CN113263803A - Coating for building glass, preparation method and application - Google Patents

Coating for building glass, preparation method and application Download PDF

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Publication number
CN113263803A
CN113263803A CN202110553339.4A CN202110553339A CN113263803A CN 113263803 A CN113263803 A CN 113263803A CN 202110553339 A CN202110553339 A CN 202110553339A CN 113263803 A CN113263803 A CN 113263803A
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China
Prior art keywords
film
coating
layer
agent
flow guide
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Pending
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CN202110553339.4A
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Chinese (zh)
Inventor
赵倩
司化
申道明
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Xinxiang University
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Xinxiang University
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Priority to CN202110553339.4A priority Critical patent/CN113263803A/en
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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    • B32B7/04Interconnection of layers
    • B32B7/05Interconnection of layers the layers not being connected over the whole surface, e.g. discontinuous connection or patterned connection
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
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    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0866Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0867Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having acoustic absorption means on the visible surface
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0875Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/02Coating on the layer surface on fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0223Vinyl resin fibres
    • B32B2262/0238Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21Anti-static
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
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    • C08K2003/2244Oxides; Hydroxides of metals of zirconium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • EFIXED CONSTRUCTIONS
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    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
    • E04F2290/041Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against noise
    • E04F2290/042Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against noise with a facing or top layer for sound insulation

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fluid Mechanics (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a coating for building glass, which comprises a base layer, an interlayer, a subsurface layer and an outer surface layer, wherein the base layer is a high-transparency film or a glass substrate, the interlayer is a nano transparent heat-insulation functional pressure-sensitive adhesive coating, the subsurface layer is a high-transparency film or a glass substrate, and the outer surface layer is formed by laminating three layers of films.

Description

Coating for building glass, preparation method and application
The invention relates to a divisional application, wherein the application number of a parent case is 201910498539.7, the name of the invention is a composite film structure of a building surface layer, a preparation method and application, the application date is 6 months and 10 days in 2019, and the application publication number is CN 110154468A.
Technical Field
The invention relates to the technical field of building materials, in particular to a coating for building glass, a preparation method and application.
Background
The building surface layer is generally a building surface layer directly felt by people through vision, and mainly has the functions of heat preservation, heat insulation, ventilation, lighting, sun shading, sound insulation and the like. With the continuous improvement of aesthetic concepts and living quality requirements of people, the requirements on building materials are gradually increased. At present, materials commonly used mainly include polytetrafluoroethylene film materials, polyvinyl chloride film materials, ethylene-tetrafluoroethylene copolymer film materials, and the like, and among them, polytetrafluoroethylene film materials and ethylene-tetrafluoroethylene copolymer film materials are favored because of their excellent properties.
In the prior art, although ethylene-tetrafluoroethylene copolymer film materials are mostly used to be combined with other materials to improve the tensile property, the film materials are further suitable for application with larger span. However, the advantage of the building roof material is relatively obvious when the building roof material is used as a roof material, but as an outer wall, the flow conductivity of the building roof material is greatly limited, when strong wind strikes, the building roof material is often subjected to the feeling of being suddenly strong, weak and suddenly falling, and because the building blocks the flow of wind speed, the wind pressure difference of different parts is caused, the larger the area of a plane building is, the smaller the amplitude of shaking is, and conversely, the smaller the total area of the plane building is, the larger the amplitude of shaking is. In addition, when the sealing structure of the existing membrane material is damaged, flow guide cannot be formed in the membrane material, and the filling structure is required to be inflated, the advantages of the membrane material in the aspects of tensile property and span can be greatly reduced.
Disclosure of Invention
Objects of the invention
The invention aims to provide a composite membrane structure on the surface layer of a building, wherein two closed spaces are formed by designing three membrane layers, so that the tension of the composite membrane structure can be increased, airflow guiding and gas exchange circulation are carried out in the two closed spaces through a flow guide assembly, the deposition of dust can be reduced, and meanwhile, the two closed spaces can increase the heat preservation and sound insulation functions of the composite membrane structure.
