CN113713603A - Multifunctional biodegradable deodorant and preparation method and application thereof - Google Patents
Multifunctional biodegradable deodorant and preparation method and application thereof Download PDFInfo
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- CN113713603A CN113713603A CN202110996806.0A CN202110996806A CN113713603A CN 113713603 A CN113713603 A CN 113713603A CN 202110996806 A CN202110996806 A CN 202110996806A CN 113713603 A CN113713603 A CN 113713603A
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- 238000002360 preparation method Methods 0.000 title description 8
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- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
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- 238000005809 transesterification reaction Methods 0.000 description 2
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- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- 229920001450 Alpha-Cyclodextrin Polymers 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
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- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
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- 229910021536 Zeolite Inorganic materials 0.000 description 1
- MQTPMDMFXZTBDK-UHFFFAOYSA-N [Na+].Cl[O-].OC(=O)C1=CC=CC=C1O Chemical compound [Na+].Cl[O-].OC(=O)C1=CC=CC=C1O MQTPMDMFXZTBDK-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
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- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 description 1
- 229940043377 alpha-cyclodextrin Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
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- 230000002542 deteriorative effect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229940079919 digestives enzyme preparation Drugs 0.000 description 1
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- 239000012895 dilution Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
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- KZRPHCQLJZXMJV-UHFFFAOYSA-N sodium 4-(pyridin-2-yldiazenyl)benzene-1,3-diol Chemical compound [Na+].OC1=CC(O)=CC=C1N=NC1=CC=CC=N1 KZRPHCQLJZXMJV-UHFFFAOYSA-N 0.000 description 1
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- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/84—Biological processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
- B01D53/10—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a multifunctional biodegradable deodorant, which comprises the following components in parts by weight: 5-20 parts of protease, 20-50 parts of cellulolytic enzyme, 8-25 parts of amylase, 1-10 parts of lipase, 1-5 parts of pectinolytic enzyme, 1-2.5 parts of lysozyme, 20-25 parts of plant ash and 8-10 parts of hydroxypropyl-beta cyclodextrin. Compared with the prior art, the multifunctional biodegradable deodorant disclosed by the invention can be suitable for various production or living scenes needing deodorization, such as kitchen and bathroom garbage deodorization, excrement deodorization, toilet paper deodorization and the like, and is high in deodorization speed and long in deodorization time.
Description
Technical Field
The invention relates to the technical field of deodorization, in particular to a multifunctional biodegradable deodorant, a preparation method and application thereof, which can be used for removing the odor of household garbage and the odor of various waste discharge matters.
Background
Kitchen and household garbage recycling stations are mostly built around living areas, and because organic matters in the kitchen and household garbage recycling stations are decomposed, odor pollution is inevitably generated, and the living environment of residents is influenced. In addition, in the processes of storing, loading and unloading the household garbage and the kitchen garbage, tiling, compacting and the like in a landfill, the external release of malodorous gas cannot be avoided, and the influence on the surrounding human environment can be avoided. The natural degradation only takes a long time.
At present, public toilets and mobile toilets can generate odor diffusion in the use process as an important component of living facilities. And the public toilet and the mobile toilet septic tank are decomposed and degraded by natural strains all the time, the processing capacity is weak, fiber matters such as toilet paper and the like float and block to block the pipeline after a long time, the odor returning phenomenon occurs, and the odor of the well mouth of each large-city sewage pipeline is diffused. The prior treatment method is to clean the septic tank by a person at regular intervals, but floating objects which are cleaned become odor solid wastes which are difficult to treat. Therefore, the air deodorization and septic tank cleaning in public toilets and mobile toilets become an important subject for research.
The current plant often has very big peculiar smell and foul smell, and its excrement and urine and other emissions are all in the same degradation pond of collecting, discharge again after coming out through natural degradation. However, the traditional method cannot avoid the generation of odor and has long degradation period. The daily discharge of the farm is large, the degradation pond is quickly filled, and large discharge matters are discharged outside without being subjected to degradation treatment. This has a great influence on the surrounding environment.
