CN113582460A - Medical sewage treatment method - Google Patents

Medical sewage treatment method Download PDF

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Publication number
CN113582460A
CN113582460A CN202110932887.8A CN202110932887A CN113582460A CN 113582460 A CN113582460 A CN 113582460A CN 202110932887 A CN202110932887 A CN 202110932887A CN 113582460 A CN113582460 A CN 113582460A
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China
Prior art keywords
medical sewage
disinfection
sterilization
medical
tank
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Pending
Application number
CN202110932887.8A
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Chinese (zh)
Inventor
黄尧冠
马艳芳
张立果
张秀春
李智强
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Guangzhou Bofang Environmental Protection Technology Co ltd
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Guangzhou Bofang Environmental Protection Technology Co ltd
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Priority to CN202110932887.8A priority Critical patent/CN113582460A/en
Publication of CN113582460A publication Critical patent/CN113582460A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/12Halogens or halogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F7/00Aeration of stretches of water

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention relates to a medical sewage treatment method, which comprises the following steps: s1, passing the medical sewage through a filtering treatment system; s2, transferring the medical sewage treated by the S1 to a biological membrane treatment system; s3, transferring the medical sewage treated by the S2 to an MBR system; s4, transferring the medical sewage treated by the S3 into a disinfection system; s5 detects emissions. The invention has the effects of denitrification and dephosphorization, degradation of organic pollutants and high-efficiency sterilization and disinfection, and the quality of the effluent is detected to be superior to the discharge standard of the first-class A in GB18918-2002, thereby solving the problems of large floor area and high capital cost of the traditional treatment method; meanwhile, the defects of high cost of operating agents, unstable effluent quality and the like of a primary strong physicochemical technology are overcome.

