CN113754397A - Gypsum-based vitrified micro-bead insulation board for external wall internal insulation and processing method thereof - Google Patents

Gypsum-based vitrified micro-bead insulation board for external wall internal insulation and processing method thereof Download PDF

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Publication number
CN113754397A
CN113754397A CN202111063535.XA CN202111063535A CN113754397A CN 113754397 A CN113754397 A CN 113754397A CN 202111063535 A CN202111063535 A CN 202111063535A CN 113754397 A CN113754397 A CN 113754397A
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China
Prior art keywords
gypsum
insulation board
external wall
thermal insulation
insulation
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CN202111063535.XA
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Inventor
周之红
李功才
熊友东
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Guizhou Wisdom Quick Carving Environmental Protection Technology Co ltd
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Guizhou Wisdom Quick Carving Environmental Protection Technology Co ltd
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Priority to CN202111063535.XA priority Critical patent/CN113754397A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/22Glass ; Devitrified glass
    • C04B14/24Glass ; Devitrified glass porous, e.g. foamed glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/142Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
    • C04B28/144Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Building Environments (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention provides a gypsum-based vitrified microsphere insulation board for internal insulation of an external wall, which relates to the technical field of building materials, and comprises the following components in percentage by weight: 60-80% of building gypsum, 20-30% of vitrified micro bubbles, 3-5% of cement, 0.1-0.6% of water-retaining agent, 0.1-0.5% of foaming agent, 0.01-0.5% of retarder and 0-2% of functional additive. The processing method of the gypsum-based vitrified microsphere insulation board for internal insulation of the external wall is simple and convenient, can be prefabricated in advance, and can also transport uniformly mixed ingredients to a construction site for subsequent processing; the comprehensive cost is low; the heat-conducting coefficient is low, the heat-insulating effect is excellent, the material is an A-grade fireproof material, and the strength is good; the use is convenient; has excellent flatness, and is convenient for subsequent plastering or putty construction.

Description

Gypsum-based vitrified micro-bead insulation board for external wall internal insulation and processing method thereof
Technical Field
The invention relates to the technical field of building materials, in particular to a gypsum-based vitrified micro-bead insulation board for the internal insulation of an external wall and a processing method thereof.
Background
The building energy-saving wall system comprises an outer wall outer heat-insulating wall system, an outer wall inner heat-insulating wall system and a sandwich composite heat-insulating wall system; the three systems are different in the position of the heat-insulating layer in the wall body; if the heat-insulating layer is arranged on the outer side of the main body wall structure, the heat-insulating layer is called external wall external heat-insulating; if the heat insulation structure is arranged on the indoor side of the main wall, the heat insulation structure is called as outer wall inner heat insulation; if the heat insulation plate is arranged between two layers of dense structure walls on the same outer wall, the sandwich composite heat insulation is called. At present, the heat insulating materials can be divided into two types from the composition: thermal insulation mortar and thermal insulation boards; the material can be divided into organic and inorganic heat-insulating materials. The thermal conductivity coefficient of the thermal insulation mortar is relatively low, but the thermal insulation mortar must be stirred on a construction site; the construction period is long. The heat-insulating board can be prefabricated, cut and assembled on site; the construction efficiency is high.
The external wall external insulation has potential safety hazards of easy falling and flammability; in recent years, fire accidents and falling-off injury accidents of external wall external insulation are frequent, so that the internal insulation construction process of the external wall is emphasized and popularized and applied in various places. The traditional construction process of the polyphenyl particle thermal insulation mortar for the inner wall is complicated, the construction period is long, the leveling is difficult in the construction process, and the strength is poor. The polyphenyl particle thermal insulation mortar is an organic thermal insulation mortar material prepared by taking polyphenyl particles as a lightweight aggregate and polyphenyl particle thermal insulation rubber powder materials according to a certain proportion. The material can be applied to construction by adding water and stirring into slurry on a construction site, and can be used for internal and external heat preservation of building external walls. The polystyrene particles are all called expanded polystyrene foam particles; due to the material of the material, the material belongs to a flammable thermal insulation material, and the flame retardant grade can only reach B2 grade; the flame-retardant and fire-retardant properties are relatively poor. The vitrified microsphere insulation board is a board compressed by vitrified microsphere raw materials, and has the characteristics of very stable physical and chemical properties, strong aging resistance and weather resistance, excellent heat insulation, fire prevention and sound absorption because the surface is vitrified to form certain particle strength.
