CN112957302B - Amino acid facial cleanser and preparation method thereof - Google Patents

Amino acid facial cleanser and preparation method thereof Download PDF

Info

Publication number
CN112957302B
CN112957302B CN202110179948.8A CN202110179948A CN112957302B CN 112957302 B CN112957302 B CN 112957302B CN 202110179948 A CN202110179948 A CN 202110179948A CN 112957302 B CN112957302 B CN 112957302B
Authority
CN
China
Prior art keywords
parts
amino acid
stirring
facial cleanser
extract
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202110179948.8A
Other languages
Chinese (zh)
Other versions
CN112957302A (en
Inventor
王汪送
廖忠华
沈育松
谢阿贵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian Pientzehuang Cosmetics Co ltd
Original Assignee
Fujian Pientzehuang Cosmetics Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujian Pientzehuang Cosmetics Co ltd filed Critical Fujian Pientzehuang Cosmetics Co ltd
Priority to CN202110179948.8A priority Critical patent/CN112957302B/en
Publication of CN112957302A publication Critical patent/CN112957302A/en
Application granted granted Critical
Publication of CN112957302B publication Critical patent/CN112957302B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9794Liliopsida [monocotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/602Glycosides, e.g. rutin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63Steroids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9728Fungi, e.g. yeasts
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/008Preparations for oily skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48Thickener, Thickening system
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/596Mixtures of surface active compounds

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

The invention belongs to the technical field of cosmetics, and particularly relates to amino acid facial cleanser and a preparation method thereof. The amino acid facial cleanser provided by the invention mainly comprises the following components in parts by weight: 7-20 parts of amino acid surfactant, 3-13 parts of auxiliary surfactant, 2-5 parts of thickening agent, 4-16 parts of humectant, 0.5-2 parts of pearling agent and 38.5-80.5 parts of water. The amino acid facial cleanser provided by the invention is close to the pH value of human skin, is safe and mild, and is skin-friendly and low in stimulation; the foam is rich and fine, and is high-efficiency and clean; moisten and nourish skin, and is fresh and tight.

