CN113968728B - High-hardness super-wear-resistant fully-polished marble tile and preparation method thereof - Google Patents
High-hardness super-wear-resistant fully-polished marble tile and preparation method thereof Download PDFInfo
- Publication number
- CN113968728B CN113968728B CN202111136549.XA CN202111136549A CN113968728B CN 113968728 B CN113968728 B CN 113968728B CN 202111136549 A CN202111136549 A CN 202111136549A CN 113968728 B CN113968728 B CN 113968728B
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- hardness
- wear
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/19—Alkali metal aluminosilicates, e.g. spodumene
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Finishing Walls (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention specifically relates to a high-hardness super-wear-resistant full-polished marble tile and a preparation method thereof, wherein the full-polished marble tile sequentially comprises the following components from bottom to top: a blank layer, a surface glaze layer and a high-hardness super-wear-resistant glaze polishing layer; transparent corundum particles and quartz particles are distributed in the high-hardness super wear-resistant glaze layer; the overglaze layer is provided with pattern texture. The preparation method comprises the following steps: the method comprises the steps of preparing a blank, preparing overglaze slurry, preparing glaze polishing slurry, preparing high-hardness ultra-wear-resistant glaze polishing slurry, preparing pattern textures and firing. The glaze of the high-hardness, super-wear-resistant and fully-polished marble ceramic tile is perfectly combined with the corundum particles and the quartz particles in a high-temperature molten state, so that the whole glaze is completely integrated, and the glaze is supported by the high-hardness materials of the corundum particles and the quartz particles to form high-hardness glaze, the Vickers hardness of the product glaze can reach more than HV800, and the transparency of the glaze is good.
Description
Technical Field
The invention belongs to the technical field of production of ceramic glaze and marble ceramic tiles, and particularly relates to a high-hardness super-wear-resistant fully-polished marble ceramic tile and a preparation method thereof.
Background
At present, the ceramic floor tiles used in the building material industry are mainly of two types, one is a full-polished marble tile, and the other is an antique brick. The fully-polished marble tile is an in-glaze color tile with the surface brightness of more than 90 degrees or 55 degrees and soft light, and the surface of the in-glaze color tile is polished. The antique brick is a matte ceramic tile with the brightness of about 10 degrees, the surface of the antique brick is not polished, a layer of very thin protective glaze is generally adopted, the requirement on very thin transparency is low, some high-hardness materials can be added in the formula, the Vickers hardness of the surface of a general antique brick product can reach HV850, and the Vickers hardness of most of fully polished marble ceramic tiles on the market is between HV450 and HV 500. The full-polished marble tile is always favored by people because the texture of natural marble is restored by high definition, but after the full-polished marble tile is paved and used for 8-10 years, people find that the full-polished marble tile has serious surface abrasion, mainly low local surface glossiness or obvious scratch, because the surface hardness is lower.
A formula and a production process of wear-resistant high-hardness ceramic are disclosed in a Chinese patent with the publication number CN104803604B, a micro-nano composite glaze is disclosed in a Chinese patent with the publication number CN105036558B, a wear-resistant high-hardness diamond glaze, a preparation method and application are disclosed in a Chinese patent with the publication number CN105272375B, a wear-resistant full-raw-material super-flat thick glaze and application thereof are disclosed in a Chinese patent with the publication number CN106542735B, a frit for glaze and a preparation method thereof are disclosed in a Chinese patent with the publication number CN105967523B, and a low-temperature high-hardness high-wear-resistant full-glaze is disclosed in a Chinese patent with the publication number CN 106966598B.
The technical scheme of the patent improves the hardness and the wear resistance of the ceramic glaze layer or the blank to a certain extent, the hardness and the wear resistance of the glaze layer are improved mainly by optimizing the formula or introducing other materials, but the transparency and the hardness of the glaze are hardly considered, because many glaze materials are changed by the characteristics of minerals after being ball-milled into glaze slurry, the transparency of the glaze layer can be reduced by the materials which can improve the hardness after being substituted into the formula and being ball-milled, and the materials cannot be introduced too much for ensuring the ultratransparency of the full-glazed marble tile.
Disclosure of Invention
In order to solve the problem that transparency and hardness of a full-glazed tile are difficult to achieve simultaneously in the prior art, the invention provides a high-hardness and super-wear-resistant full-glazed marble tile and a preparation method thereof. The technical problem to be solved by the invention is realized by the following technical scheme:
the utility model provides a marble ceramic tile is thrown entirely to super wear-resisting of high rigidity, by supreme down including in proper order: a blank layer, a surface glaze layer and a high-hardness super-wear-resistant glaze polishing layer; transparent corundum particles and quartz particles are distributed in the high-hardness super wear-resistant glaze-polished layer.
Further, the overglaze layer is provided with pattern textures.
Further, the composition of the blank is as follows: 20 to 30 parts of albite, 10 to 16 parts of potash feldspar, 4 to 9 parts of kaolin, 6 to 12 parts of quartz sand, 3 to 6 parts of high alumina clay, 7 to 13 parts of calcite, 1 to 5 parts of talcum, 5 to 20 parts of lithium porcelain stone, 6 to 14 parts of cordierite and 1 to 5 parts of zircon sand.
Further, the composition of the overglaze layer is as follows: 20-40 parts of albite, 10-30 parts of potash feldspar, 10-30 parts of kaolin, 10-30 parts of quartz sand, 1-3 parts of ball clay, 3-10 parts of zinc oxide, 1-10 parts of talc, 5-15 parts of zircon sand and 5-20 parts of alumina.
Further, the composition of the glaze polishing layer is as follows: 30-50 parts of albite, 5-15 parts of wollastonite, 5-15 parts of calcite, 5-15 parts of white jade, 5-10 parts of zinc oxide, 1-8 parts of alumina, 2-8 parts of nepheline, 1-8 parts of barium carbonate and 1-5 parts of talcum.
Further, the particle size of the transparent corundum particles and the quartz particles is between 150um and 250 um.
