CN113446792B - Deoxidization subassembly, storing device and refrigerator - Google Patents

Deoxidization subassembly, storing device and refrigerator Download PDF

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Publication number
CN113446792B
CN113446792B CN202010211417.8A CN202010211417A CN113446792B CN 113446792 B CN113446792 B CN 113446792B CN 202010211417 A CN202010211417 A CN 202010211417A CN 113446792 B CN113446792 B CN 113446792B
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Prior art keywords
oxygen scavenging
oxygen
electrolyte
cavity
gas
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CN202010211417.8A
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Chinese (zh)
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CN113446792A (en
Inventor
任志洁
任相华
张瑞钦
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Hefei Hualing Co Ltd
Midea Group Co Ltd
Hefei Midea Refrigerator Co Ltd
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Hefei Hualing Co Ltd
Midea Group Co Ltd
Hefei Midea Refrigerator Co Ltd
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Priority to CN202010211417.8A priority Critical patent/CN113446792B/en
Publication of CN113446792A publication Critical patent/CN113446792A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/12Arrangements of compartments additional to cooling compartments; Combinations of refrigerators with other equipment, e.g. stove
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3409Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23L3/3418Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D11/00Self-contained movable devices, e.g. domestic refrigerators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • F25D17/042Air treating means within refrigerated spaces
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D25/00Charging, supporting, and discharging the articles to be cooled
    • F25D25/02Charging, supporting, and discharging the articles to be cooled by shelves
    • F25D25/024Slidable shelves
    • F25D25/025Drawers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2317/00Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
    • F25D2317/04Treating air flowing to refrigeration compartments

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Nutrition Science (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses a deoxidizing component, a storage device and a refrigerator, and relates to the technical field of refrigeration storage equipment, wherein the deoxidizing component comprises a deoxidizing module and a separating structure in sealed connection with the deoxidizing module, the separating structure comprises a separating cavity formed by a cover plate and a top cover, an air overflow port is formed in the cover plate and is communicated with a liquid storage cavity and the separating cavity, partition plates are arranged on the cover plate at intervals in the extending direction and extend towards the top cover to enable the separating cavity to form a plurality of mutually independent separating cavities, the separating cavities are communicated through compression pipes, a return pipe is connected in each separating cavity, and an exhaust port communicated with the separating cavity is formed in the top cover. According to the invention, oxygen replaced by the deoxygenation module overflows from the upper part of the liquid level of the electrolyte to form a mixture, the mixture is discharged by the overflow port and then subjected to gas-liquid separation for a plurality of times under the action of the plurality of separation cavities and the compression pipes, and the separated electrolyte and water vapor flow back to the liquid storage cavity, so that the loss of the electrolyte in the deoxygenation module can be effectively reduced.

Description

Deoxidization subassembly, storing device and refrigerator
Technical Field
The invention relates to the technical field of refrigeration storage equipment, in particular to a deoxidizing component, a storage device and a refrigerator.
Background
In the related art, the refrigeration storage device can adjust the gas component proportion in the storage space of the refrigeration storage device through the oxygen removal module. The deoxidization module utilizes electrolyte to replace and discharge the oxygen in to the storing space to realize the fresh-keeping effect of hypoxemia. However, electrolyte and vapor can be taken away when the oxygen after current deoxidization module will replace is discharged from the electrolyte liquid level to influence the effect of oxygen replacement, and then influence deoxidization module to storage space's fresh-keeping effect.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art. Therefore, the invention provides the deoxidizing component which can effectively reduce the loss of electrolyte and water vapor and ensure the fresh-keeping effect of a storage space.
The invention also provides a storage device with the deoxidizing component.
The invention also provides a refrigerator with the deoxidizing assembly.
