CN112919678A - Acetic acid production wastewater treatment process - Google Patents
Acetic acid production wastewater treatment process Download PDFInfo
- Publication number
- CN112919678A CN112919678A CN202110122699.9A CN202110122699A CN112919678A CN 112919678 A CN112919678 A CN 112919678A CN 202110122699 A CN202110122699 A CN 202110122699A CN 112919678 A CN112919678 A CN 112919678A
- Authority
- CN
- China
- Prior art keywords
- liquid
- acetic acid
- phase product
- acid production
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/13—Iodine; Hydrogen iodide
- C01B7/14—Iodine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Water Treatment By Sorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Removal Of Specific Substances (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention discloses a process for treating acetic acid production wastewater, which comprises the following steps: adding aqueous hydrogen peroxide into acetic acid production wastewater, and reacting hydrogen peroxide with iodide ions in the wastewater to generate an iodine simple substance; filtering solid iodine elementary substance generated by the reaction out of the wastewater, wherein the residual liquid is a liquid-phase product 1; adding activated carbon powder into the treated liquid-phase product 1; filtering the treated liquid-phase product 1, separating out the active carbon in the liquid-phase product, and taking the residual liquid as a liquid-phase product 2; adding aqueous hydrogen peroxide into the treated liquid-phase product 2, reacting hydrogen peroxide with acetaldehyde in the liquid-phase product 2 to generate acetic acid, converting the liquid into a liquid-phase product 3, and conveying the liquid-phase product 3 to an acetic acid production system for separating the acetic acid. The acetic acid production wastewater treatment process can recycle iodine generated by iodine in the wastewater, convert acetaldehyde in the wastewater into acetic acid, improve the yield of the acetic acid and avoid environmental pollution.
Description
Technical Field
The invention belongs to the technical field of industrial wastewater treatment and effective substance recycling, in particular to a treatment process of acetic acid production wastewater, and particularly relates to a low-cost treatment process of acetic acid production wastewater for recycling iodine and acetaldehyde in the acetic acid production wastewater.
Background
In the current acetic acid production process, methanol carbonylation reaction is taken as a main production process, and a large amount of hydroiodic acid is used in the production process. In the prior art, the methanol carbonylation reaction is not easy to completely react, homogeneous hydriodic acid and acetic acid products are not easy to separate, after a crude product is obtained, the crude product needs to be refined through a plurality of procedures such as primary separation, catalyst removal, promoter removal, acetaldehyde enrichment and the like to obtain a product acetic acid, waste water generated in the refining process is difficult to effectively recycle due to very high organic content and iodine content, and the organic matter in the waste water is further treated after iodine is absorbed by a silver-based material, so that the waste water can be discharged after reaching a discharge standard. The existing acetic acid production wastewater treatment process has the defects that the cost of the silver-based material adopted by the existing acetic acid production wastewater treatment process is very high, so that the wastewater treatment cost is greatly increased, and the method only discharges the wastewater after the wastewater treatment reaches the discharge standard, so that the acetaldehyde and the iodine in the wastewater cannot be effectively recycled, and the resource waste is caused, so that the existing acetic acid production wastewater treatment process needs to be improved.
Disclosure of Invention
The invention aims to provide a treatment process for acetic acid production wastewater, which can solve the problems that the treatment process for acetic acid production wastewater in the prior art is high in cost and acetaldehyde and iodine in the wastewater cannot be recycled.
In order to achieve the purpose, the invention is realized by the following technical scheme: the acetic acid production wastewater treatment process is characterized in that: which comprises the following steps:
s1, adding aqueous hydrogen peroxide into acetic acid production wastewater, wherein the molar equivalent ratio of hydrogen peroxide to iodine in the wastewater is 1: 1-3: 1, and reacting the hydrogen peroxide with iodine ions in the wastewater to generate an iodine simple substance;
s2, filtering the mixture after the reaction in the step S1, separating solid iodine elementary substance generated by the reaction from the wastewater, and taking the residual liquid as a liquid-phase product 1;
s3, adding activated carbon powder into the liquid-phase product 1 treated in the step S2, wherein the mass ratio of the added activated carbon to the iodine remained in the liquid-phase product 1 is 1: 1000-1: 100;
s4, filtering the liquid-phase product 1 treated in the step S3, separating out activated carbon in the liquid-phase product, and obtaining a residual liquid which is a liquid-phase product 2;
s5, adding aqueous hydrogen peroxide into the liquid-phase product 2 treated in the step S4, wherein the molar equivalent ratio of hydrogen peroxide to acetaldehyde in the wastewater is 1: 1-5: 1, reacting the hydrogen peroxide with the acetaldehyde in the liquid-phase product 2 to generate acetic acid, converting the liquid into a liquid-phase product 3, and conveying the liquid-phase product 3 to an acetic acid production system for separating the acetic acid.
