CN113337778A - Oil well load-bearing detection cable armored steel wire and production method thereof - Google Patents

Oil well load-bearing detection cable armored steel wire and production method thereof Download PDF

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CN113337778A
CN113337778A CN202110521130.XA CN202110521130A CN113337778A CN 113337778 A CN113337778 A CN 113337778A CN 202110521130 A CN202110521130 A CN 202110521130A CN 113337778 A CN113337778 A CN 113337778A
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steel wire
oil well
plating
load
cold
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方峰
胡璠
蒋建清
周雪峰
夏文伟
杨恒勇
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Southeast University
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C1/00Manufacture of metal sheets, metal wire, metal rods, metal tubes by drawing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C18/00Alloys based on zinc
    • C22C18/04Alloys based on zinc with aluminium as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/38Wires; Tubes
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/001Austenite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses a load-bearing detection cable armored steel wire for an oil well and a production method thereof, wherein the steel wire comprises the following elements in percentage by mass: c, Mn, Si, Cr, Fe (0.78-0.85 wt%), 0.2-0.3 wt%, 0.5-0.6 wt%, 0.2-0.5 wt%, and the rest. The method comprises the following steps: carrying out cold drawing deformation on the wire rod to obtain a cold-drawn steel wire; carrying out austenitizing heat treatment and quenching treatment on the cold-drawn steel wire to obtain a sorbite structure; the steel wire is dipped with a Zn-Al-Mg coating and then is cold drawn to obtain the steel wire. The invention improves the strength and corrosion resistance of the steel wire; the initial diameter of the wire rod is increased, the austenitizing heat treatment temperature and time are reduced, and the Zn-Al-Mg alloy coating is plated on the surface of the steel wire in a double-plating way, so that the strength and the thermal stability of the steel wire are improved; the strength of the steel wire can reach 2000-2400 MPa.

Description

Oil well load-bearing detection cable armored steel wire and production method thereof
Technical Field
The invention relates to a cable armored steel wire and a production method thereof, in particular to a load-bearing detection cable armored steel wire for an oil well and a production method thereof.
Background
The load-bearing detection cable is a steel wire armored cable which bears mechanical load and is mainly used for oil well surveying. The method can be used for oil and gas resource detection, and can also be applied to the fields of ocean investigation, coal field geological exploration, geothermal well logging and the like. The development of oil well exploration technology and the increase of oil well detection depth put forward higher requirements for the overall breaking force of the load-bearing detection cable, the strength of the steel wire for the load-bearing detection cable determines the limit detection depth of the cable, and meanwhile, the load-bearing detection cable is exposed to the abnormal and complicated corrosive environments of drilling fluid, hydrogen sulfide, high temperature and high pressure and the like in the underground, so that the service life of the load-bearing detection cable is greatly shortened. Therefore, the requirements of high strength, corrosion resistance and certain temperature resistance are put forward for the armored steel wire of the load-bearing detection cable. At present, the depth of an oil well in Xinjiang area in China breaks 8000m, the strength of a load-bearing detection cable steel wire is required to exceed 2100MP, the temperature of an ultra-deep well can reach 180 ℃, and a cold-drawn steel wire can be softened, so that the strength is reduced.
At present, the production flow of the armored steel wire of the load-bearing detection cable is as follows: 1) carrying out first cold drawing deformation on the steel wire rod; 2) then carrying out complete austenitizing heat treatment and isothermal quenching to recover the plastic deformation capacity of the steel wire; 3) carrying out surface cleaning and hot-dip galvanizing treatment on the steel wire to form a continuous hot-dip galvanizing coating on the surface of the steel wire, so that the corrosion resistance of the steel wire is improved; 4) and performing secondary cold drawing to obtain high strength (less than or equal to 2000 MPa). The steel wire produced by the process is widely applied to manufacturing load bearing detection cable steel wires with the depth of less than 7000m, but has the problem of short service life, mainly because the hot-dip galvanized steel wire is insufficient in corrosion resistance, and the strength of the steel wire is lower than a specified value due to softening of the steel wire after the steel wire is generally used for a period of time.
Disclosure of Invention
The purpose of the invention is as follows: the invention aims to provide a high-strength and strong-corrosion-resistance armored steel wire of a load-bearing detection cable for an oil well;
the invention also aims to provide a production method of the armored steel wire of the load-bearing detection cable for the oil well.