An oxygen scavenging assembly in accordance with an embodiment of the first aspect of the present invention comprises: the deoxidization module is internally provided with a liquid storage cavity for storing electrolyte; the isolating construction, the isolating construction is including being used for sealing the apron in stock solution chamber, and with at least part apron sealing connection's top cap, at least part the apron with be formed with the disengagement chamber between the top cap, be equipped with the overflow mouth on the apron, overflow mouth intercommunication the stock solution chamber with the disengagement chamber, the apron is equipped with the baffle at the interval on the extending direction, the baffle orientation the top cap extends so that the disengagement chamber forms a plurality of mutually independent separate chambers, be equipped with the compression pipe on the baffle so that it is adjacent to separate the chamber intercommunication, every separate the intracavity and all be connected with the back flow, it is a plurality of the lower extreme of back flow all is located extremely electrolyte liquid level below, the top cap is equipped with the gas vent, the gas vent with the overflow mouth is located the difference respectively separate the intracavity.
The oxygen removing assembly provided by the embodiment of the invention has at least the following beneficial effects:
through the stock solution chamber sealing connection separation structure at the deoxidization module, separation structure includes apron and top cap, oxygen after the deoxidization module replacement overflows from electrolyte liquid level top and forms the mixture, the overflow mouth discharges the mixture to the separation intracavity that apron and top cap formed so that the gas-liquid separation takes place for the mixture, the apron is equipped with the baffle in the extending direction thereby form a plurality of independent separate chambeies, only through compression pipe intercommunication between the adjacent separate chambeies, the mixture is compressed and gets into another separate chamber through the compression pipe when the mixture in separate intracavity accumulates to enough big pressure, the export area increases suddenly when discharging the mixture from the export of compression pipe, the mixture takes place gas-liquid separation once more, after the mixture carries out gas-liquid separation a plurality of times on its flow path, electrolyte liquid drop and vapor flow back to the stock solution chamber through the back flow, oxygen outwards discharges through the gas vent, thereby can effectively reduce the loss of electrolyte in the deoxidization module, the processing capacity of the deoxidizing component to oxygen in the storage space is guaranteed, and the fresh-keeping effect of the storage space is improved.
According to some embodiments of the invention, the overflow port and the exhaust port are located at opposite ends of the separation chamber, respectively.
According to some embodiments of the invention, the compression tubes on adjacent said baffles are staggered along the projection in a direction parallel to said baffles.
According to some embodiments of the invention, the compression tube has an inner diameter D that satisfies: d is more than or equal to 2mm and less than or equal to 10 mm.
According to some embodiments of the invention, the compression tube has a length L, the L satisfying: L/D is more than or equal to 2 and less than or equal to 3.
According to some embodiments of the present invention, a baffle is formed in each of the compartments of the cover plate, a plurality of the baffles are disposed in an inclined manner, and a plurality of the return pipes are respectively connected to the plurality of the baffles.
According to some embodiments of the present invention, the guide plate is provided with a guide hole, the guide hole is located at the lowest position of the guide plate in the up-down direction, and the guide hole is connected to the return pipe.
According to some embodiments of the invention, the cover plate is further provided with a pressure relief valve, and the pressure relief valve is communicated with the liquid storage cavity and arranged in a staggered manner with the top cover.
According to some embodiments of the invention, a water replenishing port is provided on the cover plate, and the water replenishing port is communicated with the liquid storage cavity.
According to a second aspect embodiment of the present invention, a storage device includes: the frame is internally provided with a storage space and is provided with an exhaust hole communicated with the storage space; the drawer is arranged in the frame through a guide rail; above embodiment the deoxidization subassembly, the deoxidization unit mount in the frame orientation the one end in exhaust hole, the deoxidization module have with the relative bleeder vent that sets up in exhaust hole, install the ventilated membrane on the bleeder vent.
According to the storage device provided by the embodiment of the invention, at least the following beneficial effects are achieved:
through the structure formed by the frame, the drawer and the deoxidizing component, oxygen in the storage space of the frame is discharged through the vent hole and enters the deoxidizing component through the breathable film on the vent hole, so that a low-oxygen negative pressure state is formed in the storage space, the oxygen content of the storage space is reduced, and the storage space has a low-oxygen fresh-keeping function; the drawer is arranged in the frame through a guide rail, so that a user can conveniently store and take food materials in the storage space; and the deoxidization subassembly adopts deoxidization module and separate structure's integrated configuration, can effectively reduce the loss of electrolyte in the deoxidization module, has guaranteed the throughput of deoxidization subassembly oxygen in to storage space, has promoted storage space's fresh-keeping effect.
A refrigerator according to an embodiment of a third aspect of the present invention includes the oxygen scavenging assembly described in the above embodiments.
According to the refrigerator provided by the embodiment of the invention, at least the following beneficial effects are achieved:
through deoxidization subassembly setting and stock solution chamber sealing connection's of deoxidization module separation structure, separation structure includes apron and top cap, oxygen after the deoxidization module replacement overflows from electrolyte liquid level top and forms the mixture, the flash port discharges the mixture to the separation intracavity that apron and top cap formed so that the gas-liquid separation takes place for the mixture, the apron is equipped with the baffle in the extending direction thereby form a plurality of independent separate chambeies, only communicate through the compression pipe between the adjacent separate chamber, the mixture is compressed and gets into another separate chamber through the compression pipe when the mixture that separates the intracavity accumulates to pressure big enough, export area increases suddenly when the export of compression pipe is discharged the mixture, gas-liquid separation takes place once more for the mixture, after the mixture carries out a plurality of gas-liquid separations in its flow path, electrolyte liquid drop and vapor pass through the back flow to the stock solution chamber, oxygen outwards discharges through the gas vent, thereby can effectively reduce the loss of electrolyte in the deoxidization module, guarantee the deoxidization subassembly to the throughput of the indoor oxygen of room of refrigerator, promote the fresh-keeping effect of refrigerator.
Additional aspects and advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
Drawings
The above and/or additional aspects and advantages of the present invention will become apparent and readily appreciated from the following description of the embodiments, taken in conjunction with the accompanying drawings of which:
fig. 1 is a schematic structural view of a refrigerator according to an embodiment of the present invention;
FIG. 2 is a schematic structural view of a storage device according to an embodiment of the present invention;
FIG. 3 is a rear view of the frame of FIG. 2;
FIG. 4 is a schematic perspective view of an oxygen scavenging assembly according to one embodiment of the present invention;
FIG. 5 is a partial cross-sectional view of FIG. 4;
fig. 6 is an enlarged view of a point a in fig. 5.
Reference numerals:
an oxygen scavenging assembly 10; a compartment 20; a storage device 30;
an oxygen removal module 100; a reservoir chamber 110; an air hole 120;
a separation structure 200; a cover plate 210; an overflow port 211; a return pipe 212; a deflector 213; flow guide holes 214; a top cover 220; an exhaust port 221; a separation chamber 230; a compartment 231; a partition 240; a compression tube 241; a pressure relief valve 250; a water replenishing port 260;
a frame 300; a storage space 310; an exhaust hole 320; a sidewall 330;
a drawer 400; a guide rail 410; a sealing strip 420.
Detailed Description
Reference will now be made in detail to embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to the same or similar elements or elements having the same or similar function throughout. The embodiments described below with reference to the accompanying drawings are illustrative only for the purpose of explaining the present invention and are not to be construed as limiting the present invention.
In the description of the present invention, it should be understood that the orientation or positional relationship referred to in the description of the orientation, such as the upper, lower, left, right, front, rear, etc., is based on the orientation or positional relationship shown in the drawings, and is only for convenience of description and simplification of description, and does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and thus, should not be construed as limiting the present invention.
In the description of the present invention, several means are one or more, and more means are two or more. If the first and second are described for the purpose of distinguishing technical features, they are not to be understood as indicating or implying relative importance or implicitly indicating the number of technical features indicated or implicitly indicating the precedence of the technical features indicated.
In the description of the present invention, unless otherwise specifically limited, terms such as set, installation, connection and the like should be understood in a broad sense, and those skilled in the art can reasonably determine the specific meanings of the above terms in the present invention by combining the specific contents of the technical solutions.
Referring to fig. 1, a refrigerator according to an embodiment of the present invention may be understood as a broad type of refrigeration storage device, including but not limited to, a refrigerator, an ice chest, and a freezer. The refrigerator of the embodiment comprises a compartment 20 for storing food materials, wherein a storage device 30 is arranged in the compartment 20, and the storage device 30 can further keep the food materials fresh. Referring to fig. 2, the storage device 30 according to an embodiment of the present invention includes an oxygen removing assembly 10, wherein the oxygen removing assembly 10 is in communication with the storage space 310 inside the storage device 30 and can treat oxygen inside the storage space 310, so as to reduce the oxygen content inside the storage space 310 and further improve the freshness-keeping effect of the storage device 30.
Referring to fig. 4, an oxygen scavenging assembly 10 according to one embodiment of the present invention, which is used in a refrigerator, includes an oxygen scavenging module 100. Specifically, the oxygen removal module 100 adopts the electrochemical principle, and oxygen entering the oxygen removal module 100 is subjected to oxidation-reduction reaction through electrodes and electrolyte, so that the oxygen is replaced and discharged. It can be understood that, when the gas in the storing space 310 contacts with the deoxidization module 100, deoxidization module 100 has a ventilated membrane (not shown in the figure) with storing space 310 intercommunication department, oxygen in the air enters into the electrolyte of deoxidization module 100 through the ventilated membrane, deoxidization module 100 consumes the oxygen in the storing space 310, make storing space 310 form the state of low oxygen negative pressure, oxygen constantly permeates to the electrolyte through the ventilated membrane, and deoxidization module 100 does not consume other gases (nitrogen is main) except oxygen in the air in the storing space 310, make other gaseous equilibrium states that form. Therefore, the oxygen removal module 100 can adjust the gas component ratio in the storage space 310, so as to obtain an environment rich in nitrogen and poor in oxygen, which is beneficial to keeping food materials in the storage space 310 fresh. Further, the environment rich in nitrogen and poor in oxygen can effectively inhibit the respiration of fruits and vegetables, reduce the consumption of organic substances, and can also make the cells of the fruits and vegetables slowly breathe, maintain the vitality of the cells and keep the excellent quality and the fragrant smell of the fruits and vegetables; but also can effectively inhibit the breeding of aerobic bacteria and anaerobic bacteria and prevent microorganisms from rotting fruits and vegetables. In addition, the environment rich in nitrogen and oxygen can also inhibit the activity of certain enzymes, inhibit the generation of ethylene, delay the after-ripening and aging process and keep the nutrition of the fruits fresh for a long time.
Referring to fig. 4 and 5, in the oxygen removal module 10 according to one embodiment of the present invention, a reservoir chamber 110 for storing electrolyte is defined in the oxygen removal module 100, oxygen is displaced from the reservoir chamber 110 through electrodes and the electrolyte, oxygen bubbles are formed in the electrolyte, and the oxygen bubbles are broken at the electrolyte level to overflow above the electrolyte level to form a mixture, wherein the mixture at least comprises oxygen, electrolyte droplets, water vapor and the like.