The preparation method of the high-hardness super-wear-resistant full-polished marble tile comprises the following steps:
the method comprises the following steps: preparing a blank body: weighing raw materials in a corresponding amount according to a blank composition formula, adding water and additives, putting into a ball mill for ball milling to prepare blank slurry, then sieving to remove iron, performing spray granulation, aging and homogenizing, performing compression molding, and drying to prepare a blank for later use;
step two: preparing overglaze slurry: weighing raw materials in a corresponding amount according to a composition formula of the overglaze layer, adding water, putting into a ball mill for ball milling to prepare overglaze slurry, and then removing iron and sieving for later use;
step three: preparing polishing slurry: weighing a corresponding amount of raw materials according to a glaze polishing layer composition formula, adding water, putting into a ball mill for ball milling to prepare glaze polishing slurry, removing iron, and sieving for later use;
step four: preparing high-hardness super wear-resistant glaze polishing slurry: adding transparent corundum particles and transparent quartz particles into the glaze polishing slurry obtained in the step three, and uniformly stirring to obtain the modified high-hardness and super-wear-resistant glaze polishing slurry, wherein the adding proportion of the transparent corundum particles is 5-20 parts, and the adding proportion of the transparent quartz particles is 5-20 parts;
step five: preparing pattern texture: uniformly spraying the overglaze slurry obtained in the step two onto the blank by using a bell jar glaze spraying device, controlling the weight to be 500-800 g per square meter, then printing marble textures onto the glaze through ink jet printing or screen printing or rubber roll printing, and uniformly spraying the high-hardness super wear-resistant glaze polishing slurry obtained in the step four onto the pattern by using a bell jar;
step six: and (3) firing: and putting the semi-finished product obtained in the fifth step into a kiln for sintering, wherein the sintering temperature is 1170-1230 ℃, and the sintering time is controlled to be 35-60 minutes.
Furthermore, in the third step, the particle size of the residue after ball milling is controlled to be 0.5-1.5um.
Further, in the first step, the second step and the third step, the adding proportion of the water is 28-38%.
Further, the above additives are mainly debonders.
Compared with the prior art, the invention has the following beneficial effects:
1. according to the high-hardness ultra-wear-resistant fully-polished marble tile, the glaze surface is supported by corundum particles and quartz particle high-hardness materials, the Vickers hardness of the polished product glaze surface can reach more than HV800, and is completely improved by several grades relative to HV 400-HV 500 grades of common polished glaze, and a wear resistance test also shows that the product wear resistance is improved to 4-6000 turns from 3-750 turns of common polished glaze through the corundum particles introduced by the scheme;
2. according to the preparation method of the high-hardness super-wear-resistant full-polished marble ceramic tile, the glaze is perfectly combined with the transparent corundum particles and the quartz particles in a high-temperature molten state, so that the whole glaze is completely integrated, the Vickers hardness of the glaze can reach more than HV800, and the glaze has good transparency;
3. according to the preparation method of the high-hardness super-wear-resistant full-polished marble ceramic tile, corundum particles and quartz particles which increase the hardness of the glaze are introduced into the glaze layer in an additional mode, the problem that ball milling is carried out in the prior art, the transparency of the glaze is reduced due to the fact that the performance is changed after ball milling and crushing are avoided, and the original hardness of the material cannot be better shown after the particles become thin is solved;
4. according to the preparation method of the high-hardness super-wear-resistant fully-polished marble ceramic tile, the fire of the glaze surface is increased due to the fact that the basic polished glaze is not broken by corundum caused by ball milling, so that the obtained glaze has better transparency, and the color range is wider compared with other patent schemes.
Drawings
Fig. 1 is a schematic structural view of the high-hardness super-wear-resistant fully-polished marble tile of the present invention.
Fig. 2 is the hardness test result of example 1.
Fig. 3 is the hardness test result of example 2.
Fig. 4 is the hardness test result of comparative example 1.
Fig. 5 is the hardness test result of comparative example 2.
Fig. 6 is a graph comparing the wear resistance of example 1 with that of a general marble tile.
In the figure: 1. a green body layer; 2. a cover glaze layer; 3. high-hardness super wear-resistant layer.
Detailed Description
The present invention will be described in further detail with reference to specific examples, but the embodiments of the present invention are not limited thereto.
The invention aims to provide a high-hardness super-wear-resistant fully-polished marble ceramic tile and a preparation method thereof, and aims to solve the problem that the prior art is difficult to meet the market demand of fully-polished glazed tiles with higher hardness and wear resistance.
Referring to the attached figure 1, the high-hardness and super-wear-resistant fully-polished marble tile sequentially comprises the following components in sequence from bottom to top: a blank layer, a surface glaze layer and a high-hardness super-wear-resistant glaze polishing layer; transparent corundum particles and quartz particles are distributed in the high-hardness super wear-resistant glaze layer; the overglaze layer is provided with pattern texture. The particle size of the transparent corundum particles and the quartz particles is between 150um and 250 um.
The composition of the green body is: 20 to 30 parts of albite, 10 to 16 parts of potash feldspar, 4 to 9 parts of kaolin, 6 to 12 parts of quartz sand, 3 to 6 parts of high alumina clay, 7 to 13 parts of calcite, 1 to 5 parts of talcum, 5 to 20 parts of lithium porcelain stone, 6 to 14 parts of cordierite and 1 to 5 parts of zircon sand.
The overglaze layer comprises the following components: 20-40 parts of albite, 10-30 parts of potash feldspar, 10-30 parts of kaolin, 10-30 parts of quartz sand, 1-3 parts of ball clay, 3-10 parts of zinc oxide, 1-10 parts of talc, 5-15 parts of zircon sand and 5-20 parts of alumina.
The composition of the glaze polishing layer is as follows: 30-50 parts of albite, 5-15 parts of wollastonite, 5-15 parts of calcite, 5-15 parts of white jade, 5-10 parts of zinc oxide, 1-8 parts of alumina, 2-8 parts of nepheline, 1-8 parts of barium carbonate and 1-5 parts of talcum.