The vitrified micro bubble insulation board in the prior art still has a complex processing mode; the processing technology period is long; the strength is insufficient; poor fire-proof performance.
Disclosure of Invention
The invention aims to provide a gypsum-based vitrified microsphere insulation board for insulation in an outer wall and a processing method thereof, so as to solve the technical problems.
In order to achieve the purpose, the gypsum-based vitrified micro bubble insulation board for the internal insulation of the external wall comprises the following components in percentage by weight:
60-80% of building gypsum, 20-30% of vitrified micro bubbles, 3-5% of cement, 0.1-0.6% of water-retaining agent, 0.1-0.5% of foaming agent, 0.01-0.5% of retarder and 0-2% of functional additive.
Furthermore, the building gypsum is prepared by drying and calcining natural gypsum or flue gas desulfurization gypsum with the purity of more than 85 percent, the initial setting time of the building gypsum is not less than 3min, and the flexural strength of the building gypsum after 2h is not less than 2.0 MPa.
Furthermore, the particle size distribution of the vitrified micro bubbles is 0.2 mm-2.25 mm, and the bulk density is 50 g/L-150 g/L.
Further, the cement is portland cement, and preferably, the portland cement is any one of 32.5 portland cement, 42.5 portland cement, or 52.5 portland cement, or a combination thereof.
Further, the viscosity range of the water retention agent is 20000 mPas-150000 mPas; preferably, the water-retaining agent is hydroxyethyl methylcellulose (HEMC) or hydroxypropyl methylcellulose (HPMC).
Further, the foaming agent is a powder foaming agent or a liquid foaming agent; preferably, the foaming agent is one or a combination of lauryl sodium sulfate (K12) and fatty alcohol-polyoxyethylene ether sodium sulfate (AES) anionic surfactant.
Further, the retarder is any one or combination of a gluconate retarder and a soluble salt gypsum retarder thereof, a phosphate gypsum retarder and a protein gypsum retarder.
Still further, the functional additives include, but are not limited to, redispersible latex powders, air entraining agents, starch ethers, wetting and dispersing agents, thixotropic lubricants, glass fibers, polypropylene fibers, lignocelluloses, polyvinyl alcohol.
A method for processing a gypsum-based vitrified micro bubble insulation board for internal insulation of an external wall comprises the following steps of:
60-80% of building gypsum, 20-30% of vitrified micro bubbles, 3-5% of cement, 0.1-0.6% of water-retaining agent, 0.1-0.5% of foaming agent, 0.01-0.5% of retarder and 0-2% of functional additive.
The processing method comprises the following steps:
step 1: uniformly mixing the solid components in the components according to the weight percentage to obtain mixed powder;
step 2: respectively adding the liquid components in the components into 50-75% of water according to the weight percentage, stirring uniformly, slowly adding into the mixed powder, and mixing uniformly to prepare mortar material; if all the components are solid, slowly adding 50-75% of water into the mixed powder, and uniformly mixing to prepare mortar material;
and step 3: pouring the mortar material into a mould, and leveling; forming a heat insulation board after the mortar material is hardened; and taking out the insulation board to naturally dry or dry.
The gypsum-based vitrified microsphere insulation board for heat insulation in the outer wall can be prefabricated before construction or can be processed on site in a construction site. Because of the constraints imposed by the conditions and equipment at the construction site; more suitably, when all components of the vitrified microsphere insulation board are solid, the mixed powder uniformly mixed in the step 1 is packaged and bagged and then transported to a construction site, and the subsequent steps 2 and 3 are carried out on the construction site.
