CN113647676A - Degradable alginate fiber cigarette filter rod and preparation method thereof - Google Patents
Degradable alginate fiber cigarette filter rod and preparation method thereof Download PDFInfo
- Publication number
- CN113647676A CN113647676A CN202110864383.7A CN202110864383A CN113647676A CN 113647676 A CN113647676 A CN 113647676A CN 202110864383 A CN202110864383 A CN 202110864383A CN 113647676 A CN113647676 A CN 113647676A
- Authority
- CN
- China
- Prior art keywords
- fiber
- cigarette
- filter stick
- alginate
- preparation
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- 239000000835 fiber Substances 0.000 title claims abstract description 142
- 235000010443 alginic acid Nutrition 0.000 title claims abstract description 108
- 229920000615 alginic acid Polymers 0.000 title claims abstract description 108
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 91
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 229940072056 alginate Drugs 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 46
- 229960001126 alginic acid Drugs 0.000 claims abstract description 35
- 239000000783 alginic acid Substances 0.000 claims abstract description 35
- 150000004781 alginic acids Chemical class 0.000 claims abstract description 35
- 238000000034 method Methods 0.000 claims abstract description 29
- 239000003063 flame retardant Substances 0.000 claims abstract description 25
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 24
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 22
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000001110 calcium chloride Substances 0.000 claims abstract description 21
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 21
- 239000011574 phosphorus Substances 0.000 claims abstract description 21
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 21
- 238000001914 filtration Methods 0.000 claims abstract description 16
- 230000008569 process Effects 0.000 claims abstract description 16
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims description 21
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 12
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 12
- 235000011152 sodium sulphate Nutrition 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 229920006221 acetate fiber Polymers 0.000 abstract description 8
- 230000000391 smoking effect Effects 0.000 abstract description 8
- 229920001282 polysaccharide Polymers 0.000 abstract description 4
- 239000005017 polysaccharide Substances 0.000 abstract description 4
- 150000004804 polysaccharides Chemical class 0.000 abstract description 4
- 239000000155 melt Substances 0.000 abstract 1
- 239000002912 waste gas Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 14
- 239000000661 sodium alginate Substances 0.000 description 14
- 235000010413 sodium alginate Nutrition 0.000 description 14
- 229940005550 sodium alginate Drugs 0.000 description 14
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 10
- 238000009987 spinning Methods 0.000 description 9
- 239000000779 smoke Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 5
- 229910001424 calcium ion Inorganic materials 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229910001415 sodium ion Inorganic materials 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000002344 surface layer Substances 0.000 description 5
- 159000000007 calcium salts Chemical class 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000011162 core material Substances 0.000 description 3
- 239000012024 dehydrating agents Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000002166 wet spinning Methods 0.000 description 3
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229920001747 Cellulose diacetate Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000208125 Nicotiana Species 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000000648 calcium alginate Substances 0.000 description 2
- 235000010410 calcium alginate Nutrition 0.000 description 2
- 229960002681 calcium alginate Drugs 0.000 description 2
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical group [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229960002715 nicotine Drugs 0.000 description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 206010013911 Dysgeusia Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- HZEBHPIOVYHPMT-OUBTZVSYSA-N Polonium-210 Chemical compound [210Po] HZEBHPIOVYHPMT-OUBTZVSYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- -1 phosphate ester Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0229—Filter rod forming processes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/04—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of alginates
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The utility model relates to a filter stick for degradable alginate fiber cigarette and a preparation method thereof, wherein the filter stick for cigarette comprises alginate fiber; the surface structure of the alginate fiber is rough; when the alginic acid fiber is prepared, the curing solution comprises calcium chloride and an organic phosphorus flame retardant; the concentration of calcium chloride is 2-10 wt%; the dosage of the organic phosphorus flame retardant is 2-5 percent; the alginic acid fiber is prepared into a sheet-shaped cigarette filtering material by a non-woven fabric process; the sheet filter material is made into a filter stick for cigarettes. For traditional acetate fiber cigarette filter rod, this disclosure uses natural polysaccharide fibre preparation cigarette filter rod, and natural polysaccharide's alginic acid fibre has natural degradability, can degrade naturally in the environment, reduction waste gas cigarette end that can show to the pollution problem of environment to can improve cigarette smoking and experience the sense, this filter rod is fire-retardant and do not have the melt and drip.
