CN1136496A - Fine hair product and fine hair composite - Google Patents
Fine hair product and fine hair composite Download PDFInfo
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- CN1136496A CN1136496A CN96100450A CN96100450A CN1136496A CN 1136496 A CN1136496 A CN 1136496A CN 96100450 A CN96100450 A CN 96100450A CN 96100450 A CN96100450 A CN 96100450A CN 1136496 A CN1136496 A CN 1136496A
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- fine hair
- fiber
- dyeing
- collapsible
- composite
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H11/00—Non-woven pile fabrics
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/02—Pile fabrics or articles having similar surface features
- D04B1/025—Pile fabrics or articles having similar surface features incorporating loose fibres, e.g. high-pile fabrics or artificial fur
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2403/00—Details of fabric structure established in the fabric forming process
- D10B2403/01—Surface features
- D10B2403/011—Dissimilar front and back faces
- D10B2403/0112—One smooth surface, e.g. laminated or coated
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
- D10B2501/044—Fur garments; Garments of fur substitutes
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Knitting Of Fabric (AREA)
- Woven Fabrics (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Artificial Filaments (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Abstract
To obtain a natural fur-type pile product having characteristics further close to a natural fur, i.e., having a soft touch feeling such as that of the natural fur, a coloring effect by a double layered structure and a raised nap structure closely resemble to the natural fur, and excellent in blooming properties. This pile product comprises the pile part which is constituted by 20-98wt.% shrinking yarn of solution dyed acryl based synthetic fibers having 1-10 de, >=15% shrinking ratio and <=0.230 static friction coefficient between the fibers, and non-shrinking fibers having 3-40 de and flat cross sections or oval cross sections, and has a 2-70mm difference in pile length between the shrinking fibers and non shrinking fibers.
Description
The present invention relates to a kind of fine hair composite, the fine hair product of the atural fur color and luster that it provided have atural fur intrinsic soft feel, with by the color and luster effect that double-decker brought that is similar to atural fur, and have excellent velvet (blooming) property because of the napping structure that is similar to atural fur.
Atural fur is made up of the double-decker of outer layer protection hair part and fine hair part, has excellent characteristic in feel, outward appearance and function aspects, is mainly used in clothes.With the fur is example, its fur by account for fine hair about 70%-80%, thin and short and account for about 20-30%, thick and outer layer protection hair that grow is formed, fine hair is being supported the outer layer protection hair, thereby demonstrates the napping state and bring velvet.In addition, the double-decker of this fine hair and outer layer protection hair provides color and luster effect and soft feel.
In order to improve furry goods, make their above-mentioned characteristics near atural fur, people are doing deep research aspect the braiding of villus material and fine hair and the textile technology.
For example, one of these methods are when making fur with the fine hair manufacturer that becomes mildewed, can not make fine hair product with thick long collapsible mixed with fibers by high shrinkage with what carefully lack, thereby make it show the double-decker of napping state and atural fur.But in the method, because thin weak point can not possess basicly stable villus length by high shrinkage, so can not get being similar to the double-decker of atural fur and the color and luster effect brought of structure thus.
In addition, the method of known a kind of manufacturing money look (mint-tone) Fake Furs, comprise that by mixing thin staple fibre and thick long fiber obtains thin down and thick villose double-decker braiding and weaving making herbs into wool hair carry out shrink process with the fine hair of gained and make contractile filament contraction.But, collapsible fiber generally shrinks in staining procedure, and therefore, collapsible fiber no longer possesses shrinkage after dyeing, can not after fine hair braiding and weaving form down, shrink by shrink process, and then form can not high shrinkage down and villose double-decker.So the collapsible fiber of dyeing can not be used for this method.For this reason, the collapsible fiber that can be used in the method only limits to have the un-dyed fibers of natural colored.Therefore limit the color and luster effect, particularly limited fur look and the necessary soft feel of sable colour product, and can not get being similar to the color and luster effect that the double-decker of atural fur brings, can not fully present the velvet that the napping structure is brought.
