CN113174289B - 一种亲水性常温轧制液 - Google Patents
一种亲水性常温轧制液 Download PDFInfo
- Publication number
- CN113174289B CN113174289B CN202110502906.3A CN202110502906A CN113174289B CN 113174289 B CN113174289 B CN 113174289B CN 202110502906 A CN202110502906 A CN 202110502906A CN 113174289 B CN113174289 B CN 113174289B
- Authority
- CN
- China
- Prior art keywords
- rolling
- oil
- hydrophilic
- percent
- normal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005096 rolling process Methods 0.000 title claims abstract description 35
- 239000007788 liquid Substances 0.000 title claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000012188 paraffin wax Substances 0.000 claims abstract description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 8
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims abstract description 8
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims abstract description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 4
- BVTJGGGYKAMDBN-UHFFFAOYSA-N Dioxetane Chemical compound C1COO1 BVTJGGGYKAMDBN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920013822 aminosilicone Polymers 0.000 claims abstract description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims abstract description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 4
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 4
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 4
- 239000004317 sodium nitrate Substances 0.000 claims abstract description 4
- 235000010288 sodium nitrite Nutrition 0.000 claims abstract description 4
- 239000008367 deionised water Substances 0.000 claims abstract description 3
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 3
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000010731 rolling oil Substances 0.000 abstract description 21
- 229910000831 Steel Inorganic materials 0.000 abstract description 14
- 239000010959 steel Substances 0.000 abstract description 14
- 239000003921 oil Substances 0.000 abstract description 11
- 238000005238 degreasing Methods 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- 238000003756 stirring Methods 0.000 abstract description 7
- 238000004880 explosion Methods 0.000 abstract description 5
- 238000005097 cold rolling Methods 0.000 abstract description 4
- 238000013517 stratification Methods 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 description 8
- 239000002699 waste material Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- 238000002310 reflectometry Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/082—Inorganic acids or salts thereof containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/082—Inorganic acids or salts thereof containing nitrogen
- C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
- C10M2229/052—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Metal Rolling (AREA)
Abstract
本发明提供了一种亲水性常温轧制液，由氨基硅油、石蜡、异构十三醇氧乙烯醚、硝酸钠、亚硝酸钠、2，6‑二叔丁基‑4‑甲基苯酚、苯甲酸钠和去离子水制备组成。本发明提供的一种冷轧机组生产带钢时的轧制液，是一种亲水性的配方，通过这种新型亲水性的配方，能彻底解决传统轧制油的燃爆危险、排污污染、脱脂耗电、搅拌、油水分层的技术问题。本发明在冷轧带钢时无燃爆危险、油水不分层、免脱脂、不搅拌、排污少，实现了安全低耗的清洁生产。
