CN113716726A - Double-separation type sewage treatment equipment for treating p-hydroxybenzoic acid production sewage - Google Patents
Double-separation type sewage treatment equipment for treating p-hydroxybenzoic acid production sewage Download PDFInfo
- Publication number
- CN113716726A CN113716726A CN202111182958.3A CN202111182958A CN113716726A CN 113716726 A CN113716726 A CN 113716726A CN 202111182958 A CN202111182958 A CN 202111182958A CN 113716726 A CN113716726 A CN 113716726A
- Authority
- CN
- China
- Prior art keywords
- chamber
- cylinder
- sweeping
- conical
- plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000926 separation method Methods 0.000 title claims abstract description 54
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000010865 sewage Substances 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 30
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 title claims abstract description 18
- 238000001914 filtration Methods 0.000 claims abstract description 118
- 238000010408 sweeping Methods 0.000 claims abstract description 90
- 239000000463 material Substances 0.000 claims abstract description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 238000005192 partition Methods 0.000 claims abstract description 29
- 239000007788 liquid Substances 0.000 claims description 33
- 238000005406 washing Methods 0.000 claims description 21
- 230000002000 scavenging effect Effects 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 4
- 210000001503 joint Anatomy 0.000 claims description 2
- 230000009977 dual effect Effects 0.000 claims 2
- 239000012452 mother liquor Substances 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 9
- 230000008901 benefit Effects 0.000 abstract description 5
- 239000002699 waste material Substances 0.000 abstract description 2
- 238000007796 conventional method Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 description 21
- 239000002351 wastewater Substances 0.000 description 20
- 229920003210 poly(4-hydroxy benzoic acid) Polymers 0.000 description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 230000009471 action Effects 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 230000008569 process Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000006473 carboxylation reaction Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- 238000004065 wastewater treatment Methods 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- ZGJADVGJIVEEGF-UHFFFAOYSA-M potassium;phenoxide Chemical compound [K+].[O-]C1=CC=CC=C1 ZGJADVGJIVEEGF-UHFFFAOYSA-M 0.000 description 3
- 239000002910 solid waste Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PTLKXMHIRDLHIM-UHFFFAOYSA-N 4-(pyridin-2-yldisulfanyl)butanimidamide Chemical compound NC(=N)CCCSSC1=CC=CC=N1 PTLKXMHIRDLHIM-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229960004889 salicylic acid Drugs 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 238000007065 Kolbe-Schmitt synthesis reaction Methods 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003031 feeding effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- NESLWCLHZZISNB-UHFFFAOYSA-M sodium phenolate Chemical compound [Na+].[O-]C1=CC=CC=C1 NESLWCLHZZISNB-UHFFFAOYSA-M 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/38—Treatment of water, waste water, or sewage by centrifugal separation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
- C02F2101/345—Phenols
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/02—Temperature
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/03—Pressure
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Centrifugal Separators (AREA)
Abstract
The invention discloses a double-separation type sewage treatment device for treating p-hydroxybenzoic acid production sewage, which comprises a circulation separation device, wherein the circulation separation device comprises a circulation separation cavity, a conical material sweeping cylinder and a centrifugal cylinder butted at the lower end of the conical material sweeping cylinder are arranged in the circulation separation cavity, the centrifugal cylinder and the conical material sweeping cylinder divide the circulation separation cavity into an inner cavity and an outer cavity, and the outer cavity is sequentially provided with a coarse filtration clapboard, a fine filtration clapboard and a partition board from top to bottom to isolate a primary filtration chamber, a fine filtration chamber, a water passing chamber and a concentrated solution chamber; the feed cylinder is swept to toper is equipped with the water hole of crossing of intercommunication inner chamber and crossing the hydroecium, and the partition panel is located the top of centrifuge drum, and the upper end of feed cylinder is swept to the toper is passed through the upper shaft head and is rotated with the circulation separation chamber and link together, and the lower extreme passes through the lower shaft head and rotates with the circulation separation chamber and link together, and the upper shaft head links together with the rotatory motor of drive toper feed cylinder. The method has the advantage of pretreating the mother liquor, and solves the problems of low treatment efficiency and resource waste of the conventional method.
Description
Technical Field
The application relates to the technical field of phenolic wastewater treatment equipment, in particular to double-separation type sewage treatment equipment for treating p-hydroxybenzoic acid production sewage.
Background
P-hydroxybenzoic acid, PHBA, is an important organic synthetic material, and due to its unique hydroxyl and carboxyl functional groups, it is one of the most widely used materials in organic chemical raw materials, and is widely used in the fields of medicine, pesticide, food, electronic communication, polymer material industry, etc. In recent years, PHBA is in great demand in domestic and foreign markets. Compared with foreign technologies, the PHBA production process in China is relatively laggard, the operation is complex, the yield is low, the energy consumption is high, and the wastewater production capacity is high. In addition, with the continuous development of society, the demand of related downstream industries on high-purity, low-chroma and high-stability PHBA is increasing. In order to solve the problem of neck clamping in the field of liquid crystal high-molecular materials in China, breakthrough is realized in the direction of high-end electronic chemicals, and the development of a PHBA high-efficiency green synthesis technology becomes an important research content of the PHBA industry in China under the large background of innovation and upgrade and green transformation of the manufacturing industry.
