CN114085068A - Aluminum ash light brick and preparation method thereof - Google Patents

Aluminum ash light brick and preparation method thereof Download PDF

Info

Publication number
CN114085068A
CN114085068A CN202111532588.1A CN202111532588A CN114085068A CN 114085068 A CN114085068 A CN 114085068A CN 202111532588 A CN202111532588 A CN 202111532588A CN 114085068 A CN114085068 A CN 114085068A
Authority
CN
China
Prior art keywords
aluminum ash
brick
aluminum
ash
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111532588.1A
Other languages
Chinese (zh)
Inventor
侯浩波
蔡建亮
纪建业
何彩霞
张鹏举
徐兰
游以文
李文辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institute Of Resources And Environmental Technology Wuhan University Zhaoqing
Original Assignee
Institute Of Resources And Environmental Technology Wuhan University Zhaoqing
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute Of Resources And Environmental Technology Wuhan University Zhaoqing filed Critical Institute Of Resources And Environmental Technology Wuhan University Zhaoqing
Priority to CN202111532588.1A priority Critical patent/CN114085068A/en
Publication of CN114085068A publication Critical patent/CN114085068A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/138Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/135Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1352Fuel ashes, e.g. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/77Density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The invention discloses an aluminum ash light brick and a preparation method thereof, wherein the aluminum ash light brick is prepared from the following raw materials in parts by weight: 50-70 parts of aluminum ash, 15-20 parts of fly ash, 20-30 parts of mineral powder and 1-3 parts of auxiliary agent, obtaining a proper particle size after ball milling and screening the aluminum ash, and then uniformly mixing the aluminum ash, the mineral powder and the auxiliary agent; then pouring the mixture into a grinding tool, and pressing and forming the mixture by a static pressure machine; and demolding, sintering and cooling to obtain the light brick with low density and uniform size. Compared with the traditional clay brick, the lightweight brick taking the aluminum ash as the main raw material has lower density and higher strength, can effectively reduce the bearing of a building, and has good heat-insulating and sound-insulating effects due to the uniform pore structure, thereby replacing the clay brick or the common lightweight brick to a certain extent as a novel building material.