The technical scheme is as follows: the invention relates to a load-bearing detection cable armored steel wire for an oil well, which comprises the following elements in percentage by mass: c, Mn, Si, Cr, Fe (0.78-0.85 wt%), 0.2-0.3 wt%, 0.5-0.6 wt%, 0.2-0.5 wt%, and the rest.
The invention relates to a production method of a load-bearing detection cable armored steel wire for an oil well, which comprises the following steps:
(1) carrying out cold drawing deformation on the wire rod to obtain a cold-drawn steel wire;
(2) carrying out austenitizing heat treatment and quenching treatment on the cold-drawn steel wire to obtain a sorbite structure;
(3) and dip-plating a Zn-Al-Mg coating on the steel wire, and then performing cold drawing to obtain the oil well load-bearing detection cable armored steel wire.
Preferably, in the step (3), the Zn is added to Mg in the Zn-Al-Mg plating layer (4.8 to 5.2 wt%) (0.6 to 1.6 wt%) (the rest).
Preferably, in the step (3), the method for dip-plating the steel wire with the Zn-Al-Mg plating layer comprises the following steps: firstly hot dip plating Zn, and then hot dip plating a Zn-Al-Mg alloy coating on the steel wire.
Preferably, the hot-dip plating temperature of the hot-dip plating Zn is 430-450 ℃, and the hot-dip plating time is 30-60 s.
Preferably, the temperature of the hot-dip Zn-Al-Mg alloy coating is 420-440 ℃ and the time is 10-20 s.
Preferably, in the step (2), the austenitizing heat treatment is carried out at 760-850 ℃ for 5-15 min.
Preferably, before the step (3), the steel wire is subjected to plating assistant treatment, wherein the plating assistant time is 1-3 min.
Preferably, in the step (1), the diameter of the wire rod is 6-7 mm.
Preferably, in the step (3), after the cold drawing, the steel wire is subjected to heat stabilization treatment by keeping the temperature of the steel wire at 200 +/-5 ℃ for 20-60 min.
Has the advantages that: compared with the prior art, the invention has the following remarkable effects: 1. the content of C, Si and Cr elements is increased, the initial strength of the carbon steel wire rod is increased, and the tempering softening resistance of the steel wire is improved; the corrosion resistance is also improved; 2. the surface of the steel wire adopts hot dip coating Zn-Al-Mg to replace the traditional pure zinc coating, thus obviously improving the corrosion resistance of the armored steel wire of the load-bearing detection cable; 3. the strength and the thermal stability of the steel wire are improved by changing the initial diameter of the steel wire rod, reducing the austenitizing heat treatment temperature and time and utilizing the texture genetic principle of austenitizing the large-deformation pearlite steel wire; 4. the added thermal stabilization treatment process can reduce the internal stress of the armored steel wire of the load-bearing detection cable and obviously reduce the strength deterioration of the steel wire in the use process; 5. the strength of the steel wire can reach 2000-2400MPa, and the strength requirement of the armored steel wire of the load-bearing detection cable of the ultra-deep oil well (more than or equal to 8000m) is met; 6. the method is simple to operate and easy to control.
Detailed Description
The present invention is described in further detail below.
Example 1
A production method of a load-bearing detection cable armored steel wire for an ultra-deep oil well mainly comprises the following steps:
(1) carrying out cold drawing deformation on the high-carbon wire rod with the diameter of phi 7mm to obtain a cold-drawn steel wire with the diameter of phi 4.5 mm; the steel wire comprises the following components: 0.78 wt% of Mn, 0.2 wt% of Cr and 0.4 wt% of Fe, the balance being Mn, Cr and Fe;
(2) carrying out austenitizing heat treatment on the cold-drawn steel wire: austenitizing temperature 850 ℃, time: 5 minutes;
(3) immersing the austenite steel wire into a lead bath for isothermal quenching treatment to obtain a sorbite structure;
(4) carrying out surface treatment on the steel wire subjected to austenitizing and isothermal quenching, wherein the surface treatment comprises alkali washing, water washing, acid washing and water washing, and then drying;
(5) plating assisting treatment is carried out on the steel wire at the temperature of about 80 ℃, the plating assisting time is 3min, and drying is carried out after plating assisting;
(6) firstly, hot-dip plating Zn on the steel wire subjected to plating assistance, wherein the hot-dip plating temperature is 450 ℃, and the hot-dip plating time is 30 s; then hot-dip plating the steel wire with a Zn-Al-Mg alloy coating at 440 ℃, wherein the process is called double plating, the double plating time is 10s, and water cooling is adopted after the double plating;
(7) cold-drawing the steel wire with the double Zn-Al-Mg plating layers to phi 1.6 mm; wherein, the Al, the Mg and the Zn account for 4.8wt percent and 0.6wt percent, and the rest is.