Description
Technical Field
The disclosure belongs to fiber materials, relates to a filter material prepared from fibers, and particularly relates to a alginate fiber cigarette filter rod and a preparation method thereof.
Background
Although it is generally known that cigarette smokers generally depend on cigarette, the cigarette generates over 4000 harmful chemical substances such as tar, amonia, nicotine, suspended particles, PM2.5, polonium-210, etc. and dozens of carcinogens during combustion, and the harmful substances cause serious indoor pollution and affect human health, and it is the direction of research by researchers to prevent the harmful substances from entering human bodies.
Alginate fiber is prepared through extruding water solution of sodium alginate into water solution of calcium chloride through a spinneret plate, stretching the nascent fiber in hot water, washing with water and drying. The alginate fiber is a natural fiber, and the fiber has more calcium ions, so the fiber has better flame retardant property and can be applied to cigarette filtering scenes.
The traditional cigarette filter stick material is acetate fiber, namely cellulose diacetate, the fiber is mainly used for filtering, and is non-toxic, harmless and excellent in filtering effect, according to the cigarette sales data of 2015, the weight of the cellulose diacetate consumed for cigarettes is at least 6kt, and the discarded filter stick used along is mainly treated in a burning and burying mode, so that the environment is greatly influenced by the traditional filter stick used along, and a biodegradable filtering material is urgently needed to replace the traditional acetate fiber.
Alginate fiber is a natural non-combustible fiber, and the alginate fiber has biodegradability and can be decomposed under outdoor conditions without special treatment, but the application of alginate fiber to cigarettes is rarely mentioned.
Chinese patent grant publication no: CN102524956B discloses a cigarette filter stick containing alginate fibers and a preparation method thereof, wherein a core material of the cigarette filter stick is a alginate fiber bundle (similar yarn) with the diameter of 0.5-4mm, and the preparation method of the alginate fiber filter stick comprises the following steps: spinning the alginate fibers into single yarns by a traditional spinning process and plying to prepare alginate fiber bundles; in the production process of the filter stick, the alginate fiber bundle is drawn to a forming machine through a drawing and positioning device and is added to the center of the filter stick through filter stick forming equipment to prepare a midline filter stick; wherein the circumference of the aluminum bar is 24.25mm, and the diameter of the alginic acid fiber filter core is 0.5-4 mm. Therefore, the invention discloses a structure of a cigarette filter stick, alginic acid fiber is used in the structure, the cigarette filter stick effectively reduces harmful substance components in smoke under the condition that the release amount of tar and nicotine in the smoke of the cigarette is basically unchanged, the removal rate of phenol can reach about 39%, and the removal rate of nitrosamine is about 28%. Meanwhile, on the premise of not changing the smoking style of the cigarette, the smoking quality of the cigarette can be improved by adding the alginate fiber into the filter stick. However, the prior art only uses the alginate fibers as the filter element, and the integral cigarette filter rod lacks the complete degradable performance.
The present disclosure aims to solve the above technical problems in the prior art, and provide a alginate fiber cigarette filter rod and a preparation method thereof, wherein a filter element prepared from alginate fiber has excellent filtering effect, is biodegradable, and is environment-friendly.
Disclosure of Invention
In view of the above problems, the present disclosure provides a alginate fiber cigarette filter stick and a preparation method thereof, wherein the cigarette filter stick has biodegradable properties, and can effectively filter toxic and harmful gases generated by the combustion of tobacco and some positively charged particles (smoke) generated during the combustion.
The idea of the disclosure is to prepare the alginate fiber, the surface layer structure of the alginate fiber is rough, the specific surface area of the fiber can be effectively improved, and the alginate fiber further has excellent adsorption performance, and meanwhile, the alginate fiber is used for preparing a cigarette filter stick.
The conception of the disclosure is also that the alginic acid fiber is prepared by using wet spinning, and the method for preparing the alginic acid fiber is environment-friendly. The cigarette filter stick is different from the existing cigarette filter stick which uses acetate fiber as the cigarette filter stick, uses organic solvent in the preparation process of the acetate fiber, uses water as the solvent in the preparation of the alginic acid fiber, and does not influence the smoking taste due to the release of non-aqueous solvent in the process of filtering and adsorbing the burning high-temperature smoke.
The idea of the disclosure is that the alginic acid fiber is made into a non-woven fiber sheet-shaped filter material, and the filter element can be obtained by only winding and pressing the sheet-shaped filter material in the process of preparing the filter stick.
The conception of the present disclosure is that the filter material made of the alginate fiber prepared by the present disclosure has excellent flame retardance, and can not be burnt when being prepared into cigarette filters.
Specifically, the disclosure provides a preparation method of alginate fibers, which comprises the following steps: dissolving sodium alginate in water to obtain a sodium alginate solution;
defoaming the sodium alginate solution to obtain a spinning solution;
putting the spinning solution into a spinning tank for wet spinning;
and solidifying and drafting the alginic acid nascent fiber in a solidifying solution to obtain the alginic acid fiber.
In some embodiments, the solidifying fluid comprises calcium chloride; the concentration of the calcium chloride is 2-10 wt%.
The present disclosure cures alginic acid nascent fibers, wherein calcium chloride is used as a curing agent in the curing liquid. Because the negative ions of the calcium chloride are small, the curing speed of the alginic acid fiber is too high, and the shape of the surface of the fiber is compact and smooth.
In some embodiments, the curing liquid further comprises an organic phosphorus flame retardant;
the dosage of the organic phosphorus flame retardant is 2-5%;
the organic phosphorus flame retardant is one or more of phosphate, phosphite and phosphate;
the organic phosphorus flame retardant is decomposed under the condition of high temperature, the phosphorus flame retardant → phosphoric acid → polymetaphosphoric acid, the polymetaphosphoric acid is a stable compound which is not easy to volatilize, a thin glass-shaped or liquid protective layer is formed on the surface layer of the fiber, and meanwhile, the phosphorus flame retardant is provided with a strong dehydrating agent, the polymer surface is isolated from air, and the dehydrated water vapor absorbs a large amount of heat, so that the decomposition speed of the alginic acid fiber is rapidly reduced.
In addition, the alginate fiber contains a large amount of calcium ions, and the calcium ions can be solidified on the surface layer of the fiber under the high-temperature condition, so that the thermal insulation performance is realized, the thermal decomposition of the fiber is reduced, the surface layer structure of the alginate fiber under the high-temperature condition is further kept stable, and the effect of continuously adsorbing harmful gases is realized.
And thirdly, the curing liquid contains an organic phosphorus flame retardant which comprises a phosphorus element, and the element can be adsorbed on the surface of the fiber in the curing process of alginic acid, so that the form of the surface of the fiber is improved, the form of the surface of the fiber is rough, and the absorption of harmful gases is facilitated.
Furthermore, another purpose of the phosphorus-based flame retardant used in the present disclosure is that the polymetaphosphoric acid generated by the phosphorus-based flame retardant at high temperature is a strong dehydrating agent, and can remove the water fixed in alginic acid at high temperature, so as to make the smoke of the burning tobacco more moist and improve the taste of the smoking of the consumer. The traditional cigarette mainly utilizes polyol such as glycerol to improve smoking taste, particularly humidity of smoke, but the polyol is organic in nature, can improve humidity, but can influence the smoking taste of the cigarette.
In some embodiments, the present disclosure also discloses a sheet-form cigarette filter material of alginate fibers.
The cigarette filter material is prepared from the flame-retardant alginate fiber;
in some embodiments, the alginate fiber sheet-shaped cigarette filter material is prepared by a non-woven fabric process using the above flame-retardant alginate fiber;
furthermore, the non-woven fabric process adopts a spunlace non-woven fabric preparation process.
In the spunlace nonwoven fabric process, the spunlace liquid contains calcium salt and sodium salt.
Further, the calcium salt is calcium chloride; the sodium salt is sodium sulfate.
