CN114038321A - Display device - Google Patents

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Publication number
CN114038321A
CN114038321A CN202111386633.7A CN202111386633A CN114038321A CN 114038321 A CN114038321 A CN 114038321A CN 202111386633 A CN202111386633 A CN 202111386633A CN 114038321 A CN114038321 A CN 114038321A
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China
Prior art keywords
substrate
conductive fibers
conductive
display
fiber
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CN202111386633.7A
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CN114038321B (en
Inventor
白雪
周淼
孙承啸
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Shenzhen China Star Optoelectronics Semiconductor Display Technology Co Ltd
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Shenzhen China Star Optoelectronics Semiconductor Display Technology Co Ltd
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Publication of CN114038321A publication Critical patent/CN114038321A/en
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    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F9/00Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
    • G09F9/30Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
    • G09F9/301Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements flexible foldable or roll-able electronic displays, e.g. thin LCD, OLED

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Electroluminescent Light Sources (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)

Abstract

The invention provides a display, which comprises a plurality of first conductive fibers and a plurality of second conductive fibers, wherein each first conductive fiber sequentially comprises a first substrate, a first transparent electrode layer and an electroluminescent layer from inside to outside; the plurality of second conductive fibers and the plurality of first conductive fibers are arranged in a crossed mode, and each second conductive fiber comprises a second substrate and a second transparent electrode layer wrapping the second substrate; the first substrate and the second substrate are both polymer linear substrates; according to the invention, the first substrate and the second substrate are both polymer linear substrates, so that the first transparent electrode layer and the second transparent electrode layer can be uniformly coated on the surface of the polymer linear substrate, the process for manufacturing the first conductive fiber and the second conductive fiber is simple, the cost is low, the effect is good, the problems of non-uniform luminescence, Joule heat and the like caused by the rough fabric substrate are improved, and the polymer linear substrate is stable in structure and not easy to deform.

Description

Display device
Technical Field
The invention relates to the technical field of display, in particular to a display.
Background
With the increasing demand of the market for wearable display devices, the display devices have gradually developed from rigid substrates to flexible films, wherein fabric display becomes a big hotspot in the field of wearable displays. However, the manufacturing process of the electroluminescent device is not suitable for the preparation of the fabric display device, let alone the reliability test of bending, abrasion, etc. during the use of the device. In addition, although the conventional optical fiber light emitting device can achieve the above-described functions, it cannot achieve dynamic display, and the color and arrangement of pixels are also limited.
In the prior art, a plurality of luminescent fibers are manufactured by forming a film on the surfaces of a plurality of conductive fibers by using fluorescent powder, the luminescent fibers are used as warps of a fluorescent fabric, a plurality of electrode fibers are used as wefts of the fluorescent fabric, and the luminescent fibers are communicated with the electrode fibers at cross points to realize electroluminescence of pixel positions. However, since the light-emitting fibers and the electrode fibers both use fiber yarns as substrates, and the surfaces of the fiber yarns are rough, the film-forming properties and the process methods of the conductive film layer and the light-emitting film layer are limited, the manufacturing cost is very high, the problems of non-uniform light emission, joule heat and the like are easily caused, the service life of the fiber yarns is limited, and the problems of high temperature or easy deformation in washing exist, so that the fabric display technology cannot be well applied. Therefore, it is necessary to improve this defect.
Disclosure of Invention
The embodiment of the invention provides a display, which is used for solving the technical problems that in the prior art, both luminescent fibers and electrode fibers displayed by a fabric adopt fiber yarns as substrates, the surfaces of the fiber yarns are rough, so that the preparation process is complex, the cost is high, non-uniform luminescence and Joule heat are easily caused, the service life of the fiber yarns is limited, and the fiber yarns are easy to deform at high temperature or washing.