In with the above-mentioned common collapsible fibrous fine hair product that is unstained, connect each other in the shrink process of collapsible fiber after braiding and weaving making herbs into wool, and, collapsible fiber can not tangle between high shrinkage each other, and shrink, in glazing step subsequently, since very serious in the curling stretching that is bound up on fiber (glazing arrangement) of fiber, so effect only can reach the part near the fine hair surface.As a result, than in atural fur, the napping state of fine hair part is obviously relatively poor.From the feel angle, break or roughness bigger, lack very much the draping property of fine hair raw yarn.Therefore, not fit with the clothes that this fine hair is made, shape is unnatural yet.Such clothes nature is less than the clothes of atural fur.
Consider above-mentioned situation, the inventor has illustrated the reason of these phenomenons.The result is, the inventor notices the connection resistance between the fiber after the shrink process, and it is considered to most important reason, and has successfully solved this problem.
JP-A 60-209048 (Japan's special permission is open) has disclosed a kind of fine hair composite that addresses this problem.This fine hair composite comprise 20-98% weight, shrinkage factor be 15% or higher, interfibrous confficient of static friction be 0.230 or lower collapsible fiber as the fiber of fine hair part.Because confficient of static friction is low between contracted fiber, in the shrink process after making herbs into wool braiding and weaving, the connection resistance force diminishes between the fiber, in the optical processing, curling stretching becomes easily on subsequently, and the fine hair product of gained has excellent outward appearance.In addition, connect a little less than the resistance,, can access the good fine hair of draping property even goods still keep soft hand feeling when the fine hair raw yarn is crooked because fine hair shrinks the back.
Consider the problems referred to above of the fine hair product of traditional atural fur color and luster, we find to use the collapsible fiber of proposing previously can obtain desirable fine hair product.
Therefore, an object of the present invention is to provide a kind of fine hair product of atural fur color and luster, its characteristic is more near atural fur, promptly, have atural fur intrinsic soft feel and the color and luster effect of bringing by double-decker, also has the napping structure that is similar to atural fur, the velvet excellent performance.
Another object of the present invention provides a kind of fine hair composite that above-mentioned fine hair product can be provided.
Fine hair product according to the present invention has such fine hair part: it is included in the resulting down of collapsible filament contraction that will dye in the shrink process after making herbs into wool braiding and the weaving, with long wool hair that can not high shrinkage, the length difference that wherein dyes between down and the long wool hair is 2-7mm.
If the length difference between down and the long wool hair less than 2mm, as the approaching villose length as outer layer protection hair part of the length of fine hair down partly, just can not wish to obtain the nap effect step by step that double-decker forms.In addition, if the length difference of fine hair surpasses 70mm, the color and luster effect is relatively poor, and is undesirable.
Fine hair product used in the present invention is meant general fine hair product, be by the sliver knitting machine, to form the sliver (sliver) that the fibrous raw material of fine hair part makes with basic yarn and make pile fabric, on the basal surface of this fabric, be coated with and be covered with binding agent, again with the binding agent drying.
In addition, the raw material that constitutes the fine hair part in the fine hair product of the present invention is to comprise collapsible fiber of dyeing and fine hair composite that can not the high shrinkage mixture.
The component of the collapsible fiber of dyeing in the fine hair composite is a thermoplastic polymer, preferred acrylic copolymer.Have the composition that contains copolymer in the acrylic acid synthetic fiber, this copolymer comprises 30% weight or more acrylonitrile (for for simplicity, hereinafter state be " AN ").This copolymer is by obtaining AN and at least a polymerisable olefinic type monomers copolymerization.If the amount of AN is less than 30% weight, the feel of the feel of goods and wild animal fur falls far short, and is clamminess, and lacks the volume sense.In addition, the arrangement of shrink process and glazing must be finished under given conditions.
The example of monoene class monomer is an acrylate, methacrylate, acrylamide, Methacrylamide, the compound of or their list-or two-replace; Acrylic acid, methacrylic acid, itaconic acid, vinyl chloride, dichloroethylene, vinyl acetate (as vinylacetate), vinyl pyrrolidone, vinylpyridine, or the compound of their alkyl replacement; Styrene sulfonic acid, allyl sulphonic acid, pib sulfonic acid, to methacryloyl oxo benzene sulfonic acid, methacryloyl oxopropyl sulfonic acid, 2-acrylamide ,-methyl-propyl sulfonic acid, or their slaine and amine salt; Or the like.
