CN113637538A - Small white shoe cleaning agent and preparation method thereof - Google Patents

Small white shoe cleaning agent and preparation method thereof Download PDF

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Publication number
CN113637538A
CN113637538A CN202110756341.1A CN202110756341A CN113637538A CN 113637538 A CN113637538 A CN 113637538A CN 202110756341 A CN202110756341 A CN 202110756341A CN 113637538 A CN113637538 A CN 113637538A
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China
Prior art keywords
parts
agent
cleaning agent
fluorescent whitening
mixture
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CN202110756341.1A
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Chinese (zh)
Inventor
汪远昊
刘光焰
冀亚雄
赵未
羊梦婷
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Guilin University of Technology
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Guilin University of Technology
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Priority to CN202110756341.1A priority Critical patent/CN113637538A/en
Publication of CN113637538A publication Critical patent/CN113637538A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a cleaning agent for small white shoes and a preparation method thereof, belonging to the technical field of cosmetics. The small white shoe cleaning agent is prepared from the following raw materials: anionic surfactant, nonionic surfactant, antiseptic, deionized water, soapberry extract, anti-settling agent, friction particles, fluorescent whitening agent, soap base, essence, biological enzyme and alkaline compound. The invention also discloses a preparation method of the white shoe cleaning agent. The cleaning agent for the small white shoes is suitable for deep stain removal and bright color protection of the small white shoes, can ensure that the vamps of the small white shoes to be cleaned have good service performance, fresh smell and no volatile peculiar smell, has no stimulation to the skin, optic nerves and respiratory systems of human bodies, is environment-friendly and safe, and does not cause environmental pollution.

Description

Small white shoe cleaning agent and preparation method thereof
Technical Field
The invention relates to a cleaning agent for small white shoes and a preparation method thereof, belonging to the technical field of cosmetics.
Background
The small white shoes refer to white shoes, and the shoes with white appearance are called small white shoes. The small white shoes become a trend, are shoe patterns which most people like to wear, have various styles, and are clean and refreshing. However, most of the small white shoe uppers are white, so that the shoes are easy to get dirty when being careless to wear, dirt such as dust, oil stain and the like is difficult to avoid, and the shoes are easy to turn yellow when not being cleaned in place, thereby affecting the service life of the small leather shoes.
At present, the market of cleaning products is increasingly developed, and the types of the cleaning products for cleaning the shoe uppers are also more and more abundant. However, the existing cleaning agent has the following problems: 1. the cleaning effect is not good, and the vamp is easy to yellow; 2. easily hurting hands and having peculiar smell; 3. contains organic solvents such as methanol, ethanol, benzene series, acetone, turpentine and the like, and is easy to cause environmental pollution.
In view of the above, it is necessary to provide a cleaning agent for white shoes and a preparation method thereof to solve the deficiencies of the prior art.
Disclosure of Invention
The invention aims to provide a cleaning agent for small white shoes. The cleaning agent for the small white shoes can deeply remove stains, is bright and color-protecting, can ensure that the vamps of the small white shoes have good service performance, has fresh smell and no volatile peculiar smell, has no stimulation to the skin, optic nerves and respiratory systems of human bodies, is environment-friendly and safe, and does not cause environmental pollution.
The scheme for solving the technical problems is as follows: a cleaning agent for small white shoes is prepared from the following raw materials in parts by weight: 5-10 parts of anionic surfactant, 5-10 parts of nonionic surfactant, 5-10 parts of preservative, 20-35 parts of friction particles, 40-160 parts of deionized water, 10-20 parts of soapberry extract, 15-30 parts of anti-settling agent, 5-10 parts of fluorescent whitening agent, 5-20 parts of soap base, 3-8 parts of essence, 4-5 parts of biological enzyme and 1.5-3.5 parts of alkaline compound.
The brief introduction of the raw materials in the white shoe cleaning agent of the invention is as follows:
1. anionic surfactants
Anionic surfactants, known by the english name An-ionic surfactants, are partially negatively charged surfactants that act as surface active agents upon ionization in water. The anionic surfactant is mainly in the forms of semitransparent viscous liquid, white needle-shaped, white powder and the like. The anionic surfactant dissociates in water to form a hydrophobic anion.
2. Nonionic surfactant
Nonionic surfactants, known in the english names nonionics surfactants, non-ionics surfactants, and non-ionics, refer to surfactants having oxygen-containing groups as the main hydrophilic groups that are not dissociated in aqueous solutions in the molecule.