Description

Amino acid facial cleanser and preparation method thereof
Technical Field
The invention belongs to the technical field of cosmetics, and particularly relates to amino acid facial cleanser and a preparation method thereof.
Background
The face cleansing cream on the market can be roughly divided into three types, namely a common surfactant type, a fatty acid salt type and an amino acid surfactant type according to the types of the surfactants.
The amino acid facial cleanser is a facial cleanser product which takes amino acid type surface activity as a main cleaning active ingredient, and the weakly acidic amino acid type surfactant is prepared from natural ingredients and is green and natural; the pH value is close to the human skin, and the pH value of the skin cannot be influenced; amino acid is a basic unit for forming protein, so that the product is mild and skin-friendly, has low irritation and proper cleaning capability, and is touted by consumers.
However, the amino acid facial cleanser is difficult to thicken, and the coating property and the foaming property of the facial cleanser are often influenced by adding the high molecular polymer for thickening, so that the amino acid facial cleanser is difficult to coat and melt in the using process, and the foaming time is long. The self-crystallizing thickening type amino acid facial cleanser has the problems of high stability such as alcohol precipitation, water yielding, layering and the like although the foaming is rapid and the foam is rich.
The two types of amino acid facial cleansers have respective defects, and the industrial application development of the amino acid facial cleansers is limited. This phenomenon is urgently to be solved.
Disclosure of Invention
The invention aims to provide an amino acid facial cleanser and a preparation method thereof. The amino acid facial cleanser provided by the invention has good stability; the pH value of the skin of a human body is within a proper range, so that the skin care liquid is safe and mild, is skin-friendly and has low stimulation; the foam is rich and fine, the cleaning is efficient, and the detergent is fresh and not tight after being washed.
The technical scheme of the invention is as follows:
an amino acid facial cleanser mainly comprises the following components in parts by weight: 7-20 parts of amino acid surfactant, 3-13 parts of auxiliary surfactant, 2-5 parts of thickening agent, 4-16 parts of humectant, 0.5-2 parts of pearling agent and 38.5-80.5 parts of water; the pH value of the amino acid facial cleanser is 5.5-7.5; the amino acid surfactant is potassium cocoyl glycinate, the auxiliary surfactant is cocamidopropyl hydroxysulfobetaine and decyl glucoside, the thickening agent is composed of acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 5:1, the humectant is glycerin, the pearling agent is ethylene glycol distearate, and the skin conditioner is yeast/rice fermentation product filtrate, dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria cocos extract, radix scrophulariae extract and radix ophiopogonis extract.
Further, the amino acid facial cleanser mainly comprises the following components in parts by weight: 13.5 parts of amino acid surfactant, 8 parts of auxiliary surfactant, 3.5 parts of thickening agent, 10 parts of humectant, 1.5 parts of pearling agent and 59.5 parts of water.
Further, the amino acid surfactant is potassium cocoyl glycinate; the cosurfactants are cocamidopropyl hydroxysultaine and decyl glucoside.
Further, the humectant is glycerin.
Further, the pearlizing agent is ethylene glycol distearate.
Further, the skin conditioner is yeast/rice fermentation product filtrate and plant extract.
Further, the plant extract comprises dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria cocos extract, radix scrophulariae extract and radix ophiopogonis extract.
Further, the thickening agent consists of acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 3: 1.
The preparation method of the amino acid facial cleanser comprises the following steps:
s1, adding the amino acid surfactant, the auxiliary surfactant and the humectant into an emulsifying cylinder, heating and stirring uniformly until the mixture is dissolved, and keeping the temperature and stirring for 10-30min when the temperature of the emulsifying cylinder reaches 70-90 ℃, so as to remove the foam in the solution;
s2, adding a pearling agent (ethylene glycol distearate) and an acrylic acid (ester) copolymer in a thickening agent into the mixed solution obtained in the step S1, keeping the temperature at 80-90 ℃, stirring for 15-25min, then opening a cooling system, and cooling to 60-75 ℃ while stirring;
s3, adding PEG-120 methyl glucose trioleate in a thickening agent into the mixture obtained in the step S2, keeping the temperature of 60-75 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 45-50 ℃ while stirring;
s4 adding the skin conditioner, essence and antiseptic into the mixture obtained in step S3, keeping the temperature at 45-50 deg.C, stirring for 10-15min, continuing to open the cooling system, cooling to 35-42 deg.C while stirring, and stopping cooling to obtain a smooth and uniform body.
Further, the stirring speed in the step S1, the step S2, the step S3 and the step S4 is 10-35 r/min.
In the invention, the added amino acid surfactant potassium cocoyl glycinate and the auxiliary surfactant cocoamidopropyl hydroxysultaine and decyl glucoside have high safety, good foaming capacity, fine and elastic foam, and capability of mildly cleaning dirt and redundant grease on the face, and the skin is fresh and not tight after washing.
According to the amino acid facial cleanser provided by the invention, the humectant is glycerin, so that the amino acid facial cleanser has high hygroscopicity and good moisturizing effect.
The amino acid cleansing milk provided by the invention comprises yeast/rice fermentation product filtrate, plant extracts dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria cocos extract, radix scrophulariae extract and radix ophiopogonis extract.
The amino acid facial cleanser provided by the invention has the advantages that the thickening agent is composed of acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to a certain proportion, the thickening agent is matched according to a proper proportion, the prepared facial cleanser is moderate in consistency, good in stability, easy to coat and use, good in foaming performance, fine and dense in foam, elastic, and fresh, smooth and tight in skin after washing.
Compared with the prior art, the amino acid facial cleanser provided by the invention has the following advantages:
(1) the amino acid facial cleanser provided by the invention has the advantages that the potassium cocoyl glycinate which is high in safety, mild and non-irritant is selected as the main surfactant, the cocoamidopropyl hydroxysulfobetaine and decyl glucoside are used as auxiliary agents, the pH value range of the human skin is suitable, dirt and redundant grease on the face are mildly cleaned, and the skin is fresh and tight after washing.
(2) The thickener component in the amino acid facial cleanser influences the difficulty of technological deaeration, the spreadability of the formula and the stability. According to the invention, the acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate are added in a proper proportion to form a thickening framework, so that the stability of the formula is ensured, the influence on the foam performance is minimized, and the fine and elastic foam is provided for the formula.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention clearer, the technical solutions of the present invention will be described in detail below, but the present invention is not limited thereto, and all other embodiments obtained by a person skilled in the art according to the basic idea of the present invention belong to the protection scope of the present invention.
The raw materials adopted in the invention are all commercially available cosmetic raw material products.
Example 1
The amino acid facial cleanser comprises the following components in parts by weight: 7 parts of amino acid surfactant potassium cocoyl glycinate, 3 parts of auxiliary surfactant cocoamidopropyl hydroxysulfobetaine and decyl glucoside, 2 parts of thickener acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate, 4 parts of humectant glycerol, 0.5 part of pearling agent ethylene glycol distearate, 1.5 parts of skin conditioner yeast/rice fermentation product filtrate, dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria cocos extract, radix scrophulariae extract, radix ophiopogonis extract and 80.5 parts of water; the pH value of the amino acid facial cleanser is 6.7.
The thickening agent consists of acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 5: 1.
The skin conditioner consists of 0.05-0.5% of saccharomycete/rice fermentation product filtrate, 0.05-0.2% of dipotassium glycyrrhizinate, 0.0008-0.1% of pseudo-ginseng, 0.05-0.15% of dendrobium officinale stem extract, 0.05-0.15% of polygonatum odoratum extract, 0.05-0.15% of poria cocos extract, 0.05-0.15% of radix scrophulariae extract and 0.05-0.15% of radix ophiopogonis extract.
The preparation method of the amino acid facial cleanser comprises the following steps:
s1, adding the amino acid surfactant, the auxiliary surfactant and the humectant into an emulsifying cylinder, heating and stirring uniformly until the mixture is dissolved, and when the temperature of the emulsifying cylinder reaches 70-90 ℃, keeping the temperature and stirring for 10-30min to remove the foam in the solution;
s2, adding a pearling agent (ethylene glycol distearate) and an acrylic acid (ester) copolymer in a thickening agent into the mixed solution obtained in the step S1, keeping the temperature at 80-90 ℃, stirring for 15-25min, then opening a cooling system, and cooling to 60-75 ℃ while stirring;
s3, adding PEG-120 methyl glucose trioleate in a thickening agent into the mixture obtained in the step S2, keeping the temperature of 60-75 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 45-50 ℃ while stirring;
s4, adding the skin conditioner, the essence and the preservative into the mixture obtained in the step S3, keeping the temperature at 45-50 ℃, stirring for 10-15min, continuing to open the cooling system, and cooling to 35-42 ℃ while stirring, and stopping cooling to form a smooth and uniform material body.
The stirring speed in the step S1, the step S2, the step S3 and the step S4 is 10 r/min.
Example 2
The amino acid facial cleanser comprises the following components in parts by weight: 13.5 parts of amino acid surfactant potassium cocoyl glycinate, 8 parts of auxiliary surfactant cocoamidopropyl hydroxy sulfobetaine and decyl glucoside, 3.5 parts of thickener acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate, 10 parts of humectant glycerin, 1.5 parts of pearling agent ethylene glycol distearate, 1.5 parts of skin conditioner yeast/rice fermentation product filtrate, dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria cocos extract, radix scrophulariae extract and radix ophiopogonis extract and 59.5 parts of water; the pH value of the amino acid facial cleanser is 6.1.
The thickening agent consists of acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 5: 1.
The skin conditioner consists of 0.05-0.5% of saccharomycetes/rice fermentation product filtrate, 0.05-0.2% of dipotassium glycyrrhizinate, 0.0008-0.1% of pseudo-ginseng, 0.05-0.15% of dendrobium officinale stem extract, 0.05-0.15% of polygonatum odoratum extract, 0.05-0.15% of poria cocos extract, 0.05-0.15% of radix scrophulariae extract and 0.05-0.15% of radix ophiopogonis extract.
The preparation method of the amino acid facial cleanser comprises the following steps:
s1, adding the amino acid surfactant, the auxiliary surfactant and the humectant into an emulsifying cylinder, heating and stirring uniformly until the mixture is dissolved, and when the temperature of the emulsifying cylinder reaches 70-90 ℃, keeping the temperature and stirring for 10-30min to remove the foam in the solution;
s2, adding a pearling agent (ethylene glycol distearate) and an acrylic acid (ester) copolymer in a thickening agent into the mixed solution obtained in the step S1, keeping the temperature at 80-90 ℃, stirring for 15-25min, then opening a cooling system, and cooling to 60-75 ℃ while stirring;
s3, adding PEG-120 methyl glucose trioleate in a thickening agent into the mixture obtained in the step S2, keeping the temperature of 60-75 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 45-50 ℃ while stirring;
s4, adding the skin conditioner, the essence and the preservative into the mixture obtained in the step S3, keeping the temperature at 45-50 ℃, stirring for 10-15min, continuing to open the cooling system, and cooling to 35-42 ℃ while stirring, and stopping cooling to form a smooth and uniform material body.
The stirring speed in the step S1, the step S2, the step S3 and the step S4 was 23 r/min.
Example 3
The amino acid facial cleanser comprises the following components in parts by weight: 20 parts of amino acid surfactant potassium cocoyl glycinate, 13 parts of auxiliary surfactant cocoamidopropyl hydroxysultaine and decyl glucoside, 5 parts of thickener acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate, 16 parts of humectant glycerol, 2 parts of pearling agent ethylene glycol distearate, 1.5 parts of skin conditioner yeast/rice fermentation product filtrate, dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria cocos extract, radix scrophulariae extract and radix ophiopogonis extract and 38.5 parts of water; the pH value of the amino acid facial cleanser is 6.5.