In the present invention, but the monomer of copolymerization does not have strict restriction, any general, can all can use with the monoolefine unsaturated compound of acrylonitrile compolymer.
Can use common compound, as, acrylic copolymer obtained as polymerization initiator by traditional vinyl polymerization method such as peroxide, azo-compound or various redox compounds etc.
Acrylic copolymer is dissolved in organic solvent, as, form spinning solution in acetone, acetonitrile, dimethyl formamide, dimethylacetylamide or the dimethyl sulfoxide (DMSO).With common doing or wet spinning, spinning solution is pulled out from spinning nozzle, with after-drawing and drying.If desired, can stretch and heat treatment.The shrinkage factor of the collapsible fiber of using among the present invention is 15% or bigger.Obtain shrinkage factor and be 15% or higher collapsible fiber, can realize by be stretching under the temperature that is higher than 70 ℃-140 ℃ formed long filament with 1.2-4.0 extensibility doubly.
As mentioned above, the used collapsible fiber of the present invention is that shrinkage factor is 15% or higher, preferred 20% or higher thermoplastic fibre.The reason of this restriction is; when the fine hair that weaves and goods be with shrinkage factor less than 15% fiber make the time; the length of the fine hair of the outer layer protection hair part of can not high shrinkage forming and approaching by the length of the fine hair of collapsible fibroplastic fine hair part; the result; the effect that double-decker brings; that is, nap effect has step by step just reduced.In addition, use the reason of thermoplastic fibre to be, for example, can obtain last light effect subsequently, be i.e. the curling stretching of the fiber that obtains by mobile gradually hot-rolling (edged hot rollers).Term used in the present invention " shrinkage factor " with the length of percentage (%) expression contraction change with respect to the ratio of perisystolic length, be by fibre length, the fine hair that is shunk in more damp and hotter or the dry heat treatment weave and the textile finishing step in the fibre length of being shunk or with the similar condition of the condition of shrink process under handle contraction fibre length obtain.In other words, the meaning of " shrinkage factor is 15% or higher " both had been meant that damp and hot shrinkage factor was 15% or higher among the present invention, was meant that again dry-hot shrinkage is 15% or higher.
The fineness of the used collapsible fiber of dyeing is preferably 1-10 dawn (for for simplicity, hereinafter state be " d "), more preferably 2-7d among the present invention.
The fibre length of coloured fibre was preferably 20-64mm before shrinking, more preferably 25-51mm.
Cross section to the collapsible fiber that dyes has no particular limits, and can be selected from following shape, as, circle, open circles, oval shape, silk cocoon shape, flat, ellipse, trilobal, quatrefoil, five leaf, or the like.
The color and luster of the collapsible fiber of dyeing used in the present invention is selected from can make us expecting to be the color of atural fur and style color thereof.Giving the colouring agent of collapsible fiber colouring is dyestuff or pigment, and they can use separately also can mix use.The common cation dyes of preferred use, anionic example comprises chlorion, alkyl sulfonate ion, alkyl-bitter edible plant sulfonate ion, dialkyl group sulfo-coral amber acid ion and alkyl two-phenyl ether disulfonic acid radical ion.The example of pigment comprises carbon black, organic pigment and inorganic pigment.
The method of dyeing is such, with dyestuff or pigment dissolved or be dispersed in organic solvent or the part spinning solution, the mixture with gained mixes with spinning solution then.When dye solution or dispersion liquid are mixed with spinning solution, be necessary the solution of its gained is mixed equably.Operable mixed method has, and dye solution or dispersion liquid are directly introduced in the spinning solution groove, and maybe can use line mixer to carry out pipeline and mix, or the like.In addition, can use so-called gelling decoration method in the gelatinization of wet method weaving, to use cationic dyeing.Certainly, can in spinning solution, add the stabilizing agent that needs at the characteristic of fiber to add, fluorescent pigment, delustering agent (dullingagent) etc.
