CN113384846B - Heavy metal waste residue processing apparatus based on solidification principle - Google Patents

Heavy metal waste residue processing apparatus based on solidification principle Download PDF

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CN113384846B
CN113384846B CN202110611162.9A CN202110611162A CN113384846B CN 113384846 B CN113384846 B CN 113384846B CN 202110611162 A CN202110611162 A CN 202110611162A CN 113384846 B CN113384846 B CN 113384846B
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cylinder body
main cylinder
rotary drum
heavy metal
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CN113384846A (en
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Shenzhen City Longgang District Dongjiang Industrial Waste Disposal Co ltd
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Shenzhen City Longgang District Dongjiang Industrial Waste Disposal Co ltd
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/30Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
    • A62D3/33Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by chemical fixing the harmful substance, e.g. by chelation or complexation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/38Treatment of water, waste water, or sewage by centrifugal separation

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  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
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  • Treatment Of Sludge (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a heavy metal waste residue treatment device based on a solidification principle, which comprises a main cylinder body, wherein a heavy metal slag discharge hopper is arranged on the outer wall of the main cylinder body, an inner cylinder body is arranged inside the main cylinder body, the bottom of the inner cylinder body is of an outer flaring structure, a solidification device is arranged at the top of the main cylinder body, rotors are uniformly arranged on the outer wall of the inner cylinder body, stators are uniformly arranged on the inner wall of the main cylinder body, the rotors and the stators are mutually and electromagnetically matched, one side of the rotor is provided with a rotational flow blade, a sundries separation device is arranged inside the inner cylinder body and comprises a rotary drum, first spiral sheets are uniformly arranged on the outer wall of the rotary drum, separation holes are uniformly formed in the outer wall of the rotary drum, one end of the rotary drum is connected with a conical part, a second spiral sheet is arranged outside the conical part, and a rotary shell is sleeved outside the rotary drum.

Description

Heavy metal waste residue processing apparatus based on solidification principle
Technical Field
The invention relates to the technical field of heavy metal waste residue treatment, in particular to a heavy metal waste residue treatment device based on a solidification principle.
Background
With the increasing use frequency of nonferrous metals, the treatment of heavy metal waste residues becomes an increasingly important problem. At present, stabilizer and curing agent are adopted to carry out stabilization and curing treatment on heavy metal waste residue, and the reduction of the harm of the heavy metal waste residue to the environment is one of the main treatment methods.
The existing solidification technology mainly comprises cement and lime solidification and stabilization technologies, but because the types of mineral resources are more, the characteristics of waste residues are different, the difference of the stabilization and solidification processes of different waste residues is very large, and the problems of mismatching of dosing devices and unsmooth operation are easily caused; in addition, the heavy metal waste residues contain a large amount of weeds, stones, a plurality of roots and the like, so that the machine is easy to block, and manual assistance is needed. Therefore, it is necessary to design a heavy metal waste residue treatment device based on the solidification principle, which has stable solidification effect and avoids sundry blockage.
Disclosure of Invention
The invention aims to provide a heavy metal waste residue treatment device based on a solidification principle, so as to solve the problems in the background technology.
In order to solve the technical problems, the invention provides the following technical scheme: the utility model provides a heavy metal waste residue processing apparatus based on solidification principle, includes the main barrel, the heavy metal is installed on the outer wall of main barrel and is gone out the slag tap fill, the internally mounted of main barrel has interior barrel, the bottom of interior barrel is outer flaring structure, solidification equipment is installed at the top of main barrel, and the waste liquid is let in at the top of barrel in the during operation, and solidification effect through solidification equipment is with the solidification separation of metal waste residue to discharge from heavy metal is gone out the slag tap and is fought, has realized the effect of solidification separation, and separation efficiency is high.