(8) And (3) keeping the temperature of the steel wire at 200 +/-5 ℃ for 60min, and then cooling the steel wire to room temperature in air.
After testing, the steel wire for the 2100 MPa-level load-bearing detection cable is obtained, and the neutral salt spray corrosion rate is 0.1798 g.m-2·h-1And the detection requirement of an oil well of 8000m is met.
Example 2
A production method of a load-bearing detection cable armored steel wire for an ultra-deep oil well mainly comprises the following steps:
(1) and (3) carrying out cold drawing deformation on the high-carbon wire rod with the diameter of phi 6mm to obtain a cold-drawn steel wire with the diameter of phi 4.0 mm. The steel wire comprises the following components: 0.80 wt% of Mn, 0.3 wt% of Cr and 0.2 wt% of Fe, the balance being Mn, 0.6 wt% and 0.2 wt% of Fe;
(2) carrying out austenitizing heat treatment on the cold-drawn steel wire: austenitizing temperature 760 ℃, time: 15 minutes;
(3) immersing the austenite steel wire into a lead bath for isothermal quenching treatment to obtain a sorbite structure;
(4) carrying out surface treatment on the steel wire subjected to austenitizing and isothermal quenching, wherein the surface treatment comprises alkali washing, water washing, acid washing and water washing, and then drying;
(5) plating assistant treatment is carried out on the steel wire at the temperature of about 80 ℃, the plating assistant time is 2min, and the steel wire is dried after plating assistant;
(6) after plating assistance, hot-dip plating Zn on the steel wire at the temperature of 430 ℃ for 60 s; then hot-dip plating the steel wire with a Zn-Al-Mg alloy coating at 420 ℃ for 20s, and cooling by water after double plating; wherein, the Al, the Mg and the Zn account for 5.0wt percent and 1.0wt percent, and the rest is.
(7) Cold-drawing the steel wire with the double Zn-Al-Mg plating layers to phi 1.1 mm;
(8) and (3) keeping the temperature of the steel wire at 200 +/-5 ℃ for 30min, and then cooling the steel wire to room temperature in air.
After testing, the steel wire for the load-bearing detection cable with the strength of 2200MPa is obtained, and the neutral salt spray corrosion rate is 0.1243 g.m-2·h-1And the detection requirement of 8500m oil well is met.
Example 3
A production method of a load-bearing detection cable armored steel wire for an ultra-deep oil well mainly comprises the following steps:
(1) and (3) carrying out cold drawing deformation on the high-carbon wire rod with the diameter of phi 7mm to obtain a cold-drawn steel wire with the diameter of phi 4.0 mm. The steel wire comprises the following components: 0.85 wt% of Mn, 0.3 wt% of Cr and 0.5 wt% of Fe, the balance being Mn, 0.6 wt% and 0.5 wt%;
(2) carrying out austenitizing heat treatment on the cold-drawn steel wire: austenitizing temperature 800 ℃, time: 10 minutes;
(3) immersing the austenite steel wire into a lead bath for isothermal quenching treatment to obtain a sorbite structure;
(4) carrying out surface treatment on the steel wire subjected to austenitizing and isothermal quenching, wherein the surface treatment comprises alkali washing, water washing, acid washing and water washing, and then drying;
(5) plating assistant treatment is carried out on the steel wire at the temperature of about 80 ℃, the plating assistant time is 1min, and the steel wire is dried after plating assistant;
(6) after plating assistance, hot-dip plating Zn on the steel wire at 440 ℃ for 45 s; hot-dip plating the steel wire with a Zn-Al-Mg alloy coating at 430 ℃ for 15s, and cooling by water after double plating; wherein, the Al, the Mg and the Zn account for 5.2wt percent and 1.0wt percent, and the rest is.
(7) Cold-drawing the steel wire with the double Zn-Al-Mg plating layers to phi 1.2 mm;
(8) and (3) keeping the temperature of the steel wire at 200 +/-5 ℃ for 20min, and then cooling the steel wire to room temperature in air.