Description
技术领域：
本发明属于化工领域，涉及一种轧制液，具体来说是一种亲水性常温轧制液。
背景技术：
近年来，冷轧薄板的轧制技术发生了巨大的进步，冷轧连轧机向高速、全连续、高精度、大变形量和薄规格的方向发展，尤其是不锈钢板对带钢板面的质量和清洁性也提出了越来越高的要求，同时，传统轧制油生产时的燃爆危险性，轧制油废弃物的危废处理，乳化液的外排环保压力，成为了传统轧制油发展的瓶颈。
传统轧制油在投入生产时有以下特点：
1，轧制油生产时需要加温乳化成为乳化液，一般要加温到58℃，加温就需要能源；另外需要不断的搅拌，搅拌同样需要能源；
2，轧制油的基油一般是矿物油、(动、植)物脂肪、合成脂，呈憎水性，所以要分层，油箱内轧制油液面上漂浮废油，每天有很多危废物产生；
3，轧制油成为乳化液时加温，加温造成油雾，生产环境非常恶劣，易***作工人吸入，而且生产环境有燃爆的危险；
4，轧制油为油性产品，轧完后钢板上留有油迹，后道工序需要脱脂清洗，增加了费用和废液排放。
发明内容：
针对现有技术中的上述技术问题，本发明提供了一种亲水性常温轧制液，所述的这种亲水性常温轧制液要解决现有技术中的传统轧制油的加温和搅拌的能耗问题，油水分层产生的危废问题，油雾造成的环境和燃爆问题，脱脂需要的成本和废液环保的技术问题。
本发明提供了一种亲水性常温轧制液，由如下质量百分比的原料制备而成：
氨基硅油 25.00～50.00％；
石蜡 8.00～16.00％；
异构十三醇氧乙烯醚 7.00～14.00％；
硝酸钠 0.10～0.50％；
亚硝酸钠 0.01～0.05％；
2，6-二叔丁基-4-甲基苯酚 0.01～0.05％；
苯甲酸钠 0.10～0.50％；
去离子水 余量。
具体的，上述的一种亲水性常温轧制液，由如下质量百分比的原料制备而成：
本发明的制备方法是，按照质量百分比称取各反应物质，然后混合均匀即可。
冷轧产线对于轧制液的主要功能是润滑，其次要求带钢表面无斑痕，因此对润滑和防腐蚀要求特别高，同时，通过乳化剂对润滑剂和缓蚀剂进行乳化，因此本发明在制备时需要协同作用，即本发明的轧制液在出厂前已经进行了乳化，达到不分层的目的，从而不需要在轧制生产前加温乳化。
本发明采用的氨基硅油和石蜡具有润滑的作用，异构十三醇氧乙烯醚具有乳化的作用，其中，硝酸钠和亚硝酸钠具有缓蚀的效果，2，6-二叔丁基-4-甲基苯酚具有抗氧化的作用，另外，苯甲酸钠是一种防腐剂。
本发明的技术效果如下：
·带钢在轧制生产过程中，进入轧机前带钢温度为常温，轧制时温度升高，轧制后又恢复常温，呈一个曲线形，因此轧制液除了具备恰到好处的润滑功能，还兼具降温功能；本发明的轧制液中，其石蜡组分是非晶体，石蜡受热时随温度提高而熔点增加，温度下降时其熔点又降低，契合轧制过程的带钢温度曲线；因此，本发明的轧制液在常温时粘度很低，所以很难粘附钢板，但轧制时随着温度升高粘度也随之提高，从而提高润滑性能。
·不分层和节能：由于本发明中的组分制备过程是在常温下完成了乳化过程，因此在带钢轧制时不需要加温乳化，即可满足乳化要求。在轧制生产前不需要预热，轧制生产时不需要保温，也不需要搅拌，因此也节省了加热和搅拌的能源；
·免脱脂：传统的基油性轧制油PH小于7，呈酸性，因此需要在后道工序进行脱脂去油；本发明的轧制液PH＝8.77，呈碱性，因此后道工序不需要脱脂，节省了脱脂费用。
·环保：因此不需要脱脂工艺，大大节省了脱脂废液，不仅环保而且节省了水处费。
本发明和已有传统轧制油技术相比，其技术进步是显著的，并且具有颠覆性。本发明产品不分层，没有废弃物，环保，而且用量少，使用成本降低。本发明产品在常温下即可生产，因为是亲水性，所以不需要加温乳化，节省能源。本发明产品不挥发，对环境非常友好，没有燃爆危险。本发明产品在轧制过程中，不存在传统轧制油的油迹，不需要脱脂，省了脱脂费用，减少了废液排放和水处理费用。
具体实施方式:
实施例1
种亲水性常温轧制液，由如下质量百分比的原料制备而成：
本发明的制备方法是，按照质量百分比称取各反应物质，然后混合均匀即可。
具体试验：广西某钢铁厂
轧机为串列式三连轧机，仅需一个水箱(利用原油箱)，水箱体积分别为220m3，试验时有效存水容积180m3，加入有效存水容积的1.5％的轧制液；(下面的百分比数据为有效存水容积的体积百分数)。
钢种：不锈钢2E板，规格0.6*1250
测试方法：采用梅特勒-托利多折光率仪Easy R40。
实施结果
本实施结果各重要指标与美国斯图尔特公司的弥撒技术轧制油(AS-2200)进行比较
轧制油(乳化液)油基的检测依据武汉双星科技发展有限公司的企业标准《乳化液理化指标检测标准》SXRB，本发明的水基轧制液检测依据GB/T6144-2010的合成切削液标准。
实施结果评价：
1)平均反射率是评价乳化液润滑性和清洁性最重要的指标，反射率越高润滑
性和清洁度越好，本发明的平均反射率明显高于传统轧制油。
2)平均含铁量是评价轧制过程中去氧化皮的指标，本发明的含铁量明显比轧
制油低，说明去除氧化皮的效果比轧制油好。
3)皂化值数据是评价酸值的指标，一般情况下，酸值越低，乳化液PH值越高，
酸值越低越有利于乳化液性能的提高。本发明属于碱性配方，而轧制油属
于酸性配方，本发明的酸值自然比轧制油的酸值低，轧制液(乳化液)性
能自然好。
4)本发明配方为浓缩液，因此使用浓度比传统轧制油低，运输存储试用都有
明显的优势。
5)本发明在常温下使用，省却很多能源。
Claims (1)
1.一种亲水性常温轧制液，其特征在于，由如下质量百分比的原料制备而成：
氨基硅油 28.00%；
石蜡 9.00%；
异构十三醇氧乙烯醚 8.00%；
硝酸钠 0.20%
亚硝酸钠 0.02%；
2，6-二叔丁基-4-甲基苯酚 0.03%；
苯甲酸钠 0.20%；
去离子水 余量；
上述亲水性常温轧制液的制备方法是，按照质量百分比称取各反应物质，然后混合均匀即可。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110502906.3A CN113174289B (zh) | 2021-05-10 | 2021-05-10 | 一种亲水性常温轧制液 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110502906.3A CN113174289B (zh) | 2021-05-10 | 2021-05-10 | 一种亲水性常温轧制液 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113174289A CN113174289A (zh) | 2021-07-27 |
| CN113174289B true CN113174289B (zh) | 2023-01-03 |
Family
ID=76928550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110502906.3A Active CN113174289B (zh) | 2021-05-10 | 2021-05-10 | 一种亲水性常温轧制液 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113174289B (zh) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU5975800A (en) * | 1999-07-22 | 2001-02-13 | Diversey, Inc. | Lubricant composition for lubricating a conveyor belt |
| CN101955844A (zh) * | 2010-08-13 | 2011-01-26 | 武汉柏康科技有限责任公司 | 一种用于链条输送带的水基干膜润滑剂及其制备方法 |
| CN102757852A (zh) * | 2011-04-29 | 2012-10-31 | 中国石油化工股份有限公司 | 轧制润滑剂组合物及其用途 |
| CN104342274A (zh) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | 全合成不锈钢冷轧轧制液组合物及其用途 |
| CN105038915A (zh) * | 2015-06-08 | 2015-11-11 | 黄惠娟 | 一种镁板带轧制润滑剂 |
| CN109370751A (zh) * | 2018-12-26 | 2019-02-22 | 奎克化学（中国）有限公司 | 一种新型不锈钢轧制油及其制备方法和使用方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005054009A (ja) * | 2003-07-31 | 2005-03-03 | Yushiro Chem Ind Co Ltd | マグネシウム系金属用圧延油組成物、マグネシウム系金属の加工方法及びマグネシウム系金属の加工品 |
-
2021
- 2021-05-10 CN CN202110502906.3A patent/CN113174289B/zh active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU5975800A (en) * | 1999-07-22 | 2001-02-13 | Diversey, Inc. | Lubricant composition for lubricating a conveyor belt |
| CN101955844A (zh) * | 2010-08-13 | 2011-01-26 | 武汉柏康科技有限责任公司 | 一种用于链条输送带的水基干膜润滑剂及其制备方法 |
| CN102757852A (zh) * | 2011-04-29 | 2012-10-31 | 中国石油化工股份有限公司 | 轧制润滑剂组合物及其用途 |
| CN104342274A (zh) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | 全合成不锈钢冷轧轧制液组合物及其用途 |
| CN105038915A (zh) * | 2015-06-08 | 2015-11-11 | 黄惠娟 | 一种镁板带轧制润滑剂 |
| CN109370751A (zh) * | 2018-12-26 | 2019-02-22 | 奎克化学（中国）有限公司 | 一种新型不锈钢轧制油及其制备方法和使用方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113174289A (zh) | 2021-07-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101870909B (zh) | 一种镁合金切削液 | |
| CN106520289A (zh) | 一种冷轧油气润滑专用润滑材料 | |
| CN104830516B (zh) | 一种极压型铝板铝带热轧乳液及其制备方法 | |
| CN101812380B (zh) | 多功能导热油在线清洗剂组合物 | |
| CN105001964A (zh) | 微乳化切削液 | |
| CN103320187B (zh) | 生物基甲醇汽油防腐缓蚀剂及其制备方法 | |
| CN107446681B (zh) | 一种微乳化型水溶性金属切削液及其制备方法 | |
| CN103351932B (zh) | 一种透明水溶性切削液及其制备方法 | |
| CN108822951A (zh) | 一种环保型铝合金全合成液组合物 | |
| CN109929666A (zh) | 水基通用型钕铁硼乳化防锈加工液及其制备方法 | |
| CN102758210A (zh) | 飞机防腐油清洗剂 | |
| CN105088260A (zh) | 一种金属表面除油清洗剂 | |
| CN106590907A (zh) | 一种含石墨烯的金属切削液及其制备方法 | |
| CN101705136A (zh) | 一种可生物降解的金属拉丝润滑油及其生产方法 | |
| CN104818103B (zh) | 汽车用低碳钢件冷挤压成形润滑剂及其制备方法 | |
| CN103849451B (zh) | 一种用于二次冷轧机组的具有高效清洗能力的平整液 | |
| CN113174289B (zh) | 一种亲水性常温轧制液 | |
| CN112481009B (zh) | 一种铜铝铁材加工用微乳化切削液及其制备方法 | |
| CN112538633B (zh) | 一种可回收循环利用的金属清洗剂及其制备方法 | |
| CN105154192B (zh) | 一种用于铝材热轧的轧制油及其制备方法 | |
| CN106566625B (zh) | 一种植物油基钛合金乳化加工液 | |
| CN112940833A (zh) | 一种长寿环保切削液及其制备方法 | |
| CN102433211A (zh) | 铜拉丝水基冷轧液及其制备方法 | |
| CN105062646A (zh) | 一种冷轧薄板轧制油 | |
| CN113403128B (zh) | 一种高分子环保型轧制液及其制备方法和使用方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240131 Address after: 200444 room 505, building 4, No. 69, Yuanfeng Road, Baoshan District, Shanghai Patentee after: Shanghai Wansen Low Carbon Technology Co.,Ltd. Country or region after: China Address before: 201900 Fujin Road, Baoshan District, Shanghai 885 Patentee before: Guo Shengqing Country or region before: China |
|
| TR01 | Transfer of patent right |