidoalkyl, hydroxyalkyl and alkyl ester group, with and compositions.The substituent group carbon number that this surfactant contains on a quaternary nitrogen atoms or the cationic amino nitrogen atom at least is no more than 4 (comprising 4), the hydrophilic group that preferably is no more than 3 (comprising 3).Be purpose of the present invention, this means that the nearest non-carbon atom of cations nitrogen must be within the carbon atom number (with respect to said nitrogen-atoms) of regulation in the hydrophilic group.In addition, as the carbon atom adjacent with other hydrophilic group of a part of hydrophilic group, for example the hydrophilic polyoxyalkylene is (as ,-CH
2-CH
2-carbon atom in O-) is when the decision hydrophilic segment contains the carbon atom that is no more than 4 (or preferred 3) cationic nitrogen, in this part carbon atom is not included in.Usually, the moieties of any one hydrophilic group is C
1-C
3Alkyl.Suitable hydrophilic radical as non-ionic hydrophilic group comprises, as ethyoxyl, propoxyl group, polyoxyethylene, polyoxypropylene, acetamido, propionamido-, methylol, ethoxy, hydroxypropyl, methyl ester, ethyl ester, propyl diester or its mixture.
Be applicable to that quaternary ammonium salt cationic surfactant of the present invention is the material with following general formula:
R wherein
1, R
2, R
3, R
4Group comprises that respectively carbon number is approximately 1 to 30 replacement or unsubstituted hydrocarbon chain, or carbon number be 1 to 30 alkyl and contain one or more aromatics, ether, ester, amide or amino bridged bond as substituent group or group chain exist, R wherein
1-R
4At least one contains one or more alkoxyls that are selected from and (is preferably C in the group
1-C
3Alkoxyl), polyoxyalkylene (is preferably C
1-C
3Polyoxyalkylene), alkylamide, hydroxyalkyl, Arrcostab and composition thereof.Preferably, this cationic conditioning surfactant contains the non-ionic hydrophilic group in about 2～10 above-mentioned scopes.For the purposes of the present invention, each hydrophilic amide groups, alkoxyl, hydroxyalkyl, Arrcostab, alkylamidoalkyl or other group are considered to a kind of typical non-ionic hydrophilic group.X is a kind of anion that forms soluble-salt, and it preferably is selected from halogen (especially chlorine), acetate ion, phosphate anion, nitrate ion, sulfonate ion and alkylsurfuric acid salt ion.
Preferred quaternary surfactant comprises the material with following structural formula:
Wherein, n is 8～28, is preferably 16, and X+Y=2 is to about 15.Z is a short-chain alkyl, is preferably C
1-C
3Alkyl, methyl more preferably, X is for forming anion (for example, Cl, the SO of water soluble salt
4 2-Or the like).
Other preferred quaternary surfactant comprises the material with following structural formula:
Z wherein
1And Z
2Be respectively replacement or unsubstituted alkyl, preferably, Z
1Be alkyl (C preferably
1-C
3Alkyl more preferably is a methyl), Z
2Be the short chain hydroxyalkyl, be preferably methylol or ethoxy, n and m are respectively 2～4 integer (comprising 2 and 4), are preferably 2～3 integer (comprising 2 and 3), more preferably 2, R ' and R " is respectively and replaces or unsubstituted alkyl, be preferably C
12-C
20Alkyl or alkenyl, X is anion (for example, the SO that forms water soluble salt
4 2-, Cl
-, or the like).
The object lesson of preferred quaternary ammonium salt comprises polyoxyethylene (2) stearyl ammonio methacrylate, methyl two (hydrogenated tallow amido-ethyl) 2-ethoxy methylsulfuric acid ammonium, polyoxypropylene (9) diethylmethyl ammonium chloride, three polyoxy ethylene (total PEG=10) stearyl ammonium phosphate, two (N-ethoxy-2-oil-based imidazoline chloride) Polyethylene Glycol (12), and Fancol ID base phenyl three ethanol based ammonium chloride.Especially preferred is three (cetyl) ammonio methacrylate (" TCMAC "), and it can have been bought from AKzo-Chemie, is 90% suspension, and its commodity are called ARQUAD-316.
Another particularly preferred cationic surfactant is VARISOFT110 (a dihydro Adeps Bovis seu Bubali base acylamino-ethyl-hydroxyethyl ammonium methoxyl group sulfate).
The cationic polymer hair conditioner is water miscible cationic organic polymer.The mean molecule quantity of cation type polymer of the present invention generally is approximately 5,000 at least, is at least about 10,000 and be no more than 10,000,000 usually.Cation type polymer contains cationic nitrogen-containing group such as quaternary ammonium salt or cationic amino group or its mixture.This cationic nitrogen-containing group normally exists as a substituent group, and this substituent group is on the part of the whole monomeric unit of cationic hair conditioning polymer.Like this, this cation type polymer can comprise that quaternary ammonium salt or the cationic amino monomeric unit that replaces and other the present invention are as the unitary copolymer of non-cationic of basic monomeric unit at interval, terpolymer or the like.Such polymer is known in the prior art, many can be in CTFA cosmetic composition dictionary, the third edition, by Estrin, Crosley and Haynes edit (The Cosme-tic Toiletry.and Fragrance Association, Inc., Washington, D.C.1982).
