CN113633579B - Color-locking hair-care essential oil and preparation method thereof - Google Patents

Color-locking hair-care essential oil and preparation method thereof Download PDF

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CN113633579B
CN113633579B CN202110933393.1A CN202110933393A CN113633579B CN 113633579 B CN113633579 B CN 113633579B CN 202110933393 A CN202110933393 A CN 202110933393A CN 113633579 B CN113633579 B CN 113633579B
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CN113633579A (en
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黄加将
黄胜珠
黄珍珠
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Guangzhou Sluj Special Chemical Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585Organosilicon compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/002Preparations for repairing the hair, e.g. hair cure
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18

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Abstract

The application relates to the field of cosmetics, and particularly discloses color-locking hair-care essential oil and a preparation method thereof. The color-locking hair-care essential oil comprises bis-aminopropyl polydimethylsiloxane, crambe abyssinica seed oil, argania spinosa kernel oil, cyclopentadimethylsiloxane, a thickening agent and a softening agent. The preparation method comprises the following steps: firstly, mixing cyclopentadimethylsiloxane, crambe shepherd's purse seed oil and acanthus seed oil in deep sea, and uniformly stirring to obtain a mixed solution; then, preparing a softener; and finally, mixing the bis-aminopropyl polydimethylsiloxane, the thickening agent and the softening agent with the mixed solution, and uniformly stirring to obtain the color-locking hair-care essential oil. This application has the advantage that promotes the lock look utility of hair care essential oil.

Description

Color-locking hair-care essential oil and preparation method thereof
Technical Field
The invention relates to the field of cosmetics, in particular to color-locking hair-care essential oil and a preparation method thereof.
Background
The hair care essential oil refers to an oil-based raw material derived from natural plants, and with the improvement of living standard, the pursuit of people for beauty and hairdressing is continuously increased, and the hair care essential oil becomes an important product for hair care.
For people who often have hair dyeing, the hair care essential oil is often needed to be used for maintaining damaged hair, the hair care essential oil on the market at present mainly aims at the problems of hair moistening and repairing, can promote the propagation and growth of hair cells, activate hair follicle cells and repair damaged cell tissues of the hair, but the locking effect of the hair care essential oil on pigment particles in hair after hair dyeing is not strong, after multiple times of washing, the artificial pigment particles in the hair are washed, and the dyed hair still cannot keep the color for a long time. In response to this phenomenon, the inventors considered that the color-locking function of the hair care essential oil with respect to the dyed particles in the hair is yet to be further enhanced.
Disclosure of Invention
In order to improve the color-locking effect of the hair-care essential oil, the application provides the color-locking hair-care essential oil and a preparation method thereof.
In a first aspect, the application provides a color-locking hair-care essential oil which adopts the following technical scheme:
the color-locking hair-care essential oil comprises the following components in parts by weight:
5-15 parts of bis-aminopropyl polydimethylsiloxane;
35-53 parts of cyclopentasiloxane;
0.5-1.5 parts of abyssal sea purse seed oil;
0.5-1.5 parts of acanthus seed oil;
4-12 parts of a thickening agent;
26-44 parts of a softener.
Preferably, the composition comprises the following components in parts by weight:
8-12 parts of bis-aminopropyl polydimethylsiloxane;
40-48 parts of cyclopentadimethylsiloxane;
0.8-1.2 parts of deep sea two-section camelina sativa seed oil;
0.8-1.2 parts of argania spinosa kernel oil;
6-10 parts of a thickening agent;
31-39 parts of a softener.
By adopting the technical scheme, the hydrophobic mucous membrane with stronger ductility is formed under the combined action of the cyclopentadidimethyl siloxane, the crambe shepherd's purse oil and the argania spinosa kernel oil, when the essential oil is used, the hydrophobic mucous membrane can permeate into hair scales of hair, and then the hydrophobic mucous membrane is stuck to the outer surfaces of a plurality of pigment particles covered in the hair scales to form a plurality of hydrophobic pigment clusters, so that the pigment particles are isolated from moisture, the problem that the pigment particles fall off from the hair along with water flow flushing is reduced, and the color locking capability of the essential oil is further improved.