What use with collapsible fiber can not high shrinkage can be the fiber or the undyed fiber of dyeing.Use the undyed fiber can be by being called as dyeing such as over myer dyeing machine.The term that uses among the present invention " can not high shrinkage " refers to that shrinkage factor is 10% or lower fiber.
Fineness that can not high shrinkage is preferably 3-40d, more preferably 5-30d.
Fibre length that can not high shrinkage is preferably 25-127mm, more preferably 38-89mm before contraction.
Cross section that can not high shrinkage is selected from circle, open circles, oval shape, silk cocoon shape, flat, ellipse, trilobal, quatrefoil, five leaf, or the like.In order on visual effect, to resemble the outer layer protection hair, preferred flat and ellipse in these shapes.
Can not a kind of fineness, fibre length, color and luster and shrinkage factor can be selected arbitrarily by high shrinkage, wherein two or more cotton mixture can be used as.
Fine hair product of the present invention is following manufacturing.With the collapsible fiber of above-mentioned dyeing with can not high shrinkage mix, the mixture of gained is made card sliver (card sliver) by opener (opener) and carding machine.With high-pile knitter Wool top feeding type braiding card sliver.In this case, in order to obtain double-decker color and luster effect of bringing and the structure that is similar to atural fur, pre-glazing and pre-cropping are important step.After cropping makes fibre length constant, coat the binding agent of acrylate and so at the back side of fine hair.In this case, the back side that vapor stream is crossed pile fabric makes fine hair collapsible filament contraction partly, forms the down of dyeing, and improves the viscosity of binding agent.Drying is for example to carry out 5 minutes under 130 ℃, finishing shrink process simultaneously.After this, under high temperature (140-165 ℃), carry out glazing and brushing (brushing), in conjunction with in the temperature (130-110 ℃) and low temperature (100-80 ℃) glazing and cropping, thereby obtain plush.Preferably, in whole fibers of fine hair part, braiding and weaving preferably account for 40-70% weight after shrink process is shunk the 20-98% weight that the formed staple fibre of the collapsible fiber of dyeing accounts for the fine hair product of gained.If comprise that the down of collapsible fiber is less than 20% weight or, just can not fully form double-decker more than 98% weight.
As mentioned above, fine hair product of the present invention is, use the fine hair part that forms by collapsible fiber of dyeing and the fine hair composite can not high shrinkage formed, it comprises the down of dyeing and long wool hair that can not high shrinkage, and the collapsible fiber in the dyeing down is to shrink in the shrink process after fine hair braiding and weaving.Preferably, owing to form the collapsible fiber of dyeing of down be with selected confficient of static friction, for example, fiber with dyed in the mass (solution-dyed), fiber does not receive heat when dyeing, therefore, the effect of the abundant glazing in plush arrangement step is untied interfibrous connection, thereby makes goods have soft hand feeling and velvet performance.In addition, this fine hair product is, the fine hair composite that will comprise collapsible fiber of dyeing and mixture that can not high shrinkage is as the fine hair raw material, it is 2-7mm that combination by each method for sorting makes down and villose length difference, thereby form the double-decker and the napping structure that are similar to atural fur, as a result, obtained color and luster effect and the velvet performance brought by double-decker.
Illustrate in greater detail the present invention below in conjunction with embodiment and Comparative Examples, be not limited to this but should understand the present invention.
Before describing embodiment, the method for earlier that the present invention is used evaluation fiber is done one and is explained.
(1) damp and hot shrinkage factor
Length (L when measuring sample load being 10mg/d before shrinking
w).Handle sample with atmospheric steam and made it in 30 minutes to shrink, get back to room temperature then.Measure the length of sample under the 10mg/d load (L '
w).With following equation shrinkage from mold dimensions.
Shrinkage factor (%)=[(L
w-L '
w)/L
w] * 100
(2) dry-hot shrinkage
Method by the damp and hot shrinkage factor of said determination is measured, and just handles 20 minutes in 130 ℃ soaking pit (soaking o ven).Measure sample in perisystolic length L
DLength L after shrinking with sample '
D, be calculated as follows shrinkage factor.