3. Preservative
The preservative has good sterilization and corrosion prevention effects, and can prolong the shelf life of the white shoe cleaning agent.
4. Sapindus mukurossi extract
The fructus Sapindi Mukouossi is seed of Sapindus mukorossi Gaertn of Sapindaceae. Sapindaceae plants have more than 50 species of 25 genus in China. The soapberry contains abundant saponin substances, mainly triterpenoid saponins and sesquiterpene glycosides, has strong surface activity, and can provide soap base, so that the addition amount of the surfactant can be reduced.
The soapberry extract is adopted, so that the surface active substances and the soap base are further released in the vamp contacting process, and the stability of the white shoe cleaning agent is maintained for a longer time. Moreover, the soapberry extract can be dissolved by adopting deionized water, so that the soapberry extract is very convenient.
5. Anti-settling agent
The anti-settling agent is added, so that dirt can be separated from the vamp and quickly settled, the contact between the dirt and the vamp is reduced, the re-adhesion can be prevented, and the problem of moving the dirt or washing the dirt uniformly in the washing process is solved.
6. Friction particles
According to the invention, the friction particles are added, so that the friction touch feeling is stronger in the vamp cleaning process, and the dirt removing capability of the cleaning agent on vamp stains is greatly improved.
7. Fluorescent whitening agent
The fluorescent whitening agent is added, so that the whiteness and the brightness of the vamp to be cleaned can be improved, and the fading and yellowing can be counteracted.
8. Soap base
The soap base, also called soap particles, is a natural renewable surfactant, is usually composed of fatty acid substances and sodium hydroxide, is refined from vegetable oil, contains nutrient and moisturizing elements such as coconut oil, olive oil, palm oil, castor oil, glycerin and the like, and has the advantages of green source, high cleaning power, high water-bleaching property, antibacterial property, low cost and the like. The invention adds soap base, which can improve the decontamination performance. In the present invention, the soap base may be commercially available, for example, from Pelland Biotechnology (Shanghai) corporation.
9. Essence
The essence is added, so that the odor of the white shoe cleaning agent disclosed by the invention is fresh, and the white shoe cleaning agent is more easily accepted by consumers.
10. Biological enzymes
The biological enzyme is added, so that the decontamination performance can be improved, heavy dirt such as fruit stains, oil stains and the like can be directly decomposed, the dosage of the surfactant can be reduced, and the environmental pollution is reduced.
11. Basic compound
The alkaline compound is added to adjust the pH value of the white shoe cleaning agent.
The raw materials involved in the invention are all commercially available.
In conclusion, the small white shoe cleaning agent disclosed by the invention is added with two surfactants, namely the anionic surfactant and the nonionic surfactant, so that a large amount of fine foams can be generated, the specific surface area of the cleaning agent can be increased, the effects of permeation, emulsification, solubilization and dispersion are increased, and stains falling off by friction can be absorbed and taken away; the friction particles are added, so that the paint can be fully rubbed with stains, and the stain removing effect is better; the soapberry extract is added, so that the soap is natural, healthy, green and environment-friendly, and the dosage of the surfactant, the friction particles and the soap base is greatly reduced; the essence is added, so that the taste is fresh and the health of human bodies is benefited. The cleaning agent is compounded with the raw materials, can exert the cleaning and decontamination functions in a synergistic manner, is suitable for deep-layer stain removal and bright color protection of the white shoes, can ensure that the vamps of the white shoes to be cleaned have good service performance, have fresh smell and no volatile peculiar smell, do not irritate the skin, optic nerves and respiratory systems of human bodies, are environment-friendly and safe, and do not cause environmental pollution.
The white shoe cleaning agent has the beneficial effects that:
1. the white shoe cleaning agent disclosed by the invention can deeply remove stains, is bright and color-protecting, can ensure that the vamp to be cleaned has good service performance, has fresh smell and no volatile peculiar smell, does not irritate the skin, optic nerve and respiratory system of a human body, is environment-friendly and safe, and reduces the pollution to the environment.
2. The cleaning agent has the advantages of easily available raw materials, low cost, good cleaning effect and wide market prospect.
On the basis of the technical scheme, the invention can be further improved as follows.