The preparation method comprises the following steps:
the method comprises the following steps: preparing a blank body: weighing a corresponding amount of raw materials according to a blank composition formula, adding water and an additive, wherein the adding proportion of the water is 28-35%, the additive is mainly a dispergator, putting the dispergator into a ball mill for ball milling to prepare blank slurry, and then sieving to remove iron, carrying out spray granulation, carrying out aging and homogenization, carrying out compression molding, and drying to prepare a blank for later use;
step two: preparing overglaze slurry: weighing corresponding amount of raw materials according to the composition formula of the surface glaze layer, adding water with the adding proportion of 28-35%, putting into a ball mill for ball milling to prepare surface glaze slurry, then removing iron and sieving for later use;
step three: preparing glaze polishing slurry: weighing corresponding amount of raw materials according to a composition formula of a glaze polishing layer, adding water with the addition ratio of 28-35%, putting into a ball mill for ball milling, controlling the particle size of the residue after ball milling to be 0.5-1.5 mu m, preparing glaze polishing slurry, removing iron, and sieving for later use;
step four: preparing high-hardness super wear-resistant glaze polishing slurry: adding transparent corundum particles and transparent quartz particles into the glaze polishing slurry obtained in the step three, and uniformly stirring to obtain the modified high-hardness super wear-resistant glaze polishing slurry, wherein the adding proportion of the transparent corundum particles is 5-20%, and the adding proportion of the transparent quartz particles is 5-20%;
step five: preparing pattern texture: uniformly spraying the overglaze slurry obtained in the second step on the blank by using a bell jar glaze spraying device, controlling the weight to be 500-800 g/square meter, then performing ink-jet printing or screen printing and rubber roll printing to print marble textures on a glaze, and uniformly spraying the high-hardness super wear-resistant polishing glaze slurry obtained in the fourth step on a pattern by using a bell jar;
step six: and (3) firing: and (4) placing the semi-finished product obtained in the fifth step into a kiln for sintering, wherein the sintering temperature is 1170-1230 ℃, and the sintering period can be controlled within 35-60 minutes according to the length of the kiln.
Example 1:
the high-hardness super-wear-resistant full-polishing marble tile and the preparation method thereof provided by the embodiment sequentially comprise the following components from bottom to top: a blank layer, a surface glaze layer and a high-hardness super-wear-resistant polishing glaze layer; transparent corundum particles and quartz particles are distributed in the high-hardness super wear-resistant glaze layer; the overglaze layer is provided with pattern texture. The particle size of the transparent corundum particles and the quartz particles in the embodiment is between 150um and 250 um.
The composition of the green body in this example was: 20 parts of albite, 16 parts of potassium feldspar, 9 parts of kaolin, 12 parts of quartz sand, 6 parts of high alumina clay, 13 parts of calcite, 1 part of talcum, 5 parts of lithium porcelain stone, 14 parts of cordierite and 2 parts of zircon sand.
The composition of the overglaze layer in this example is: 20 parts of albite, 30 parts of potassium feldspar, 10 parts of kaolin, 12 parts of quartz sand, 1 part of ball clay, 5 parts of zinc oxide, 2 parts of talc, 15 parts of zircon sand and 5 parts of alumina.
The composition of the glaze polishing layer in the embodiment is as follows: 30 parts of albite, 15 parts of wollastonite, 15 parts of calcite, 15 parts of white jade, 5 parts of zinc oxide, 8 parts of aluminum oxide, 2 parts of nepheline, 5 parts of barium carbonate and 5 parts of talc.
The preparation method of the high-hardness and super-wear-resistant fully-polished marble tile comprises the following steps:
the method comprises the following steps: preparing a blank body: weighing a corresponding amount of raw materials according to a blank composition formula, adding water and an additive, wherein the adding proportion of the water is 35%, the additive mainly is a dispergator, putting the dispergator into a ball mill for ball milling to prepare blank slurry, and then sieving to remove iron, performing spray granulation, ageing and homogenizing, performing compression molding, and drying to prepare a blank for later use;
step two: preparing overglaze slurry: weighing a corresponding amount of raw materials according to a composition formula of the overglaze layer, adding water with the water addition ratio of 30%, putting the mixture into a ball mill for ball milling to prepare overglaze slurry, and then removing iron and sieving for later use;
step three: preparing glaze polishing slurry: weighing a corresponding amount of raw materials according to a glaze polishing layer composition formula, adding water with the water addition ratio of 30%, putting the raw materials into a ball mill for ball milling, controlling the particle size of residues after ball milling to be 0.5-1.5 mu m, preparing glaze polishing slurry, removing iron, and sieving for later use;
step four: preparing high-hardness super wear-resistant glaze polishing slurry: adding transparent corundum particles and transparent quartz particles into the glaze polishing slurry obtained in the step three, wherein the transparent corundum particles and the transparent quartz particles are added according to the proportion of 20%, and uniformly stirring to obtain the modified high-hardness super-wear-resistant glaze polishing slurry;
step five: preparing pattern texture: uniformly spraying the overglaze slurry obtained in the step two onto the blank by using a bell jar glaze spraying device, controlling the weight to be 500-800 g per square meter, then printing marble textures onto the glaze through ink jet printing or screen printing or rubber roll printing, and uniformly spraying the high-hardness super wear-resistant glaze polishing slurry obtained in the step four onto the pattern by using a bell jar;
step six: firing: and (5) placing the semi-finished product obtained in the fifth step into a kiln for sintering, wherein the sintering temperature is 1170-1230 ℃, and the sintering period can be controlled to be 35-60 minutes according to the length of the kiln.
Example 1 the hardness test results of the fully polished marble tile are shown in fig. 2.
The abrasion resistance of the fully polished marble tile of example 1 of the present invention was tested according to the regulations of GB/3810.7-2006, related to "determination of abrasion resistance of glazed tile", and the test results refer to FIG. 6.