(II) technical scheme
In order to solve the above problems, a first aspect of the present invention provides a composite membrane structure for a building surface layer, comprising at least three membrane layers and a flow guide assembly:
the first film layer is arranged on the surface layer of the building; the second film layer is connected with the first film layer in a sealing mode to form a sealed space; the third film layer is hermetically connected with the second film layer to form a flow guide space; the sealed space is arranged at a position close to the surface layer of the building relative to the diversion space; the flow guide assembly is arranged in the flow guide space and is used for dredging the gas in the flow guide space.
Furthermore, the third film layer and the second film layer are connected in a dotted manner to form a plurality of flow guiding spaces formed by connecting and penetrating umbrella-shaped spaces.
Furthermore, the composite membrane structure also comprises a shunt part, and a convex structure is arranged at the point-shaped connection position on the surface of the third membrane layer.
Furthermore, the joint of every two umbrella-shaped spaces is close to the second film layer to form a groove; the grooves extending from one of the ridge-like structures to the other of the ridge-like structures
Further, the flow guide assembly comprises a flow guide pipe, one end of the flow guide pipe extends to the sealed space, and the sealed space is inflated or exhausted.
Furthermore, the flow guide assembly also comprises a fan which is arranged at the other end of the flow guide pipe; the fan rotates positively to inflate the sealed space; the fan rotates reversely to exhaust the air in the sealed space.
Further, the first film layer comprises a film material taking a fabric as a base material; the second film layer comprises an isolating layer film; the third film layer comprises a film material without a fabric substrate.
Further, the membrane material with the fabric as the base material is a polyvinyl chloride (PVC) film; the isolating layer film is a Polyethylene (PE) film; the film material of the non-woven fabric substrate is an ethylene-tetrafluoroethylene copolymer (ETFE) film.
Further, the outer surface of the first film layer is coated with at least 2 layers of polyvinylidene fluoride in sequence; the polyvinylidene fluoride contains nano titanium dioxide; and the outer surface of the third film layer is coated with a flame retardant.
According to another aspect of the present invention, there is provided a method for preparing the above-mentioned composite membrane structure for building surface layer, comprising: the first film layer and the second film layer are jointed through an aluminum extrusion pressing plate to form a sealed space; arranging the flow guide assembly between the second membrane layer and the third membrane layer; and jointing the third film layer to the second film layer through an aluminum extrusion pressing plate to form a flow guide space, so as to obtain the composite film structure on the surface layer of the building.
According to a further aspect of the present invention there is provided the use of a composite membrane structure as a building skin, in the application of a composite membrane structure as defined in any one of the preceding claims or as prepared by the method as defined above to a building skin.
According to another aspect of the present invention, the coating for the building glass is a thermal insulation ultraviolet-resistant transparent composite film, comprising a base layer, an interlayer, a subsurface layer and an outer surface layer, wherein the base layer is a high transparent film or a glass substrate, the interlayer is a nano transparent thermal insulation functional light-cured coating layer or a nano transparent thermal insulation functional pressure-sensitive adhesive coating layer, and the subsurface layer is a high transparent film or a glass substrate, wherein the nano transparent thermal insulation functional light-cured coating layer or the nano transparent thermal insulation functional pressure-sensitive adhesive coating layer comprises the following components by weight percent:
pressure sensitive glue: 45.0-48.0;
nano powder: 12.0-13.0;
filling agent: 2.0-3.0;
diluent agent: 32.0-34.0;
buffering agent: 4.0-11.0; the sum of the weight percentages is 100 percent.
Wherein the outer surface layer is formed by sequentially laminating a polyvinyl chloride (PVC) film, a Polyethylene (PE) film and an ethylene-tetrafluoroethylene copolymer (ETFE) film, and the thicknesses of the PVC film, the PE film and the ETFE film are equal; the fire retardant is filled among the three layered materials.
Wherein the pressure-sensitive adhesive is pressure-sensitive cured acrylic adhesive or pressure-sensitive cured polyester adhesive.
The nano powder is a mixture of tetragonal zinc oxide and high-temperature ceramic zirconium oxide, and the mass ratio of the tetragonal zinc oxide to the high-temperature ceramic zirconium oxide is 1: 1; the particle size range of the nano powder is 1-90 nm.