Description

Medical sewage treatment method
Technical Field
The invention belongs to the technical field of sewage treatment, and particularly relates to a medical sewage treatment method.
Background
Medical wastewater is mainly wastewater discharged from a clinic, laboratory, ward, laundry, radiography room, operating room, etc. of a hospital (general hospital, professional hospital, and other types of hospitals) to the natural environment or urban pipelines. The medical sewage has complex sources and components, contains pathogenic microorganisms, toxic and harmful physical and chemical pollutants, radioactive pollutants and the like, and has the characteristics of space pollution, acute infection, latent infection and the like. Therefore, medical sewage is directly discharged into urban sewers without being subjected to harmless treatment such as disinfection and inactivation, so that water and soil pollution is caused, various diseases are caused seriously, and the outbreak of infectious diseases is caused. At present, hospitals which can achieve the discharge of medical sewage reaching national standards are few, the laws are not standard, the environmental awareness is weak, and the direct discharge of medical wastewater and the conditions of high pollution and low treatment in hospitals are caused.
The traditional primary strong physicochemical treatment is adopted in the existing medical sewage treatment technology, and the technology has the defects of low treatment efficiency, easy influence of suspended matters on the disinfection effect, unstable effluent and the like; when the two-stage activated sludge process technology is adopted, the defects of large occupied area, long construction period and the like mainly exist, and the above technologies have some defects.
Patent No. CN 109205892A discloses a technique of filtration first, flocculation and precipitation again disinfection treatment, and this method needs to use a large amount of flocculating agent, has increaseed the post processing degree of difficulty on the one hand, and its flocculation basin area is very big on the other hand, and the construction cycle is long.
Patent No. CN105906003A discloses a medical sewage purification treatment material, which can reduce the COD, BOD and sulfide content of medical sewage and kill escherichia coli, candida albicans and pseudomonas aeruginosa, but the medical sewage purification treatment material uses a large amount of chemical reagents, which removes impurities from medical sewage and kills bacteria while introducing a lot of chemical reagents, which has a great impact on the environment.
Patent No. CN110255800A discloses a medical sewage purification treatment method, which adopts solid-liquid separation; the method adopts high-temperature high-pressure sterilization, and then adopts an evaporation and condensation mode to purify water, and has the advantages of high heating temperature, large energy consumption and limited treatment capacity. The method carries out combustion treatment on solid waste in the solid-liquid separation, although the treatment of combustion tail gas is introduced, toxic and harmful bacteria in the solid waste are difficult to be preserved and cannot leak out in the combustion treatment process, and secondary pollution is generated.
Patent No. CN111908705A discloses a process for removing nitrogen and phosphorus, which relates to a plurality of sedimentation tanks and coagulation reaction tanks, uses a large amount of coagulation and flocculation reagents, complicates the whole treatment process, and has the defects of floor area, cost investment and post-treatment.
Disclosure of Invention
In order to solve the problems, the invention provides a medical sewage treatment method, which comprises the following steps:
s1, filtering: intercepting suspended matters of the medical sewage by the medical sewage through a buffer tank with a grid forming an angle of 35 degrees with the horizontal plane;
s2, biofilm treatment: transferring the medical sewage treated by the S1 to an anaerobic tank provided with a stirring device and a denitrifying bacteria biofilm, an anoxic tank provided with a stirring device and anaerobic ammonia oxidizing bacteria, and an aerobic tank provided with a stirring device and a nitrifying bacteria biofilm for removing nitrogen and degrading organic matters;
s3, MBR system: transferring the medical sewage treated by S2 to an MBR system, adding a phosphorus removing agent, treating for 2-4h, fully removing phosphorus and intercepting bacterial viruses in the medical sewage;
s4, disinfection and sterilization system: transferring the medical sewage treated by the S3 to a disinfection and sterilization system, and adopting a composite disinfection and sterilization mode of ultraviolet disinfection and electrolytic disinfection and sterilization.
And S5, detecting the medical sewage after treatment, and discharging after reaching the standard.
The buffer tank is provided with an aeration device for removing residual effective chlorine in the medical raw water.
The dissolved oxygen in the anaerobic tank is less than 0.2mg/L, and the treatment time of the anaerobic tank is 0.5-2 h.
The dissolved oxygen in the anoxic tank is 0.2-0.5mg/L, and the treatment time of the anoxic tank is 0.5-2 h.
The dissolved oxygen in the aerobic tank is more than 0.5mg/L, and the treatment time of the aerobic tank is 1-3 h.
The phosphorus removing agent adopts an autonomous patent technology product (CN201210317806.4), mainly comprises composite polyaluminium chloride and a high-efficiency phosphorus removing agent, and the adding amount is 20-50 ppm.
The MBR membrane adopts a flat membrane.
The disinfection and sterilization system adopts a composite disinfection and sterilization mode of ultraviolet disinfection and sterilization and electrolysis disinfection and sterilization, the electrolysis sterilizer adopts an independent patent technology product (CN2020226410003), and the disinfection and sterilization time is 1-2 h.
The invention achieves the following beneficial effects:
1. the grid of the adjusting tank selected by the invention forms an angle of 35 degrees with the horizontal plane, so that most of suspended matters in sewage can be removed, and the phenomenon of sudden and reverse gushing of water flow can not occur.
2. The aeration device is arranged in the buffer tank, so that residual effective chlorine in the medical raw water can be effectively removed to provide guarantee for the rear-end unit.
3. The anaerobic tank, the anoxic tank and the aerobic tank are provided with the stirrers, so that the biological membrane can be fully contacted with pollutants, and the aims of fully removing nitrogen and fully degrading organic matters are fulfilled.
4. The anaerobic ammonia oxidizing bacteria in an anoxic environment convert ammonia nitrogen contained in sewage into nitrogen to be removed by taking carbon dioxide or carbonate as a carbon source, taking ammonium salt as an electron donor and taking nitrite/nitrate as an electron acceptor, and assist in improving the denitrification effect of the biological membrane system.