As can be seen from fig. 6, the conventional marble tile had a wear trace at a grinding revolution of 750 revolutions, and the full-polished marble tile of example 1 had no wear trace at a grinding revolution of 6000 revolutions, and its wear resistance was significantly superior to that of the conventional marble tile.
Example 2:
the super wear-resisting marble ceramic tile of throwing entirely of high rigidity of this embodiment includes by supreme down in proper order: a blank layer, a surface glaze layer and a high-hardness super-wear-resistant polishing glaze layer; transparent corundum particles and quartz particles are distributed in the high-hardness super wear-resistant glaze layer; the overglaze layer is provided with pattern grains. The particle size of the transparent corundum particles and the quartz particles in the embodiment is between 150um and 250 um.
The composition of the green body in this example was: 30 parts of albite, 10 parts of potassium feldspar, 4 parts of kaolin, 6 parts of quartz sand, 3 parts of high alumina clay, 11 parts of calcite, 5 parts of talc, 20 parts of laponite, 6 parts of cordierite and 5 parts of zircon sand.
The composition of the overglaze layer in this example is: 40 parts of albite, 10 parts of potassium feldspar, 12 parts of kaolin, 10 parts of quartz sand, 3 parts of ball clay, 10 parts of zinc oxide, 1 part of talc, 7 parts of zircon sand and 7 parts of alumina.
The composition of the glaze polishing layer in the embodiment is as follows: 50 parts of albite, 5 parts of wollastonite, 10 parts of calcite, 5 parts of white jade, 10 parts of zinc oxide, 1 part of aluminum oxide, 8 parts of nepheline, 8 parts of barium carbonate and 3 parts of talc.
The preparation method of the high-hardness super-wear-resistant full-polished marble tile comprises the following steps:
the method comprises the following steps: preparing a blank body: weighing a corresponding amount of raw materials according to a blank composition formula, adding water and an additive, wherein the adding proportion of the water is 38%, the additive mainly is a dispergator, putting the dispergator into a ball mill for ball milling to prepare blank slurry, and then sieving to remove iron, performing spray granulation, ageing and homogenizing, performing compression molding, and drying to prepare a blank for later use;
step two: preparing overglaze slurry: weighing a corresponding amount of raw materials according to a composition formula of the overglaze layer, adding water with the water addition ratio of 28%, putting the mixture into a ball mill for ball milling to prepare overglaze slurry, and then removing iron and sieving for later use;
step three: preparing glaze polishing slurry: weighing a corresponding amount of raw materials according to a glaze polishing layer composition formula, adding water, wherein the adding proportion of the water is 38%, putting the raw materials into a ball mill for ball milling, controlling the granularity of residues after ball milling to be 0.5-1.5 mu m, preparing glaze polishing slurry, removing iron, and sieving for later use;
step four: preparing high-hardness super wear-resistant glaze polishing slurry: adding transparent corundum particles and transparent quartz particles into the glaze polishing slurry obtained in the step three, and uniformly stirring to obtain the modified high-hardness super wear-resistant glaze polishing slurry, wherein the adding proportion of the transparent corundum particles is 15%, and the adding proportion of the transparent quartz particles is 15%;
step five: preparing pattern texture: uniformly spraying the overglaze slurry obtained in the step two onto the blank by using a bell jar glaze spraying device, controlling the weight to be 500-800 g per square meter, then printing marble textures onto the glaze through ink jet printing or screen printing or rubber roll printing, and uniformly spraying the high-hardness super wear-resistant glaze polishing slurry obtained in the step four onto the pattern by using a bell jar;
step six: firing: and (4) placing the semi-finished product obtained in the fifth step into a kiln for sintering, wherein the sintering temperature is 1170-1230 ℃, and the sintering period can be controlled within 35-60 minutes according to the length of the kiln.
Example 2 the hardness test results of the fully polished marble tile are shown in fig. 3.
Example 3:
the super wear-resisting marble ceramic tile of throwing entirely of high rigidity of this embodiment includes by supreme down in proper order: a blank layer, a surface glaze layer and a high-hardness super-wear-resistant glaze polishing layer; transparent corundum particles and quartz particles are distributed in the high-hardness super wear-resistant glaze layer; the overglaze layer is provided with pattern texture. The particle size of the transparent corundum particles and the quartz particles in the embodiment is between 150um and 250 um.
The composition of the green body in this example was: 25 parts of albite, 14 parts of potassium feldspar, 8 parts of kaolin, 10 parts of quartz sand, 5 parts of high alumina clay, 7 parts of calcite, 3 parts of talc, 15 parts of lithium porcelain stone, 12 parts of cordierite and 1 part of zircon sand.
The composition of the overglaze layer in the embodiment is as follows: 25 parts of albite, 15 parts of potassium feldspar, 20 parts of kaolin, 20 parts of quartz sand, 2 parts of ball clay, 3 parts of zinc oxide, 10 parts of talc, 5 parts of zircon sand and 20 parts of alumina.
The composition of the glaze polishing layer in the embodiment is as follows: 45 parts of albite, 12 parts of wollastonite, 5 parts of calcite, 10 parts of white jade, 15 parts of zinc oxide, 5 parts of aluminum oxide, 6 parts of nepheline, 1 part of barium carbonate and 1 part of talc.