The buffering agent is sodium polycarboxylate; the filler is perfluoroalkyl ethyl sulfonate; the diluent is ethyl acetate or absolute ethyl alcohol.
The high-transparency film is one of transparent PVC, PVB, PC, PE, OPP or PET plastic films, the heat insulation composite film is composed of a transparent film substrate and a photocuring coating layer or two transparent film substrates and a transparent heat insulation pressure-sensitive adhesive layer, and the thickness of the heat insulation coating on the surface of the substrate is 1-8 mu m.
(III) advantageous effects
The technical scheme of the invention has the following beneficial technical effects:
two closed spaces, namely a sealed space and a flow guide space, are formed by designing three films, and the tension of the composite film structure can be increased when the air inflation amount of the two closed spaces is balanced; and the airflow guide is carried out in the two closed spaces through the flow guide assembly, so that the closed spaces and the flow guide spaces can be controlled to exchange and circulate air, the dust deposition can be reduced, and the increase and the decrease of the amount of the air in the closed spaces can be controlled through the flow guide assembly, so that the air guide device is suitable for different buildings or different parts of the buildings. In addition, two airtight spaces can increase the heat preservation sound insulation function of complex film structure.
In addition, the coating, namely the heat-insulating anti-ultraviolet transparent composite film adopts the pressure-sensitive adhesive, so that the abrasion resistance of the coating is greatly improved, the transmittance is good, the adhesion between film layers is good, and the coating is coated on the surface of the transparent film or glass by adopting the anilox roller transfer coating technology, so that the coating raw materials are saved, the film forming is uniform, and the speed is greatly improved. Has good light transmittance in the visible light region. The basic performance of the transparent heat insulation film is measured according to related national standards, and the result proves that the transparent heat insulation film has the visible light transmittance of more than 77%, the near infrared shielding rate of more than 65% and the ultraviolet shielding rate of more than 99%. Therefore, the transparent heat insulation film has the characteristics of transparency, ultraviolet ray shielding, infrared ray shielding, abrasion resistance, static electricity prevention, glare prevention and the like, and has excellent comprehensive performance.
Drawings
FIG. 1 is a schematic structural diagram of a cross section of a composite membrane structure of a surface layer of a building according to an embodiment of the present invention;
FIG. 2 is a schematic diagram of a planar structure of a third membrane layer of a composite membrane structure of a surface layer of a building according to an embodiment of the present invention;
FIG. 3 is a flow chart of a method for preparing a composite membrane structure for a surface layer of a building according to an embodiment of the present invention.
Reference numerals:
1: a first film layer; 2: a second film layer; 3: a third film layer; 4: a flow guide assembly; 41: a flow guide pipe; 42: a fan; 5: a flow guiding space; 6: sealing the space; 7: a flow dividing member; 8: a heat-insulating layer; 9: a flexible solar module.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail with reference to the accompanying drawings in conjunction with the following detailed description. It should be understood that the description is intended to be exemplary only, and is not intended to limit the scope of the present invention. Moreover, in the following description, descriptions of well-known structures and techniques are omitted so as to not unnecessarily obscure the concepts of the present invention.
In the drawings a schematic view of a layer structure according to an embodiment of the invention is shown. The figures are not drawn to scale, wherein certain details are exaggerated and possibly omitted for clarity.
It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that the terms "first", "second", and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In addition, the technical features involved in the different embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
The invention will be described in more detail below with reference to the accompanying drawings. Like elements in the various figures are denoted by like reference numerals. For purposes of clarity, the various features in the drawings are not necessarily drawn to scale.
Referring to fig. 1, fig. 1 is a schematic structural cross-sectional view of a composite membrane structure of a building surface layer according to an embodiment of the present invention.
One embodiment of the present invention, as shown in fig. 1, provides a composite membrane structure for building surface layer, comprising at least three membrane layers and a flow guiding component 4: the first film layer 1 is arranged on the surface layer of the building; the second film layer 2 is hermetically connected with the first film layer 1 to form a sealed space 6; the third film layer 3 is hermetically connected with the second film layer 2 to form a flow guide space 5; the sealed space 6 is arranged at a position close to the surface layer of the building relative to the diversion space 5; the flow guide assembly 4 is arranged in the flow guide space 5 and is used for guiding the gas in the flow guide space 5.
In this embodiment, a vent is further disposed on the connection layer between the second film layer 2 and the third film layer 3, the vent is connected to the flow guide assembly 4, when the sealed space 6 needs to be inflated or exhausted, the vent is in a closed state to seal the sealed space 6 and the flow guide space 5, and when the sealed space 6 needs to be inflated or exhausted, the vent is in an open state to communicate the sealed space 6 with the flow guide assembly 4 for inflation or exhaust.
The three film layers form two closed spaces, namely a sealed space 6 and a flow guide space 5, and the two closed spaces can increase the tension of the composite film structure when the air inflation amount reaches a balanced state; and the airflow guide is carried out in the two closed spaces through the flow guide assembly 4, so that the gas exchange and circulation of the closed spaces and the flow guide space 5 can be controlled, the deposition of dust can be reduced, and the increase and decrease of the gas quantity in the closed spaces can be controlled through the flow guide assembly 4, so that the air flow guide device is suitable for different buildings or different parts of the buildings. In addition, two airtight spaces can increase the heat preservation sound insulation function of complex film structure.
In an alternative embodiment, as shown in fig. 1, the third film layer 3 and the second film layer 2 are further connected in a dotted manner to form a plurality of flow guiding spaces 5 formed by connecting and penetrating umbrella-shaped spaces.
The third rete 3 of this embodiment complex film structure towards outside sets up to a plurality of umbrella-type spaces and is favorable to when wind speed and the contact of third rete 3, makes the air current pass through the arc structure dispersion air current on rete top layer, has weakened the impact of air current to the wall body. In addition, the shape of the third film layer in the invention also provides the functions of decoration and beautification for buildings, and improves the functionality.
In an alternative embodiment, as shown in fig. 1, the composite membrane structure further comprises a shunt member 7, and a convex structure is disposed at the point-like connection of the surface of the third membrane layer 3.
In the composite membrane structure of the embodiment, the shunting parts 7 are respectively arranged at each point-like connection position on the surface of the third membrane layer 3, and because the composite membrane structure is of a convex structure, when wind blows to the outer surface of the composite membrane structure from the front side, and the wind contacts the shunting parts 7, the wind power disperses the airflow to two sides through the arc-shaped surfaces of the shunting parts 7, and the impact of the wind power on the building surface is also reduced.
Referring to fig. 1 and 2, fig. 2 is a schematic view illustrating a plane structure of a third film layer of a composite film structure of a building surface layer according to an embodiment of the present invention.
In an alternative embodiment, as shown in fig. 1 and 2, every two umbrella-shaped spaces are connected to form a groove 9 close to the second film layer 2; the grooves 9 extend from one to the other of the bulge-like structures.
In this embodiment, building top complex film structure has wind-force direction function, through the setting of groove 9 for when openly blowing to building top complex film structure with the side, wind is through the reposition of redundant personnel effect that third rete 3 and the reposition of redundant personnel part 7 that distributes on it played, disperses the air current in the groove 9 around the reposition of redundant personnel part 7, makes the air current disperse, subducts the impact of wind-force to the building face through the opening of difference.
In an alternative embodiment, as shown in fig. 1, the flow guide assembly 4 includes a flow guide tube 41 having one end extending into the enclosed space 6 for inflating or deflating the enclosed space 6.
In this embodiment, a vent is further disposed on the connection layer between the second film layer 2 and the third film layer 3, the vent is connected to the flow guide tube 41, when the sealed space 6 needs to be inflated or deflated, the vent is in a closed state to seal the sealed space 6 and the flow guide space 5, and when the sealed space 6 needs to be inflated or deflated, the vent is in an open state to communicate the sealed space 6 with the flow guide tube 41 for inflation or deflation. The duct 41 may be a hose, such as a band hose, or a rigid pipe, such as a steel pipe, but is not limited to the above.