The embodiment of the invention provides a display, which comprises a plurality of first conductive fibers and a plurality of second conductive fibers, wherein each first conductive fiber sequentially comprises a first substrate, a first transparent electrode layer and an electroluminescent layer from inside to outside; the plurality of second conductive fibers and the plurality of first conductive fibers are arranged in a crossed mode, and each second conductive fiber comprises a second substrate and a second transparent electrode layer wrapping the second substrate; wherein the first substrate and the second substrate are both polymer wire-like substrates.
In the display provided by the embodiment of the present invention, the polymer linear substrate is an organic polymer linear substrate, and the material of the organic polymer linear substrate is any one of polyethylene terephthalate, polystyrene, polymethyl methacrylate, polyethylene, polypropylene, polyvinyl chloride, polycarbonate, and polyamide resin.
In the display provided in the embodiment of the invention, the shape of the polymer linear substrate in a direction perpendicular to the extending direction of the first conductive fibers or the second conductive fibers is any one of a circle, an ellipse, a rectangle, and a square.
In the display provided by the embodiment of the invention, the width of the polymer linear substrate in the direction perpendicular to the extending direction of the first conductive fiber or the second conductive fiber is greater than or equal to 5 micrometers and less than or equal to 500 micrometers.
In the display provided by the embodiment of the invention, the plurality of first conductive fibers include a plurality of red conductive fibers, a plurality of green conductive fibers and a plurality of blue conductive fibers.
In the display provided by the embodiment of the invention, the material of the electroluminescent layer is a quantum dot material or a chalcogenide of a two-dimensional transition metal.
In a display provided by an embodiment of the present invention, the display further comprises a textile web substrate comprising a plurality of first textile substrates and a plurality of second textile substrates, the plurality of first textile substrates being arranged in parallel with the first conductive fibers, the plurality of second textile substrates being arranged in parallel with the second conductive fibers; the red conductive fiber, the green conductive fiber and the blue conductive fiber are positioned between two adjacent first textile substrates; one said second conductive fibre is located between two adjacent said second textile substrates.
In a display provided by an embodiment of the invention, the first conductive fibers are located between the second conductive fibers and the second textile substrate; the second conductive fibers are located between the first conductive fibers and the first textile substrate.
In the display provided by the embodiment of the invention, the textile net substrate is made of any one of fibers, yarns, hemp, terylene and chinlon.
In the display provided by the embodiment of the invention, the required power supply is provided by a plurality of first conductive fibers and a plurality of second conductive fibers through alternating current, and the voltage value of the alternating current is greater than or equal to 2 volts and less than or equal to 15 volts.
Has the advantages that: the display provided by the embodiment of the invention comprises a plurality of first conductive fibers and a plurality of second conductive fibers, wherein each first conductive fiber sequentially comprises a first substrate, a first transparent electrode layer and an electroluminescent layer from inside to outside; the plurality of second conductive fibers and the plurality of first conductive fibers are arranged in a crossed mode, and each second conductive fiber comprises a second substrate and a second transparent electrode layer wrapping the second substrate; wherein the first substrate and the second substrate are both polymer linear substrates; according to the invention, the first substrates of the plurality of first conductive fibers and the second substrates of the plurality of second conductive fibers are polymer linear substrates, so that the first transparent electrode layer and the second transparent electrode layer can be uniformly coated on the surface of the polymer linear substrate, the process for manufacturing the first conductive fibers and the second conductive fibers is simple, the cost is low, the effect is good, the problems of non-uniform luminescence, Joule heat and the like caused by the roughness of the fabric substrate are improved, and the polymer linear substrate is stable in structure and not easy to deform.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings used in the description of the embodiments will be briefly introduced below.
Fig. 1 is a schematic diagram of a basic structure of a display provided in an embodiment of the present invention.
Detailed Description
The technical solution in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. In the drawings, the size and thickness of components illustrated in the drawings are not to scale for clarity and ease of understanding and description.
