CN113062006A - Environment-friendly composite textile material and preparation method thereof - Google Patents
Environment-friendly composite textile material and preparation method thereof Download PDFInfo
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- CN113062006A CN113062006A CN202110359982.3A CN202110359982A CN113062006A CN 113062006 A CN113062006 A CN 113062006A CN 202110359982 A CN202110359982 A CN 202110359982A CN 113062006 A CN113062006 A CN 113062006A
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- textile material
- regenerated pet
- environment
- composite textile
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- 239000004753 textile Substances 0.000 title claims abstract description 71
- 239000000463 material Substances 0.000 title claims abstract description 67
- 239000002131 composite material Substances 0.000 title claims abstract description 65
- 238000002360 preparation method Methods 0.000 title claims abstract description 38
- 239000000835 fiber Substances 0.000 claims abstract description 181
- 238000009987 spinning Methods 0.000 claims abstract description 30
- 238000005470 impregnation Methods 0.000 claims abstract description 25
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 238000002156 mixing Methods 0.000 claims abstract description 21
- 238000001035 drying Methods 0.000 claims abstract description 18
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 16
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 16
- 241001330002 Bambuseae Species 0.000 claims abstract description 16
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 16
- 239000011425 bamboo Substances 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 14
- 239000004626 polylactic acid Substances 0.000 claims abstract description 14
- 238000002074 melt spinning Methods 0.000 claims abstract description 9
- 210000002268 wool Anatomy 0.000 claims abstract description 7
- 238000004140 cleaning Methods 0.000 claims abstract description 3
- 239000011435 rock Substances 0.000 claims description 33
- 239000002245 particle Substances 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 13
- 238000007664 blowing Methods 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 8
- 150000001408 amides Chemical class 0.000 claims description 8
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 8
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 8
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- -1 polyoxyethylene Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 6
- 238000004804 winding Methods 0.000 claims description 6
- 239000005696 Diammonium phosphate Substances 0.000 claims description 5
- VCNTUJWBXWAWEJ-UHFFFAOYSA-J aluminum;sodium;dicarbonate Chemical compound [Na+].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O VCNTUJWBXWAWEJ-UHFFFAOYSA-J 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- NMDQPQZRIKCRDU-UHFFFAOYSA-N 3-chloro-2-dodecylpyridine Chemical compound CCCCCCCCCCCCC1=NC=CC=C1Cl NMDQPQZRIKCRDU-UHFFFAOYSA-N 0.000 claims description 4
- 239000012670 alkaline solution Substances 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- PCRDIRUKXOTDNN-UHFFFAOYSA-K aluminum;sodium;carbonate;hydroxide Chemical compound [OH-].[Na+].[Al+3].[O-]C([O-])=O PCRDIRUKXOTDNN-UHFFFAOYSA-K 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 2
- 230000035699 permeability Effects 0.000 abstract description 16
- 238000010521 absorption reaction Methods 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 9
- 239000002699 waste material Substances 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 6
- 238000004040 coloring Methods 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 230000009467 reduction Effects 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 239000004744 fabric Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 230000008859 change Effects 0.000 description 6
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 206010004542 Bezoar Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- FJQXCDYVZAHXNS-UHFFFAOYSA-N methadone hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(CC(C)N(C)C)(C(=O)CC)C1=CC=CC=C1 FJQXCDYVZAHXNS-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/10—Bamboo
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Abstract
The invention discloses an environment-friendly composite textile material and a preparation method thereof, and relates to the technical field of textile materials. The invention discloses an environment-friendly composite textile material which is prepared from the following raw materials in parts by weight: 60-80 parts of regenerated PET modified fiber, 10-20 parts of bamboo fiber, 10-20 parts of polylactic acid fiber and a proper amount of fiber impregnation liquid; the preparation method comprises the steps of placing the regenerated PET modified fiber and the bamboo fiber into a wool blending machine, mixing, placing into fiber impregnation liquid, taking out after impregnating for a period of time, drying in the air, cleaning, drying, adding into a high-speed mixer together with the polylactic acid fiber, mixing, and carrying out melt spinning to obtain the PET modified fiber and bamboo fiber. The environment-friendly composite textile material has high strength, excellent toughness, hydrophilicity, air permeability and coloring effect, and good moisture absorption, quick drying and elasticity; the textile material is made of the regenerated PET fibers and the environment-friendly material, has wide sources and lower cost, has good spinning effect, reasonably utilizes the recycled waste resources, reduces the environmental pollution, and achieves the purposes of environmental protection and resource consumption reduction.