Advantageous effects
1) The method for processing the gypsum-based vitrified micro bubble insulation board for internal insulation of the external wall is simple and convenient, can be prefabricated in advance, and can also be used for transporting the uniformly mixed powder to a construction site for subsequent processing; the comprehensive cost is low.
2) The gypsum-based vitrified micro bubble heat insulation board for heat insulation in the outer wall has low heat conductivity coefficient and excellent heat insulation effect, is an A-grade fireproof material and has better strength.
3) The gypsum-based vitrified micro-bead heat insulation board for heat insulation in the outer wall is convenient to use; has excellent flatness, and is convenient for subsequent plastering or putty construction.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention clearer, the technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention. Unless defined otherwise, technical or scientific terms used herein shall have the ordinary meaning as understood by one of ordinary skill in the art to which this invention belongs. As used herein, the word "comprising" and similar words are intended to mean that the element or item listed before the word covers the element or item listed after the word and its equivalents, but does not exclude other elements or items.
Aiming at the problems in the prior art, the embodiment of the invention provides a gypsum-based vitrified micro bubble insulation board for the internal insulation of an external wall and a processing method thereof.
The performance requirements of some of the materials used in examples 1-3 are:
building gypsum: the gypsum is prepared by drying and calcining natural gypsum or flue gas desulfurization gypsum with the purity of more than 85 percent, the initial setting time is not less than 3min, and the flexural strength is not less than 2.0MPa after 2 h.
Vitrification of the micro-beads: the particle size distribution is 0.2 mm-2.25 mm, and the bulk density is 50 g/L-150 g/L.
Hydroxyethyl methylcellulose (HEMC) or hydroxypropyl methylcellulose (HPMC): the viscosity range is 20000 mPas-150000 mPas;
example 1
A gypsum-based vitrified micro-bead insulation board for heat insulation in an external wall comprises the following components in percentage by weight: 74.45 percent of building gypsum, 20 percent of vitrified micro bubbles, 5 percent of PO 42.5 cement, 0.2 percent of hydroxypropyl methyl cellulose HPMC, 0.25 percent of sodium dodecyl sulfate powder foaming agent (K12) and 0.1 percent of phosphate gypsum retarder.
The gypsum-based vitrified micro bubble heat insulation board for heat insulation in the external wall with the composition ratio is processed by adopting the following method, and the method comprises the following steps:
step 1: uniformly mixing the components according to the weight percentage to obtain mixed powder;
step 2: slowly adding 65% of water into the mixed powder, and uniformly mixing to prepare mortar material;
and step 3: pouring the mortar material into a mould of 900mm by 600mm by 40mm, and leveling; forming a heat insulation board after the mortar material is hardened; and taking out the insulation board and naturally drying.
The gypsum-based vitrified microsphere insulation board for insulation in the outer wall of the embodiment is solid in all components, and the mixed powder uniformly mixed in the step 1 can be transported to a construction site for subsequent processing.
Example 2
A gypsum-based vitrified micro-bead insulation board for heat insulation in an external wall comprises the following components in percentage by weight: 67.29 percent of building gypsum, 25 percent of vitrified micro bubbles, 5 percent of PO 42.5 cement, 0.2 percent of hydroxypropyl methyl cellulose HPMC, 0.5 percent of fatty alcohol-polyoxyethylene ether sodium sulfate (AES) liquid foaming agent, 0.01 percent of retarder PLAST RETARD-PE, and 2 percent of redispersible emulsion powder.
The redispersible latex powder is German Wake redispersible latex powder 5044N (
Figure BDA0003257500640000051
RE5044N)。
Retarder PLAST RETARD-PE is a gypsum retarder developed and produced by SISISIIT 2000, Western Italy.