It is further noted that the oxygen removing assembly 10 of the embodiment of the present invention further includes a separating structure 200, the separating structure 200 includes a cover plate 210 for sealing the reservoir 110, and a top cover 220 connected to at least a portion of the cover plate 210 in a sealing manner, as shown in fig. 5 and 6, a separating cavity 230 is formed between at least a portion of the cover plate 210 and the top cover 220, an air overflow opening 211 is provided on the cover plate 210, the air overflow opening 211 communicates the reservoir 110 and the separating cavity 230, and the air overflow opening 211 is located above the liquid level of the electrolyte to discharge the mixture in the reservoir 110 to the separating cavity 230. It will be understood that the mixture in the reservoir 110 is discharged from the overflow port 211 by the air pressure after being accumulated to a certain extent, because the outlet of the overflow port 211 is communicated with the separation chamber 230, the area of the outlet of the overflow port 211 is suddenly increased, according to the flow formula: when the flow rate is constant, the passage area increases and the flow rate of the gas decreases, so that the electrolyte droplets fall by gravity and are separated from the oxygen and water vapor streams. In addition, the air overflow port 211 may have a through hole structure, a tubular structure, or the like, and is not particularly limited herein.
Referring to fig. 6, the cover plate 210 is provided with one or more partitions 240 at intervals in the extending direction, the partitions 240 are provided with one or more partitions 240, the partitions 240 extend towards the top cover 220 so that the separating chamber 230 forms a plurality of separate compartments 231, the partitions 240 are provided with compression pipes 241 so that adjacent compartments 231 are communicated, the adjacent compartments 231 are sealed with each other and are communicated only through the compression pipes 241, when the mixture in the compartments 231 is accumulated to a sufficient pressure, the mixture is compressed and enters the next compartment 231 along the airflow path through the compression pipes 241, and the outlet area of the airflow is suddenly increased when the mixture is discharged from the outlet of the compression pipes 241, according to the flow formula: when the flow rate is constant, the passage area increases, the flow rate of the gas decreases, and the mixture is separated again into gas and liquid, so that the oxygen gas flow can be further separated from the electrolyte droplets and the water vapor. In addition, each separation chamber 231 is connected with a return pipe 212, and the lower ends of the return pipes 212 are located below the electrolyte level, so that separated electrolyte droplets flow back to the liquid storage chamber 110 through the return pipes 212.
It can be understood that, when the mixture passes through the structure of the plurality of separation chambers 231 and the compression pipes 241 on the flow path of the mixture in the separation chamber 230, the mixture is subjected to gas-liquid separation for a plurality of times, the oxygen is separated more thoroughly, most of the electrolyte droplets and the water vapor flow back into the oxygen removal module 100 through the return pipe 212, the top cover 220 is provided with the exhaust port 221, and the oxygen is discharged outwards through the exhaust port 221, so that the loss of the electrolyte in the oxygen removal module 100 can be effectively reduced, the processing capacity of the oxygen removal assembly 10 on the oxygen in the storage space 310 is ensured, and the fresh-keeping effect of the storage space 310 is improved; the gas outlet 221 and the gas overflow port 211 are respectively located in different compartments 231, so that the mixture discharged from the gas overflow port 211 is prevented from being discharged from the gas outlet 221 without being compressed and amplified by the compartments 231, and the effect of gas-liquid separation is prevented from being influenced. It should be noted that the lower end of the return pipe 212 is located below the liquid level of the electrolyte, so that the mixture in the liquid storage chamber 110 is prevented from being discharged through the return pipe, and the gas-liquid separation effect of the gas overflow port 211 is prevented from being affected.
In some embodiments of the present invention, further, the gas overflow port 211 and the gas exhaust port 221 are respectively located at two opposite ends of the separation chamber 230, so that the mixture discharged from the gas overflow port 211 can pass through all the compartments 231 along the gas flow path in the separation chamber 230, so that the oxygen in the mixed gas flow can be completely separated and then discharged from the gas exhaust port 221, thereby further increasing the backflow amount of the electrolyte and reducing the loss of the electrolyte in the oxygen removal module 100.
Still further, one or more compression pipes 241 may be disposed on each partition 240, and the number of the compression pipes 241 on each partition 240 is designed according to actual needs and is not limited in detail herein. It should be noted that, the projections of the compression pipes 241 on the adjacent partition plates 240 are staggered in the direction parallel to the partition plates 240, so that all the compression pipes 241 on the two adjacent partition plates 240 are spaced apart from each other, and it is ensured that the mixture discharged from the outlets of the compression pipes 241 can be sufficiently separated into gas and liquid in each compartment 231, so that the separated electrolyte droplets and water vapor can flow into the return pipe 212 along the inner wall of the compartment 231, thereby preventing the mixture from entering the next compression pipe 241 for compression without sufficient gas and liquid separation, and improving the separation effect of each compression pipe 241 and the compartment 231 on the mixture.
Referring to fig. 6, in some embodiments of the invention, the compression tube 241 has an inner diameter D that satisfies: d is more than or equal to 2mm and less than or equal to 10 mm. The inner diameter D of the compression pipe 241 may be designed to be 2mm, 5mm, 8mm or 10mm, etc., which have a better gas-liquid separation effect on the mixture, and the specific inner diameter is not limited thereto. It can be understood that when the value of the inner diameter D is too small, the compression pipe 241 is difficult to process and costly, but the compression effect is not greatly improved; when the value of the inner diameter D is too large, the degree of compression of the mixture in the compression pipe 241 is small, and the effect of gas-liquid separation at the outlet of the compression pipe 241 is poor.
Referring to fig. 6, in some embodiments of the invention, the compression tube 241 has a length L that satisfies: L/D is more than or equal to 2 and less than or equal to 3. The length L of the compression pipe 241 may be 2 times, 2.5 times or 3 times the inner diameter D, and the like, and all have a better gas-liquid separation effect on the mixture, and the specific inner diameter is not limited in detail here. It can be understood that when the ratio of the length L to the inner diameter D is too small, the compression effect of the mixture is deteriorated when passing through the compression pipe 241, affecting the effect of gas-liquid separation at the outlet of the compression pipe 241; when the ratio of the length L to the inner diameter D is too large, the mixture is easily discharged at the outlet of the compression pipe 241 and directly enters the next compression pipe 241, resulting in poor gas-liquid separation.
Referring to fig. 6, in some embodiments of the present invention, a flow guide plate 213 is formed in each compartment 231 of the cover plate 210, the flow guide plates 213 are arranged in an inclined downward manner, and the plurality of return pipes 212 are respectively and correspondingly connected to the plurality of flow guide plates 213, so that after a mixture discharged from the gas overflow port 211 or the compression pipe 241 is subjected to gas-liquid separation in each compartment 231, electrolyte droplets fall to the surface of the flow guide plate 213 under the action of gravity, and the electrolyte droplets are accumulated on the surface of the flow guide plate 213 and then return to the liquid storage chamber 110 through the corresponding return pipe 212, thereby improving the efficiency of electrolyte return.
Furthermore, the guide plate 213 is provided with a guide hole 214, the guide hole 214 is located at the lowest position of the guide plate 213 along the up-down direction, and the guide hole 214 is connected with the return pipe 212, so that electrolyte droplets accumulated in the separation cavity 231 fall to the surface of the guide plate 213 under the action of gravity, flow into the guide hole 214 through the guide plate 213 after accumulation, and flow back to the electrolyte through the return pipe 212, thereby avoiding the electrolyte droplets and water from remaining in the separation cavity 231, and enabling the electrolyte to flow back more thoroughly.
Referring to fig. 4 and 5, in some embodiments of the present invention, a pressure release valve 250 is further disposed on the cover plate 210, the pressure release valve 250 is communicated with the liquid storage chamber 110 and is disposed in a staggered manner with respect to the top cover 220, when the air overflow port 211 cannot discharge oxygen in the liquid storage chamber 110 in time, the pressure release valve 250 can release pressure outwards, thereby avoiding a large pressure generated in the oxygen removal module 100 to damage the gas permeable membrane.