Description

Aluminum ash light brick and preparation method thereof
Technical Field
The invention belongs to the technical field of building materials, relates to a resource utilization method of industrial solid waste, and particularly relates to an aluminum ash light brick and a preparation method thereof.
Background
The aluminum ash (also called aluminum slag ash or aluminum slag) is a kind of dross generated in the primary and secondary aluminum industrial production, is the main loss part of liquid raw aluminum in the electrolytic aluminum production, mainly comes from infusible inclusion floating on the surface of aluminum melt in the casting process, additive and substance generated by physical and chemical reaction with the additive, and is in loose ash shape. The aluminum ash produced during the liquid primary aluminum processing process generally contains 30-70% of metallic aluminum, and is generally called lime or primary aluminum ash, and can be used as a raw material for secondary aluminum industrial production. The secondary aluminum industry is primarily concerned with the recovery of aluminum from various wastes (e.g., primary aluminum ash, aluminum scrap, etc. from aluminum processing). The waste produced by the secondary aluminum industry typically contains 5% to 20% metallic aluminum and a large amount of soluble salts, commonly referred to as black ash. The aluminum ash contains a plurality of substances which are directly or indirectly harmful to the environment, and the direct discarding can cause environmental pollution; the aluminum ash is a renewable resource with comprehensive utilization value, and secondary energy sources such as aluminum, salt, aluminum oxide and the like can be recycled from the aluminum ash; it can also be used as raw material for refractory material, road and building material, and desulfurizing agent for steel-smelting.
The bricks traditionally used in the construction industry are mostly formed by evenly stirring clay and other auxiliary materials and then forming the mixture by a briquetting machine and then firing the mixture. Traditional brick is heavier when building a wall, and is hard when building a wall, and the inevitable bearing burden that has increased the building, and the wall that this brick was built simultaneously gives sound insulation, keeps warm, the effect of taking precautions against earthquakes is poor, and anti-seismic performance is low. In addition, the preparation raw materials need a large amount of clay, which has great negative effects on natural resources and ecological balance.
As a result, the brick sintered by the aluminum ash has more porous structures, compared with the traditional solid brick, the weight of the aluminum ash light brick is only 60% -70%, the density is obviously reduced, and compared with the hollow brick, the brick has the advantages of compact structure and good strength. The reactive aluminum nitride contained in the aluminum ash raw material is decomposed after high-temperature sintering, and the nitrogen and other halogen elements in the reactive aluminum nitride are volatilized in a gas form, so that the dangerous characteristic of the aluminum ash is eliminated. In addition, the aluminum ash sintered brick has a porous structure, has the effects of sound insulation, noise reduction, heat preservation and shock resistance when being used for building walls, is particularly suitable for non-bearing walls of commercial places and entertainment places, and is an excellent building brick.
Disclosure of Invention
In order to solve the problems in the prior art, the invention aims to provide an aluminum ash lightweight brick and a preparation method thereof, the lightweight brick taking aluminum ash as a main raw material has lower density and higher strength, can effectively reduce the load bearing of a building, and has good heat preservation and sound insulation effects due to a uniform pore structure, so that the lightweight brick replaces a clay brick or a common lightweight brick to a certain extent as a novel building material.
The invention uses fine aluminum ash to sinter high-strength light bricks, wherein the aluminum ash contains high aluminum oxide. The high-strength light-weight brick is prepared by ball milling the aluminum ash, winnowing and screening to obtain the aluminum ash with proper particle size, mixing the aluminum ash with the fly ash, the mineral powder and the auxiliary agent, and sintering.
The purpose of the invention is realized by the following technical scheme:
an aluminum ash light brick is prepared from the following raw materials in parts by weight:
Figure BDA0003411953970000021
preferably, the aluminum ash is ball-milled, and the ball-milling process parameters are as follows: the ball milling revolution is 300 and 2500 revolutions per minute, and the ball milling time is 0.5 to 2 hours; then passing through a wind separation sieve, the particle size is 200-400 meshes.
Preferably, the particle size of the fly ash is 300-600 meshes, and the content of alumina is lower than 35 wt%.
Preferably, the ore fines are of the type S75, S95 or S105 ore fines.
Preferably, the auxiliary agent is fluorite tailing slag or boric acid.
According to the invention, the fluorite tailing slag or boric acid is added, so that the sintering temperature of the light brick can be effectively reduced, and the pore density of the light brick can be increased.
The invention also provides a preparation method of the aluminum ash light brick, which comprises the following steps:
(1) uniformly mixing the aluminum ash, the mineral powder, the fly ash and the auxiliary agent in a stirring tank according to a set proportion to obtain a mixture;
(2) pouring the mixture into a mold, pressing and molding the material through a static pressure machine, delivering the molded material into a sintering kiln, sintering at the temperature of 900-1050 ℃, cooling, and demolding to obtain the aluminum ash light brick.
The invention has the advantages and effects that:
the invention takes the aluminum ash as the main raw material, the aluminum ash generates weak reaction with water at normal temperature, and can release gases such as ammonia gas and the like at high temperature to form uniform air holes in the material, thereby effectively reducing the density of the material.
The aluminum ash is mixed with the fly ash and the mineral powder, then the sintering temperature is further reduced and the pore density of the light brick is increased under the cooperation of the auxiliary agent, so that the aluminum ash light brick with lower density and higher strength can be obtained.
Compared with the traditional clay brick, the light brick taking the aluminum ash as the main raw material has lower density and higher strength, and can effectively reduce the bearing of a building, thereby replacing the clay brick or the common light brick to a certain extent as a novel building material.
Drawings
FIG. 1 is a flow chart of the preparation process of the aluminum ash lightweight brick of the invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below.
Example 1
An aluminum ash light brick and a preparation method thereof are as follows:
(1) ball milling, winnowing and screening the aluminum ash, wherein the ball milling speed of the aluminum ash is 1500 rpm, the ball milling time is 1.5 hours, and the screening particle size is 200-400 meshes;
(2) uniformly mixing 55 parts of aluminum ash, 15 parts of fly ash, 28 parts of mineral powder and 1 part of boric acid additive according to parts by weight, wherein the stirring speed is 240 revolutions per minute;
(3) adding 6 parts of water into the stirred mixture, pouring the mixture into a mold, and pressing and molding the mixture;
(4) placing the pressed aluminum ash brick blocks for 24 hours and then demoulding;
(5) and (3) putting the demolded aluminum ash bricks into a kiln for calcining, wherein the calcining temperature is 1000 ℃.
Example 2
An aluminum ash light brick and a preparation method thereof are as follows:
(1) ball milling, winnowing and screening the aluminum ash, wherein the ball milling speed of the aluminum ash is 1200 r/min, the ball milling time is 2 hours, and the screening particle size is 200-400 meshes;
(2) uniformly mixing 60 parts of aluminum ash, 15 parts of fly ash, 22 parts of mineral powder and 1 part of boric acid additive in parts by weight, wherein the stirring speed is 240 revolutions per minute;
(3) adding 6 parts of water into the stirred mixture, pouring the mixture into a mold, and pressing and molding the mixture;
(4) placing the pressed aluminum ash brick blocks for 24 hours and then demoulding;
(5) and (3) putting the demolded aluminum ash bricks into a kiln for calcining, wherein the calcining temperature is 1000 ℃.
Example 3
An aluminum ash light brick and a preparation method thereof are as follows:
(1) ball milling, winnowing and screening the aluminum ash, wherein the ball milling speed of the aluminum ash is 1800 rpm, the ball milling time is 1.8 hours, and the screening particle size is 200-400 meshes;
(2) according to the weight portion, 65 portions of aluminum ash, 18 portions of fly ash, 25 portions of mineral powder and 2 portions of boric acid additive are uniformly mixed, and the stirring speed is 240 r/m;
(3) adding 6 parts of water into the stirred mixture, pouring the mixture into a mold, and pressing and molding the mixture;
(4) placing the pressed aluminum ash brick blocks for 24 hours and then demoulding;
(5) and putting the demolded aluminum ash bricks into a kiln for calcining, wherein the calcining temperature is 950 ℃.
TABLE 1 comparison of main Properties of the lightweight bricks according to the invention
Figure BDA0003411953970000041
The compressive strength of the clay brick purchased from the market is 18.2MPa, and the bulk density is 2085kg/m3The compressive strength of the baking-free light brick prepared in the embodiments 1 to 3 is 11.5MPa to 12.5MPa, which is lower than that of a sintered clay brick, but the compressive strength of the baking-free light brick meets the MU10 standard value of GB5101-2003, and the baking-free light brick can be used for non-load-bearing walls; the bulk density is 1030kg/m3~1070kg/m3Much lower than the bulk density of the fired clay brick.
The light brick prepared by the invention has the characteristics of light weight, good strength and high temperature resistance.
It is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made to the present invention by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (6)