Currently, the PHBA production processes widely adopted in domestic and foreign industries mainly comprise the following three processes:
1. salicylic acid is used as a raw material, is converted into potassium salt by potassium hydroxide, is converted at high temperature in the presence of potassium carbonate, and is acidified to prepare PHBA. Although the process is mature, the salicylic acid is synthesized by carboxylation and then converted into PHBA. The indirect synthesis production method has the advantages of longer production process flow, low yield and high cost.
2. Potassium phenolate or sodium phenolate is used as a raw material, and is subjected to carboxylation reaction with carbon monoxide under the action of formate and under the pressure of 5.88 MPa and at high temperature, so that the PHBA with high yield is obtained. Although the yield of this route is high, the required pressure is high, and therefore the equipment requirements are extremely high. In addition, the process requires continuous production of carbon monoxide gas for carboxylation reaction, and thus the production has a high difficulty.
3. The Kolbe-Schmitt synthesis method is utilized, firstly, phenol and potassium hydroxide are prepared into potassium phenoxide, then the potassium phenoxide is used as a raw material to perform a carboxylation reaction with carbon dioxide in a certain medium under the pressure of 0.49-0.88MPa and the high temperature of 150 ℃ plus 270 ℃, and then the crude product PHBA is obtained by hydrochloric acid precipitation, filtration and drying. The production method has lower reaction pressure, and the used carbon dioxide, potassium hydroxide and phenol have rich sources, thereby being easy to realize industrialization. However, the process is operated intermittently, and the yield is low. In addition, a large amount of waste gas, waste water and solid waste are generated in the process reaction and intermediate treatment process, particularly the generated phenol-containing waste water is difficult to treat, is not beneficial to environmental protection, and simultaneously influences the economic benefit to a certain extent.
The existing method for treating PHBA production sewage is to convey mother liquor (containing recyclable solid substances) and washing water to corresponding sewage treatment equipment together for treatment, so that the wastewater treatment efficiency is low and resources are wasted.
Disclosure of Invention
The invention provides double-separation type sewage treatment equipment for treating p-hydroxybenzoic acid production sewage, which is used for pretreating mother liquor and solves the problems of low treatment efficiency and resource waste in the conventional mode.
The technical problem is solved by the following technical scheme: a double-separation type sewage treatment device for treating p-hydroxybenzoic acid production sewage is characterized by comprising a mother liquid pool and a washing water pool, wherein a circulation separation device is arranged between the mother liquid pool and the washing water pool, the circulation separation device comprises a circulation separation cavity, a conical material sweeping cylinder with a closed upper end and an open lower end is arranged in the circulation separation cavity, the upper end of the conical material sweeping cylinder is small, the lower end of the conical material sweeping cylinder is large, the lower end of the conical material sweeping cylinder is in butt joint with a centrifugal cylinder with an open upper end and a closed lower end, the circulation separation cavity is divided into an inner cavity and an outer cavity by the centrifugal cylinder and the conical material sweeping cylinder, the outer cavity is sequentially provided with a rough filtering partition plate, a fine filtering partition plate and a partition plate from top to bottom, the rough filtering chamber, the fine filtering chamber, a water filtering chamber and a concentrated liquid chamber are sequentially distributed in the outer cavity from top to bottom, and the mother liquid pool is communicated with rough filtering chamber; the part of the conical sweeping cylinder corresponding to the water passing chamber is provided with a water passing hole communicated with the inner chamber, the inner chamber is communicated with a washing water tank, the partition board is positioned above the centrifugal cylinder, the upper end of the conical sweeping cylinder is rotationally connected with the circulating separation cavity through an upper shaft head, the lower end of the conical sweeping cylinder is rotationally connected with the circulating separation cavity through a lower shaft head, and the upper shaft head is connected with a motor driving the conical sweeping cylinder to rotate.
According to the technical scheme, the mother liquor flows into the washing water tank after being subjected to solid-liquid separation, and then is conveyed away together for treatment, the mother liquor is pretreated, solid matters in the mother liquor can be separated out for recycling, resources are saved, the solid matter content in the subsequently-treated wastewater is low, and the discharging efficiency can be improved. After coarse and fine filtration, centrifugal separation is carried out under the action of a centrifugal cylinder, so that the solid content of the finally flowing water is low, the filtration and concentration of solid wastes with different diameters are realized, and the solid wastes are conveniently discharged from the solid discharge holes of the corresponding chambers in a targeted manner. The sewage passing through the circulating separation device can directly enter a washing water tank for sewage treatment, so that the sewage treatment efficiency is improved; can accomplish the separately processing of the solid residue of phenol-containing waste water and waste water in the PDBA production process through this application, cubic solid-liquid separation accomplishes the solid residue of different particle diameters respectively and clears away, compares traditional centrifuge, and the toper is swept the feed cylinder and is joined in marriage centrifuge bowl of this application and not only can play centrifugal separation's effect, still has the centrifugation many times of circulation to the filterable benefit of layering, the treatment effeciency of the phenol-containing waste water of improvement PHBA production that can be very big.
Preferably, a filter screen is arranged in the inner chamber, the inner chamber is separated into an upper chamber and a lower chamber by the filter screen, the water passing hole is located in the lower chamber, and the washing water tank is communicated with the upper chamber. The solid-liquid separation effect can be further improved, so that the content of solid matters output into the washing tank is small, the filter screen is arranged in an upper output mode, the filter screen at the upper end is not easy to block, and the solid matters after filtering can be centrifuged to the concentrated solution chamber by the centrifugal cylinder.
