CN113480825A - Process for preparing hot melt adhesive elastic grid by using plastic suction method - Google Patents

Process for preparing hot melt adhesive elastic grid by using plastic suction method Download PDF

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Publication number
CN113480825A
CN113480825A CN202110735442.0A CN202110735442A CN113480825A CN 113480825 A CN113480825 A CN 113480825A CN 202110735442 A CN202110735442 A CN 202110735442A CN 113480825 A CN113480825 A CN 113480825A
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Prior art keywords
melt adhesive
hot melt
elastic grid
adhesive elastic
plastic suction
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CN202110735442.0A
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CN113480825B (en
Inventor
李健生
王佩朝
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PINGHU ZHANPENG HOT MELT ADHESIVE WEB & FILM CO LTD
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PINGHU ZHANPENG HOT MELT ADHESIVE WEB & FILM CO LTD
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/24Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/10Forming by pressure difference, e.g. vacuum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a process for preparing a hot melt adhesive elastic grid by a plastic suction method, which comprises the steps of placing hydrogenated styrene-butadiene block copolymer and white oil in a specific proportion into a heated stirrer, stirring and filling oil, and adding polypropylene, silica anti-adhesion master batch, an antistatic agent and an antioxidant into the heated stirrer after the oil is filled; and (3) casting the uniformly mixed raw materials into a film by a single-screw extruder, and simultaneously carrying out vacuum suction on the cast film through a nickel screen with square holes to prepare the hot melt adhesive elastic grid. The invention adopts the hydrogenated styrene-butadiene block copolymer with low melting point and high melt index as the matrix material, and can meet the compounding requirement under the condition that the fabric does not change color and does not become hard; the casting film is a transverse and longitudinal grid with a vertical stem through nickel mesh vacuum forming of square holes, transverse and longitudinal mechanical properties can be exerted under the condition that the ventilation effect is guaranteed, and the casting film has high tensile strength, so that the use requirement of the shaping clothes is met.

Description

Process for preparing hot melt adhesive elastic grid by using plastic suction method
Technical Field
The invention relates to preparation of an elastic hot melt adhesive net for shaping clothes, in particular to a process for preparing a hot melt adhesive elastic grid by a plastic uptake method.
Background
The body shaping clothes are made by adopting human engineering, belong to a functional underwear of an adjustable type, and are called body beautifying clothes, body shaping clothes, shaping clothes and the like, and have soft hand feeling, good rebound resilience and good shaping. Currently, in the preparation process of shaping clothes on the market, the main application is polyurethane type glue film or glue net, but the glue of the type has some defects, such as:
1. the specific gravity of the polyurethane is higher and is 1.2g/cm3The plastic cement is made of a higher material, and the polyurethane with higher gram weight can influence the hand feeling;
2. the general yellowing resistance of polyurethane is poor, the yellowing time is mainly prolonged by adding a UV (ultraviolet) auxiliary agent in the industry at present, but for some white or light-colored fabrics, the yellowing time is only delayed by adding the UV auxiliary agent, and the yellowing resistance of the fabrics cannot be improved;
3. the polyurethane net film fiber is in a non-woven fabric shape in a random way, so the tensile strength and the recovery rate are greatly reduced, and the effect required by shaping clothes can not be achieved.
The above problems may cause the texture of the shaping clothes to be decreased, and the shaping clothes are not durable, so that the ideal using effect of the shaping clothes is difficult to achieve, and thus the requirements of consumers cannot be met.
Therefore, the invention provides a process for preparing the hot melt adhesive elastic grid by a plastic uptake method to solve the problems.
Disclosure of Invention
The invention aims to provide a process for preparing a hot melt adhesive elastic grid by a plastic uptake method aiming at the defects in the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme:
a process for preparing a hot melt adhesive elastic grid by a plastic suction method comprises the following steps of (by mass), preparing the hot melt adhesive elastic grid by using 40-70% of hydrogenated styrene-butadiene block copolymer, 5-20% of polypropylene, 1-5% of silicon dioxide master batch, 2-8% of antistatic agent, 20-40% of white oil and 0.1-0.2% of antioxidant; the hot melt adhesive elastic grid is prepared according to the following steps:
s1: placing hydrogenated styrene-butadiene block copolymer in a 50-80 deg.C stirrer, adding white oil into the stirrer three times at an interval of 10min each time, and stirring;
s2: adding polypropylene, silicon dioxide master batch, antistatic agent and antioxidant, and continuously stirring for 10 min;
s3: and extruding the mixed raw materials into a single screw to form a casting film, and simultaneously carrying out vacuum suction on the casting film through a nickel net with square holes to prepare the hot melt adhesive elastic grid.