1. The aluminum ash light brick is characterized by being prepared from the following raw materials in parts by weight:
Figure FDA0003411953960000011
2. the aluminum ash light brick as claimed in claim 1, wherein the aluminum ash is ball milled first, and the ball milling process parameters are as follows: the ball milling revolution is 300 and 2500 revolutions per minute, and the ball milling time is 0.5 to 2 hours; then passing through a wind separation sieve, the particle size is 200-400 meshes.
3. The aluminum ash lightweight brick as claimed in claim 1, wherein the particle size of the fly ash is 300-600 mesh, and the content of alumina is less than 35 wt%.
4. The aluminum ash lightweight brick as claimed in claim 1, wherein the ore powder type is S75, S95 or S105 ore powder.
5. The aluminum ash lightweight brick according to claim 1, wherein the auxiliary is fluorite tailing slag or boric acid.
6. The method for preparing an aluminum ash lightweight brick according to any one of claims 1 to 5, which comprises the steps of:
(1) uniformly mixing the aluminum ash, the mineral powder, the fly ash and the auxiliary agent in a stirring tank according to a set proportion to obtain a mixture;
(2) pouring the mixture into a mold, pressing and molding the material through a static pressure machine, delivering the molded material into a sintering kiln, sintering at the temperature of 900-1050 ℃, cooling, and demolding to obtain the aluminum ash light brick.
CN202111532588.1A 2021-12-15 2021-12-15 Aluminum ash light brick and preparation method thereof Pending CN114085068A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111532588.1A CN114085068A (en) 2021-12-15 2021-12-15 Aluminum ash light brick and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111532588.1A CN114085068A (en) 2021-12-15 2021-12-15 Aluminum ash light brick and preparation method thereof

Publications (1)

Publication Number Publication Date
CN114085068A true CN114085068A (en) 2022-02-25

Family

ID=80307274

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111532588.1A Pending CN114085068A (en) 2021-12-15 2021-12-15 Aluminum ash light brick and preparation method thereof

Country Status (1)

Country Link
CN (1) CN114085068A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114644506A (en) * 2022-04-08 2022-06-21 福建省德化县合和陶瓷技术开发有限公司 Environment-friendly high-whiteness domestic ceramic product and preparation process thereof
CN115432997A (en) * 2022-10-18 2022-12-06 中南大学 Ceramic-based molten salt composite phase-change heat storage material and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005060741A (en) * 2003-08-19 2005-03-10 Nippon Steel Corp Method for modifying steelmaking slag
CN102515635A (en) * 2011-11-21 2012-06-27 赵汝雄 Ceramsite heat insulation brick and preparation method thereof
CN104961444A (en) * 2015-06-30 2015-10-07 苏州卡迪亚铝业有限公司 Method for manufacturing high-strength durable ganged bricks with waste aluminum ash
CN105036699A (en) * 2015-06-30 2015-11-11 苏州卡迪亚铝业有限公司 High-strength and durable ganged brick prepared by utilizing aluminium scruff ash
CN106630939A (en) * 2016-11-28 2017-05-10 河南同伟建材有限公司 Light-weight porous floor tile and manufacturing method thereof
CN113213892A (en) * 2021-04-25 2021-08-06 南通大学 Method for preparing sintered brick from aluminum ash end ash
CN113563102A (en) * 2021-08-23 2021-10-29 北京科技大学 Method for preparing porous ceramic by in-situ curing and forming aluminum-containing ash water-based slurry

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005060741A (en) * 2003-08-19 2005-03-10 Nippon Steel Corp Method for modifying steelmaking slag
CN102515635A (en) * 2011-11-21 2012-06-27 赵汝雄 Ceramsite heat insulation brick and preparation method thereof
CN104961444A (en) * 2015-06-30 2015-10-07 苏州卡迪亚铝业有限公司 Method for manufacturing high-strength durable ganged bricks with waste aluminum ash
CN105036699A (en) * 2015-06-30 2015-11-11 苏州卡迪亚铝业有限公司 High-strength and durable ganged brick prepared by utilizing aluminium scruff ash
CN106630939A (en) * 2016-11-28 2017-05-10 河南同伟建材有限公司 Light-weight porous floor tile and manufacturing method thereof
CN113213892A (en) * 2021-04-25 2021-08-06 南通大学 Method for preparing sintered brick from aluminum ash end ash
CN113563102A (en) * 2021-08-23 2021-10-29 北京科技大学 Method for preparing porous ceramic by in-situ curing and forming aluminum-containing ash water-based slurry

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
华南工学院: "《硅酸盐岩相学》" *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114644506A (en) * 2022-04-08 2022-06-21 福建省德化县合和陶瓷技术开发有限公司 Environment-friendly high-whiteness domestic ceramic product and preparation process thereof
CN115432997A (en) * 2022-10-18 2022-12-06 中南大学 Ceramic-based molten salt composite phase-change heat storage material and preparation method thereof
CN115432997B (en) * 2022-10-18 2023-08-22 中南大学 Ceramic-based fused salt composite phase-change heat storage material and preparation method thereof

Similar Documents

Publication Publication Date Title
KR20130009000A (en) Coal gangue ceramsite and its preparation approach
CN114085068A (en) Aluminum ash light brick and preparation method thereof
CN108821621B (en) Light high-strength ceramsite and preparation method thereof
CN110950631A (en) Lightweight foamed ceramic insulation board prepared from tailings and preparation method thereof
CN104478329B (en) Preparation method for producing autoclaved aerated concrete block by using antimony ore tailing
CN108706962B (en) High-strength ceramic tile of coal gangue-fly ash-desulfurized gypsum system and preparation method thereof
CN112552072A (en) Construction waste regenerated foamed ceramic and preparation method thereof
CN104529518B (en) A kind of lead-zinc ore tailings-red mud-fly ash base foamed ceramics and preparation method thereof
CN113173802A (en) Method for preparing porous mullite brick by using secondary aluminum ash
CN111205103A (en) Method for preparing light ceramic tile by using graphite tailings
CN110963807A (en) Energy-saving mullite refractory brick for cement kiln transition zone and preparation method thereof
CN114195461A (en) Molybdenum tailing active powder concrete archaized brick and preparation method thereof
CN114276097A (en) Nickel slag cementing material for improving activity of nickel slag through split-phase activation and preparation method thereof
CN106747620A (en) A kind of low energy consumption sintering seepage brick and its manufacture method
CN114716193B (en) Preparation method of recycled slag-soil brick
CN108395264B (en) Regenerated brick for carbon furnace and preparation method thereof
CN110668820A (en) Preparation method of high-performance carbon graphite product with superfine structure
CN115403401A (en) Method for preparing foamed ceramic wallboard based on high-temperature jet flow process
CN104973853A (en) Method for preparing high-strength shale brick from waste aluminum ash
CN115724652A (en) Preparation method of low-density high-strength calcium feldspar heat insulation material for hydrogen metallurgy field
CN115321897A (en) Low-carbon cementing material with high early strength and processing method thereof
CN115536358A (en) Industrial solid waste carbonization and solidification baking-free building block and preparation method thereof
CN111848037B (en) Composition for preparing slate tailing brick, tailing brick and preparation method thereof
CN109942279B (en) Ordinary baked brick prepared from casting waste
CN113277738A (en) Artificial volcanic rock calcined by using red mud and steel slag as main raw materials and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20220225

RJ01 Rejection of invention patent application after publication