Preferably, an inner spindle head coaxial with the conical sweeping cylinder is arranged in the lower inner chamber, the lower end of the inner spindle head is connected with the bottom wall of the centrifugal cylinder, the upper end of the inner spindle head penetrates through the filter screen and then extends into the upper chamber, a liquid flow output channel axially extending along the inner spindle head is arranged in the inner spindle head, a liquid inlet communicated with the liquid flow output channel is formed in the part of the inner spindle head located in the upper chamber, the lower end of the liquid flow output channel extends into the lower spindle head and penetrates through the lower end face of the lower spindle head to form a liquid outlet, and a washing water tank is communicated with the liquid outlet. Layout output can be performed conveniently.
Preferably, the conical material sweeping cylinder is provided with a first material sweeping plate matched with the upper side of the primary filter plate and a second material sweeping plate matched with the upper side of the fine filter partition plate, the coarse filtering partition plate is provided with a plurality of strip-shaped coarse filtering grooves which are distributed on the coarse filtering partition plate in a circumferential array with the conical material sweeping barrel as the center, the fine filter baffle is provided with a plurality of strip-shaped fine filter grooves, the fine filter grooves are distributed on the fine filter baffle in a circumferential array way by taking the conical material sweeping barrel as the center, the coarse filter grooves and the fine filter grooves are straight grooves, the extension direction of the coarse filter grooves is crossed with the radial direction of the primary filter baffle, the extension direction of the fine filter grooves is crossed with the radial direction of the fine filter baffle, the shape of first scanning board and second scanning board is the ring shape that extends along toper scanning feed cylinder circumference, is equipped with on the first scanning board and supplies the material to pass through and get into a plurality of first scanning board portion unloading groove of coarse filtration groove, is equipped with on the second scanning board and supplies the material to pass through and get into a plurality of second scanning board portion unloading groove of fine filtration groove. The arrangement of the first and second material sweeping plates can prevent the coarse filter tank and the fine filter tank from being blocked, and the reliability of the circulating separation device is improved; and the first and second sweeping plates are arranged so that the conical sweeping cylinder also has the function of pushing sewage to flow downwards, and the material driving function is formed when the first and second sweeping plates rotate around the supporting rotating shaft. The filtering capacity of first baffle and second baffle can be guaranteed to the even setting respectively of coarse filter tank and thin filter tank, and the slope setting of coarse filter tank and thin filter tank can improve stifled ability between them to because the slope setting of coarse filter tank and thin filter tank, first scanning board and second are swept the flitch and are difficult to take place to collide with when sliding on first baffle and second baffle, can improve first scanning board and second and sweep the material reliability of sweeping of flitch. The material cylinder is swept to the first sweep plate that the ring shape set up and second have higher rotational stability, sweep the flitch with the second and sweep the material cylinder along with the toper and rotate together when, two-layer intercommunication about the feed chute rotates when reaching the position relative with coarse filtration groove or thin filter cell to play centrifugal filterable effect, multiunit feed chute synergism guarantees the reliability of filter action.
Preferably, the feeding trough of the first scanning plate part is positioned at one end of the first scanning plate connected with the conical scanning barrel, and the feeding trough of the second scanning plate part is positioned at one end of the second scanning plate connected with the conical scanning barrel. When the feed cylinder rotates is swept along with the toper to first sweeping board and second, because the centrifugal action that the rotation produced, the great residue of size and quality is got rid of the outer end that first sweeping board and second swept the flitch, and the unloading trench is located the inner that first sweeping board and second swept the flitch, consequently can guarantee that the residue of relative thinness can filter the next floor, prevents that big volume's residue from blockking up unloading silo or coarse filter tank and fine filter tank, improves the filtering action.
Preferably, the first scanning plate is provided with a first scanning plate part sweeping baffle plate, and the first scanning plate part sweeping baffle plate is positioned on one side of the discharging chute along the circumferential direction of the conical sweeping cylinder; the second sweeping baffle is arranged on the second sweeping plate and located on one side of the lower trough along the circumferential direction of the conical sweeping cylinder. The feeding effect can be improved.
Preferably, a first scanning plate horizontally arranged on the upper side of the rough filtering partition plate is arranged on the conical material sweeping cylinder, a plurality of strip-shaped rough filtering grooves are arranged on the rough filtering partition plate, the rough filtering grooves are distributed on the rough filtering partition plate in a circumferential array by taking the conical material sweeping cylinder as a center, the rough filtering grooves are arc-shaped, the extending direction of the rough filtering grooves is crossed with the circumferential direction of the conical material sweeping cylinder, a plurality of strip-shaped first scanning plate part feeding grooves are arranged on the first scanning plate, the first scanning plate part feeding grooves are straight grooves extending along the radial direction of the conical material sweeping cylinder, and the first scanning plate part feeding grooves are distributed on the rough filtering partition plate in a circumferential array by taking the conical material sweeping cylinder as a center; the flitch is swept to the second that is equipped with on the toper on the feed cylinder and puts on the fine filter baffle upside, be equipped with the fine filter cell of a plurality of rectangular shapes on the coarse filter baffle, the fine filter cell uses the toper to sweep the circumference array distribution that the feed cylinder was the center on the coarse filter baffle, and the fine filter cell is the arc, and the extending direction of fine filter cell sweeps the circumference intersection of feed cylinder with the toper, and the second that is equipped with a plurality of rectangular shapes on the second sweeps the feed cylinder on the feed cylinder, and the straight flute of radial extension of feed cylinder is swept along the toper to the second, and the second is swept the circumference array distribution that the feed cylinder was the center on the fine filter baffle with the toper. According to the technical scheme, when the coarse filter tank and the feeding chute of the first scanning plate part are crossed, the coarse filter holes of the grooves at the overlapped parts are formed, so that the coarse filter holes are dynamically moved, the rotation of the first scanning plate can drive the shearing action of solids just positioned in the coarse filter holes, and the blockage of the coarse filter holes is not easily caused. The same is true of the placement of the fine filtration pores.