Suitable cationic hair conditioning polymer comprises, for example: l-vinyl-2-pyrrolidone and the 1-vinyl-3-methyl-imidazoline salt (for example, villaumite) copolymer, (in cosmetics, emollient, perfume association " CTFA " industry, being called Polyquaterni-um-16), as can (Parsippany, NJ USA) have bought from BASF Wyandotte company on those markets, its commodity are called LUVIQUAT (for example, LUVIQUAT FC370); The copolymer of l-vinyl-2-pyrrolidone and dimethoxy-ethyl methacrylate (in CTFA industry, being called Polyquaternium-11), as can buy from Gaf company on those markets (Wayne, NJ, USA), its commodity are called GAFQUAT (for example, GAFQUAT 755N); High molecular quarternary ammonium salt compound such as hydroxypropyl three ammonium chloride guar gums (guar hydro-xypropyltrimonium chloride) (can buy with JAG-UAR commodity series from Rhone-Poulenc on the market); The cationic polymer that contains the diallyl quaternary ammonium salt, comprise, for example, the copolymer of dimethyl diallyl ammonium chloride homopolymer and acrylamide and dimethyl diallyl ammonium chloride is called Polyquaternium 6 and Polyquaternium 7 respectively in CTFA industry; And the mineral acid salt (United States Patent (USP) 4,009,256 in be described) that the amino-Arrcostab of the homopolymerization of unsaturated carboxylic acid of 3～5 carbon atoms or copolymer is arranged, introduce among the present invention as a reference.
Other operable cationic polymer comprises polysaccharide polymer, as cationic cellulose derivative and cationic starch derivant.Cationic cellulose is the salt that is formed by the epoxide reaction that hydroxyethyl-cellulose and trimethyl ammonium replace, (CTFA) is called Polyquaternium 10 in industry, Polyquaterninm 10 can be from (the Edison of Amerchol company, NJ, USA) with polymer JR and LR commodity series polymer and obtain, also can be from (the Danbury of Union Carbide Corporation, Connecticut, USA) obtain with commodity UCARE POLYMER JR series by name, for example, UCARE POLYMER JR-30M, JR-125 and JR-400.The cationic cellulose of other type comprises the high molecular quaternary ammonium salt that the epoxide reaction of hydroxyethyl-cellulose and the replacement of lauryl dimethyl ammonium obtains, and (CTFA) is called Polyquaternium 24 in industry.These materials can (Edison, NJ USA) obtain, and its trade mark is called Polymer LM-200 from Amerchol company.
Organically hair conditioner also can be as the conditioner of shampoo Compositions of the present invention.Organic hair conditioning material among the present invention comprises the liquid that is selected from hydrocarbon ils and fatty acid ester.Hydrocarbon ils comprises cyclic hydrocarbon, straight chain aliphatic hydrocarbon (saturated or unsaturated) and a chain aliphatic hydrocarbon (saturated or unsaturated).The straight chain hydrocarbon ils preferably contains about 12～19 carbon atoms, and the side chain hydrocarbon ils can and contain the more carbon atom of more number usually.By alkenyl monomer, as C
2-C
6The hydrocarbon that aggregates into of alkenyl monomer be also contained among the present invention.These polymer can be the polymer of straight or branched.The straight chain polymer normal length is shorter relatively, and its total carbon number is general identical with the carbon number of above-mentioned straight chain hydrocarbon ils.Branch polymer has higher carbon chain lengths usually.The mean molecule quantity of this class material changes greatly, but generally reaches as high as approximately 500, is preferably about 200～400, more preferably about 300～350.The instantiation of suitable material comprises mineral oil (preferably), paraffin oil, saturated and undersaturated dodecane, saturated and undersaturated tridecane, saturated and the undersaturated tetradecane, saturated and undersaturated pentadecane and saturated and undersaturated hexadecane with and composition thereof.Also can use the branched chain isomer of these chemical compounds and the branched chain isomer of longer carbon chain compound.Typical branched chain isomer is the saturated or undersaturated alkane of height collateralization, as complete methyl substituted isomer, as the complete methyl substituted isomer of hexadecane and eicosane, as 2,2,4,4,6,6,8,8-dimethyl-10-methyl hendecane and 2,2,4,4,6,6-dimethyl-8-methylnonane, they are sold by Permethyl Corporation.High molecular hydrocarbon ils also can be used as conditioner.A kind of preferred hydrocarbon polymer is a polybutene, as the copolymer of isobutene. and n-butene; Commercially available such material is Amoco Chemical Co. (Ch-icago, Illinois, Indopol L-14 polybutene U.S.A).Other macromolecule conditioner comprises polyisoprene, polybutadiene and other C
4-C
12Straight chain and the list of side chain and two monomeric hydrocarbon polymer of unsaturated fatty acids and derivants thereof.
Feature as the fatty acid ester of conditioner is to have 10 carbon atoms at least, and comprises the ester that contains the hydrocarbon chain that derives from fatty acid or alcohol, as monoesters, and polyol ester, and two and tricarboxylic ester.The alkyl of fatty acid ester of the present invention also can comprise or have covalent bonds other suitable degree of functionality thereon, as amide and alkoxyl (as ethyoxyl or ether chain, or the like).
