CN112919831A - Explosion-proof glass - Google Patents
Explosion-proof glass Download PDFInfo
- Publication number
- CN112919831A CN112919831A CN201911238093.0A CN201911238093A CN112919831A CN 112919831 A CN112919831 A CN 112919831A CN 201911238093 A CN201911238093 A CN 201911238093A CN 112919831 A CN112919831 A CN 112919831A
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- China
- Prior art keywords
- parts
- explosion
- oxide
- glass
- proof
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/002—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/02—Fibres; Filaments; Yarns; Felts; Woven material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/08—Metals
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Laminated Bodies (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses explosion-proof glass, which comprises a plurality of layers of toughened glass and a PVB adhesive film sandwiched between two adjacent layers of toughened glass, wherein the toughened glass comprises the following components in parts by weight: 120 parts of quartz sand, 20-25 parts of carbon nanofiber, 12-15 parts of boron oxide, 2-3 parts of nano zinc oxide, 8-10 parts of bentonite, 5-6 parts of aluminum oxide, 3-4 parts of zirconium oxide, 3-5 parts of potassium carbonate, 2-3 parts of mirabilite and 0.5-1 part of antimony powder. The explosion-proof glass provided by the invention has higher strength, rigidity and toughness and good explosion-proof effect.
Description
Technical Field
The invention relates to the technical field of special glass, in particular to explosion-proof glass.
Background
The explosion-proof glass is glass capable of preventing violent impact, is special glass which is machined by using special additives and an intermediate interlayer, and cannot easily fall off even if the glass is broken, because the intermediate material is fully bonded with the explosion-proof glass on the other side. Therefore, the explosion-proof glass can greatly reduce the damage to personnel and valuables when encountering violent impact.
The explosion-proof glass is divided into two types according to different production and processing technologies:
the common explosion-proof glass is characterized in that the glass structure is special glass made of single float glass through strengthening treatment, the strengthened glass surface has strong anti-impact capacity, the explosion-proof effect of the glass is continuously enhanced along with the continuous thickening of the glass, the thickness of the glass is generally 20 mm, the glass with the thickness exceeding 20 mm is made into the explosion-proof glass, the strengthening treatment is difficult to be in place at one time, and the glass needs to be careful for selecting common explosion-proof glass user groups. Once the common explosion-proof glass is broken, the glass becomes fragments and cannot effectively resist wind pressure or secondary impact of heavy objects. In a strict sense, the common explosion-proof glass does not belong to the true "explosion-proof glass".
The reinforced explosion-proof glass is made up by sandwiching two or more pieces of float glass with strong PVB film, pressing by hot press, exhausting air from the space, and high-temp and-pressure steaming.
The invention aims to provide novel explosion-proof glass.
Disclosure of Invention
The invention aims to provide explosion-proof glass with good explosion-proof effect.
In order to solve the problems, the technical scheme of the invention is as follows:
the explosion-proof glass comprises a plurality of layers of toughened glass and a PVB adhesive film sandwiched between two adjacent layers of toughened glass, wherein the toughened glass comprises the following components in parts by weight:
120 parts of quartz sand, 20-25 parts of carbon nanofiber, 12-15 parts of boron oxide, 2-3 parts of nano zinc oxide, 8-10 parts of bentonite, 5-6 parts of aluminum oxide, 3-4 parts of zirconium oxide, 3-5 parts of potassium carbonate, 2-3 parts of mirabilite and 0.5-1 part of antimony powder.
Further, the aspect ratio of the nano carbon fiber is 150-200: 1.
Further, the particle size of the nano zinc oxide is 60-80 nm.
Further, the toughened glass comprises the following components in parts by weight:
110 parts of quartz sand, 20 parts of carbon nanofibers, 12 parts of boron oxide, 2 parts of nano zinc oxide, 10 parts of bentonite, 5 parts of aluminum oxide, 3 parts of zirconium oxide, 3 parts of potassium carbonate, 2 parts of mirabilite and 0.5 part of antimony powder.
Further, the toughened glass comprises the following components in parts by weight:
120 parts of quartz sand, 25 parts of carbon nanofibers, 15 parts of boron oxide, 3 parts of nano zinc oxide, 8 parts of bentonite, 6 parts of aluminum oxide, 4 parts of zirconium oxide, 5 parts of potassium carbonate, 3 parts of mirabilite and 1 part of antimony powder.
Further, the toughened glass comprises the following components in parts by weight:
115 parts of quartz sand, 23 parts of carbon nanofibers, 13 parts of boron oxide, 3 parts of nano zinc oxide, 9 parts of bentonite, 6 parts of aluminum oxide, 3 parts of zirconium oxide, 4 parts of potassium carbonate, 2 parts of mirabilite and 0.8 part of antimony powder.
Compared with the prior art, the explosion-proof glass provided by the invention has the beneficial effects that:
the explosion-proof glass is added with the components of nano zinc oxide, aluminum oxide, zirconium oxide, boron oxide and the like, and is used for increasing the strength and the rigidity of the explosion-proof glass; proper amount of potassium carbonate is added to improve the toughness of the explosion-proof glass; smooth antimony powder was added to improve the reaction temperature conditions. The explosion-proof glass has high strength, rigidity and toughness and good explosion-proof effect.
Detailed Description
The following description of the present invention is provided to enable those skilled in the art to better understand the technical solutions in the embodiments of the present invention and to make the above objects, features and advantages of the present invention more comprehensible.
The endpoints of the ranges and any values disclosed herein are not limited to the precise range or value, and such ranges or values should be understood to encompass values close to those ranges or values. For ranges of values, between the endpoints of each of the ranges and the individual values, and between the individual values may be combined with each other to yield one or more new ranges of values, which ranges of values should be considered as specifically disclosed herein.
The utility model provides an explosion-proof glass, includes multilayer toughened glass and mix with the PVB glued membrane between adjacent two-layer toughened glass, toughened glass includes the following composition by weight:
120 parts of quartz sand, 20-25 parts of carbon nanofiber, 12-15 parts of boron oxide, 2-3 parts of nano zinc oxide, 8-10 parts of bentonite, 5-6 parts of aluminum oxide, 3-4 parts of zirconium oxide, 3-5 parts of potassium carbonate, 2-3 parts of mirabilite and 0.5-1 part of antimony powder.
The length-diameter ratio of the nano carbon fiber is 150-200: 1;
the particle size of the nano zinc oxide is 60-80 nm.
The following describes the explosion-proof glass of the present invention in detail with reference to specific examples.
Example 1
The utility model provides an explosion-proof glass, includes multilayer toughened glass and mix with the PVB glued membrane between adjacent two-layer toughened glass, toughened glass includes the following composition by weight:
110 parts of quartz sand, 20 parts of carbon nanofibers, 12 parts of boron oxide, 2 parts of nano zinc oxide, 10 parts of bentonite, 5 parts of aluminum oxide, 3 parts of zirconium oxide, 3 parts of potassium carbonate, 2 parts of mirabilite and 0.5 part of antimony powder.
Example 2
The utility model provides an explosion-proof glass, includes multilayer toughened glass and mix with the PVB glued membrane between adjacent two-layer toughened glass, toughened glass includes the following composition by weight:
120 parts of quartz sand, 25 parts of carbon nanofibers, 15 parts of boron oxide, 3 parts of nano zinc oxide, 8 parts of bentonite, 6 parts of aluminum oxide, 4 parts of zirconium oxide, 5 parts of potassium carbonate, 3 parts of mirabilite and 1 part of antimony powder.
Example 3
The utility model provides an explosion-proof glass, includes multilayer toughened glass and mix with the PVB glued membrane between adjacent two-layer toughened glass, toughened glass includes the following composition by weight:
115 parts of quartz sand, 23 parts of carbon nanofibers, 13 parts of boron oxide, 3 parts of nano zinc oxide, 9 parts of bentonite, 6 parts of aluminum oxide, 3 parts of zirconium oxide, 4 parts of potassium carbonate, 2 parts of mirabilite and 0.8 part of antimony powder.
The explosion-proof glass is added with the components of nano zinc oxide, aluminum oxide, zirconium oxide, boron oxide and the like, and is used for increasing the strength and the rigidity of the explosion-proof glass; proper amount of potassium carbonate is added to improve the toughness of the explosion-proof glass; smooth antimony powder was added to improve the reaction temperature conditions. The explosion-proof glass has high strength, rigidity and toughness and good explosion-proof effect.
The embodiments of the present invention have been described in detail, but the present invention is not limited to the described embodiments. Various changes, modifications, substitutions and alterations to these embodiments will occur to those skilled in the art without departing from the spirit and scope of the present invention.
Claims (6)
1. The explosion-proof glass is characterized by comprising a plurality of layers of toughened glass and a PVB adhesive film sandwiched between two adjacent layers of toughened glass, wherein the toughened glass comprises the following components in parts by weight:
120 parts of quartz sand, 20-25 parts of carbon nanofiber, 12-15 parts of boron oxide, 2-3 parts of nano zinc oxide, 8-10 parts of bentonite, 5-6 parts of aluminum oxide, 3-4 parts of zirconium oxide, 3-5 parts of potassium carbonate, 2-3 parts of mirabilite and 0.5-1 part of antimony powder.
2. The explosion-proof glass as claimed in claim 1, wherein the aspect ratio of the carbon nanofibers is 150-200: 1.
3. The blast-resistant glass according to claim 1, wherein the nano zinc oxide has a particle size of 60-80 nm.
4. The explosion-proof glass according to any one of claims 1 to 3, wherein the tempered glass comprises the following components in parts by weight:
110 parts of quartz sand, 20 parts of carbon nanofibers, 12 parts of boron oxide, 2 parts of nano zinc oxide, 10 parts of bentonite, 5 parts of aluminum oxide, 3 parts of zirconium oxide, 3 parts of potassium carbonate, 2 parts of mirabilite and 0.5 part of antimony powder.
5. The explosion-proof glass according to any one of claims 1 to 3, wherein the tempered glass comprises the following components in parts by weight:
120 parts of quartz sand, 25 parts of carbon nanofibers, 15 parts of boron oxide, 3 parts of nano zinc oxide, 8 parts of bentonite, 6 parts of aluminum oxide, 4 parts of zirconium oxide, 5 parts of potassium carbonate, 3 parts of mirabilite and 1 part of antimony powder.
6. The explosion-proof glass according to any one of claims 1 to 3, wherein the tempered glass comprises the following components in parts by weight:
115 parts of quartz sand, 23 parts of carbon nanofibers, 13 parts of boron oxide, 3 parts of nano zinc oxide, 9 parts of bentonite, 6 parts of aluminum oxide, 3 parts of zirconium oxide, 4 parts of potassium carbonate, 2 parts of mirabilite and 0.8 part of antimony powder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201911238093.0A CN112919831A (en) | 2019-12-06 | 2019-12-06 | Explosion-proof glass |
Applications Claiming Priority (1)
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CN201911238093.0A CN112919831A (en) | 2019-12-06 | 2019-12-06 | Explosion-proof glass |
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CN112919831A true CN112919831A (en) | 2021-06-08 |
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Family Applications (1)
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CN201911238093.0A Withdrawn CN112919831A (en) | 2019-12-06 | 2019-12-06 | Explosion-proof glass |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114133138A (en) * | 2021-12-17 | 2022-03-04 | 福建新天龙玻璃科技有限公司 | High-strength explosion-proof toughened glass and manufacturing process thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3761293A (en) * | 1971-04-27 | 1973-09-25 | Hommel Co O | Ceramic coating compositions for continuous cleaning surfaces |
CN107226623A (en) * | 2017-07-24 | 2017-10-03 | 太仓市科教新城琉璃艺术策划中心 | A kind of coloured glaze containing Red Stone Ware composition |
CN107933010A (en) * | 2017-11-20 | 2018-04-20 | 重庆艺美玻璃有限公司 | A kind of explosion-proof hollow glass |
CN108503229A (en) * | 2018-04-24 | 2018-09-07 | 山东博丽电子商务有限公司 | Implosion guard product and its preparation process |
CN108891105A (en) * | 2018-06-13 | 2018-11-27 | 浙江西溪玻璃有限公司 | Explosion-proof glass and preparation method thereof |
-
2019
- 2019-12-06 CN CN201911238093.0A patent/CN112919831A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3761293A (en) * | 1971-04-27 | 1973-09-25 | Hommel Co O | Ceramic coating compositions for continuous cleaning surfaces |
CN107226623A (en) * | 2017-07-24 | 2017-10-03 | 太仓市科教新城琉璃艺术策划中心 | A kind of coloured glaze containing Red Stone Ware composition |
CN107933010A (en) * | 2017-11-20 | 2018-04-20 | 重庆艺美玻璃有限公司 | A kind of explosion-proof hollow glass |
CN108503229A (en) * | 2018-04-24 | 2018-09-07 | 山东博丽电子商务有限公司 | Implosion guard product and its preparation process |
CN108891105A (en) * | 2018-06-13 | 2018-11-27 | 浙江西溪玻璃有限公司 | Explosion-proof glass and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114133138A (en) * | 2021-12-17 | 2022-03-04 | 福建新天龙玻璃科技有限公司 | High-strength explosion-proof toughened glass and manufacturing process thereof |
CN114133138B (en) * | 2021-12-17 | 2023-10-20 | 福建新天龙玻璃科技有限公司 | High-strength explosion-proof toughened glass and manufacturing process thereof |
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Application publication date: 20210608 |