In view of the odor generated in various living or production scenes, deodorizers for removing the odor of household garbage or the odor of a breeding place have appeared on the market. At present, deodorizers mainly comprise plant deodorizers, chemical deodorizers and multifunctional microbial deodorizers in the market. The plant deodorant is prepared by extracting plant essential oil to cover odor, but the pollutants cannot be decomposed, and when the plant essential oil is completely volatilized, the odor is revealed to form secondary pollution. Moreover, the extraction process of the plant deodorant is complex, difficult to obtain, high in production cost and incapable of being used on a large scale. Besides high cost, the chemical deodorant has hidden danger in use safety, and new compounds can be generated after the chemical deodorant reacts with odor to form unknown secondary pollution.
The current mature microbial multifunctional deodorant in the market utilizes EM (effective microorganisms) strains to breed and generate a large amount of bacteria, and then utilizes various bacteria with different attributes to swallow and decompose odor and garbage. The product has strict requirements on the environment in the use process, certain temperature and humidity are required for strain propagation, and the strain propagation is influenced by overhigh or overlow temperature and humidity, so the use is inconvenient.
In the prior application CN112191655A of the present application, a multifunctional biodegradable deodorant is disclosed, which comprises the following components in parts by weight: 5-20 parts of protease, 20-50 parts of cellulolytic enzyme, 8-25 parts of amylase, 1-10 parts of lipase, 1-5 parts of pectinolytic enzyme, 1-2.5 parts of lysozyme, 1-15 parts of 4A zeolite, 1-10 parts of protein cotton, 0.1-0.5 part of sodium polyacrylate and 0.1-5 parts of sodium citrate. The multifunctional biodegradable deodorant can be suitable for various production or living scenes needing deodorization, such as kitchen and bathroom garbage deodorization, excrement deodorization, toilet paper deodorization and the like, and is high in deodorization speed.
However, the plant ash used in the above-mentioned biodegradable deodorant is not easily degraded, and the sodium polyacrylate and sodium citrate used are expensive. In addition, the long-term deodorizing ability of the above deodorant is yet to be further enhanced. The invention realizes the deodorizing ability with quick effect and also has long-term deodorizing ability by adjusting the formula of the deodorant, and the used components are all biodegradable, thereby being beneficial to the use in the actual production.
Disclosure of Invention
The present invention is directed to overcoming the above-mentioned drawbacks of the prior art and providing a multifunctional biodegradable deodorant which is applicable to various production or living scenes requiring deodorization, such as kitchen and bath garbage deodorization, feces deodorization, toilet paper deodorization, etc., and has a fast deodorization speed and a long deodorization time.
In order to achieve the purpose, the invention adopts the following technical scheme:
a multifunctional biodegradable deodorant comprises the following components in parts by weight:
5-20 parts of protease
20-50 parts of cellulolytic enzyme
8-25 parts of amylase
1-10 parts of lipase
1-5 parts of pectinolytic enzyme
1-2.5 parts of lysozyme
20-25 parts of plant ash
8-10 parts of hydroxypropyl-beta cyclodextrin.
A multifunctional biodegradable deodorant comprises the following components in parts by weight:
5-10 parts of protease
20-40 parts of cellulolytic enzyme
15-20 parts of amylase
8-10 parts of lipase
2.5-4.5 parts of pectinolytic enzyme
1-2 parts of lysozyme
20-25 parts of plant ash
8-10 parts of hydroxypropyl-beta cyclodextrin.
A multifunctional biodegradable deodorant comprises the following components in parts by weight:
protease 5 parts
40 parts of cellulolytic enzyme
15 portions of amylase
8 portions of lipase
4.5 parts of pectinolytic enzyme
1 part of lysozyme
22 parts of plant ash
And 9 parts of hydroxypropyl-beta cyclodextrin.