Other conditioner that is suitable for shampoo Compositions of the present invention comprises water-fast nonvolatile siloxanes hair conditioner.Silicone conditioning agent comprises a kind of silicone liquid, also comprise simultaneously other composition, as silicone resin with the deposition efficiency of strengthening silicone liquid or the gloss that strengthens hair (especially when using high refractive index, as about silicone conditioning agent more than 1.46, as the height benzene siloxanes in generation).
The siloxanes hair conditioner also can comprise volatile silicone component.Usually, when having volatile siloxane, it is normally as the solvent or the carrier that are used for the non-volatile siloxane composition (as siloxane glue and resin) of commercially available form.
The content of normally used siloxanes hair conditioner in the shampoo Compositions of the present invention, weight according to compositions is calculated, and is approximately 0.05%-10%, is preferably about 0.1%-8%, more preferably be about 0.1%-5%, most preferably be approximately 0.1%-4%.
Silicone liquid among a kind of the present invention of can be used for is a silicone oil.Viscosity was 1,000 when the meaning of " silicone oil " title was meant 25 ℃, the flowable silicone material that 000 centistoke is following.Usually, the viscosity of this class I liquid I (25 ℃) is approximately 5-1, and 000,000 centistoke is preferably about 10-100,000 centistoke.Suitable silicone oil comprises many alkylsiloxanes, polyaryl siloxanes, many alkylaryls siloxanes, polyether radical siloxane copolymer and composition thereof.That also can use other has the insoluble of hair conditioning performance, a nonvolatile silicone liquid.
Especially it should be noted that the silicone oil of using among the present invention comprises many alkyl or the polyaryl siloxanes with following array structure:
Wherein R is aliphatic group (being preferably alkyl or alkene), or aryl, and R can be replacement or non-replacement, and X is an about 1-8,000 integer.The R base of suitable non-replacement comprises what alkoxyl, aryloxy group, alkylaryl, aryl alkyl, aryl alkenyl, alkylamino and ether replaced, and hydroxyl replaces, and the aliphatic group and the aryl of halogen atom replacement.The suitable R base also comprises the group of cationic amine and quaternary ammonium.
Aliphatic or aromatic substituents at the siloxanes chain substitution can have as long as guarantee the arbitrary structures that resulting siloxanes has following properties, these characteristics comprise: at room temperature be liquid, hydrophobic, non-stimulated, nontoxic, harmless to hair when being used for hair, compatible with other composition energy of compositions, chemical property is stable under common use and storage requirement, is insoluble in compositions, can be deposited on the hair and the energy conditioning hair.
Two R bases on the silicon atom of each siloxanyl monomers can be identical group or different groups.Preferably, two R bases are identical groups.
Preferred alkyl and alkenyl group are C
1-C
5Alkyl and thiazolinyl are more preferably C
1-C
4, most preferably be C
1-C
2Other contains alkyl, and the aliphatic portion of the group of alkenyl or alkynyl (as alkoxyl, alkaryl and alkylamino) can be a straight or branched, preferably have 1-5 carbon atom, more preferably have 1-4 carbon atom, more preferably have 1-3 carbon atom again, most preferably have 1-2 carbon atom.As discussed above, R substituent group of the present invention also can comprise amino functionality, and as alkylamino, it can be primary amine, secondary amine, tertiary amine or quaternary amine.These groups comprise the aliphatic portion chain length be preferably the list of above-mentioned length-, two-and three-alkylamino and alcoxyl amino.This R substituent group can replace through other base, as halogen atom (for example, Cl, F, Br), and halogenated aliphatic or aromatic group, and hydroxyl (as the aliphatic group of hydroxyl replacement).Suitable halogenated R base can comprise, as the alkyl of three halos (being preferably fluoro), as-R
1-C (F)
3, R wherein
1Be C
1-C
3Alkyl.The example of such polysiloxanes comprises poly-methyl-3,3, the 3-trifluoropropyl siloxane.
Operable nonvolatile poly-alkylsiloxane oil comprises, as polydimethylsiloxane.These alcoxyl alkane can from, obtain with DowCorning200 series commodity with Viscasil R and SF96 series commodity and from Dow Corning as General Electric Company (General Electric).Polydimethyl siloxane oil also is called " dimeth-icone " oil.
Operable polyoxyethylene alkyl aryl radical siloxane oil also comprises, as PSI.These siloxanes can from, for example, General Electric Company obtains with 556 cosmetics-stage liquid commodities with SF1075 aminomethyl phenyl liquid commodity or from Dow Corning.
Operable polyether siloxane copolymer comprises that for example, a kind of polydimethylsiloxane of poly(propylene oxide) modification (for example, Dow Corning DC-1248) is although also can use the mixture of oxirane or oxirane and expoxy propane.