In an alternative embodiment, as shown in fig. 1, the flow guiding assembly 4 further includes a fan 42 disposed at the other end of the flow guiding pipe 41; the fan 42 rotates forward to inflate the sealed space 6; the fan 42 is rotated reversely to discharge the air into the sealed space 6.
In an alternative embodiment, the first film layer 1 includes a film material with a fabric as a substrate; the second film layer 2 comprises an isolating layer film; the third film layer 3 comprises a film material without a woven substrate.
Wherein, third rete 3 can also include the waterproof layer, is connected the internal surface that the point ground through pressfitting, hot melt connection or mode that bonds to improve the waterproof performance of complex film structure, improve its practicality. The inner surface of the waterproof film and/or the outer surface of the third film layer 3 may be coated with at least one layer of a flame retardant to increase the functionality and safety index of the composite film structure. The third film layer 3 can also comprise a heat-insulating layer 8, so that the heat-insulating property of the composite film structure can be improved, and the functions of impurity removal and noise reduction can be realized. The surface of the second film layer 2 facing the third film layer 3 may further comprise a flexible solar module 9 for absorbing incident sunlight and converting light energy into electric energy to provide electric energy for the power component. A ring of adsorption layer can be arranged around the flexible solar module 9 to adsorb dust in the gas for alternating current. The side of the second film layer 2 facing the sealed space 6 may be further provided with an adsorption layer for adsorbing dust in the gas to be exchanged in the sealed space 6. The insulating layer 8 may be embodied as a polymer foam layer, preferably a transparent polyurethane foam layer.
In an alternative embodiment, the film material with the fabric as the substrate is a polyvinyl chloride (PVC) film; the isolating layer film is a Polyethylene (PE) film; the film material of the non-woven fabric substrate is an ethylene-tetrafluoroethylene copolymer (ETFE) film.
In this embodiment, it is preferable that at least one uv blocking coating layer and an antioxidant may be coated on the outer surface of the ethylene-tetrafluoroethylene copolymer (ETFE) film. And the aging speed is slowed down.
In an alternative embodiment, the outer surface of the first film layer 1 is coated with at least 2 layers of polyvinylidene fluoride in sequence; the polyvinylidene fluoride contains nano titanium dioxide; the outer surface of the third film layer 3 is coated with a flame retardant. Its one side towards confined space 6 of first rete 1 can the laminating be provided with heat preservation 8, can increase the thermal insulation performance of complex film structure on the one hand, and on the other hand can the effect of making an uproar falls in the edulcoration. The insulating layer 8 may be embodied as a polymer foam layer, preferably a transparent polyurethane foam layer.
In an alternative embodiment, as shown in fig. 1, the composite membrane structure further includes two insulating layers 8 respectively disposed in the sealed space 6 and the guiding space 5.
In an alternative embodiment, as shown in fig. 1, the composite film structure further includes a flexible solar module 9 disposed in the diversion space 5 for providing electrical energy to the diversion module 4 and the external electrical device. An energy storage battery can be further arranged in the diversion space 5 and used for storing the electric energy converted from the solar energy for power supply.
The three films of the present invention are preferably joined by aluminum extruded press platens to form two closed space structures. In the present application, a hole communicating with the flow guide tube 41 may be formed at the junction of the three films, and the hole is opened when gas exchange with the outside is required, and closed when the two closed spaces are in a sealed state. A filter screen can be arranged at the hole to filter outside air flow and prevent dust from entering. Or, an air inlet pipe and an air outlet pipe are respectively arranged at the joint, when the air exchange with the outside is needed, the two pipes are opened, and when the two closed spaces are in a sealed state, the two closed spaces are closed; the air inlet can be also provided with a filter screen to filter the air entering the diversion space 5 from the outside and prevent dust from entering.
Referring to fig. 3, fig. 3 is a flow chart of a method for preparing a composite membrane structure for a surface layer of a building according to an embodiment of the present invention.
According to another embodiment of the present invention, as shown in fig. 3, there is provided a method for preparing a composite membrane structure for a building surface layer, including:
s100: and jointing the first film layer and the second film layer through an aluminum extrusion pressing plate to form a sealed space.