The preparation method of the high-hardness and super-wear-resistant fully-polished marble tile comprises the following steps:
the method comprises the following steps: preparing a blank body: weighing a corresponding amount of raw materials according to a blank composition formula, adding water and an additive, wherein the adding proportion of the water is 28%, the additive mainly is a dispergator, putting the dispergator into a ball mill for ball milling to prepare blank slurry, and then sieving to remove iron, performing spray granulation, ageing and homogenizing, performing compression molding, and drying to prepare a blank for later use;
step two: preparing overglaze slurry: weighing a corresponding amount of raw materials according to a composition formula of the overglaze layer, adding water, wherein the adding proportion of the water is 38%, putting the mixture into a ball mill for ball milling to prepare overglaze slurry, and then removing iron and sieving for later use;
step three: preparing glaze polishing slurry: weighing a corresponding amount of raw materials according to a glaze polishing layer composition formula, adding water, wherein the adding proportion of the water is 38%, putting the raw materials into a ball mill for ball milling, controlling the particle size of the residues after ball milling to be 0.5-1.5 mu m, preparing glaze polishing slurry, removing iron, and sieving for later use;
step four: preparing high-hardness super wear-resistant glaze polishing slurry: adding transparent corundum particles and transparent quartz particles into the glaze polishing slurry obtained in the step three according to the proportion of 5%, and uniformly stirring to obtain the modified high-hardness super-wear-resistant glaze polishing slurry;
step five: preparing pattern texture: uniformly spraying the overglaze slurry obtained in the step two onto the blank by using a bell jar glaze spraying device, controlling the weight to be 500-800 g per square meter, then printing marble textures onto the glaze through ink jet printing or screen printing or rubber roll printing, and uniformly spraying the high-hardness super wear-resistant glaze polishing slurry obtained in the step four onto the pattern by using a bell jar;
step six: and (3) firing: and (4) placing the semi-finished product obtained in the fifth step into a kiln for sintering, wherein the sintering temperature is 1170-1230 ℃, and the sintering period can be controlled within 35-60 minutes according to the length of the kiln.
Example 4:
the super wear-resisting marble ceramic tile of throwing entirely of high rigidity of this embodiment includes by supreme down in proper order: a blank layer, a surface glaze layer and a high-hardness super-wear-resistant polishing glaze layer; transparent corundum particles and quartz particles are distributed in the high-hardness super wear-resistant polished glaze layer; the overglaze layer is provided with pattern grains. The particle size of the transparent corundum particles and the quartz particles in the embodiment is between 150um and 250 um.
The composition of the green body in this example was: 30 parts of albite, 10 parts of potassium feldspar, 4 parts of kaolin, 6 parts of quartz sand, 3 parts of high alumina clay, 11 parts of calcite, 5 parts of talc, 20 parts of laponite, 6 parts of cordierite and 5 parts of zircon sand.
The composition of the overglaze layer in this example is: 40 parts of albite, 10 parts of potassium feldspar, 12 parts of kaolin, 10 parts of quartz sand, 3 parts of ball clay, 10 parts of zinc oxide, 1 part of talc, 7 parts of zircon sand and 7 parts of alumina.
The composition of the glaze polishing layer in the embodiment is as follows: 50 parts of albite, 5 parts of wollastonite, 10 parts of calcite, 5 parts of white jade, 10 parts of zinc oxide, 1 part of alumina, 8 parts of nepheline, 8 parts of barium carbonate and 3 parts of talc.
The preparation method of the high-hardness super-wear-resistant full-polished marble tile comprises the following steps:
the method comprises the following steps: preparing a blank body: weighing a corresponding amount of raw materials according to a blank composition formula, adding water and an additive, wherein the adding proportion of the water is 35%, the additive mainly is a dispergator, putting the dispergator into a ball mill for ball milling to prepare blank slurry, and then sieving to remove iron, performing spray granulation, ageing and homogenizing, performing compression molding, and drying to prepare a blank for later use;
step two: preparing overglaze slurry: weighing a corresponding amount of raw materials according to a composition formula of a surface glaze layer, adding water, wherein the adding proportion of the water is 35%, putting the mixture into a ball mill for ball milling to prepare surface glaze slurry, and then removing iron and sieving for later use;
step three: preparing polishing slurry: weighing a corresponding amount of raw materials according to a glaze polishing layer composition formula, adding water, wherein the adding proportion of the water is 35%, putting the raw materials into a ball mill for ball milling, controlling the particle size of the residues after ball milling to be 0.5-1.5 mu m, preparing glaze polishing slurry, removing iron, and sieving for later use;
step four: preparing high-hardness super wear-resistant glaze polishing slurry: adding transparent corundum particles and transparent quartz particles into the glaze polishing slurry obtained in the step three, and uniformly stirring to obtain the modified high-hardness super wear-resistant glaze polishing slurry, wherein the adding proportion of the transparent corundum particles is 8%, and the adding proportion of the transparent quartz particles is 12%;
step five: preparing pattern texture: uniformly spraying the overglaze slurry obtained in the step two onto the blank by using a bell jar glaze spraying device, controlling the weight to be 500-800 g per square meter, then printing marble textures onto the glaze through ink jet printing or screen printing or rubber roll printing, and uniformly spraying the high-hardness super wear-resistant glaze polishing slurry obtained in the step four onto the pattern by using a bell jar;
step six: firing: and (5) placing the semi-finished product obtained in the fifth step into a kiln for sintering, wherein the sintering temperature is 1170-1230 ℃, and the sintering period can be controlled to be 35-60 minutes according to the length of the kiln.
Comparative example 1:
the high-hardness super-wear-resistant full-polishing marble tile and the preparation method thereof provided by the embodiment sequentially comprise the following components from bottom to top: a blank layer, a surface glaze layer and a high-hardness super-wear-resistant glaze polishing layer; transparent corundum particles and quartz particles are distributed in the high-hardness super wear-resistant polished glaze layer; the overglaze layer is provided with pattern grains. The particle size of the transparent corundum particles and the quartz particles in the embodiment is between 150um and 250 um.
The composition of the green body in this example was: 20 parts of albite, 16 parts of potassium feldspar, 9 parts of kaolin, 12 parts of quartz sand, 6 parts of high alumina clay, 13 parts of calcite, 1 part of talcum, 5 parts of lithium porcelain stone, 14 parts of cordierite and 2 parts of zircon sand.
The composition of the overglaze layer in this example is: 20 parts of albite, 30 parts of potassium feldspar, 10 parts of kaolin, 12 parts of quartz sand, 1 part of ball clay, 5 parts of zinc oxide, 2 parts of talc, 15 parts of zircon sand and 5 parts of alumina.