After testing, the steel wire for the load-bearing detection cable with the strength of 2400MPa grade is obtained, and the neutral salt spray corrosion rate is 0.1597 g.m-2·h-1And the detection requirement of a 10000m oil well is met.
Example 4
A production method of a load-bearing detection cable armored steel wire for an ultra-deep oil well mainly comprises the following steps:
(1) and (3) carrying out cold drawing deformation on the high-carbon wire rod with the diameter of 6.5mm to obtain a cold-drawn steel wire with the diameter of 4.2 mm. The steel wire comprises the following components: 0.83 wt% of Mn, 0.3 wt% of Cr and 0.3 wt% of Fe, the balance being 0.3 wt%;
(2) carrying out austenitizing heat treatment on the cold-drawn steel wire: austenitizing temperature 820 ℃, time: 8 minutes;
(3) immersing the austenite steel wire into a lead bath for isothermal quenching treatment to obtain a sorbite structure;
(4) carrying out surface treatment on the steel wire subjected to austenitizing and isothermal quenching, wherein the surface treatment comprises alkali washing, water washing, acid washing and water washing, and then drying;
(5) plating assistant treatment is carried out on the steel wire at the temperature of about 80 ℃, the plating assistant time is 2min, and the steel wire is dried after plating assistant;
(6) after plating assistance, hot-dip plating Zn on the steel wire at 440 ℃ for 40 s; hot-dip plating the steel wire with a Zn-Al-Mg alloy coating at 430 ℃ for 15s, and cooling by water after double plating; wherein, the Al, the Mg and the Zn account for 5.0wt percent and 1.6wt percent, and the rest is.
(7) Cold-drawing the steel wire with the double Zn-Al-Mg plating layers to phi 1.3 mm;
(8) and (3) keeping the temperature of the steel wire at 200 +/-5 ℃ for 30min, and then cooling the steel wire to room temperature in air.
After testing, the steel wire for the load-bearing detection cable with the strength of 2300MPa can be obtained, and the neutral salt spray corrosion rate is 0.1632 g.m-2·h-1And the detection requirement of a 9000m oil well is met.
Comparative example 1
A production method of a load-bearing exploration cable armored steel wire mainly comprises the following steps:
(1) carrying out cold drawing deformation on the high-carbon wire rod with the diameter of phi 6.5mm to obtain a cold-drawn steel wire with the diameter of phi 4.1 mm; the steel wire comprises the following components: 0.72 wt% of Mn, 0.1 wt% of Cr and 0.1 wt% of Fe, the balance being 0.1 wt%;
(2) carrying out austenitizing heat treatment on the cold-drawn steel wire: austenitizing temperature 820 ℃, time: 6 minutes;
(3) immersing the austenite steel wire into a lead bath for isothermal quenching treatment to obtain a sorbite structure;
(4) carrying out surface treatment on the steel wire subjected to austenitizing and isothermal quenching, wherein the surface treatment comprises alkali washing, water washing, acid washing and water washing, and then drying;
(5) plating assistant treatment is carried out on the steel wire at the temperature of about 80 ℃, the plating assistant time is 2min, and the steel wire is dried after plating assistant;
(6) after plating, hot-dip plating Zn on the steel wire, wherein the hot-dip plating temperature is 440 ℃, the hot-dip plating time is 40s, and water cooling is adopted after plating;
(7) cold-drawing the steel wire with the hot-dip Zn coating to phi 1.2 mm;
(8) and (3) keeping the temperature of the steel wire at 200 +/-5 ℃ for 30min, and then cooling the steel wire to room temperature in air.
After testing, the steel wire for the load-bearing detection cable with the strength of 1800MPa is obtained, and the neutral salt spray corrosion rate is 0.2686 g.m-2·h-1And the detection requirement of a 6000m oil well is met.