Further, the feed is prepared from the following raw materials in parts by weight: 5 parts of anionic surfactant, 10 parts of nonionic surfactant, 5 parts of preservative, 40 parts of deionized water, 20 parts of soapberry extract, 15 parts of anti-settling agent, 35 parts of friction particles, 10 parts of fluorescent whitening agent, 5 parts of soap base, 8 parts of essence, 4 parts of biological enzyme and 3.5 parts of alkaline compound.
The adoption of the further beneficial effects is as follows: the above parameters are the optimal parameters, and the obtained white shoe cleaning agent has the optimal efficacy.
Further, the feed is prepared from the following raw materials in parts by weight: 7.5 parts of anionic surfactant, 7.5 parts of nonionic surfactant, 7.5 parts of preservative, 100 parts of deionized water, 15 parts of soapberry extract, 22.5 parts of anti-settling agent, 27.5 parts of friction particles, 7.5 parts of fluorescent whitening agent, 12.5 parts of soap base, 5.5 parts of essence, 4.5 parts of biological enzyme and 2.5 parts of alkaline compound.
The adoption of the further beneficial effects is as follows: the above parameters are the optimal parameters, and the obtained white shoe cleaning agent has the optimal efficacy.
Further, the feed is prepared from the following raw materials in parts by weight: 10 parts of anionic surfactant, 5 parts of nonionic surfactant, 10 parts of preservative, 160 parts of deionized water, 10 parts of soapberry extract, 30 parts of anti-settling agent, 20 parts of friction particles, 5 parts of fluorescent whitening agent, 20 parts of soap base, 3 parts of essence, 5 parts of biological enzyme and 1.5 parts of alkaline compound.
The adoption of the further beneficial effects is as follows: the above parameters are the optimal parameters, and the obtained white shoe cleaning agent has the optimal efficacy.
Further, the anionic surfactant is any one or a mixture of more than two of sodium alkyl benzene sulfonate, sodium alkyl polyoxyethylene ether sulfate, sodium alkyl sulfate, sodium fatty acid and sodium alkyl polyoxyethylene ether carboxylate.
The adoption of the further beneficial effects is as follows: the above substances can be used as anionic surfactant, and have the performances of decontamination, wetting, foaming, emulsification, dispersion, etc.
Still further, the anionic surfactant is sodium alkyl benzene sulfonate.
The further beneficial effects of the adoption are as follows: sodium alkyl benzene sulfonate with molecular formula of C18H29NaO3S, molecular weight 348.48, CAS number 5-30-0. The sodium alkyl benzene sulfonate has strong foaming capacity, is relatively stable in hard water and has good cleaning effect.
Further, the nonionic surfactant is any one or a mixture of more than two of fatty alcohol-polyoxyethylene ether, fatty acid-polyoxyethylene ester and polyoxyethylene alkylamine.
The further beneficial effects of the adoption are as follows: the above substances can be used as nonionic surfactant, and have solubilizing, antistatic, calcium soap dispersing, etc., low irritation, and excellent wetting and washing functions.
Further, the nonionic surfactant is fatty alcohol-polyoxyethylene ether.
The further beneficial effects of the adoption are as follows: fatty alcohol polyoxyethylene ether, also known as polyoxyethylene fatty alcohol ether, has the general formula RO (CH)2CH2O)nH, CAS number 68131-39-5.
Further, the preservative is isothiazolinone.
The adoption of the further beneficial effects is as follows: isothiazolinone of formula C8H9ClN2O2S2The molecular weight is 264.75, CAS number is 55965-84-9, and the bactericide is high-efficiency, low-alcohol and broad-spectrum.
Further, the friction particles are any one or a mixture of more than two of light calcium carbonate, magnesium oxide, aluminum hydroxide and calcium hydrophosphate.
The adoption of the further beneficial effects is as follows: all the substances can be used as friction particles for increasing the dirt removing capability of the cleaning agent on vamp stains.
Further, the light calcium carbonate is spherical.
The further beneficial effects of the adoption are as follows: the light calcium carbonate particles are regular in shape, can be regarded as monodisperse powder, and have various powder shapes, such as spindle shape, cubic shape, needle shape, chain shape, sheet shape, spherical shape and quadrangular prism shape, and have small particle size, and the average particle size is 1-3 μm. The applicant finds that the spherical light calcium carbonate has small particle size, large specific surface area and good solubility.
Further, the soapberry extract is a soapberry extract.
The adoption of the further beneficial effects is as follows: the soapberry fruit extract is adopted because the raw materials are low in price and the content of saponin substances is high.
Further, the anti-precipitating agent is propylene glycol alginate.