S200: arranging the flow guide assembly between the second membrane layer and the third membrane layer;
s300: and jointing the third film layer to the second film layer through an aluminum extrusion pressing plate to form a flow guide space, so as to obtain the composite film structure on the surface layer of the building.
In this embodiment, S100, S200, and S300 are not intended to limit the order of steps performed in the preparation method, for example, the invention may be implemented by stacking the three films in sequence, placing the flow guide member between the second film and the third film according to a predetermined shape, position, or any shape and position, and bonding the films by an aluminum extrusion press once after placing. In another mode, the first film layer and the second film layer can be jointed through an aluminum extrusion pressing plate, then the flow guide assemblies are arranged between the second film layer and the third film layer, and then the third film layer is jointed on the jointed second film layer through the aluminum extrusion pressing plate. In another mode, the flow guide assembly can be arranged between the second film layer and the third film layer, the third film layer and the second film layer are jointed through the aluminum extrusion pressing plate, and then the first film layer is jointed on the second film layer which is jointed through the aluminum extrusion pressing plate. But are not limited to the above list.
According to a further embodiment of the present invention, there is provided a use of a composite film structure for a building outer skin, wherein the composite film structure is prepared by any one of the above-described methods or the above-described method. The method can be applied to the walls of buildings and roofs of buildings in particular, but not limited to.
The invention aims to protect a composite membrane structure on the surface layer of a building and a preparation method and application thereof. The composite membrane structure is provided with three membrane layers to form two closed spaces, namely a sealed space 6 and a diversion space 5, and the two closed spaces can increase the tension of the composite membrane structure when the air inflation quantity is balanced; and the airflow guide is carried out in the two closed spaces through the flow guide assembly 4, so that the gas exchange and circulation of the closed spaces and the flow guide space 5 can be controlled, the deposition of dust can be reduced, and the increase and decrease of the gas quantity in the closed spaces can be controlled through the flow guide assembly 4, so that the air flow guide device is suitable for different buildings or different parts of the buildings. In addition, two airtight spaces can increase the heat preservation sound insulation function of complex film structure.
According to another embodiment of the present invention, a coating for building glass is a thermal insulation ultraviolet-resistant transparent composite film, comprising a base layer, an interlayer, a subsurface layer and an outer surface layer, wherein the base layer is a high transparent film or a glass substrate, the interlayer is a nano transparent thermal insulation functional light-cured paint layer or a nano transparent thermal insulation functional pressure-sensitive adhesive coating, and the subsurface layer is a high transparent film or a glass substrate, wherein the nano transparent thermal insulation functional light-cured paint layer or the nano transparent thermal insulation functional pressure-sensitive adhesive coating preferably comprises the following components by weight percent:
pressure sensitive glue: 45.0-48.0;
nano powder: 12.0-13.0;
filling agent: 2.0-3.0;
diluent agent: 32.0-34.0;
buffering agent: 4.0-11.0;
the sum of the weight percentages of the components is 100 percent;
more preferably:
pressure sensitive glue: 47.0;
nano powder: 13.0;
filling agent: 2.0;
diluent agent: 34.0;
buffering agent: 4.0;
it is also more preferable that:
pressure sensitive glue: 45.0 of the total weight of the mixture;
nano powder: 10.0;
filling agent: 2.0;
diluent agent: 32.0 of the total weight of the alloy;
buffering agent: 11.0;
for each of the above embodiments, the outer surface layer is formed by sequentially laminating a polyvinyl chloride (PVC) film, a Polyethylene (PE) film, and an ethylene-tetrafluoroethylene copolymer (ETFE) film, and the thicknesses of the three films are uniform; flame retardant is filled among the three layered materials; wherein the pressure-sensitive adhesive is pressure-sensitive cured acrylic adhesive or pressure-sensitive cured polyester adhesive; the nano powder is a mixture of tetragonal zinc oxide and high-temperature ceramic zirconium oxide, and the mass ratio of the tetragonal zinc oxide to the high-temperature ceramic zirconium oxide is 1: 1; the particle size range of the nano powder is 1-90 nm; the buffering agent is sodium polycarboxylate; the filler is perfluoroalkyl ethyl sulfonate; the diluent is ethyl acetate or absolute ethyl alcohol; the high-transparency film is one of transparent PVC, PVB, PC, PE, OPP or PET plastic films, the heat insulation composite film is composed of a transparent film substrate and a photocuring coating layer or two transparent film substrates and a transparent heat insulation pressure-sensitive adhesive layer, and the thickness of the heat insulation coating on the surface of the substrate is 1-8 mu m.