Comparative example 2
A production method of a load-bearing exploration cable armored steel wire mainly comprises the following steps:
(1) and (3) carrying out cold drawing deformation on the high-carbon wire rod with the diameter of phi 5.5mm to obtain a cold-drawn steel wire with the diameter of phi 4.1 mm. The steel wire comprises the following components: 0.82 wt% of Mn, 0.2 wt% of Cr and 0.3 wt% of Fe, the balance being Mn and the balance being 0.5 wt%;
(2) carrying out austenitizing heat treatment on the cold-drawn steel wire: austenitizing temperature 840 ℃, time: 8 minutes;
(3) immersing the austenite steel wire into a lead bath for isothermal quenching treatment to obtain a sorbite structure;
(4) carrying out surface treatment on the steel wire subjected to austenitizing and isothermal quenching, wherein the surface treatment comprises alkali washing, water washing, acid washing and water washing, and then drying;
(5) plating assistant treatment is carried out on the steel wire at the temperature of about 80 ℃, the plating assistant time is 2min, and the steel wire is dried after plating assistant;
(6) after plating, hot-dip plating Zn on the steel wire, wherein the hot-dip plating temperature is 440 ℃, the hot-dip plating time is 40s, and water cooling is adopted after plating;
(7) cold-drawing the dip-plated Zn steel wire to phi 1.4 mm;
(8) and (3) keeping the temperature of the steel wire at 200 +/-5 ℃ for 30min, and then cooling the steel wire to room temperature in air.
After testing, the strength of 1960MPa grade is obtainedThe neutral salt spray corrosion rate of the steel wire for the load-bearing detection cable is 0.2825 g.m-2·h-1And the detection requirement of the 7000m oil well is met.
Comparative example 3
A production method of a load-bearing exploration cable armored steel wire mainly comprises the following steps:
(1) and (3) carrying out cold drawing deformation on the high-carbon wire rod with the diameter of phi 7mm to obtain a cold-drawn steel wire with the diameter of phi 4.3 mm. The steel wire comprises the following components: 0.85 wt% of Mn, 0.3 wt% of Cr and 0.3 wt% of Fe, the balance being 0.3 wt%;
(2) carrying out austenitizing heat treatment on the cold-drawn steel wire: austenitizing temperature 830 ℃, time: 6 minutes;
(3) immersing the austenite steel wire into a lead bath for isothermal quenching treatment to obtain a sorbite structure;
(4) carrying out surface treatment on the steel wire subjected to austenitizing and isothermal quenching, wherein the surface treatment comprises alkali washing, water washing, acid washing and water washing, and then drying;
(5) plating assistant treatment is carried out on the steel wire at the temperature of about 80 ℃, the plating assistant time is 2min, and the steel wire is dried after plating assistant;
(6) after plating, hot-dip plating Zn on the steel wire, wherein the hot-dip plating temperature is 450 ℃, the hot-dip plating time is 30s, and water cooling is adopted after plating;
(7) and cold-drawing the hot-dip Zn-plated steel wire to phi 1.2 mm.
After testing, the steel wire for the load-bearing detection cable with the strength of 2000MPa is obtained, and the neutral salt spray corrosion rate is 0.2965 g.m-2·h-1And the detection requirement of the 7000m oil well is met.
Comparative example 4
A production method of a load-bearing exploration cable armored steel wire mainly comprises the following steps:
(1) and (3) carrying out cold drawing deformation on the high-carbon wire rod with the diameter of 6.5mm to obtain a cold-drawn steel wire with the diameter of 4.1 mm. The steel wire comprises the following components: 0.82 wt% of Mn, 0.3 wt% of Cr and 0.3 wt% of Fe, the balance being 0.3 wt%;
(2) carrying out austenitizing heat treatment on the cold-drawn steel wire: austenitizing temperature 900 ℃, time: 8 minutes;
(3) immersing the austenite steel wire into a lead bath for isothermal quenching treatment to obtain a sorbite structure;
(4) carrying out surface treatment on the steel wire subjected to austenitizing and isothermal quenching, wherein the surface treatment comprises alkali washing, water washing, acid washing and water washing, and then drying;
(5) plating assistant treatment is carried out on the steel wire at the temperature of about 80 ℃, the plating assistant time is 2min, and the steel wire is dried after plating assistant;
(6) after plating assistant, hot-dip plating Zn on the steel wire, wherein the hot-dip plating temperature is 440 ℃, and the hot-dip plating time is 40 s;
(7) cold-drawing the hot-dipped Zn-plated steel wire to phi 1.2 mm;
(8) and (3) keeping the temperature of the steel wire at 200 +/-5 ℃ for 30min, and then cooling the steel wire to room temperature in air.
After testing, the steel wire for the load-bearing detection cable with the strength of 1960MPa is obtained, and the neutral salt spray corrosion rate is 0.3555 g.m-2·h-1And the detection requirement of the 7000m oil well is met.