The composition of the glaze polishing layer in the embodiment is as follows: 30 parts of albite, 15 parts of wollastonite, 15 parts of calcite, 15 parts of white jade, 5 parts of zinc oxide, 8 parts of aluminum oxide, 2 parts of nepheline, 5 parts of barium carbonate and 5 parts of talc.
The preparation method of the high-hardness super-wear-resistant full-polished marble tile comprises the following steps:
the method comprises the following steps: preparing a blank body: weighing a corresponding amount of raw materials according to a blank composition formula, adding water and an additive, wherein the adding proportion of the water is 35%, the additive mainly is a dispergator, putting the dispergator into a ball mill for ball milling to prepare blank slurry, and then sieving to remove iron, performing spray granulation, ageing and homogenizing, performing compression molding, and drying to prepare a blank for later use;
step two: preparing overglaze slurry: weighing a corresponding amount of raw materials according to a composition formula of the overglaze layer, adding water with the water addition ratio of 30%, putting the mixture into a ball mill for ball milling to prepare overglaze slurry, and then removing iron and sieving for later use;
step three: preparing polishing slurry: weighing corresponding amount of raw materials according to a glaze polishing layer composition formula, adding water with the adding proportion of 30%, putting into a ball mill for ball milling, controlling the particle size of the residues after ball milling to be 0.5-1.5 mu m, preparing glaze polishing slurry, removing iron, and sieving for later use;
step four: preparing high-hardness super wear-resistant glaze polishing slurry: adding transparent corundum particles and transparent quartz particles into the glaze polishing slurry obtained in the step three, wherein the transparent corundum particles and the transparent quartz particles are added according to the proportion of 3%, and uniformly stirring to obtain the modified high-hardness super-wear-resistant glaze polishing slurry;
step five: preparing pattern texture: uniformly spraying the overglaze slurry obtained in the step two onto the blank by using a bell jar glaze spraying device, controlling the weight to be 500-800 g per square meter, then printing marble textures onto the glaze through ink jet printing or screen printing or rubber roll printing, and uniformly spraying the high-hardness super wear-resistant glaze polishing slurry obtained in the step four onto the pattern by using a bell jar;
step six: firing: and (4) placing the semi-finished product obtained in the fifth step into a kiln for sintering, wherein the sintering temperature is 1170-1230 ℃, and the sintering period can be controlled within 35-60 minutes according to the length of the kiln.
Comparative example 1 the hardness test results of the fully polished marble tile are shown in fig. 4.
Comparative example 2:
the difference from the embodiment 1 is that: the high-hardness super-wear-resistant full-polishing marble tile and the preparation method thereof provided by the embodiment sequentially comprise the following components from bottom to top: a body layer, a cover glaze layer and a glaze polishing layer; the overglaze layer is provided with pattern grains.
The composition of the green body in this example was: 20 parts of albite, 16 parts of potassium feldspar, 9 parts of kaolin, 12 parts of quartz sand, 6 parts of high alumina clay, 13 parts of calcite, 1 part of talcum, 5 parts of lithium porcelain stone, 14 parts of cordierite and 2 parts of zircon sand.
The composition of the overglaze layer in this example is: 20 parts of albite, 30 parts of potassium feldspar, 10 parts of kaolin, 12 parts of quartz sand, 1 part of ball clay, 5 parts of zinc oxide, 2 parts of talc, 15 parts of zircon sand and 5 parts of alumina.
The composition of the glaze polishing layer in the embodiment is as follows: 30 parts of albite, 15 parts of wollastonite, 15 parts of calcite, 15 parts of white jade, 5 parts of zinc oxide, 8 parts of aluminum oxide, 2 parts of nepheline, 5 parts of barium carbonate and 5 parts of talc.
The preparation method of the high-hardness super-wear-resistant full-polished marble tile comprises the following steps:
the method comprises the following steps: preparing a blank body: weighing raw materials in a corresponding amount according to a blank composition formula, adding water and an additive, wherein the adding proportion of the water is 35 percent, and the additive mainly is a dispergator, putting the dispergator into a ball mill for ball milling to prepare blank slurry, and then sieving to remove iron, carrying out spray granulation, ageing and homogenizing, carrying out compression molding, and drying to prepare a blank for later use;
step two: preparing overglaze slurry: weighing a corresponding amount of raw materials according to a composition formula of the overglaze layer, adding water with the water addition ratio of 30%, putting the mixture into a ball mill for ball milling to prepare overglaze slurry, and then removing iron and sieving for later use;
step three: preparing glaze polishing slurry: weighing a corresponding amount of raw materials according to a glaze polishing layer composition formula, adding water with the water addition ratio of 30%, putting the raw materials into a ball mill for ball milling, controlling the particle size of residues after ball milling to be 0.5-1.5 mu m, preparing glaze polishing slurry, removing iron, and sieving for later use;
step four: preparing pattern texture: uniformly spraying the overglaze slurry obtained in the second step on the blank by using a bell jar glaze spraying device, controlling the weight to be 500-800 g/square meter, then performing ink-jet printing or screen printing and rubber roll printing to print marble textures on a glaze, and uniformly spraying the glaze polishing slurry obtained in the third step on the pattern by using a bell jar;
step five: firing: and (4) placing the semi-finished product obtained in the fifth step into a kiln for sintering, wherein the sintering temperature is 1170-1230 ℃, and the sintering period can be controlled within 35-60 minutes according to the length of the kiln.
Comparative example 2 the hardness test results of the fully polished marble tile are shown in fig. 5.
The foregoing is a more detailed description of the invention in connection with specific preferred embodiments and it is not intended that the invention be limited to these specific details. For those skilled in the art to which the invention pertains, several simple deductions or substitutions can be made without departing from the spirit of the invention, and all shall be considered as belonging to the protection scope of the invention.