The adoption of the further beneficial effects is as follows: propylene Glycol Alginate, abbreviated as PGA, is called Propylene Glycol Alginate and Propylene Glycol Alginate in English. The molecular formula is (C)9H14O7) n, CAS number 9005-37-2. In the present invention, propylene glycol alginate is added as an anti-precipitant.
Further, the fluorescent whitening agent is any one or a mixture of more than two of white carbon black, a fluorescent whitening agent 393, a fluorescent whitening agent OB, a fluorescent whitening agent KCB, a fluorescent whitening agent KSN and a fluorescent whitening agent CBS-127.
The adoption of the further beneficial effects is as follows: white carbon black is a general term for white powdery X-ray amorphous silicic acid and silicate products, mainly referring to precipitated silica, fumed silica, ultrafine silica gel and aerogel, and also including powdery synthetic aluminum silicate, calcium silicate, and the like. The white carbon black is porous material, and its composition can be SiO2·nH2O represents, wherein nH2O is present in the form of surface hydroxyl groups.
The fluorescent whitening agent 393 with the chemical name of 2,2'- (4,4' -distyryl-) dibenzoxazole and the CAS number of 1533-45-5 and the molecular formula of C28H18N2O2。
Fluorescent brightener OB with chemical name of 2, 5-bis- (5-tert-butyl-2-benzoxazolyl) thiophene, CAS number of 7128-64-5 and molecular formula of C26H26N2O2S。
Fluorescent brightener KCB with chemical name of 1, 4-bis (benzoxazolyl-2-yl) naphthalene, CAS number of 5089-22-5 and molecular formula of C24H14N2O2。
The fluorescent whitening agent KSN has the chemical name of 4, 4-bis (5-methyl-2-benzoxazolyl) stilbene, the CAS number of 5242-49-9 and the molecular formula of C29H20N2O 2.
The fluorescent whitening agent CBS-127 has the chemical name of 4, 4-bis (2-methoxystyryl) biphenyl, the CAS number of 40470-68-6 and the molecular formula of C30H26O2。
Further, the fluorescent whitening agent is white carbon black.
The further beneficial effects of the adoption are as follows: white carbon black is used as the fluorescent whitening agent, so that the fluorescent whitening agent has the advantages of high whiteness, good solubility and dispersibility and high transparency, does not contain phosphorus element, and cannot cause environmental pollution.
Further, the essence is any one or a mixture of more than two of orange essential oil, rose essential oil and jasmine essential oil.
The adoption of the further beneficial effects is as follows: the substances have unique fragrance, can be used as essence, can make the odor of the white shoe cleaning agent fresh, and is more easily accepted by consumers.
Further, the essence is orange essential oil.
Further, the biological enzyme is one or a mixture of more than two of protease, lipase, amylase and cellulase, and the enzyme activity is 30000U/g-100000U/g.
The adoption of the further beneficial effects is as follows: the biological enzyme can directly decompose and decompose the heavy dirt such as fruit stain, oil stain and the like, improve the detergency and reduce the dosage of the surfactant.
Still further, the biological enzyme is a protease.
Further, the alkaline compound is any one of sodium hydroxide, sodium carbonate and sodium bicarbonate.
The adoption of the further beneficial effects is as follows: the above substances can be used for adjusting the pH value of the white shoe cleaning agent.
Still further, the basic compound is sodium hydroxide.
The second purpose of the invention is to provide a preparation method of the white shoe cleaning agent. The preparation method of the white shoe cleaning agent is simple, low in cost, easy to operate, wide in market prospect and suitable for large-scale popularization and application.
The scheme for solving the technical problems is as follows: a preparation method of a white shoe cleaning agent comprises the following steps:
step 1: respectively weighing the following raw materials in parts by weight: 5-10 parts of anionic surfactant, 5-10 parts of nonionic surfactant, 5-10 parts of preservative, 40-160 parts of deionized water, 10-20 parts of soapberry extract, 15-30 parts of anti-precipitant, 20-35 parts of friction particles, 5-10 parts of fluorescent brightener, 5-20 parts of soap base, 3-8 parts of essence, 4-5 parts of biological enzyme and 1.5-3.5 parts of alkaline compound;
step 2: sequentially putting an anionic surfactant, a nonionic surfactant and the soapberry extract into deionized water, and uniformly stirring to obtain a first mixture;
and step 3: adding an anti-precipitating agent, a soap base, a fluorescent whitening agent, essence, a biological enzyme and a preservative into the mixture I obtained in the step 2, and uniformly stirring to obtain a mixture II;
and 4, step 4: adding an aqueous solution of an alkaline compound into the mixture II obtained in the step 3 until the pH value is 6.8-7.2 to obtain a mixture III;
and 5: and (4) adding the friction particles into the mixture III obtained in the step (4), and uniformly stirring to obtain the small white shoe cleaning agent.