Shrinkage factor (%)=[(L
D-L '
D)/L
D] * 100
(3) characteristic of fine hair product
By five adjusters (1) soft feeling from the angle evaluation gained fine hair product of vision and sense of touch, (2) velvet sense, the color and luster effect that (3) double-decker brings and (4) are similar to the napping state of atural fur.Carrying out for three steps estimates.The 1-5 branch is chosen as " being unsatisfied with " (*), and the 6-10 branch is chosen as " satisfied a little " (△), and the 11-15 branch is chosen as " satisfaction " (zero).
Embodiment 1
A kind of fine hair composite, comprise that 40% weight cross section is an oval shape, interfibrous static friction rate is 0.220, and fineness is 4d, fibre length is 32mm, is flat with dyestuff through collapsible modacrylic fiber of dyed in the mass (dry-hot shrinkage: 30%, color and luster: brown deeply) and 60% weight cross section, fineness is 15d, fibre length is the not collapsible modacrylic fiber (dry-hot shrinkage: 4.0%, color and luster: brown) of 51mm, through fully mixing the sliver that obtains 18g/m.Use the sliver knitting machine, make pile fabric with the Double bottom line of polyester filament (150d).Carry out pre-glazing and pre-cropping, making villus length is 17mm, and the esters of acrylic acid binding agent is coated at the back side of fine hair.Collapsible fiber fully shrinks and is dry simultaneously.Carry out glazing and brushing at 155 ℃, in conjunction with in the temperature (120 ℃) and low temperature (90 ℃) glazing and cropping, making villus length is the fur look plush of 23mm.In this fine hair product, be 11mm as the dyeing down of fine hair with as the villus length difference between the long wool hair of outer layer protection hair, down accounts for 53% weight in the fiber of fine hair part.
Embodiment 2
A kind of fine hair composite, comprise that 40% weight cross section is an oval shape, interfibrous static friction rate is 0.225, fineness is 3d, fibre length is 32mm, with cation dyes and carbon black collapsible modacrylic fiber (dry-hot shrinkage: 30% through dyed in the mass, color and luster: black), with 40% weight cross section be flat, fineness is 15d, fibre length is 51mm, becomes the not collapsible modacrylic fiber (dry-hot shrinkage: 4.0%), use the method identical with the foregoing description 1 that it is made the plush of fur look of black through dyed in the mass.In this fine hair product, be 11mm as the dyeing down of fine hair with as the villus length difference between the long wool hair of outer layer protection hair, down accounts for 53% weight in the fiber of fine hair part.
Embodiment 3
A kind of fine hair composite, comprise that 30% weight cross section is an oval shape, interfibrous static friction rate is 0.190, fineness is 4d, fibre length is 32mm, with the collapsible modacrylic fiber (dry-hot shrinkage: 20% of pigment through dyed in the mass, color and luster: brown), with 30% weight cross section be flat, fineness is 10d, and fibre length is 51mm, through the not collapsible acrylic fiber (dry-hot shrinkage: 4.0% of cationic dyeing, color and luster: ecru (beige)), with 40% weight cross section be flat, fineness is 15d, fibre length is 51mm, dye pale cream not collapsible modacrylic fiber (dry-hot shrinkage: 4.0%), use the method identical that it is made the plush of fur look through cation dyes with the foregoing description 1.In this fine hair product, be 9mm as the dyeing down of fine hair with as the villus length difference between the long wool hair of outer layer protection hair, down accounts for 53% weight in the fiber of down part.
Embodiment 4
A kind of fine hair composite, comprise that 40% weight cross section is an oval shape, interfibrous static friction rate is 0.220, and fineness is 4d, fibre length is 32mm, is flat with dyestuff through collapsible modacrylic fiber of dyed in the mass (dry-hot shrinkage: 30%, color and luster: brown deeply) and 60% weight cross section, fineness is 11d, fibre length is the not collapsible modacrylic fiber (dry-hot shrinkage: 5.0%, color and luster: brown) of 51mm, through fully mixing the sliver that obtains 18g/m.Use the sliver knitting machine, make pile fabric with the Double bottom line of polyester filament (150d).Carry out pre-glazing and pre-cropping, making villus length is 25mm, and the esters of acrylic acid binding agent is coated at the back side of fine hair.Collapsible fiber fully shrinks in drying.Carry out glazing and brushing at 155 ℃, in conjunction with in the temperature (120 ℃) and low temperature (90 ℃) glazing and cropping, making villus length is the sable look plush of 30mm.In this fine hair product, be 11mm as the dyeing down of fine hair with as the villus length difference between the long wool hair of outer layer protection hair, down accounts for 42% weight in the fiber of fine hair part.