Further, the stator is evenly installed to the inner wall of the main barrel body, rotor and stator electromagnetic fit each other, the whirl blade is installed to one side of rotor, and rotor and stator rotation each other when the circular telegram to drive whirl blade and interior barrel and rotate, give a rotatory centrifugal force of liquid, the convenient radial distribution of density realization according to the heavy metal granule.
Further, the inside of interior barrel is provided with debris separator, debris separator includes the rotary drum, the outer wall of rotary drum evenly is provided with first flight, the separation hole has evenly been seted up to the outer wall of rotary drum, the one end of rotary drum is connected with the toper portion, the outside of toper portion is provided with the second flight, the outside of rotary drum has cup jointed changes the shell, it contacts with first flight to change the shell, the second flight leaves the gap with the inner wall of changeing the shell, the one end of rotary drum is connected with the inlet pipe, and the during operation rotary drum is rotatory, drives first helical blade and rotates, because the great heavy metal granule of density is firmly laminated at changeing the shell inner wall under the high-speed rotatory condition to transported to the top by first flight, from changeing the outer wall of shell to the whereabouts of spiral, and the lower silt of density then takes the piece downstream by the second owing to laminating power, discharges to holding the mud pit from the toper portion, utilizes rotary drum and helical blade to realize the separation of silt and heavy metal, holds in the mud pit after will separating, the heavy metal is followed up solidification discharge.
Further, the outer wall of commentaries on classics shell corresponds installs first magnetism suspensoid, the second magnetism suspensoid is evenly installed to the inner wall of interior barrel, first magnetism suspensoid is located same vertical plane with second magnetism suspensoid, the inner wall of changeing shell and interior barrel has certain gap, and the during operation makes first magnetism suspensoid and second magnetism suspensoid circular telegram each other, makes the inner wall of interior barrel suspension at the main barrel, avoids noise and vibrations of silt when rotatory for complete machine job stabilization.
Further, discharging device is installed to the outer wall of main barrel, discharging device includes the second motor, the second motor passes through welded fastening at the top of main barrel, the output shaft of second motor passes the inner wall of main barrel, and output shaft connection has the pivot, the outside of pivot is through welded fastening has the diamond-shaped block, the spout has been seted up to the outer wall of diamond-shaped block, the inner wall of main barrel has evenly seted up the slag hole, the inner wall of main barrel evenly has hinge branch through hinge swing joint, hinge swing joint has the connecting rod one end of hinge branch, the one end of connecting rod and the inner wall sliding connection of spout, the during operation pivot drives the connecting rod motion, and when diamond-shaped block rotated to suitable position, hinge branch moved the striker plate, is convenient for open the striker plate after a period of solidification, discharges the heavy metal waste residue of the sediment after the solidification, and water was discharged from the play water end in other times.
Further, the curing device comprises an annular partition plate, the annular partition plate is a plurality of annular cylinders which are concentrically sleeved, the annular partition plate is fixed with the main cylinder body through bolts, a first motor is installed on the outer wall of the main cylinder body, an output shaft of the first motor is connected with a gear through a coupling, the top of the main cylinder body is movably connected with an upper shell through a bearing, outer teeth are uniformly arranged on the outer peripheral surface of the upper shell, a curing agent inlet pipe is uniformly inserted and fixed to the top of the upper shell, a curing agent charging box is connected to the top of the curing agent inlet pipe, mounting holes are uniformly formed in the top of the upper shell, a stop block is arranged inside each mounting hole, the annular partition plate divides the inside of the main cylinder body into a plurality of spaces, different curing agents are charged into the different curing agent charging boxes, the first motor is started during operation, the output shaft of the first motor drives the gear to rotate, the upper shell rotates and uniformly feeds the curing agents into the adjacent annular partition plates, the targeted curing agent use according to the heavy metal type is realized, and when more curing agents need to be used, the stop block is opened.