Another silicone liquid that is particularly useful in silicone conditioning agent is insoluble silicone gum.Viscosity when " silicone gum " used among the present invention is meant 25 ℃ is more than or equal to 1,000, the polysiloxanes of 000 centistoke.Petrarch and other people describe " silicone gum " conduct: comprise United States Patent (USP) 4,152,416, (announcing on May 1st, 1979) and Noll by people such as Spitzer, Walter is at New York Academic Press, the Chemistry and Technology of Silicone.GeneralElectric Silicone Rubber Product Data Sheets SE30 that nineteen sixty-eight publishes, SE33, SE54 and SE76 also are described silicone gum.The present invention introduces these reference materials as a reference.The molecular weight of " silicone gum " generally surpasses 200,000 approximately, usually greatly about 200,000 to 1,000, between 000.Object lesson comprises polydimethylsiloxane, (polydimethylsiloxane) (ethylene methacrylic radical siloxane) copolymer, poly-(dimethyl siloxane) (diphenyl siloxane) (ethylene methacrylic radical siloxane) copolymer with and composition thereof.The polydimethylsiloxane sizing material also is called " dimethicone " sizing material.
Preferably, the siloxanes hair conditioner comprises that (viscosity is approximately 1 to a kind of polydimethylsiloxane sizing material, 000, more than 000 centistoke) and polydimethyl siloxane oil (viscosity is approximately 10-100,000 centistoke) mixture, wherein the ratio of sizing material and liquid is approximately 30: 70 to 70: 30, is preferably about 40: 60 to 60: 40.
United States Patent (USP) 5,100, the 13rd hurdle of 657 (belong to people such as Ansher-Jackson, on March 31st, 1992 announced), the 65th row be to the 18th hurdle, the 47th row to the silicone hair conditioner as describing (introduce among the present invention as a reference) in detail.
Be suitable for many dissimilar conditioners of the present invention and in following patent (introduce the present invention in as a reference), done further description: United States Patent (USP) 5,100,657 (belong to people such as Ansher-Jackson, announced on March 31st, 1992); United States Patent (USP) 5,106,609 (belong to Bolich, people such as Jr. announced on April 21st, 1992); And United States Patent (USP) 5,120,532 (belong to people such as Wells, announced on June 9th, 1992).
Preferred shampoo Compositions of the present invention comprises the mixture that can be deposited on the following functional substance on the hair: hydroxypropyl three ammonium chlorides (hydroxypropyltrimonium chl-cride) guar gum (preferred content is about 0.05% (weight)～0.70% (weight)), hydrocarbon ils (preferred content is about 0.10% (weight)～1.40% (weight)), and the mixture of polydimethyl siloxane oil and poly dimethyl silane sizing material (preferred content is about 0.1% (weight)-4.0% (weight)).Dandruff removing agent
Dandruff removing agent also can be as the functional substance of shampoo Compositions of the present invention.Suitable dandruff removing agent comprises, for example, and sulfur, selenium sulfide and pyrithione.Preferred dandruff removing agent is the heavy metallic salt and the selenium sulfide of 1-hydroxyl-2-pyrithione.The preferred consumption of dandruff removing agent is about 0.1%-5% of shampoo Compositions weight, more preferably is about 0.3%-5%.
Selenium sulfide is commercial material commonly used.It is considered to the chemical compound of 1 mole of selenium and 2 molar sulphur usually.But it can have the circulus form, SexSy, wherein x+y=8.United States Patent (USP) 2,694,668 (people such as Baldwin announced on November 16th, 1954); United States Patent (USP) 3,152,046 (Kapral announced on October 6th, 1984); United States Patent (USP) 4,089,945 (Brinkman announced on May 16th, 1978); And United States Patent (USP) 4,885,107 (Wetzel announced in December in 1989 on the 12nd); More than these are introduced the present invention's patent as a reference selenium sulfide are described as active component in the antidandruff shampoo compositions.Selenium sulfide (selenium sulfide) below about 15 μ of average out to, more preferably is below about 10 μ preferably.Can use a forward direction laser light scattering device (for example, Malvern3600 device) to measure.
Preferred pyrithione dandruff removing agent is water-fast 1-hydroxyl-2-pyrithione, and preferred salt is heavy metallic salt, as zinc, stannum, cadmium, magnesium, aluminum and zirconium.Most preferred metal is a zinc among the present invention.Most preferred active component is the zinc salt of 1-hydroxyl-2-pyrithione, is called Zinc Pyrithione (ZPT) usually.Other cation also is suitable as sodium, and the dandruff removing agent of these types is known in the prior art.Following patent disclosure used 1-hydroxyl-2-pyrithione in the antidandruff shampoo: United States Patent (USP) 2,809,971 (Berns-tein announces October 15 nineteen fifty-seven); United States Patent (USP) 3,236,733 (people such as Karsten announced on February 22nd, 1966); United States Patent (USP) 3,753,196 (Parran announced on August 21st, 1973); United States Patent (USP) 3,761,418 (Parran, JIUYUE was announced on the 25th in 1973); United States Patent (USP) 4,345,080 (Bolich announces August 17 nineteen eighty-two); United States Patent (USP) 4,323,683 (people such as Bolich announces April 6 nineteen eighty-two); United States Patent (USP) 4,379,753 (Bolich announces April 12 nineteen eighty-three) and United States Patent (USP) 4,470,982 (Winkler, JIUYUE was announced on the 11st in 1984); The present invention introduces above-mentioned patent as a reference.Especially preferred be those with 1-hydroxyl-2-pyrithione that particulate form exists, wherein the average-size of particle reaches as high as about 20 microns, preferably reaches as high as about 8 microns, most preferably reaches as high as about 5 microns.Hairspray
Functional substance used in the shampoo Compositions of the present invention also can comprise one or more setting agents, designs this class material and helps user and make the hair washed keep specific shape.The consumption (based on the weight of shampoo Compositions) of preferred hairspray is preferably about 0.2%-20%, more preferably about 2%-6%.