Preferably, the rear end of the first scanning plate part feeding groove along the rotation direction of the conical scanning barrel is provided with a first scanning plate part vertical pushing plate extending along the extension direction of the first scanning plate part feeding groove, and two ends of the first scanning plate part vertical pushing plate in the horizontal direction exceed two ends of the first scanning plate part feeding groove; the second is swept the flitch feed chute and is swept the rear end of feed chute rotation direction along the toper and be equipped with along the second and sweep the flitch vertical push pedal of flitch extending of flitch feed chute extending direction, and the second is swept the flitch and is erected the both ends of push pedal horizontal direction and surpass the both ends that the flitch feed chute was swept to the second. When the feeding groove device is used, the pressure of the upper end of the feeding groove, namely the feeding end, can be improved, and therefore materials at the upper end can pass through more smoothly.
Preferably, an upper return pipeline is arranged between the coarse filtration chamber and the fine filtration chamber, and two ends of the upper return pipeline are respectively connected to the upper end of the coarse filtration chamber and the upper end of the fine filtration chamber; and a lower backflow pipeline is arranged between the fine filtering chamber and the water passing chamber, and two ends of the lower backflow pipeline are respectively connected to the upper end of the fine filtering chamber and the upper end of the water passing chamber. The arrangement of the backflow pipeline can realize multiple times of circulating filtration of wastewater, the backflow pipeline is arranged at the upper ends of the coarse filter layer and the fine filter layer, solid impurities are less accumulated, and the reliability of the circulating filtration effect is ensured. The drive power of backward flow effect is for sweeping the feed cylinder centrifugal drive effect under and producing at the toper, need not to set up the power supply in addition, can put up the pressure differential of high coarse filtration baffle and fine filtration baffle business turn over side, and the upper end filters more high-efficiently.
Preferably, the lower ends of the primary filtering chamber, the fine filtering chamber and the water passing chamber are provided with sewage draining holes. The solid matter can be easily discharged.
The invention has the following beneficial effects: can accomplish the separately processing of the solid residue of containing phenol waste water and waste water in the PDBA production process, the coarse filtration, carefully strain and centrifugation, accomplish the solid residue of different particle diameters respectively and clear away, compare traditional centrifuge, the toper of this application is swept feed cylinder cooperation centrifugal vane and is not only can be played centrifugal separation's effect, still has the centrifugation many times of circulation to the filterable benefit of layering, the treatment effeciency of the containing phenol waste water of improvement PHBA production that can be very big.
Drawings
FIG. 1 is a schematic structural diagram of a first embodiment of the present invention;
FIG. 2 is a top view of the first scanner plate of FIG. 1;
FIG. 3 is a top plan view of the coarse filter screen of FIG. 1;
FIG. 4 is a schematic structural diagram of a second embodiment of the present invention;
fig. 5 is a top view schematic of the first scanner plate and the outfeed baffle.
In the figure: a mother liquor pool 1, a washing pool 2, a circulating separation cavity 3, a conical material sweeping cylinder 4, a centrifugal cylinder 5, a rough filtering clapboard 6, a fine filtering clapboard 7, a partition plate 8, a preliminary filtering chamber 9, a fine filtering chamber 10, a water passing chamber 11, a concentrated solution chamber 12, a discharge hole 13, a water passing hole 14, an upper shaft head 15, a lower shaft head 16, a motor 17, a filter screen 18 and an upper cavity 19, the device comprises a lower cavity 20, an inner shaft head 21, a liquid flow output channel 22, a liquid inlet 23, a liquid outlet 24, a first scanning plate 25, a second scanning plate 26, a rough filtering groove 27, a fine filtering groove 28, a first scanning plate part blanking groove 30, a second scanning plate part blanking groove 32, a first scanning plate part scanning baffle 33, a second scanning plate part scanning baffle 34, an upper return pipeline 35, a lower return pipeline 36, a first scanning plate part feeding groove 37, a second scanning plate part feeding groove 38, a first scanning plate part vertical push plate 39 and a second scanning plate part vertical push plate 40.
Detailed Description
The invention is further illustrated with reference to the figures and the specific embodiments.