Claims (7)
1. The utility model provides a marble ceramic tile is thrown entirely to super wear-resisting of high rigidity which characterized in that: from bottom to top include in proper order: a blank layer, a surface glaze layer and a high-hardness super-wear-resistant polishing glaze layer; transparent corundum particles and quartz particles are distributed in the high-hardness super wear-resistant polished glaze layer, and the particle size of the transparent corundum particles and the particle size of the quartz particles are between 150 and 250 micrometers;
the high-hardness super-wear-resistant glaze polishing layer comprises the following components: 30-50 parts of albite, 5-15 parts of wollastonite, 5-15 parts of calcite, 5-15 parts of white jade, 5-10 parts of zinc oxide, 1-8 parts of alumina, 2-8 parts of nepheline, 1-8 parts of barium carbonate and 1-5 parts of talcum;
the preparation method of the high-hardness super-wear-resistant fully-polished marble ceramic tile comprises the following steps:
the method comprises the following steps: preparing a blank body: weighing raw materials in a corresponding amount according to a blank composition formula, adding water and additives, putting into a ball mill for ball milling to prepare blank slurry, then sieving to remove iron, performing spray granulation, aging and homogenizing, performing compression molding, and drying to prepare a blank for later use;
step two: preparing overglaze slurry: weighing raw materials in a corresponding amount according to a composition formula of the overglaze layer, adding water, putting into a ball mill for ball milling to prepare overglaze slurry, and then removing iron and sieving for later use;
step three: preparing polishing slurry: weighing a corresponding amount of raw materials according to a glaze polishing layer composition formula, adding water, putting into a ball mill for ball milling to prepare glaze polishing slurry, removing iron, and sieving for later use;
step four: preparing high-hardness super wear-resistant glaze polishing slurry: adding transparent corundum particles and transparent quartz particles into the glaze polishing slurry obtained in the step three, and uniformly stirring to obtain the modified high-hardness and super-wear-resistant glaze polishing slurry, wherein the adding proportion of the transparent corundum particles is 5-20 parts, and the adding proportion of the transparent quartz particles is 5-20 parts;
step five: preparing pattern texture: uniformly spraying the overglaze slurry obtained in the second step on the blank by using a bell jar glaze spraying device, controlling the weight to be 500-800 g per square meter, printing marble textures on the glaze surface, and uniformly spraying the high-hardness and super-wear-resistant glaze polishing slurry obtained in the fourth step on the pattern by using a bell jar;
step six: firing: and (5) placing the semi-finished product obtained in the step five into a kiln for sintering, wherein the sintering temperature is 1170-1230 ℃, and the sintering time is controlled to be 35-60 minutes.
2. The high-hardness ultra-wear-resistant full-polished marble tile according to claim 1, wherein the overglaze layer is provided with a pattern texture.
3. The high-hardness ultra-wear-resistant full-polished marble tile according to claim 2, wherein the composition of the green body is: 20 to 30 parts of albite, 10 to 16 parts of potash feldspar, 4 to 9 parts of kaolin, 6 to 12 parts of quartz sand, 3 to 6 parts of high alumina clay, 7 to 13 parts of calcite, 1 to 5 parts of talcum, 5 to 20 parts of lithium porcelain stone, 6 to 14 parts of cordierite and 1 to 5 parts of zircon sand.
4. The high-hardness ultra-wear-resistant full-polished marble tile according to claim 2, wherein the composition of the overglaze layer is: 20-40 parts of albite, 10-30 parts of potassium feldspar, 10-30 parts of kaolin, 10-30 parts of quartz sand, 1-3 parts of ball clay, 3-10 parts of zinc oxide, 1-10 parts of talc, 5-15 parts of zircon sand and 5-20 parts of alumina.
5. The high-hardness ultra-wear-resistant fully-polished marble tile according to claim 1, wherein: in the third step, the granularity of the residue after ball milling is controlled to be 0.5-1.5um.
6. The high-hardness ultra-wear-resistant full-polished marble tile according to claim 1, wherein: in the first step, the second step and the third step, the adding proportion of the water is 28-38%.
7. The high-hardness ultra-wear-resistant full-polished marble tile according to claim 1, wherein: the additive is mainly a debonder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111136549.XA CN113968728B (en) | 2021-09-27 | 2021-09-27 | High-hardness super-wear-resistant fully-polished marble tile and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111136549.XA CN113968728B (en) | 2021-09-27 | 2021-09-27 | High-hardness super-wear-resistant fully-polished marble tile and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113968728A CN113968728A (en) | 2022-01-25 |
| CN113968728B true CN113968728B (en) | 2022-11-01 |
Family
ID=79587177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111136549.XA Active CN113968728B (en) | 2021-09-27 | 2021-09-27 | High-hardness super-wear-resistant fully-polished marble tile and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113968728B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114890818B (en) * | 2022-05-30 | 2023-04-28 | 河北浩锐陶瓷制品有限公司 | High-brightness ceramic tile and production process thereof |
| CN115304408B (en) * | 2022-10-12 | 2023-02-03 | 佛山市东鹏陶瓷有限公司 | Wear-resistant glazed brick with good color development, strong transparency and high hardness and preparation process thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6174608B1 (en) * | 1997-11-27 | 2001-01-16 | Ferro (Italia) Srl | Ceramic tile and glaze for use thereon |
| CN106542735A (en) * | 2017-01-19 | 2017-03-29 | 佛山市三水大岛制釉有限公司 | A kind of super flat thickness throwing glaze of wear-resisting full raw material and its application |
