CN113117676A - Cu2Preparation method of O-CuO/bentonite photocatalytic composite material - Google Patents
Cu2Preparation method of O-CuO/bentonite photocatalytic composite material Download PDFInfo
- Publication number
- CN113117676A CN113117676A CN202110251234.3A CN202110251234A CN113117676A CN 113117676 A CN113117676 A CN 113117676A CN 202110251234 A CN202110251234 A CN 202110251234A CN 113117676 A CN113117676 A CN 113117676A
- Authority
- CN
- China
- Prior art keywords
- bentonite
- cuo
- composite material
- photocatalytic composite
- copper nitrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910000278 bentonite Inorganic materials 0.000 title claims abstract description 46
- 239000000440 bentonite Substances 0.000 title claims abstract description 46
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 28
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title description 11
- 229940092782 bentonite Drugs 0.000 claims abstract description 45
- 239000010949 copper Substances 0.000 claims abstract description 19
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 17
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229940080314 sodium bentonite Drugs 0.000 claims abstract description 14
- 229910000280 sodium bentonite Inorganic materials 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000002002 slurry Substances 0.000 claims abstract description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims description 9
- 238000007865 diluting Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 238000000643 oven drying Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 abstract description 5
- 238000001354 calcination Methods 0.000 abstract description 2
- 239000002351 wastewater Substances 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 239000011941 photocatalyst Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
- CQBLUJRVOKGWCF-UHFFFAOYSA-N [O].[AlH3] Chemical compound [O].[AlH3] CQBLUJRVOKGWCF-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 238000010170 biological method Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 229910000161 silver phosphate Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B01J35/39—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Abstract
The invention discloses a Cu2The O-CuO/bentonite photocatalytic composite material comprises the following specific steps: placing bentonite in deionized water, and stirring Na2CO3Dissolving in bentonite slurry to obtain sodium bentonite; dissolving copper nitrate in deionized water to prepare a copper nitrate solution, adding sodium bentonite, stirring at room temperature for 2-4h, putting the dried sample into a muffle furnace, and calcining at the temperature of 300-600 ℃ for 3-6h to prepare Cu2O-CuO/bentonite photocatalytic composite material. The preparation method provided by the invention is simple and easy to operate, and has practical performanceFeasibility of and Cu produced2The O-CuO/bentonite photocatalytic composite material has low cost and no pollution.
Description
Technical Field
The invention belongs to the technical field of preparation of photocatalytic materials, and particularly relates to Cu2A preparation method of O-CuO/bentonite photocatalytic composite material.
Background
With the rise of printing and dyeing and textile industry, the environmental problems caused by organic dye wastewater are becoming more serious, and the treatment of organic dye wastewater becomes the central importance of sewage treatment. The organic dye wastewater has high chromaticity, is toxic and is not easy to be biochemically degraded, and the current common methods for treating the wastewater comprise an adsorption method, a chemical oxidation method, a biological method and the like, but the methods can not efficiently remove organic pollutants in the dye wastewater. Therefore, the research and development of the treatment technology and the method for efficiently treating the organic dye wastewater have important theoretical and practical significance.
In the face of these problems, many scientists thought to utilize photocatalytic oxidation technology to treat organic matter in dye wastewater and achieved considerable results. Of which the nanometer TiO is widely concerned by the big families2But TiO 22There are also problems with application in the field of photocatalytic oxidation. First, TiO2The forbidden band width of the light absorption material is 3.2eV, the light absorption material can only absorb about 4% of ultraviolet light in sunlight, and the utilization rate of visible light is low. Second, photo-excited TiO2Easily generate electron-hole pairs, and generate electrons to TiO by light2In the process of surface migration, electrons and holes can be in TiO2Internal or surface recombination of (2) resulting in a reduction of TiO2The efficiency of the light quanta of (c). Finally, by means of TiO2When the organic dye wastewater is degraded, the problems of easy agglomeration, difficult recovery and the like exist. Therefore, researchers have searched for photocatalysts having a relatively narrow forbidden band width and capable of utilizing sunlight sufficiently to solve the above-mentioned problems.