Hairspray can be selected from various kinds of resin and sizing material.The preferred setting agent of the present invention comprises the polymer compatible with shampoo, and these polymer are the homopolymer or the copolymer of hydrophobic monomer normally.In addition, can be the copolymer of a kind of hydrophilic monomer and a kind of hydrophobic monomer as the hydrophilic polymer of setting agent of the present invention, or its mixture.The example of complicated polymer system can be found in following patent: United States Patent (USP) 3,222,329 (belonging to people such as Grosser, in the announcement on the 7th of nineteen sixty-five December); United States Patent (USP) 3,577,517 (belong to people such as Kubot, announce) on May 4th, 1971; United States Patent (USP) 4,012,501 (belong to Farber, announce) on March 15th, 1977; United States Patent (USP) 4,272,511 (belong to Papantoniou and Mondet, announce) on June 9th, 1981; United States Patent (USP) 4,196,190 (belong to people such as Gehman, announce) on April 1st, 1980.The example of block polymer system can be found in following patent: United States Patent (USP) 3,907,984 (belong to people such as Calvert, announced in 23rd in JIUYUE in 1975); United States Patent (USP) 4,030,512 (belong to people such as Papantoniou, announce) on June 21st, 1977; And United States Patent (USP) 4,283,384 (belong to people such as Jacquet, announce) on August 11st, 1981.
The hair fixing copolymer that is preferably used as setting agent of the present invention is at United States Patent (USP) 5,120, the 2nd hurdle of 531 (belong to people such as Wells, announce) on June 9th, 1992, and the 35th walks to the 4th hurdle, and the 68th row is described; On the 5th hurdle of this patent, the 1st walks to the 6th hurdle, and the 16th row is described (all these all introduce among the present invention as a reference) to the used solvent of polymer.Water
The water that comprises about 35%-95% (weight) in the shampoo Compositions of the present invention.The water that contains the 50%-85% that has an appointment in the preferred shampoo Compositions contains the water of the 60%-80% that has an appointment in the most preferred compositions.
The pH value of this shampoo Compositions is unimportant, can be preferably about 4-8 in about 2-10 scope, more preferably about 5.5-8.Optional ingredients
Many other optional compositions also can be used in the shampoo Compositions of the present invention.The optional component of this class comprises, for example, and antiseptic such as benzylalcohol, p-hydroxybenzoic acid methyl formate, propyl parabene and imidazolidinyl urea; The high molecular foam booster of quaternary amine type preferably is about the 0.01%-0.2% of composition weight; Aliphatic alcohol; The block polymer of oxirane and expoxy propane, the Pluronic F88 that provides as BASF Wyandotte; Ammonium xylene sulfonate; Propylene glycol; Polyvinyl alcohol; Ethanol; PH regulator such as sodium dihydrogen phosphate, sodium hydrogen phosphate, citric acid, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate, or the like; Chelating agen such as ethylenediaminetetraacetic acid (EDTA) salt; Thickening agent such as sodium chloride; Spice and dyestuff.But the common consumption of these optional components is approximately the 0.01%-10% of composition weight.Above-named optional components is not got rid of other component, can use other optional ingredients yet.
Shampoo Compositions of the present invention can randomly comprise a kind of suspending agent; this suspending agent is used for the dandruff removing agent (or other functional substance) of particle shape and is used for thickener composition; its content generally is about the 0.5%-10% of shampoo weight; preferred crystalline suspending agent is the acyl derivative of long carbochain and the amino oxide of long carbochain, and the mixture of this class material.Comprise: long carbochain glycol ester, the alkanolamide of long carbon chain fatty acid, the long carbochain ester of long carbon chain fatty acid, the glyceride of long carbochain, the long carbochain ester of long carbochain alkanolamide, and long alkyl chain length dimethyl amine oxide and composition thereof.United States Patent (USP) 4,741,855 (Grote and Russell announced on May 3rd, 1988) are described the example of the crystalline suspending agent of this class, introduce the present invention as a reference.Other operable optional suspending agent comprises high molecular thickening agent, as carboxy vinyl polymer.Preferred carboxy vinyl polymer is acrylic acid and polyene propyl group sucrose crosslinked copolymers, and as United States Patent (USP) 2,798,053 (Brown announced July 2 nineteen fifty-seven) is described, introduces among the present invention for referencial use.With for example, Carbopol 934,940,941 and 956 commodity provide these polymer by B.F.Goodrich Company.