Further, the quantity that the curing agent lets in the pipe is corresponding with annular partition plate, one section distance of annular partition plate is inserted to the bottom that the curing agent lets in the pipe, the curing agent lets in to manage and is provided with solenoid valve, adjusts corresponding aperture for the curing agent is different at the volume of letting in between every annular partition plate, finds the most suitable curing agent and distributes, makes different kinds of heavy metal realize stabilizing the solidification with different curing agents and handles, avoids appearing the unmatched problem of medicine.
Compared with the prior art, the invention has the following beneficial effects: in the invention, the raw materials are mixed,
(1) By arranging the main cylinder and the inner cylinder, the wastewater containing the heavy metal waste residues is rotated and centrifuged by utilizing the relative rotation of the rotor and the stator, and the heavy metal waste residues are separated according to the density, so that the subsequent separation is facilitated;
(2) By arranging the curing device, different curing agents are filled into different curing agent charging boxes, the curing agent proportion between the annular partition plates is adjusted by controlling the opening and closing of different electromagnetic valves, the most suitable curing agent distribution is found, different curing agents enable different types of heavy metals to realize stable curing treatment, and the problem of unmatched dosing is avoided;
(3) The rotary drum is suspended in the main cylinder by the aid of the sundries separating device and a magnetic suspension effect, noise and vibration of silt during rotation are avoided, the whole machine works stably, the silt and heavy metal are separated by the aid of the rotary drum and the helical blades, the separated silt is introduced into the silt storage pool, and the separated heavy metal is subsequently solidified and discharged;
(4) Through being provided with discharging device, utilize the rotation of motor to drive two striker plates and realize the interval and open and shut, open the striker plate after a period of solidification, the heavy metal waste residue of the deposit after the discharge solidification, water is discharged from water outlet end in other times.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention and not to limit the invention. In the drawings:
FIG. 1 is an overall cross-sectional elevational view of the invention;
FIG. 2 is a schematic view of the curing apparatus of the present invention;
FIG. 3 is a schematic structural view of the impurity separating device according to the present invention;
FIG. 4 is a schematic view of the mounting of the rotating housing and inner barrel of the present invention;
FIG. 5 is a schematic view of the discharge device of the present invention;
in the figure: 1. a main cylinder; 11. a heavy metal slag discharge hopper; 12. a stator; 13. a slag hole; 2. a curing device; 21. introducing a curing agent into the pipe; 22. an annular partition plate; 23. an upper shell; 231. a stopper; 24. a first motor; 241. a gear; 25. a curing agent charging box; 3. a sundry separating device; 31. a drum; 311. a first helical flight; 312. a separation well; 313. a feed pipe; 32. a tapered portion; 321. a second flight; 33. rotating the shell; 331. a first magnetic suspension body; 4. an inner cylinder; 41. a rotor; 411. a swirl vane; 42. a second magnetic suspension body; 5. a discharging device; 51. a second motor; 52. a rotating shaft; 53. diamond-shaped blocks; 531. a chute; 54. a connecting rod; 55. a striker plate; 56. hinging a support rod; 6. a mud storage tank.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, the present invention provides a technical solution: a heavy metal waste residue treatment device based on a solidification principle comprises a main cylinder body 1, wherein a heavy metal slag discharge hopper 11 is installed on the outer wall of the main cylinder body 1, an inner cylinder body 4 is installed inside the main cylinder body 1, the bottom of the inner cylinder body 4 is of an outer flaring structure, a solidification device 2 is installed at the top of the main cylinder body 1, waste liquid is introduced into the top of the inner cylinder body 4 during operation, the metal waste residue is solidified and separated through the solidification effect of the solidification device 2 and is discharged from the heavy metal slag discharge hopper 11, the solidification and separation effects are achieved, and the separation efficiency is high;