Description
Technical Field
The invention belongs to the technical field of textile materials, and particularly relates to an environment-friendly composite textile material and a preparation method thereof.
Background
With the rapid development of textile industry in China, the problem of textile materials becomes a bottleneck for hindering the development of the textile industry. With the idea of circular economy, energy conservation and environmental protection, natural fibers are gradually deepened into the daily life of people, but the growth speed of the natural fibers is far from the development speed of the textile industry, the textile materials in the market are mainly chemical fibers at present, but the production of the chemical fibers shows that the periodic and structural capacity is excessive, and a large amount of production can bring huge environmental pollution and is not in accordance with the national situation of sustainable development of China. In recent years, the polyester industry in China is developed rapidly, the capacity accounts for more than 40% of the world proportion, but the efficient utilization and recovery of polyester are far from foreign countries, particularly the PET recovery and utilization rate in China is low, and the environmental protection concept is not compounded, so that the recovery and the recycle of PET fibers are changed into valuable, the environmental protection concept is met, and the important effect on solving the problem of shortage of social resources in China is achieved.
The raw material sources of the regenerated PET fiber mainly comprise waste drinking water and beverage packaging bottles, membranes, clothes and non-woven fabrics, waste silk and waste blocks generated in the production process of polyester and fiber, and the polyester bottle sheets are used as the main sources. The regenerated PET fiber has a special high molecular structure, and has the advantages of low production cost, light weight, high strength, high modulus, no toxicity, strong impact strength, acid resistance, oxidation resistance and the like, so that the application field of the regenerated PET fiber is greatly widened. The recycled polyester industry in China begins to develop 40 years ago, but the industry is developed mature gradually in recent years, the level of development and utilization of recycled polyester by domestic enterprises is insufficient, the scientific research input liquid of a bottle-grade polyester re-spinning technology is insufficient, the quality of the bottle-grade polyester re-spinning technology cannot meet the requirements of textile fibers, and most of the bottle-grade polyester re-spinning technology is used as a common filling material. The intrinsic viscosity of the existing PET product is generally not more than 0.7dL/g, the PET product is reduced under the action of thermal stress in the preparation process, and in the recycling process, the PET product is contacted with water, acid, alkali, alcohol and the like to generate slow thermal degradation and hydrolysis, so that the molecular weight and the intrinsic viscosity of the polyester are further reduced. Therefore, the regenerated PET fiber must be pretreated before spinning to meet the requirements of intrinsic viscosity, molecular weight, crystallinity, etc. The existing regenerated PET fiber has the defects of low moisture regain, poor moisture absorption and quick drying property, high fiber strength, small elongation at break, large rigidity and small elasticity, and the regenerated PET fiber has the similar polyester, namely the defects of low moisture content, poor air permeability, poor dyeing property, easy pilling and fluffing, easy contamination and the like. Therefore, it is required to modify the regenerated PET fiber and develop an environment-friendly composite textile material which has good spinnability and excellent comprehensive performance and can utilize the regenerated PET fiber.
Disclosure of Invention
The invention aims to provide an environment-friendly composite textile material which has high strength, excellent toughness, hydrophilicity, air permeability and coloring effect, and good moisture absorption, quick drying and elasticity; the textile material is made of the regenerated PET fibers and the environment-friendly material, has wide sources and lower cost, has good spinning effect, reasonably utilizes the recycled waste resources, reduces the environmental pollution, and achieves the purposes of environmental protection and resource consumption reduction.
In order to realize the purpose of the invention, the invention provides an environment-friendly composite textile material which is prepared from the following raw materials in parts by weight: 60-80 parts of regenerated PET modified fiber, 10-20 parts of bamboo fiber, 10-20 parts of polylactic acid fiber and fiber impregnation liquid, wherein the solid-to-liquid ratio is 1: (10-50).