The hydro-entangled non-woven fabric is added in the preparation process of the alginate fiber sheet-shaped cigarette filter material, and when liquid is subjected to hydro-entanglement in the preparation process, the alginate fiber is calcium alginate, and sodium ions can perform particle exchange with calcium ions, so that in the hydro-entangled process, the surface layer of the fiber is damaged, and the surface structure of the fiber in the prepared sheet-shaped cigarette filter material is rough. However, the inventors considered that if the degree of ion exchange between the sodium salt and sodium alginate is too high, the alginate fibers are broken, and the mechanical properties of the resulting sheet material are greatly reduced. In order to ensure the complete shape of the alginate fibers, calcium chloride is also added into the spunlace liquid, so that calcium ions and sodium ions compete on the alginate fibers, and the fiber surfaces are obviously etched under the condition of ensuring the complete structure of the alginate fibers, thereby improving the adsorption capacity of the filter material for cigarette smoke.
Further, in the hydroentangling liquid, the concentration of calcium chloride is 5 to 10% and the concentration of sodium sulfate is less than 1%.
In the process of competing and combining sodium salt and calcium salt, the concentration of calcium is ensured to be obviously higher than that of sodium ions, under the condition, the etching effect on the surface of the alginic acid fiber is achieved, and meanwhile, the alginic acid fiber is ensured not to break, so that the sheet-shaped filtering material has better mechanical property, and the subsequent processing is facilitated.
Meanwhile, the method also considers that the calcium sulfate is slightly soluble in water, the spunlace liquid contains two substances of sodium sulfate and calcium chloride, the calcium sulfate is easily generated in the solution to precipitate, the calcium sulfate in the needling solution is converted too much, and the high-pressure needling injection hole is easily blocked, so that in order to prevent the generation of the calcium sulfate and the separation from the solution, the concentration of the sodium sulfate is regulated to be less than 1%, and under the condition, the obvious separation phenomenon of the calcium sulfate cannot occur in the spunlace liquid.
Further, the concentration of sodium sulfate in the spunlace liquid is 0.1-0.8%, and further, the concentration of sodium sulfate is 0.5-0.8%
After the alginic acid non-woven fabric obtained by the method is subjected to spunlace by using spunlace liquid with sodium ions, partial sodium ions and calcium on the surface of calcium alginate fibers are subjected to particle replacement, the surface of the alginic acid fibers is etched, and the surface of the fibers is rough and uneven. Meanwhile, part of the sodium alginate is attached to the surface of the fiber, and the sodium alginate has positive charges after moisture absorption and is easier to adsorb harmful substances.
Furthermore, the alginic acid fiber comprises sodium alginate, and the sodium alginate has an adsorption effect on positively charged particles, and can efficiently adsorb harmful substances when being used as a cigarette filtering material.
In some embodiments, the present disclosure also provides an alginate fiber cigarette filter rod;
specifically, the alginate fiber cigarette filter stick is prepared by using the alginate fiber sheet-shaped cigarette filter material.
In some embodiments, the present disclosure also provides a method of making an alginate fiber cigarette filter rod;
the preparation method comprises the following steps:
1) preparing alginate fibers;
2) preparing a sheet-shaped cigarette filter material from the alginate fibers in the step 1);
3) the filter stick for cigarettes is prepared by the sheet-shaped cigarette filter material obtained in the step 2).
More specifically, the preparation of the cigarette filter stick is to prepare the cigarette filter stick on a filter stick forming machine.
Compared with the prior art, the method has the following advantages that:
1. compared with the traditional acetate fiber cigarette filter stick, the cigarette filter stick is prepared by using the natural polysaccharide fiber, and the alginic acid fiber of the natural polysaccharide has natural degradability and can be naturally degraded in the environment, so that the problem of pollution of waste cigarette ends to the environment can be remarkably reduced.