the rotor 41 is uniformly arranged on the outer wall of the inner cylinder 4, the stator 12 is uniformly arranged on the inner wall of the main cylinder 1, the rotor 41 and the stator 12 are mutually and electromagnetically matched, the rotational flow blade 411 is arranged on one side of the rotor 41, when the rotor 41 and the stator 12 are electrified, the rotor 41 and the stator 12 rotate mutually and drive the rotational flow blade 411 and the inner cylinder 4 to rotate, a rotary centrifugal force is given to liquid, and radial distribution is conveniently realized according to the density of heavy metal particles;
as shown in fig. 3, the impurity separating device 3 is disposed inside the inner cylinder 4, the impurity separating device 3 includes a rotating drum 31, first spiral plates 311 are uniformly disposed on the outer wall of the rotating drum 31, separating holes 312 are uniformly disposed on the outer wall of the rotating drum 31, one end of the rotating drum 31 is connected to a conical portion 32, a second spiral plate 321 is disposed outside the conical portion 32, a rotating shell 33 is sleeved outside the rotating drum 31, the rotating shell 33 contacts with the first spiral plates 311, a gap is reserved between the second spiral plates 321 and the inner wall of the rotating shell 33, one end of the rotating drum 31 is connected to a feed pipe 313, the rotating drum 31 rotates during operation to drive the first spiral plates 311 to rotate, heavy metal particles with high density are firmly attached to the inner wall of the rotating shell 33 under the condition of high-speed rotation, and are transported to the upper side by the first spiral plates 311, and fall from the outer wall of the rotating shell 33, and silt with low density is carried by the second spiral plates 321 to move downwards, and is discharged from the conical portion 32 to the mud storage tank 6, separation of heavy metals and the rotating drum and the heavy metals are used to introduce the separated mud storage tank, and the separated silt is discharged and the solidified heavy metals;
as shown in fig. 4, the outer wall of the rotating shell 33 is correspondingly provided with a first magnetic suspension body 331, the inner wall of the inner cylinder 4 is uniformly provided with a second magnetic suspension body 42, the first magnetic suspension body 331 and the second magnetic suspension body 42 are located in the same vertical plane, the rotating shell 33 and the inner wall of the inner cylinder 4 have a certain gap, when in use, the first magnetic suspension body 331 and the second magnetic suspension body 42 are electrified with each other, the inner cylinder 4 is suspended on the inner wall of the main cylinder 1, noise and vibration of silt during rotation are avoided, and the whole machine works stably;
as shown in fig. 5, a discharging device 5 is installed on the outer wall of the main cylinder 1, the discharging device 5 includes a second motor 51, the second motor 51 is fixed on the top of the main cylinder 1 by welding, an output shaft of the second motor 51 penetrates through the inner wall of the main cylinder 1, and the output shaft is connected with a rotating shaft 52, a diamond 53 is fixed outside the rotating shaft 52 by welding, a chute 531 is formed on the outer wall of the diamond 53, slag holes 13 are uniformly formed on the inner wall of the main cylinder 1, a hinge support rod 56 is uniformly and movably connected to the inner wall of the main cylinder 1 by a hinge, a connecting rod 54 is movably connected to one end of the hinge support rod 56 by a hinge, one end of the connecting rod 54 is slidably connected to the inner wall of the chute 531, the rotating shaft 52 drives the connecting rod 54 to move during operation, when the diamond 53 rotates to a proper position, the hinge support rod 56 moves the baffle 55, so that the baffle 55 is opened after a period of curing, heavy metal waste residues precipitated after curing is discharged, and water is discharged from a water outlet end at other times;
as shown in fig. 2, the curing device 2 includes an annular partition 22, the annular partition 22 is a plurality of concentrically sleeved annular cylinders, the annular partition 22 is fixed to the main cylinder 1 by bolts, a first motor 24 is installed on the outer wall of the main cylinder 1, an output shaft of the first motor 24 is connected with a gear 241 through a coupling, the top of the main cylinder 1 is movably connected with an upper shell 23 through a bearing, outer teeth are uniformly arranged on the outer circumferential surface of the upper shell 23, a curing agent introducing pipe 21 is uniformly inserted and fixed on the top of the upper shell 23, a curing agent charging box 25 is connected to the top of the curing agent introducing pipe 21, a mounting hole is uniformly arranged on the top of the upper shell 23, a stopper 231 is arranged inside the mounting hole, the annular partition 22 divides the inside of the main cylinder 1 into a plurality of spaces, different curing agents are charged into the different curing agents in the different curing agent charging boxes 25, the first motor 24 is started during operation, an output shaft thereof drives the gear 241 to rotate, the upper shell 23 rotates and uniformly introduces the curing agent into the adjacent annular partition 22, targeted use of the curing agent according to the heavy metal is realized, and when more curing agents are needed, the curing agent can be used, the stopper 231 is opened;
as figure 1, the quantity that the curing agent lets in pipe 21 is corresponding with annular baffle 22, and the bottom that the curing agent lets in pipe 21 inserts annular baffle 22 a section distance, curing agent lets in and is provided with solenoid valve on the pipe 21, utilizes the good procedure of setting for to open solenoid valve when the during operation, adjusts corresponding aperture for the curing agent is different in the input between every annular baffle 22, finds the most suitable curing agent and distributes, makes different kinds of heavy metal realize stabilizing the solidification with different curing agents and handles, avoids appearing the unmatched problem of medicine.
Example (b): when the waste residue treatment device is used, waste liquid is introduced into the top of the inner cylinder 4 during work, the metal waste residue is solidified and separated through the solidification effect of the solidification device 2 and is discharged from the heavy metal slag hopper 11, the solidification and separation effect is realized, the separation efficiency is high, the rotor 41 and the stator 12 rotate mutually when the power is on, the cyclone blades 411 and the inner cylinder 4 are driven to rotate, a rotary centrifugal force is given to liquid, the radial distribution is conveniently realized according to the density of heavy metal particles, the rotary drum 31 rotates during work, the first spiral blade 311 is driven to rotate, heavy metal particles with high density are firmly attached to the inner wall of the rotary shell 33 under the condition of high-speed rotation, the heavy metal particles are transported to the upper part by the first spiral blade 311 and fall down from the outer wall of the rotary shell 33, silt with low density is driven by the second spiral blade 321 to move downwards due to insufficient attaching force, and is discharged to the mud storage tank 6 from the conical part 32, the separation of silt and heavy metal is realized by using a rotary drum and a helical blade, the separated silt is introduced into a silt storage tank, the separated heavy metal is solidified and discharged subsequently, when the device works, the first magnetic suspension 331 and the second magnetic suspension 42 are electrified mutually, the inner cylinder 4 is suspended on the inner wall of the main cylinder 1, the noise and vibration of the silt during rotation are avoided, the whole device works stably, the rotary shaft 52 drives the connecting rod 54 to move during the work, when the diamond block 53 rotates to a proper position, the hinge support rod 56 moves the baffle plate 55, the baffle plate 55 is convenient to open after a period of solidification, the solidified precipitated heavy metal waste residue is discharged, otherwise, water is discharged from the water outlet end, different curing agent charging boxes 25 are filled with different curing agents, when the device works, the first motor 24 is started, the output shaft drives the gear 241 to rotate, the upper shell 23 rotates and uniformly introduces the curing agents into the adjacent annular partition plates 22, the realization is used according to the heavy metal kind to pertinence ground curing agent, when needing to use more curing agents, open the dog 231 can, utilize the good procedure of setting for to open solenoid valve when the during operation, adjust corresponding aperture for the curing agent is different at the input between every annular baffle 22, finds the most suitable curing agent and distributes, makes the heavy metal of different kinds realize stabilizing the solidification processing with different curing agents, avoids appearing adding the unmatched problem of medicine.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments described above, or equivalents may be substituted for elements thereof. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (1)