As shown in fig. 1, which is a schematic diagram of a basic structure of a display provided in an embodiment of the present invention, the display includes a plurality of first conductive fibers 10 and a plurality of second conductive fibers 20, each of the first conductive fibers 10 includes, in order from inside to outside, a first substrate (not shown), a first transparent electrode layer (not shown), and an electroluminescent layer (not shown); a plurality of the second conductive fibers 20 are disposed to cross the plurality of the first conductive fibers 10, each of the second conductive fibers 20 includes a second substrate (not shown) and a second transparent electrode layer (not shown) covering the second substrate; wherein the first substrate and the second substrate are both polymer wire-like substrates.
It should be noted that the preparation process of the first conductive fiber 10 includes: firstly, coating a layer of transparent electrode material on a polymer linear substrate by using a dip coating method to form a first transparent electrode layer for coating the polymer linear substrate; then, an electroluminescent thin film is coated on the first transparent electrode layer to form an electroluminescent layer, thereby preparing the first conductive fiber 10. The preparation process of the second conductive fiber 20 comprises the following steps: the polymer wire substrate is coated with a layer of transparent electrode material using a dip coating method to form a second transparent electrode layer covering the polymer wire substrate, thereby preparing the second conductive fiber 20.
It should be noted that the display provided by the present invention is a light emitting color changing fabric, and the plurality of first conductive fibers 10 and the plurality of second conductive fibers 20 are arranged in a crossing manner to form a warp and weft lap joint, and after an ac voltage is applied to the plurality of first conductive fibers 10 and the plurality of second conductive fibers 20, respectively, electrons and holes are transmitted at the crossing of the first transparent electrode layer and the second transparent electrode layer, respectively, so as to form a light emitting spot in an electroluminescent layer in a composite manner, thereby serving as a sub-pixel. Through the selection of the electroluminescent material, the construction of the sub-pixels with various colors is realized, and the luminous color-changing fabric can be obtained by weaving the second conductive fibers 20 and the first conductive fibers 10 through weaving, knitting and other textile methods.
It can be understood that the conductive fiber in the prior art adopts fiber yarn as a substrate, and due to the rough surface of the fiber yarn, the film forming performance and the process method of the conductive film layer and the luminous film layer are limited, the manufacturing cost is very high, the problems of non-uniform light emission, joule heat and the like are easily caused, and the fiber yarn has a limited service life and is easy to deform at high temperature or washing. According to the invention, the first substrates of the plurality of first conductive fibers 10 and the second substrates of the plurality of second conductive fibers 20 are polymer linear substrates, so that the first transparent electrode layer and the second transparent electrode layer can be uniformly coated on the surface of the polymer linear substrate, the process for manufacturing the first conductive fibers 10 and the second conductive fibers 20 is simple, the cost is low, the effect is good, the problems of non-uniform luminescence, joule heat and the like caused by the roughness of the fabric substrate are solved, and the polymer linear substrate is stable in structure and is not easy to deform.
In one embodiment, the polymer strand substrate is an organic polymer strand substrate, and the material of the organic polymer strand substrate is any one of polyethylene terephthalate, polystyrene, polymethyl methacrylate, polyethylene, polypropylene, polyvinyl chloride, polycarbonate, and polyamide resin.
In one embodiment, the shape of the polymer wire-like base is any one of circular, elliptical, rectangular, and square in a direction perpendicular to the extending direction of the first conductive fiber 10 or the second conductive fiber 20. Namely, the first substrate and the second substrate are integrally any one of a circular line body, an elliptical line body, a rectangular line body and a square line body. When the first substrate and the second substrate are rectangular lines as a whole, the light emitting area of the sub-pixels can be increased. Specifically, the first substrate and the second substrate are arranged into the rectangular line body, so that the size of the sub-pixels of the display is increased, the occupation ratio of a blank area of the pixels is reduced, and the display effect can be optimized.
