CN113145156A - Preparation of NiO-based Z-type heterojunction photoelectric catalytic material - Google Patents
Preparation of NiO-based Z-type heterojunction photoelectric catalytic material Download PDFInfo
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- CN113145156A CN113145156A CN202110264956.2A CN202110264956A CN113145156A CN 113145156 A CN113145156 A CN 113145156A CN 202110264956 A CN202110264956 A CN 202110264956A CN 113145156 A CN113145156 A CN 113145156A
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- 239000000463 material Substances 0.000 title claims abstract description 17
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims description 4
- 229920000128 polypyrrole Polymers 0.000 claims abstract description 28
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002131 composite material Substances 0.000 claims abstract description 10
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 claims abstract description 10
- 229940012189 methyl orange Drugs 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 7
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 7
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 238000010521 absorption reaction Methods 0.000 claims abstract description 5
- 229910052709 silver Inorganic materials 0.000 claims abstract description 5
- 239000004332 silver Substances 0.000 claims abstract description 5
- -1 sulfhydryl acetic acid Chemical compound 0.000 claims abstract description 5
- 238000001308 synthesis method Methods 0.000 claims abstract description 5
- 238000009713 electroplating Methods 0.000 claims abstract description 4
- 238000011065 in-situ storage Methods 0.000 claims abstract description 4
- 239000002135 nanosheet Substances 0.000 claims abstract description 4
- 239000000243 solution Substances 0.000 claims description 14
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 9
- 239000011259 mixed solution Substances 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000012456 homogeneous solution Substances 0.000 claims description 6
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 6
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 6
- 239000012498 ultrapure water Substances 0.000 claims description 6
- 229910052724 xenon Inorganic materials 0.000 claims description 6
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 230000001678 irradiating effect Effects 0.000 claims description 4
- 238000013033 photocatalytic degradation reaction Methods 0.000 claims description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 239000004809 Teflon Substances 0.000 claims description 3
- 229920006362 Teflon® Polymers 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- PLKATZNSTYDYJW-UHFFFAOYSA-N azane silver Chemical compound N.[Ag] PLKATZNSTYDYJW-UHFFFAOYSA-N 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000003795 desorption Methods 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 3
- 238000004070 electrodeposition Methods 0.000 claims description 3
- 239000003792 electrolyte Substances 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 3
- 230000001939 inductive effect Effects 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 229940078487 nickel acetate tetrahydrate Drugs 0.000 claims description 3
- OINIXPNQKAZCRL-UHFFFAOYSA-L nickel(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Ni+2].CC([O-])=O.CC([O-])=O OINIXPNQKAZCRL-UHFFFAOYSA-L 0.000 claims description 3
- 239000007800 oxidant agent Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 229910001868 water Inorganic materials 0.000 abstract description 8
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 230000033116 oxidation-reduction process Effects 0.000 abstract description 2
- 230000001699 photocatalysis Effects 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 230000002194 synthesizing effect Effects 0.000 abstract description 2
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 229910000480 nickel oxide Inorganic materials 0.000 abstract 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract 1
- 230000027756 respiratory electron transport chain Effects 0.000 abstract 1
- 238000010189 synthetic method Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 6
- 239000013543 active substance Substances 0.000 description 2
- 206010021143 Hypoxia Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- B01J35/33—
-
- B01J35/39—
-
- B01J35/61—
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Abstract
The invention discloses a synthesis method of a novel Z-type heterojunction photoelectric catalytic material, and belongs to the technical field of photoelectric catalysis. The method comprises the following steps: growing a NiO nano sheet on the foamed nickel in situ, electroplating silver, synthesizing a sulfhydryl acetic acid polypyrrole composite material, and modifying a substrate material with the sulfhydryl acetic acid polypyrrole. The invention is characterized in that the nickel oxide with wide forbidden band and the polypyrrole with good conductivity with narrow forbidden band are compounded together by taking silver as an electron transfer medium, and a synthetic method of a novel Z-type heterojunction photocatalytic material is researched. The synthesized catalytic material has the advantages of wide spectrum absorption range, large specific surface area, high stability, simple synthesis method and the like, and the Z-type heterojunction structure better retains the oxidation-reduction capability of a photoproduction electron hole compared with the traditional II-type heterojunction structure, so that the catalytic activity is high, and the efficient degradation of methyl orange in a water body is realized.
Description
Technical Field
The invention relates to the technical field of photoelectrocatalysis, in particular to a synthesis method of a novel Z-type heterojunction structure photoelectrocatalysis material.
Background
Photocatalytic degradation is a viable method for removing organic matter from water sources. Due to the advantages of low cost, multiple functions, high efficiency, mild reaction conditions, etc., photocatalysis is increasingly applied to the degradation of organic pollutants.
Researchers have also been working on the design and synthesis of a wide variety of highly efficient photocatalysts that convert inexhaustible solar energy into the driving force for photodegradation. In various heterojunction structures, more active substances are generated because the Z-type heterojunction system retains the stronger reducibility and oxidizability of electrons and holes. These active substances produced (·O2 -、·OH and h+) Can effectively degrade organic substances.
Methyl orange is a commonly used indicator in analytical chemistry. Methyl orange is also an azo dye and can be used for printing and dyeing textiles. The discharge of dye wastewater such as methyl orange and the like can cause visual pollution, when the color of the water body is deepened, sunlight is prevented from irradiating the water body to a great extent, and then the growth of animals and plants in the water is influenced. Meanwhile, the natural decomposition of the organic dye in the environment consumes a large amount of oxygen, and the water body can smell due to oxygen deficiency, thereby further causing the pollution of water resources.
Disclosure of Invention
The invention provides a synthesis method of a novel Z-type heterojunction structure photoelectrocatalysis material, which can be easily realized in most laboratories without complex and fussy large-scale equipment support. The specific preparation scheme is as follows:
(1) growing NiO nano-sheets on the foamed nickel in situ: 1.2488 g of nickel acetate tetrahydrate (C) were weighed out4H14NiO8) 3 g Urea (CH)4N2O) and 0.74 g of ammonium fluoride (NH)4F) Dissolved in 100 mL of deionized water and magnetically stirred for 20 min. 17 mL of the solution was measured and transferred to a 50 mL stainless steel autoclave lined with Teflon, and a piece of pre-cleaned Nickel Foam (NF) was placed in the autoclave in advance and reacted for 5 hours at 130 ℃ under hydrothermal reaction. Naturally cooling the high-pressure autoclave to room temperature, taking out the NF sheet, washing with deionized water, and then heating at 80 deg.CDrying in vacuum for 10 h to obtain Ni (OH)2Modified NF (Ni (OH)2/NF) and calcining for 3 hours at 400 ℃ to obtain NF/NiO.
(2) Silver electroplating: and (2) placing the NF/NiO sheet prepared in the step (1) into 3 mL of silver ammonia solution, 2 mL of H2O and 1 mL of electrolyte mixed with KNO3 by adopting a traditional three-electrode system electrochemical deposition method, depositing for 1200 s at minus 0.2V, and finally washing with ultrapure water to obtain the NF/NiO/Au.
(3) Synthesis of a sulfhydryl acetic acid polypyrrole (PPy/MAA) composite material: at 25 deg.C, 0.8 mL of pyrrole (Py) monomer was injected into 60 mL of aqueous solution containing 1.6 mL of thioglycolic acid (MAA). The above mixed solution was stirred for 30 min to ensure complete dissolution, and then 20 mL of 6.8 g Ammonium Persulfate (APS) solution was added dropwise as an oxidizing agent to initiate polymerization. During the polymerization, the solution changed from colorless to dark gray, indicating the formation of polypyrrole (Ppy). The mixed solution obtained by the reaction was left at room temperature for 6 hours to complete the polymerization, the obtained precipitate was washed with ultrapure water and then with acetone several times (about 10 times), and the finally obtained PPy/MAA composite material was subsequently dried under vacuum at 60 ℃.
(4) PPy/MAA modified substrate material: the resulting PPy/MAA composite was ground to a powder and sonicated to form a 2 mg/mL homogeneous solution. And (3) uniformly dripping 1 mL of the homogeneous solution on the NF/NiO/Au substrate prepared in the step (2), repeatedly dripping and coating for many times, and drying at 60 ℃ to finally obtain the photoelectric material with the Z-type heterojunction structure of NF/NiO/Au/PPy/MAA.
(5) Application of photoelectrocatalysis: immersing the NF/NiO/Au/PPy/MAA electrode in 60-80 mL of 1 g/L Methyl Orange (MO) solution, and magnetically inducing and stirring the suspension in the dark for 20-30 min to establish the absorption and desorption balance of the dye and the electrode surface under normal atmospheric conditions. And (3) using a xenon lamp as sunlight, irradiating the sunlight by using the xenon lamp to perform photocatalytic degradation reaction, and collecting the mixed solution every 3-6 min. The residual concentration of the dye was determined using a uv-vis spectrometer.
The invention has the beneficial effects that:
(1) the method has the advantages of low cost, simple experimental operation and easily controlled reaction conditions;
(2) the prepared NF-NiO/Ag/MAA-PPy catalytic material has the advantages of wide spectrum absorption range, large specific surface area, high stability and the like.
(3) Compared with the traditional II type heterojunction structure, the Z type heterojunction structure better reserves the oxidation reduction capability of a photoproduction electron hole, so that the catalytic activity is high.
The following is a description of detailed embodiments of the present invention: a method for synthesizing a novel Z-shaped heterojunction structure photoelectric catalytic material.
Example 1
(1) Growing NiO nano-sheets on the foamed nickel in situ: 1.2488 g of nickel acetate tetrahydrate (C) were weighed out4H14NiO8) 3 g Urea (CH)4N2O) and 0.74 g of ammonium fluoride (NH)4F) Dissolved in 100 mL of deionized water and magnetically stirred for 20 min. 17 mL of the solution was measured and transferred to a 50 mL stainless steel autoclave lined with Teflon, and a piece of pre-cleaned Nickel Foam (NF) was placed in the autoclave in advance and reacted for 5 hours at 130 ℃ under hydrothermal reaction. Naturally cooling the autoclave to room temperature, taking out the NF sheets, washing with deionized water, and then drying in vacuum at 80 ℃ for 10 h to obtain Ni (OH)2Modified Ni (OH)2and/NF, and calcining for 3 hours at 400 ℃ to obtain NF/NiO.
(2) Silver electroplating: placing the NF/NiO sheet prepared in the step (1) in 3 mL of silver ammonia solution and 2 mL of H by adopting a traditional three-electrode system electrochemical deposition method2O，1 mL KNO3In the mixed electrolyte, the solution was deposited for 1200 s at-0.2V and finally rinsed with ultrapure water to obtain NF/NiO/Au.
(3) Synthesis of a sulfhydryl acetic acid polypyrrole (PPy/MAA) composite material: at 25 deg.C, 0.8 mL of pyrrole (Py) monomer was injected into 60 mL of aqueous solution containing 1.6 mL of thioglycolic acid (MAA). The above mixed solution was stirred for 30 min to ensure complete dissolution, and then 20 mL of 6.8 g Ammonium Persulfate (APS) solution was added dropwise as an oxidizing agent to initiate polymerization. During the polymerization, the solution changed from colorless to dark gray, indicating the formation of polypyrrole (Ppy). The mixed solution obtained by the reaction was left at room temperature for 6 hours to complete the polymerization, the obtained precipitate was washed with ultrapure water and then with acetone several times (about 10 times), and the finally obtained PPy/MAA composite material was subsequently dried under vacuum at 60 ℃.
(4) PPy/MAA modified substrate material: the resulting PPy/MAA composite was ground to a powder and sonicated to form a 2 mg/mL homogeneous solution. And (3) uniformly dripping 1 mL of the homogeneous solution on the NF/NiO/Au substrate prepared in the step (2), repeatedly dripping and coating for many times, and drying at 60 ℃ to finally obtain the photoelectric material with the Z-type heterojunction structure of NF/NiO/Au/PPy/MAA.
(5) Application of photoelectrocatalysis: immersing the NF/NiO/Au/PPy/MAA electrode in 60-80 mL of 1 g/L Methyl Orange (MO) solution, and magnetically inducing and stirring the suspension in the dark for 20-30 min to establish the absorption and desorption balance of the dye and the electrode surface under normal atmospheric conditions. And (3) using a xenon lamp as sunlight, irradiating the sunlight by using the xenon lamp to perform photocatalytic degradation reaction, and collecting the mixed solution every 3-6 min. The residual concentration of the dye was determined using a uv-vis spectrometer.
Claims (1)
1. The invention provides a synthesis method of a novel Z-type heterojunction structure photoelectric catalytic material, which comprises the following specific preparation scheme:
(1) growing NiO nano-sheets on the foamed nickel in situ: 1.2488 g of nickel acetate tetrahydrate (C) were weighed out4H14NiO8) 3 g Urea (CH)4N2O) and 0.74 g of ammonium fluoride (NH)4F) Dissolved in 100 mL of deionized water and magnetically stirred for 20 min. 17 mL of the solution was measured and transferred to a 50 mL stainless steel autoclave lined with Teflon, and a piece of pre-cleaned Nickel Foam (NF) was placed in the autoclave in advance and reacted for 5 hours at 130 ℃ under hydrothermal reaction. Naturally cooling the autoclave to room temperature, taking out the NF sheets, washing with deionized water, and then drying in vacuum at 80 ℃ for 10 h to obtain Ni (OH)2Modified Ni (OH)2and/NF, and calcining for 3 hours at 400 ℃ to obtain NF/NiO.
(2) Silver electroplating: placing the NF/NiO sheet prepared in the step (1) in 3 mL of silver ammonia solution and 2 mL of H by adopting a traditional three-electrode system electrochemical deposition method2O，1 mL KNO3In the mixed electrolyte, the solution was deposited for 1200 s at-0.2V and finally rinsed with ultrapure water to obtain NF/NiO/Au.
(3) Synthesis of a sulfhydryl acetic acid polypyrrole (PPy/MAA) composite material: at 25 deg.C, 0.8 mL of pyrrole (Py) monomer was injected into 60 mL of aqueous solution containing 1.6 mL of thioglycolic acid (MAA). The above mixed solution was stirred for 30 min to ensure complete dissolution, and then 20 mL of 6.8 g Ammonium Persulfate (APS) solution was added dropwise as an oxidizing agent to initiate polymerization. During the polymerization, the solution changed from colorless to dark gray, indicating the formation of polypyrrole (Ppy). The mixed solution obtained by the reaction was left at room temperature for 6 hours to complete the polymerization, the obtained precipitate was washed with ultrapure water and then with acetone several times (about 10 times), and the finally obtained PPy/MAA composite material was subsequently dried under vacuum at 60 ℃.
(4) PPy/MAA modified substrate material: the resulting PPy/MAA composite was ground to a powder and sonicated to form a 2 mg/mL homogeneous solution. And (3) uniformly dripping 1 mL of the homogeneous solution on the NF/NiO/Au substrate prepared in the step (2), repeatedly dripping and coating for many times, and drying at 60 ℃ to finally obtain the photoelectric material with the Z-type heterojunction structure of NF/NiO/Au/PPy/MAA.
(5) Application of photoelectrocatalysis: immersing the NF/NiO/Au/PPy/MAA electrode in 60-80 mL of 1 g/L Methyl Orange (MO) solution, and magnetically inducing and stirring the suspension in the dark for 20-30 min to establish the absorption and desorption balance of the dye and the electrode surface under normal atmospheric conditions. And (3) using a xenon lamp as sunlight, irradiating the sunlight by using the xenon lamp to perform photocatalytic degradation reaction, and collecting the mixed solution every 3-6 min. The residual concentration of the dye was determined using a uv-vis spectrometer.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113231099A (en) * | 2021-05-21 | 2021-08-10 | 吉林大学 | Preparation and application of Z-type polypyrrole-bismuth tungstate photocatalyst |
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|---|---|---|---|---|
| US20100111817A1 (en) * | 2007-04-18 | 2010-05-06 | Panasonic Corporation | Titanium oxide photocatalyst and method for producing the same |
| CN108855142A (en) * | 2018-08-01 | 2018-11-23 | 辽宁大学 | 3D chrysanthemum shape Z-type Bi2S3@CoO hetero-junctions composite catalyst and its preparation method and application |
| US20190329236A1 (en) * | 2018-04-27 | 2019-10-31 | Soochow University | Loaded multifunctional catalysis composite material, preparation method thereof and application of composite material to catalytic removal of water pollutants |
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2021
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100111817A1 (en) * | 2007-04-18 | 2010-05-06 | Panasonic Corporation | Titanium oxide photocatalyst and method for producing the same |
| US20190329236A1 (en) * | 2018-04-27 | 2019-10-31 | Soochow University | Loaded multifunctional catalysis composite material, preparation method thereof and application of composite material to catalytic removal of water pollutants |
| CN108855142A (en) * | 2018-08-01 | 2018-11-23 | 辽宁大学 | 3D chrysanthemum shape Z-type Bi2S3@CoO hetero-junctions composite catalyst and its preparation method and application |
Non-Patent Citations (2)
| Title |
|---|
| DAS RAGHUNATH等: "High-Performance Hg(II) Removal Using Thiol-Functionalized Polypyrrole (PPy/MAA) Composite and Effective Catalytic Activity of Hg(II)-Adsorbed Waste Material", 《ACS SUSTAINABLE CHEMISTRY & ENGINEERING》 * |
| 李超: "微凝胶负载纳米银和聚吡咯复合材料制备及性能研究", 《中国优秀博硕士学位论文全文数据库(硕士)工程科技Ⅰ辑》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113231099A (en) * | 2021-05-21 | 2021-08-10 | 吉林大学 | Preparation and application of Z-type polypyrrole-bismuth tungstate photocatalyst |
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Application publication date: 20210723 |