First embodiment, referring to fig. 1 to 3, a double separation type sewage treatment apparatus for treating p-hydroxybenzoic acid production sewage comprises a mother liquor pool 1 and a washing pool 2, wherein a circulation separation device is arranged between the mother liquor pool and the washing pool. Circulation separator includes circulation separation chamber 3, be equipped with the toper that the lower extreme open-ended is sealed to the upper end in the circulation separation chamber and sweep feed cylinder 4, the toper is swept the little lower extreme in feed cylinder upper end and is big, the toper is swept feed cylinder lower extreme and is docked has upper end opening lower extreme confined centrifuge bowl 5, centrifuge bowl and toper are swept the feed cylinder and are divided into inner chamber and exocoel with circulation separation chamber, exocoel from the top down is equipped with coarse filtration baffle 6 in proper order, fine filtration baffle 7 and partition panel 8, coarse filtration baffle, fine filtration baffle and partition panel keep apart out the primary filter chamber 9 that distributes from the top down in proper order at the exocoel, fine filter chamber 10, water passing chamber 11 and dense fluid chamber 12. The lower ends of the primary filtering chamber, the fine filtering chamber, the water passing chamber and the concentrated solution chamber are all provided with discharge holes 13, and the mother solution water tank is communicated with the coarse filtering chamber and is provided with a valve control. The part of the conical scavenging cylinder corresponding to the water passing chamber is provided with a water passing hole 14 communicated with the inner chamber, and the inner chamber is communicated with the washing water tank and is provided with a control valve. The partition board is located above the centrifugal cylinder, the upper end of the conical material sweeping cylinder is rotationally connected with the circulating separation cavity through an upper shaft head 15, the lower end of the conical material sweeping cylinder is rotationally connected with the circulating separation cavity through a lower shaft head 16, and the upper shaft head is connected with a motor 17 for driving the conical material sweeping cylinder to rotate. A filter screen 18 is arranged in the inner chamber, the filter screen separates the inner chamber into an upper chamber 19 and a lower chamber 20, and a water passing hole is positioned in the lower chamber. The washing water tank is communicated with the upper cavity, and specifically: an inner shaft head 21 coaxial with the conical sweeping cylinder is arranged in the lower inner chamber, the lower end of the inner shaft head is connected with the bottom wall of the centrifugal cylinder, the upper end of the inner shaft head penetrates through the filter screen and then extends into the upper chamber, a liquid flow output channel 22 axially extending along the inner shaft head is arranged in the inner shaft head, a liquid inlet 23 communicated with the liquid flow output channel is arranged on the part of the inner shaft head positioned in the upper chamber, the lower end of the liquid flow output channel extends into the lower shaft head and penetrates through the lower end surface of the lower shaft head to form a liquid outlet 24, and the washing water tank is communicated with the liquid outlet. The conical material sweeping cylinder is provided with a first material sweeping plate 25 matched with the upper side of the primary filtering plate and a second material sweeping plate 26 matched with the upper side of the fine filtering plate, the coarse filtering tank is provided with a plurality of long-strip-shaped coarse filtering grooves 27, the coarse filtering grooves are distributed on the coarse filtering plate in a circumferential array mode by taking the conical material sweeping cylinder as a center, the fine filtering plate is provided with a plurality of long-strip-shaped fine filtering grooves 28, the fine filtering grooves are distributed on the fine filtering plate in a circumferential array mode by taking the conical material sweeping cylinder as a center, the coarse filtering grooves and the fine filtering grooves are straight grooves, the extending direction of the coarse filtering grooves is crossed with the radial direction of the primary filtering plate, the extending direction of the fine filtering grooves is crossed with the radial direction of the fine filtering plate, the shapes of the first material sweeping plate and the second material sweeping plate are circular rings extending along the circumferential direction of the conical material sweeping cylinder, the first material sweeping plate is provided with a plurality of first material sweeping grooves 30 for materials to pass through and enter the coarse filtering grooves, and the second material sweeping grooves 32 for materials to pass through and enter the fine filtering grooves are arranged on the second material sweeping plate. The feeding groove of the first scanning plate part is located at one end, connected with the conical scanning barrel, of the first scanning plate, and the feeding groove of the second scanning plate part is located at one end, connected with the conical scanning barrel, of the second scanning plate. A first scanning plate part sweeping baffle 33 is arranged on the first scanning plate and is positioned on one side of the discharging chute along the circumferential direction of the conical sweeping barrel; the second sweeping baffle 34 is arranged on the second sweeping plate and located on one side of the lower trough along the circumferential direction of the conical sweeping cylinder. An upper return pipeline 35 is arranged between the coarse filtration chamber and the fine filtration chamber, and two ends of the upper return pipeline are respectively connected with the upper end of the coarse filtration chamber and the upper end of the fine filtration chamber; a lower return pipeline 36 is arranged between the fine filtering chamber and the water passing chamber, and two ends of the lower return pipeline are respectively connected with the upper end of the fine filtering chamber and the upper end of the water passing chamber.