In one embodiment, the width of the polymer wire-like substrate in a direction perpendicular to the extending direction of the first conductive fibers 10 or the second conductive fibers 20 is greater than or equal to 5 micrometers and less than or equal to 500 micrometers. Specifically, when the polymer linear substrate is a circular wire body, the diameter of the circular wire body is between 5 micrometers and 500 micrometers; when the polymer linear substrate is an elliptical linear body, the major axis of the elliptical linear body is between 5 microns and 500 microns; when the polymer linear substrate is a rectangular linear body, the length of the rectangle is between 5 and 500 micrometers; when the polymer wire substrate is square, the sides of the square are between 5 microns and 500 microns.
In one embodiment, the materials of the first transparent electrode layer and the second transparent electrode layer are Indium Tin Oxide (ITO), poly 3, 4-ethylenedioxythiophene: polystyrene sulfonate (PEDOT: PSS), zinc oxide (ZnO), and silver thin film (Ag thin film) having a nano-scale thickness. It should be noted that zinc oxide is an oxide of zinc, is hardly soluble in water, and is soluble in acid and strong alkali. The zinc oxide has large energy band gap and exciton binding energy, high transparency and excellent normal temperature luminescence property. The zinc oxide films prepared under different process conditions have different performances, and the zinc oxide transparent conductive film has light transmittance of more than 90% in a visible light range of 100-800 nm. About 2 percent of alumina film is doped in the process of preparing the zinc oxide film, the resistance of each square can be controlled below 100 ohm, and the light transmittance is unchanged.
In one embodiment, the plurality of first conductive fibers 10 includes a plurality of red conductive fibers 101, a plurality of green conductive fibers 102, and a plurality of blue conductive fibers 103. I.e. the electroluminescent layer comprises a layer of red light-emitting material, a layer of green light-emitting material and a layer of blue light-emitting material. It can be understood that the invention can realize dynamic driving display by combining the red conductive fibers 101, the green conductive fibers 102 and the blue conductive fibers 103, can be applied in combination with other wearable fabrics, can realize overall color change of the fabrics by lighting the conductive fibers with different colors, and can realize light emission in a specific mode by further weaving patterns and designing a control circuit.
In one embodiment, the material of the electroluminescent layer is a quantum dot material or a chalcogenide of two-dimensional transition metal (2D-TMD). The quantum dot material comprises traditional quantum dots and perovskite quantum dots. It is noted that conventional quantum dots are mainly composed of group IIB-VIA, IIIA-VA or IVA-VIA elements. The luminescent spectra of the quantum dots with different sizes and materials are in different wave band regions. For example, the light emission spectra of zinc sulfide quantum dots with different sizes substantially cover the ultraviolet region, the light emission spectra of cadmium selenide quantum dots substantially cover the visible region, and the light emission spectra of lead selenide quantum dots substantially cover the infrared region. Even if the same quantum dot material is used, the emission spectra of the quantum dot material are different according to different sizes. In the case of cadmium selenide, the emission wavelength of cadmium selenide increases from 510 nm to 610 nm as the radius of the cadmium selenide particle increases from 1.35 nm to 2.40 nm.
It can be understood that due to the quantum size effect and the quantum confinement effect, the spectrum of the prepared quantum dot can be made to cover all bands from blue light to near infrared by simply regulating and controlling the size of the quantum dot. Such as cadmium selenide quantum dots, the color of which can be changed from blue to red under the irradiation of ultraviolet light when the synthesized particle size is increased from 2 nanometers to 8 nanometers. Therefore, the quantum dots can emit R, G, B three-color light by regulating the materials and the sizes of the quantum dots.
In one embodiment, the display further comprises a textile web substrate 30, the textile web substrate 30 comprising a plurality of first textile substrates 301 and a plurality of second textile substrates 302, the plurality of first textile substrates 301 being arranged in parallel with the first conductive fibres 10, the plurality of second textile substrates 302 being arranged in parallel with the second conductive fibres 20; one red conductive fiber 101, one green conductive fiber 102 and one blue conductive fiber 103 are located between two adjacent first textile substrates 301; one of the second conductive fibres 20 is located between two adjacent ones of the second textile substrates 302. It will be appreciated that the present invention can achieve the effect of a full color display by regularly arranging electroluminescent layers emitting R, G, B three colors of light respectively in textile web substrate 30 to form red sub-pixel 401, green sub-pixel 402 and blue sub-pixel 403.
