CN113461432A - Anti-scouring anhydrous stemming - Google Patents

Anti-scouring anhydrous stemming Download PDF

Info

Publication number
CN113461432A
CN113461432A CN202110859061.3A CN202110859061A CN113461432A CN 113461432 A CN113461432 A CN 113461432A CN 202110859061 A CN202110859061 A CN 202110859061A CN 113461432 A CN113461432 A CN 113461432A
Authority
CN
China
Prior art keywords
parts
powder
mesh
silicon carbide
granules
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110859061.3A
Other languages
Chinese (zh)
Inventor
张翠青
薛文东
蒲李刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gongyi Fuhao Metallurgical Materials Co ltd
Original Assignee
Gongyi Fuhao Metallurgical Materials Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gongyi Fuhao Metallurgical Materials Co ltd filed Critical Gongyi Fuhao Metallurgical Materials Co ltd
Priority to CN202110859061.3A priority Critical patent/CN113461432A/en
Publication of CN113461432A publication Critical patent/CN113461432A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C04B35/101Refractories from grain sized mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3865Aluminium nitrides
    • C04B2235/3869Aluminium oxynitrides, e.g. AlON, sialon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40Metallic constituents or additives not added as binding phase
    • C04B2235/402Aluminium
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/422Carbon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/428Silicon

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Ceramic Products (AREA)

Abstract

The invention relates to the technical field of refractory materials, in particular to an anti-scouring anhydrous stemming, which comprises a dry material and environment-friendly resin oil, wherein the dry material comprises corundum aggregate, silicon carbide granules, coke granules, high-alumina fine powder, silicon carbide micro powder, active alumina powder, metal silicon, a metal sialon compound and clay in specific weight parts, the environment-friendly resin oil is a novel bonding agent which is treated by a high-pressure kettle and has harmful gas discharge amount meeting national requirements, the raw materials are stirred and mixed according to a certain proportion to prepare the anti-scouring sewage-free stemming, and the mixture is added with the metal silicon and the metal sialon compound, so that on one hand, the anti-scouring capability of the material is improved by utilizing the sialon phase per se, on the other hand, under the high-temperature use environment of the metal sialon compound, the sialon is generated by in-situ reaction with alumina micro powder, silicon carbide micro powder and the like in the raw materials, so that the strength and the anti-scouring performance of the material are effectively improved.

Description

Anti-scouring anhydrous stemming
Technical Field
The invention relates to the technical field of refractory materials, in particular to an anti-scouring anhydrous stemming.
Background
The stemming is a refractory material for blocking the tap hole of the iron-making blast furnace, and the quality of the performance of the stemming is directly related to whether the blast furnace can safely operate or not. In the running process of the blast furnace, the stemming has three functions: blocking the tap hole, stably discharging molten iron and slag, protecting the hearth and prolonging the service life of the refractory bricks at the bottom of the blast furnace. With the development of new steel smelting technology, modern blast furnaces develop towards large-scale, ultra-large-scale, automatic, long-life, high-pressure, high-strength and other smelting directions, and are intensively smelted by adopting high-blast-temperature, high-pressure furnace top, coal injection, computer control and other high-technology, and meanwhile, the utilization coefficient of the blast furnaces is higher and higher, the daily iron output is higher and higher, so that the working conditions and the technical requirements of stemming are increasingly strict. The stemming is gradually converted into a functional refractory material from a pure consumable refractory material, and the enlargement of a blast furnace puts higher requirements on the strength of anhydrous stemming. The production finds that the existing anhydrous stemming can not meet the use requirement and needs to maintain the blast furnace at high frequency, so the anhydrous stemming with high anti-scouring performance and suitable for the iron-making blast furnace is needed.
Disclosure of Invention
In order to solve the problems, the invention provides an anti-scouring anhydrous stemming, which comprises a dry material and environment-friendly resin oil, wherein the dry material comprises corundum aggregate, silicon carbide granules, coke granules, high-alumina fine powder, silicon carbide micro powder, activated alumina powder, metal silicon, a metal sialon compound and clay in a specific weight proportion, the environment-friendly resin oil is novel inorganic environment-friendly resin oil, the raw materials are stirred and mixed according to a certain proportion and a certain adding mode to prepare the anti-scouring sewage-free stemming, and the metal silicon and the metal sialon compound are added into the mixture, so that on one hand, the anti-scouring capability of the material is improved by utilizing the sialon phase per se, on the other hand, under the high-temperature use environment, the sialon is generated by in-situ reaction with alumina micro powder, silicon carbide micro powder and the like in the raw materials, so that the strength and the anti-scouring performance of the material are effectively improved.
The invention provides an anti-scouring anhydrous stemming for solving the problems, which comprises a dry material and environment-friendly resin oil, wherein the dry material comprises the following raw materials in parts by weight: 10-20 parts of brown corundum granules, 10-17 parts of white corundum granules, 5-10 parts of silicon carbide granules, 8-15 parts of coke granules, 5-10 parts of high-aluminum fine powder, 6-10 parts of 200-mesh silicon carbide powder, 2-5 parts of 325-mesh silicon carbide powder, 3-8 parts of metal sialon compound, 2-6 parts of activated alumina powder, 1-5 parts of silicon micropowder, 5-12 parts of Guangxi clay and 1-5 parts of metal silicon, wherein the weight parts of the environment-friendly resin oil are 8-15 parts.
As a further scheme of the anti-scouring anhydrous stemming, the particle size of the brown corundum particles is 1-2mm, the particle size of the white corundum particles is 0.21-1mm, the particle size of the silicon carbide particles is 0.21-1mm, the particle size of the coke particles is 0.21-1mm, the high-aluminum fine powder is 200-mesh powder, the Guangxi clay is 200-mesh powder, and the metal silicon is 325-mesh powder.
As a further scheme of the anti-scouring anhydrous stemming, the dry material comprises the following raw materials in parts by weight: 10 parts of brown corundum particles with the particle size of 1-2mm, 10 parts of white corundum particles with the particle size of 0.21-1mm, 5 parts of silicon carbide particles with the particle size of 0.21-1mm, 8 parts of coke particles with the particle size of 0.21-1mm, 5 parts of 200-mesh high-aluminum fine powder, 6 parts of 200-mesh silicon carbide powder, 2 parts of 325-mesh silicon carbide powder, 3 parts of metal sialon compound, 2 parts of activated alumina powder, 1 part of silicon micro powder, 5 parts of 200-mesh Guangxi clay and 1 part of 325-mesh metal silicon, and 8 parts of environment-friendly resin oil.
As a further scheme of the anti-scouring anhydrous stemming, the dry material comprises the following raw materials in parts by weight: 20 parts of brown corundum granules with the granularity of 1-2mm, 17 parts of white corundum granules with the granularity of 0.21-1mm, 10 parts of silicon carbide granules with the granularity of 0.21-1mm, 15 parts of coke granules with the granularity of 0.21-1mm, 10 parts of 200-mesh high-aluminum fine powder, 10 parts of 200-mesh silicon carbide powder, 5 parts of 325-mesh silicon carbide powder, 8 parts of metal sialon compound, 6 parts of activated alumina powder, 5 parts of silicon micropowder, 12 parts of 200-mesh Guangxi clay and 15 parts of 325-mesh metal silicon, and 15 parts of environment-friendly resin oil.
As a further scheme of the anti-scouring anhydrous stemming, the dry material comprises the following raw materials in parts by weight: 15 parts of brown corundum granules with the granularity of 1-2mm, 13 parts of white corundum granules with the granularity of 0.21-1mm, 8 parts of silicon carbide granules with the granularity of 0.21-1mm, 11 parts of coke granules with the granularity of 0.21-1mm, 8 parts of 200-mesh high-alumina fine powder, 8 parts of 200-mesh silicon carbide powder, 3.5 parts of 325-mesh silicon carbide powder, 5.5 parts of metal sialon compound, 4 parts of active alumina powder, 3 parts of silicon micropowder, 8 parts of 200-mesh Guangxi clay and 3 parts of 325-mesh metal silicon, and 11.5 parts of environment-friendly resin oil.
Compared with the prior art, the invention has the following beneficial effects: through adding metal silicon and metal sialon compound in this scheme, utilize the sialon of material self to promote the holistic scour resistance of stemming on the one hand in the use, on the other hand metal sialon compound and the aluminium oxide miropowder in the raw materials, carborundum miropowder etc. normal position reaction production sialon under high temperature environment, it is that stemming intensity can further improve, in the organic environmental protection resin oil in the material, beta resin content is higher, can further promote stemming intensity with material reaction at high temperature, thereby promote stemming's scour resistance.
Detailed Description
Example 1
The anti-scouring anhydrous stemming comprises a dry material and environment-friendly resin oil, wherein the dry material comprises the following raw materials in parts by weight: 10-20 parts of brown corundum particles, 10-17 parts of white corundum particles, 5-10 parts of silicon carbide particles, 8-15 parts of coke particles, 5-10 parts of high-aluminum fine powder, 6-10 parts of 200-mesh silicon carbide powder, 2-5 parts of 325-mesh silicon carbide powder, 3-8 parts of metal sialon compound, 2-6 parts of activated alumina powder, 1-5 parts of silicon micropowder, 5-12 parts of Guangxi clay and 1-5 parts of metal silicon, wherein the environment-friendly resin oil is 8-15 parts by weight, and is novel organic environment-friendly resin oil. The particle size of the brown corundum particle material is 1-2mm, the particle size of the white corundum particle material is 0.21-1mm, the particle size of the silicon carbide particle material is 0.21-1mm, the particle size of the coke particle material is 0.21-1mm, the high-aluminum fine powder is 200 meshes of powder, the Guangxi clay is 200 meshes of powder, and the metal silicon is 325 meshes of powder.
The anhydrous stemming of the scheme comprises corundum aggregate, silicon carbide granules, coke granules, high-alumina fine powder, silicon carbide micro powder, activated alumina powder, metal silicon, a metal sialon compound and clay in a specific weight ratio, the environment-friendly silicon-aluminum alloy material is prepared by mixing and stirring the environment-friendly silicon-aluminum alloy material and organic environment-friendly resin oil in specific parts by weight, and metal silicon and a metal sialon compound are added in the formula, so that on one hand, the anti-scouring capability of the material is improved by utilizing the sialon phase per se, on the other hand, the metal sialon compound reacts with alumina micro powder and silicon carbide micro powder in the raw material at high temperature in situ, the high-temperature bonding strength of the material is improved, the anti-scouring performance of the material is improved, the beta resin content in the organic environment-friendly resin oil used in the scheme is higher, and a high-strength carbon bonding structure is formed between the organic environment-friendly resin oil and the mixture material at high temperature, so that the high-strength carbon bonding structure is beneficial to improving the slag and anti-scouring performance of the stemming, and is particularly suitable for various furnace types with higher utilization coefficient of a blast furnace. The physical and chemical indexes of the anti-scour anhydrous stemming prepared by the embodiment are as follows.
Al2O3(%) C(%) SiC(%) Bulk Density (g/cm)3 Line change rate (%) Compressive strength MPa (1200 ℃ x 3h)
35~40 5~30 16~22 ≥2.0 +0.1~+0.5 ≥30
Example 2
The anti-scouring anhydrous stemming comprises a dry material and environment-friendly resin oil, wherein the dry material comprises the following raw materials in parts by weight: 10 parts of brown corundum particles with the particle size of 1-2mm, 10 parts of white corundum particles with the particle size of 0.21-1mm, 5 parts of silicon carbide particles with the particle size of 0.21-1mm, 8 parts of coke particles with the particle size of 0.21-1mm, 5 parts of 200-mesh high-aluminum fine powder, 6 parts of 200-mesh silicon carbide powder, 2 parts of 325-mesh silicon carbide powder, 3 parts of metal sialon compound, 2 parts of activated alumina powder, 1 part of silicon micro powder, 5 parts of 200-mesh Guangxi clay and 1 part of 325-mesh metal silicon, and 8 parts of environment-friendly resin oil.
Example 3
The anti-scouring anhydrous stemming comprises a dry material and environment-friendly resin oil, wherein the dry material comprises the following raw materials in parts by weight: 20 parts of brown corundum granules with the granularity of 1-2mm, 17 parts of white corundum granules with the granularity of 0.21-1mm, 10 parts of silicon carbide granules with the granularity of 0.21-1mm, 15 parts of coke granules with the granularity of 0.21-1mm, 10 parts of 200-mesh high-aluminum fine powder, 10 parts of 200-mesh silicon carbide powder, 5 parts of 325-mesh silicon carbide powder, 8 parts of metal sialon compound, 6 parts of activated alumina powder, 5 parts of silicon micropowder, 12 parts of 200-mesh Guangxi clay and 15 parts of 325-mesh metal silicon, and 15 parts of environment-friendly resin oil.
Example 4
The anti-scouring anhydrous stemming comprises a dry material and environment-friendly resin oil, wherein the dry material comprises the following raw materials in parts by weight: 15 parts of brown corundum granules with the granularity of 1-2mm, 13 parts of white corundum granules with the granularity of 0.21-1mm, 8 parts of silicon carbide granules with the granularity of 0.21-1mm, 11 parts of coke granules with the granularity of 0.21-1mm, 8 parts of 200-mesh high-alumina fine powder, 8 parts of 200-mesh silicon carbide powder, 3.5 parts of 325-mesh silicon carbide powder, 5.5 parts of metal sialon compound, 4 parts of active alumina powder, 3 parts of silicon micropowder, 8 parts of 200-mesh Guangxi clay and 3 parts of 325-mesh metal silicon, and 11.5 parts of environment-friendly resin oil.
Although the present invention has been described with reference to a preferred embodiment, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (5)

1. An antiscour anhydrous stemming which is characterized in that: the environment-friendly resin oil comprises a dry material and environment-friendly resin oil, wherein the dry material comprises the following raw materials in parts by weight: 10-20 parts of brown corundum granules, 10-17 parts of white corundum granules, 5-10 parts of silicon carbide granules, 8-15 parts of coke granules, 5-10 parts of high-aluminum fine powder, 6-10 parts of 200-mesh silicon carbide powder, 2-5 parts of 325-mesh silicon carbide powder, 3-8 parts of metal sialon compound, 2-6 parts of activated alumina powder, 1-5 parts of silicon micropowder, 5-12 parts of Guangxi clay and 1-5 parts of metal silicon, wherein the weight parts of the environment-friendly resin oil are 8-15 parts.
2. An antiscour waterless stemming as defined in claim 1, wherein: the particle size of the brown corundum particle material is 1-2mm, the particle size of the white corundum particle material is 0.21-1mm, the particle size of the silicon carbide particle material is 0.21-1mm, the particle size of the coke particle material is 0.21-1mm, the high-aluminum fine powder is 200 meshes of powder, the Guangxi clay is 200 meshes of powder, and the metal silicon is 325 meshes of powder.
3. An antiscour waterless stemming as defined in claim 2, wherein: the dry material comprises the following raw materials in parts by weight: 10 parts of brown corundum particles with the particle size of 1-2mm, 10 parts of white corundum particles with the particle size of 0.21-1mm, 5 parts of silicon carbide particles with the particle size of 0.21-1mm, 8 parts of coke particles with the particle size of 0.21-1mm, 5 parts of 200-mesh high-aluminum fine powder, 6 parts of 200-mesh silicon carbide powder, 2 parts of 325-mesh silicon carbide powder, 3 parts of metal sialon compound, 2 parts of activated alumina powder, 1 part of silicon micro powder, 5 parts of 200-mesh Guangxi clay and 1 part of 325-mesh metal silicon, and 8 parts of environment-friendly resin oil.
4. An antiscour waterless stemming as defined in claim 2, wherein: the dry material comprises the following raw materials in parts by weight: 20 parts of brown corundum granules with the granularity of 1-2mm, 17 parts of white corundum granules with the granularity of 0.21-1mm, 10 parts of silicon carbide granules with the granularity of 0.21-1mm, 15 parts of coke granules with the granularity of 0.21-1mm, 10 parts of 200-mesh high-aluminum fine powder, 10 parts of 200-mesh silicon carbide powder, 5 parts of 325-mesh silicon carbide powder, 8 parts of metal sialon compound, 6 parts of activated alumina powder, 5 parts of silicon micropowder, 12 parts of 200-mesh Guangxi clay and 15 parts of 325-mesh metal silicon, and 15 parts of environment-friendly resin oil.
5. An antiscour waterless stemming as defined in claim 2, wherein: the dry material comprises the following raw materials in parts by weight: 15 parts of brown corundum granules with the granularity of 1-2mm, 13 parts of white corundum granules with the granularity of 0.21-1mm, 8 parts of silicon carbide granules with the granularity of 0.21-1mm, 11 parts of coke granules with the granularity of 0.21-1mm, 8 parts of 200-mesh high-alumina fine powder, 8 parts of 200-mesh silicon carbide powder, 3.5 parts of 325-mesh silicon carbide powder, 5.5 parts of metal sialon compound, 4 parts of active alumina powder, 3 parts of silicon micropowder, 8 parts of 200-mesh Guangxi clay and 3 parts of 325-mesh metal silicon, and 11.5 parts of environment-friendly resin oil.
CN202110859061.3A 2021-07-28 2021-07-28 Anti-scouring anhydrous stemming Pending CN113461432A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110859061.3A CN113461432A (en) 2021-07-28 2021-07-28 Anti-scouring anhydrous stemming

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110859061.3A CN113461432A (en) 2021-07-28 2021-07-28 Anti-scouring anhydrous stemming

Publications (1)

Publication Number Publication Date
CN113461432A true CN113461432A (en) 2021-10-01

Family

ID=77883073

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110859061.3A Pending CN113461432A (en) 2021-07-28 2021-07-28 Anti-scouring anhydrous stemming

Country Status (1)

Country Link
CN (1) CN113461432A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115259868A (en) * 2022-07-28 2022-11-01 江西联达冶金有限公司 Anhydrous stemming based on environment-friendly resin

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS649877A (en) * 1987-07-03 1989-01-13 Nippon Kokan Kk Pouring material for hot metal-carrying vessel
US5783509A (en) * 1996-03-04 1998-07-21 Pem Abrasifs Refractaires Process for preparing a refractory powder from spent contact masses issuing from the production of silanes, and to refactory products obtained therefrom
CN1485300A (en) * 2002-09-29 2004-03-31 宝山钢铁股份有限公司 Sialon combined fireproof material containing aluminum silicon alloy
CN102219532A (en) * 2011-03-29 2011-10-19 中国地质大学(北京) Preparation method of refractory Fe-Sialon raw material
CN103172389A (en) * 2011-12-22 2013-06-26 中冶建筑研究总院有限公司 Blast furnace gun mud added with SiAlON synthesized through coal ash and preparation method of blast furnace gun mud
CN108610067A (en) * 2018-05-18 2018-10-02 中钢集团耐火材料有限公司 A kind of silicon carbide articles and preparation method thereof of Gao Sailong phases
CN110937883A (en) * 2019-11-07 2020-03-31 浙江锦诚新材料股份有限公司 Cement-free iron runner castable

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS649877A (en) * 1987-07-03 1989-01-13 Nippon Kokan Kk Pouring material for hot metal-carrying vessel
US5783509A (en) * 1996-03-04 1998-07-21 Pem Abrasifs Refractaires Process for preparing a refractory powder from spent contact masses issuing from the production of silanes, and to refactory products obtained therefrom
CN1485300A (en) * 2002-09-29 2004-03-31 宝山钢铁股份有限公司 Sialon combined fireproof material containing aluminum silicon alloy
CN102219532A (en) * 2011-03-29 2011-10-19 中国地质大学(北京) Preparation method of refractory Fe-Sialon raw material
CN103172389A (en) * 2011-12-22 2013-06-26 中冶建筑研究总院有限公司 Blast furnace gun mud added with SiAlON synthesized through coal ash and preparation method of blast furnace gun mud
CN108610067A (en) * 2018-05-18 2018-10-02 中钢集团耐火材料有限公司 A kind of silicon carbide articles and preparation method thereof of Gao Sailong phases
CN110937883A (en) * 2019-11-07 2020-03-31 浙江锦诚新材料股份有限公司 Cement-free iron runner castable

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
XUEYIN LIU ET. AL: "Fe-Sialon-Ti(C,N) composites from carbothermal reduction-nitridation of low-priced minerals and their application in taphole clay refractories", 《CERAMICS INTERNATIONAL》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115259868A (en) * 2022-07-28 2022-11-01 江西联达冶金有限公司 Anhydrous stemming based on environment-friendly resin

Similar Documents

Publication Publication Date Title
CN107973610B (en) Silicon carbide ramming mass taking waste silicon carbide saggar as main raw material
EP2767597B1 (en) Method of reduction processing of steel-making slag
CN107673756B (en) Mineral hot furnace magnesia anhydrous stemming and preparation method thereof
CN106946554B (en) Anhydrous stemming
CN106544464A (en) Environment-friendly type splashing slag in converter material and preparation method thereof
CN107963895A (en) A kind of blast furnace iron outlet groove castable in main trough
CN102020481A (en) Novel anhydrous stemming for blast furnace
CN109627026B (en) Regenerated silicon carbide Al2O3-SiC-C iron runner castable and preparation method thereof
CN108218448A (en) A kind of mineral hot furnace stemming and preparation method thereof
CN113461432A (en) Anti-scouring anhydrous stemming
CN110156445B (en) High-strength wear-resistant castable for rotary hearth furnace and preparation method thereof
CN111675545A (en) Blast furnace tapping channel castable
CN111646784A (en) Al (aluminum)2O3-SiC-C refractory castable and preparation method thereof
CN100395351C (en) Method for preparing cast material of AL2O3-SiC-Ciron runner
CN112225541B (en) Electric furnace gunning material and gunning furnace protection method
CN101602609B (en) Method for preparing Fe-Si3N4 fireproof raw material
CN100567216C (en) Desulfurization ladle brick
CN103936431B (en) A kind of fusion reducing furnace iron notch ramming mass
CN115650743B (en) Main runner castable containing calcium dialuminate
CN110256056B (en) Titanium-containing furnace protection ramming mass for overall restoration of blast furnace hearth and use method
CN114315388B (en) Anti-splashing anhydrous stemming for blast furnace and preparation method thereof
CN1680059A (en) Bottom fire-proof material of large steel ladle
CN108249900B (en) High performance Al2O3Additive for-SiC-C castable and preparation method thereof
KR101320083B1 (en) Binder for manufacturing Fe-containing briquettes using electric furnace reduction slag and manufacturing method thereof
CN110372388B (en) SiC combined Si for completely replacing blast furnace cooling wall inlaid brick3N4Castable and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20211001