The preparation method of the composite textile material specifically comprises the following steps:
(1) and (3) placing the regenerated PET modified fiber and the bamboo fiber in a wool blending machine, and mixing for 0.5h at normal temperature to obtain the mixed fiber.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1, adding 0.5g/L dodecyl pyridine chloride solution into 0.4mol/L NaOH solution, and stirring at the rotation speed of 120-; soaking the regenerated PET fiber in the alkaline solution for 30min at 70-80 ℃, taking out and drying to obtain surface-modified regenerated PET fiber;
p2, selecting a proper amount of volcanic rock, crushing and sieving the volcanic rock by a 100-mesh sieve to obtain volcanic rock particles, putting the volcanic rock particles into a dilute nitric acid solution of 2mol/L, stirring for 10-20min, filtering, cleaning the volcanic rock particles by deionized water, and drying the volcanic rock particles for 2 hours at 100 ℃ to obtain pretreated volcanic rock particles;
and P3, stirring the pretreated volcanic particles, the nano calcium carbonate and the polyoxyethylene amide in a mixer for 30min, adding the surface-modified regenerated PET fibers and the vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double-screw extruder, and performing melt distribution pipe, spinning box, metering pump, composite spinning assembly, cross air blowing, cluster oiling, winding and chemical fiber treatment to obtain the regenerated PET modified fibers.
(2) And (3) placing the mixed fiber into a fiber impregnation solution, impregnating for 10-18h at 40-50 ℃, taking out and airing after impregnation, washing with deionized water for three times, and drying to obtain the treated mixed fiber.
(3) And adding the treated mixed fiber and polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, and carrying out melt spinning to obtain the composite textile material.
Further, the fiber impregnation liquid is composed of the following raw materials in percentage by mass: 0.8-1.6% of sulfosuccinate, 4-8% of EVA emulsion, 1.6-2.5% of diammonium hydrogen phosphate, 0.5-1.2% of sodium aluminum carbonate hydroxide, 5-10% of polyethylene glycol, 20-30% of ethanol and the balance of water.
Further, the fiber impregnation liquid is composed of the following raw materials in percentage by mass: 1.2 percent of sulfosuccinate, 5.6 percent of EVA emulsion, 2.1 percent of diammonium phosphate, 0.6 percent of basic sodium aluminum carbonate, 8.3 percent of polyethylene glycol, 22 percent of ethanol and the balance of water.
Furthermore, in the preparation method of the regenerated PET modified fiber, the mass of the nano calcium carbonate is 10-15% of the mass of the pretreated volcanic rock particles, the mass of the polyoxyethylene amide is 5-8% of the mass of the pretreated volcanic rock particles, the mass of the pretreated volcanic rock particles is 8-12% of the mass of the surface modified regenerated PET fiber, and the mass of the vinyl trimethoxy silane is 0.5-0.8% of the mass of the surface modified regenerated PET fiber.
Further, in the preparation method of the regenerated PET modified fiber, the extrusion temperature of the twin-screw extruder in P3 is 260-280 ℃.
Further, in the step (3), the melt spinning process parameters are as follows: the spinning temperature is 250-275 ℃, the temperature of the lateral blowing cooling air is 25 ℃, the wind speed of the lateral blowing is 1m/s, the spinning speed is 2500-3800m/min, and the drawing ratio is 2.0-5.0.
The invention achieves the following beneficial effects:
1. the composite textile material is prepared from the regenerated PET modified fibers, the bamboo fibers and the polylactic acid fibers, the regenerated PET modified fibers are prepared by modifying the regenerated PET fibers, and the regenerated PET fibers are a resource for recycling waste polyester, so that waste is changed into valuable, the cost is saved, the environment is protected, the resource is saved, and the composite textile material has excellent properties such as good strength, acid and alkali resistance, oxidation resistance and the like; the bamboo fiber is a natural material, is biodegradable, and has good air permeability, water absorption, wear resistance and coloring effect, so that the air permeability, the water absorption and the dyeing property of the composite textile material are improved by the proportion of the bamboo fiber; the polylactic acid fiber is biodegradable synthetic fiber, has good biocompatibility, strength and heat resistance, improves the compatibility among all components in the composite textile material, further improves the strength and the heat resistance of the composite textile material, and increases the environmental degradation performance of the composite textile material.
2. The regenerated PET fiber is modified by alkaline liquid, and under the action of the alkaline liquid and a cationic surfactant (dodecyl pyridine chloride), the internal gaps and the pits of the regenerated PET fiber are increased, so that the specific surface area of the regenerated PET fiber is increased, and the compatibility and the adsorbability between the regenerated PET fiber and other components are improved, thereby improving the moisture absorption and quick drying performance of the composite textile fiber; the concentration of the alkaline solution can also ensure that the strength of the regenerated PET fiber is reduced to the minimum and the regenerated PET fiber still has good strength.
3. The regenerated PET modified fiber is added with the pretreated volcanic rock, so that the heat insulation, fire resistance and corrosion resistance of the composite textile material are improved, the strength of the regenerated PET modified fiber is further improved, the volcanic rock has more pores and light weight, the specific surface area is very high, and the air permeability of the composite textile material is increased; the nano calcium carbonate is added into the regenerated PET modified fiber, the surface of the nano calcium carbonate is oleophilic and hydrophobic, the compatibility among all components is improved, the toughness, the dimensional stability and the heat resistance of the composite textile fiber are improved, the spinning effect is improved, the reinforcing and toughening effects are achieved, the porosity of the regenerated PET modified fiber is reduced, and the regenerated PET modified fiber has excellent air permeability and excellent heat insulation and preservation effects.
4. The mixed fiber is soaked in the fiber soaking solution, so that the components such as flame retardance, hydrophilicity and the like are adhered to the mixed fiber, the compatibility between the mixed fiber and the polylactic acid fiber is improved, the spinning property of the regenerated PET fiber is improved, the mixed fiber has excellent flame retardance, aging resistance, light resistance and hydrophilicity, and the toughness and the strength of the mixed fiber are improved.
5. The raw materials used in the invention are wide in source, environment-friendly and easy to degrade, and the composite textile material has excellent flame retardance, strength, toughness, hygroscopicity and air permeability, is soft and smooth in hand feeling, good in dyeing property and excellent in aging resistance, and can be used in the fields of medical treatment, clothes, daily necessities and the like.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The solid-liquid ratio in the invention refers to the ratio of the total mass of the regenerated PET modified fiber and the bamboo fiber to the mass of the fiber impregnation liquid.
The environment-friendly composite textile material and the preparation method thereof according to the present invention will be described with reference to the following embodiments.
Example 1 an Environment-friendly composite textile Material
The preparation method of the environment-friendly composite textile material comprises the following steps: placing 600g of regenerated PET modified fiber and 200g of bamboo fiber in a wool mixing machine, and mixing for 30min to obtain mixed fiber; placing the mixed fiber into 40kg of fiber impregnation liquid, impregnating for 10h at 50 ℃, taking out and airing after impregnation, washing with deionized water for three times, and drying to obtain the treated mixed fiber; and adding the treated mixed fiber and 200g of polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, carrying out melt spinning at the spinning temperature of 250 ℃, the side-blown cooling air temperature of 25 ℃, the side-blown air speed of 1m/s, the spinning speed of 2800m/min and the drafting ratio of 4, and thus obtaining the composite textile material.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1. adding 0.5 g/L1L dodecyl pyridine chloride solution into 0.4 mol/L1L NaOH solution, and stirring at the rotation speed of 120-. Soaking regenerated PET fiber (sold in market) in the alkaline solution for 30min at 70-80 ℃, taking out and drying to obtain the surface modified regenerated PET fiber.
And P2, selecting a proper amount of volcanic, crushing and sieving by a 100-mesh sieve to obtain volcanic particles, putting the volcanic particles into a 2mol/L dilute nitric acid solution, stirring for 10-20min, filtering, washing with deionized water, and drying at 100 ℃ for 2h to obtain the pretreated volcanic particles.
And P3, firstly stirring 120g of pretreated volcanic rock particles, 18g of nano calcium carbonate and 9.6g of polyoxyethylene amide in a mixer for 30min, then adding 1kg of surface-modified regenerated PET fibers and 5g of vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double-screw extruder, extruding at the temperature of 260-280 ℃, and performing melt distribution pipe, spinning manifold, metering pump, composite spinning assembly, side blowing, cluster oiling, winding and chemical fiber treatment to obtain the regenerated PET modified fibers.
The fiber impregnation liquid is prepared from the following raw materials in percentage by mass: 1.6 percent of sulfosuccinate, 4 percent of EVA emulsion, 2.5 percent of diammonium phosphate, 0.8 percent of basic sodium aluminum carbonate, 10 percent of polyethylene glycol, 20 percent of ethanol and the balance of water.
Example 2 an Environment-friendly composite textile Material
The preparation method of the environment-friendly composite textile material comprises the following steps: placing 800g of regenerated PET modified fiber and 100g of bamboo fiber in a wool mixing machine, and mixing for 30min to obtain mixed fiber; putting the mixed fiber into 9kg of fiber impregnation liquid, impregnating for 18h at 40 ℃, taking out and airing after impregnation, washing with deionized water for three times, and drying to obtain the treated mixed fiber; and adding the treated mixed fiber and 100g of polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, carrying out melt spinning at 275 ℃, 25 ℃ as well as 1m/s as well as 2500m/min as well as 5 as drafting ratio, and thus obtaining the composite textile material.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1. preparation of surface-modified recycled PET fiber, the preparation method is the same as in example 1, with specific reference to example 1.
P2. preparation of pretreated volcanic rock particles, the preparation method is the same as in example 1, with specific reference to example 1.
And P3, firstly stirring 80g of pretreated volcanic rock particles, 8g of nano calcium carbonate and 4g of polyoxyethylene amide in a mixer for 30min, then adding 1kg of surface-modified regenerated PET fibers and 8g of vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double-screw extruder, extruding at the temperature of 260-280 ℃, and performing melt distribution pipe, spinning box, metering pump, composite spinning assembly, side blowing, cluster oiling, winding and chemical fiber treatment to obtain the regenerated PET modified fibers.
The fiber impregnation liquid is prepared from the following raw materials in percentage by mass: 0.8% of sulfosuccinate, 8% of EVA emulsion, 1.6% of diammonium hydrogen phosphate, 1.2% of sodium aluminum carbonate hydroxide, 5% of polyethylene glycol, 30% of ethanol and the balance of water.
Example 3 an Environment-friendly composite textile Material
The preparation method of the environment-friendly composite textile material comprises the following steps: placing 700g of regenerated PET modified fiber and 100g of bamboo fiber in a wool mixing machine, and mixing for 30min to obtain mixed fiber; placing the mixed fiber into 24kg of fiber impregnation liquid, impregnating for 15h at 50 ℃, taking out and airing after impregnation, washing with deionized water for three times, and drying to obtain the treated mixed fiber; and adding the treated mixed fiber and 200g of polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, carrying out melt spinning at the spinning temperature of 260 ℃, the side-blown cooling air temperature of 25 ℃, the side-blown air speed of 1m/s, the spinning speed of 3800m/min and the drafting magnification of 2, and thus obtaining the composite textile material.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1. preparation of surface-modified recycled PET fiber, the preparation method is the same as in example 1, with specific reference to example 1.
P2. preparation of pretreated volcanic rock particles, the preparation method is the same as in example 1, with specific reference to example 1.
And P3, firstly stirring 100g of pretreated volcanic rock particles, 12g of nano calcium carbonate and 6g of polyoxyethylene amide in a mixer for 30min, then adding 1kg of surface-modified regenerated PET fibers and 6.4g of vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double-screw extruder, extruding at the temperature of 260-280 ℃, and performing melt distribution pipe, spinning manifold, metering pump, composite spinning assembly, side blowing, cluster oiling, winding and chemical fiber treatment to obtain the regenerated PET modified fibers.
The fiber impregnation liquid is prepared from the following raw materials in percentage by mass: 1.0 percent of sulfosuccinate, 6.3 percent of EVA emulsion, 2.2 percent of diammonium phosphate, 0.5 percent of basic sodium aluminum carbonate, 8.6 percent of polyethylene glycol, 23 percent of ethanol and the balance of water.
Example 4 an Environment-friendly composite textile Material
The preparation method of the environment-friendly composite textile material comprises the following steps: placing 700g of regenerated PET modified fiber and 150g of bamboo fiber in a wool mixing machine, and mixing for 30min to obtain mixed fiber; placing the mixed fiber into 30kg of fiber impregnation liquid, impregnating for 15h at 50 ℃, taking out and airing after impregnation, washing with deionized water for three times, and drying to obtain the treated mixed fiber; and adding the treated mixed fiber and 150g of polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, carrying out melt spinning at the spinning temperature of 265 ℃, the side-blown cooling air temperature of 25 ℃, the side-blown air speed of 1m/s, the spinning speed of 3200m/min and the drafting magnification of 3.6, and thus obtaining the composite textile material.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1. preparation of surface-modified recycled PET fiber, the preparation method is the same as in example 1, with specific reference to example 1.
P2. preparation of pretreated volcanic rock particles, the preparation method is the same as in example 1, with specific reference to example 1.