The thickening agent consists of acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 5: 1.
The skin conditioner consists of 0.05-0.5% of saccharomycete/rice fermentation product filtrate, 0.05-0.2% of dipotassium glycyrrhizinate, 0.0008-0.1% of pseudo-ginseng, 0.05-0.15% of dendrobium officinale stem extract, 0.05-0.15% of polygonatum odoratum extract, 0.05-0.15% of poria cocos extract, 0.05-0.15% of radix scrophulariae extract and 0.05-0.15% of radix ophiopogonis extract.
The preparation method of the amino acid facial cleanser comprises the following steps:
s1, adding the amino acid surfactant, the auxiliary surfactant and the humectant into an emulsifying cylinder, heating and stirring uniformly until the mixture is dissolved, and when the temperature of the emulsifying cylinder reaches 70-90 ℃, keeping the temperature and stirring for 10-30min to remove the foam in the solution;
s2, adding a pearling agent (ethylene glycol distearate) and an acrylic acid (ester) copolymer in a thickening agent into the mixed solution obtained in the step S1, keeping the temperature at 80-90 ℃, stirring for 15-25min, then opening a cooling system, and cooling to 60-75 ℃ while stirring;
s3, adding PEG-120 methyl glucose trioleate in a thickening agent into the mixture obtained in the step S2, keeping the temperature of 60-75 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 45-50 ℃ while stirring;
s4, adding the skin conditioner, the essence and the preservative into the mixture obtained in the step S3, keeping the temperature at 45-50 ℃, stirring for 10-15min, continuing to open the cooling system, and cooling to 35-42 ℃ while stirring, and stopping cooling to form a smooth and uniform material body.
The stirring speed in the step S1, the step S2, the step S3 and the step S4 was 45 r/min.
Example 4
The amino acid facial cleanser comprises the following components in parts by weight: 13.5 parts of amino acid surfactant potassium cocoyl glycinate, 8 parts of auxiliary surfactant cocoamidopropyl hydroxy sulfobetaine and decyl glucoside, 3.5 parts of thickener acrylate copolymer and PEG-120 methyl glucose trioleate, 10 parts of humectant glycerol, 1.5 parts of pearling agent ethylene glycol distearate and 62.62 parts of water; the pH value of the amino acid facial cleanser is 6.2.
The thickening agent consists of acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 5: 1.
The preparation method of the amino acid facial cleanser comprises the following steps:
s1, adding the amino acid surfactant, the auxiliary surfactant and the humectant into an emulsifying cylinder, heating and stirring uniformly until the mixture is dissolved, and keeping the temperature and stirring for 10-30min when the temperature of the emulsifying cylinder reaches 70-90 ℃, so as to remove the foam in the solution;
s2, adding an acrylic acid (ester) copolymer in a pearling agent (ethylene glycol distearate) thickening agent into the mixed solution obtained in the step S1, keeping the temperature at 80-90 ℃, stirring for 15-25min, then opening a cooling system, and cooling to 60-75 ℃ while stirring;
s3, adding PEG-120 methyl glucose trioleate in a thickening agent into the mixture obtained in the step S2, keeping the temperature of 60-75 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 45-50 ℃ while stirring;
s4, adding essence and preservative into the mixture obtained in the step S3, keeping the temperature at 45-50 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 35-42 ℃ while stirring, and stopping cooling to form a smooth and uniform material body.
The stirring speed in the step S1, the step S2, the step S3 and the step S4 was 28 r/min.
Comparative example 1 an amino acid facial cleanser.
The formulation composition of the amino acid facial cleanser was similar to that of example 2.
The preparation method of the amino acid facial cleanser comprises the following steps:
s1, adding the amino acid surfactant, the auxiliary surfactant and the humectant into an emulsifying cylinder, heating and stirring uniformly until the mixture is dissolved, and keeping the temperature and stirring for 10-30min when the temperature of the emulsifying cylinder reaches 70-90 ℃, so as to remove the foam in the solution;
s2, adding a pearling agent (ethylene glycol distearate) and an acrylic acid (ester) copolymer in a thickening agent into the mixed solution obtained in the step S1, keeping the temperature at 80-90 ℃, stirring for 15-25min, then opening a cooling system, and cooling to 60-75 ℃ while stirring;
s3, adding PEG-120 methyl glucose trioleate in a thickening agent into the mixture obtained in the step S2, keeping the temperature of 60-75 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 45-50 ℃ while stirring;
s4 adding skin conditioner, essence, and antiseptic into the mixture obtained in step S3, stirring at 45-50 deg.C for 10-15min, continuing to open cooling system, and cooling to 35-42 deg.C under stirring to stop cooling.
The stirring speed in the step S1, the step S2, the step S3 and the step S4 was 6 r/min.
The difference from example 2 is that the stirring speed is reduced to 6 r/min.
Comparative example 2 an amino acid facial cleanser.
The formulation composition of the amino acid facial cleanser was similar to that of example 2.
The preparation method of the amino acid facial cleanser comprises the following steps:
s1, adding the amino acid surfactant, the auxiliary surfactant and the humectant into an emulsifying cylinder, heating and stirring uniformly until the mixture is dissolved, and keeping the temperature and stirring for 10-30min when the temperature of the emulsifying cylinder reaches 70-90 ℃, so as to remove the foam in the solution;
s2, adding a pearling agent (ethylene glycol distearate) and an acrylic acid (ester) copolymer in a thickening agent into the mixed solution obtained in the step S1, keeping the temperature at 80-90 ℃, stirring for 15-25min, then opening a cooling system, and cooling to 60-75 ℃ while stirring;
s3, adding PEG-120 methyl glucose trioleate in a thickening agent into the mixture obtained in the step S2, keeping the temperature of 60-75 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 45-50 ℃ while stirring;
s4 adding skin conditioner, essence, and antiseptic into the mixture obtained in step S3, stirring at 45-50 deg.C for 10-15min, continuing to open cooling system, and cooling to 35-42 deg.C under stirring to stop cooling.
The stirring speed in the step S1, the step S2, the step S3 and the step S4 was 45 r/min.
The difference from example 2 is that the stirring speed is increased to 45 r/min.
Comparative example 3 an amino acid facial cleanser.
The formulation composition of the amino acid facial cleanser was similar to that of example 2.
The preparation method of the amino acid facial cleanser comprises the following steps:
s1, adding the amino acid surfactant, the auxiliary surfactant and the humectant into an emulsifying cylinder, heating and stirring uniformly until the mixture is dissolved, and keeping the temperature and stirring for 10-30min when the temperature of the emulsifying cylinder reaches 70-90 ℃, so as to remove the foam in the solution;
s2, adding a pearling agent (ethylene glycol distearate) and an acrylic acid (ester) copolymer in a thickening agent into the mixed solution obtained in the step S1, keeping the temperature at 70 ℃, stirring for 15-25min, then opening a cooling system, and cooling to 60-75 ℃ while stirring;
s3, adding PEG-120 methyl glucose trioleate in a thickening agent into the mixture obtained in the step S2, keeping the temperature of 60-75 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 45-50 ℃ while stirring;
s4 adding skin conditioner, essence, and antiseptic into the mixture obtained in step S3, stirring at 45-50 deg.C for 10-15min, continuing to open cooling system, and cooling to 35-42 deg.C under stirring to stop cooling.
The stirring speed in the step S1, the step S2, the step S3 and the step S4 was 23 r/min.
The difference from example 2 is that the holding temperature of the pearling agent (ethylene glycol distearate) and the acrylic acid (ester) copolymer in the thickener in the step S2 is reduced to 70 ℃.
Comparative example 4 an amino acid facial cleanser.
The amino acid facial cleanser comprises the following components in parts by weight: 13.5 parts of amino acid surfactant potassium cocoyl glycinate, 3.5 parts of thickener acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate, 10 parts of humectant glycerol, 1.5 parts of pearling agent ethylene glycol distearate, 1.5 parts of skin conditioner yeast/rice fermentation product filtrate, 1.5 parts of dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria extract, radix scrophulariae extract and radix ophiopogonis extract and 70.62 parts of water; the pH value of the amino acid facial cleanser is 7.1.
The thickening agent consists of acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 5: 1.
The skin conditioner consists of 0.05-0.5% of saccharomycetes/rice fermentation product filtrate, 0.05-0.2% of dipotassium glycyrrhizinate, 0.0008-0.1% of pseudo-ginseng, 0.05-0.15% of dendrobium officinale stem extract, 0.05-0.15% of polygonatum odoratum extract, 0.05-0.15% of poria cocos extract, 0.05-0.15% of radix scrophulariae extract and 0.05-0.15% of radix ophiopogonis extract.
The amino acid facial cleanser was prepared in a similar manner to example 2.
The difference from example 2 is that the cosurfactants cocamidopropyl hydroxysultaine and decyl glucoside were not added.
Comparative example 5 an amino acid facial cleanser.
The amino acid facial cleanser comprises the following components in parts by weight: 13.5 parts of amino acid surfactant potassium cocoyl glycinate, 8 parts of auxiliary surfactant cocoamidopropyl hydroxysulfobetaine and decyl glucoside, 3.5 parts of thickener acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate, 10 parts of humectant glycerol, 1.5 parts of pearling agent ethylene glycol distearate, 1.5 parts of skin conditioner yeast/rice fermentation product filtrate, 1.5 parts of dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria cocos extract, radix scrophulariae extract and radix ophiopogonis extract and 62.62 parts of water; the pH value of the amino acid facial cleanser is 6.0.
The thickening agent is prepared from acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 9: 1.
The skin conditioner consists of 0.05-0.5% of saccharomycetes/rice fermentation product filtrate, 0.05-0.2% of dipotassium glycyrrhizinate, 0.0008-0.1% of pseudo-ginseng, 0.05-0.15% of dendrobium officinale stem extract, 0.05-0.15% of polygonatum odoratum extract, 0.05-0.15% of poria cocos extract, 0.05-0.15% of radix scrophulariae extract and 0.05-0.15% of radix ophiopogonis extract.
The preparation method of the amino acid facial cleanser is similar to that of the example 2.
The difference from example 2 is that the thickener consists of an acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate 9: 1.
Comparative example 6 an amino acid facial cleanser.
The amino acid facial cleanser consists of the following components in parts by weight: 13.5 parts of amino acid surfactant potassium cocoyl glycinate, 8 parts of auxiliary surfactant cocoamidopropyl hydroxysulfobetaine and decyl glucoside, 3.5 parts of thickener acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate, 10 parts of humectant glycerol, 1.5 parts of pearling agent ethylene glycol distearate, 1.5 parts of skin conditioner yeast/rice fermentation product filtrate, 1.5 parts of dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria cocos extract, radix scrophulariae extract and radix ophiopogonis extract and 62.62 parts of water; the pH value of the amino acid facial cleanser is 6.7.
The thickening agent is prepared from acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 1: 1.
The skin conditioner consists of 0.05-0.5% of saccharomycete/rice fermentation product filtrate, 0.05-0.2% of dipotassium glycyrrhizinate, 0.0008-0.1% of pseudo-ginseng, 0.05-0.15% of dendrobium officinale stem extract, 0.05-0.15% of polygonatum odoratum extract, 0.05-0.15% of poria cocos extract, 0.05-0.15% of radix scrophulariae extract and 0.05-0.15% of radix ophiopogonis extract.
The amino acid facial cleanser was prepared in a similar manner to example 2.
The difference from example 2 is that the thickener consists of an acrylic acid (ester) copolymer and PEG-120 methyl glucose trioleate 1: 1.
Test example one, evaluation of the preparation method.
The preparation method comprises the following steps: in the preparation process, each operation step is observed, and abnormal conditions occurring in the operation process are recorded.
And (3) test results: the results are shown in Table 1
Table 1 amino acid facial cleanser preparation method results
Figure BDA0002941174250000091
It can be seen from the above table that the proper conditions of stirring speed and heat preservation temperature are the key to obtain a fine, smooth and non-obvious foam sample, and the condition of too low stirring speed or too low heat preservation temperature makes the acrylic acid (ester) copolymer as the thickening agent difficult to completely disperse, resulting in a transparent granular product; the stirring speed is too high, a large amount of foam of a product is difficult to remove in the preparation process, and finally a large amount of foam and unsmooth paste of a sample are caused.