Referring to fig. 4, in some embodiments of the present invention, a water replenishing port 260 is provided on the cover plate 210, and the water replenishing port 260 communicates with the liquid storage cavity 120. It can be understood that the electrolyte of the oxygen removal module 100 is consumed after a long time use, and the electrolyte can be supplemented through the water replenishing port 260, so that the maintenance of the oxygen removal module 100 is facilitated.
Referring to fig. 2 and 3, a storage device 30 according to an embodiment of the present invention includes a frame 300, a drawer 400, and an oxygen removing assembly 10, wherein the frame 300 defines a storage space 310 for storing food materials, and is provided with a plurality of exhaust holes 320 communicated with the storage space 310, the exhaust holes 320 may be provided with a plurality of exhaust holes 320 arranged in an array on one side wall 330, and the oxygen removing assembly 10 is mounted at an end of the frame 300 facing the exhaust holes 320 and is hermetically connected to the corresponding side wall 330 of the frame 300. Referring to fig. 4, the oxygen removing module 100 has an air vent 130 opposite to the air vent 320, and a breathable film (not shown in the figure) is installed on the air vent 130, so that the storage space 310 is communicated with the breathable film, and the oxygen removing assembly 10 can consume oxygen in the storage space 310, so that a low-oxygen negative pressure state is formed in the storage space 310, the oxygen content in the storage space 310 is reduced, and the storage space 310 has a low-oxygen fresh-keeping function. Moreover, the drawer 400 is installed in the frame 300 through the guide rail 410, so that a user can conveniently access the food in the storage space 310; the sealing strip 420 is arranged at the matching position of the corresponding side end surfaces of the drawer 400 and the frame 300, so that the sealing performance of the storage space 310 is improved. In addition, deoxidization subassembly 10 adopts the integrated configuration of deoxidization module 100 and the separation structure 200 of above-mentioned embodiment, can effectively reduce the loss of electrolyte in the deoxidization module 100, has guaranteed deoxidization subassembly 10 to the throughput of oxygen in the storing space 310, has promoted the fresh-keeping effect of storing space 310.
Referring to fig. 1 and 2, a refrigerator according to an embodiment of the present invention includes the oxygen scavenging assembly 10 of the above embodiment. The refrigerator of the present embodiment is provided with a separation structure 200 hermetically connected to the liquid storage chamber 110 of the oxygen removal module 100 through the oxygen removal assembly 10, the separation structure 200 includes a cover plate 210 and a top cover 220, oxygen displaced by the oxygen removal module 100 overflows from the upper side of the liquid level of the electrolyte to form a mixture, an air overflow port 211 discharges the mixture into a separation chamber 230 formed by the cover plate 210 and the top cover 220 to separate the mixture into gas and liquid, the cover plate 210 is provided with a partition 240 in the extending direction to form a plurality of independent compartments 231, adjacent compartments 231 are communicated with each other only through a compression pipe 241, when the mixture in the compartments 231 is accumulated to a sufficient pressure, the mixture is compressed and enters another compartment 231 through the compression pipe 241, the outlet area of the compression pipe 241 is suddenly increased to cause the mixture to be separated into gas and liquid again, after the mixture is separated into gas and liquid on a flow path in the separation chamber 230 for a plurality of times, electrolyte liquid drops and vapor flow back to the liquid storage cavity 110 through the return pipe 212, and oxygen is discharged outwards through the exhaust port 221, so that the loss of the electrolyte in the deoxidizing module 100 can be effectively reduced, the processing capacity of the deoxidizing component 10 on the oxygen in the compartment 20 of the refrigerator is guaranteed, and the fresh-keeping effect of the refrigerator is improved.
The embodiments of the present invention have been described in detail with reference to the accompanying drawings, but the present invention is not limited to the above embodiments, and various changes can be made within the knowledge of those skilled in the art without departing from the gist of the present invention.