2. Compared with the traditional method for controlling the taste of cigarettes by adding polyhydric alcohol and the like into the cigarette filter stick, the method uses a certain amount of phosphorus flame retardant, the flame retardant is converted into the dehydrating agent under the high-temperature condition, meanwhile, the water absorption and moisture retention of the natural alginic acid fiber are very beneficial, and the phosphorus flame retardant can excite the water in the filter stick under the high-temperature condition, so that the purposes of controlling the humidity of the cigarettes and improving the smoking taste of the cigarettes are achieved.
3. Compared with the acetate fiber preparation process, the use of some organic solvents is difficult to avoid, when the acetate fiber is used as the traditional filter stick, the organic solvents can be volatilized under the high temperature condition and can be sucked by consumers, and the organic solvents can generate adverse effects on the taste of the cigarette and the health of the consumers; the alginate fibers of the present disclosure are prepared by using water as a solvent, so that the above problems do not exist.
4. The alginic acid fiber prepared by the method has a rough surface structure, and mainly uses calcium chloride in the fiber preparation process, so that the solidification rate is slowed down, and the surface of the fiber is rough; in addition, the method for preparing the sheet-shaped filter material by using the needle-punched non-woven fabric comprises the steps of adding two salts of calcium chloride and sodium sulfate into a water-punched liquid, and enabling the surface of the alginate fiber to be etched through the competition of calcium salt and sodium salt, so that the specific surface area of the alginate fiber is increased, the filtering performance of the filter material on cigarette smoke is further improved, and the taste of the cigarette is improved.
Detailed Description
The elastic multifunctional alginic acid composite fiber and the preparation method thereof according to the present disclosure are further described in detail with reference to the following embodiments:
example 1
Preparation method of alginic acid fiber
The method comprises the following steps: 1) dissolving sodium alginate in water to obtain a sodium alginate solution;
stirring for 3h when the concentration of the sodium alginate is 4% to obtain a sodium alginate solution;
placing sodium alginate in a hollow dryer, and performing vacuum defoaming to obtain a spinning solution;
putting the spinning solution into a spinning tank for wet spinning;
the spinning solidification liquid is a 10% sodium sulfate solution; the draw ratio was 1: 4.
The curing liquid also comprises an organic phosphorus flame retardant, and the content of the phosphate ester is 2 percent.
Drying the obtained alginic acid fiber to obtain the alginic acid fiber.
Example 2
A method for preparing alginate fibers, which is the same as that in example 1, except that a 10% calcium chloride solution is used in the curing process.
Example 3
The preparation method of the alginic acid fiber is the same as that of the alginic acid fiber in example 2, and is different from the preparation method in that no organic phosphorus flame retardant is added into a curing liquid in the curing process.
Example 4
Preparation of alginate fiber sheet-shaped cigarette filtering material
Alginate fibers obtained in examples 1 to 3 were used as raw materials to prepare alginate fiber sheet-like cigarette filter materials, respectively, by the following specific methods:
firstly, cutting off the alginate fiber filament with the length of 3-8cm, opening the fiber, and then lapping on a lapping machine;
and carrying out spunlace on the laid alginate fibers to obtain spunlace non-woven fabrics, namely the sheet-shaped cigarette filtering materials made of the alginate fibers.
Wherein, the solvent of the spunlace liquid is water, wherein, the sodium sulfate is 1 percent, and the calcium chloride is 10 percent.
The resulting sheet-like filter materials were respectively labeled as follows:
the fibers of example 1 correspond to filter material a;
the fiber of example 2 corresponds to filter material B;
the fiber of example 3 corresponds to filter material C.
Example 5
Preparation of alginate fiber sheet-shaped cigarette filtering material
Alginate fibers obtained in examples 1 to 3 were used as raw materials to prepare alginate fiber sheet-like cigarette filter materials, respectively, by the following specific methods:
firstly, cutting off the alginate fiber filament with the length of 3-8cm, opening the fiber, and then lapping on a lapping machine;
and carrying out spunlace on the laid alginate fibers to obtain spunlace non-woven fabrics, namely the sheet-shaped cigarette filtering materials made of the alginate fibers.
Wherein, the solvent of the spunlace liquid is water, wherein, the sodium sulfate is 3 percent, and the calcium chloride is 10 percent.