Other also can comprise that those can make compositions have gel viscosity as the material of optional suspending agent, as water miscible or gelationus water miscible polymer such as cellulose ether (for example, hydroxyethyl-cellulose), guar gum, polyvinyl alcohol, polyethylene pyrrolinone, hydroxypropyl guar gum, starch and starch derivatives, and other thickening agent, viscosity modifier, gellant, or the like.Also can use the mixture of these materials.Another kind of operable suspending agent is an xanthan gum.Utilize xanthan gum as the shampoo Compositions of the suspending agent of siloxanes hair conditioning component at United States Patent (USP) 4,788, be described in 006 (Bolich and Williams announced on November 29th, 1988), introduce the present invention as a reference.Kelco, Merch ﹠amp; Co.Inc. a department provides xanthan gum with the KeltrolR commodity.Xanthan gum when being used as the suspending agent of siloxanes hair conditioning component, generally exists with the mobile liquid dosage form, and its content is about 0.02%-3% of present composition weight, is preferably about 0.03%-1.2%.
Following Example has further described and has illustrated preferred embodiment within the scope of the present invention.These examples only are used for further instruction, and can not to be construed to be restriction of the present invention, because can allow many variations that do not break away from its spirit and scope.Embodiment 1-4
Shampoo Compositions of the present invention is prepared as follows.Wherein the percent of being given all is based on the percent that shampoo weight is calculated.
Embodiment composition 1234 ammonium lauryl sulfate, 6.6 2.5 2.3 3.5 lauryls (EO)
3Ammonium sulfate 12.1 15.0 12.8 8.4 lauryl N-methyl glucose amides 2.0 2.5 2.0 2.1 polydimethylsiloxanemixture mixture
10.8 0.5 0.5 1.0 guar gum derivatives
2-0.2--hydrocarbon ils
3-0.4--fatty alcohol--0.6 0.6 diglycol stearate 1.5 1.5 2.0 1.5EDTA disodium salts, 0.1 0.1 0.1 0.1 sodium dihydrogen phosphates and sodium hydrogen phosphate 0.4 0.4 0.4 0.4 sodium chloride, 1.0 1.0 1.0 1.0 pigment solution 0.1 0.1 0.1 0.1 spice solutions, 0.7 0.7 0.7 0.7 water and auxiliary material 74.7 75.1 77.5 80.3 sums 100.0 100.0 100.0 100.0
1. SE-76 polydimethylsiloxane glue and a kind of viscosity of having bought from the siloxanes department of general electronic corporation (General Electric) is the mixture of the polydimethyl siloxane oil of 350 centistokes, and glue is 40/60 with the weight ratio of oil in this mixture.
2.Jaguar C-17, the trade name of hydroxypropyl triamine chloride (hydroxypropyltrimoniumchloride) guar gum, a kind of can be from Rhone-Poulenc (Cranbury, NJ, the cation type polymer of USA) having bought.
3. from Amoco Chemical Co. (Chicago, IL, the IndopolL-14 polybutene of USA) having bought.
The method for making of embodiments of the invention compositions is to add following material while stirring in a premix groove, and is heated to 72 ℃:
A) part lauryl (EO)
3Ammonium sulfate
B) all lauryl N-methyl glucose amide
C) part water begins to add when the temperature of solution rises to 72 ℃:
D) guar gum derivatives
E) hydrocarbon ils
F) aliphatic alcohol
G) EDTA disodium salt
H) sodium dihydrogen phosphate and sodium hydrogen phosphate
I) diglycol stearate stirred 30 minutes at least.After 30 minutes, mixture is cooled to about 30 ℃ (by before the heat exchanger, using a high shear stirring machine).Add following material then:
J) all ammonium lauryl sulfate
K) Yu Xia lauryl (EO)
3The ammonium sulfate part.
L) mixture of polydimethylsiloxane.
M) sodium chloride
N) pigment solution
O) spice solution
P) water and adjuvant
Shampoo Compositions of the present invention has soft property and high bubble property.In addition, shampoo Compositions of the present invention makes that functional substance's's (polydimethylsiloxanemixture mixture, guar gum derivatives and hydrocarbon ils) deposition properties is good.
Claims (14)
1, a kind of shampoo Compositions, it comprises:
(a) about 5% surfactant system to about 40% (weight), this surfactant system comprises: (i) about 80% of surfactant system weight to about 99% anion surfactant, these anion surfactants are that the sulfate and the alkyl sulfate of alkyl ethoxylated combines in about 1: 1 to 1: 0 ratio; And (ii) about 1% to 20% polyhydroxy fatty acid amide surfactant of surfactant system weight;
(b) about 0.05% functional substance to about 25% (weight); And
(c) water of about 35% to 95% (weight).
2, according to a kind of shampoo Compositions of claim 1, wherein, the sulfate of alkyl ethoxylated and the ratio of alkyl sulfate are about 1: 1 to about 10: 1.
3, according to the shampoo Compositions of claim 1, it comprises about 7% surfactant system to about 35% (weight).
4, according to a kind of shampoo Compositions of claim 1, it contains about 85% to about 95% anion surfactant of surfactant system weight, and these surfactants are selected from the sulfate of alkyl ethoxylated, alkyl sulfate and composition thereof.
5, according to a kind of shampoo Compositions of claim 1, it contains about 5% to about 15% polyhydroxy fatty acid amide surfactant of surfactant system weight.
6, according to a kind of shampoo Compositions of claim 1, wherein, polyhydroxy fatty acid amide surfactant is a glucose amide.