Embodiment 5
A kind of fine hair composite, comprise that 40% weight cross section is an oval shape, interfibrous static friction rate is 0.210, and fineness is 3d, fibre length is 28mm, is flat with pigment through collapsible modacrylic fiber of dyed in the mass (dry-hot shrinkage: 18%, color and luster: brown) and 60% weight cross section, fineness is 7d, fibre length is 32mm, through the not collapsible modacrylic fiber (dry-hot shrinkage: 8.0), obtain the sliver of 18g/m through abundant mixing of cationic dyeing.Use the sliver knitting machine, make pile fabric with the Double bottom line of polyester filament (150d).Carry out pre-glazing and pre-cropping, and coat the esters of acrylic acid binding agent at the back side of fine hair.Fully shrink in the time of collapsible fiber drying.Carry out glazing and brushing at 155 ℃, in conjunction with in the temperature (120 ℃) and low temperature (90 ℃) glazing and cropping, make the plush that villus length is 17mm.In this fine hair product, be 2.0mm as the dyeing down of fine hair with as the villus length difference between the long wool hair of outer layer protection hair, down accounts for 40% weight in the fiber of fine hair part.
Embodiment 6
A kind of fine hair composite, comprise that 40% weight cross section is a silk cocoon shape, interfibrous static friction rate is 0.230, and fineness is 5d, fibre length is 32mm, is oval with dyestuff through collapsible modacrylic fiber of dyed in the mass (dry-hot shrinkage: 40%, color and luster: brown) and 60% weight cross section, fineness is 12d, fibre length is 127mm, dyes beige not collapsible modacrylic fiber (dry-hot shrinkage: 4.0%), obtain the sliver of 18g/m through abundant mixing through cation dyes.Use the sliver knitting machine, make pile fabric with the Double bottom line of polyester filament (150d).Carry out pre-glazing and pre-cropping, the esters of acrylic acid binding agent is coated at the back side of fine hair.Collapsible fiber fully shrinks in drying.Carry out glazing and brushing at 155 ℃, in conjunction with in the temperature (120 ℃) and low temperature (90 ℃) glazing and cropping, make the plush that villus length is 80mm.In this fine hair product, be 70mm as the dyeing down of fine hair with as the villus length difference between the long wool hair of outer layer protection hair, down accounts for 42% weight in the fiber of fine hair part.
Embodiment 7
A kind of fine hair composite, comprise that 15% weight cross section is an oval shape, interfibrous static friction rate is 0.230, and fineness is 4d, fibre length is 32mm, is flat with pigment through collapsible modacrylic fiber of dyed in the mass (dry-hot shrinkage: 30%, color and luster: brown deeply) and 85% weight cross section, fineness is 7d, fibre length is 51mm, dyes the not collapsible modacrylic fiber (dry-hot shrinkage: 4.0%), obtain the sliver of 18g/m through abundant mixing of brown through cation dyes.Use the sliver knitting machine, make pile fabric with the Double bottom line of polyester filament (150d).Carry out pre-glazing and pre-cropping, and coat the esters of acrylic acid binding agent at the back side of fine hair.Collapsible fiber fully shrinks in drying.Carry out glazing and brushing at 155 ℃, in conjunction with in the temperature (120 ℃) and low temperature (90 ℃) glazing and cropping, make the plush that villus length is 25mm.In this fine hair product, be 13mm as the dyeing down of fine hair with as the villus length difference between the long wool hair of outer layer protection hair, down accounts for 20% weight in the fiber of fine hair part.
