CN113101803A - Device for eliminating ammonia gas and hydrogen sulfide and sterilizing and deodorizing chicken house excrement channel - Google Patents

Device for eliminating ammonia gas and hydrogen sulfide and sterilizing and deodorizing chicken house excrement channel Download PDF

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Publication number
CN113101803A
CN113101803A CN202110433902.4A CN202110433902A CN113101803A CN 113101803 A CN113101803 A CN 113101803A CN 202110433902 A CN202110433902 A CN 202110433902A CN 113101803 A CN113101803 A CN 113101803A
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China
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ultraviolet
hydrogen sulfide
tube shell
sterilizing
tube
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CN202110433902.4A
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Chinese (zh)
Inventor
张跃杰
张建迎
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Hebei Daguo Craftsman Engineering Technology Co ltd
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Hebei Daguo Craftsman Engineering Technology Co ltd
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Priority to CN202110433902.4A priority Critical patent/CN113101803A/en
Publication of CN113101803A publication Critical patent/CN113101803A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8634Ammonia
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/015Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/18Radiation
    • A61L9/20Ultraviolet radiation
    • A61L9/205Ultraviolet radiation using a photocatalyst or photosensitiser
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8612Hydrogen sulfide
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/21Use of chemical compounds for treating air or the like
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/21Use of chemical compounds for treating air or the like
    • A61L2209/212Use of ozone, e.g. generated by UV radiation or electrical discharge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/104Ozone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry

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  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Veterinary Medicine (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

The invention discloses a device for eliminating ammonia gas and hydrogen sulfide, sterilizing and deodorizing chicken house excreta passage, which comprises an ultraviolet light-emitting tube and nano TiO2And a control power supply, the ultraviolet luminous tube and the nano TiO2The control power supply is arranged in the poultry house and is electrically connected with the ultraviolet luminotron. The invention belongs to the technical field of poultry house environment treatment, and particularly relates to a device for eliminating ammonia gas and hydrogen sulfide, sterilizing and deodorizing chicken house excreta, which utilizes ultraviolet photons with 185nm and 253.7nm wavelengths emitted by an ultraviolet light emitting tube and generated O3And ultraviolet light catalyzed nano TiO2The generated hydroxyl radical has multi-aspect synergistic effect, greatly accelerates NH3、H2Decomposition of harmful gas such as S and elimination of odor, ultraviolet photons with wavelength of 185nm and 253.7nm and generated O3Directly kill microorganisms in the excrement and cut off the source of harmful gas.

Description

Device for eliminating ammonia gas and hydrogen sulfide and sterilizing and deodorizing chicken house excrement channel
Technical Field
The invention belongs to the technical field of poultry house environment treatment, and particularly relates to a device for eliminating ammonia gas and hydrogen sulfide, sterilizing and deodorizing a poultry house excrement channel.
Background
Harmful gas NH in chicken house3、H2The S is mainly because the digestive tract of the chicken is short and the digestibility is low, 20 to 25 percent of nutrient substances can not be digested and absorbed by the organism and are discharged out of the body along with excrement, wherein part of sulfur-containing protein is decomposed by microorganisms under the conditions of proper temperature and humidity, and a large amount of ammonia gas and hydrogen sulfide gas are discharged, thereby polluting the air in the house.
At present, the large-scale livestock and poultry breeding industry in China mainly takes closed type captive breeding as a main part. The colony house has poor environment, unsmooth air circulation and heavy peculiar smell, which causes a great amount of bacteria breeding and NH3、H2S and other harmful gases are released, poultry house diseases occur frequently, even epidemic outbreaks occur, and farmers are disastrous. In order to reduce the breeding risk and the morbidity and mortality, a large amount of disinfectant, hormone, antibiotic and other medicines have to be used, so that the production cost is increased, the growth and development of animals and the yield and quality of meat and eggs are influenced, and the health of workers on site for a long time is also harmed. Therefore, the physical method is adopted to purify, reduce the environmental pollution and sterilize the air, which is the key for effectively preventing and controlling the airborne livestock and poultry diseases, especially the avian influenza. The physical method has the main characteristics of no secondary pollution and no residue. At present, an ozone generator is used in a chicken house to generate O3And then dispersed to the whole chicken house by using a pipeline or a fan to eliminate NH3、H2S and other harmful gases and peculiar smell, although having a certain effect, O3The concentration is not easy to control, the speed is slow and uneven. Active carbon is also used for adsorbing harmful gases, so that the cost is high and the effect is limited.
Disclosure of Invention
Aiming at the situation, in order to overcome the defects of the prior art, the invention provides a device for eliminating ammonia gas and hydrogen sulfide, sterilizing and deodorizing chicken house excreta, which utilizes ultraviolet photons with 185nm and 253.7nm wavelengths emitted by an ultraviolet light emitting tube and generated O3And ultraviolet light catalyzed nano TiO2The generated hydroxyl radical has multi-aspect synergistic effect, greatly accelerates NH3、H2Decomposition of harmful gas such as S and elimination of odor, ultraviolet photons with wavelength of 185nm and 253.7nm and generated O3Directly kill microorganisms in the excrement and cut off the source of harmful gas.
The technical scheme adopted by the invention is as follows: the invention relates to a device for eliminating ammonia gas and hydrogen sulfide, sterilizing and deodorizing chicken house excreta passage, which comprises an ultraviolet light-emitting tube and nano TiO2And a control power supply, the ultraviolet luminous tube and the nano TiO2The control power supply is arranged in the poultry house and is electrically connected with the ultraviolet light-emitting tube; the ultraviolet luminotron comprises a tube shell, a lamp holder, an electrode, a tungsten filament, inert gas, mercury drops and a pin, wherein the lamp holder is arranged at one end of the tube shell, the motor is arranged at the other end of the tube shell, the pin is respectively arranged at two sides of the lamp holder and the electrode, the tungsten filament is arranged on the electrode, the inert gas is arranged in the tube shell, and the mercury drops are arranged in the tube shell.
Further, the tube shell is made of far ultraviolet quartz glass, the transmittance of the far ultraviolet quartz glass to 185nm ultraviolet light spectrum is not lower than 70%, and the transmittance of the far ultraviolet quartz glass to the spectrum of the waveband with the wavelength of more than 200nm is more than 80%.
Further, the inert gas and mercury droplets are filled into the tube shell in a vacuum pumping mode, ultraviolet rays with the wavelengths of 185nm and 253.7nm are generated in the process of collision of low-pressure mercury vapor and high-speed electrons and can be emitted to the surrounding space through the tube shell, ultraviolet photons with the wavelengths of 185nm are most easily absorbed by O2 in the air to be decomposed into monatomic oxygen, and the monatomic oxygen and the O2 are formed2Combine to form O3,O3Can be directly reacted with NH3、H2S reaction: o is3+H2S=S+O2+H2O or O3+3H2S=3S+3H2O;7O3+6NH3=6NO2+9H2O or 5O3+6NH3=6NO+9H2The ultraviolet ray with the wavelength of 253.7nm of O not only directly plays a role in sterilization, but also simultaneously ultraviolet photons and O3Synergistic effect accelerates NH3、H2Decomposition and sterilization effects of S gas.
Further, the nano TiO2Can generate hydroxyl radical with strong oxidizing ability under the excitation of ultraviolet photon, and can oxidize harmful gas NH3、H2S is oxidized into harmless substances.
The invention with the structure has the following beneficial effects: the device for eliminating ammonia gas and hydrogen sulfide and sterilizing and deodorizing the chicken house excreta passage utilizes ultraviolet photons with 185nm and 253.7nm wavelengths emitted by an ultraviolet light emitting tube and generated O3And ultraviolet light catalyzed nano TiO2The generated hydroxyl radical has multi-aspect synergistic effect, greatly accelerates NH3、H2Decomposition of harmful gas such as S and elimination of odor, ultraviolet photons with wavelength of 185nm and 253.7nm and generated O3Directly kill microorganisms in the excrement and cut off the source of harmful gas.
Drawings
FIG. 1 is a schematic view of the structure of an ultraviolet light emitting tube of a sterilization and deodorization device for eliminating ammonia and hydrogen sulfide in a chicken house excreta passage.
The lamp comprises an ultraviolet light emitting tube 1, an ultraviolet light emitting tube 2, a tube shell 3, a lamp holder 4, an electrode 5, a tungsten filament 6, inert gas 7, mercury drops 8 and a terminal pin.
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention and not to limit the invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments; all other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
As shown in figure 1, the device for eliminating ammonia gas and hydrogen sulfide, sterilizing and deodorizing chicken house excreta comprises an ultraviolet light emitting tube 1, nano TiO2 and a control power supply, wherein the ultraviolet light emitting tube 1 and the nano TiO2 are arranged in a poultry house, and the control power supply is electrically connected with the ultraviolet light emitting tube 1; the ultraviolet light-emitting tube 1 comprises a tube shell 2, a lamp holder 3, an electrode 4, a tungsten filament 5, inert gas 6, mercury droplets 7 and pins 8, wherein the lamp holder 3 is arranged at one end of the tube shell 2, the motor is arranged at the other end of the tube shell 2, the pins 8 are respectively arranged at two sides of the lamp holder 3 and the electrode 4, the tungsten filament 5 is arranged on the electrode 4, the inert gas 6 is arranged in the tube shell 2, and the mercury droplets 7 are arranged in the tube shell 2.
The tube shell 2 is made of far ultraviolet quartz glass, and the transmittance of the far ultraviolet quartz glass to 185nm ultraviolet light spectrum is not less than 70%, and the transmittance of the far ultraviolet quartz glass to the spectrum of the waveband with the wavelength of more than 200nm is more than 80%.
The inert gas 6 and the mercury drops 7 are filled into the tube shell 2 in a vacuumizing mode, ultraviolet rays with the wavelengths of 185nm and 253.7nm are generated in the process that low-pressure mercury vapor collides with high-speed electrons and can be emitted to the surrounding space through the tube shell 2, ultraviolet photons with the wavelengths of 185nm are most easily absorbed by O2 in the air and are decomposed to form monatomic oxygen, the monatomic oxygen is combined with O2 to form O3, and O3 can directly react with NH3 and H2S: o3+ H2S ═ S + O2+ H2O or O3+3H2S ═ 3S +3H 2O; 7O3+6NH3 ═ 6NO2+9H2O or 5O3+6NH3 ═ 6NO +9H2O, ultraviolet rays with the wavelength of 253.7nm not only directly play a role in sterilization, but also ultraviolet photons and O3 cooperate to accelerate decomposition and sterilization effects of NH3 and H2S gases.
The nano TiO2 can generate hydroxyl radicals with extremely strong oxidizing ability under the excitation of ultraviolet photons, and harmful gases NH3 and H2S are oxidized into harmless substances through oxidation.
When the device is used specifically, a user vacuumizes the tube shell 2, fills the inert gas 6 and the mercury drops 7, generates ultraviolet rays with the wavelengths of 185nm and 253.7nm in the process of collision of low-pressure mercury vapor and high-speed electrons, and can shoot the ultraviolet rays to the surrounding space through the far ultraviolet quartz glass tube shell 2. Ultraviolet photons with the wavelength of 185nm are most easily absorbed by O2 in the air to be decomposed into monatomic oxygen, the monatomic oxygen is combined with O2 to form O3, and O3 can directly react with NH3 and H2S: o3+ H2S ═ S + O2+ H2O or O3+3H2S ═ 3S +3H 2O; ultraviolet light with the wavelength of 7O3+6NH3 being 6NO2+9H2O or 5O3+6NH3 being 6NO +9H2O and the wavelength of 253.7nm not only directly plays a role in sterilization, but also ultraviolet photons and O3 cooperate to accelerate decomposition and sterilization of NH3 and H2S gases, nano TiO2 is sprayed on the walls on the two sides of the excrement channel to generate hydroxyl radicals with extremely strong oxidizing power under the excitation of the ultraviolet photons, harmful gases NH3 and H2S are oxidized into harmless substances through the oxidizing function, the ultraviolet photons with the wavelength of 185nm and 253.7nm cooperate with the generated O3 and hydroxyl radicals in multiple aspects, decomposition and elimination of odor of harmful gases such as NH3 and H2S are greatly accelerated, and ultraviolet photons with the wavelength of 185nm and 253.7nm and the generated O3 directly kill microorganisms in excrement at the bottom of the excrement channel, and the source of the harmful gases is cut off. The above is the overall working process of the invention, and the steps are repeated when the device is used next time.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
The present invention and its embodiments have been described above, and the description is not intended to be limiting, and the drawings are only one embodiment of the present invention, and the actual structure is not limited thereto. In summary, those skilled in the art should appreciate that they can readily use the disclosed conception and specific embodiments as a basis for designing or modifying other structures for carrying out the same purposes of the present invention without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (3)

1. The utility model provides a chicken coop excrement is said and is eliminated ammonia, hydrogen sulfide, sterilization deodorizing device which characterized in that: comprises an ultraviolet luminous tube and nano TiO2And a control power supply, the ultraviolet luminous tube and the nano TiO2The control power supply is arranged in the poultry house and is electrically connected with the ultraviolet light-emitting tube; the ultraviolet luminotron comprises a tube shell, a lamp holder, an electrode, a tungsten filament, inert gas, mercury drops and a pin, wherein the lamp holder is arranged at one end of the tube shell, the motor is arranged at the other end of the tube shell, the pin is respectively arranged at two sides of the lamp holder and the electrode, the tungsten filament is arranged on the electrode, the inert gas is arranged in the tube shell, and the mercury drops are arranged in the tube shell.
2. The device for eliminating ammonia gas and hydrogen sulfide, sterilizing and deodorizing chicken house excreta according to claim 1, characterized in that: the tube shell is made of far ultraviolet quartz glass, the transmittance of the far ultraviolet quartz glass to 185nm ultraviolet light spectrum is not less than 70%, and the transmittance of the far ultraviolet quartz glass to the spectrum of the waveband with the wavelength of more than 200nm is more than 80%.
3. The device for eliminating ammonia gas and hydrogen sulfide, sterilizing and deodorizing in the henhouse excreta tract of claim 2, characterized in that: the inert gas and the mercury drops are filled into the tube shell in a vacuumizing mode.
CN202110433902.4A 2021-04-21 2021-04-21 Device for eliminating ammonia gas and hydrogen sulfide and sterilizing and deodorizing chicken house excrement channel Pending CN113101803A (en)

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CN202110433902.4A CN113101803A (en) 2021-04-21 2021-04-21 Device for eliminating ammonia gas and hydrogen sulfide and sterilizing and deodorizing chicken house excrement channel

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001078793A1 (en) * 2000-04-12 2001-10-25 Purizer Corporation Sterilization process for air, liquid and surfaces
CN101966347A (en) * 2010-08-16 2011-02-09 南通格林福得禽业科技有限公司 Light source special for livestock and poultry building
CN201768197U (en) * 2010-08-26 2011-03-23 南通格林福得禽业科技有限公司 Special light source luminous structure for poultry buildings
CN206463778U (en) * 2016-12-20 2017-09-05 云南沃润特环境工程有限公司 A kind of ultraviolet light deodorizing sterilizing device
CN208032278U (en) * 2018-02-08 2018-11-02 青岛华世洁环保科技有限公司 Processing unit for removing the exhaust gas containing VOCs

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001078793A1 (en) * 2000-04-12 2001-10-25 Purizer Corporation Sterilization process for air, liquid and surfaces
CN101966347A (en) * 2010-08-16 2011-02-09 南通格林福得禽业科技有限公司 Light source special for livestock and poultry building
CN201768197U (en) * 2010-08-26 2011-03-23 南通格林福得禽业科技有限公司 Special light source luminous structure for poultry buildings
CN206463778U (en) * 2016-12-20 2017-09-05 云南沃润特环境工程有限公司 A kind of ultraviolet light deodorizing sterilizing device
CN208032278U (en) * 2018-02-08 2018-11-02 青岛华世洁环保科技有限公司 Processing unit for removing the exhaust gas containing VOCs

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