1. The utility model provides a heavy metal waste residue processing apparatus based on solidification principle, includes main barrel (1), heavy metal slag discharging fill (11), its characterized in that are installed to the outer wall of main barrel (1): an inner cylinder (4) is installed inside the main cylinder (1), the bottom of the inner cylinder (4) is of an outer flaring structure, a curing device (2) is installed at the top of the main cylinder (1), rotors (41) are evenly installed on the outer wall of the inner cylinder (4), stators (12) are evenly installed on the inner wall of the main cylinder (1), the rotors (41) and the stators (12) are mutually and electromagnetically matched, swirl vanes (411) are installed on one side of the rotors (41), a sundry separating device (3) is arranged inside the inner cylinder (4), the sundry separating device (3) comprises a rotary drum (31), first spiral sheets (311) are evenly arranged on the outer wall of the rotary drum (31), separating holes (312) are evenly formed in the outer wall of the rotary drum (31), one end of the rotary drum (31) is connected with a conical portion (32), second spiral sheets (321) are arranged outside the conical portion (32), a rotary shell (33) is sleeved outside the rotary drum (31), the rotary shell (33) is in contact with the first spiral sheets (311), a gap is reserved between the second spiral sheet (313) and the inner wall of the rotary drum (31), and a gap is reserved between the rotary shell (33); the discharging device (5) is installed on the outer wall of the main cylinder body (1), the discharging device (5) comprises a second motor (51) and a material baffle plate (55), the second motor (51) is fixed to the top of the main cylinder body (1) through welding, an output shaft of the second motor (51) penetrates through the inner wall of the main cylinder body (1), the output shaft is connected with a rotating shaft (52), a diamond block (53) is fixed to the outer portion of the rotating shaft (52) through welding, a sliding groove (531) is formed in the outer wall of the diamond block (53), slag holes (13) are uniformly formed in the inner wall of the main cylinder body (1), hinge support rods (56) are uniformly and movably connected to the inner wall of the main cylinder body (1) through hinges, one ends of the hinge support rods (56) are movably connected with connecting rods (54) through hinges, one ends of the connecting rods (54) are slidably connected with the inner wall of the sliding groove (531), the connecting rods (54) are driven to move by the rotating shaft (52) during work, and the hinge support rods (56) move the material baffle plate (55) when the diamond block (53) rotates to a proper position;
a first magnetic suspension body (331) is correspondingly installed on the outer wall of the rotating shell (33), a second magnetic suspension body (42) is uniformly installed on the inner wall of the inner cylinder body (4), the first magnetic suspension body (331) and the second magnetic suspension body (42) are located in the same vertical plane, and a certain gap is formed between the rotating shell (33) and the inner wall of the inner cylinder body (4);
the curing device (2) comprises an annular partition plate (22), the annular partition plate (22) is a plurality of annular cylinders which are concentrically sleeved, the annular partition plate (22) is fixed with the main cylinder body (1) through bolts, a first motor (24) is installed on the outer wall of the main cylinder body (1), an output shaft of the first motor (24) is connected with a gear (241) through a coupling, the top of the main cylinder body (1) is movably connected with an upper shell (23) through a bearing, external teeth are uniformly formed in the outer peripheral face of the upper shell (23), a curing agent inlet pipe (21) is uniformly inserted and fixedly into the top of the upper shell (23), a curing agent charging box (25) is connected to the top of the curing agent inlet pipe (21), mounting holes are uniformly formed in the top of the upper shell (23), a stop block (231) is arranged inside the mounting holes, and the annular partition plate (22) divides the inside of the main cylinder body (1) into a plurality of spaces.
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CN110272106A (en) * 2019-06-17 2019-09-24 安吉绿金金属材料有限公司 The wastewater treatment equipment and its processing method of waste and old lead acid accumulator processing
CN113384846B (en) * 2020-02-08 2023-03-28 深圳市龙岗区东江工业废物处置有限公司 Heavy metal waste residue processing apparatus based on solidification principle

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