Preferably, the softener is prepared by mixing cyclohexasiloxane and dimethiconol.
By adopting the technical scheme, a layer of adsorption film which is good in ductility and easy to spread can be formed under the combined action of the polydimethylsiloxane alcohol and the cyclohexasiloxane, certain adsorption and fusion can be carried out between the adsorption film and a hydrophobic mucous membrane formed by the cyclopentadimethylsiloxane, the crambe abyssinica seed oil and the argania spinosa kernel oil, and a plurality of hydrophobic color clusters are fused on the adsorption film, so that the associativity among the hydrophobic color clusters is enhanced, the stability of the hydrophobic color clusters in the hair scales is enhanced, and the color locking effect of the essential oil is improved.
Preferably, the softener is prepared by mixing cyclohexasiloxane and butyl myristate.
By adopting the technical scheme, a layer of continuous adsorption film can be formed under the combined action of the butyl myristate and the cyclohexasiloxane, certain adsorption and fusion can be carried out between the adsorption film and a hydrophobic mucous membrane formed by the cyclopentadimethylsiloxane, the crambe oil in deep sea and the argania spinosa kernel oil, and a plurality of hydrophobic color clusters are fused on the adsorption film, so that the coupling property between the hydrophobic color clusters is enhanced, the stability of the hydrophobic color clusters in the hair scales is enhanced, and the color locking effect of the essential oil is improved.
Preferably, the softener is prepared by mixing cyclohexasiloxane and butyl myristate in a mass ratio of (1.2-1.5): 1.
By adopting the technical scheme, when the cyclohexasiloxane and the butyl myristate are mixed according to a certain proportion, the adsorption film structure formed by the combined action of the cyclohexasiloxane and the butyl myristate is compact, the extensibility is good, the adsorption property with the hydrophobic mucous membrane is strong, the fusion degree is high, and the improvement on the stability of the hydrophobic color clusters in the hair and hair scales is more obvious.
Preferably, the thickener is a vinyl dimethicone/methicone silsesquioxane crosspolymer.
By adopting the technical scheme, the vinyl groups in the vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer can enable the high molecular chains to be easily cross-linked, so that the adhesive property between the adsorption membrane and the hydrophobic mucous membrane is increased, and the viscosity of raw materials such as bis-aminopropyl polydimethylsiloxane and the like can be improved; the polymethylsiloxane silsesquioxane has good oleophylic property, so that the connectivity between the adsorption film and the hydrophobic mucous membrane is enhanced, and the color locking effect of the essential oil is further enhanced; the vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer plays an important role in improving the connectivity between the adsorption membrane and the hydrophobic mucous membrane and adjusting the viscosity of essential oil.
Preferably, 0.5-1.5 parts by weight of essence is also included.
Through adopting above-mentioned technical scheme, the use of essence can make essential oil have multiple fragrant smell, and essential oil has fragrant smell and can promote user's use sense.
In a second aspect, the application provides a preparation method of the color-locking hair-care essential oil, which adopts the following technical scheme:
a preparation method of the color-locking hair-care essential oil comprises the following steps:
s1, mixing cyclopentadimethylsiloxane, crambe shepherd' S purse seed oil and acanthus seed oil in deep sea, and uniformly stirring to obtain a mixed solution;
s2, preparing a softener;
and S3, mixing the bis-aminopropyl polydimethylsiloxane, the thickening agent and the softening agent with the mixed solution, and uniformly stirring to obtain the color-locking hair-care essential oil.
By adopting the technical scheme, firstly, cyclopentadimethylsiloxane, crambe shepherd's purse seed oil in deep sea and argan tree seed oil are uniformly mixed and fully combined, so that other raw material molecules are prevented from entering cyclopentadimethylsiloxane with good compatibility to be combined with cyclopentadimethylsiloxane to reduce the film forming rate of a hydrophobic mucous membrane; then preparing the softener to reduce the influence of other raw material molecules on the performance of the softener; and finally, uniformly mixing the mixed solution, the softener, the bis-aminopropyl polydimethylsiloxane and the thickening agent integrally to obtain the color-locking and hair-protecting essential oil.
Preferably, essence is further added in the S3.
By adopting the technical scheme, the essence is added at last, so that the essential oil is fragrant, and the influence of the components in the essence on other raw material substances in the essential oil is reduced.
In summary, the present application has the following beneficial effects:
1. the cyclopentadimethylsiloxane, the crambe abyssinica seed oil and the argania spinosa seed oil are mixed according to a certain proportion, a hydrophobic mucous membrane with strong ductility can be formed under the interaction of the cyclopentadimethylsiloxane, the crambe abyssinica seed oil and the argania spinosa seed oil, when the essential oil is used, the hydrophobic mucous membrane can be adhered to the outer surface of pigment particles in hair, the pigment particles are isolated from water, and hydrophobic pigment clusters are formed, so that the problem that the pigment particles fall off from the hair along with water flow flushing is solved, and the color locking capability of the essential oil is improved;
2. the cyclohexasiloxane and butyl myristate interact and generate an adsorption film, the adsorption film adsorbs a plurality of hydrophobic color clusters, and the outer hydrophobic mucous membrane of the hydrophobic color clusters and the adsorption film are fused to a certain extent, so that the associativity among the hydrophobic color clusters is improved, the stability of the hydrophobic color clusters in the hairline is improved, and the color locking performance of the essential oil is improved.
Detailed Description
The present application will be described in further detail with reference to examples.
The source information of the raw materials used in the following examples and comparative examples is detailed in table 1.
TABLE 1
Figure BDA0003211921830000031
Figure BDA0003211921830000041
Examples
Examples 1 to 5
A color-locking hair-care essential oil and a preparation method of the hair-care essential oil comprise the following steps:
s1, mixing cyclopentadimethylsiloxane, crambe shepherd' S purse seed oil and acanthus seed oil, adding the mixture into a stirring emulsifying pot, and stirring for 5 minutes at normal temperature and at the rotating speed of 4500r/min to obtain a mixed solution;
s2, adding butyl stearate into a stirring emulsifying pot, and stirring for 3 minutes at normal temperature and at the rotating speed of 4500r/min to obtain a softener;
and S3, mixing the bis-aminopropyl polydimethylsiloxane, the sodium carboxymethyl cellulose solvent, the softener and the mixed solution, adding into a stirring emulsifying pot, and stirring for 5 minutes at the normal temperature and at the rotating speed of 4800r/min to obtain the color-locking hair-care essential oil.
The amounts (unit: kg) of the respective raw material components of examples 1 to 5 are specified in tables 2 and 3.
TABLE 2
Figure BDA0003211921830000051
Example 6
A method for preparing color-locking hair-care essential oil, which is different from the method in example 5 in that: in S2, 35kg of butyl stearate is replaced by 11.7kg of cyclohexasiloxane and 23.3kg of dimethiconol, namely the cyclohexasiloxane and the dimethiconol are added into a stirring emulsifying pot according to the mass ratio of 0.5.
Example 7
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: in S2, 35kg of butyl stearate is replaced by 11.7kg of cyclohexasiloxane and 23.3kg of butyl myristate, namely the cyclohexasiloxane and the butyl myristate are added into a stirring emulsifying pot according to the mass ratio of 0.5.
Example 8
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: in S2, 35kg of butyl stearate is replaced by 19.1kg of cyclohexasiloxane and 15.9kg of butyl myristate, namely the cyclohexasiloxane and the butyl myristate are added into a stirring emulsifying pot according to the mass ratio of 1.2.
Example 9
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: in S2, 35kg of butyl stearate is replaced by 21.0kg of cyclohexasiloxane and 14.0kg of butyl myristate, namely the cyclohexasiloxane and the butyl myristate are added into a stirring emulsifying pot according to the mass ratio of 1.5.
Example 10
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: in S3, 8.0kg of sodium carboxymethylcellulose solvent was replaced with 8.0kg of vinyl dimethicone/methicone silsesquioxane crosspolymer.
Examples 11 to 13
A preparation method of the color-locking hair-care essential oil comprises the following steps:
s1, mixing cyclopentadimethylsiloxane, crambe abyssinica seed oil and argania spinosa seed oil, adding into a stirring emulsifying pot, and stirring for 5 minutes at normal temperature and at the rotating speed of 4500r/min to obtain a mixed solution;
s2, adding the cyclohexasiloxane and the butyl myristate into a stirring emulsifying pot according to the mass ratio of (1.2-1.5) to 1, and stirring for 3 minutes at normal temperature and at the rotating speed of 4500r/min to obtain a softener;
and S3, mixing the bis-aminopropyl polydimethylsiloxane, the vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer, the softener and the mixed solution, adding into a stirring emulsifying pot, and stirring for 5 minutes at the normal temperature and at the rotating speed of 4800r/min to obtain the color-locking hair-care essential oil.
The amounts (unit: kg) of the respective raw material components of examples 11 to 13 are specified in Table 3.
TABLE 3
Figure BDA0003211921830000061
Comparative example
Comparative example 1
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: 44.0kg of cyclopentasimethicone is replaced by 22.0kg of crambe abyssinica seed oil and 22.0kg of argania spinosa seed oil.
Comparative example 2
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: the two sections of the seed oil of the camelina sativa in the deep sea are replaced by the same amount of argania spinosa kernel oil.
Comparative example 3
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: replacing the acanthus spinosus kernel oil with two sections of camelina sativa seed oil in the same amount.
Comparative example 4
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: replacing cyclopentadimethylsiloxane and the seed oil of the two sections of the Capsella bursa-pastoris with the same amount of the seed oil of the Aralia elata seem.
Comparative example 5
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: replacing cyclopentadimethylsiloxane and Aralia mandshurica kernel oil with equal amount of the seed oil of two sections of the deep sea camelina sativa.
Comparative example 6
A method for preparing a color-locking hair-care essential oil, which is different from the method in example 5 in that: the two sections of the camelina sativa seed oil and the argania spinosa seed oil in the deep sea are replaced by equal amount of cyclopentadimethylsiloxane.
Performance test
1. Color locking detection: a section of real hair sample is cut from a hair die, washed and dried by deionized water, and then the sample is dyed by the same red hair dye, 15g of the hair dye is used for dyeing three times each time, and 15 minutes is used for dyeing each time; comparing the dyed color of the sample with the 1797C standard chroma in an RAL international color number comparison table, and recording the initial l, a and b values of the sample; then dividing the sample into two parts, marking the two parts as a sample A and a sample B, uniformly coating the color-locking hair-care essential oil prepared in the embodiment 1 on the sample A, massaging for 5 minutes, washing and drying the sample A by using clear water, and washing and drying the sample B by using the same amount of clear water; and then washing the sample A and the sample B with the same amount of the same shampoo for one time, washing after washing and drying, recording the values of l, a and B detected by a spectrophotometer after the sample A and the sample B are washed for five times and washed for ten times respectively, and finishing the color locking detection test. The essential oils obtained in examples 1 to 10 and comparative examples 1 to 4 were subjected to a color-locking test one by one.