In one embodiment, the first conductive fibers 10 are located between the second conductive fibers 20 and the second textile substrate 302; the second conductive fibres 20 are located between the first conductive fibres 10 and the first textile substrate 301. Namely, the first conductive fibers 10 are clamped and fixed up and down between the second conductive fibers 20 and the second textile substrate 302; the second conductive fibers 20 are sandwiched and fixed up and down between the first conductive fibers 10 and the first textile substrate 301.
In one embodiment, the material of the textile web substrate 30 is any one of fiber, yarn, hemp, polyester, and nylon.
In one embodiment, the plurality of first conductive fibers 10 and the plurality of second conductive fibers 20 are each supplied with the required power by an alternating current having a voltage value greater than or equal to 2 volts and less than or equal to 15 volts.
In summary, the display provided in the embodiments of the present invention includes a plurality of first conductive fibers and a plurality of second conductive fibers, each of the first conductive fibers sequentially includes a first substrate, a first transparent electrode layer, and an electroluminescent layer from inside to outside; the plurality of second conductive fibers and the plurality of first conductive fibers are arranged in a crossed mode, and each second conductive fiber comprises a second substrate and a second transparent electrode layer wrapping the second substrate; wherein the first substrate and the second substrate are both polymer linear substrates; the invention adopts a polymer linear substrate as the first substrate of a plurality of first conductive fibers and the second substrate of a plurality of second conductive fibers, so that the first transparent electrode layer and the second transparent electrode layer can be uniformly coated on the surface of the polymer linear substrate, so that the process for manufacturing the first conductive fiber and the second conductive fiber is simple, the cost is lower, the effect is better, the problems of non-uniform luminescence, Joule heat and the like caused by the roughness of the fabric substrate are improved, and the polymer linear substrate has stable structure and is not easy to deform, thereby solving the problems that the luminous fiber and the electrode fiber displayed by the fabric in the prior art both adopt fiber yarn as the substrate, the rough surface of the fiber yarn causes complex preparation process and higher cost, and is easy to cause the problems of non-uniform luminescence and joule heat, and the fiber yarn has limited service life and is easy to deform under high temperature or washing.
A display provided by an embodiment of the present invention is described in detail above. It should be understood that the exemplary embodiments described herein should be considered merely illustrative for facilitating understanding of the method of the present invention and its core ideas, and not restrictive.

Claims (10)

1. A display, comprising:
the first conductive fibers sequentially comprise a first substrate, a first transparent electrode layer and an electroluminescent layer from inside to outside;
a plurality of second conductive fibers arranged to cross the plurality of first conductive fibers, each of the second conductive fibers including a second substrate and a second transparent electrode layer covering the second substrate;
wherein the first substrate and the second substrate are both polymer wire-like substrates.
2. The display according to claim 1, wherein the polymer wire substrate is an organic polymer wire substrate, and a material of the organic polymer wire substrate is any one of polyethylene terephthalate, polystyrene, polymethyl methacrylate, polyethylene, polypropylene, polyvinyl chloride, polycarbonate, and polyamide resin.
3. The display according to claim 1, wherein the polymer wire substrate has a shape of any one of a circle, an ellipse, a rectangle, and a square in a direction perpendicular to an extending direction of the first conductive fiber or the second conductive fiber.
4. The display of claim 3, wherein the width of the polymer wire-like substrate in a direction perpendicular to the direction of extension of the first conductive fibers or the second conductive fibers is greater than or equal to 5 micrometers and less than or equal to 500 micrometers.
5. The display of claim 1, wherein the plurality of first conductive fibers comprises a plurality of red conductive fibers, a plurality of green conductive fibers, and a plurality of blue conductive fibers.
6. The display of claim 5, wherein the electroluminescent layer is a quantum dot material or a chalcogenide of a two-dimensional transition metal.
7. The display of claim 5, further comprising a textile web substrate comprising a plurality of first textile substrates disposed in parallel with the first conductive fibers and a plurality of second textile substrates disposed in parallel with the second conductive fibers;
the red conductive fiber, the green conductive fiber and the blue conductive fiber are positioned between two adjacent first textile substrates; one said second conductive fibre is located between two adjacent said second textile substrates.
8. The display of claim 7, wherein the first conductive fibers are located between the second conductive fibers and the second textile substrate; the second conductive fibers are located between the first conductive fibers and the first textile substrate.
9. The display of claim 7, wherein the material of the textile web substrate is any one of fiber, yarn, hemp, polyester, and nylon.
10. The display of claim 1, wherein a plurality of the first conductive fibers and a plurality of the second conductive fibers each provide a desired power source via an alternating current having a voltage value greater than or equal to 2 volts and less than or equal to 15 volts.
CN202111386633.7A 2021-11-22 2021-11-22 Display device Active CN114038321B (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6538375B1 (en) * 2000-08-17 2003-03-25 General Electric Company Oled fiber light source
US20050140861A1 (en) * 2003-11-06 2005-06-30 Shinsuke Saida Display device
CN1649539A (en) * 2002-05-10 2005-08-03 沙诺夫股份有限公司 Woven electronic textile, yarn and article
CN1669143A (en) * 2002-07-17 2005-09-14 皇家飞利浦电子股份有限公司 Electroluminescent devices comprising two-dimensional array
CN1926600A (en) * 2004-03-02 2007-03-07 皇家飞利浦电子股份有限公司 Elongated display fibers and displays made thereof
CN101523469A (en) * 2005-11-14 2009-09-02 伊里娜·基留谢夫 Display module and tiled display manufacturing method
US20100277065A1 (en) * 2007-12-12 2010-11-04 Kolon Glotech, Inc. Electroluminescent fabric embedding illuminated fabric display
US20140170920A1 (en) * 2012-12-14 2014-06-19 Sasikanth Manipatruni Electrically functional fabric for flexible electronics
CN111304770A (en) * 2020-02-17 2020-06-19 复旦大学 Transparent conductive fiber, preparation method thereof and application thereof in fabric display
CN113672125A (en) * 2021-08-30 2021-11-19 武汉纺织大学 Fabric-based flexible luminous electronic screen

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6538375B1 (en) * 2000-08-17 2003-03-25 General Electric Company Oled fiber light source
CN1649539A (en) * 2002-05-10 2005-08-03 沙诺夫股份有限公司 Woven electronic textile, yarn and article
CN1669143A (en) * 2002-07-17 2005-09-14 皇家飞利浦电子股份有限公司 Electroluminescent devices comprising two-dimensional array
US20050140861A1 (en) * 2003-11-06 2005-06-30 Shinsuke Saida Display device
CN1926600A (en) * 2004-03-02 2007-03-07 皇家飞利浦电子股份有限公司 Elongated display fibers and displays made thereof
CN101523469A (en) * 2005-11-14 2009-09-02 伊里娜·基留谢夫 Display module and tiled display manufacturing method
US20100277065A1 (en) * 2007-12-12 2010-11-04 Kolon Glotech, Inc. Electroluminescent fabric embedding illuminated fabric display
US20140170920A1 (en) * 2012-12-14 2014-06-19 Sasikanth Manipatruni Electrically functional fabric for flexible electronics
CN111304770A (en) * 2020-02-17 2020-06-19 复旦大学 Transparent conductive fiber, preparation method thereof and application thereof in fabric display
CN113672125A (en) * 2021-08-30 2021-11-19 武汉纺织大学 Fabric-based flexible luminous electronic screen

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