Preferably, the hydrogenated styrene-butadiene block copolymer has a melting point of 120-140 ℃ and a melt index of 40-220g/10min at a temperature of 230 ℃ and a load of 2.16 kg.
Preferably, the antistatic agent is a polyether chain segment based polyamide permanent antistatic agent and is in an interpenetrating network structure.
Preferably, in step S3, the vacuum suction roll is under negative pressure when the nickel screen is vacuum-formed, and is controlled by a ross blower; a hot air device is arranged right above the plastic suction position of the plastic suction roller; the hot air device heats the casting film at the plastic suction position to 80-120 ℃.
Preferably, the hot melt adhesive elastic grid and the glassine release paper are bonded together in a false pressing mode, and the method comprises the following specific steps: loading the cast film subjected to plastic uptake into an unreeling frame, and unreeling the cast film without tension; then the elastic grid enters a wool roller filled with cooling water; and finally, allowing the heavy stripped glassine release paper to enter a preheating roller group, and rolling after the glassine release paper is subjected to counter-pressure pseudo-adhesion at the roller.
In the preparation of the hot melt adhesive elastic grid and tape release paper, the unwinding device adopts a tension-free controller, so that the adhesive net can be prevented from stretching and deforming; the wool roller is cooled and adhered to the elastic grid by the residual heat of the glassine release paper.
Compared with the prior art, the invention has the beneficial effects that:
1. the elastic grid adopts hydrogenated styrene-butadiene block copolymer with the melting point of 120-140 ℃ and the melting point of 40-220g/10min (230-2.16 kg) as the matrix material, has much lower melting point and much higher melting point than the traditional SEBS, and can meet the compounding requirement under the condition that the fabric does not change color and does not become hard; the elongation at break of the rubber net of the hydrogenated styrene-butadiene block copolymer system can reach 800 percent.
2. In order to ensure the uniformity and stability of the prepared film, the hydrogenated styrene-butadiene block copolymer material is subjected to heating oil filling treatment, so that the processing performance of the material can be greatly improved, and the film can be easily broken into grids instead of being stretched and lengthened in the plastic sucking process.
3. The permanent antistatic agent added in the invention belongs to a polymer type antistatic agent, and can play a good antistatic effect without precipitation of a small molecular antistatic agent.
4. The silicon dioxide master batch adopted by the invention is an anti-adhesion master batch compounded by gas phase method silicon dioxide as a main material, a plurality of opening agents and a slipping agent, and can ensure that a casting film is not sticky at high temperature, thereby reducing the plastic uptake difficulty and improving the yield.
5. The elastic grid is formed by vacuum forming of the nickel net with the square holes, the grid is of a cross-shaped structure with transverse and longitudinal stems vertical, transverse and longitudinal mechanical properties can be exerted under the effect of air permeability, the tensile strength is high, if the nickel net with the diamond holes is used for vacuum forming, the transverse and longitudinal tensile strength is lost by about 30%, and the elongation rate is greatly reduced.
6. The elastic grid prepared by the invention can be deeply processed, namely the grid is lined on the glassine release paper in a false adhesion mode, so that the positioning and cutting are convenient during use.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The test methods or test methods described in the following examples are conventional methods unless otherwise specified; the reagents and materials, unless otherwise indicated, are conventionally obtained commercially or prepared by conventional methods.
Example 1
The hot melt adhesive elastic grid of the embodiment comprises, by mass%, 60% of hydrogenated styrene-butadiene block copolymer, 10% of polypropylene, 5% of silica master batch, 5% of antistatic agent, 20% of white oil and 0.15% of antioxidant; the hot melt adhesive elastic grid is prepared according to the following steps:
s1: placing hydrogenated styrene-butadiene block copolymer in a stirrer at 60 deg.C, adding white oil into the stirrer three times at an interval of 10min each time, and stirring;
s2: adding polypropylene, silicon dioxide master batch, antistatic agent and antioxidant, and continuously stirring for 10 min;
s3: and extruding the mixed raw materials into a single screw to form a casting film, and simultaneously carrying out vacuum suction on the casting film through a nickel net with square holes to prepare the hot melt adhesive elastic grid.
In step S3, negative pressure is formed in the plastic suction roller when the nickel screen is subjected to vacuum plastic suction and is controlled by a Ross blower; a hot air device is arranged right above the plastic suction position of the plastic suction roller; the casting film at the blister position was heated to 100 ℃ by a hot air device.
In this example, the hydrogenated styrene-butadiene block copolymer had a melting point of 120-140 ℃ and a melting point of 40-220g/10min (230-2.16 kg).
Example 2
The hot melt adhesive elastic grid of the embodiment comprises, by mass%, 50% of hydrogenated styrene-butadiene block copolymer, 15% of polypropylene, 2% of silica master batch, 3% of antistatic agent, 30% of white oil and 0.15% of antioxidant; the hot melt adhesive elastic grid is prepared according to the following steps:
s1: placing hydrogenated styrene-butadiene block copolymer in a stirrer at 80 deg.C, adding white oil into the stirrer three times, each time at an interval of 10min, and stirring;
s2: adding polypropylene, silicon dioxide master batch, antistatic agent and antioxidant, and continuously stirring for 10 min;
s3: and extruding the mixed raw materials into a single screw to form a casting film, and simultaneously carrying out vacuum suction on the casting film through a nickel net with square holes to prepare the hot melt adhesive elastic grid.
In step S3, negative pressure is formed in the plastic suction roller when the nickel screen is subjected to vacuum plastic suction and is controlled by a Ross blower; a hot air device is arranged right above the plastic suction position of the plastic suction roller; the cast film at the blister position was heated to 120 ℃ by a hot air device.
In this example, the hydrogenated styrene-butadiene block copolymer had a melting point of 120-140 ℃ and a melting point of 40-220g/10min (230-2.16 kg).
Example 3
The hot melt adhesive elastic grid of the embodiment comprises, by mass%, 40% of hydrogenated styrene-butadiene block copolymer, 10% of polypropylene, 5% of silica master batch, 5% of antistatic agent, 40% of white oil and 0.15% of antioxidant; the hot melt adhesive elastic grid is prepared according to the following steps:
s1: placing hydrogenated styrene-butadiene block copolymer in a 75 deg.C stirrer, adding white oil into the stirrer three times at an interval of 10min each time, and stirring;
s2: adding polypropylene, silicon dioxide master batch, antistatic agent and antioxidant, and continuously stirring for 10 min;
s3: and extruding the mixed raw materials into a single screw to form a casting film, and simultaneously carrying out vacuum suction on the casting film through a nickel net with square holes to prepare the hot melt adhesive elastic grid.
In step S3, negative pressure is formed in the plastic suction roller when the nickel screen is subjected to vacuum plastic suction and is controlled by a Ross blower; a hot air device is arranged right above the plastic suction position of the plastic suction roller; the cast film at the blister position was heated to 110 ℃ by a hot air device.
In this example, the hydrogenated styrene-butadiene block copolymer had a melting point of 120-140 ℃ and a melting point of 40-220g/10min (230-2.16 kg).
Example 4
The hot melt adhesive elastic grid of the embodiment comprises, by mass%, 70% of hydrogenated styrene-butadiene block copolymer, 20% of polypropylene, 5% of silica master batch, 8% of antistatic agent, 40% of white oil and 0.2% of antioxidant; the hot melt adhesive elastic grid is prepared according to the following steps:
s1: placing hydrogenated styrene-butadiene block copolymer in a stirrer at 80 deg.C, adding white oil into the stirrer three times, each time at an interval of 10min, and stirring;
s2: adding polypropylene, silicon dioxide master batch, antistatic agent and antioxidant, and continuously stirring for 10 min;
s3: and extruding the mixed raw materials into a single screw to form a casting film, and simultaneously carrying out vacuum suction on the casting film through a nickel net with square holes to prepare the hot melt adhesive elastic grid.
In step S3, negative pressure is formed in the plastic suction roller when the nickel screen is subjected to vacuum plastic suction and is controlled by a Ross blower; a hot air device is arranged right above the plastic suction position of the plastic suction roller; the cast film at the blister position was heated to 120 ℃ by a hot air device.
In this example, the hydrogenated styrene-butadiene block copolymer had a melting point of 120-140 ℃ and a melting point of 40-220g/10min (230-2.16 kg).
Example 5
The elastic grid prepared by the invention can be deeply processed, namely the grid is lined on glassine release paper in a false adhesion mode, and the method comprises the following specific steps: filling the cast films formed by plastic suction in the embodiments 1 to 4 into a unreeling frame, and unreeling by tension-free; then the elastic grid enters a wool roller filled with cooling water; and finally, allowing the heavy stripped glassine release paper to enter a preheating roller group, and rolling after the glassine release paper is subjected to counter-pressure pseudo-adhesion at the roller.
In conclusion, the elastic grid adopts the hydrogenated styrene-butadiene block copolymer with the melting point of 120-140 ℃ and the melting point of 40-220g/10min (230-2.16 kg) as the matrix material, has a melting point which is much lower than that of the traditional SEBS and is much higher than that of the traditional SEBS, and can meet the compounding requirement under the condition that the fabric does not change color and does not become hard; the elongation at break of the rubber net of the hydrogenated styrene-butadiene block copolymer system can reach 800 percent. The film is vacuum-formed into a transverse and longitudinal grid with a vertical stem by a nickel net with square holes, so that transverse and longitudinal mechanical properties can be exerted under the condition of ensuring the ventilation effect, and the film has high tensile strength. The elastic grid prepared by the invention has good elasticity, can meet the use requirement of shaping clothes, and can be deeply processed, namely the grid is lined on glassine release paper in a false bonding mode, so that the positioning and cutting during use are convenient.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (5)

1. The process for preparing the hot melt adhesive elastic grid by the plastic suction method is characterized in that the hot melt adhesive elastic grid comprises, by mass, 40% -70% of hydrogenated styrene-butadiene block copolymer, 5% -20% of polypropylene, 1% -5% of silicon dioxide master batch, 2% -8% of antistatic agent, 20% -40% of white oil and 0.1% -0.2% of antioxidant; the hot melt adhesive elastic grid is prepared according to the following steps:
s1: placing hydrogenated styrene-butadiene block copolymer in a 50-80 deg.C stirrer, adding white oil into the stirrer three times at an interval of 10min each time, and stirring;
s2: adding polypropylene, silicon dioxide master batch, antistatic agent and antioxidant, and continuously stirring for 10 min;
s3: and extruding the mixed raw materials into a single screw to form a casting film, and simultaneously carrying out vacuum suction on the casting film through a nickel net with square holes to prepare the hot melt adhesive elastic grid.
2. The process for preparing a hot melt adhesive elastic grid by the vacuum forming method as claimed in claim 1, wherein the melting point of the hydrogenated styrene-butadiene block copolymer is 120-140 ℃, and the melt index of the hydrogenated styrene-butadiene block copolymer is 40-220g/10min at a temperature of 230 ℃ and a load of 2.16 kg.
3. The process for preparing the hot melt adhesive elastic grid by the plastic suction method according to claim 1, wherein the antistatic agent is a polyether chain segment based polyamide permanent antistatic agent and is in an interpenetrating network structure.
4. The process for preparing the hot melt adhesive elastic grid by the plastic suction method according to the claim 1, wherein in the step S3, the inside of the plastic suction roller is in negative pressure when the nickel screen is subjected to vacuum plastic suction, and the process is controlled by a Ross blower; a hot air device is arranged right above the plastic suction position of the plastic suction roller; the hot air device heats the casting film at the plastic suction position to 80-120 ℃.
5. The process for preparing the hot melt adhesive elastic grid by the plastic uptake method according to claim 4, wherein the hot melt adhesive elastic grid is bonded with glassine release paper in a pressing and false mode, and the specific steps are as follows: loading the cast film subjected to plastic uptake into an unreeling frame, and unreeling the cast film without tension; then the elastic grid enters a wool roller filled with cooling water; and finally, allowing the heavy stripped glassine release paper to enter a preheating roller group, and rolling after the glassine release paper is subjected to counter-pressure pseudo-adhesion at the roller.
CN202110735442.0A 2021-06-30 2021-06-30 Process for preparing hot melt adhesive elastic grid by plastic suction method Active CN113480825B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090325447A1 (en) * 2008-06-30 2009-12-31 James Austin Elastic Composite Formed from Multiple Laminate Structures
CN108517076A (en) * 2018-04-24 2018-09-11 武汉工程大学 A kind of degradable plastic uptake sheet material and preparation method thereof
CN109090720A (en) * 2018-06-25 2018-12-28 宏杰内衣股份有限公司 A kind of seamless body modelling dress of far infrared
CN109536054A (en) * 2018-12-13 2019-03-29 深圳百凯纺织辅料有限公司 A kind of compound elastic gum net and preparation method thereof
CN110964289A (en) * 2019-11-05 2020-04-07 南通普力马弹性体技术有限公司 Antistatic elastomer material and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090325447A1 (en) * 2008-06-30 2009-12-31 James Austin Elastic Composite Formed from Multiple Laminate Structures
CN108517076A (en) * 2018-04-24 2018-09-11 武汉工程大学 A kind of degradable plastic uptake sheet material and preparation method thereof
CN109090720A (en) * 2018-06-25 2018-12-28 宏杰内衣股份有限公司 A kind of seamless body modelling dress of far infrared
CN109536054A (en) * 2018-12-13 2019-03-29 深圳百凯纺织辅料有限公司 A kind of compound elastic gum net and preparation method thereof
CN110964289A (en) * 2019-11-05 2020-04-07 南通普力马弹性体技术有限公司 Antistatic elastomer material and preparation method thereof

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