In particular, in the spectrophotometer, l represents the brightness (black and white), a represents red and green, and b represents yellow and blue; the value of l is positive, indicating that the sample is brighter than the standard plate; if the value is a negative value, the value is dark;
the value of a is positive, indicating that the sample is redder than the standard plate; if the value is negative, the value is greenish;
the value of b is positive, which indicates that the sample is more yellow than the standard plate; if the value is negative, the color is blue;
the detailed assay data for the experiments are detailed in tables 4-7 (Δ = sample value-initial value).
TABLE 4
Figure BDA0003211921830000081
According to the detection data of examples 1-5 in Table 4, in the same batch of samples, the values of delta l and delta a are negative numbers, the glossiness of the samples is reduced, and the reddening of the color is declined; the Δ b value is positive and the sample color shifts toward the hair primary tan. The samples A applied with the essential oils obtained in examples 1 to 5 had larger Deltals and Deltaa than those of the samples B not applied with the essential oils; the Δ B value of the sample A is smaller than the Δ B value of the sample B, which indicates that the change range of the values of the value l, the value a and the value B of the same initial value of the sample A coated with the essential oil prepared in examples 1-5 is smaller than that of the value l, the value a and the value B of the same initial value of the sample B not coated with the essential oil, the gloss reduction rate of the sample A coated with the essential oil prepared in examples 1-5 is slower, the hair fading speed is slower, and the essential oil prepared in examples 1-5 has good color locking capability. And as the number of washing times increases, the difference between the value of the sample a and the value of the sample B increases, and the color locking efficacy of the essential oils prepared in examples 1 to 5 is more remarkable.
Comparing the variation ranges of the values of the sample A, the value a and the value b of the initial comparison value of the sample A in different batches shows that the variation range of the value A of the sample A coated with the essential oil prepared in the examples 3 and 4 is smaller than that of the sample A coated with the essential oil prepared in the examples 1 and 2, which indicates that the color locking capability of the essential oil prepared in the examples 3 and 4 is stronger than that of the essential oil prepared in the examples 1 and 2, and the variation range of the value A of the sample A coated with the essential oil prepared in the example 5 is the smallest compared with that of the initial comparison value, which indicates that the color locking capability of the essential oil prepared in the example 5 is the best.
The inventor analyzes and considers that the components adopted by the raw materials in the example 5 have better associativity among the raw materials in the essential oil, and the synergistic effect among the cyclopentadimethylsiloxane, the crambe abyssinica seed oil and the argania spinosa kernel oil is better, so that the color locking effect of the essential oil is more remarkable.
TABLE 5
Figure BDA0003211921830000091
Figure BDA0003211921830000101
According to the detection data of comparative examples 1 to 6 in table 5, in the same batch of samples, the change ranges of the l value, the a value and the B value of the samples a and B coated with the essential oils prepared in comparative examples 1 to 6 compared with the initial values of the samples are similar, which shows that the gloss reduction rate of the samples a and B coated with the essential oils prepared in comparative examples 1 to 6 are similar, and the hair fading speed is similar, and the obvious change ranges of the l value, the a value and the B value of the samples a and B coated with the essential oils prepared in example 5 compared with the initial values of the samples are similar, which shows that the essential oils prepared in comparative examples 1 to 6 have weaker color locking capability and far less lasting color locking effect.
The inventor analyzes and considers that the crambe abyssinica seed oil and the crambe spinosa seed oil penetrate into hair scales of hair, and the crambe abyssinica seed oil molecules are used as nonionic surfactants, so that the surface activation energy of pigment particles can be reduced, and hydrophobic mucous membranes can be favorably adhered to the surfaces of the pigment particles; the argania spinosa kernel oil molecules have good flexibility, so that the hydrophobic mucous membrane has good ductility, the hydrophobic mucous membrane can coat pigment particles in a larger range, cyclopentadidimethyl siloxane has excellent hydrophobicity and is a source of hydrophobic characteristics of the hydrophobic mucous membrane, the hydrophobic mucous membrane generated by the combined action of the cyclopentadidimethyl siloxane, the water and the water molecules coats the pigment particles into a plurality of hydrophobic pigment particle groups in the hair scales, the effect of blocking the pigment particles and the water molecules is achieved, the phenomenon that the pigment particles are lost from the hair scales along with the water molecules is reduced, the pigment particles are stabilized in the hair scales, and the essential oil has color locking capability.
TABLE 6
Figure BDA0003211921830000102
Figure BDA0003211921830000111
According to the test data of examples 5 to 9 in table 6, it can be seen that by comparing the variation ranges of the value l, the value a and the value b of the initial value of the comparison of the sample a in different batches, the variation range of the value of the sample a coated with the essential oil obtained in example 5 is larger than that of the sample a coated with the essential oil obtained in examples 6 to 9, which indicates that the effect of the butyl stearate as the softener on the color-locking effect of the essential oil is smaller in example 5, and the effect of the mixture of cyclohexasiloxane and dimethiconol as the softener in example 6 or the mixture of cyclohexasiloxane and butyl myristate as the softener in examples 7 to 9 on the color-locking effect of the essential oil is better.
The numerical variation range of the sample A coated with the essential oil prepared in example 6 is larger than that of the sample A coated with the essential oil prepared in example 7, which shows that the gain effect on the color locking effect of the essential oil generated by using the mixture of the cyclohexasiloxane and the dimethiconol as the softener is smaller than the gain effect on the color locking effect of the essential oil generated by using the mixture of the cyclohexasiloxane and the butyl myristate as the softener.
The range of values for sample a applied with the essential oil obtained in example 7 was greater than the range of values for sample a applied with the essential oils obtained in examples 8 and 9, indicating that the essential oil obtained in example 7 in a ratio of the mass ratio cyclohexasiloxane to butyl myristate of 0.5.
The inventor analyzes that the cyclohexasiloxane and the dimethiconol can be mixed to form an adsorption film with better ductility, the adsorption film and a hydrophobic mucous membrane formed by cyclopentadimethicone, crambe abyssinica seed oil and argania spinosa seed oil are adsorbed and fused to a certain extent, and a plurality of hydrophobic color clusters are fused on the adsorption film, so that the coupling property among the hydrophobic color clusters is enhanced, the stability of the hydrophobic color clusters in the hair scales is enhanced, and the color locking effect of the essential oil is improved.
When the cyclohexasiloxane and the butyl myristate are mixed and act together, a continuous adsorption film can be formed, particularly, when the cyclohexasiloxane and the butyl myristate act together within the mass ratio range of (1.2-1.5): 1, the butyl myristate and the cyclohexasiloxane can be fully combined to form the adsorption film, the structural performance of the adsorption film is better, the adsorption strength is greater than that of the adsorption film formed by mixing the cyclohexasiloxane and the dimethiconol, the coupling property between hydrophobic color clusters can be better enhanced, and the color locking effect of the essential oil is improved; beyond this range: the bonding rate of the cyclohexasiloxane and butyl myristate is reduced, and the number of generated adsorption films is small; more cyclohexasiloxane exists, and the self-lubricating property of the cyclohexasiloxane reduces the adsorbability of an adsorption film formed by the cyclohexasiloxane and the cyclohexasiloxane, so that the cyclohexasiloxane and the adsorption film are not favorable for adsorbing hydrophobic color clusters.
TABLE 7
Figure BDA0003211921830000121
From the test data in Table 7, example 5 and example 10, it can be seen that the range of values for sample A for the essential oil obtained in example 5 was greater than the range of values for sample A for the essential oil obtained in example 10, indicating that the color locking ability of the essential oil obtained in example 5 using sodium carboxymethylcellulose as the thickening agent was less strong than that of the essential oil obtained in example 10 using the polyvinyldimethicone/polymethylsilsesquioxane crosspolymer as the thickening agent.
The inventor analyzes and considers that compared with other thickening agents, the vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer has a better effect of enhancing the adhesion between the adsorption film and the hydrophobic mucous membrane, so that the color locking effect of the essential oil is better enhanced, the connectivity among raw materials in the essential oil is improved, and the essential oil is durable.
TABLE 8
Figure BDA0003211921830000131
According to the test data of example 5 and examples 11 to 13 in Table 8, it can be seen that the range of the value of sample A applied with the essential oils obtained in examples 11 to 13 is smaller than that of sample A applied with the essential oil obtained in example 5 by comparing the variation ranges of the value of sample A to the value of the initial value of value l, value a and value b in different batches, which indicates that the color-locking ability of the essential oils obtained in examples 11 to 13 is stronger than that of the essential oil obtained in example 5.
The inventor analyzes and considers that the raw materials in the embodiments 11 to 13 have good combined connection effect, the hydrophobic mucous membrane generated by the synergistic effect of the cyclopentadienylmethane siloxane, the crambe's purse oil and the argania spinosa kernel oil has more comprehensive coating on pigment particles in hair, the color locking capability is stronger, the adsorption membrane generated by the synergistic effect of the cyclohexasiloxane and the butyl myristate has obvious gain effect on the hydrophobic mucous membrane, the color locking effect of the essential oil is further improved, and the thickener and the bis-aminopropyl polydimethylsiloxane in the raw materials play good roles, so that the better embodiment of the application is obtained.
The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.

Claims (9)

1. The color-locking hair care essential oil is characterized in that: the paint comprises the following components in parts by weight:
5-15 parts of bis-aminopropyl polydimethylsiloxane;
35-53 parts of cyclopentasiloxane;
0.5-1.5 parts of abyssal sea purse seed oil;
0.5-1.5 parts of acanthus seed oil;
4-12 parts of a thickening agent;
26-44 parts of a softener.
2. The color-locking hair care essential oil according to claim 1, which is characterized in that: the paint comprises the following components in parts by weight:
8-12 parts of bis-aminopropyl polydimethylsiloxane;
40-48 parts of cyclopentadimethylsiloxane;
0.8-1.2 parts of deep sea two-section camelina sativa seed oil;
0.8-1.2 parts of acanthus seed oil;
6-10 parts of a thickening agent;
31-39 parts of a softener.
3. The color-locking hair care essential oil according to claim 1 or 2, which is characterized in that: the softener is prepared by mixing cyclohexasiloxane and dimethiconol.
4. The color-locking hair care essential oil according to claim 1 or 2, which is characterized in that: the softener is prepared by mixing cyclohexasiloxane and butyl myristate.
5. The color-locking hair-care essential oil according to claim 4, which is characterized in that: the softener is prepared by mixing cyclohexasiloxane and butyl myristate according to the mass ratio of (1.2-1.5) to 1.
6. A color-locking hair care essential oil according to claim 1 or 2, which is characterized in that: the thickening agent is vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer.
7. A color-locking hair care essential oil according to claim 1 or 2, which is characterized in that: also comprises 0.5 to 1.5 weight parts of essence.
8. A process for the preparation of a color-locking hair care essential oil according to any one of claims 1 to 6, comprising the steps of:
s1, mixing cyclopentadimethylsiloxane, crambe shepherd' S purse seed oil and acanthus seed oil in deep sea, and uniformly stirring to obtain a mixed solution;
s2, preparing a softener;
and S3, mixing the bis-aminopropyl polydimethylsiloxane, the thickening agent and the softening agent with the mixed solution, and uniformly stirring to obtain the color-locking hair-care essential oil.
9. The method for preparing the color-locking hair-care essential oil according to claim 8, which is characterized by comprising the following steps: essence is also added in the S3.
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CN104224634A (en) * 2014-09-30 2014-12-24 澳宝化妆品(惠州)有限公司 Hair conditioning combination and application thereof in hair conditioning products
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