Comparative example 5
A production method of a load-bearing exploration cable armored steel wire mainly comprises the following steps:
(1) and (3) carrying out cold drawing deformation on the high-carbon wire rod with the diameter of phi 7mm to obtain a cold-drawn steel wire with the diameter of phi 4.1 mm. The steel wire comprises the following components: 0.83 wt% of Mn, 0.2 wt% of Cr and 0.3 wt% of Fe, the balance being Mn and the balance being 0.5 wt%;
(2) carrying out austenitizing heat treatment on the cold-drawn steel wire: the austenitizing temperature is 900 ℃, and the time is 8 minutes;
(3) immersing the austenite steel wire into a lead bath for isothermal quenching treatment to obtain a sorbite structure;
(4) carrying out surface treatment on the steel wire subjected to austenitizing and isothermal quenching, wherein the surface treatment comprises alkali washing, water washing, acid washing and water washing, and then drying;
(5) plating assistant treatment is carried out on the steel wire at the temperature of about 80 ℃, the plating assistant time is 2min, and the steel wire is dried after plating assistant;
(6) after plating assistance, hot-dip plating Zn on the steel wire, wherein the hot-dip plating temperature is 430 ℃, and the hot-dip plating time is 50 s;
(7) cold-drawing the hot-dip Zn-plated steel wire to phi 1.3 mm;
(8) and (3) keeping the temperature of the steel wire at 200 +/-5 ℃ for 30min, and then cooling the steel wire to room temperature in air.
After testing, the steel wire for the 1900 MPa-level load-bearing detection cable is obtained,the corrosion rate of the neutral salt spray is 0.2802 g.m-2·h-1And the detection requirement of a 6500m oil well is met.

Claims (10)

1. The oil well is with holding a burden exploration cable armor steel wire which characterized in that, includes following element according to the mass ratio: c, Mn, Si, Cr, Fe (0.78-0.85 wt%), 0.2-0.3 wt%, 0.5-0.6 wt%, 0.2-0.5 wt%, and the rest.
2. A production method of an oil well load-bearing detection cable armored steel wire is characterized by comprising the following steps:
(1) carrying out cold drawing deformation on the wire rod to obtain a cold-drawn steel wire;
(2) carrying out austenitizing heat treatment and quenching treatment on the cold-drawn steel wire to obtain a sorbite structure;
(3) and dip-plating a Zn-Al-Mg coating on the steel wire, and then performing cold drawing to obtain the oil well load-bearing detection cable armored steel wire.
3. The method for producing a load-bearing exploration cable armored wire for an oil well as defined in claim 2, wherein in the step (3), Al, Mg and Zn in the Zn-Al-Mg coating layer (4.8 to 5.2 wt%) (0.6 to 1.6 wt%) (the balance).
4. The method for producing the oil well load-bearing exploration cable armored steel wire according to claim 2, wherein in the step (3), the method for dip-coating the steel wire with the Zn-Al-Mg coating comprises the following steps: firstly hot dip plating Zn, and then hot dip plating a Zn-Al-Mg alloy coating on the steel wire.
5. The method for producing the armored steel wire for the load-bearing exploration cable for the oil well as claimed in claim 4, wherein the hot-dip Zn plating temperature is 430-450 ℃ and the hot-dip time is 30-60 s.
6. The method for producing the oil well load-bearing exploration cable armored steel wire according to claim 4, wherein the temperature of the hot-dip Zn-Al-Mg alloy coating is 420 to 440 ℃ and the time is 10 to 20 s.
7. The method for producing the oil well load-bearing exploration cable armored steel wire according to claim 2, wherein in the step (2), the austenitizing heat treatment temperature is 760-850 ℃ and the time is 5-15 min.
8. The method for producing the oil well load-bearing exploration cable armored steel wire according to claim 2, wherein before the step (3), the steel wire is subjected to plating assistant treatment, and the plating assistant time is 1-3 min.
9. The method for producing the oil well load-bearing exploration cable armored steel wire according to claim 2, wherein in the step (1), the diameter of the wire rod is 6-7 mm.
10. The method for producing the armored steel wire for the load-bearing detection cable for the oil well according to claim 2, wherein the steel wire is subjected to heat stabilization treatment by keeping the temperature of the steel wire at 200 ± 5 ℃ for 20-60 min after the cold drawing in the step (3).
CN202110521130.XA 2021-05-13 2021-05-13 Oil well load-bearing detection cable armored steel wire and production method thereof Pending CN113337778A (en)

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Application publication date: 20210903