CN113463400A - Antibacterial cloth and manufacturing process thereof - Google Patents
Antibacterial cloth and manufacturing process thereof Download PDFInfo
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- CN113463400A CN113463400A CN202110753965.8A CN202110753965A CN113463400A CN 113463400 A CN113463400 A CN 113463400A CN 202110753965 A CN202110753965 A CN 202110753965A CN 113463400 A CN113463400 A CN 113463400A
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- antibacterial
- antibacterial agent
- cloth
- master batch
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 77
- 239000004744 fabric Substances 0.000 title claims abstract description 76
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 61
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 32
- 238000010041 electrostatic spinning Methods 0.000 claims abstract description 27
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003054 catalyst Substances 0.000 claims abstract description 16
- -1 polyhexamethylene guanidine Polymers 0.000 claims abstract description 14
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 9
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 4
- 150000001336 alkenes Chemical class 0.000 claims abstract description 3
- 238000002844 melting Methods 0.000 claims abstract description 3
- 230000008018 melting Effects 0.000 claims abstract description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 5
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical group O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 238000001523 electrospinning Methods 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 3
- 230000007774 longterm Effects 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 5
- 235000017491 Bambusa tulda Nutrition 0.000 description 5
- 241001330002 Bambuseae Species 0.000 description 5
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 5
- 239000011425 bamboo Substances 0.000 description 5
- 239000003610 charcoal Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229940070527 tourmaline Drugs 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
- 239000011032 tourmaline Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
- C08F212/22—Oxygen
- C08F212/24—Phenols or alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/42—Oxides or hydroxides of copper, silver or gold
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
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- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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Abstract
The invention discloses an antibacterial cloth and a manufacturing process thereof. The manufacturing process comprises the following steps: olefin treatment of organic antibacterial agent: taking 5-methyl-2-isopropyl phenol, and reacting in a catalyst to obtain a treated organic antibacterial agent; adding an organic antibacterial agent and butadiene into a reaction kettle, adding a catalyst, and reacting to obtain master batch A containing the antibacterial agent; adding an organic antibacterial agent and styrene into a reaction kettle, adding a catalyst, and reacting to obtain master batch B containing the antibacterial agent; heating and melting the base particle A containing the antibacterial agent, the master batch B containing the antibacterial agent, the polyhexamethylene guanidine and the n-butyl alcohol, and preparing the antibacterial cloth by adopting an electrostatic spinning method; and (5) carrying out hydrophobic treatment to obtain the product. According to the invention, the antibacterial agent raw material is modified and then polymerized with butadiene or styrene, so that the antibacterial agent is bonded in the master batch, and the antibacterial cloth prepared by a subsequent method has a long-term antibacterial effect.
Description
Technical Field
The invention belongs to the field of antibiosis, and particularly relates to an antibacterial cloth and a manufacturing process thereof.
Background
The antibacterial cloth is a cloth with an antibacterial effect, is usually made of antibacterial fabric, and has the effects of hydrophobicity, breathability and antibacterium. The antibacterial cloth can be applied to the medical or living field. Such as medical disposable bedsheets, operation table cloths and the like.
The principle of non-antibacterial is that an antibacterial agent is usually added, and the antibacterial agent is generally divided into a natural antibacterial agent, an organic antibacterial agent and an inorganic antibacterial agent. However, the existing antibacterial cloth generally has the defects of poor antibacterial effect, easy shedding of antibacterial substances, influence on service life and the like. Through a great deal of research, the applicant finds that the reasons are mainly the method problem of the antibacterial cloth in the manufacturing process and the problem of the treatment of the manufactured cloth, so that the existing antibacterial cloth has poor effect.
For example, chinese patent CN202010944701.6 discloses a method for preparing an antibacterial fabric and an antibacterial fabric, in which the antibacterial fabric is prepared by directly soaking the antibacterial agent in the antibacterial agent and then making the fabric, which is easy to cause the antibacterial agent to fall off. The invention adopts a new treatment method, and can effectively overcome the problem that the antibacterial agent is easy to fall off.
Disclosure of Invention
The invention overcomes the defects and provides the antibacterial cloth and the manufacturing process thereof, and the antibacterial cloth has the efficient and lasting antibacterial effect.
The technical scheme of the invention is as follows.
A manufacturing process of antibacterial cloth comprises the following steps:
(1) olefin treatment of organic antibacterial agent: taking an organic antibacterial agent (5-methyl-2-isopropylphenol) to react for 6-7h at the temperature of 500 ℃ and 700 ℃ in the presence of a catalyst to obtain a treated organic antibacterial agent;
(2) adding the organic antibacterial agent obtained in the step (1) and butadiene into a reaction kettle according to the mass ratio of 1-2: 1, adding a catalyst, and reacting at 100-150 ℃ for 5-6h to obtain a master batch A containing the antibacterial agent;
(3) adding the organic antibacterial agent obtained in the step (1) and styrene in a ratio of 1-2: 1 into a reaction kettle, adding a catalyst, and reacting at 100-150 ℃ for 4-7h to obtain a master batch B containing the antibacterial agent;
(4) heating and melting the antibacterial agent-containing base particle A, the antibacterial agent-containing master particle B, the polyhexamethylene guanidine and the n-butyl alcohol obtained in the step (2), and preparing the antibacterial cloth by adopting an electrostatic spinning method;
(5) and (4) carrying out hydrophobic treatment on the antibacterial cloth obtained in the step (3).
In the invention, in the step (1), the catalyst is ferric oxide.
In the present invention, in the step (2) and the step (3), the catalyst is hydrogen peroxide.
In the invention, in the step (3), the addition amount of the antibacterial agent-containing base particle A, the antibacterial agent-containing master particle B, the polyhexamethylene guanidine and the n-butyl alcohol satisfies the mass ratio of 1-2: 3: 2-3: 5.
in the invention, in the step (4), the electrostatic spinning parameter is 8-50 kV.
In the invention, in the step (4), the inner diameter of the electrostatic spinning spinneret is 0.2-1 m.
In the invention, in the step (4), the flow rate of the solution is 5-50 ml/h, the temperature of the molten master batch slurry in the electrostatic spinning nozzle is 120-150 ℃, and the distance between the electrostatic spinning nozzle and the receiving device is controlled to be 15-30 cm.
In the invention, in the step (5), the specific steps are as follows: and soaking the antibacterial cloth in 15-20% polydimethylsiloxane ethanol solution for 2-4 h.
In the present application, the modification reaction formula in step (1) is as follows:
the reaction formula of the step (2) is as follows:
the reaction formula of the step (3) is as follows:
the polymerization degree of all polymers is 100000-500000. In the application, the antibacterial cloth is prepared by adopting two master batches, fusing and then combining the antibacterial agent and adopting an electrostatic spinning method. The master batch prepared from the treated organic antibacterial agent prepared in the step (1) in the application can enable the final antibacterial cloth to have a long-term antibacterial effect, and the antibacterial performance of the product can be obviously improved by the polyhexamethylene guanidine added in the step (4). In addition, the applicant finds out through a large amount of research that the antibacterial cloth is subjected to hydrophobic treatment, so that the antibacterial effect can be further improved, and bacteria are not easy to breed in application. The product of the invention can be loaded on other cloth.
The product of the invention can be applied to medical bedsheets, surgical drapes and surgical table cloths.
In the invention, the adopted electrostatic spinning method is to carry 8-50 kV high-voltage static electricity, and charged polymer liquid drops are accelerated at the Taylor cone vertex of the capillary under the action of an electric field force. The polymer droplets overcome surface tension to form a jet stream. The solvent is evaporated or solidified in the fine flow in the spraying process, and finally the fine flow falls on a receiving device to obtain the antibacterial cloth.
Compared with the prior art, the invention has the advantages that:
according to the invention, the antibacterial agent raw material is modified and then polymerized with butadiene or styrene, so that the antibacterial agent is bonded in the master batch, and the antibacterial cloth prepared by a subsequent method has a long-term antibacterial effect.
Drawings
FIG. 1 is a 1000-fold microscope image of a common commercial nonwoven fabric placed in the air for 24 hours.
FIG. 2 is a 500-fold image of the antibacterial fabric in example 1, which is taken under a microscope and is enlarged 24 hours in the air.
FIG. 3 is a 1000-fold image of the antibacterial fabric in example 1, which is taken under a microscope and is enlarged 24 hours in the air.
FIG. 4 is a 1000-fold image of the antibacterial fabric in example 2, which is taken under a microscope and is enlarged 24 hours in the air.
FIG. 5 is a 1000-fold image of the antibacterial fabric in example 3, which is taken under a microscope and is enlarged 24 hours in the air.
Detailed Description
The present invention will be described in further detail with reference to specific examples, but the embodiments of the present invention are not limited thereto, and may be carried out with reference to conventional techniques for process parameters not particularly noted.
Example 1
(1) Taking 10mol of 5-methyl-2-isopropyl phenol, adding ferric oxide into a reaction kettle, and reacting for 6h at 600 ℃ to obtain the treated antibacterial agent.
(2) Adding 7mol of the organic antibacterial agent obtained in the step (1) and 7mol of butadiene into a reaction kettle, adding hydrogen peroxide, and reacting at 150 ℃ for 6h to obtain master batch A containing the antibacterial agent.
(3) Adding 9mol of the organic antibacterial agent obtained in the step (1) and 7mol of styrene into a reaction kettle, adding a catalyst, and reacting at 150 ℃ for 7h to obtain master batch B containing the antibacterial agent;
(4) and (3) heating 5mol of the master batch A obtained in the step (2), 10mol of the master batch B obtained in the step (3), 5mol of polyhexamethylene guanidine and 10 milliliters of n-butyl alcohol to 150 ℃ to melt the master batch, and preparing the antibacterial cloth by adopting an electrostatic spinning method, wherein the electrostatic spinning parameter is 35kV, the inner diameter of an electrostatic spinning spinneret is 0.2m, the solution flow rate is 10ml/h, the temperature of the master batch slurry in a molten state in the electrostatic spinning spinneret is 140 ℃, and the distance between the electrostatic spinning spinneret and a receiving device is controlled to be 15 cm. In this embodiment, a super-absorbent antibacterial fabric is laid on the receiving device, the fabric is woven by bamboo charcoal fibers, an antibacterial layer is coated on the bamboo charcoal fibers, and the antibacterial layer is prepared from the following materials:
100g of attapulgite, 100g of volcanic ash, 500g of clay, 50g of medical stone, 30g of titanium dioxide, 20g of cuprous oxide and 70g of magnesium tourmaline are ground to 200 meshes, 1000g of water is added for stirring, then precipitates are obtained by centrifugation and then fired, the firing is carried out by heating to 500 ℃ for 2 hours, then heating to 1000 ℃ for 3.5 hours, then heating to 1600 ℃ for 3 hours, and the material after firing is ground to 200 meshes according to the proportion of 1: 1, adding glue, and coating on the cloth woven by the bamboo charcoal fiber.
In this embodiment, the filamentous material sprayed from the electrospinning spinneret covers two sides of the fabric woven from the bamboo charcoal fiber coated with the antibacterial layer, respectively, wherein the antibacterial fabric quality of the upper side is controlled, and the antibacterial fabric quality of the lower side and the fabric woven from the bamboo charcoal fiber coated with the antibacterial layer have a mass of 1: 2: 1.
(5) and (3) placing the prepared antibacterial cloth in 15% polydimethylsiloxane ethanol solution for 4h to obtain the antibacterial cloth.
Example 2
(1) Taking 15mol of 5-methyl-2-isopropyl phenol, adding ferric oxide into a reaction kettle, and reacting for 6h at 600 ℃ to obtain the treated antibacterial agent.
(2) Adding 10mol of the organic antibacterial agent obtained in the step (1) and 9mol of butadiene into a reaction kettle, adding hydrogen peroxide, and reacting at 140 ℃ for 6h to obtain master batch A containing the antibacterial agent.
(3) Adding 14mol of the organic antibacterial agent obtained in the step (1) and 7mol of styrene into a reaction kettle, adding a catalyst, and reacting at 140 ℃ for 7 hours to obtain master batch B containing the antibacterial agent;
(4) heating the obtained master batch A5 mol, the master batch B7 mol, polyhexamethylene guanidine 5mol and n-butanol 10ml to 130 ℃ to melt the master batch A and the master batch B, preparing the antibacterial cloth by adopting an electrostatic spinning method, wherein the electrostatic spinning parameter is voltage 50kV, the inner diameter of an electrostatic spinning spinneret is 0.5m, the solution flow rate is 30ml/h, the temperature of the master batch slurry in a molten state in the electrostatic spinning spinneret is 150 ℃, and the distance between the electrostatic spinning spinneret and a receiving device is controlled to be 15cm, in the embodiment, the receiving device is paved with waterproof cloth (PE cloth); in this embodiment, the filamentous material sprayed from the electrospinning spinneret is covered on both sides of the waterproof cloth, wherein the mass of the antibacterial cloth on the upper side is controlled, and the mass of the antibacterial cloth on the lower side and the mass of the waterproof cloth are controlled to be 1: 2: 1.
(5) and (3) placing the prepared antibacterial cloth in 15% polydimethylsiloxane ethanol solution for 4h to obtain the antibacterial cloth.
Example 3
(1) Taking 10mol of 5-methyl-2-isopropyl phenol, adding ferric oxide into a reaction kettle, and reacting at 600 ℃ for 6.5h to obtain the treated antibacterial agent.
(2) Adding 8mol of the organic antibacterial agent obtained in the step (1) and 8mol of butadiene into a reaction kettle, adding hydrogen peroxide, and reacting at 150 ℃ for 5h to obtain master batch A containing the antibacterial agent.
(3) Adding 8mol of the organic antibacterial agent obtained in the step (1) and 8mol of styrene into a reaction kettle, adding a catalyst, and reacting at 150 ℃ for 7h to obtain master batch B containing the antibacterial agent;
(4) and (3) heating 6mol of master batch A and 8mol of master batch B obtained in the step (2), 6mol of polyhexamethylene guanidine and 10ml of n-butyl alcohol to 150 ℃ to melt the master batch A and the master batch B, preparing the antibacterial cloth by adopting an electrostatic spinning method, wherein the electrostatic spinning parameter is voltage of 15kV, the inner diameter of an electrostatic spinning spinneret is 0.2m, the solution flow rate is 10ml/h, the temperature of the molten master batch slurry in the electrostatic spinning spinneret is 140 ℃, and the distance between the electrostatic spinning spinneret and a receiving device is controlled to be 15 cm. In this embodiment, a common knitted fabric is laid on the receiving device.
In this embodiment, the filamentous material sprayed from the electrospinning spinneret covers two sides of the knitted fabric, respectively, wherein the mass of the antibacterial fabric on the upper side is controlled, and the mass of the antibacterial fabric on the lower side and the mass of the knitted fabric are 1: 3: 1.
(5) and (3) placing the prepared antibacterial cloth in a 20% polydimethylsiloxane ethanol solution for 4h to obtain the antibacterial cloth.
The antibacterial fabric obtained in examples 1 to 3 is placed in the air for 24 hours and observed under the microscope magnification, and meanwhile, common non-woven fabrics on the market are compared, as shown in fig. 1 to 5, wherein fig. 2 and 3 are pictures of 500 times and 1000 times of microscope magnification after the antibacterial fabric in example 1 is placed in the air for 24 hours, and compared with fig. 1, bacteria are visible in fig. 1, but fig. 2 and 3 do not. Similarly, fig. 4 and 5 do not show any antibacterial effect, and it can be seen that the antibacterial cloth of the present invention has a significant antibacterial effect.
Claims (9)
1. The manufacturing process of the antibacterial cloth is characterized by comprising the following steps of:
(1) olefin treatment of organic antibacterial agent: reacting the organic antibacterial agent for 6-7h at the temperature of 500 ℃ and 700 ℃ in the presence of a catalyst to obtain the treated organic antibacterial agent; the organic antibacterial agent is 5-methyl-2-isopropyl phenol;
(2) adding the organic antibacterial agent obtained in the step (1) and butadiene into a reaction kettle according to the mass ratio of 1-2: 1, adding a catalyst, and reacting at 100-150 ℃ for 5-6h to obtain a master batch A containing the antibacterial agent;
(3) adding the organic antibacterial agent obtained in the step (1) and styrene in a ratio of 1-2: 1 into a reaction kettle, adding a catalyst, and reacting at 100-150 ℃ for 4-7h to obtain a master batch B containing the antibacterial agent;
(4) heating and melting the antibacterial agent-containing base particle A, the antibacterial agent-containing master particle B, the polyhexamethylene guanidine and the n-butyl alcohol obtained in the step (2), and preparing the antibacterial cloth by adopting an electrostatic spinning method;
(5) and (4) carrying out hydrophobic treatment on the antibacterial cloth obtained in the step (3).
2. The process for manufacturing the antibacterial cloth according to claim 1, wherein in the step (1), the catalyst is ferric oxide.
3. The process for preparing the antibacterial cloth according to claim 1, wherein in the step (2) and the step (3), the catalyst is hydrogen peroxide.
4. The manufacturing process of the antibacterial cloth according to claim 1, wherein in the step (3), the addition amount of the antibacterial agent-containing base particle A, the antibacterial agent-containing master particle B, the polyhexamethylene guanidine and the n-butanol is 1-2: 3: 2-3: 5.
5. the manufacturing process of the antibacterial cloth according to claim 1, wherein in the step (4), the electrostatic spinning parameter is 8-50 kV.
6. The process for manufacturing the antibacterial cloth according to claim 1, wherein in the step (4), the inner diameter of the electrospinning spinneret is 0.2-1 m.
7. The process for manufacturing the antibacterial cloth according to claim 1, wherein in the step (4), the flow rate of the solution is 5-50 ml/h, the temperature of the molten master batch slurry in the electrostatic spinning nozzle is 120-150 ℃, and the distance between the electrostatic spinning nozzle and the receiving device is controlled to be 15-30 cm.
8. The manufacturing process of the antibacterial cloth according to claim 1, wherein in the step (5), the specific steps are as follows: and soaking the antibacterial cloth in 15-20% polydimethylsiloxane ethanol solution for 2-4 h.
9. An antibacterial cloth prepared by the manufacturing process of any one of claims 1 to 7.
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