Embodiment 8
A kind of fine hair composite, comprise that 90% weight cross section is an oval shape, interfibrous static friction rate is 0.220, and fineness is 4d, fibre length is 32mm, is flat with pigment through collapsible modacrylic fiber of dyed in the mass (dry-hot shrinkage: 30%, color and luster: brown deeply) and 10% weight cross section, fineness is 20d, fibre length is 51mm, dyes the not collapsible modacrylic fiber (dry-hot shrinkage: 4.0%), obtain the sliver of 18g/m through abundant mixing of brown through cation dyes.Use the sliver knitting machine, make pile fabric with the Double bottom line of polyester filament (150d).Carry out pre-glazing and make villus length be stabilized in 20mm, and coat the esters of acrylic acid binding agent at the back side of fine hair with pre-cropping.Collapsible fiber fully shrinks in drying.Carry out glazing and brushing at 155 ℃, in conjunction with in the temperature (120 ℃) and low temperature (90 ℃) glazing and cropping, make the plush that villus length is 25mm.In this fine hair product, be 13mm as the dyeing down of fine hair with as the villus length difference between the long wool hair of outer layer protection hair, down accounts for 95% weight in the fiber of fine hair part.
Comparative Examples 1
A kind of fine hair composite, comprise that 40% weight cross section is an oval shape, interfibrous static friction rate is 0.350, fineness is 3d, fibre length be 51mm the modacrylic fiber that is unstained (dry-hot shrinkage: 4.0%) and 60% weight cross section be flat, fineness is 10d, fibre length is 51mm, dyes pale cream not collapsible acrylic fiber (dry-hot shrinkage: 4.0%), use the method identical with the foregoing description 1 that it is made plush through cation dyes.In this fine hair product, be 1mm as the fine hair of fine hair with as the villus length difference between the long wool hair of outer layer protection hair, in the fiber of fine hair part, account for 40% weight as the fine hair of fine hair.
The evaluation result of the fine hair product that is used for the fine hair composite of the foregoing description 1-8 and Comparative Examples 1 and makes with these fine hair composites is listed in the following table 1.
Table 1.
Fine hair product
Collapsible collapsible fiber
The fiber that fiber contracts and not collapsible
The ratio of fiber
Quiet doing carefully done thin (weight ratio)
The temperature of rubbing temperature
Wipe to receive (d) rub (d)
The rate wiping of contracting
Rate rate embodiment 1 0.220 30% 4 4% 15 40/60 embodiment 2 0.225 30% 3 4% 15 40/40+20
4% 20 embodiment 3 0.190,20% 4 4% 10 30/30+40
4% 15 embodiment 4 0.220,30% 4 5% 11 40/60 embodiment 5 0.210,18% 3 8% 7 40/60 embodiment 6 0.230,40% 5 4% 12 40/60 embodiment 7 0.230,30% 4 4% 7 15/85 embodiment 8 0.220,30% 4 4% 20 90/10 Comparative Examples 1 0.350 4% 3 4% 10 40/60
Table 1 (continuous table).
Fine hair product
Down and down are in evaluation result
The fine hair product of long wool hair
Between villus fiber in gentle silk look rise
The soft suede of length difference ratio pool suede
(mm) (% weight) perception is imitated shape
Fruit attitude embodiment 1 11 53 zero zero zero zero embodiment 2 11 53 zero zero △ zero embodiment 39 53 zero zero zero zero embodiment 4 11 42 zero zero zero zero embodiment 52 40 △ zero △ zero embodiment 6 70 42 zero zero △ zero embodiment 7 13 20 △ 000 embodiment 8 13 95 zero zero zero zero Comparative Examples 11 40 * △ * *
From the listed result of above-mentioned table 1 as can be seen, when using fine hair composite of the present invention, the fine hair product of gained all is gratifying in soft feeling, velvet performance, color and luster effect and the napping configuration aspects that is similar to atural fur.
Claims (11)
1, a kind of fine hair product has and shrinks dyeing resulting down of collapsible fiber and villose fine hair part that can not high shrinkage in the shrink process that is included in after the fine hair braiding, and wherein, the length difference between dyeing down and the long wool hair is 2-70mm.
2, fine hair product as claimed in claim 1, wherein, the dyeing down accounts for 20-98% weight in the fiber of fine hair part.