The preparation method of the white shoe cleaning agent has the beneficial effects that:
the preparation method of the white shoe cleaning agent is simple to operate, low in cost, wide in market prospect and suitable for large-scale popularization and application.
On the basis of the technical scheme, the invention can be further improved as follows.
Further, in the step 2, the step 3 and the step 5, the rotating speed of the stirring is 600r/min-1000r/min, and the time is 60min-100 min.
The adoption of the further beneficial effects is as follows: with the above parameters, the mixing is more uniform.
The specific use method of the small white shoe cleaning agent for cleaning the small white shoes comprises the following steps:
and (3) taking the small white shoe cleaning agent, directly spraying the small white shoe cleaning agent on the vamp of the small white shoe, or spraying the small white shoe cleaning agent on a shoe brush firstly, wetting the vamp, and repeatedly rubbing the shoe brush until stains disappear, thus finishing cleaning the small white shoe.
Detailed Description
The principles and features of this invention are described below in conjunction with specific embodiments, which are set forth merely to illustrate the invention and are not intended to limit the scope of the invention.
Example 1
The white shoe cleaning agent is prepared from the following raw materials in parts by weight: 5g of sodium alkyl benzene sulfonate, 10g of fatty alcohol-polyoxyethylene ether, 5g of isothiazolinone, 40g of deionized water, 20g of soapberry extract, 15g of propylene glycol alginate, 35g of magnesium oxide, 39310g of fluorescent whitening agent, 5g of soap base, 8g of rose essential oil, 4g of lipase with enzyme activity of 30000U/g and 3.5g of sodium carbonate.
The preparation method of the white shoe cleaning agent comprises the following steps:
step 1: respectively weighing the following raw materials by weight: 5g of sodium alkyl benzene sulfonate, 10g of fatty alcohol-polyoxyethylene ether, 5g of isothiazolinone, 40g of deionized water, 20g of soapberry extract, 15g of propylene glycol alginate, 35g of magnesium oxide, 39310g of fluorescent whitening agent, 5g of soap base, 8g of rose essential oil, 4g of lipase with enzyme activity of 30000U/g and 3.5g of sodium carbonate;
step 2: sequentially putting sodium alkyl benzene sulfonate, fatty alcohol-polyoxyethylene ether and soapberry extract into deionized water, and stirring at a rotation speed of 600r/min for 100min to obtain a first mixture;
and step 3: adding propylene glycol alginate, isothiazolinone, fluorescent whitening agent 393, soap base, rose essential oil and lipase into the mixture I obtained in the step 2, and stirring for 100min at the rotating speed of 600r/min to obtain a mixture II;
and 4, step 4: adding a sodium carbonate aqueous solution into the mixture II obtained in the step 3 until the pH value is 6.8 to obtain a mixture III;
and 5: and (4) adding magnesium oxide into the mixture III obtained in the step (4), and stirring at the rotating speed of 600r/min for 100min to obtain the small white shoe cleaning agent.
Example 2
The white shoe cleaning agent is prepared from the following raw materials in parts by weight: 7.5g of sodium alkyl sulfonate, 7.5g of polyoxyethylene fatty acid ester, 7.5g of isothiazolinone, 100g of deionized water, 15g of soapberry extract, 22.5g of propylene glycol alginate, 27.5g of spherical light calcium carbonate, 7.5g of white carbon black, 12.5g of soap base, 5.5g of orange essential oil, 4.5g of protease with the enzyme activity of 50000U/g and 2.5g of sodium hydroxide.