The gypsum-based vitrified micro bubble heat insulation board for heat insulation in the external wall with the composition ratio is processed by adopting the following method, and the method comprises the following steps:
step 1: uniformly mixing the powder materials in the components according to the weight percentage to obtain mixed powder; the building gypsum, the vitrified micro bubbles, the PO 42.5 cement, the hydroxypropyl methyl cellulose HPMC, the retarder PLAST RETARD-PE and the redispersible emulsion powder are all powder materials.
Step 2: adding a fatty alcohol-polyoxyethylene ether sodium sulfate (AES) liquid foaming agent into 60% of water according to the weight percentage, stirring uniformly, slowly adding into the mixed powder, and mixing uniformly to prepare mortar material;
and step 3: pouring the mortar material into a mold of 1000mm by 50mm, and leveling; forming a heat insulation board after the mortar material is hardened; and taking out the insulation board and naturally drying.
The composition of the gypsum-based vitrified microsphere insulation board for internal insulation of an external wall of the embodiment contains a fatty alcohol-polyoxyethylene ether sodium sulfate (AES) liquid foaming agent, other components are powder materials, and the fatty alcohol-polyoxyethylene ether sodium sulfate (AES) liquid foaming agent is not suitable for being mixed with the powder materials and then transported, so that the vitrified microsphere insulation board of the embodiment is more suitable for being transported to a construction site after being prefabricated in a factory for use.
Example 3
A gypsum-based vitrified micro-bead insulation board for heat insulation in an external wall comprises the following components in percentage by weight: 65.88% of building gypsum, 30% of vitrified micro bubbles, 3% of PO 52.5 cement, 0.3% of hydroxyethyl methyl cellulose (HEMC), 0.3% of sodium dodecyl sulfate powder foaming agent (K12), 0.02% of retarder PLAST RETARD-PE and 0.5% of lignocellulose.
Retarder PLAST RETARD-PE is a gypsum retarder developed and produced by SISISIIT 2000, Western Italy.
The gypsum-based vitrified micro bubble heat insulation board for heat insulation in the external wall with the composition ratio is processed by adopting the following method, and the method comprises the following steps:
step 1: uniformly mixing the components according to the weight percentage to obtain mixed powder;
step 2: slowly adding 68% of water into the mixed powder, and uniformly mixing to prepare mortar material;
and step 3: pouring the mortar material into a die with the thickness of 1200mm by 50mm, and leveling; forming a heat insulation board after the mortar material is hardened; and taking out the insulation board and naturally drying.
The gypsum-based vitrified microsphere insulation board for insulation in the outer wall of the embodiment is solid in all components, and the mixed powder uniformly mixed in the step 1 can be transported to a construction site for subsequent processing.
Although the embodiments of the present invention have been described in detail hereinabove, it is apparent to those skilled in the art that various modifications and variations can be made to these embodiments. However, it is to be understood that such modifications and variations are within the scope and spirit of the present invention as set forth in the following claims. Moreover, the invention as described herein is capable of other embodiments and of being practiced or of being carried out in various ways.

Claims (10)

1. The utility model provides a heat preservation uses gypsum base vitrification bead heated board in outer wall which characterized in that, heat preservation includes according to weight percent in the outer wall with gypsum base vitrification bead heated board:
60-80% of building gypsum, 20-30% of vitrified micro bubbles, 3-5% of cement, 0.1-0.6% of water-retaining agent, 0.1-0.5% of foaming agent, 0.01-0.5% of retarder and 0-2% of functional additive.
2. The gypsum-based vitrified microsphere thermal insulation board for thermal insulation in the outer wall according to claim 1, wherein the building gypsum is prepared by drying and calcining natural gypsum or flue gas desulfurization gypsum with the purity of more than 85 percent, the initial setting time of the building gypsum is not less than 3min, and the flexural strength of the building gypsum is not less than 2.0MPa after 2 h.
3. The gypsum-based vitrified microsphere insulation board for heat insulation in an external wall according to claim 1, wherein the vitrified microsphere has a particle size distribution of 0.2mm to 2.25mm and a bulk density of 50g/L to 150 g/L.