According to another embodiment of the invention, the coating consists of a transparent film substrate and a nano transparent heat-insulating functional photocuring coating, and the thickness of the coating is 8 μm. The raw materials are defoamed and stirred by a vacuum stirrer, then are subjected to sand grinding and dispersion by a sand mill for standby, then a PET film is unreeled and tensioned by a special optical film coating machine, is dedusted, is destaticized and is subjected to corona treatment, then a transparent heat insulation coating is coated on the surface of a PET substrate by transfer coating of an anilox roller, is preheated for 1min by a segmented oven at 100 ℃, and is cured for 1-30s by an ultraviolet curing device to form the nano transparent heat insulation functional photocuring film of the PET substrate, wherein the heat insulation film has good heat insulation performance and visible light transmittance, and the light transmittance reaches 90%, the red shielding rate reaches 65% and the ultraviolet resistance reaches 99% through related tests and calculation.
It is to be understood that the above-described embodiments of the present invention are merely illustrative of or explaining the principles of the invention and are not to be construed as limiting the invention. Therefore, any modification, equivalent replacement, improvement and the like made without departing from the spirit and scope of the present invention should be included in the protection scope of the present invention. Further, it is intended that the appended claims cover all such variations and modifications as fall within the scope and boundaries of the appended claims or the equivalents of such scope and boundaries.

Claims (9)

1. A coating for building glass, comprising a base layer, an interlayer, a subsurface layer and an outer skin,
the base layer is a high-transparency film or a glass substrate,
the interlayer is a nano transparent heat-insulating pressure-sensitive adhesive coating,
the subsurface layer is a high-transparency film or a glass substrate,
the outer surface layer is formed by laminating three layers of films.
2. The coating of claim 1, wherein the outer surface layer is formed by sequentially laminating a polyvinyl chloride (PVC) film, a Polyethylene (PE) film, and an ethylene-tetrafluoroethylene copolymer (ETFE) film, and the thicknesses of the three films are uniform.
3. The coating of claim 1, wherein the nano transparent heat-insulating functional pressure-sensitive adhesive coating comprises the following components in percentage by weight:
pressure sensitive glue: 45.0-48.0;
nano powder: 12.0-13.0;
filling agent: 2.0-3.0;
diluent agent: 32.0-34.0;
buffering agent: 4.0 to 11.0 percent, and the sum of the weight percentages of the components is 100 percent.
4. The coating of claim 3, wherein the coating is a polymer coating
Pressure sensitive glue: 47.0;
nano powder: 13.0;
filling agent: 2.0;
diluent agent: 34.0;
buffering agent: 4.0.
5. the coating of claim 3, wherein the coating is a polymer coating
Pressure sensitive glue: 45.0 of the total weight of the mixture;
nano powder: 10.0;
filling agent: 2.0;
diluent agent: 32.0 of the total weight of the alloy;
buffering agent: 11.0.
6. the coating of claim 4 or 5, wherein the pressure sensitive adhesive is a pressure sensitive cured acrylic adhesive or a pressure sensitive cured polyester adhesive; the nano powder is a mixture of tetragonal zinc oxide and high-temperature ceramic zirconium oxide, and the mass ratio of the tetragonal zinc oxide to the high-temperature ceramic zirconium oxide is 1: 1; the buffering agent is sodium polycarboxylate; the filler is perfluoroalkyl ethyl sulfonate; the diluent is ethyl acetate or absolute ethyl alcohol.
7. The coating of claim 4 or 5, wherein the nanopowder has a particle size in the range of 1 to 90 nm.
8. The coating of claim 1, wherein the high clarity film is one of clear PVC, PVB, PC, PE, OPP, or PET plastic film.
9. The coating of claim 2 wherein the three layered material is filled with a flame retardant.
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