When the device is used, the waste water in the mother liquor pool 1 is conveyed to the interior of the circulating filter device from the rough filter chamber. It should be noted that, in the drawings of the specification, the groove widths of the coarse filter groove, the fine filter groove and the blanking groove, the thickness and the size of the first scanning plate, the second scanning plate and the cylindrical ring plate, etc. are shown by exaggerated drawing for convenience, and the actual size is far smaller than that in the drawings. After the wastewater enters the circulating separation device, the main flow path of the mother liquor wastewater is large-particle solid residues which are blocked in a coarse filtration layer by a coarse filtration clapboard, the small-size solid residues and the wastewater flow into a fine filtration chamber, the wastewater flows into a lower cavity from a water passing chamber after being filtered again, the solids enter a concentrated solution chamber under the action of a centrifugal cylinder, and the liquid enters an upper cavity through a filter screen, so that the wastewater which is finally positioned in the upper cavity and has less solid residues and no large-size solid residues flows into a washing water tank for treatment. Besides the main flow path, a circulation separation path actually exists, the circulation path comprises a centrifugal force generated by rotation of the conical sweeping cylinder, a first circulation path which is formed by matching an upper return pipeline and a lower return pipeline and is used for enabling waste water in the fine filtering chamber to flow back into the coarse filtering chamber, a second circulation path which is formed by matching the waste water in the water passing chamber and is used for enabling the waste water in the fine filtering chamber to flow back into the fine filtering chamber, and a third circulation path which is used for enabling solid residues thrown out to the concentrated solution chamber under the action of the centrifugal cylinder, the matching of the coarse filtering partition plate and the first sweeping plate and the matching of the fine filtering partition plate and the second sweeping plate can also play a role in grinding the broken slag, the size of the solid residues is reduced, the subsequent waste water treatment is facilitated, and the efficiency of the subsequent waste water treatment can be improved.
The second embodiment is different from the first embodiment in that:
referring to fig. 4 and 5, the first scanning plate is flatly arranged and attached to the upper side of the rough filtering partition plate, the rough filtering groove is arc-shaped, the extending direction of the rough filtering groove is crossed with the circumferential direction of the conical material sweeping barrel, a plurality of strip-shaped first scanning plate part feeding grooves 37 are arranged on the first scanning plate, the first scanning plate part feeding grooves are straight grooves extending along the radial direction of the conical material sweeping barrel, and the first scanning plate part feeding grooves are distributed on the rough filtering partition plate in a circumferential array with the conical material sweeping barrel as the center; the second is swept the flitch and is put the laminating in carefully straining the baffle upside, and thin filter cell is the arc, and the extending direction of thin filter cell is crossed with the circumference that the feed cylinder was swept to the toper, and the second is swept the flitch and is equipped with the second of a plurality of rectangular shapes and sweeps flitch feed chute 38, and the second is swept flitch feed chute and is swept the straight flute that the feed cylinder radially extended for following the toper, and the second is swept flitch feed chute and is swept the circumference array distribution that the feed cylinder was the center with the toper on the thin filter baffle. The rear end of the first scanning plate part feeding groove along the rotating direction of the conical scanning cylinder is provided with a first scanning plate part vertical push plate 39 extending along the extending direction of the first scanning plate part feeding groove, and two ends of the first scanning plate part vertical push plate in the horizontal direction exceed two ends of the first scanning plate part feeding groove; the second is swept the flitch feed chute and is swept the rear end of feed chute rotation direction along the toper and be equipped with along the second and sweep flitch portion vertical push pedal 40 that flitch portion feed chute extending direction was stretched, and the second is swept the flitch portion and is erected the both ends of push pedal horizontal direction and surpass the both ends that the flitch feed chute was swept to the second.
This technical scheme has realized that the filtration pore position can produce the shearing action in the filtration process at the dynamic change on the baffle is strained to thickness.
Claims (10)
1. A double-separation type sewage treatment device for treating p-hydroxybenzoic acid production sewage is characterized by comprising a mother liquid pool and a washing water pool, wherein a circulation separation device is arranged between the mother liquid pool and the washing water pool, the circulation separation device comprises a circulation separation cavity, a conical material sweeping cylinder with a closed upper end and an open lower end is arranged in the circulation separation cavity, the upper end of the conical material sweeping cylinder is small, the lower end of the conical material sweeping cylinder is large, the lower end of the conical material sweeping cylinder is in butt joint with a centrifugal cylinder with an open upper end and a closed lower end, the circulation separation cavity is divided into an inner cavity and an outer cavity by the centrifugal cylinder and the conical material sweeping cylinder, the outer cavity is sequentially provided with a rough filtering partition plate, a fine filtering partition plate and a partition plate from top to bottom, the rough filtering chamber, the fine filtering chamber, a water filtering chamber and a concentrated liquid chamber are sequentially distributed in the outer cavity from top to bottom, and the mother liquid pool is communicated with rough filtering chamber; the part of the conical sweeping cylinder corresponding to the water passing chamber is provided with a water passing hole communicated with the inner chamber, the inner chamber is communicated with a washing water tank, the partition board is positioned above the centrifugal cylinder, the upper end of the conical sweeping cylinder is rotationally connected with the circulating separation cavity through an upper shaft head, the lower end of the conical sweeping cylinder is rotationally connected with the circulating separation cavity through a lower shaft head, and the upper shaft head is connected with a motor driving the conical sweeping cylinder to rotate.
2. The dual-separation sewage treatment equipment for treating p-hydroxybenzoic acid production sewage according to claim 1, wherein a filter screen is arranged in the inner chamber, the filter screen separates the inner chamber into an upper chamber and a lower chamber, the water through hole is located in the lower chamber, and the washing water tank is communicated with the upper chamber.
3. The double-separation sewage treatment equipment for treating p-hydroxybenzoic acid production sewage according to claim 2, wherein an inner spindle head coaxial with the conical sweeping cylinder is arranged in the lower inner chamber, the lower end of the inner spindle head is connected with the bottom wall of the centrifugal cylinder, the upper end of the inner spindle head passes through the filter screen and then extends into the upper chamber, a liquid flow output channel axially extending along the inner spindle head is arranged in the inner spindle head, a liquid inlet communicated with the liquid flow output channel is arranged in the part of the inner spindle head positioned in the upper chamber, the lower end of the liquid flow output channel extends into the lower spindle head and penetrates through the lower end surface of the lower spindle head to form a liquid outlet, and a washing water tank is communicated with the liquid outlet.
4. The double separation type sewage treatment apparatus for treating p-hydroxybenzoic acid production sewage according to claim 1, wherein the conical hopper is provided with a first hopper fitted on the upper side of the primary filter plate and a second hopper fitted on the upper side of the fine filter plate, the primary filter plate is provided with a plurality of elongated coarse filter cells, the coarse filter cells are distributed on the coarse filter plate in a circumferential array centered on the conical hopper, the fine filter plate is provided with a plurality of elongated fine filter cells, the fine filter cells are distributed on the fine filter plate in a circumferential array centered on the conical hopper, the coarse filter cells and the fine filter cells are straight cells, the extending direction of the coarse filter cells intersects with the radial direction of the primary filter plate, the extending direction of the fine filter cells intersects with the radial direction of the fine filter plate, the first hopper and the second hopper are both in a circular ring shape extending in the circumferential direction of the conical hopper, the first hopper is provided with a plurality of first hopper portions for the material to pass through to enter the coarse filter cells, the second sweeping plate is provided with a plurality of discharging grooves at the second sweeping plate part for the materials to pass through and enter the fine filter tank.
5. The dual separation-type sewage treatment apparatus for treating p-hydroxybenzoic acid production sewage according to claim 4, wherein the first sweeping plate part chute is located at the end where the first sweeping plate is connected to the tapered sweeping cylinder, and the second sweeping plate part chute is located at the end where the second sweeping plate is connected to the tapered sweeping cylinder.
6. The double-separation sewage treatment equipment for treating p-hydroxybenzoic acid production sewage according to claim 4 or 5, wherein the first scanning plate is provided with a first scanning plate sweeping baffle, and the first scanning plate sweeping baffle is positioned on one side of the blanking tank along the circumferential direction of the tapered sweeping cylinder; the second sweeping baffle is arranged on the second sweeping plate and located on one side of the lower trough along the circumferential direction of the conical sweeping cylinder.
7. The dual separation type sewage treatment apparatus for treating p-hydroxybenzoic acid production sewage according to claim 1, wherein the conical scavenging barrel is provided with a first scanning plate disposed horizontally on the upper side of the coarse filtering partition plate, the coarse filtering partition plate is provided with a plurality of elongated coarse filtering troughs, the coarse filtering troughs are distributed on the coarse filtering partition plate in a circumferential array centered on the conical scavenging barrel, the coarse filtering troughs are arc-shaped, the extending direction of the coarse filtering troughs intersects with the circumferential direction of the conical scavenging barrel, the first scanning plate is provided with a plurality of elongated first scanning plate part feeding troughs, the first scanning plate part feeding troughs are straight troughs extending in the radial direction of the conical scavenging barrel, and the first scanning plate part feeding troughs are distributed on the coarse filtering partition plate in a circumferential array centered on the conical scavenging barrel; the flitch is swept to the second that is equipped with on the toper on the feed cylinder and puts on the fine filter baffle upside, be equipped with the fine filter cell of a plurality of rectangular shapes on the coarse filter baffle, the fine filter cell uses the toper to sweep the circumference array distribution that the feed cylinder was the center on the coarse filter baffle, and the fine filter cell is the arc, and the extending direction of fine filter cell sweeps the circumference intersection of feed cylinder with the toper, and the second that is equipped with a plurality of rectangular shapes on the second sweeps the feed cylinder on the feed cylinder, and the straight flute of radial extension of feed cylinder is swept along the toper to the second, and the second is swept the circumference array distribution that the feed cylinder was the center on the fine filter baffle with the toper.
8. The dual-separation sewage treatment equipment for treating p-hydroxybenzoic acid production sewage according to claim 7, wherein the rear end of the first scanning plate part feeding chute in the rotating direction of the tapered scanning barrel is provided with a first scanning plate part vertical pushing plate extending in the extending direction of the first scanning plate part feeding chute, and both ends of the first scanning plate part vertical pushing plate in the horizontal direction exceed both ends of the first scanning plate part feeding chute; the second is swept the flitch feed chute and is swept the rear end of feed chute rotation direction along the toper and be equipped with along the second and sweep the flitch vertical push pedal of flitch extending of flitch feed chute extending direction, and the second is swept the flitch and is erected the both ends of push pedal horizontal direction and surpass the both ends that the flitch feed chute was swept to the second.
9. The dual-separation sewage treatment equipment for treating p-hydroxybenzoic acid production sewage according to claim 1, wherein an upper return pipeline is arranged between the coarse filtration chamber and the fine filtration chamber, and two ends of the upper return pipeline are respectively connected to the upper end of the coarse filtration chamber and the upper end of the fine filtration chamber; and a lower backflow pipeline is arranged between the fine filtering chamber and the water passing chamber, and two ends of the lower backflow pipeline are respectively connected to the upper end of the fine filtering chamber and the upper end of the water passing chamber.
10. The double-separation sewage treatment equipment for treating p-hydroxybenzoic acid production sewage according to claim 1, wherein the lower ends of the primary filtering chamber, the fine filtering chamber and the water passing chamber are provided with discharge holes.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111182958.3A CN113716726A (en) | 2021-10-11 | 2021-10-11 | Double-separation type sewage treatment equipment for treating p-hydroxybenzoic acid production sewage |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111182958.3A CN113716726A (en) | 2021-10-11 | 2021-10-11 | Double-separation type sewage treatment equipment for treating p-hydroxybenzoic acid production sewage |
Publications (1)
Publication Number | Publication Date |
---|---|
CN113716726A true CN113716726A (en) | 2021-11-30 |
Family
ID=78685862
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111182958.3A Pending CN113716726A (en) | 2021-10-11 | 2021-10-11 | Double-separation type sewage treatment equipment for treating p-hydroxybenzoic acid production sewage |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113716726A (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003200181A (en) * | 2001-12-28 | 2003-07-15 | Daiden:Kk | Method for cleaning sewage, device for cleaning sewage used therefor and mixed foreign matter separator for cleaning tank |
CN208466405U (en) * | 2018-07-03 | 2019-02-05 | 湖北高森特钢制品股份有限公司 | It is a kind of for producing the screening plant of hot candied powder |
CN212383320U (en) * | 2020-02-28 | 2021-01-22 | 林金海 | Sewage treatment equipment with centrifugal device |
CN213590675U (en) * | 2020-10-08 | 2021-07-02 | 山西欧文科技有限公司 | Novel material crushing device |
CN214004243U (en) * | 2020-12-17 | 2021-08-20 | 海南飞海环保工程有限公司 | Multistage filtration formula sewage treatment device |
-
2021
- 2021-10-11 CN CN202111182958.3A patent/CN113716726A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003200181A (en) * | 2001-12-28 | 2003-07-15 | Daiden:Kk | Method for cleaning sewage, device for cleaning sewage used therefor and mixed foreign matter separator for cleaning tank |
CN208466405U (en) * | 2018-07-03 | 2019-02-05 | 湖北高森特钢制品股份有限公司 | It is a kind of for producing the screening plant of hot candied powder |
CN212383320U (en) * | 2020-02-28 | 2021-01-22 | 林金海 | Sewage treatment equipment with centrifugal device |
CN213590675U (en) * | 2020-10-08 | 2021-07-02 | 山西欧文科技有限公司 | Novel material crushing device |
CN214004243U (en) * | 2020-12-17 | 2021-08-20 | 海南飞海环保工程有限公司 | Multistage filtration formula sewage treatment device |
Non-Patent Citations (1)
Title |
---|
格鲁捷夫等: "《金属压力加工中的摩擦和润滑手册》", 航空工业出版社, pages: 484 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN215886994U (en) | Production system for anaerobic fermentation of vinasse and high-concentration wastewater | |
CN217220523U (en) | High-efficient variable pore filtering pond | |
CN109173422B (en) | Batch complete filtering process for pre-crystallization procedure API liquid medicine in medicine production | |
CN208898726U (en) | A kind of heavy duty detergent soil block sludge solid-liquid separator | |
CN216549853U (en) | Three-stage separation type p-hydroxybenzoic acid production sewage treatment mechanism | |
CN216549854U (en) | Circulation separator that sewage that separation p hydroxybenzoic acid production produced was used | |
CN113716726A (en) | Double-separation type sewage treatment equipment for treating p-hydroxybenzoic acid production sewage | |
CN216549855U (en) | Shearing filtration formula p hydroxybenzoic acid production sewage treatment plant | |
CN113716729A (en) | Method for treating sewage generated in preparation of p-hydroxybenzoic acid | |
CN216038936U (en) | Be applied to phenol-containing effluent disposal system of high-efficient production of p hydroxybenzoic acid | |
CN102397719B (en) | Elutriation and filter device used for waste cutting fluid containing two types of solid substances of different particle diameters | |
CN113716728A (en) | P hydroxybenzoic acid production sewage treatment system with dynamically arranged filter holes | |
CN113716727A (en) | Be applied to phenol-containing waste water treatment equipment of high-efficient production of p hydroxybenzoic acid | |
CN214639022U (en) | Anaerobic digestion treatment device for kitchen garbage | |
CN211199885U (en) | Pulping device for raw paper pulp of double-sided adhesive tape | |
CN210786304U (en) | Equipment for continuously crystallizing and centrifuging trimellitic acid to form anhydride | |
CN212731373U (en) | Separator suitable for gypsum slurry dehydration | |
CN210905178U (en) | Solvent reverse-rotation solid-liquid separation system in 4-bromopyrrole production | |
CN218553342U (en) | Utilize industry solid useless sludge dewatering device in coordination | |
CN213467033U (en) | Light calcium carbonate production is with subsiding device | |
CN219860601U (en) | Large granule calcined soda processing preparation facilities | |
CN219355526U (en) | Solid catalyst separator | |
CN218421432U (en) | Self-rotating impurity filtering mixing tank | |
CN221254387U (en) | Sludge solid-liquid separation device | |
CN216538831U (en) | Kitchen waste desanding, crushing and impurity removing integrated pretreatment equipment |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211130 |