CuO and Cu2O is a p-type semiconductor havingHigh photocatalytic activity, low cost, stable chemical property, etc. CuO and Cu2The forbidden band width of O is 1.2eV and 2.0eV respectively, and the carrier can be generated under visible light, thereby not only overcoming the defect that TiO2The defect of low utilization rate of visible light can be overcome, and CuO can be used for TiO2Modified to reduce TiO2Probability of photo-generated electron-hole recombination. These advantages result in CuO and Cu2The O has good application prospect in the field of treating organic dye wastewater. However, the use of CuO and Cu is under way2In the process of carrying out photocatalytic oxidation treatment on organic dye wastewater by O, the problems of easy agglomeration, difficult recovery and the like also exist. To solve these problems, scientists have studied supported CuO and Cu2O, thereby obtaining the photocatalytic composite material with larger specific surface area and better photocatalytic effect, and being beneficial to recycling.
Bentonite is a 2:1 type crystal structure of layered silicate mineral composed of two layers of silicon-oxygen tetrahedron and one layer of aluminum-oxygen octahedron, and has the characteristics of large specific surface area, good adsorption performance, strong ion exchange, stable property, low price, large reserve capacity and the like, and is one of the best choices of carriers. By utilizing the structural characteristics of the expanded soil, photocatalyst particles are introduced on the surface and in the interlayer space of the expanded soil, and the supported photocatalyst can be prepared. It is reported that bentonite can react with ZnO, Ag3PO4、Au-TiO2And the composite photocatalyst is prepared by combining the steps of the preparation method and the application, and is used for treating the dye pollutants.
Disclosure of Invention
The invention solves the technical problem of providing the Cu2The method for preparing the O-CuO/bentonite photocatalytic composite material can further improve the high added value utilization of the bentonite, solve the problems that the photocatalyst is difficult to recover in the wastewater treatment process and the like, and finally synthesize Cu by utilizing the respective advantages of the bentonite and the CuO2O-CuO/bentonite photocatalytic composite material.
The invention adopts the following technical scheme to solve the technical problems2The O-CuO/bentonite photocatalytic composite material is characterized by comprising the following specific steps:
step S1: placing bentonite in the containerIonized water, then adding Na while stirring2CO3Dissolving in bentonite slurry, stirring at 60-70 deg.C for 2-4h, standing overnight, diluting to 20-30 wt%, centrifuging, oven drying at 110 deg.C, grinding, and sieving to obtain sodium bentonite;
step S2: dissolving copper nitrate in deionized water to prepare a copper nitrate solution, adding the sodium bentonite obtained in the step S1, stirring at room temperature for 2-4h, placing the reacted sample in a drying box to dry at 60-80 ℃, and then placing the dried sample in a muffle furnace to calcine at 300-600 ℃ for 3-6h to prepare Cu2O-CuO/bentonite photocatalytic composite material.
Further defined, said Na in step S12CO3Preparing 12 to 15 weight percent of bentonite slurry with 3 to 5 weight percent of bentonite.
Further limiting, in the step S2, the concentration of the copper nitrate solution is 0.2-0.5mol/L, and the feeding ratio of the sodium bentonite and the copper nitrate is 8-10g:0.02-0.05 mol.
The invention has the following beneficial effects: 1. cu prepared by the invention2After various tests, the O-CuO/bentonite photocatalytic composite material has a decolorization rate of over 97.8 percent for methylene blue solution and shows good photocatalytic activity; 2. the preparation method provided by the invention is simple and easy to operate, has practical feasibility, and the prepared Cu2The O-CuO/bentonite photocatalytic composite material has low cost and no pollution.
Drawings
FIG. 1 shows Cu obtained in example 12SEM image of O-CuO/bentonite photocatalytic composite material.
Detailed Description
The present invention is described in further detail below with reference to examples, but it should not be construed that the scope of the above subject matter of the present invention is limited to the following examples, and that all the technologies realized based on the above subject matter of the present invention belong to the scope of the present invention.
Example 1
Step S1: placing bentonite in deionized water, and stirring Na2CO3Preparing 12wt% bentonite slurry with 3wt% bentonite, stirring at 60 deg.C for 2 hr, standing overnight, diluting the bentonite slurry to 20wt%, centrifuging, oven drying at 100 deg.C, grinding, and sieving to obtain sodium bentonite;
step S2: dissolving copper nitrate in deionized water to prepare 0.2mol/L copper nitrate solution, adding 8g of sodium bentonite obtained in the step S1 into 100mL of copper nitrate solution, stirring at room temperature for 2h, putting the reacted sample into a drying oven to be dried at 60 ℃, putting the dried sample into a muffle furnace to be calcined at 300 ℃ for 3h to prepare Cu2O-CuO/bentonite photocatalytic composite material.
Example 2
Step S1: placing bentonite in deionized water, and stirring Na2CO3Preparing 13wt% of bentonite slurry with 4 wt% of bentonite, stirring at 65 ℃ for 3h, standing overnight, diluting the bentonite slurry to 25wt%, centrifugally separating, drying at 105 ℃, grinding and sieving to obtain sodium bentonite;
step S2: dissolving copper nitrate in deionized water to prepare 0.3mol/L copper nitrate solution, adding 9g of sodium bentonite obtained in the step S1 into 100mL of copper nitrate solution, stirring at room temperature for 3h, drying the reacted sample in a drying oven at 70 ℃, and calcining the dried sample in a muffle furnace at 400 ℃ for 4h to prepare Cu2O-CuO/bentonite photocatalytic composite material.
Example 3
Step S1: placing bentonite in deionized water, and stirring Na2CO3Preparing 15wt% bentonite slurry with 5wt% bentonite, stirring at 70 deg.C for 4 hr, standing overnight, diluting the bentonite slurry to 30wt%, centrifuging, oven drying at 110 deg.C, grinding, and sieving to obtain sodium bentonite;
step S2: dissolving copper nitrate in deionized water to obtain 0.5mol/L copper nitrate solution, adding 10g of sodium bentonite obtained in the step S1 into 100mL of copper nitrate solution, stirring at room temperature for 4h, drying the reacted sample in a drying oven at 80 ℃, and then putting the dried sample in a drying ovenCalcining the mixture in a muffle furnace for 6 hours at the temperature of 600 ℃ to prepare Cu2O-CuO/bentonite photocatalytic composite material.
The foregoing embodiments illustrate the principles, principal features and advantages of the invention, and it will be understood by those skilled in the art that the invention is not limited to the foregoing embodiments, which are merely illustrative of the principles of the invention, and that various changes and modifications may be made therein without departing from the scope of the principles of the invention.
Claims (3)
1. Cu2The O-CuO/bentonite photocatalytic composite material is characterized by comprising the following specific steps:
step S1: placing bentonite in deionized water, and stirring Na2CO3Dissolving in bentonite slurry, stirring at 60-70 deg.C for 2-4h, standing overnight, diluting to 20-30 wt%, centrifuging, oven drying at 110 deg.C, grinding, and sieving to obtain sodium bentonite;
step S2: dissolving copper nitrate in deionized water to prepare a copper nitrate solution, adding the sodium bentonite obtained in the step S1, stirring at room temperature for 2-4h, placing the reacted sample in a drying box to dry at 60-80 ℃, and then placing the dried sample in a muffle furnace to calcine at 300-600 ℃ for 3-6h to prepare Cu2O-CuO/bentonite photocatalytic composite material.
2. Cu according to claim 12The O-CuO/bentonite photocatalytic composite material is characterized in that: na in step S12CO3Preparing 12 to 15 weight percent of bentonite slurry with 3 to 5 weight percent of bentonite.
3. Cu according to claim 12The O-CuO/bentonite photocatalytic composite material is characterized in that: in the step S2, the concentration of the copper nitrate solution is 0.2-0.5mol/L, and the feeding ratio of the sodium bentonite to the copper nitrate is 8-10g:0.02-0.05 mol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110251234.3A CN113117676A (en) | 2021-03-08 | 2021-03-08 | Cu2Preparation method of O-CuO/bentonite photocatalytic composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110251234.3A CN113117676A (en) | 2021-03-08 | 2021-03-08 | Cu2Preparation method of O-CuO/bentonite photocatalytic composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113117676A true CN113117676A (en) | 2021-07-16 |
Family
ID=76772830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110251234.3A Withdrawn CN113117676A (en) | 2021-03-08 | 2021-03-08 | Cu2Preparation method of O-CuO/bentonite photocatalytic composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113117676A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010207769A (en) * | 2009-03-12 | 2010-09-24 | Aomori Prefectural Industrial Technology Research Center | Photocatalyst for making hydrogen |
| US20110172085A1 (en) * | 2008-05-30 | 2011-07-14 | Süd-Chemie AG | Nanocrystalline copper oxide, and method for the production thereof |
| CN103071498A (en) * | 2013-01-14 | 2013-05-01 | 杜亚丽 | Preparation method of Cu2O compound photocatalyst |
| CN103406122A (en) * | 2013-08-06 | 2013-11-27 | 湖南师范大学 | Catalyst for desorbing nitrogen oxides and carbon monoxide at low temperature and preparation method thereof |
| CN106732589A (en) * | 2016-11-18 | 2017-05-31 | 中国计量大学 | A kind of preparation method of cupric oxide/cuprous oxide/graphene nanocomposite material |
| CN107088413A (en) * | 2017-06-23 | 2017-08-25 | 闽南师范大学 | A kind of CuO/Cu2O photochemical catalysts and preparation method and application |
| CN110152665A (en) * | 2019-05-29 | 2019-08-23 | 湖南人文科技学院 | CuO/Cu2The preparation method of O/Cu trielement composite material |
| CN110227457A (en) * | 2019-06-26 | 2019-09-13 | 成都理工大学 | A kind of preparation method of low temperature liquid phase precipitation method cuprous oxide visible light photochemical catalyst |
| CN111495365A (en) * | 2020-05-29 | 2020-08-07 | 扬州大学 | Novel n-Cu2Preparation method of O/CuO semiconductor photocatalyst |
-
2021
- 2021-03-08 CN CN202110251234.3A patent/CN113117676A/en not_active Withdrawn
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110172085A1 (en) * | 2008-05-30 | 2011-07-14 | Süd-Chemie AG | Nanocrystalline copper oxide, and method for the production thereof |
| JP2010207769A (en) * | 2009-03-12 | 2010-09-24 | Aomori Prefectural Industrial Technology Research Center | Photocatalyst for making hydrogen |
| CN103071498A (en) * | 2013-01-14 | 2013-05-01 | 杜亚丽 | Preparation method of Cu2O compound photocatalyst |
| CN103406122A (en) * | 2013-08-06 | 2013-11-27 | 湖南师范大学 | Catalyst for desorbing nitrogen oxides and carbon monoxide at low temperature and preparation method thereof |
| CN106732589A (en) * | 2016-11-18 | 2017-05-31 | 中国计量大学 | A kind of preparation method of cupric oxide/cuprous oxide/graphene nanocomposite material |
| CN107088413A (en) * | 2017-06-23 | 2017-08-25 | 闽南师范大学 | A kind of CuO/Cu2O photochemical catalysts and preparation method and application |
| CN110152665A (en) * | 2019-05-29 | 2019-08-23 | 湖南人文科技学院 | CuO/Cu2The preparation method of O/Cu trielement composite material |
| CN110227457A (en) * | 2019-06-26 | 2019-09-13 | 成都理工大学 | A kind of preparation method of low temperature liquid phase precipitation method cuprous oxide visible light photochemical catalyst |
| CN111495365A (en) * | 2020-05-29 | 2020-08-07 | 扬州大学 | Novel n-Cu2Preparation method of O/CuO semiconductor photocatalyst |
Non-Patent Citations (1)
| Title |
|---|
| NAI LI等: ""Simple synthesisofCu2O/Na-bentonite compositesandtheirexcellent photocatalytic propertiesintreatingmethylorangesolution"", 《CERAMICSINTERNATIONAL》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102580742B (en) | Activated carbon-loaded cuprous oxide photocatalyst and preparation method thereof | |
| CN110152711B (en) | CeO (CeO)2@MoS2/g-C3N4Ternary composite photocatalyst and preparation method thereof | |
| CN109985618B (en) | H occupies BiVO4-OVs photocatalytic material, preparation method and application thereof | |
| CN110776049B (en) | Method for treating organic wastewater by activating peroxymonosulfate with functionalized zirconium-based metal organic framework/protonated carbon nitride composite material | |
| CN108355669B (en) | Magnetic nano onion carbon loaded Bi2WO6Photocatalyst and preparation method and application thereof | |
| CN105126917B (en) | A kind of preparation method of copper/cuprous oxide/cyclization polyacrylonitrile visible light catalyst | |
| CN109622013B (en) | Graphite-like carbon nitride- (110) crystal face bismuth vanadate Z-type heterojunction photocatalyst and preparation method and application thereof | |
| CN108325555B (en) | Nitrogen self-doped graphitized carbon nitride nanosheet photocatalyst and preparation method and application thereof | |
| CN106552651B (en) | Bi12O17Br2Synthesis and application method of photocatalyst | |
| CN106693996B (en) | Preparation method and application of bismuth sulfide-bismuth ferrite composite visible-light-driven photocatalyst | |
| CN109453800B (en) | All-solid-state silver iodide/carbon nitride/bismuth tungstate double-Z-type ternary heterojunction photocatalyst and preparation method and application thereof | |
| CN111874988A (en) | Based on multi-element co-doped TiO2Organic wastewater treatment method of nano photocatalytic material | |
| CN108906090B (en) | Photocatalytic composite material with p-n heterojunction and preparation method and application thereof | |
| CN111992216B (en) | Preparation method and application of composite heterojunction photocatalyst | |
| CN112742419A (en) | Novel visible-light-responsive nano catalyst and preparation method and application thereof | |
| WO2023108950A1 (en) | PREPARATION METHOD FOR Z-SCHEME α-FE2O3/ZNIN2S4 COMPOSITE PHOTOCATALYST AND USE THEREOF | |
| CN110302826B (en) | Basic bismuth nitrate and bismuth oxyiodide composite photocatalyst and preparation method and application thereof | |
| CN113976147B (en) | Bi/Bi 4 O 5 Br 2 Photocatalyst, preparation method and application thereof | |
| CN111604083A (en) | Graphite type carbon nitride composite photocatalytic material with oxygen vacancy bismuth tungstate/oxygen-enriched structure and preparation method and application thereof | |
| CN108940349B (en) | Method for removing dye pollutants by using silver chromate/sulfur-doped nitrogen carbon Z-type photocatalyst | |
| CN108435149B (en) | Nano cuprous oxide-based dye adsorption material and preparation method thereof | |
| CN112121866A (en) | Photocatalyst and preparation method thereof | |
| CN113117676A (en) | Cu2Preparation method of O-CuO/bentonite photocatalytic composite material | |
| CN113976107B (en) | Method for preparing Mn-based composite catalyst by using organic waste liquid and application of Mn-based composite catalyst in decomposition of indoor formaldehyde | |
| CN113101959B (en) | Graphite-like phase carbon nitride composite material for soil remediation and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20210716 |
|
| WW01 | Invention patent application withdrawn after publication |