The invention also provides a preparation method of the multifunctional biodegradable deodorant, which comprises the following steps:
adding the components according to the formula ratio into a stirrer, stirring and mixing uniformly, and then packaging.
The invention also provides application of the multifunctional biodegradable deodorant, which is to contain the multifunctional biodegradable deodorant in water, and then put the multifunctional biodegradable deodorant into dirt to degrade the dirt and remove the odor of the dirt.
Further, the multifunctional biodegradable deodorant is dissolved in water according to the proportion of 10-50 g/L.
Further, the weight ratio of the multifunctional biodegradable deodorant to the dirt is 1: 20.
compared with the prior art, the invention has the beneficial effects that:
the invention uses the compounding of various enzyme preparations, uses plant ash and hydroxypropyl beta-cyclodextrin as enzyme carriers and peculiar smell adsorbents, uses the characteristics of the enzyme for catalysis, and uses the plant ash and the hydroxypropyl beta-cyclodextrin as the adsorbents, thereby accelerating the speed of chemical reaction and the biological decomposition speed, and being beneficial to the long-term function of the enzyme, and further achieving the functions of quickly deodorizing and decomposing pollutants for a long time. On the other hand, the components of the formula can be directly mixed for use, and the preparation method is simple and quick.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments obtained by a person skilled in the art without making any inventive step are within the scope of the present invention.
Example 1:
a multifunctional biodegradable deodorant comprises the following components in parts by weight:
protease 5 parts
40 parts of cellulolytic enzyme
15 portions of amylase
8 portions of lipase
4.5 parts of pectinolytic enzyme
1 part of lysozyme
22 parts of plant ash
And 9 parts of hydroxypropyl-beta cyclodextrin.
In the invention, plant ash and hydroxypropyl-beta cyclodextrin are used as odor adsorbent components, so that odor can be adsorbed and locked, the diffusion of odor is reduced, and then plant ash and hydroxypropyl-beta are utilized as carriers of enzyme, so that the long-term odor decomposition of the enzyme preparation is facilitated.
In the invention, the protease generated by fermenting bacillus subtilis JNB001 can change a macromolecular protein structure into a simple small molecular peptide chain or amino acid, so that protein dirt such as blood stain, sweat stain, milk stain and the like is easy to dissolve, and the protease has the functions of hydrolyzing ester bonds, amido bonds, transesterification and phthalein.
In the invention, the cellulolytic enzyme is a complex enzyme, and comprises C1 enzyme, CX enzyme and glucosidase enzyme, wherein the C1 enzyme and the CX enzyme decompose cellulose into cellobiose, the glucosidase decomposes the cellobiose into glucose, and the cellulose is finally hydrolyzed into the glucose under the synergistic action of the three enzymes, so that the cellulose loses the connection function, thereby promoting the dissolution of the cellulose. In the present invention, a cellulolytic enzyme acts on a stain containing cellulose such as a paper towel, a fruit peel, a vegetable leaf, leftovers, and the like.
Lipases are serine hydrolases which catalyze the hydrolysis of fatty acid glycerides to produce glycerol and fatty acids, the hydrolysis reaction being characterized by taking place at the oil-water interface. The enzyme may also catalyze ester synthesis and transesterification reactions. Lipase, triacylglycerol acyl hydrolase, which catalyzes the hydrolysis of natural substrate oil to produce fatty acid, glycerin and monoglyceride or diglyceride, and the hydrolyzed product forms the propagation condition of the strain. In the present invention, the lipase is a lipase produced by fermentation of Aspergillus niger. In the present invention, lipase mainly acts on fatty acid and ester dirt.