The resulting sheet-like filter materials were respectively labeled as follows:
the fiber of example 1 corresponds to filter material a 1;
the fiber of example 2 corresponds to filter material B1;
the fiber of example 3 corresponds to the filter material C1.
Example 6
Preparation of alginate fiber sheet-shaped cigarette filtering material
In this example, the preparation operation was the same as that provided in example 4, except that in the water-jet process, the solvent water was changed to an organic solvent, specifically ethanol.
The resulting sheet-like filter materials were respectively labeled as follows:
the fibers of example 1 correspond to filter material a;
the fibers of example 2 correspond to filter material b;
the fibers of example 3 correspond to filter material c.
Example 7
A filter rod for an alginic acid fiber cigarette is prepared by using the filter material as in examples 4 to 6.
Example 8
A cigarette using the filter plug for a cigarette made of alginic acid fiber, which was produced by using the filter plug for a cigarette as in example 7.
The cigarettes prepared above were tested according to the method of GB5606.4-2005, and the evaluation criteria test results were as follows:
all cigarettes were of the same cut filler, the comparative example was a conventional acetate filter, and the cigarettes were distinguished in the table below by the filter.
Wherein the gloss is 5 points; fragrance is divided into 32 points; harmonizing for 6 points; miscellaneous gas is divided into 32 minutes; irritation of 20 points; the aftertaste is 25 points, and the total score is 100 points (see GB5606.4-2005 for specific score).
The present disclosure has been described in detail above, and the principles and embodiments of the present disclosure have been explained herein using specific examples, which are provided only to assist understanding of the present disclosure and the core concepts. It should be noted that, for those skilled in the art, it is possible to make several improvements and modifications to the present disclosure without departing from the principle of the present disclosure, and such improvements and modifications also fall within the scope of the claims of the present disclosure.
Claims (7)
1. A degradable alginate fiber filter stick for cigarette is characterized in that:
the filter stick for the cigarette comprises alginic acid fibers;
the surface structure of the alginate fiber is rough;
the curing liquid comprises calcium chloride when the alginic acid fiber is prepared;
the concentration of the calcium chloride is 2-10 wt%;
the alginic acid fiber is prepared into a sheet-shaped cigarette filtering material by a non-woven fabric process;
the sheet filter material is made into a filter stick for cigarettes.
2. The filter stick for degradable alginate fiber cigarettes of claim 1, wherein:
the curing liquid also comprises an organic phosphorus flame retardant;
the amount of the organic phosphorus flame retardant is 2-5%.
3. The filter stick for degradable alginate fiber cigarettes as claimed in claim 2, wherein:
the organic phosphorus flame retardant is one or more of phosphate, phosphite and phosphate.
4. The filter stick for degradable alginate fiber cigarettes of claim 1, wherein:
the non-woven fabric process is a spunlace non-woven fabric process;
the liquid in the spunlace non-assistance process comprises sodium sulfate and calcium chloride, wherein the concentration of the calcium chloride is 5-10%, and the concentration of the sodium sulfate is 0.2-1%.
5. The preparation method of the filter stick for the degradable alginate fiber cigarette as claimed in any one of claims 1 to 4, wherein the preparation method comprises the following steps:
1) preparing alginate fibers;
2) preparing a sheet-shaped cigarette filter material from the alginate fibers in the step 1);
3) the filter stick for cigarettes is prepared by the sheet-shaped cigarette filter material obtained in the step 2).
6. The preparation method of the filter stick for degradable alginate fiber cigarettes as claimed in claim 5, wherein the preparation method comprises the following steps:
the curing agent in the step 1 comprises calcium chloride and an organic phosphorus flame retardant;
the concentration of the calcium chloride is 2-10 wt%; the amount of the organic phosphorus flame retardant is 2-5%.
7. The preparation method of the filter stick for degradable alginate fiber cigarettes as claimed in claim 5, wherein the preparation method comprises the following steps:
and 3) preparing the cigarette filter stick by using a filter stick forming machine.
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| CN202110864383.7A CN113647676A (en) | 2021-07-29 | 2021-07-29 | Degradable alginate fiber cigarette filter rod and preparation method thereof |
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Cited By (1)
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