Test example two safety test.
The safety evaluation method comprises the following steps: multiple (acute) skin irritation tests.
And (3) test results: the results are shown in Table 2
Table 2 amino acid facial cleanser safety test results
Figure BDA0002941174250000092
As can be seen from the above table, the formula of the face cleansers of examples 1-3 is highly safe, and has safe, mild and low-irritation characteristics under the condition that no soothing components such as dipotassium glycyrrhizinate are added by taking potassium cocoyl glycinate as a main surfactant and matching with appropriate cocoamidopropyl hydroxy sulfobetaine and decyl glucoside auxiliary surfactants.
Third test example, physical and chemical Properties test
The appearance evaluation method comprises the following steps: a proper amount of sample is squeezed on clean white paper, 30 volunteers are smeared and spread by hands, and the color and the state of the sample are evaluated.
pH test method: the sample was diluted with deionized water to 10% by mass by the dilution method, and the test was performed with a pH meter.
Viscosity test method: about 200ml of sample is put into a 250ml beaker and placed in a water bath at 25.0 ℃ for 1h, and the temperature of the material body is actually measured to be 25 +/-0.2 ℃. The viscosity measurements were then performed using BROOKFIELD DV-1VISCOMETER at 100rpm with 7# rotor.
And (3) test results: the results are shown in Table 3
TABLE 3 results of testing physicochemical Properties of amino acid face wash
Figure BDA0002941174250000101
As can be seen from the above table, examples 1-4 and comparative examples 4-6 are all milky in appearance, with a pH in the range of 5.5-7.5. The formula sample in the example 2 is fine and easy to coat and dissolve, and compared with the formula sample in the example 2, the formula sample in the comparative example 4 is not added with the cosurfactant of cocamidopropyl hydroxysultaine and decyl glucoside, the coating and spreading performance of the formula sample is obviously reduced, and the coating and spreading performance is difficult to apply and spread when the formula sample is used. Comparative example 5 the proportion of acrylic acid (ester) copolymer in the thickener was increased compared to example 2, and the spreadability of the coating sample was significantly reduced. Comparative example 6 the proportion of PEG-120 methyl glucose trioleate in the thickener was increased relative to example 2, and the formula sample had a certain pectin feel and was difficult to spread.
Test example four, stability test.
The stability test method comprises the following steps: taking about 30g of the facial cleanser samples obtained in the examples 1-4 and the comparative examples 4-6 in a 50ml transparent inspection bottle, placing the bottle in an oven at 45 +/-1 ℃ for 3 months, and observing the appearance of the sample after the temperature is restored to room temperature so as to detect the heat resistance of the sample; placing in a high-low temperature alternating test chamber at (48 +/-1 ℃) to (-15 +/-1 ℃) for 1 month, and observing the appearance of the sample after the sample is restored to the room temperature so as to detect the cold-heat exchange resistance of the sample; and placing the sample in an oven with the temperature of-10 +/-1 ℃ for 3 months, and observing the appearance of the sample after the sample is restored to the room temperature so as to detect the cold resistance of the sample.
And (3) test results: the results are shown in Table 4
Table 4 stability test results of amino acid face wash
Item Example 1 Example 2 Example 3 Example 4 Comparative example 4 Comparative example 5 Comparative example 6
Heat resistance Is normal Is normal and normal Is normal Is normal Is normal Is normal Is normal
Alternating cold and hot Is normal Is normal Is normal Is normal Is normal Is normal and normal Is normal
Cold-resistant Is normal Is normal Is normal Is normal Is normal Is normal Is normal and normal
As can be seen from the above table, examples 1 to 4 and comparative examples 4 to 6 are all normal in heat resistance, cold and hot alternation, and cold resistance, and have good stability.
Test example five evaluation of skin feel
Skin feel evaluation method: 30 volunteers were selected to perform facial cleansing using the same method using the formula samples of example 2 and comparative examples 4-6, respectively. Wetting the face with clear water, spreading a proper amount of the product on the palm, adding a small amount of clear water to gently knead the palm, beating out abundant foam, finely kneading the face to clean, and then washing with clear water. And (4) after face cleaning is finished, filling out a mark on a trial questionnaire, wherein a 7-point system is adopted, and the higher the mark is, the better the satisfaction is. The evaluation indexes include the preference of the appearance of the paste, the preference of the thickness of the paste, the preference of the foam during application, the cleanliness of rinsing, the preference of the skin feeling after rinsing, and the overall evaluation
And (3) test results: the results are shown in Table 5
TABLE 5 skin feel evaluation results
Item Example 2 Comparative example 4 Comparative example 5 Comparative example 6
Preference of appearance of paste 5.6 5.0 5.5 5.3
Preference for thickness of paste 5.5 5.2 5.4 5.5
Foam preference during application 5.5 4.5 4.9 5.0
Cleanliness of rinsing 5.8 5.0 5.0 5.5
Skin feel preference after rinsing 5.7 4.0 5.1 5.3
General evaluation 5.8 4.5 5.0 5.0
As can be seen from the results of the trial skin feel evaluation of the volunteers in Table 5, the amino acid facial cleanser prepared in example 2 is superior in foaming property, cleansing effect and skin feel after use. The cleansing milk of comparative example 4 did not contain the appropriate co-surfactants cocamidopropyl hydroxysultaine and decyl glucoside, resulting in a significant reduction in lather, lather richness, and lather resiliency. The facial cleansers of comparative example 5 and comparative example 6 increase the ratio of acrylic acid (ester) copolymer, PEG-120 methyl glucose trioleate in the thickener, respectively, and the foaming performance, cleansing effect and skin feel in use are all in adverse directions.
The above description is only an embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can make appropriate modifications or improvements within the technical scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.