The preparation method of the white shoe cleaning agent comprises the following steps:
step 1: respectively weighing the following raw materials by weight: 5g of sodium alkylsulfonate, 10g of polyoxyethylene fatty acid ester, 5g of isothiazolinone, 40g of deionized water, 20g of soapberry extract, 15g of propylene glycol alginate, 35g of spherical light calcium carbonate, 10g of white carbon black, 5g of soap base, 8g of orange essential oil, 4g of protease with the enzyme activity of 50000U/g and 3.5g of sodium hydroxide;
step 2: sequentially putting the alkyl sodium sulfonate, the polyoxyethylene fatty acid ester and the soapberry extract into deionized water, and stirring for 80min at the rotating speed of 800r/min to obtain a first mixture;
and step 3: adding propylene glycol alginate, isothiazolinone, white carbon black, soap base, orange essential oil and protease into the mixture I obtained in the step 2, and stirring for 80min at the rotating speed of 800r/min to obtain a mixture II;
and 4, step 4: adding an aqueous solution of sodium hydroxide into the mixture II obtained in the step 3 until the pH value is 7.0 to obtain a mixture III;
and 5: and (4) adding spherical light calcium carbonate into the mixture III obtained in the step (4), and stirring at the rotating speed of 800r/min for 80min to obtain the small white shoe cleaning agent.
Example 3
The white shoe cleaning agent is prepared from the following raw materials in parts by weight: 10g of alkyl polyoxyethylene ether sodium sulfate, 5g of polyoxyethylene alkylamine, 10g of isothiazolinone, 160g of deionized water, 10g of soapberry extract, 30g of alginic acid propylene glycol ester, 20g of aluminum hydroxide, 5g of fluorescent whitening agent OB, 20g of soap base, 3g of jasmine essential oil, 5g of cellulase with enzyme activity of 100000U/g and 1.5g of sodium bicarbonate.
The preparation method of the white shoe cleaning agent comprises the following steps:
step 1: respectively weighing the following raw materials by weight: 5g of alkyl polyoxyethylene ether sodium sulfate, 10g of polyoxyethylene alkylamine, 5g of isothiazolinone, 40g of deionized water, 20g of soapberry extract, 15g of alginic acid propylene glycol ester, 35g of aluminum hydroxide, 10g of fluorescent whitening agent OB, 5g of soap base, 8g of jasmine essential oil, 4g of cellulase with enzyme activity of 100000U/g and 3.5g of sodium bicarbonate;
step 2: sequentially putting alkyl polyoxyethylene ether sodium sulfate, polyoxyethylene alkylamine and soapberry extract into deionized water, and stirring at the rotating speed of 1000r/min for 60min to obtain a first mixture;
and step 3: adding propylene glycol alginate, isothiazolinone, fluorescent whitening agent OB, soap base, jasmine essential oil and cellulase into the mixture I obtained in the step 2, and stirring for 60min at the rotating speed of 1000r/min to obtain a mixture II;
and 4, step 4: adding an aqueous solution of sodium bicarbonate into the mixture II obtained in the step 3 until the pH value is 7.2 to obtain a mixture III;
and 5: and (4) adding aluminum hydroxide into the mixture III obtained in the step (4), and stirring at the rotating speed of 1000r/min for 60min to obtain the small white shoe cleaning agent.
Comparative example 1
The difference from example 2 is that the raw material of this comparative example does not contain soapberry extract, and the rest is the same. Specifically, the white shoe cleaning agent of the comparative example is prepared from the following raw materials in parts by weight: 7.5g of sodium alkylsulfonate, 7.5g of polyoxyethylene fatty acid ester, 7.5g of isothiazolinone, 100g of deionized water, 22.5g of propylene glycol alginate, 27.5g of spherical light calcium carbonate, 7.5g of white carbon black, 12.5g of soap base, 5.5g of orange essential oil, 4.5g of protease with the enzyme activity of 50000U/g and 2.5g of sodium hydroxide.
The procedure of the preparation of the white shoe cleanser of this comparative example is the same as that of example 2.
Comparative example 2
The difference from example 2 is that the raw material of this comparative example does not contain a biological enzyme, and the rest is the same. Specifically, the white shoe cleaning agent of the comparative example is prepared from the following raw materials in parts by weight: 7.5g of sodium alkyl sulfonate, 7.5g of polyoxyethylene fatty acid ester, 7.5g of isothiazolinone, 100g of deionized water, 15g of soapberry extract, 22.5g of propylene glycol alginate, 27.5g of spherical light calcium carbonate, 7.5g of white carbon black, 12.5g of soap base, 5.5g of orange essential oil and 2.5g of sodium hydroxide.
The procedure of the preparation of the white shoe cleanser of this comparative example is the same as that of example 2.
Comparative example 3
The difference from example 2 was that the amount of the soapberry extract in the raw material of this comparative example was the same. Specifically, the white shoe cleaning agent of the comparative example is prepared from the following raw materials in parts by weight: 7.5g of sodium alkyl sulfonate, 7.5g of polyoxyethylene fatty acid ester, 7.5g of isothiazolinone, 100g of deionized water, 30g of soapberry extract, 22.5g of propylene glycol alginate, 27.5g of spherical light calcium carbonate, 7.5g of white carbon black, 12.5g of soap base, 5.5g of orange essential oil, 4.5g of protease with the enzyme activity of 50000U/g and 2.5g of sodium hydroxide.
The procedure of the preparation of the white shoe cleanser of this comparative example is the same as that of example 2.
Examples of the experiments
The white shoe cleaning agents prepared in examples 1 to 3 and comparative examples 1 to 3 were applied to a cleaning brush, and the upper with the same dirt area was wetted and the dirt was repeatedly rubbed with the cleaning brush until it disappeared. The areas of the shoe upper remaining soil were measured separately as shown in table 1.
TABLE 1
Figure BDA0003147679420000131
As can be seen from the above table, in examples 1 to 3, the remaining area of the upper dirt gradually decreased as the content of the soapberry extract in the raw material of the white shoe cleanser increased. The result shows that the content of the soapberry extract is increased, and the cleaning effect of the white shoe cleaning agent on the dirt on the surfaces of the shoes can be greatly improved.
Compared with the example 2, the cleaning agent for the small white shoes does not contain the soapberry extract, and the residual area of the dirt on the shoe uppers is slightly larger. This indicates that the stain removal performance was slightly poor without the addition of soapberry extract.
Compared with the example 2, the raw materials of the white shoe cleaning agent are not added with the biological enzyme, and the residual area of the dirt on the vamp is slightly larger. This indicates that the stain removal performance is slightly poor without the addition of bio-enzyme.
Compared with the example 2, the raw material of the small white shoe cleaning agent has high soapberry extract content, and the residual area of dirt on the vamp is small. This indicates that the soapberry extract is high in content and has strong detergency.
In conclusion, the white shoe cleaning agent can deeply remove stains, is bright and color-protecting, can ensure that the vamp to be cleaned has good service performance, has fresh smell, no volatile peculiar smell, no stimulation to the skin, optic nerve and respiratory system of a human body, is environment-friendly and safe, and reduces the pollution to the environment
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (10)

1. The small white shoe cleaning agent is characterized by being prepared from the following raw materials in parts by weight: 5-10 parts of anionic surfactant, 5-10 parts of nonionic surfactant, 5-10 parts of preservative, 40-160 parts of deionized water, 10-20 parts of soapberry extract, 15-30 parts of anti-precipitant, 20-35 parts of friction particles, 5-10 parts of fluorescent brightener, 5-20 parts of soap base, 3-8 parts of essence, 4-5 parts of biological enzyme and 1.5-3.5 parts of alkaline compound.
2. The small white shoe cleaning agent as claimed in claim 1, which is prepared from the following raw materials in parts by weight: 5 parts of anionic surfactant, 10 parts of nonionic surfactant, 5 parts of preservative, 40 parts of deionized water, 20 parts of soapberry extract, 15 parts of anti-settling agent, 35 parts of friction particles, 10 parts of fluorescent whitening agent, 5 parts of soap base, 8 parts of essence, 4 parts of biological enzyme and 3.5 parts of alkaline compound.
3. The small white shoe cleaning agent as claimed in claim 1, which is prepared from the following raw materials in parts by weight: 7.5 parts of anionic surfactant, 7.5 parts of nonionic surfactant, 7.5 parts of preservative, 100 parts of deionized water, 15 parts of soapberry extract, 22.5 parts of anti-settling agent, 27.5 parts of friction particles, 7.5 parts of fluorescent whitening agent, 12.5 parts of soap base, 5.5 parts of essence, 4.5 parts of biological enzyme and 2.5 parts of alkaline compound.
4. The small white shoe cleaning agent as claimed in claim 1, which is prepared from the following raw materials in parts by weight: 10 parts of anionic surfactant, 5 parts of nonionic surfactant, 10 parts of preservative, 160 parts of deionized water, 10 parts of soapberry extract, 30 parts of anti-settling agent, 20 parts of friction particles, 5 parts of fluorescent whitening agent, 20 parts of soap base, 3 parts of essence, 5 parts of biological enzyme and 1.5 parts of alkaline compound.