7, according to a kind of shampoo Compositions of claim 1, wherein, the sulfate of alkyl ethoxylated is selected from lauryl triethylene glycol ether sodium sulfate and lauryl triethylene glycol ether ammonium sulfate and composition thereof.
8, according to a kind of shampoo Compositions of claim 1, wherein, alkyl sulfate is selected from sodium lauryl sulfate, ammonium lauryl sulfate and composition thereof.
9, according to a kind of shampoo Compositions of claim 1, it contains 0.1% functional substance to about 10% (weight) that has an appointment.
10, according to a kind of shampoo Compositions of claim 1, wherein, the functional substance comprises that content is about 0.05% to about 8% conditioner of shampoo Compositions weight.
11, according to a kind of shampoo prescription of claim 10, wherein, conditioner is hydroxypropyl triamine chloride guar gum (guar hydroxypropyltrimonium chloride), the mixture of hydrocarbon ils and polydimethyl siloxane oil and polydimethylsiloxane glue blend.
12, according to a kind of shampoo Compositions of claim 1, wherein, the functional substance comprises hairspray, and its content is about 2% to about 6% of shampoo Compositions weight.
13, according to a kind of shampoo Compositions of claim 1, wherein, the functional substance comprises dandruff removing agent, and its content is about 0.1% to about 5% of shampoo Compositions weight.
14, according to the shampoo Compositions of claim 1, it contains 50% water to about 85% (weight) of having an appointment.
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| US17599293A | 1993-12-30 | 1993-12-30 | |
| US08/175,992 | 1993-12-30 |
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| CN 94194746 Pending CN1140987A (en) | 1993-12-30 | 1994-12-15 | High lathering and high depositing shampoos with mild surfactant system |
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| EP (1) | EP0738140A1 (en) |
| JP (1) | JPH09510956A (en) |
| CN (1) | CN1140987A (en) |
| AU (1) | AU1306095A (en) |
| BR (1) | BR9408437A (en) |
| CA (1) | CA2179278A1 (en) |
| MA (1) | MA23415A1 (en) |
| PE (1) | PE44495A1 (en) |
| WO (1) | WO1995017880A1 (en) |
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| CN104582678A (en) * | 2012-05-30 | 2015-04-29 | 科莱恩金融(Bvi)有限公司 | Use of N-methyl-N-acylglucamines as thickening agents in surfactant solutions |
| US10772324B2 (en) | 2012-11-03 | 2020-09-15 | Clariant International Ltd. | Aqueous adjuvant-compositions |
| US10813862B2 (en) | 2012-05-30 | 2020-10-27 | Clariant International Ltd. | Use of N-methyl-N-acylglucamines as solubilizers |
| US10864275B2 (en) | 2012-05-30 | 2020-12-15 | Clariant International Ltd. | N-methyl-N-acylglucamine-containing composition |
| US10920080B2 (en) | 2015-10-09 | 2021-02-16 | Clariant International Ltd. | N-Alkyl glucamine-based universal pigment dispersions |
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| US11220603B2 (en) | 2016-05-09 | 2022-01-11 | Clariant International Ltd. | Stabilizers for silicate paints |
| CN114727918A (en) * | 2019-11-19 | 2022-07-08 | 联合利华知识产权控股有限公司 | Hair care composition |
| CN114917154A (en) * | 2021-07-29 | 2022-08-19 | 青龙高科技股份有限公司 | Tea oil shampoo and preparation method thereof |
| US11425904B2 (en) | 2014-04-23 | 2022-08-30 | Clariant International Ltd. | Use of aqueous drift-reducing compositions |
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|---|---|---|---|---|
| DE4422404C2 (en) * | 1994-06-27 | 2001-06-07 | Cognis Deutschland Gmbh | Use of cosmetic compositions for hair rinses and hair treatments |
| DE4435383C1 (en) * | 1994-10-04 | 1995-11-09 | Henkel Kgaa | Cosmetic products |
| DE19619645A1 (en) * | 1996-05-15 | 1997-11-20 | Henkel Kgaa | Hair treatment products |
| GB9615632D0 (en) * | 1996-07-25 | 1996-09-04 | Procter & Gamble | Shampoo compositions |
| JP3887283B2 (en) * | 2002-08-09 | 2007-02-28 | 花王株式会社 | Shampoo composition |
| EP1656109A2 (en) * | 2003-05-23 | 2006-05-17 | The Procter & Gamble Company | Clear personal care compositions containing a cationic conditioning polymer and an anionic surfactant system |
| JP2007517805A (en) | 2004-01-16 | 2007-07-05 | ザ プロクター アンド ギャンブル カンパニー | Conditioning shampoo composition |
| JP5670131B2 (en) * | 2010-09-13 | 2015-02-18 | 東邦化学工業株式会社 | Hair composition |
| CN104540931A (en) | 2012-05-30 | 2015-04-22 | 科莱恩金融(Bvi)有限公司 | N-methyl-N-acylglucamine-containing composition |