Claims (4)

1. The amino acid facial cleanser is characterized by mainly comprising the following components in parts by weight: 7-20 parts of amino acid surfactant, 3-13 parts of auxiliary surfactant, 2-5 parts of thickening agent, 4-16 parts of humectant, 0.5-2 parts of pearling agent and 38.5-80.5 parts of water; the pH value of the amino acid facial cleanser is 5.5-7.5;
the amino acid surfactant is potassium cocoyl glycinate, the auxiliary surfactant is cocamidopropyl hydroxysulfobetaine and decyl glucoside, the thickening agent is composed of acrylate copolymer and PEG-120 methyl glucose trioleate according to the weight ratio of 5:1, the humectant is glycerin, the pearling agent is ethylene glycol distearate, and the skin conditioner is yeast/rice fermentation product filtrate, dipotassium glycyrrhizinate, pseudo-ginseng, dendrobium officinale stem extract, polygonatum extract, poria cocos extract, radix scrophulariae extract and radix ophiopogonis extract.
2. The amino acid facial cleanser of claim 1, which is mainly composed of the following components in parts by weight: 13.5 parts of amino acid surfactant, 8 parts of auxiliary surfactant, 3.5 parts of thickening agent, 10 parts of humectant, 1.5 parts of pearling agent and 59.5 parts of water.
3. The method for preparing the amino acid facial cleanser according to any one of claims 1 to 2, comprising the steps of:
s1, adding the amino acid surfactant, the auxiliary surfactant and the humectant into an emulsifying cylinder, heating and stirring uniformly until the mixture is dissolved, and keeping the temperature and stirring for 10-30min when the temperature of the emulsifying cylinder reaches 70-90 ℃, so as to remove the foam in the solution;
s2, adding pearling agent ethylene glycol distearate and acrylate copolymer in the thickening agent into the mixed solution obtained in the step S1, keeping the temperature at 80-90 ℃, stirring for 15-25min, then opening a cooling system, and cooling to 60-75 ℃ while stirring;
s3, adding PEG-120 methyl glucose trioleate in a thickening agent into the mixture obtained in the step S2, keeping the temperature of 60-75 ℃, stirring for 10-15min, continuing to open a cooling system, and cooling to 45-50 ℃ while stirring;
s4, adding the skin conditioner, the essence and the preservative into the mixture obtained in the step S3, keeping the temperature at 45-50 ℃, stirring for 10-15min, continuing to open the cooling system, and cooling to 35-42 ℃ while stirring, and stopping cooling to form a smooth and uniform material body.
4. The method for preparing amino acid facial cleanser of claim 3, wherein the stirring rate in step S1, step S2, step S3 and step S4 is 10-35 r/min.
CN202110179948.8A 2021-02-08 2021-02-08 Amino acid facial cleanser and preparation method thereof Active CN112957302B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110179948.8A CN112957302B (en) 2021-02-08 2021-02-08 Amino acid facial cleanser and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110179948.8A CN112957302B (en) 2021-02-08 2021-02-08 Amino acid facial cleanser and preparation method thereof