5. The denitrifying bacteria utilize organic matters as carbon sources and NO 3-and NO 2-as electron acceptors in an anoxic environment, so that NO 3-and NO 2-are reduced into N2 to escape, and denitrification is performed, so that the nitrogen content is greatly reduced, the sewage load is reduced, and the denitrification effect of the whole system is further improved.
6. According to the invention, an MBR membrane system is selected, the separation effect is far better than that of the traditional sedimentation tank, the treated effluent is extremely clear and occupies more than 50% of the ground, suspended matters and turbidity are close to zero, and bacteria and viruses are greatly removed and separated.
7. The phosphorus removing agent adopted by the invention adopts an autonomous patent technology product, mainly comprises composite polyaluminium chloride and a high-efficiency phosphorus removing agent, and the dosage is 20-50 ppm.
8. The MBR membrane selected by the invention is a flat membrane, and the flat membrane has the advantages of high strength, strong pollution resistance, high mechanical strength, long cleaning period, long service life and the like.
9. The invention adopts a compound disinfection and sterilization mode of ultraviolet disinfection and electrolytic disinfection and sterilization, can fully kill toxic bacteria, fungi, viruses and the like, and leads the water quality to reach the dischargeable standard.
Detailed Description
In order that the objects and advantages of the invention will be more clearly understood, the invention is further described below with reference to examples; it should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Example 1
Firstly, medical sewage to be discharged passes through a buffer tank with a grid forming an angle of 35 degrees with the horizontal plane to intercept suspended matters of the medical sewage, the medical sewage in the buffer tank is transferred to an anaerobic tank provided with a stirring device and containing a denitrifying bacteria biofilm, the dissolved oxygen concentration of the anaerobic tank is 0.1mg/L, the medical sewage is transferred to the stirring device and an anoxic tank containing anaerobic ammonium oxidation bacteria after being treated for 1h, the dissolved oxygen concentration of the anoxic tank is 0.3mg/L, the medical sewage is transferred to an aerobic tank provided with the stirring device and containing the nitrifying bacteria biofilm after being treated for 0.5h, the dissolved oxygen concentration of the aerobic tank is 0.8mg/L, and nitrogen-containing substances and organic substances in the medical sewage are effectively removed and degraded after being treated for 1 h. And then transferring the medical sewage to an MBR system, adding 20ppm of a phosphorus removal agent, and treating for 3 hours to fully remove and intercept phosphorus and bacterial viruses in the medical sewage. And finally transferring the treated medical sewage to a composite disinfection and sterilization system for ultraviolet disinfection and sterilization and electrolytic disinfection and sterilization to kill bacteria for 2 hours, wherein the parameters of the medical sewage before detection treatment are as follows: CODcr: 150-250mg/L, BOD 5: 50-120mg/L, TP: 2.5-4.5mg/L, ammonia nitrogen: 20-40 mg/L; and SS: 100-250 mg/L. The parameters of the treated medical sewage are as follows: CODcr: less than or equal to 30.0mg/L, BOD 5: : less than or equal to 10.0mg/L, TP: less than or equal to 0.4mg/L, ammonia nitrogen: less than or equal to 1.0 mg/L; and SS: less than or equal to 10.0 mg/Lmg/L; coli groups were not detected; salmonella is not detected; the shiga bacteria were not detected. Completely reaches the emission standard.
Example 2
Firstly, medical sewage to be discharged passes through a buffer tank with a grid forming an angle of 35 degrees with the horizontal plane to intercept suspended matters of the medical sewage, the medical sewage in the buffer tank is transferred to an anaerobic tank provided with a stirring device and containing a denitrifying bacteria biofilm, the dissolved oxygen concentration of the anaerobic tank is 0.05mg/L, the medical sewage is transferred to the stirring device and an anoxic tank containing anaerobic ammonium oxidation bacteria after being treated for 1.5h, the dissolved oxygen concentration of the anoxic tank is 0.4mg/L, the medical sewage is transferred to an aerobic tank provided with the stirring device and containing the nitrifying bacteria biofilm after being treated for 1h, the dissolved oxygen concentration of the aerobic tank is 1.2mg/L, and nitrogen-containing substances and organic substances in the medical sewage are effectively removed and degraded after being treated for 2.5 h. And then transferring the medical sewage to an MBR system, adding 30ppm of a phosphorus removal agent, and treating for 2 hours to fully remove and intercept phosphorus and bacterial viruses in the medical sewage. And finally transferring the treated medical sewage to a composite disinfection and sterilization system for ultraviolet disinfection and sterilization and electrolytic disinfection and sterilization to kill the bacteria for 1.5h, wherein the parameters of the medical sewage before detection treatment are as follows: CODcr: 200-250mg/L, BOD 5: 70-130mg/L, TP: 2.5-4.5mg/L, ammonia nitrogen: 20-40 mg/L; and SS: 150-250 mg/Lmg/L. The parameters of the treated medical sewage are as follows: CODcr: less than or equal to 30.0mg/L, BOD 5: : less than or equal to 10.0mg/L, TP: less than or equal to 0.4mg/L, ammonia nitrogen: less than or equal to 1.0 mg/L; and SS: less than or equal to 10.0 mg/L; coli groups were not detected; salmonella is not detected; the shiga bacteria were not detected. Completely reaches the emission standard.
Comparative example 1
Firstly, passing medical sewage to be discharged through a common horizontal grid, intercepting suspended matters of the medical sewage by an adjusting tank, transferring the medical sewage in a buffer tank to an anaerobic tank provided with a stirring device and containing a denitrifying bacteria biofilm, wherein the dissolved oxygen concentration of the anaerobic tank is 0.05mg/L, transferring the medical sewage after 1.5h of treatment to an aerobic tank provided with the stirring device and containing the nitrifying bacteria biofilm, wherein the dissolved oxygen concentration of the aerobic tank is 1.2mg/L, and removing and degrading nitrogenous substances and organic substances after 1.5h of treatment. Then transferring the medical sewage to an ultraviolet disinfection and sterilization system to kill bacteria for 2.5 hours, wherein the parameters of the medical sewage before detection treatment are as follows: CODcr: 200-250mg/L, BOD 5: 70-130mg/L, TP: 2.5-4.5mg/L, ammonia nitrogen: 20-40 mg/L; and SS: 150-250 mg/Lmg/L. The parameters of the treated medical sewage are as follows: CODcr: less than or equal to 90.0mg/L, BOD 5: : less than or equal to 50mg/L, TP: less than or equal to 2mg/L, ammonia nitrogen: less than or equal to 12 mg/L; and SS: less than or equal to 100mg/L, and a small amount of coliform bacteria, salmonella bacteria and shigella bacteria which do not meet the discharge standard.
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.