4. The gypsum-based vitrified microsphere thermal insulation board for thermal insulation in the outer wall according to claim 3, wherein the cement is Portland cement, and the Portland cement is any one or combination of 32.5 Portland cement, 42.5 Portland cement and 52.5 Portland cement.
5. The gypsum-based vitrified microsphere insulation board for heat insulation in an external wall according to claim 4, wherein the viscosity of the water retention agent is 20000mPa s-150000 mPa s.
6. The gypsum-based vitrified microsphere insulation board for heat insulation in the outer wall according to claim 5, wherein the water retention agent is hydroxyethyl methyl cellulose (HEMC) or hydroxypropyl methyl cellulose (HPMC).
7. The gypsum-based vitrified microsphere insulation board for heat insulation in the outer wall according to claim 6, wherein the foaming agent is a powder foaming agent or a liquid foaming agent; the foaming agent is one or a combination of lauryl sodium sulfate (K12) and fatty alcohol-polyoxyethylene ether sodium sulfate (AES) anionic surfactant.
8. The gypsum-based vitrified microsphere thermal insulation board for thermal insulation in the external wall according to claim 7, wherein the retarder is any one or combination of gluconic acid and soluble salt gypsum retarder thereof, phosphate gypsum retarder and protein gypsum retarder.
9. The gypsum-based vitrified microsphere thermal insulation board for thermal insulation in the external wall of claim 8, wherein the functional additives comprise but are not limited to re-dispersible latex powder, air entraining agent, starch ether, wetting dispersant, thixotropic lubricant, glass fiber, polypropylene fiber, lignocellulose and polyvinyl alcohol.
10. The method for processing the gypsum-based vitrified microsphere insulation board for internal thermal insulation of the external wall according to claim 1, wherein the gypsum-based vitrified microsphere insulation board for internal thermal insulation of the external wall processed by the method comprises the following components in percentage by weight:
60-80% of building gypsum, 20-30% of vitrified micro bubbles, 3-5% of cement, 0.1-0.6% of water-retaining agent, 0.1-0.5% of foaming agent, 0.01-0.5% of retarder and 0-2% of functional additive;
the processing method comprises the following steps:
step 1: uniformly mixing the solid components in the components according to the weight percentage to obtain mixed powder;
step 2: respectively adding the liquid components in the components into 50-75% of water according to the weight percentage, stirring uniformly, slowly adding into the mixed powder, and mixing uniformly to prepare mortar material; if all the components are solid, slowly adding 50-75% of water into the mixed powder, and uniformly mixing to prepare mortar material;
and step 3: pouring the mortar material into a mould, and leveling; forming a heat insulation board after the mortar material is hardened; and taking out the insulation board to naturally dry or dry.
CN202111063535.XA 2021-09-10 2021-09-10 Gypsum-based vitrified micro-bead insulation board for external wall internal insulation and processing method thereof Pending CN113754397A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114276113A (en) * 2022-01-25 2022-04-05 河北宏基舜达钢结构工程有限公司 Heat insulation board for prefabricated house and manufacturing method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107098667A (en) * 2017-06-28 2017-08-29 武汉菡美洛建筑材料有限公司 Gypsum base light energy conservation plate and preparation method thereof
CN109095867A (en) * 2018-10-30 2018-12-28 广东龙湖科技股份有限公司 A kind of water-resistant type gypsum filled pours material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107098667A (en) * 2017-06-28 2017-08-29 武汉菡美洛建筑材料有限公司 Gypsum base light energy conservation plate and preparation method thereof
CN109095867A (en) * 2018-10-30 2018-12-28 广东龙湖科技股份有限公司 A kind of water-resistant type gypsum filled pours material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114276113A (en) * 2022-01-25 2022-04-05 河北宏基舜达钢结构工程有限公司 Heat insulation board for prefabricated house and manufacturing method thereof

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Application publication date: 20211207