And P3, firstly stirring 110g of pretreated volcanic rock particles, 14.3g of nano calcium carbonate and 7.7g of polyoxyethylene amide in a mixer for 30min, then adding 1kg of surface-modified regenerated PET fibers and 5.8g of vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double-screw extruder, extruding at the temperature of 260-280 ℃, and performing melt distribution pipe, spinning box, metering pump, composite spinning assembly, side blowing, cluster oiling, winding and chemical fiber treatment to obtain the regenerated PET modified fibers.
The fiber impregnation liquid is prepared from the following raw materials in percentage by mass: 1.2 percent of sulfosuccinate, 5.6 percent of EVA emulsion, 2.1 percent of diammonium phosphate, 0.6 percent of basic sodium aluminum carbonate, 8.3 percent of polyethylene glycol, 22 percent of ethanol and the balance of water.
Example 5 an Environment-friendly composite textile Material
An environment-friendly composite textile material was prepared in the same manner as in example 4, except that the amount of the regenerated PET modified fiber was 700g, the amount of the bamboo fiber was 200g, and the amount of the polylactic acid fiber was 100 g.
Comparative example 1 an environmentally friendly composite textile material
The raw material components and the preparation method of an environment-friendly composite textile material were the same as in example 4, except that not the regenerated PET modified fiber but the unmodified commercially available regenerated PET fiber was used.
Comparative example 2 an environmentally friendly composite textile material
The raw material components and the preparation method of the environment-friendly composite textile material are the same as those in the embodiment 4, except that the regenerated PET modified fiber is not added with the pretreated volcanic rock particles, and other components and operation steps are not changed.
Comparative example 3 an environmentally friendly composite textile material
The raw material components and the preparation method of the environment-friendly composite textile material are the same as those in the embodiment 4, except that the nano calcium carbonate is not added into the regenerated PET modified fiber, and other components and operation steps are not changed.
The environmentally friendly composite textile materials prepared according to the above examples 1 to 5 and comparative examples 1 to 3 were subjected to mechanical property tests, and the test results are shown in the following table 1.
TABLE 1 mechanical property test results of environment-friendly composite textile materials
As can be seen from the mechanical property detection results in Table 1, the environment-friendly composite textile material provided by the invention has good breaking strength and breaking elongation and high initial modulus, i.e., the fabric made of the textile material is soft in hand feeling and not easy to deform. According to the invention, the breaking strength and elongation of the composite textile material are improved by modifying the regenerated PET fibers, so that the composite textile material has good hand feeling and elasticity and good strength. The strength of the composite textile material is improved by adding the pretreated volcanic rock particles or the nanometer calcium carbonate.
The environment-friendly composite textile materials prepared in the examples 1 to 5 and the comparative examples 1 to 3 are woven into fiber fabrics on a circular weft knitting machine for knitting, the weave structure of the fiber fabrics is weft-plain weave, namely the fiber fabrics are prepared by adopting the same weaving process, the weave structure and the after-finishing technology, and the density of the fiber fabrics is as follows: the transverse density/5 cm is 55, and the longitudinal density/5 cm is 65. The fiber fabrics manufactured in examples 1 to 5 and comparative examples 1 to 3 were subjected to water absorption, air permeability, and pilling resistance tests, and the test results are shown in table 2.
Water absorption: and (3) soaking the sample in deionized water for 5min, taking out and suspending until the time interval between two drops of water is not less than 30s, and calculating the water absorption rate.
In the formula, A represents water absorption,%; m is the mass of the sample after dripping no more, g; m0Is the initial mass of the sample, g.
And (3) testing air permeability: the test was carried out as specified in GB/T5435-1997 test for air Permeability of textiles.
Anti-pilling test: the test is carried out by adopting a Martindale pilling instrument model YG401G, a round sample is placed in standard atmosphere for humidifying for 24h and then clamped in a clamp holder, the friction times are set to be 50 times, the friction pressure is set to be 160g, and the average value of 5 friction tests is taken.
Table 2 performance test results of the fiber fabrics
Air permeability (mm/s) | Water absorption (%) | Pilling resistance | |
Example 1 | 3690 | 279.5 | Without change |
Example 2 | 3740 | 268.4 | Without change |
Example 3 | 3570 | 289.6 | Without change |
Example 4 | 3910 | 310.5 | Without change |
Example 5 | 3860 | 297.6 | Without change |
Comparative example 1 | 2250 | 220.3 | Ball with hair |
Comparative example 2 | 3220 | 256.4 | Individual hair ball |
Comparative example 3 | 3030 | 325.1 | Without change |
As can be seen from the performance test results in Table 2, the environment-friendly composite textile material of the invention has excellent air permeability, water absorption and pilling resistance. According to the invention, the regenerated PET fibers are modified, so that the air permeability, the water absorption and the pilling resistance of the fabric are greatly improved; according to the invention, the air permeability and the water absorption rate of the fabric are improved by adding the pretreated volcanic rock particles; the invention improves the air permeability of the fabric by adding the nano calcium carbonate.
The technical features of the embodiments described above can be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention.
Claims (6)
1. The environment-friendly composite textile material is characterized by being prepared from the following raw materials in parts by weight: 60-80 parts of regenerated PET modified fiber, 10-20 parts of bamboo fiber, 10-20 parts of polylactic acid fiber and fiber impregnation liquid, wherein the solid-to-liquid ratio is 1: (10-50);
the preparation method of the composite textile material specifically comprises the following steps:
(1) placing the regenerated PET modified fiber and the bamboo fiber in a wool blending machine, and mixing for 0.5h at normal temperature to obtain mixed fiber;
the specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1, adding 0.5g/L dodecyl pyridine chloride solution into 0.4mol/L NaOH solution, and stirring at the rotation speed of 120-; soaking the regenerated PET fiber in the alkaline solution for 30min at 70-80 ℃, taking out and drying to obtain surface-modified regenerated PET fiber;
p2, selecting a proper amount of volcanic rock, crushing and sieving the volcanic rock by a 100-mesh sieve to obtain volcanic rock particles, putting the volcanic rock particles into a dilute nitric acid solution of 2mol/L, stirring for 10-20min, filtering, cleaning the volcanic rock particles by deionized water, and drying the volcanic rock particles for 2 hours at 100 ℃ to obtain pretreated volcanic rock particles;
p3, stirring pretreated volcanic rock particles, nano calcium carbonate and polyoxyethylene amide in a mixer for 30min, adding the surface-modified regenerated PET fibers and vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double-screw extruder, and performing melt distribution pipe, spinning box, metering pump, composite spinning assembly, cross air blowing, cluster oiling, winding and chemical fiber treatment to obtain regenerated PET modified fibers;
(2) placing the mixed fiber into a fiber impregnation solution, impregnating for 10-18h at 40-50 ℃, taking out and airing after impregnation, washing with deionized water for three times, and drying to obtain the treated mixed fiber;
(3) and adding the treated mixed fiber and polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, and carrying out melt spinning to obtain the composite textile material.
2. The environment-friendly composite textile material of claim 1, wherein the fiber impregnation liquid is composed of the following raw materials by mass percent: 0.8-1.6% of sulfosuccinate, 4-8% of EVA emulsion, 1.6-2.5% of diammonium hydrogen phosphate, 0.5-1.2% of sodium aluminum carbonate hydroxide, 5-10% of polyethylene glycol, 20-30% of ethanol and the balance of water.
3. The environment-friendly composite textile material as claimed in claim 2, wherein the fiber impregnation liquid is composed of the following raw materials by mass percent: 1.2 percent of sulfosuccinate, 5.6 percent of EVA emulsion, 2.1 percent of diammonium phosphate, 0.6 percent of basic sodium aluminum carbonate, 8.3 percent of polyethylene glycol, 22 percent of ethanol and the balance of water.
4. The environment-friendly composite textile material as claimed in claim 1, wherein in the preparation method of the regenerated PET modified fiber, the mass of the nano calcium carbonate is 10-15% of the mass of the pretreated volcanic rock particles, the mass of the polyoxyethylene amide is 5-8% of the mass of the pretreated volcanic rock particles, the mass of the pretreated volcanic rock particles is 8-12% of the mass of the surface-modified regenerated PET fiber, and the mass of the vinyltrimethoxysilane is 0.5-0.8% of the mass of the surface-modified regenerated PET fiber.
5. The environment-friendly composite textile material as set forth in claim 1, wherein in the preparation method of the regenerated PET modified fiber, the extrusion temperature of the twin-screw extruder in P3 is 260-280 ℃.
6. The environment-friendly composite textile material as claimed in claim 1, wherein in the step (3), the melt spinning process parameters are as follows: the spinning temperature is 250-275 ℃, the temperature of the lateral blowing cooling air is 25 ℃, the wind speed of the lateral blowing is 1m/s, the spinning speed is 2500-3800m/min, and the drawing ratio is 2.0-5.0.
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