Claims (8)

1. A method for medical sewage treatment is characterized by comprising the following steps:
s1, filtering: intercepting suspended matters of the medical sewage by the medical sewage through a buffer tank with a grid forming an angle of 35 degrees with the horizontal plane;
s2, biofilm treatment: transferring the medical sewage treated by the S1 to an anaerobic tank provided with a stirring device and a denitrifying bacteria biofilm, an anoxic tank provided with a stirring device and anaerobic ammonia oxidizing bacteria, and an aerobic tank provided with a stirring device and a nitrifying bacteria biofilm for removing nitrogen and degrading organic matters;
s3, MBR system: transferring the medical sewage treated by S2 to an MBR system, adding a phosphorus removing agent, treating for 2-4h, fully removing phosphorus and intercepting bacterial viruses in the medical sewage;
s4, disinfection and sterilization system: transferring the medical sewage treated by the S3 to a disinfection and sterilization system, and adopting a compound disinfection and sterilization mode of ultraviolet disinfection and electrolytic disinfection and sterilization;
and S5, detecting the medical sewage after treatment, and discharging after reaching the standard.
2. The method for medical sewage treatment according to claim 1, wherein the buffer tank is provided with an aeration device for removing residual available chlorine in the medical raw water.
3. The medical sewage treatment method according to claim 1, wherein the dissolved oxygen in the anaerobic tank is less than 0.2mg/L, and the treatment time of the anaerobic tank is 0.5-2 h.
4. The medical sewage treatment method according to claim 1, wherein the dissolved oxygen in the anoxic tank is 0.2-0.5mg/L, and the treatment time in the anoxic tank is 0.5-2 h.
5. The medical sewage treatment method according to claim 1, wherein the dissolved oxygen in the aerobic tank is greater than 0.5mg/L, and the treatment time of the aerobic tank is 1-3 h.
6. The medical sewage treatment method according to claim 1, wherein the phosphorus removal agent adopts a self-patented technology product (CN201210317806.4), mainly composite polyaluminium chloride and a high-efficiency phosphorus removal agent, and the dosage is 20-50 ppm.
7. The method for medical sewage treatment according to claim 1, wherein the MBR membrane is a flat membrane.
8. The method for medical sewage treatment according to claim 1, wherein the disinfection and sterilization system uses a composite disinfection and sterilization mode of ultraviolet disinfection and electrolytic disinfection and sterilization, and the electrolytic disinfection apparatus adopts an independent patent technology product (CN2020226410003), and the disinfection and sterilization time is 1-2 h.
CN202110932887.8A 2021-08-13 2021-08-13 Medical sewage treatment method Pending CN113582460A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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CN112777865A (en) * 2021-01-05 2021-05-11 江苏泰源环保科技股份有限公司 Hospital sewage emergency treatment process and corresponding steel modular treatment equipment
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Publication number Priority date Publication date Assignee Title
CA2764209A1 (en) * 2009-06-15 2010-12-23 Saudi Arabian Oil Company Suspended media membrane biological reactor system and process including suspension system
CN204079599U (en) * 2014-08-27 2015-01-07 浙江源态环保科技服务有限公司 Sewage disposal device
KR20210013503A (en) * 2019-07-26 2021-02-04 주식회사 에싸 Hospital sewage disposal system
CN112777865A (en) * 2021-01-05 2021-05-11 江苏泰源环保科技股份有限公司 Hospital sewage emergency treatment process and corresponding steel modular treatment equipment
CN112707604A (en) * 2021-01-18 2021-04-27 长沙工研院环保有限公司 Medical wastewater treatment system
CN112939362A (en) * 2021-02-05 2021-06-11 四川国润和洁环境科技有限公司 Method for treating sewage in alpine region

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Application publication date: 20211102