| CN106966598A (en) * | 2017-04-15 | 2017-07-21 | 景德镇陶瓷大学 | A kind of low temperature high-hardness, wearable throws glaze and preparation method thereof entirely |
| CN107176790A (en) * | 2017-05-22 | 2017-09-19 | 江苏拜富科技有限公司 | Raw material high abrasion throws glaze and preparation method thereof entirely |
| CN110642521A (en) * | 2019-12-02 | 2020-01-03 | 蒙娜丽莎集团股份有限公司 | High-wear-resistance antifouling microcrystal decorative ceramic thick plate and preparation method thereof |
| CN110683767A (en) * | 2019-11-20 | 2020-01-14 | 佛山市东鹏陶瓷有限公司 | High-performance wear-resistant glaze and preparation method thereof |
| CN111470884A (en) * | 2020-06-24 | 2020-07-31 | 蒙娜丽莎集团股份有限公司 | High-hardness high-wear-resistance full-glazed ceramic tile and preparation method thereof |
| CN111548014A (en) * | 2020-06-08 | 2020-08-18 | 广东家美陶瓷有限公司 | Microcrystal glaze, wear-resistant glaze, transparent microcrystal wear-resistant fully-polished glaze tile and preparation method |
| CN111995437A (en) * | 2020-09-10 | 2020-11-27 | 淄博峰霞陶瓷有限公司 | Super wear-resistant anti-skid ceramic tile and preparation method thereof |
| CN112592063A (en) * | 2020-12-25 | 2021-04-02 | 肇庆乐华陶瓷洁具有限公司 | High-wear-resistance marble-imitated ceramic tile and preparation method thereof |
| CN113173806A (en) * | 2021-05-07 | 2021-07-27 | 佛山市东鹏陶瓷有限公司 | Production process of superfine dry particle ceramic large plate and product thereof |
-
2021
- 2021-09-27 CN CN202111136549.XA patent/CN113968728B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6174608B1 (en) * | 1997-11-27 | 2001-01-16 | Ferro (Italia) Srl | Ceramic tile and glaze for use thereon |
| CN106542735A (en) * | 2017-01-19 | 2017-03-29 | 佛山市三水大岛制釉有限公司 | A kind of super flat thickness throwing glaze of wear-resisting full raw material and its application |
| CN106966598A (en) * | 2017-04-15 | 2017-07-21 | 景德镇陶瓷大学 | A kind of low temperature high-hardness, wearable throws glaze and preparation method thereof entirely |
| CN107176790A (en) * | 2017-05-22 | 2017-09-19 | 江苏拜富科技有限公司 | Raw material high abrasion throws glaze and preparation method thereof entirely |
| CN110683767A (en) * | 2019-11-20 | 2020-01-14 | 佛山市东鹏陶瓷有限公司 | High-performance wear-resistant glaze and preparation method thereof |
| CN110642521A (en) * | 2019-12-02 | 2020-01-03 | 蒙娜丽莎集团股份有限公司 | High-wear-resistance antifouling microcrystal decorative ceramic thick plate and preparation method thereof |
| CN111548014A (en) * | 2020-06-08 | 2020-08-18 | 广东家美陶瓷有限公司 | Microcrystal glaze, wear-resistant glaze, transparent microcrystal wear-resistant fully-polished glaze tile and preparation method |
| CN111470884A (en) * | 2020-06-24 | 2020-07-31 | 蒙娜丽莎集团股份有限公司 | High-hardness high-wear-resistance full-glazed ceramic tile and preparation method thereof |
| CN111995437A (en) * | 2020-09-10 | 2020-11-27 | 淄博峰霞陶瓷有限公司 | Super wear-resistant anti-skid ceramic tile and preparation method thereof |
| CN112592063A (en) * | 2020-12-25 | 2021-04-02 | 肇庆乐华陶瓷洁具有限公司 | High-wear-resistance marble-imitated ceramic tile and preparation method thereof |
| CN113173806A (en) * | 2021-05-07 | 2021-07-27 | 佛山市东鹏陶瓷有限公司 | Production process of superfine dry particle ceramic large plate and product thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113968728A (en) | 2022-01-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112592063B (en) | High-wear-resistance marble-imitated ceramic tile and preparation method thereof | |
| CN111943729B (en) | Manufacturing method of matte marble tile | |
| CN111943723B (en) | Ceramic glaze with silk texture, preparation method and ceramic rock plate using ceramic glaze | |
| CN107963814B (en) | Composite glaze, composite glaze slip and 4-8 degree soft surface wear-resistant porcelain archaized brick | |
| CN106986540B (en) | Formula for making sunken and peeled marble glaze | |
| CN113968728B (en) | High-hardness super-wear-resistant fully-polished marble tile and preparation method thereof | |
| CN109279918A (en) | A kind of sheen brick and preparation method thereof | |
| CN109279920A (en) | A kind of wear-resisting antiskid brick and preparation method thereof | |
| CN105198217B (en) | It is a kind of to be used for throwing vitreous brick production entirely, beneficial to the ground-coat enamel of ceramic ink color development | |
| CN110642521A (en) | High-wear-resistance antifouling microcrystal decorative ceramic thick plate and preparation method thereof | |
| CN115010465A (en) | Low-temperature fast-fired ceramic rock plate and preparation method thereof | |
| CN106007377A (en) | Super-flat glazed brick | |
| CN103467103A (en) | Production method of once-fired super-spar ceramic tile and ceramic tile | |
| CN106810206A (en) | A kind of utilization gangue prepares the super flat method for throwing glaze Ceramic Tiles | |
| CN111875415A (en) | Method for manufacturing soft glazed ceramic chip | |
| CN114454303A (en) | Ceramic rock plate with low-gloss, fine and frosted effect surface and preparation method thereof | |
| CN106007800B (en) | A kind of preparation method of background wall brick and the preparation method of wall | |
| CN108752057B (en) | Soft-surface wear-resistant easy-to-clean retro brick with surface glossiness of 4-8 degrees | |
| CN112608029B (en) | Dazzling archaized brick and preparation method thereof | |
| CN111116236A (en) | Wear-resistant environment-friendly brick and preparation method thereof | |
| CN113060936A (en) | Preparation method of multi-crystal glaze effect rock plate | |
| CN114920588A (en) | Soft-light wear-resistant anti-slip glazed tile and preparation method thereof | |
| CN105293912A (en) | Manufacturing method of glazed tile with matte surface | |
| EP4230600A1 (en) | Soft-light super-wear-resistant diamond glaze, ceramic tile and preparation method there of | |
| CN112062468A (en) | Texture glaze layer applied to surface of rock plate and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |