CN113512362A - Floor wax suitable for floors with different base materials - Google Patents
Floor wax suitable for floors with different base materials Download PDFInfo
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- CN113512362A CN113512362A CN202110966142.3A CN202110966142A CN113512362A CN 113512362 A CN113512362 A CN 113512362A CN 202110966142 A CN202110966142 A CN 202110966142A CN 113512362 A CN113512362 A CN 113512362A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
- C09G1/10—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
- C09G1/12—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin mixtures of wax and silicon-containing polycondensates
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/06—Coniferophyta [gymnosperms], e.g. cypress
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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Abstract
The invention discloses floor wax suitable for floors with different base materials, which comprises the following raw materials in parts by weight: 40-80 parts of insect wax, 25-55 parts of white oil, 8-32 parts of silicone oil, 8-22 parts of propolis, 20-30 parts of modified nano silicon dioxide, 10-25 parts of camphor tree extract, 12-24 parts of pawpaw extract, 4-8 parts of ginkgo, 3-6 parts of lavender, 2-6 parts of nardostachys chinensis, 10-15 parts of lemon, 4-7 parts of mint, 4-6 parts of golden cypress, 2-5 parts of radix zanthoxyli and 2-3 parts of surfactant. According to the invention, by adding the modified nano-silica and utilizing the combination of the gingko kernel and the nano-silica, the modified nano-silica has the properties of flavonoid compounds, the antibacterial effect of the floor wax is improved, and in addition, the nano-silica is in a net structure, so that the prepared floor wax has good strength and good wear resistance, and can effectively protect the floor.
Description
Technical Field
The invention belongs to the technical field of floor wax, and particularly relates to floor wax suitable for floors with different base materials.
Background
Floor wax is one of the common products for home decoration at present, and has the functions of: stubborn stains on the floor are removed, the material is isolated from the air by waxing, the damage to the material caused by oxidation or contact with harmful substances in the air is reduced, and the purposes of prolonging the service life of the material and beautifying and smoothing the material are achieved; more importantly, the mirror-bright surface formed by the polishing agent is durable, can prevent damage caused by detergent, scratches, sliding, heel friction and the like, and has a polished wax surface which is brighter, harder and more durable, but various floor waxes on the market still have various problems.
For example, the publication number CN106905847A discloses a graphene aldehyde-removing floor wax, which does not contain organic pollutants such as formaldehyde and benzene, can enclose organic volatile substances in the floor, and remove formaldehyde, and simultaneously, the addition of graphene can also improve the decomposition and purification efficiency of harmful substances and the wear-resistant and anti-slip properties of the coating, but does not solve the existing problems of floor waxes suitable for floors with different substrates: the floor wax has the advantages of poor antibacterial property and wear resistance, low insect damage resistance and corrosion resistance, and the floor wax generally contains a chemical aromatic agent and is harmful to the health of people, so that the floor wax suitable for floors with different base materials is provided.
Disclosure of Invention
The invention aims to provide floor wax suitable for floors with different base materials, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: the floor wax suitable for floors with different base materials comprises the following raw materials in parts by weight: 40-80 parts of insect wax, 25-55 parts of white oil, 8-32 parts of silicone oil, 8-22 parts of propolis, 20-30 parts of modified nano silicon dioxide, 10-25 parts of camphor tree extract, 12-24 parts of pawpaw extract, 4-8 parts of ginkgo, 3-6 parts of lavender, 2-6 parts of nardostachys chinensis, 10-15 parts of lemon, 4-7 parts of mint, 4-6 parts of golden cypress, 2-5 parts of radix zanthoxyli and 2-3 parts of surfactant.
The preparation method of the floor wax also comprises a preparation process of the floor wax, wherein the preparation process of the floor wax comprises the following steps:
step one, raw material preparation: the raw materials are selected according to the following parts by weight: 40-80 parts of insect wax, 25-55 parts of white oil, 8-32 parts of silicone oil, 8-22 parts of propolis, 20-30 parts of modified nano silicon dioxide, 10-25 parts of camphor tree extract, 12-24 parts of pawpaw extract, 4-8 parts of ginkgo, 3-6 parts of lavender, 2-6 parts of nardostachys chinensis, 10-15 parts of lemon, 4-7 parts of mint, 4-6 parts of golden cypress, 2-5 parts of radix zanthoxyli and 2-3 parts of surfactant;
step two, preparing filtrate: pulverizing semen Ginkgo, Lavender, rhizoma Nardostachyos, fructus Citri Limoniae, herba Menthae, cortex Phellodendri, and radix Zanthoxyli to 10-25 mesh, mixing, adding ethanol, refluxing for 1-2 hr, and filtering to obtain filtrate;
step three, heating and melting: heating insect wax, white oil and silicone oil to a molten state to obtain a mixture;
step four, mixing the raw materials: adding propolis and the filtrate obtained in the second step into the mixture obtained in the third step, uniformly mixing, and performing rotary evaporation to remove ethanol solvent;
step five, preparing floor wax: adding the modified nano silicon dioxide, the camphor tree extract, the pawpaw extract and the surfactant into the mixture treated in the fourth step, keeping the temperature at 75-95 ℃, stirring for reaction for 1-3h at 1500r/min for 1000-.
Preferably, the feed comprises the following raw materials in parts by weight: 50-70 parts of insect wax, 30-50 parts of white oil, 10-20 parts of silicone oil, 10-15 parts of propolis, 24-28 parts of modified nano silicon dioxide, 12-18 parts of camphor tree extract, 16-20 parts of pawpaw extract, 5-7 parts of ginkgo, 4-5 parts of lavender, 3-5 parts of nardostachys chinensis, 12-14 parts of lemon, 5-6 parts of mint, 4-5 parts of golden cypress, 3-4 parts of radix zanthoxyli and 2.4-2.8 parts of surfactant.
Preferably, the feed comprises the following raw materials in parts by weight: 60 parts of insect wax, 40 parts of white oil, 15 parts of silicone oil, 12 parts of propolis, 26 parts of modified nano silicon dioxide, 15 parts of camphor tree extract, 18 parts of pawpaw extract, 6 parts of ginkgo, 4 parts of lavender, 4 parts of nard, 13 parts of lemon, 6 parts of mint, 4.5 parts of golden cypress, 3.5 parts of radix zanthoxyli and 2.5 parts of surfactant.
Preferably, the preparation process of the modified nano-silica comprises the following steps:
step one, preparing gingko kernel powder: cleaning semen Ginkgo, pulverizing for 20-30min, and sieving with 60-120 mesh sieve to obtain semen Ginkgo powder;
step two, preparing a gingko kernel extracting solution: mixing the silver almond powder and 65-75% of ethanol solution according to the mass ratio of 1: 10, putting the mixture into a reaction kettle, and stirring and reacting at the temperature of 50-60 ℃ at the speed of 600-1000r/min for 40-60min to obtain a silver almond extracting solution;
step three, preparing a mixed solution: mixing the gingko kernel extract obtained in the step two with 35-45% of sodium silicate solution according to the mass ratio of 1: 1, and stirring and reacting at 600-1000r/min for 40-60min to obtain a mixed solution;
step four, preparing modified nano silicon dioxide: pouring the mixed solution into a reaction kettle, adding 25-35% by mass of hydrochloric acid into the reaction kettle, adjusting the pH of the mixed solution to 4-6, stirring and reacting at the temperature of 40-70 ℃ at 1000r/min for 3-4h, and discharging to obtain the modified nano silicon dioxide.
Preferably, the preparation process of the camphor tree extract comprises the following steps:
step one, taking raw materials: taking the following components in parts by weight: 30-60 parts of camphor tree branches and leaves, 60-120 parts of complex enzyme and 300 parts of sodium chloride solution;
step two, preparing the camphor tree extract: cleaning the branches and leaves of the camphor trees according to the parts by weight, crushing the branches and leaves of the camphor trees into 60-90 meshes, adding complex enzyme for treating for 150-180min, adding sodium chloride solution, heating and boiling for 60-80min, filtering to obtain filter residues and filtrate, and drying the filtrate until the water content is one third of the original volume to obtain the camphor tree extract.
Preferably, the complex enzyme is prepared by mixing cellulase, hemicellulase and ligninase according to the mass part ratio of 3:1: 5.
