CN113073015A - Sterilization and deodorization laundry detergent for pets and preparation method thereof - Google Patents
Sterilization and deodorization laundry detergent for pets and preparation method thereof Download PDFInfo
- Publication number
- CN113073015A CN113073015A CN202110212164.0A CN202110212164A CN113073015A CN 113073015 A CN113073015 A CN 113073015A CN 202110212164 A CN202110212164 A CN 202110212164A CN 113073015 A CN113073015 A CN 113073015A
- Authority
- CN
- China
- Prior art keywords
- mass
- laundry detergent
- agent
- pets
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 55
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000004659 sterilization and disinfection Methods 0.000 title abstract description 17
- 238000004332 deodorization Methods 0.000 title abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000008213 purified water Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 18
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 13
- 238000002844 melting Methods 0.000 claims abstract description 10
- 230000008018 melting Effects 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 8
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 8
- 239000000022 bacteriostatic agent Substances 0.000 claims abstract description 8
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 8
- 239000002216 antistatic agent Substances 0.000 claims abstract description 7
- 239000002738 chelating agent Substances 0.000 claims abstract description 7
- 239000006184 cosolvent Substances 0.000 claims abstract description 7
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 7
- 239000002689 soil Substances 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- 230000000844 anti-bacterial effect Effects 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 11
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 10
- 239000002781 deodorant agent Substances 0.000 claims description 8
- 229920002413 Polyhexanide Polymers 0.000 claims description 7
- 108700004121 sarkosyl Proteins 0.000 claims description 7
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical group [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 7
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 6
- 239000001509 sodium citrate Substances 0.000 claims description 6
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical group O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 6
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 claims description 5
- 235000005979 Citrus limon Nutrition 0.000 claims description 5
- 244000131522 Citrus pyriformis Species 0.000 claims description 5
- 244000178870 Lavandula angustifolia Species 0.000 claims description 5
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 5
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 5
- 229940079868 disodium laureth sulfosuccinate Drugs 0.000 claims description 5
- YGAXLGGEEQLLKV-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-2-sulfonatobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)CC(C([O-])=O)S([O-])(=O)=O YGAXLGGEEQLLKV-UHFFFAOYSA-L 0.000 claims description 5
- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 239000001102 lavandula vera Substances 0.000 claims description 5
- 235000018219 lavender Nutrition 0.000 claims description 5
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical class NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 claims description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 229940048081 trisodium ethylenediamine disuccinate Drugs 0.000 claims description 5
- QEHXDDFROMGLSP-VDBFCSKJSA-K trisodium;(2s)-2-[2-[[(1s)-1-carboxy-2-carboxylatoethyl]amino]ethylamino]butanedioate Chemical compound [Na+].[Na+].[Na+].OC(=O)C[C@@H](C([O-])=O)NCCN[C@H](C([O-])=O)CC([O-])=O QEHXDDFROMGLSP-VDBFCSKJSA-K 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 229920002907 Guar gum Polymers 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000000665 guar gum Substances 0.000 claims description 4
- 235000010417 guar gum Nutrition 0.000 claims description 4
- 229960002154 guar gum Drugs 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 229940087291 tridecyl alcohol Drugs 0.000 claims description 2
- GOJYXPWOUJYXJC-UHFFFAOYSA-M sodium;2-[1-(2-hydroxyethyl)-2-undecyl-4,5-dihydroimidazol-1-ium-1-yl]acetate;hydroxide Chemical compound [OH-].[Na+].CCCCCCCCCCCC1=NCC[N+]1(CCO)CC([O-])=O GOJYXPWOUJYXJC-UHFFFAOYSA-M 0.000 claims 2
- 244000303965 Cyamopsis psoralioides Species 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 229920000289 Polyquaternium Polymers 0.000 claims 1
- 229940081510 piroctone olamine Drugs 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 7
- 244000052616 bacterial pathogen Species 0.000 abstract description 5
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 17
- 239000004744 fabric Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 241000699670 Mus sp. Species 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000005202 decontamination Methods 0.000 description 6
- 230000003588 decontaminative effect Effects 0.000 description 6
- HVFAVOFILADWEZ-UHFFFAOYSA-M sodium;2-[2-(dodecanoylamino)ethyl-(2-hydroxyethyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCCN(CCO)CC([O-])=O HVFAVOFILADWEZ-UHFFFAOYSA-M 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 231100000460 acute oral toxicity Toxicity 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