| CN104540550A (en) | 2012-05-30 | 2015-04-22 | 科莱恩金融(Bvi)有限公司 | Surfactant solutions containing N-methyl-N-oleylglucamines and N-methyl-N-C12-C14-acylglucamines |
| JP2015519450A (en) | 2012-05-30 | 2015-07-09 | クラリアント・ファイナンス・（ビーブイアイ）・リミテッド | Surfactant solution containing N-methyl-N-C8-C10-acyl glucamine and N-methyl-N-C12-C14-acyl glucamine |
| WO2013178670A2 (en) | 2012-05-30 | 2013-12-05 | Clariant International Ltd. | Use of n-methyl-n-acylglucamines as cold stabilizers in surfactant solutions |
| JP6537494B2 (en) * | 2013-04-20 | 2019-07-03 | クラリアント・インターナシヨナル・リミテツド | Composition comprising oily substance, fatty acid, amino acid surfactant, and N-methyl-N-acyl glucamine |
| EP3013427B1 (en) * | 2013-06-28 | 2017-08-09 | Clariant International Ltd | Use of special n-alkyl-n-acylglucamines for conditioning hair in hair washing agents |
| DE102013018001A1 (en) * | 2013-11-29 | 2015-06-03 | Clariant International Ltd. | Use of glucamides to improve the silicone position |
| DE102013018000A1 (en) * | 2013-11-29 | 2015-06-03 | Clariant International Ltd. | Conditioning shampoos containing anionic surfactants, glucamides and fatty alcohols |
| DE102013225373A1 (en) * | 2013-12-10 | 2014-04-24 | Henkel Ag & Co. Kgaa | Hair treatment composition, useful for cleaning and/or caring scalp and hair, includes carboxylic acid-N-alkylpolyhydroxyalkylamide compound, and further surfactant comprising e.g. alkyl ether sulfate and oxyethylene groups |
| WO2016062619A1 (en) * | 2014-10-23 | 2016-04-28 | Clariant International Ltd | Use of special n-alkyl-n-acylglucamines for protecting the color in hair-washing agents |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU662717B2 (en) * | 1990-09-28 | 1995-09-14 | Procter & Gamble Company, The | Improved shampoo compositions |
| WO1993019149A1 (en) * | 1992-03-25 | 1993-09-30 | The Procter & Gamble Company | Cleansing compositions |
-
1994
- 1994-12-15 CN CN 94194746 patent/CN1140987A/en active Pending
- 1994-12-15 BR BR9408437A patent/BR9408437A/en not_active Application Discontinuation
- 1994-12-15 AU AU13060/95A patent/AU1306095A/en not_active Abandoned
- 1994-12-15 EP EP95904325A patent/EP0738140A1/en not_active Ceased
- 1994-12-15 CA CA 2179278 patent/CA2179278A1/en not_active Abandoned
- 1994-12-15 WO PCT/US1994/014289 patent/WO1995017880A1/en not_active Application Discontinuation
- 1994-12-15 JP JP7518062A patent/JPH09510956A/en active Pending
- 1994-12-28 MA MA23744A patent/MA23415A1/en unknown
- 1994-12-29 PE PE25814294A patent/PE44495A1/en not_active Application Discontinuation
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104582678A (en) * | 2012-05-30 | 2015-04-29 | 科莱恩金融(Bvi)有限公司 | Use of N-methyl-N-acylglucamines as thickening agents in surfactant solutions |
| CN104582678B (en) * | 2012-05-30 | 2017-05-03 | 科莱恩金融(Bvi)有限公司 | Use of N-methyl-N-acylglucamines as thickening agents in surfactant solutions |
| US10813862B2 (en) | 2012-05-30 | 2020-10-27 | Clariant International Ltd. | Use of N-methyl-N-acylglucamines as solubilizers |
| US10864275B2 (en) | 2012-05-30 | 2020-12-15 | Clariant International Ltd. | N-methyl-N-acylglucamine-containing composition |
| US10772324B2 (en) | 2012-11-03 | 2020-09-15 | Clariant International Ltd. | Aqueous adjuvant-compositions |
| US11425904B2 (en) | 2014-04-23 | 2022-08-30 | Clariant International Ltd. | Use of aqueous drift-reducing compositions |
| US10920080B2 (en) | 2015-10-09 | 2021-02-16 | Clariant International Ltd. | N-Alkyl glucamine-based universal pigment dispersions |
| US10961484B2 (en) | 2015-10-09 | 2021-03-30 | Clariant International Ltd. | Compositions comprising sugar amine and fatty acid |
| US11220603B2 (en) | 2016-05-09 | 2022-01-11 | Clariant International Ltd. | Stabilizers for silicate paints |
| CN114727918A (en) * | 2019-11-19 | 2022-07-08 | 联合利华知识产权控股有限公司 | Hair care composition |
| CN114917154A (en) * | 2021-07-29 | 2022-08-19 | 青龙高科技股份有限公司 | Tea oil shampoo and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| PE44495A1 (en) | 1996-01-16 |
| BR9408437A (en) | 1997-08-05 |
| WO1995017880A1 (en) | 1995-07-06 |
| AU1306095A (en) | 1995-07-17 |
| MA23415A1 (en) | 1995-07-01 |
| CA2179278A1 (en) | 1995-07-06 |
| EP0738140A1 (en) | 1996-10-23 |
| JPH09510956A (en) | 1997-11-04 |
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