Publications (2)

Publication Number Publication Date
CN112957302A CN112957302A (en) 2021-06-15
CN112957302B true CN112957302B (en) 2022-09-27

Family

ID=76284608

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110179948.8A Active CN112957302B (en) 2021-02-08 2021-02-08 Amino acid facial cleanser and preparation method thereof

Country Status (1)

Country Link
CN (1) CN112957302B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114099382B (en) * 2021-11-22 2024-03-12 福建片仔癀化妆品有限公司 Soap-based facial cleanser and preparation method thereof
CN114392204A (en) * 2021-12-24 2022-04-26 广州那比昂生物科技有限公司 Skin cleaning composition and preparation method and application thereof
CN114848523B (en) * 2022-06-10 2024-02-09 广东嘉丹婷日用品有限公司 Double-tube facial cleanser
CN115813788A (en) * 2022-12-26 2023-03-21 福建片仔癀化妆品有限公司 Mild self-corrosion-resistant and foam-dense cleansing bubble liquid and preparation method thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4150361B2 (en) * 2004-06-08 2008-09-17 花王株式会社 Liquid skin cleanser
CN108403609B (en) * 2018-06-01 2020-06-23 广州澳希亚实业有限公司 Firming, skin-moistening and face-cleaning gel
CN108938540A (en) * 2018-08-28 2018-12-07 广州科玛生物科技股份有限公司 A kind of brilliant profit mildy wash
CN110279623A (en) * 2019-07-03 2019-09-27 森锐健康科技(广州)有限公司 A kind of mild Shu Min amino acid cleansing cream and preparation method thereof
CN111214384B (en) * 2019-11-18 2022-06-07 花安堂生物科技集团有限公司 Moisturizing cleansing foam and preparation method thereof
CN111759753B (en) * 2020-08-11 2023-01-06 广州美兮生物科技有限公司 Mild amino acid facial cleanser and preparation method thereof

Also Published As

Publication number Publication date
CN112957302A (en) 2021-06-15

Similar Documents

Publication Publication Date Title
CN112957302B (en) Amino acid facial cleanser and preparation method thereof
AU2020455109B2 (en) Soap/amino acid-type facial cleansing product and preparation method therefor
CN109528523B (en) Amino acid facial cleanser
CN110693747B (en) Surfactant composition, female fragrance shower gel containing surfactant composition and preparation method of shower gel
CN110638679B (en) Amino acid cleansing cream compounded by amino acid potassium salt and amino acid sodium salt and preparation method thereof
CN106420407A (en) Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil
CN109401869B (en) Liquid skin cleaning composition and preparation method and application thereof
CN109628242B (en) Mild and stable soap-based facial cleanser and preparation method thereof
CN107638362A (en) A kind of amino acid mildy wash based on hydrolysis shell nacre powder and preparation method thereof
CN110283668A (en) A kind of surface activator composition and its preparation method and application improving detergent foam performance
CN107496317A (en) A kind of restoration care shampoo of the active component containing American cockroach
CN110279623A (en) A kind of mild Shu Min amino acid cleansing cream and preparation method thereof
CN113679638A (en) Sensitive muscle amino acid mild clear face cleaning cream and preparation method thereof
CN112515995A (en) Shampoo bath lotion containing tea seed oil and preparation method thereof
CN101862276A (en) Hair conditioner
CN115192476A (en) Non-irritant shampoo and shower gel and preparation method thereof
CN109316369B (en) Face cleaning mousse and preparation method thereof
CN114306197A (en) Bubble hair conditioner
CN110368329B (en) Silicone oil-free homogeneous phase nursing composition
CN111671678A (en) Shampoo and bath foam and preparation method thereof
CN112618433B (en) Natural casein mild moisturizing washing product
CN107823078A (en) A kind of functional form shampoo
CN112754948B (en) Bright facial cleanser and preparation method thereof
CN115282090B (en) Mild children cleansing bubble compound and preparation method thereof
KR100478466B1 (en) Shampoo compositions containing extract of Dioscoreae Rhizoma

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant