CN113621949A - Aluminum alloy surface treatment process - Google Patents

Aluminum alloy surface treatment process Download PDF

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Publication number
CN113621949A
CN113621949A CN202110740457.6A CN202110740457A CN113621949A CN 113621949 A CN113621949 A CN 113621949A CN 202110740457 A CN202110740457 A CN 202110740457A CN 113621949 A CN113621949 A CN 113621949A
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Prior art keywords
concentration
cleaning
aluminum material
material treated
aluminum alloy
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CN202110740457.6A
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Chinese (zh)
Inventor
黄卫
张龙
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Zhengzhou Hengrui Precision Machinery Technology Co ltd
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Zhengzhou Hengrui Precision Machinery Technology Co ltd
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Priority to CN202110740457.6A priority Critical patent/CN113621949A/en
Publication of CN113621949A publication Critical patent/CN113621949A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F3/00Brightening metals by chemical means
    • C23F3/02Light metals
    • C23F3/03Light metals with acidic solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/1803Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
    • C23C18/1824Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
    • C23C18/1837Multistep pretreatment
    • C23C18/1844Multistep pretreatment with use of organic or inorganic compounds other than metals, first
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/52Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating using reducing agents for coating with metallic material not provided for in a single one of groups C23C18/32 - C23C18/50
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C23G1/22Light metals

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention discloses an aluminum alloy surface treatment process, which comprises the following steps: s1, immersion cleaning and washing: adopting an organic solvent for immersion cleaning, cleaning by using a mixed solution, and removing attachments such as oil stains and the like on the surface of the aluminum material; s2, polishing: polishing the aluminum material treated by the S1 in a mixed solution of phosphoric acid and glacial acetic acid to obtain a smooth plane; s3, oil removal: putting the aluminum material treated by the S2 in alkali liquor for oil removal treatment, and cleaning the surface; s4, activation: the aluminum material treated by the S3 is put into an acid activating solution for treatment to ensure the bonding force; s5, zinc dipping: soaking the aluminum material treated by the S4 in a zinc dipping solution; s6, washing: cleaning the aluminum material treated by the S5; after the surface of the aluminum alloy material is treated by the process, the welding strength of the welding part is enhanced, so that the strength of the aluminum radiator is greatly improved, the process is convenient to process, the process flow has short consumption time, and the working efficiency is high.

Description

Aluminum alloy surface treatment process
Technical Field
The invention belongs to the technical field of metal surface treatment processes, and particularly relates to an aluminum alloy surface treatment process.
Background
Aluminum and aluminum alloy have small density, high specific strength, good welding performance, easy processing and beautiful surface, and are the second most metal materials for industry at present, second to steel. The aluminum alloy has wide application in the fields of aerospace, food packaging, architectural decoration, electronic home appliances, transportation and the like. The battery radiator of the electric automobile is also generally made of aluminum alloy materials.
At present, aluminum radiators are widely regarded due to the obvious advantages of the aluminum radiators in light weight, copper radiators are gradually replaced in many fields, but after radiator parts made of aluminum alloy materials are welded, the connection strength of the radiator parts is different from that of the traditional copper welded parts.
Disclosure of Invention
The invention aims to: provides an aluminum alloy surface treatment process, aiming at solving the problems mentioned in the background technology.
The technical scheme adopted by the invention is as follows: an aluminum alloy surface treatment process comprises the following steps:
s1, immersion cleaning and washing: adopting an organic solvent for immersion cleaning, cleaning by using a mixed solution, and removing attachments such as oil stains and the like on the surface of the aluminum material;
s2, polishing: polishing the aluminum material treated by the S1 in a mixed solution of phosphoric acid and glacial acetic acid to obtain a smooth plane;
s3, oil removal: putting the aluminum material treated by the S2 in alkali liquor for oil removal treatment, and cleaning the surface;
s4, activation: the aluminum material treated by the S3 is put into an acid activating solution for treatment to ensure the bonding force;
s5, zinc dipping: soaking the aluminum material treated by the S4 in a zinc dipping solution;
s6, washing: and cleaning the aluminum material treated in the step S5.
Preferably, the organic solvent used in the immersion cleaning process in the step S1 is alcohol, and the mixed solution in the cleaning process is prepared from sodium carbonate and an emulsifier, wherein the concentration of the sodium carbonate is 30-70 g/L, the concentration of the emulsifier is 1-10 g/L, and the temperature is controlled at 40-80 ℃ during cleaning.
Preferably, the volume ratio of the phosphoric acid to the glacial acetic acid in the step S2 is 5:3, and the temperature during the polishing treatment is controlled within the range of 80-110 ℃.
Preferably, the alkali solution in step S3 is prepared from sodium hydroxide and sodium phosphate, wherein the concentration of the sodium hydroxide is 10-40 g/L, and the concentration of the sodium phosphate is 10-40 g/L.
Preferably, the acidic activating solution in step S4 is prepared from oxalic acid, ammonium acetate and alcohol, wherein the concentration of oxalic acid is 50-100 g/L, the concentration of ammonium acetate is 50-100 g/L, and the concentration of alcohol is 20-80 g/L.
Preferably, the zinc immersion liquid in step S5 is prepared from zinc sulfate, sodium hydroxide, zinc oxide and sodium tartrate, wherein the concentration of zinc sulfate is 30-60 g/L, the concentration of sodium hydroxide is 100-200 g/L, the concentration of zinc oxide is 10-50 g/L, and the concentration of sodium tartrate is 10-50 g/L.
In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:
after the surface of the aluminum alloy material is treated by the process, the welding strength of a welding part is enhanced, so that the strength of the aluminum radiator is greatly improved, the process is convenient to process, the process flow has short consumption time, and the working efficiency is high.
Detailed Description
Example 1
The specific steps of this example are as follows:
s1, immersion cleaning and washing: adopting an organic solvent for immersion cleaning, cleaning by using a mixed solution, and removing attachments such as oil stains and the like on the surface of the aluminum material; the organic solvent used in the immersion cleaning process is alcohol, the mixed solution in the cleaning process is prepared by sodium carbonate and an emulsifier, wherein the concentration of the sodium carbonate is 30g/L, the concentration of the emulsifier is 1g/L, and the temperature is controlled at 40 ℃ during cleaning;
s2, polishing: polishing the aluminum material treated by the S1 in a mixed solution of phosphoric acid and glacial acetic acid to obtain a smooth plane; the volume ratio of phosphoric acid to glacial acetic acid is 5:3, and the temperature is controlled within 80 ℃ during polishing treatment;
s3, oil removal: putting the aluminum material treated by the S2 in alkali liquor for oil removal treatment, and cleaning the surface; the alkali liquor is prepared from sodium hydroxide and sodium phosphate, wherein the concentration of the sodium hydroxide is 10g/L, and the concentration of the sodium phosphate is 10 g/L;
s4, activation: treating the aluminum material treated by the S3 in an acid activating solution; the acidic activating solution is prepared from oxalic acid, ammonium acetate and alcohol, wherein the concentration of the oxalic acid is 50g/L, the concentration of the ammonium acetate is 50g/L, and the concentration of the alcohol is 20g/L, so that the binding force is ensured;
s5, zinc dipping: soaking the aluminum material treated by the S4 in a zinc dipping solution; the zinc dipping solution is prepared from zinc sulfate, sodium hydroxide, zinc oxide and sodium tartrate, wherein the concentration of the zinc sulfate is 30g/L, the concentration of the sodium hydroxide is 100g/L, the concentration of the zinc oxide is 10g/L, and the concentration of the sodium tartrate is 10 g/L;
s6, washing: the aluminum material treated in S5 was cleaned and washed with pure water.
Example 2
The specific steps of this example are as follows:
s1, immersion cleaning and washing: adopting an organic solvent for immersion cleaning, cleaning by using a mixed solution, and removing attachments such as oil stains and the like on the surface of the aluminum material; the organic solvent used in the immersion cleaning process is alcohol, the mixed solution in the cleaning process is prepared by sodium carbonate and an emulsifier, wherein the concentration of the sodium carbonate is 50g/L, the concentration of the emulsifier is 5g/L, and the temperature is controlled at 60 ℃ during cleaning;
s2, polishing: polishing the aluminum material treated by the S1 in a mixed solution of phosphoric acid and glacial acetic acid to obtain a smooth plane; the volume ratio of phosphoric acid to glacial acetic acid is 5:3, and the temperature is controlled within the range of 95 ℃ during polishing treatment;
s3, oil removal: putting the aluminum material treated by the S2 in alkali liquor for oil removal treatment, and cleaning the surface; the alkali liquor is prepared from sodium hydroxide and sodium phosphate, wherein the concentration of the sodium hydroxide is 25g/L, and the concentration of the sodium phosphate is 25 g/L;
s4, activation: treating the aluminum material treated by the S3 in an acid activating solution; the acidic activating solution is prepared from oxalic acid, ammonium acetate and alcohol, wherein the concentration of the oxalic acid is 75g/L, the concentration of the ammonium acetate is 75g/L, and the concentration of the alcohol is 50g/L, so that the binding force is ensured;
s5, zinc dipping: soaking the aluminum material treated by the S4 in a zinc dipping solution; the zinc dipping solution is prepared from zinc sulfate, sodium hydroxide, zinc oxide and sodium tartrate, wherein the concentration of the zinc sulfate is 45g/L, the concentration of the sodium hydroxide is 150g/L, the concentration of the zinc oxide is 30g/L, and the concentration of the sodium tartrate is 30 g/L;
s6, washing: the aluminum material treated in S5 was cleaned and washed with pure water.
Example 3
The specific steps of this example are as follows:
s1, immersion cleaning and washing: adopting an organic solvent for immersion cleaning, cleaning by using a mixed solution, and removing attachments such as oil stains and the like on the surface of the aluminum material; the organic solvent used in the immersion cleaning process is alcohol, the mixed solution in the cleaning process is prepared by sodium carbonate and an emulsifier, wherein the concentration of the sodium carbonate is 70g/L, the concentration of the emulsifier is 10g/L, and the temperature is controlled at 80 ℃ during cleaning;
s2, polishing: polishing the aluminum material treated by the S1 in a mixed solution of phosphoric acid and glacial acetic acid to obtain a smooth plane; the volume ratio of phosphoric acid to glacial acetic acid is 5:3, and the temperature is controlled within 110 ℃ during polishing treatment;
s3, oil removal: putting the aluminum material treated by the S2 in alkali liquor for oil removal treatment, and cleaning the surface; the alkali liquor is prepared from sodium hydroxide and sodium phosphate, wherein the concentration of the sodium hydroxide is 40g/L, and the concentration of the sodium phosphate is 40 g/L;
s4, activation: treating the aluminum material treated by the S3 in an acid activating solution; the acidic activating solution is prepared from oxalic acid, ammonium acetate and alcohol, wherein the concentration of the oxalic acid is 100g/L, the concentration of the ammonium acetate is 100g/L, and the concentration of the alcohol is 80g/L, so that the binding force is ensured;
s5, zinc dipping: soaking the aluminum material treated by the S4 in a zinc dipping solution; the zinc dipping solution is prepared from zinc sulfate, sodium hydroxide, zinc oxide and sodium tartrate, wherein the concentration of the zinc sulfate is 60g/L, the concentration of the sodium hydroxide is 200g/L, the concentration of the zinc oxide is 50g/L, and the concentration of the sodium tartrate is 50 g/L;
s6, washing: the aluminum material treated in S5 was cleaned and washed with pure water.

Claims (6)

1. The aluminum alloy surface treatment process is characterized by comprising the following steps of:
s1, immersion cleaning and washing: adopting an organic solvent for immersion cleaning, cleaning by using a mixed solution, and removing attachments such as oil stains and the like on the surface of the aluminum material;
s2, polishing: polishing the aluminum material treated by the S1 in a mixed solution of phosphoric acid and glacial acetic acid to obtain a smooth plane;
s3, oil removal: putting the aluminum material treated by the S2 in alkali liquor for oil removal treatment, and cleaning the surface;
s4, activation: the aluminum material treated by the S3 is put into an acid activating solution for treatment to ensure the bonding force;
s5, zinc dipping: soaking the aluminum material treated by the S4 in a zinc dipping solution;
s6, washing: and cleaning the aluminum material treated in the step S5.
2. The aluminum alloy surface treatment process according to claim 1, wherein the organic solvent used in the immersion cleaning process in the step S1 is alcohol, the mixed solution in the cleaning process is prepared from sodium carbonate and an emulsifier, wherein the concentration of the sodium carbonate is 30-70 g/L, the concentration of the emulsifier is 1-10 g/L, and the temperature during cleaning is controlled to be 40-80 ℃.
3. The aluminum alloy surface treatment process as recited in claim 1, wherein the volume ratio of phosphoric acid to glacial acetic acid in step S2 is 5:3, and the temperature during polishing is controlled within a range of 80 to 110 ℃.
4. The aluminum alloy surface treatment process of claim 1, wherein the alkali solution in step S3 is prepared from sodium hydroxide and sodium phosphate, wherein the concentration of sodium hydroxide is 10-40 g/L, and the concentration of sodium phosphate is 10-40 g/L.
5. The aluminum alloy surface treatment process of claim 1, wherein the acidic activating solution in step S4 is prepared from oxalic acid, ammonium acetate and alcohol, wherein the concentration of oxalic acid is 50-100 g/L, the concentration of ammonium acetate is 50-100 g/L, and the concentration of alcohol is 20-80 g/L.
6. The aluminum alloy surface treatment process of claim 1, wherein the zinc dipping solution in the step S5 is prepared from zinc sulfate, sodium hydroxide, zinc oxide and sodium tartrate, wherein the concentration of zinc sulfate is 30-60 g/L, the concentration of sodium hydroxide is 100-200 g/L, the concentration of zinc oxide is 10-50 g/L, and the concentration of sodium tartrate is 10-50 g/L.
CN202110740457.6A 2021-06-30 2021-06-30 Aluminum alloy surface treatment process Pending CN113621949A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003089885A (en) * 2001-09-14 2003-03-28 Nippon Light Metal Co Ltd Surface treatment method for aluminum material and surface treated aluminum material
CN103205744A (en) * 2012-01-12 2013-07-17 江苏嘉和热***股份有限公司 Novel surface treatment technology of aluminum alloy for radiator
CN103668192A (en) * 2012-09-01 2014-03-26 无锡新大中薄板有限公司 Four-element zinc-tin-nickel-iron soaking technique of aluminum alloy plate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003089885A (en) * 2001-09-14 2003-03-28 Nippon Light Metal Co Ltd Surface treatment method for aluminum material and surface treated aluminum material
CN103205744A (en) * 2012-01-12 2013-07-17 江苏嘉和热***股份有限公司 Novel surface treatment technology of aluminum alloy for radiator
CN103668192A (en) * 2012-09-01 2014-03-26 无锡新大中薄板有限公司 Four-element zinc-tin-nickel-iron soaking technique of aluminum alloy plate

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Application publication date: 20211109