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- 238000002372 labelling Methods 0.000 description 3
- 210000002374 sebum Anatomy 0.000 description 3
- 229960004418 trolamine Drugs 0.000 description 3
- MDXWMKVNEYKORC-UHFFFAOYSA-N 2,2-dihydroxyethyl-methyl-tetradecylazanium bromide Chemical compound [Br-].C(CCCCCCCCCCCCC)[NH+](CC(O)O)C MDXWMKVNEYKORC-UHFFFAOYSA-N 0.000 description 2
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 229940061629 trideceth-9 Drugs 0.000 description 2
- 229940031723 1,2-octanediol Drugs 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 241000282472 Canis lupus familiaris Species 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 241000699666 Mus <mouse, genus> Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- 241000194017 Streptococcus Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229940113120 dipropylene glycol Drugs 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
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- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
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- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
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- 239000013642 negative control Substances 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
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- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
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- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/38—Products with no well-defined composition, e.g. natural products
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the technical field of detergents, in particular to a sterilization and deodorization laundry detergent for pets and a preparation method thereof, wherein the laundry detergent is prepared from the following components: the cleaning agent comprises a cationic surfactant, an anionic surfactant, an amphoteric surfactant, a nonionic surfactant, a pH regulator, a bacteriostatic agent, a chelating agent, essence, an anti-soil redeposition agent, a cosolvent, an antistatic agent and the balance of purified water, wherein the sum of the mass fractions of the components is 100%. The preparation method of the laundry detergent comprises the steps of adding the components into a material melting kettle at different temperatures, melting the materials, and filtering. Compared with the common laundry detergent, the sterilizing and deodorizing laundry detergent for pets can effectively remove excrement stains, peculiar smell, germs and the like stained on pet clothes, toys and other pet articles in a targeted manner, is clean in washing and high in sterilizing rate, and keeps the pet clothes, the toys and the like clean and fresh.
Description
Technical Field
The invention relates to the technical field of detergents, in particular to a sterilizing and deodorizing laundry detergent for pets and a preparation method thereof.
Background
In cold winter, the owners of a plurality of pets can wear pet clothes for the pet cats and the pet dogs, so that the pet clothes not only can keep the pets cold and warm, but also can dress the pets beautifully. As the pet runs under the ground, the clothes are easily polluted, and the excrement of the animal also easily falls on the clothes, the clothes of the pet can be infected with foreign matters and germs. If ordinary washing powder or laundry detergent is used, germs and odor cannot be removed effectively in a targeted mode, and therefore health risks are brought to pets and owners of the pets.
The patent with publication number CN108048242A discloses an antibacterial laundry detergent and a preparation method thereof, wherein the antibacterial laundry detergent comprises the following components: sodium laureth sulfate, dodecylbenzene sulfonic acid, sodium hydroxide, citric acid, triethanolamine, cocoyl methyl monoethanolamine, acrylate copolymer, triclocarban, p-chloro-m-xylenol, 1, 2-octanediol, dipropylene glycol, phenoxyethanol, sodium chloride, cason and water. The laundry detergent prepared by the method has high sterilization rate, but uses parachlorometaxylenol with high toxicity, and is harmful to human bodies and the environment. The patent with publication number CN106497698A discloses an anion and cation compound antibacterial laundry detergent, which comprises the following components in percentage by weight: sodium dodecyl benzene sulfonate (LAS) accounting for 1.0-9.6% of the weight, sodium fatty alcohol polyoxyethylene ether sulfate (AES) accounting for 1.0-9.6% of the weight, fatty alcohol polyoxyethylene ether accounting for 1.0-8.0% of the weight, cocoamidopropyl amine oxide accounting for 1.0-8.0% of the weight, tetradecyl methyl dihydroxyethyl ammonium bromide accounting for 0.2-1.0% of the weight, sodium citrate accounting for 2.0% of the weight, sodium hydroxide accounting for 0.01% of the weight, sodium chloride accounting for 3.0% of the weight and essence accounting for 0.1% of the weight. The laundry detergent disclosed by the patent is an anion-cation compound laundry detergent with good washing effect and remarkable antibacterial effect, but the Tetradecyl Methyl Dihydroxyethyl Ammonium Bromide (TMDAB) cationic surfactant with a complex preparation process is used, so that the processing cost is high.
The liquid detergent has solubility limit and surfactant compatibility problems, and the addition variety and amount of inorganic auxiliary agents are greatly influenced. How to prepare the mild, safe, nontoxic, high-efficiency, low-foam laundry detergent which can sterilize and deodorize while washing still remains a difficult problem to be solved in the detergent industry. In addition, the above patents are not the sterilization and deodorization laundry detergent for pets, and can not remove germs and odor specifically and effectively. Therefore, the market needs a sterilization and deodorization laundry detergent for pets, which has multiple effects of healthy natural decontamination, sterilization, mite removal, softness and static electricity resistance.
Although people in the industry have searched for laundry detergents with sterilization and deodorization at present, the search for different formulations for detergents for pet clothes still has important significance.
Disclosure of Invention
The invention provides the sterilizing and deodorizing laundry detergent for pets and the preparation method thereof, aiming at solving the problem that the market has no sterilizing and deodorizing laundry detergent for pets, which can quickly and effectively remove hidden bacteria and peculiar smell on clothes, and have the advantages of no phosphorus and fluorescent agent, little harm to human bodies and environment, simple preparation process and the like.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the bactericidal and deodorant laundry detergent for pets is prepared from, by mass, 0.5-1.5% of cationic surfactant, 15-30% of anionic surfactant, 8-16% of amphoteric surfactant, 6.5-13.5% of nonionic surfactant, 0.2-1% of pH regulator, 2.11-5.55% of bacteriostatic agent, 3.01-6.05% of chelating agent, 0.05-0.1% of essence, 0.03-0.3% of anti-soil redeposition agent, 6-12% of cosolvent, 0.1-1.5% of antistatic agent and the balance of purified water, wherein the sum of the mass fractions of the components is 100%.
Further, the cationic surfactant is polyquaternium-10;
the anionic surfactant is sodium lauroyl sarcosinate and disodium laureth sulfosuccinate;
the amphoteric surfactant is cocamidopropyl betaine and sodium lauroamphoacetate;
the nonionic surfactant is alkyl polyglucoside, tridecyl alcohol polyether-9 and glycerol stearate;
the pH regulator is sodium citrate and citric acid;
the bacteriostatic agent is polyhexamethylene biguanide hydrochloride, piroctone olamine salt and DMDM hydantoin;
the chelating agent is triethanolamine and trisodium ethylenediamine disuccinate;
the essence is lemon essence or lavender essence;
the anti-stain redeposition agent is polyvinylpyrrolidone
The cosolvent is polyethylene glycol-150 and PEG-40 hydrogenated castor oil;
the antistatic agent is guar gum hydroxypropyl trimethyl ammonium chloride.
Further, the laundry detergent is prepared from the following components in parts by mass,
a preparation method of a bactericidal and deodorant laundry detergent for pets comprises the following steps:
step 1: weighing the components according to the mass fraction, taking 30-40% of the total mass of purified water, wherein the temperature of the purified water is 55-65 ℃, adding the purified water into a material dissolving kettle, adding a cationic surfactant, an anionic surfactant, an amphoteric surfactant and a nonionic surfactant into the material dissolving kettle respectively, and stirring uniformly;
step 2: when the temperature in the material melting kettle is reduced to 45-55 ℃, respectively adding a bacteriostatic agent, a chelating agent, an anti-soil redeposition agent, a cosolvent, an antistatic agent and the rest of purified water, wherein the temperature of the purified water in the step is 45-55 ℃, and uniformly stirring;
and step 3: and (3) when the temperature in the material melting kettle is reduced to 34-45 ℃, adding a pH regulator, regulating the pH value to 6.0-9.0, then adding essence, uniformly stirring, and filtering to obtain the sterilizing and deodorizing laundry detergent for pets.
The obtained sterilizing and deodorizing laundry detergent for pets is subjected to filling, labeling and boxing after being detected to be qualified.
Further, a preparation method of the sterilizing and deodorizing laundry detergent for pets comprises the following steps:
step 1: weighing the components according to the mass fraction, taking 30-40% of the total mass of purified water, adding the purified water at the temperature of 55-65 ℃ into a material dissolving kettle, adding polyquaternium-10, sodium lauroyl sarcosinate, disodium laureth sulfosuccinate, cocamidopropyl betaine, sodium lauroamphoacetate, alkyl polyglucoside, trideceth-9 and glycerol stearate into the material dissolving kettle respectively, and uniformly stirring;
step 2: after the temperature in the material melting kettle is reduced to 45-55 ℃, polyhexamethylene biguanide hydrochloride, piroctone olamine salt, DMDM hydantoin, triethanolamine, trisodium ethylenediamine disuccinate, polyvinylpyrrolidone, polyethylene glycol-150, PEG-40 hydrogenated castor oil, guar gum hydroxypropyl trimethyl ammonium chloride and the rest purified water are respectively added and stirred uniformly;
and step 3: when the temperature in the material melting kettle is reduced to 34-45 ℃, adding sodium citrate and citric acid, adjusting the pH value to 6.0-9.0, then adding lemon essence or lavender essence, stirring uniformly, and filtering to obtain the sterilizing and deodorizing laundry detergent for pets;
the obtained sterilizing and deodorizing laundry detergent for pets is subjected to filling, labeling and boxing after being detected to be qualified.
Through the technical scheme, the invention has the beneficial effects that:
1. the sterilization rate is strong: the antibacterial agent can penetrate into clothing fiber, has a sterilization rate of more than 97% for common pathogenic bacteria such as escherichia coli and staphylococcus aureus, and has a protective effect on human and pets.
2. Fragrant and comfortable: has the advantages of clean decontamination function, unique foam control technology, easy rinsing and soft and fragrant washed clothes.
3. The safety is high: the sterilizing and deodorizing laundry detergent for pets contains a bactericide which is low-toxic and harmless to human bodies and pets, does not cause deformity, and is mild and non-irritant. Simultaneously, the dual purposes of decontamination and sterilization are achieved, no stimulation is caused to people and pets, clothes are protected from fading, and the clothes are safe and environment-friendly.
Drawings
FIG. 1 is a graph of the stain removal performance of carbon black soiled cloths of the products of examples 1-4 of the present invention and comparative examples 1-4;
FIG. 2 is a graph of the stain removal performance of protein soiled cloths of the products of examples 1-4 and comparative examples 1-4 of the present invention;
FIG. 3 is a graph of the stain removal performance of the soiled sebum cloths of examples 1-4 of the present invention and comparative examples 1-4;
FIG. 4 is a summary of the stain removal capability of carbon black soiled cloth, protein soiled cloth and sebum soiled cloth of the products of examples 1-4 of the present invention and comparative examples 1-4.
Detailed Description
The invention is further described with reference to the following figures and detailed description:
example 1
A sterilization and deodorization laundry detergent for pets is prepared from the following components in parts by mass,
the preparation method of the bactericidal deodorant laundry detergent for pets comprises the following steps:
step 1: weighing the components according to the mass fraction, taking 30-40% of the total mass of purified water, adding the purified water at the temperature of 55-65 ℃ into a material dissolving kettle, adding polyquaternium-10, sodium lauroyl sarcosinate, disodium laureth sulfosuccinate, cocamidopropyl betaine, sodium lauroamphoacetate, alkyl polyglucoside, trideceth-9 and glycerol stearate into the material dissolving kettle respectively, and uniformly stirring;
step 2: when the temperature in the material melting kettle is reduced to 45-55 ℃, adding polyhexamethylene biguanide hydrochloride, piroctone olamine salt, DMDM hydantoin, triethanolamine, trisodium ethylenediamine disuccinate, polyvinylpyrrolidone, polyethylene glycol-150, PEG-40 hydrogenated castor oil, guar gum hydroxypropyl trimethyl ammonium chloride and the rest purified water respectively, wherein the temperature of the added rest purified water is 45-55 ℃, and stirring uniformly;
and step 3: when the temperature in the material melting kettle is reduced to 34-45 ℃, adding sodium citrate and citric acid, adjusting the pH value to 6.0-9.0, then adding lemon essence or lavender essence, stirring uniformly, and filtering to obtain the sterilizing and deodorizing laundry detergent for pets;
the obtained sterilizing and deodorizing laundry detergent for pets is subjected to filling, labeling and boxing after being detected to be qualified. The laundry detergent product of the embodiment has no layering and no precipitation; fragrant smell and no peculiar smell.
Example 2
A sterilization and deodorization laundry detergent for pets is prepared from the following components in parts by mass,
the preparation method of this example is the same as example 1. The laundry detergent product of the embodiment has no layering and no precipitation; fragrant smell and no peculiar smell.
Example 3
A sterilization and deodorization laundry detergent for pets is prepared from the following components in parts by mass,
the preparation method of this example is the same as example 1. The laundry detergent product of the embodiment has no layering and no precipitation; fragrant smell and no peculiar smell.
Example 4
A sterilization and deodorization laundry detergent for pets is prepared from the following components in parts by mass,
the preparation method of this example is the same as example 1. The laundry detergent product of the embodiment has no layering and no precipitation; fragrant smell and no peculiar smell.
Comparative example 1 is the same as example 4 except that the content of sodium lauroyl sarcosinate in the anionic surfactant was reduced from 20% to 3% by weight.
Comparative example 2 is the same as example 4 except that the weight percentage of sodium lauroamphoacetate in the amphoteric surfactant is reduced from 6% to 1%.
Comparative example 3 is the same as example 4 except that the citric acid content in the pH adjuster was changed from 0.3% to 0.01% by weight.
Comparative example 4 is the same as example 4 except that the polyhexamethylene biguanide hydrochloride content of the bacteriostatic agent was changed from 0.4% to 0.05% by weight.
Experimental example 1: acute oral toxicity test in mice.
Acute oral toxicity test: experimental groups: 30 Kunming white mice are randomly divided into 3 groups, each group comprises 10 mice, each half of the mice is male and female, and the weight of the mice ranges from 18 g to 21 g. After taking white mice which are fasted for 16h, the bactericidal and deodorant laundry detergent product for pets of example 1 is taken once through oral gavage according to the amount of 3000mg/kg · bw, 4000mg/kg · bw and 5000mg/kg · bw, and the poisoning performance and the death condition are recorded after continuously observing for 14 d. Negative control group: 10 test animals, each half of male and female, weighing 17-22 g, were administered with the same amount of sterile distilled water and were observed in control with the test group. As a result: the acute oral LD50 of the mouse is more than 5000 mg/kg-bw. According to the grading standard of acute oral toxicity, the product prepared by the invention has actual non-toxic grade on the acute oral toxicity of mice.
Experimental example 2: and (5) testing the sterilization effect.
The products of examples 1 to 4 and comparative examples 1 to 4 were tested according to the evaluation method for antibacterial and bacteriostatic effects of QB-T2738-.
TABLE 1 comparison of the fungicidal Effect of examples 1 to 4 and comparative examples 1 to 4
Therefore, the sterilization effect of the embodiments 1 to 4 is obviously better than that of the comparative examples 1 to 4. In comparative example 1, sodium lauroyl sarcosinate is low, in comparative example 2, sodium lauroamphoacetate is low, in comparative example 3, citric acid is low, and in comparative example 4, polyhexamethylene biguanide hydrochloride is low, so that the bactericidal power for escherichia coli, staphylococcus aureus, candida albicans, streptococcus, pseudomonas aeruginosa and aspergillus niger is obviously reduced. Therefore, the reasonable proportion of each component in the invention is very important.
Experimental example 3: and (4) testing the dirt-removing capability of the laundry detergent.
The laundry detergent products of examples 1-4 and comparative examples 1-4 were subjected to a soil release performance test of the laundry detergent.
According to GB/T13174-2008 determination of detergency and circular washing performance of a washing agent for clothing, various dirty cloths required by an experiment are cut into test pieces with the size of 6cm multiplied by 6cm, 1L of test solution with the sample concentration of 2g/L and the constant temperature of 30 ℃ and the fixed rotating speed of 120r/min lasts for 20min by adopting 250mg/kg of hard water, the test pieces are rinsed once and then dried, whiteness values before and after washing are determined, and the detergency of each sample is calculated. As can be seen from FIGS. 1 to 4, the decontamination effects of the carbon black soiled cloth, the protein soiled cloth and the sebum soiled cloth in the examples 1 to 4 are not very different; comparative examples 1 to 4 showed a significant reduction in stain removal. Therefore, the reasonable proportion of each component in the invention is very important.
In conclusion, through the analysis of the decontamination effects of the carbon black contaminated cloth, the protein contaminated cloth and the leather contaminated cloth, the samples of the embodiments 1 to 4 of the present invention have good decontamination effects, and can effectively sterilize and deodorize.
The above-mentioned embodiments are merely preferred embodiments of the present invention, which are merely illustrative and not restrictive, and it should be understood that other embodiments may be easily implemented by those skilled in the art by means of replacement or modification according to the technical contents disclosed in the specification, and therefore, all changes and modifications that come within the spirit and technical conditions of the present invention should be included in the claims of the present invention.
Claims (4)
1. The bactericidal and deodorant laundry detergent for pets is characterized by being prepared from 0.5-1.5% by mass of cationic surfactant, 15-30% by mass of anionic surfactant, 8-16% by mass of amphoteric surfactant, 6.5-13.5% by mass of nonionic surfactant, 0.2-1% by mass of pH regulator, 2.11-5.55% by mass of bacteriostatic agent, 3.01-6.05% by mass of chelating agent, 0.05-0.1% by mass of essence, 0.03-0.3% by mass of anti-soil redeposition agent, 6-12% by mass of cosolvent, 0.1-1.5% by mass of antistatic agent and the balance of purified water, wherein the sum of the mass fractions of the components is 100%.
2. The bactericidal deodorant laundry detergent for pets according to claim 1,
the cationic surfactant is polyquaternium-10;
the anionic surfactant is sodium lauroyl sarcosinate and disodium laureth sulfosuccinate;
the amphoteric surfactant is cocamidopropyl betaine and sodium lauroamphoacetate;
the nonionic surfactant is alkyl polyglucoside, tridecyl alcohol polyether-9 and glycerol stearate;
the pH regulator is sodium citrate and citric acid;
the bacteriostatic agent is polyhexamethylene biguanide hydrochloride, piroctone olamine salt and DMDM hydantoin;
the chelating agent is triethanolamine and trisodium ethylenediamine disuccinate;
the essence is lemon essence or lavender essence;
the anti-stain redeposition agent is polyvinylpyrrolidone;
the cosolvent is polyethylene glycol-150 and PEG-40 hydrogenated castor oil;
the antistatic agent is guar gum hydroxypropyl trimethyl ammonium chloride.
3. The bactericidal and deodorant laundry detergent as claimed in claim 2, which is prepared from, by mass, 100.5-1.5% of polyquaternium, 10-20% of sodium lauroyl sarcosinate, 5-10% of disodium laureth sulfosuccinate, 3-6% of cocamidopropyl betaine, 5-10% of sodium lauroamphoacetate, 3-6% of alkylpolyglucoside, 93-6% of trideceth-93, 0.5-1.5% of glycerol stearate, 0.1-0.5% of sodium citrate, 0.1-0.5% of citric acid, 0.1-0.5% of polyhexamethylene biguanide hydrochloride, 2-5% of piroctone olamine, 0.01-0.05% of DMDM hydantoin, 3-6% of triethanolamine, 0.01-0.05% of trisodium ethylenediamine disuccinate, 0.05% of lemon essence or lavender essence, 0.05-0.1% of sodium dehydroandrene, and, 0.03-0.3% of polyvinylpyrrolidone, 1503-6% of polyethylene glycol, 3-6% of PEG-40 hydrogenated castor oil, 0.1-1.5% of guar hydroxypropyl trimethyl ammonium chloride and the balance of purified water, wherein the sum of the mass fractions of the components is 100%.
4. The preparation method of the bactericidal and deodorant laundry detergent for pets according to any one of claims 1 to 3, characterized by comprising the following steps:
step 1: weighing each component according to the mass fraction of claim 1, taking 30-40% of the total mass of purified water, adding the purified water at the temperature of 55-65 ℃ into a material dissolving kettle, adding a cationic surfactant, an anionic surfactant, an amphoteric surfactant and a nonionic surfactant into the material dissolving kettle respectively, and uniformly stirring;
step 2: when the temperature in the material melting kettle is reduced to 45-55 ℃, respectively adding a bacteriostatic agent, a chelating agent, an anti-soil redeposition agent, a cosolvent, an antistatic agent and the rest of purified water, wherein the temperature of the purified water is 45-55 ℃, and uniformly stirring;
and step 3: and (3) when the temperature in the material melting kettle is reduced to 34-45 ℃, adding a pH regulator, regulating the pH value to 6.0-9.0, then adding essence, uniformly stirring, and filtering to obtain the sterilizing and deodorizing laundry detergent for pets.
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Effective date of registration: 20240424 Address after: E214, 2nd Floor, Zone E, Building 2, No. 3100 Hutai Road, Baoshan District, Shanghai, 2019 Patentee after: Maidu Chongyi (Shanghai) Technology Development Co.,Ltd. Country or region after: China Address before: 450000 Henan Province Zhengzhou Airport Economic Comprehensive Experimental Zone Minggang office Huaxia Avenue and Nanhai Avenue intersection East 200m Road North Patentee before: ZHENGZHOU BARY ANIMAL PHARMACEUTICAL Co.,Ltd. Country or region before: China |
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