Claims (11)

1. An oxygen scavenging assembly, comprising:
the deoxidization module is internally provided with a liquid storage cavity for storing electrolyte;
separation structure, separation structure is including being used for sealing the apron in stock solution chamber, and with at least part apron sealing connection's top cap, at least part the apron with the disengagement chamber is formed with between the top cap, be equipped with the gas overflow mouth on the apron, gas overflow mouth intercommunication stock solution chamber with the disengagement chamber, the apron interval is equipped with the baffle in extending direction, the baffle orientation the top cap extends so that the disengagement chamber forms a plurality of mutually independent separate chamber, be equipped with the compression pipe on the baffle so that it is adjacent separate the chamber intercommunication, every separate the intracavity and all be connected with the back flow, it is a plurality of the lower extreme of back flow all is located extremely electrolyte liquid level below, the top cap is equipped with the gas vent, the gas vent with the gas overflow mouth is located the difference respectively separate the intracavity.
2. The oxygen scavenging assembly of claim 1 wherein: the overflow port and the exhaust port are respectively positioned at two opposite ends of the separation cavity.
3. The oxygen scavenging assembly of claim 1 wherein: the compression tubes on adjacent baffles are staggered along the projection in the direction parallel to the baffles.
4. The oxygen scavenging assembly of claim 1 or 3, wherein: the compression tube has an inner diameter D that satisfies: d is more than or equal to 2mm and less than or equal to 10 mm.
5. The oxygen scavenging assembly of claim 4 wherein: the compression tube has a length L that satisfies: L/D is more than or equal to 2 and less than or equal to 3.
6. The oxygen scavenging assembly of claim 1 wherein: the cover plate is provided with a plurality of guide plates in each partition cavity, the guide plates are arranged obliquely downwards, and the return pipes are correspondingly connected to the guide plates respectively.
7. The oxygen scavenging assembly of claim 6 wherein: the guide plate is provided with a guide hole, the guide hole is positioned at the lowest position of the guide plate along the vertical direction, and the guide hole is connected with the return pipe.
8. The oxygen scavenging assembly of claim 1 wherein: the cover plate is also provided with a pressure release valve which is communicated with the liquid storage cavity and is arranged in a staggered way with the top cover.
9. The oxygen scavenging assembly of claim 1 wherein: and the cover plate is provided with a water replenishing port which is communicated with the liquid storage cavity.
10. Storing device, its characterized in that includes:
the frame is internally provided with a storage space and is provided with an exhaust hole communicated with the storage space;
the drawer is arranged in the frame through a guide rail;
the oxygen scavenging assembly of any one of claims 1 to 9 mounted at an end of the frame facing the vent, the oxygen scavenging assembly having a vent disposed opposite the vent, the vent having a breathable membrane mounted thereon.
11. The refrigerator is characterized in that: comprising the oxygen scavenging assembly of any one of claims 1 to 9.
CN202010211417.8A 2020-03-24 2020-03-24 Deoxidization subassembly, storing device and refrigerator Active CN113446792B (en)

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Publication number Priority date Publication date Assignee Title
CN116222114A (en) * 2021-12-03 2023-06-06 青岛海尔电冰箱有限公司 Electrolytic deoxidizing device and refrigerator with same
CN218096794U (en) * 2022-02-16 2022-12-20 青岛海尔电冰箱有限公司 Air pressure adjusting device, oxygen treatment device and refrigerator

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CN209445344U (en) * 2018-11-12 2019-09-27 安徽华尔泰化工股份有限公司 A kind of novel deaerator emptying vapour-recovery unit

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JP2003035486A (en) * 2001-07-24 2003-02-07 Toshiba Corp Refrigerator
CN203822672U (en) * 2014-02-14 2014-09-10 北京矿冶研究总院 Gas-liquid separation device for vacuum pump exhaust pipeline
CN206362069U (en) * 2016-12-02 2017-07-28 青岛海尔股份有限公司 Refrigerator
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