Preferably, the preparation process of the papaya extract comprises the following steps: firstly, removing pulp of pawpaw, only reserving skin and seeds, crushing to 70-90 meshes, adding water with the weight twice that of the skin and the seeds, heating and distilling to obtain distillate, treating the distillate in a 200-400r/min centrifuge for 20-40min, and taking supernatant to obtain the pawpaw extract.
Preferably, the surfactant is an anionic surfactant, and the anionic surfactant is one or a mixture of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium fatty alcohol-polyoxyethylene ether sulfate and sodium alpha-olefin sulfonate.
Compared with the prior art, the invention has the beneficial effects that:
(1) according to the invention, by adding the modified nano-silica and utilizing the combination of the gingko kernel and the nano-silica, the modified nano-silica has the properties of flavonoid compounds, the antibacterial effect of the floor wax is improved, and in addition, the nano-silica is in a net structure, has high strength and good wear resistance, so that the prepared floor wax has good strength and good wear resistance, and can effectively protect floors.
(2) The floor wax is safe, nontoxic and good in insect resistance and corrosion resistance by adding the gingko, the lavender, the nardostachys chinensis bunge, the lemon, the mint, the golden cypress and the shinyleaf pricklyash root into the floor wax, and the camphor tree extract and the papaya extract are added to replace a chemical aromatic, so that the fragrance of the floor wax is increased, the safety is improved, and the floor wax is green and healthy.
Drawings
FIG. 1 is a flow chart of the preparation of floor polish according to the present invention;
FIG. 2 is a flow chart of the preparation of modified nano-silica in the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
Referring to fig. 1-2, the present invention provides a technical solution: the floor wax suitable for floors with different base materials comprises the following raw materials in parts by weight: 40 parts of insect wax, 25 parts of white oil, 8 parts of silicone oil, 8 parts of propolis, 20 parts of modified nano silicon dioxide, 10 parts of camphor tree extract, 12 parts of pawpaw extract, 4 parts of ginkgo, 3 parts of lavender, 2 parts of nardostachys root and rhizome, 10 parts of lemon, 4 parts of mint, 4 parts of golden cypress, 2 parts of radix zanthoxyli and 2 parts of surfactant.
The preparation method of the floor wax also comprises a preparation process of the floor wax, wherein the preparation process of the floor wax comprises the following steps:
step one, raw material preparation: the raw materials are selected according to the following parts by weight: 40 parts of insect wax, 25 parts of white oil, 8 parts of silicone oil, 8 parts of propolis, 20 parts of modified nano silicon dioxide, 10 parts of camphor tree extract, 12 parts of pawpaw extract, 4 parts of ginkgo, 3 parts of lavender, 2 parts of nardostachys root and rhizome, 10 parts of lemon, 4 parts of mint, 4 parts of phellodendron, 2 parts of radix zanthoxyli and 2 parts of surfactant;
step two, preparing filtrate: pulverizing semen Ginkgo, Lavender, rhizoma Nardostachyos, fructus Citri Limoniae, herba Menthae, cortex Phellodendri, and radix Zanthoxyli to 10 mesh, mixing, adding ethanol, refluxing for 1 hr, and filtering to obtain filtrate;
step three, heating and melting: heating insect wax, white oil and silicone oil to a molten state to obtain a mixture;
step four, mixing the raw materials: adding propolis and the filtrate obtained in the second step into the mixture obtained in the third step, uniformly mixing, and performing rotary evaporation to remove ethanol solvent;
step five, preparing floor wax: adding the modified nano silicon dioxide, the camphor tree extract, the pawpaw extract and the surfactant into the mixture treated in the fourth step, keeping the temperature at 75 ℃, stirring and reacting for 3h at 1000r/min, then cooling to 40 ℃, stirring for 3h, cooling to room temperature, and discharging to obtain the floor wax.
In this embodiment, preferably, the preparation process of the modified nano-silica includes the following steps:
step one, preparing gingko kernel powder: cleaning semen Ginkgo, pulverizing for 20min, and sieving with 60 mesh sieve to obtain semen Ginkgo powder;
step two, preparing a gingko kernel extracting solution: mixing semen Ginkgo powder and 65% ethanol solution at a mass ratio of 1: 10, placing into a reaction kettle, and stirring at 50 deg.C for 60min at 600r/min to obtain semen Ginkgo extractive solution;
step three, preparing a mixed solution: mixing the semen Ginkgo extractive solution obtained in step two with 35-45% sodium silicate solution at a mass ratio of 1: 1, stirring at 600r/min for reaction for 60min to obtain mixed solution;
step four, preparing modified nano silicon dioxide: pouring the mixed solution into a reaction kettle, adding 25 mass percent hydrochloric acid into the reaction kettle, adjusting the pH of the mixed solution to 4, stirring and reacting for 4 hours at the temperature of 40 ℃ at 600r/min, and discharging to obtain the modified nano silicon dioxide.
In this embodiment, preferably, the preparation process of the camphor tree extract includes the following steps:
step one, taking raw materials: taking the following components in parts by weight: 30 parts of camphor tree branches and leaves, 60 parts of complex enzyme and 150 parts of sodium chloride solution;
step two, preparing the camphor tree extract: cleaning branches and leaves of camphor trees according to the weight parts, crushing the branches and leaves of the camphor trees into 60 meshes, adding complex enzyme for treating the branches and leaves for 150min, adding sodium chloride solution for heating and boiling the mixture for 60min, filtering the mixture to obtain filter residues and filtrate, and drying the filtrate until the water content is one third of the original volume to obtain the camphor tree extract.
In this embodiment, preferably, the complex enzyme is prepared by mixing cellulase, hemicellulase and ligninase in a mass ratio of 3:1: 5.
In this embodiment, preferably, the preparation process of the papaya extract includes the following steps: removing pulp of fructus Chaenomelis, only leaving skin and seed, pulverizing to 70 mesh, adding water twice the weight of skin and seed, heating and distilling to obtain distillate, treating the distillate in 200r/min centrifuge for 40min, and collecting supernatant to obtain fructus Chaenomelis extract.
In this embodiment, preferably, the surfactant is an anionic surfactant, and the anionic surfactant is one or a mixture of several of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium fatty alcohol-polyoxyethylene ether sulfate, and sodium alpha-olefin sulfonate.
Example 2
Referring to fig. 1-2, the present invention provides a technical solution: the floor wax suitable for floors with different base materials comprises the following raw materials in parts by weight: 80 parts of insect wax, 55 parts of white oil, 32 parts of silicone oil, 22 parts of propolis, 30 parts of modified nano silicon dioxide, 25 parts of camphor tree extract, 24 parts of pawpaw extract, 8 parts of ginkgo, 6 parts of lavender, 6 parts of nardostachys root and rhizome, 15 parts of lemon, 7 parts of mint, 6 parts of golden cypress, 5 parts of radix zanthoxyli and 3 parts of surfactant.
The preparation method of the floor wax also comprises a preparation process of the floor wax, wherein the preparation process of the floor wax comprises the following steps:
step one, raw material preparation: the raw materials are selected according to the following parts by weight: 80 parts of insect wax, 55 parts of white oil, 32 parts of silicone oil, 22 parts of propolis, 30 parts of modified nano silicon dioxide, 25 parts of camphor tree extract, 24 parts of pawpaw extract, 8 parts of ginkgo, 6 parts of lavender, 6 parts of nardostachys root and rhizome, 15 parts of lemon, 7 parts of mint, 6 parts of golden cypress, 5 parts of radix zanthoxyli and 3 parts of surfactant;
step two, preparing filtrate: pulverizing semen Ginkgo, Lavender, rhizoma Nardostachyos, fructus Citri Limoniae, herba Menthae, cortex Phellodendri, and radix Zanthoxyli to 25 mesh, mixing, adding ethanol, refluxing for 2 hr, and filtering to obtain filtrate;
step three, heating and melting: heating insect wax, white oil and silicone oil to a molten state to obtain a mixture;
step four, mixing the raw materials: adding propolis and the filtrate obtained in the second step into the mixture obtained in the third step, uniformly mixing, and performing rotary evaporation to remove ethanol solvent;
step five, preparing floor wax: adding the modified nano silicon dioxide, the camphor tree extract, the pawpaw extract and the surfactant into the mixture treated in the fourth step, keeping the temperature at 95 ℃, stirring and reacting for 3h at 1500r/min, then cooling to 60 ℃, stirring for 3h, cooling to room temperature, and discharging to obtain the floor wax.
In this embodiment, preferably, the preparation process of the modified nano-silica includes the following steps:
step one, preparing gingko kernel powder: cleaning semen Ginkgo, pulverizing for 30min, and sieving with 120 mesh sieve to obtain semen Ginkgo powder;
step two, preparing a gingko kernel extracting solution: mixing semen Ginkgo powder and 75% ethanol solution at a mass ratio of 1: 10, placing into a reaction kettle, and stirring at 60 deg.C for 60min at 1000r/min to obtain semen Ginkgo extractive solution;
step three, preparing a mixed solution: mixing the semen Ginkgo extractive solution obtained in step two with 35-45% sodium silicate solution at a mass ratio of 1: 1, and stirring at 1000r/min for 40min to obtain mixed solution;
step four, preparing modified nano silicon dioxide: pouring the mixed solution into a reaction kettle, adding 35% hydrochloric acid by mass into the reaction kettle, adjusting the pH of the mixed solution to 6, stirring and reacting for 3 hours at the temperature of 70 ℃ at 1000r/min, and discharging to obtain the modified nano silicon dioxide.
In this embodiment, preferably, the preparation process of the camphor tree extract includes the following steps:
step one, taking raw materials: taking the following components in parts by weight: 60 parts of camphor tree branches and leaves, 120 parts of complex enzyme and 300 parts of sodium chloride solution;
step two, preparing the camphor tree extract: cleaning branches and leaves of camphor trees according to the weight parts, crushing the branches and leaves of the camphor trees into 90 meshes, adding complex enzyme for processing for 180min, adding sodium chloride solution, heating and boiling for 80min, filtering to obtain filter residue and filtrate, and drying the filtrate until the water content is one third of the original volume to obtain the camphor tree extract.
In this embodiment, preferably, the complex enzyme is prepared by mixing cellulase, hemicellulase and ligninase in a mass ratio of 3:1: 5.
In this embodiment, preferably, the preparation process of the papaya extract includes the following steps: removing pulp of fructus Chaenomelis, only leaving skin and seed, pulverizing to 90 mesh, adding water twice the weight of skin and seed, heating and distilling to obtain distillate, treating the distillate in 400r/min centrifuge for 40min, and collecting supernatant to obtain fructus Chaenomelis extract.
In this embodiment, preferably, the surfactant is an anionic surfactant, and the anionic surfactant is one or a mixture of several of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium fatty alcohol-polyoxyethylene ether sulfate, and sodium alpha-olefin sulfonate.
Example 3
Referring to fig. 1-2, the present invention provides a technical solution: the floor wax suitable for floors with different base materials comprises the following raw materials in parts by weight: 60 parts of insect wax, 40 parts of white oil, 15 parts of silicone oil, 12 parts of propolis, 26 parts of modified nano silicon dioxide, 15 parts of camphor tree extract, 18 parts of pawpaw extract, 6 parts of ginkgo, 4 parts of lavender, 4 parts of nard, 13 parts of lemon, 6 parts of mint, 4.5 parts of golden cypress, 3.5 parts of radix zanthoxyli and 2.5 parts of surfactant.
The preparation method of the floor wax also comprises a preparation process of the floor wax, wherein the preparation process of the floor wax comprises the following steps:
step one, raw material preparation: the raw materials are selected according to the following parts by weight: 60 parts of insect wax, 40 parts of white oil, 15 parts of silicone oil, 12 parts of propolis, 26 parts of modified nano silicon dioxide, 15 parts of camphor tree extract, 18 parts of pawpaw extract, 6 parts of ginkgo, 4 parts of lavender, 4 parts of nard, 13 parts of lemon, 6 parts of mint, 4.5 parts of golden cypress, 3.5 parts of radix zanthoxyli and 2.5 parts of surfactant;
step two, preparing filtrate: pulverizing semen Ginkgo, Lavender, rhizoma Nardostachyos, fructus Citri Limoniae, herba Menthae, cortex Phellodendri, and radix Zanthoxyli to 18 mesh, mixing, adding ethanol, refluxing for 1.5 hr, and filtering to obtain filtrate;
step three, heating and melting: heating insect wax, white oil and silicone oil to a molten state to obtain a mixture;
step four, mixing the raw materials: adding propolis and the filtrate obtained in the second step into the mixture obtained in the third step, uniformly mixing, and performing rotary evaporation to remove ethanol solvent;
step five, preparing floor wax: adding the modified nano silicon dioxide, the camphor tree extract, the pawpaw extract and the surfactant into the mixture treated in the fourth step, keeping the temperature at 80 ℃, stirring at 1200r/min for reaction for 2 hours, then cooling to 50 ℃, stirring for 2 hours, cooling to room temperature, and discharging to obtain the floor wax.
In this embodiment, preferably, the preparation process of the modified nano-silica includes the following steps:
step one, preparing gingko kernel powder: cleaning semen Ginkgo, pulverizing for 25min, and sieving with 80 mesh sieve to obtain semen Ginkgo powder;
step two, preparing a gingko kernel extracting solution: mixing semen Ginkgo powder and 70% ethanol solution at a mass ratio of 1: 10, placing into a reaction kettle, and stirring at 55 deg.C at 800r/min for 50min to obtain semen Ginkgo extractive solution;
step three, preparing a mixed solution: mixing the semen Ginkgo extract obtained in step two with 35-45% sodium silicate solution at a mass ratio of 1: 1, and stirring at 800r/min for 50min to obtain mixed solution;
step four, preparing modified nano silicon dioxide: pouring the mixed solution into a reaction kettle, adding hydrochloric acid with the mass fraction of 30% into the reaction kettle, adjusting the pH of the mixed solution to 5, stirring and reacting at the temperature of 50 ℃ at 800r/min for 3h, and discharging to obtain the modified nano silicon dioxide.
In this embodiment, preferably, the preparation process of the camphor tree extract includes the following steps:
step one, taking raw materials: taking the following components in parts by weight: 40 parts of camphor tree branches and leaves, 80 parts of complex enzyme and 200 parts of sodium chloride solution;
step two, preparing the camphor tree extract: cleaning branches and leaves of camphor trees according to the weight parts, crushing the branches and leaves of the camphor trees into 80 meshes, adding complex enzyme for treating the branches and leaves for 170min, adding sodium chloride solution, heating and boiling the mixture for 70min, filtering the mixture to obtain filter residues and filtrate, and drying the filtrate until the water content is one third of the original volume to obtain the camphor tree extract.
In this embodiment, preferably, the complex enzyme is prepared by mixing cellulase, hemicellulase and ligninase in a mass ratio of 3:1: 5.
In this embodiment, preferably, the preparation process of the papaya extract includes the following steps: removing pulp of fructus Chaenomelis, only leaving skin and seed, pulverizing to 80 mesh, adding water twice the weight of skin and seed, heating and distilling to obtain distillate, treating the distillate in 300r/min centrifuge for 30min, and collecting supernatant to obtain fructus Chaenomelis extract.
In this embodiment, preferably, the surfactant is an anionic surfactant, and the anionic surfactant is one or a mixture of several of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium fatty alcohol-polyoxyethylene ether sulfate, and sodium alpha-olefin sulfonate.
The working principle and the advantages of the invention are as follows: according to the floor wax, the modified nano silicon dioxide is added, and the gingko kernel and the nano silicon dioxide are combined, so that the modified nano silicon dioxide has the properties of flavonoid compounds, the antibacterial effect of the floor wax is improved, and in addition, the nano silicon dioxide is in a net structure, is high in strength and good in wear resistance, so that the prepared floor wax has good strength and good wear resistance, and can effectively protect a floor; the natural floor wax is safe and nontoxic, has good insect resistance and increased corrosion resistance by adding the gingko, the lavender, the nardostachys chinensis bunge, the lemon, the mint, the golden cypress and the shinyleaf pricklyash root into the floor wax, and is added with the camphor tree extract and the papaya extract to replace a chemical aromatic, so that the fragrance of the floor wax is increased, the safety is increased, and the floor wax is green and healthy.
The following experiments were carried out on floor wax commonly used in the production and by the floor wax of the present invention, and the contents and results of the experiments are shown in the following table
Through various experiments, the wear resistance, insect resistance, antibacterial performance and corrosion resistance of the floor wax prepared in the examples 1, 2 and 3 are improved, and the example 2 is the best example.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (8)
1. The floor wax suitable for floors with different base materials is characterized by comprising the following raw materials in parts by weight: 40-80 parts of insect wax, 25-55 parts of white oil, 8-32 parts of silicone oil, 8-22 parts of propolis, 20-30 parts of modified nano silicon dioxide, 10-25 parts of camphor tree extract, 12-24 parts of pawpaw extract, 4-8 parts of ginkgo, 3-6 parts of lavender, 2-6 parts of nardostachys chinensis, 10-15 parts of lemon, 4-7 parts of mint, 4-6 parts of golden cypress, 2-5 parts of radix zanthoxyli and 2-3 parts of surfactant.
The preparation method of the floor wax also comprises a preparation process of the floor wax, wherein the preparation process of the floor wax comprises the following steps:
step one, raw material preparation: the raw materials are selected according to the following parts by weight: 40-80 parts of insect wax, 25-55 parts of white oil, 8-32 parts of silicone oil, 8-22 parts of propolis, 20-30 parts of modified nano silicon dioxide, 10-25 parts of camphor tree extract, 12-24 parts of pawpaw extract, 4-8 parts of ginkgo, 3-6 parts of lavender, 2-6 parts of nardostachys chinensis, 10-15 parts of lemon, 4-7 parts of mint, 4-6 parts of golden cypress, 2-5 parts of radix zanthoxyli and 2-3 parts of surfactant;
step two, preparing filtrate: pulverizing semen Ginkgo, Lavender, rhizoma Nardostachyos, fructus Citri Limoniae, herba Menthae, cortex Phellodendri, and radix Zanthoxyli to 10-25 mesh, mixing, adding ethanol, refluxing for 1-2 hr, and filtering to obtain filtrate;
step three, heating and melting: heating insect wax, white oil and silicone oil to a molten state to obtain a mixture;
step four, mixing the raw materials: adding propolis and the filtrate obtained in the second step into the mixture obtained in the third step, uniformly mixing, and performing rotary evaporation to remove ethanol solvent;
step five, preparing floor wax: adding the modified nano silicon dioxide, the camphor tree extract, the pawpaw extract and the surfactant into the mixture treated in the fourth step, keeping the temperature at 75-95 ℃, stirring for reaction for 1-3h at 1500r/min for 1000-.
2. The floor wax suitable for floors with different base materials as claimed in claim 1, which comprises the following raw materials in parts by weight: 50-70 parts of insect wax, 30-50 parts of white oil, 10-20 parts of silicone oil, 10-15 parts of propolis, 24-28 parts of modified nano silicon dioxide, 12-18 parts of camphor tree extract, 16-20 parts of pawpaw extract, 5-7 parts of ginkgo, 4-5 parts of lavender, 3-5 parts of nardostachys chinensis, 12-14 parts of lemon, 5-6 parts of mint, 4-5 parts of golden cypress, 3-4 parts of radix zanthoxyli and 2.4-2.8 parts of surfactant.
3. The floor polish of claim 1, wherein the floor polish comprises: the material comprises the following raw materials in parts by weight: 60 parts of insect wax, 40 parts of white oil, 15 parts of silicone oil, 12 parts of propolis, 26 parts of modified nano silicon dioxide, 15 parts of camphor tree extract, 18 parts of pawpaw extract, 6 parts of ginkgo, 4 parts of lavender, 4 parts of nard, 13 parts of lemon, 6 parts of mint, 4.5 parts of golden cypress, 3.5 parts of radix zanthoxyli and 2.5 parts of surfactant.
4. The floor polish of claim 1, wherein the floor polish comprises: the preparation process of the modified nano silicon dioxide comprises the following steps:
step one, preparing gingko kernel powder: cleaning semen Ginkgo, pulverizing for 20-30min, and sieving with 60-120 mesh sieve to obtain semen Ginkgo powder;
step two, preparing a gingko kernel extracting solution: mixing the silver almond powder and 65-75% of ethanol solution according to the mass ratio of 1: 10, putting the mixture into a reaction kettle, and stirring and reacting at the temperature of 50-60 ℃ at the speed of 600-1000r/min for 40-60min to obtain a silver almond extracting solution;
step three, preparing a mixed solution: mixing the gingko kernel extract obtained in the step two with 35-45% of sodium silicate solution according to the mass ratio of 1: 1, and stirring and reacting at 600-1000r/min for 40-60min to obtain a mixed solution;
step four, preparing modified nano silicon dioxide: pouring the mixed solution into a reaction kettle, adding 25-35% by mass of hydrochloric acid into the reaction kettle, adjusting the pH of the mixed solution to 4-6, stirring and reacting at the temperature of 40-70 ℃ at 1000r/min for 3-4h, and discharging to obtain the modified nano silicon dioxide.
5. The floor polish of claim 1, wherein the floor polish comprises: the preparation process of the camphor tree extract comprises the following steps:
step one, taking raw materials: taking the following components in parts by weight: 30-60 parts of camphor tree branches and leaves, 60-120 parts of complex enzyme and 300 parts of sodium chloride solution;
step two, preparing the camphor tree extract: cleaning the branches and leaves of the camphor trees according to the parts by weight, crushing the branches and leaves of the camphor trees into 60-90 meshes, adding complex enzyme for treating for 150-180min, adding sodium chloride solution, heating and boiling for 60-80min, filtering to obtain filter residues and filtrate, and drying the filtrate until the water content is one third of the original volume to obtain the camphor tree extract.
6. The floor polish of claim 5, wherein the floor polish comprises: the compound enzyme is prepared by mixing cellulase, hemicellulase and ligninase according to the mass part ratio of 3:1: 5.
7. The floor polish of claim 1, wherein the floor polish comprises: the preparation process of the pawpaw extract comprises the following steps: firstly, removing pulp of pawpaw, only reserving skin and seeds, crushing to 70-90 meshes, adding water with the weight twice that of the skin and the seeds, heating and distilling to obtain distillate, treating the distillate in a 200-400r/min centrifuge for 20-40min, and taking supernatant to obtain the pawpaw extract.
8. The floor polish of claim 1, wherein the floor polish comprises: the surfactant is an anionic surfactant, and the anionic surfactant is one or a mixture of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium fatty alcohol-polyoxyethylene ether sulfate and alpha-olefin sodium sulfonate.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103275621A (en) * | 2013-05-21 | 2013-09-04 | 苏州富通高新材料科技股份有限公司 | Chinese herbal medicine inset-prevention and antibiotic floor wax and preparation method thereof |
| CN106833394A (en) * | 2016-12-06 | 2017-06-13 | 阜阳市伟叶家具有限公司 | A kind of plant floor wax |
| CN110283534A (en) * | 2019-06-12 | 2019-09-27 | 何治华 | A kind of preparation method of antibacterial floor wax |
| US20190380946A1 (en) * | 2017-01-24 | 2019-12-19 | Nutri-Woods Bio-Tech (Beijing) Co., Ltd. | Plant composition, preparation method and application thereof |
| CN112322192A (en) * | 2020-12-03 | 2021-02-05 | 上海鑫曾化工科技有限公司 | Floor wax suitable for floors with different base materials |
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2021
- 2021-08-23 CN CN202110966142.3A patent/CN113512362A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103275621A (en) * | 2013-05-21 | 2013-09-04 | 苏州富通高新材料科技股份有限公司 | Chinese herbal medicine inset-prevention and antibiotic floor wax and preparation method thereof |
| CN106833394A (en) * | 2016-12-06 | 2017-06-13 | 阜阳市伟叶家具有限公司 | A kind of plant floor wax |
| US20190380946A1 (en) * | 2017-01-24 | 2019-12-19 | Nutri-Woods Bio-Tech (Beijing) Co., Ltd. | Plant composition, preparation method and application thereof |
| CN110283534A (en) * | 2019-06-12 | 2019-09-27 | 何治华 | A kind of preparation method of antibacterial floor wax |
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