5. The shoe cleaning agent according to any one of claims 1 to 4, wherein the anionic surfactant is any one or a mixture of two or more of sodium alkylbenzenesulfonate, sodium alkylsulfonate, sodium alkylpolyoxyethylene ether sulfate, sodium alkylsulfate, sodium fatty acid, and sodium alkylpolyoxyethylene ether carboxylate; the nonionic surfactant is any one or a mixture of more than two of fatty alcohol-polyoxyethylene ether, fatty acid-polyoxyethylene ester and polyoxyethylene alkylamine.
6. The white shoe cleanser according to any one of claims 1 to 4, wherein the preservative is isothiazolinone; the soapberry extract is a soapberry extract; the anti-precipitating agent is propylene glycol alginate.
7. The small white shoe cleaner according to any one of claims 1 to 4, wherein the abrasive particles are any one or a mixture of two or more of light calcium carbonate, magnesium oxide, aluminum hydroxide and calcium hydrogen phosphate; the fluorescent whitening agent is any one or a mixture of more than two of white carbon black, a fluorescent whitening agent 393, a fluorescent whitening agent OB, a fluorescent whitening agent KCB, a fluorescent whitening agent KSN and a fluorescent whitening agent CBS-127.
8. The white shoe cleanser of claim 7, wherein said light calcium carbonate is spherical; the essence is orange essential oil; the fluorescent whitening agent is white carbon black; the biological enzyme is protease; the alkaline compound is any one of sodium hydroxide, sodium carbonate and sodium bicarbonate.
9. A process for preparing a white shoe cleaning composition according to any one of claims 1 to 8, comprising the steps of:
step 1: respectively weighing the following raw materials in parts by weight: 5-10 parts of anionic surfactant, 5-10 parts of nonionic surfactant, 5-10 parts of preservative, 40-160 parts of deionized water, 10-20 parts of soapberry extract, 15-30 parts of anti-precipitant, 20-35 parts of friction particles, 5-10 parts of fluorescent brightener, 5-20 parts of soap base, 3-8 parts of essence, 4-5 parts of biological enzyme and 1.5-3.5 parts of alkaline compound;
step 2: sequentially putting an anionic surfactant, a nonionic surfactant and the soapberry extract into deionized water, and uniformly stirring to obtain a first mixture;
and step 3: adding an anti-precipitating agent, a soap base, a fluorescent whitening agent, essence, a biological enzyme and a preservative into the mixture I obtained in the step 2, and uniformly stirring to obtain a mixture II;
and 4, step 4: adding an aqueous solution of an alkaline compound into the mixture II obtained in the step 3 until the pH value is 6.8-7.2 to obtain a mixture III;
and 5: and (4) adding the friction particles into the mixture III obtained in the step (4), and uniformly stirring to obtain the small white shoe cleaning agent.
10. The preparation method of the white shoe cleaning agent according to claim 9, wherein in the steps 2, 3 and 5, the rotation speed of the stirring is 600r/min-1000r/min, and the time is 60min-100 min.
CN202110756341.1A 2021-07-05 2021-07-05 Small white shoe cleaning agent and preparation method thereof Pending CN113637538A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009033248A1 (en) * 2009-07-14 2010-05-06 Henkel Ag & Co. Kgaa Washing- or cleaning agent, useful for cleaning highly functional materials, preferably polyester sports- and hiking clothes and sports shoes, comprises a soil-repellent, a protease, a bleaching agent and a perfume
CN106336959A (en) * 2016-08-26 2017-01-18 广州市加茜亚化妆品有限公司 Natural active washing composition and preparation method thereof
CN110857409A (en) * 2018-08-25 2020-03-03 陈勇 Shoe cleaning agent
CN111019771A (en) * 2019-12-26 2020-04-17 徐培城 Shoe cleaning agent containing friction particles

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009033248A1 (en) * 2009-07-14 2010-05-06 Henkel Ag & Co. Kgaa Washing- or cleaning agent, useful for cleaning highly functional materials, preferably polyester sports- and hiking clothes and sports shoes, comprises a soil-repellent, a protease, a bleaching agent and a perfume
CN106336959A (en) * 2016-08-26 2017-01-18 广州市加茜亚化妆品有限公司 Natural active washing composition and preparation method thereof
CN110857409A (en) * 2018-08-25 2020-03-03 陈勇 Shoe cleaning agent
CN111019771A (en) * 2019-12-26 2020-04-17 徐培城 Shoe cleaning agent containing friction particles

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