3, a kind of fine hair composite comprises collapsible fiber of dyeing and mixture that can not high shrinkage.
4, fine hair composite as claimed in claim 3, the collapsible fiber of dyeing wherein are that shrinkage factor is 15% or higher fiber.
5, fine hair composite as claimed in claim 3, the fineness of the collapsible fiber of dyeing wherein is the 1-10 dawn.
6, fine hair composite as claimed in claim 3, dyeing wherein is collapsible, and interfibrous static friction rate is 0.230 or lower.
7, fine hair composite as claimed in claim 3, the collapsible fiber of dyeing wherein are the fibers through dyed in the mass.
8, fine hair composite as claimed in claim 7, the collapsible fiber of dyeing wherein are the fibers with the mixture dyeing of dyestuff, pigment or dyestuff and pigment.
9, as each fine hair composite of claim 3-8, the collapsible fiber of dyeing wherein is the acrylic acid synthetic fiber.
10, fine hair composite as claimed in claim 3, wherein can not high shrinkage fineness be the 3-40 dawn.
11, as the fine hair composite of claim 3 or 10, wherein can not high shrinkage the cross section be flat or ellipse.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP945695 | 1995-01-25 | ||
| JP9456/1995 | 1995-01-25 | ||
| JP7142826A JPH08260289A (en) | 1995-01-25 | 1995-06-09 | Pile product and pile composition |
| JP142826/95 | 1995-06-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1136496A true CN1136496A (en) | 1996-11-27 |
| CN1095003C CN1095003C (en) | 2002-11-27 |
Family
ID=26344189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96100450A Ceased CN1095003C (en) | 1995-01-25 | 1996-01-25 | Fine hair product and fine hair composite |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPH08260289A (en) |
| KR (1) | KR100362430B1 (en) |
| CN (1) | CN1095003C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100366809C (en) * | 1997-04-14 | 2008-02-06 | 庄臣及庄臣工商有限公司 | Nonwoven fabric of multi-length, multi-denier fibers and absorbent article formed therefrom |
| CN1543519B (en) * | 2001-07-05 | 2010-05-12 | 钟渊化学工业株式会社 | Pile cloth having animal hair style |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1188554C (en) * | 2000-07-28 | 2005-02-09 | 钟渊化学工业株式会社 | Acrylic fiber with excellent appearance and woven pile fabric |
| JP4531281B2 (en) * | 2001-03-21 | 2010-08-25 | 株式会社カネカ | Far-infrared radiation raised fiber structure |
| JPWO2004009891A1 (en) * | 2002-07-19 | 2005-11-17 | 株式会社カネカ | Pile fabric |
| KR100537050B1 (en) * | 2002-09-16 | 2005-12-19 | 박동윤 | Infrared rays light by optic device |
| US8397542B2 (en) | 2009-02-18 | 2013-03-19 | Kaneka Corporation | Pile knitted fabric and sewn product employing pile knitted fabric |
| CN112127036B (en) * | 2020-09-24 | 2021-11-26 | 江苏恒科新材料有限公司 | European-imitation mink fabric |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0663158B2 (en) * | 1984-03-27 | 1994-08-17 | 鐘淵化学工業株式会社 | Pile composition |
-
1995
- 1995-06-09 JP JP7142826A patent/JPH08260289A/en active Pending
-
1996
- 1996-01-24 KR KR1019960001498A patent/KR100362430B1/en not_active IP Right Cessation
- 1996-01-25 CN CN96100450A patent/CN1095003C/en not_active Ceased
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100366809C (en) * | 1997-04-14 | 2008-02-06 | 庄臣及庄臣工商有限公司 | Nonwoven fabric of multi-length, multi-denier fibers and absorbent article formed therefrom |
| CN1543519B (en) * | 2001-07-05 | 2010-05-12 | 钟渊化学工业株式会社 | Pile cloth having animal hair style |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100362430B1 (en) | 2003-02-25 |
| KR960029508A (en) | 1996-08-17 |
| JPH08260289A (en) | 1996-10-08 |
| CN1095003C (en) | 2002-11-27 |
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| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Decision date of declaring invalidation: 20051110 Decision number of declaring invalidation: 7630 |