In the present invention, the amylase is produced by Bacillus subtilis fermentation, and can effectively hydrolyze a-1, 4 glucosidic bonds in starch, glycogen and degradation products thereof to produce dextrin and a small amount of oligosaccharide, so that the viscosity of a colloidal starch solution is rapidly reduced. The alpha-amylase (medium temperature) is a light yellow brown solid powder product, and the color of the alpha-amylase is slightly different due to the influence of factors such as fermentation raw materials, period and the like, but the using effect is not influenced. Amylases are mainly used for dough modification in bread production (reduction of dough viscosity, acceleration of the fermentation process, increase of sugar content, alleviation of bread aging); pretreatment (starch hydrolysis) of cereal raw materials in infant food; for saccharifying and decomposing undecomposed starch chemical book in beer production; liquefying and saccharifying starch in sake production; saccharification and breakdown of undecomposed starch in the alcohol industry; starch decomposition and increased filtration rate in juice processing; and processing vegetables, syrup, maltose, powdered dextrin, and glucose. In the invention, the amylase acts on paper towels, fruit peels, vegetable leaves, leftovers and other dirt to accelerate the decomposition of the dirt.
Lysozyme is obtained by adjusting the pH value of protein by adopting a bioengineering technology and adsorbing and separating by using ion exchange resin, has the molecular weight of 14307, is a glycoside hydrolase, can dissolve the cell wall of gram-positive bacteria, has strong killing effect on the gram-positive bacteria, can be used for preparing a crystallized protein lysozyme preparation to prevent food from deteriorating, and has wide application in food fresh keeping (particularly cheese and sake production), medicines (tablets, capsules, eyedrops and throat moistening liquid), daily chemicals (toothpaste and cosmetics), infant food (mother emulsified milk powder) and scientific research. The lysozyme has the inhibiting and killing effects on gram-positive bacteria, gram-negative bacteria and other bacteria, and the bacteriostatic effect is obvious. The lysozyme in the invention has the functions of dissolving and decomposing the existing strains in the dirt, inhibiting various strains generated in the fermentation and degradation process of the dirt and preventing the pollution of mixed bacteria.
The multifunctional biodegradable deodorant is prepared by adopting the following preparation method:
adding the components according to the formula ratio into a stirrer, stirring and mixing uniformly, and then packaging.
The multifunctional biodegradable deodorant is dissolved in water, and then is put into dirt to degrade the dirt and remove the odor of the dirt. Specifically, the multifunctional biodegradable deodorant is dispersed with water according to the proportion of 10-50 g/L. The weight ratio of the multifunctional biodegradable deodorant to the dirt is 1: 20.
example 2:
the same as example 1, except that 22 parts of plant ash and 8 parts of hydroxypropyl-beta cyclodextrin are used.
Comparative example 1:
the same as in example 1, except that no plant ash was added.
Comparative example 2:
the same as in example 1, except that the same weight of alpha cyclodextrin was used instead of hydroxypropyl-beta cyclodextrin.
Example 3: application experiment of biological deodorant
A plurality of sealed sheds with the same size are built in a certain pig farm, the length multiplied by the width multiplied by the height multiplied by 3m multiplied by 2m, fresh pig manure with the same mass is flatly paved at the same position in the sealed shed, 50ml of the biological deodorant of the embodiment 1-2 and the comparative example 1-2 is sprayed after the pig manure is sealed for 30 minutes, 50ml of water is sprayed as a blank component, the ammonia gas and the hydrogen sulfide value are measured by an instrument, the ammonia gas adopts a sodium hypochlorite-salicylic acid spectrophotometry (GB/T14679), the hydrogen sulfide adopts a polyvinyl alcohol ammonium phosphate absorption-methylene blue colorimetric method (GB/T16489), the human body can feel the stink degree, and the test result is shown in a table 1.
TABLE 1 variation of values of ammonia and hydrogen sulfide (in ppm) after treatment with biological deodorant
One ton of domestic garbage is divided into 5 parts, the parts are respectively placed in houses with the same area and space, 1kg of biological deodorant is respectively sprayed on the parts, the deodorization effect of the deodorant with the same volume and the same dilution is compared, the odor concentration adopts a three-point comparison type odor bag method (GB/T14675), and the results are shown in Table 2:
table 2: comparison of deodorization effects of different biological deodorants
Blank group | EXAMPLE 1 group | EXAMPLE 2 group | Comparative example 1 group | Comparative example 2 group | |
20 min odor removal (%) | 3.5 | 95.6 | 94.3 | 65.6 | 96.8 |
Maintaining the removal rate of more than 90 percent | - | 4.3h | 3.9h | - | 2.5h |
The above description is only for the purpose of illustrating the preferred embodiments of the present invention, and is not intended to limit the present invention to the particular embodiments disclosed, so that all equivalents and modifications that do not depart from the spirit of the present invention are deemed to fall within the scope of the present invention.
Claims (8)
1. A multifunctional biodegradable deodorant comprises the following components in parts by weight:
5-20 parts of protease
20-50 parts of cellulolytic enzyme
8-25 parts of amylase
1-10 parts of lipase
1-5 parts of pectinolytic enzyme
1-2.5 parts of lysozyme
20-25 parts of plant ash
8-10 parts of hydroxypropyl-beta cyclodextrin.
2. A multifunctional biodegradable deodorant comprises the following components in parts by weight:
5-10 parts of protease
20-40 parts of cellulolytic enzyme
15-20 parts of amylase
8-10 parts of lipase
2.5-4.5 parts of pectinolytic enzyme
1-2 parts of lysozyme
20-25 parts of plant ash
8-10 parts of hydroxypropyl-beta cyclodextrin.
3. A multifunctional biodegradable deodorant comprises the following components in parts by weight:
protease 5 parts
40 parts of cellulolytic enzyme
15 portions of amylase
8 portions of lipase
4.5 parts of pectinolytic enzyme
1 part of lysozyme
22 parts of plant ash
And 9 parts of hydroxypropyl-beta cyclodextrin.
4. A method for preparing the multifunctional biodegradable deodorant according to any one of claims 1 to 3, characterized by comprising the steps of:
adding the components according to the formula ratio into a stirrer, stirring and mixing uniformly, and then packaging.
5. Use of the multifunctional biodegradable deodorant according to any one of claims 1 to 3, characterized in that: dissolving the multifunctional biodegradable deodorant in water, and then adding the dissolved multifunctional biodegradable deodorant into dirt for deodorization, or directly adding the multifunctional biodegradable deodorant into the dirt for deodorization.
6. The use of claim 5, wherein: the multifunctional biodegradable deodorant is dissolved with water according to the proportion of 10-50 g/L.
7. The use of claim 5, wherein: the dirt is selected from pig manure or household garbage.
8. Use according to claim 7, wherein the deodorising rate is more than 90% for a time in the range of 0.2-3 hours after application of the deodorising agent.
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116407939A (en) * | 2023-04-14 | 2023-07-11 | 广东鹏炜精细化工有限公司 | Preparation method and application of natural plant composite biological enzyme deodorizing spray |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2579322Y (en) * | 2002-11-29 | 2003-10-15 | 中国人民解放军军事医学科学院卫生学环境医学研究所 | Combined water flushing-free biological toilet |
EP1568407A1 (en) * | 2004-02-24 | 2005-08-31 | Idrabel Italia S.r.l. | A system for controlling volatile organic compounds and ill-smelling substances emissions |
CN1970089A (en) * | 2006-12-04 | 2007-05-30 | 张涉 | Deodorant spray and its preparing method |
CN204158772U (en) * | 2014-09-04 | 2015-02-18 | 王菊 | Vegetation ashes sanitary towel |
KR101744023B1 (en) * | 2016-08-31 | 2017-06-07 | 주식회사 한국환경기술 | Wastewater treatment and odor removal microbial-enzymatic method using a complex microbial agent |
CN107496966A (en) * | 2017-07-19 | 2017-12-22 | 湖南沃邦环保科技有限公司 | A kind of special deodorant of livestock culture excrement and preparation method thereof |
CN107930337A (en) * | 2017-12-26 | 2018-04-20 | 安徽仁维环保工程科技有限公司 | A kind of method for removing livestock and poultry feces stink |
CN108325378A (en) * | 2018-04-25 | 2018-07-27 | 河南正达环保科技有限公司 | A kind of deodorizing microorganism filler and preparation method thereof |
CN108401420A (en) * | 2016-12-05 | 2018-08-14 | 郑汉洙 | The liquid phase deodorant compositions that odor prolongation is improved |
CN112107984A (en) * | 2020-09-04 | 2020-12-22 | 中国人民解放军海军特色医学中心 | Plant type sterilization deodorant and preparation method thereof |
CN112191655A (en) * | 2020-08-31 | 2021-01-08 | 广州市爱家有方日用品有限公司 | Multifunctional biodegradable deodorant and preparation method and application thereof |
CN112225598A (en) * | 2020-09-17 | 2021-01-15 | 桐庐吉诚农业开发有限公司 | Sheep manure organic fertilizer and preparation method thereof |
CN113209812A (en) * | 2021-05-10 | 2021-08-06 | 江苏雅博动物健康科技有限责任公司 | Biological deodorization particle for pet and preparation method thereof |
-
2021
- 2021-08-27 CN CN202110996806.0A patent/CN113713603A/en active Pending
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2579322Y (en) * | 2002-11-29 | 2003-10-15 | 中国人民解放军军事医学科学院卫生学环境医学研究所 | Combined water flushing-free biological toilet |
EP1568407A1 (en) * | 2004-02-24 | 2005-08-31 | Idrabel Italia S.r.l. | A system for controlling volatile organic compounds and ill-smelling substances emissions |
CN1970089A (en) * | 2006-12-04 | 2007-05-30 | 张涉 | Deodorant spray and its preparing method |
CN204158772U (en) * | 2014-09-04 | 2015-02-18 | 王菊 | Vegetation ashes sanitary towel |
KR101744023B1 (en) * | 2016-08-31 | 2017-06-07 | 주식회사 한국환경기술 | Wastewater treatment and odor removal microbial-enzymatic method using a complex microbial agent |
CN108401420A (en) * | 2016-12-05 | 2018-08-14 | 郑汉洙 | The liquid phase deodorant compositions that odor prolongation is improved |
CN107496966A (en) * | 2017-07-19 | 2017-12-22 | 湖南沃邦环保科技有限公司 | A kind of special deodorant of livestock culture excrement and preparation method thereof |
CN107930337A (en) * | 2017-12-26 | 2018-04-20 | 安徽仁维环保工程科技有限公司 | A kind of method for removing livestock and poultry feces stink |
CN108325378A (en) * | 2018-04-25 | 2018-07-27 | 河南正达环保科技有限公司 | A kind of deodorizing microorganism filler and preparation method thereof |
CN112191655A (en) * | 2020-08-31 | 2021-01-08 | 广州市爱家有方日用品有限公司 | Multifunctional biodegradable deodorant and preparation method and application thereof |
CN112107984A (en) * | 2020-09-04 | 2020-12-22 | 中国人民解放军海军特色医学中心 | Plant type sterilization deodorant and preparation method thereof |
CN112225598A (en) * | 2020-09-17 | 2021-01-15 | 桐庐吉诚农业开发有限公司 | Sheep manure organic fertilizer and preparation method thereof |
CN113209812A (en) * | 2021-05-10 | 2021-08-06 | 江苏雅博动物健康科技有限责任公司 | Biological deodorization particle for pet and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116407939A (en) * | 2023-04-14 | 2023-07-11 | 广东鹏炜精细化工有限公司 | Preparation method and application of natural plant composite biological enzyme deodorizing spray |
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