In a further scheme, in the step S1, the reaction is carried out under normal pressure, and the reaction temperature is 15-60 ℃. By controlling the reaction temperature, the rate of iodine simple substance generated by iodide ions in the wastewater is higher, the reaction efficiency is higher, and the best treatment effect is achieved.
In a further scheme, in the step S1, the reaction time is 5-60 min. By controlling the reaction time, the reaction of converting the iodide ions in the wastewater into the iodine simple substance is more sufficient, and the conversion rate is higher.
In a further scheme, in the step S5, the reaction is carried out under normal pressure, and the reaction temperature is 15-80 ℃. By controlling the reaction temperature, the ratio of acetaldehyde in the wastewater to generate acetic acid is higher, the reaction efficiency is higher, and the best treatment effect is achieved.
In a further scheme, in the step S5, the reaction time is 0.5-10 h. By controlling the reaction time, the reaction of converting acetaldehyde in the wastewater into acetic acid is more sufficient, and the conversion rate is higher.
In a further scheme, in step S5, after the reaction of the hydrogen peroxide and the acetaldehyde is completed, the wastewater is heated to 60-80 ℃ in a system with condensation reflux for 0.5-10h, so that the redundant hydrogen peroxide in the wastewater is completely decomposed. After the hydrogen peroxide is decomposed, the acetic acid in the wastewater is separated, so that the purity of the obtained acetic acid is higher, the discharged wastewater does not contain hydrogen peroxide, and the acetic acid can be prevented from volatilizing by heating through a condensation reflux system.
Further, in steps S2 and S4, the wastewater is filtered by gravity filtration or reduced pressure filtration. Through gravity filtration or reduced pressure filtration, the iodine simple substance and the active carbon in the wastewater can be thoroughly separated, and the wastewater treatment efficiency is improved.
Further, after the treatment in step S4, the iodine content in the liquid-phase product 2 is detected by starch, and the iodine recovery rate in the liquid-phase product 2 reaches above 99%, and the residual iodine content in the liquid-phase product 2 is below 100 ppm.
Further, after the treatment of step S5, the conversion rate of acetaldehyde in the liquid-phase product 2 into acetic acid is 85% or more.
Further, in steps S1 and S5, the concentration of the aqueous hydrogen peroxide solution is 30 to 40 wt%.
The invention has the beneficial effects that: 1) compared with the prior art in which a silver-based material is adopted to treat iodide ions in wastewater, the treatment process of the acetic acid production wastewater and the wastewater treatment process greatly reduce the treatment cost; 2) the acetic acid production wastewater treatment process can separate iodine in the wastewater into iodine simple substances, recycle the waste and improve the economic benefit; 3) the acetic acid production wastewater treatment process can convert acetaldehyde in the wastewater into acetic acid, not only can improve the yield of the acetic acid and the economic benefit, but also can greatly reduce the content of the acetaldehyde in the wastewater, and the wastewater can be conveyed to an acetic acid production system to be reused for acetic acid production, thereby solving the problem of wastewater discharge and avoiding environmental pollution.
Drawings
FIG. 1 is a process flow diagram of the acetic acid production wastewater treatment process of the present invention.
FIG. 2 is a process flow diagram of the wastewater treatment process of example 1.
Detailed Description
The technical solutions of the present invention are described clearly and completely by the following embodiments, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
A process for treating acetic acid production wastewater comprises the following steps:
s1, adding 30 wt% of aqueous hydrogen peroxide solution into acetic acid production wastewater, wherein the molar equivalent ratio of hydrogen peroxide to iodine in the wastewater is 1:1, reacting the hydrogen peroxide with iodine ions in the wastewater to generate iodine simple substance, and reacting at the normal pressure at the reaction temperature of 15 ℃ for 60 min;
s2, filtering the mixture after the reaction in the step S1, separating solid iodine elementary substance generated by the reaction from the wastewater, and taking the residual liquid as a liquid-phase product 1;
s3, adding activated carbon powder into the liquid-phase product 1 treated in the step S2, wherein the mass ratio of the added activated carbon to the iodine remained in the liquid-phase product 1 is 1: 1000;
s4, filtering the liquid-phase product 1 treated in the step S3, separating out activated carbon in the liquid-phase product, and obtaining a residual liquid which is a liquid-phase product 2;
s5, adding 30 wt% of hydrogen peroxide aqueous solution into the liquid-phase product 2 treated in the step S4, wherein the molar equivalent ratio of hydrogen peroxide to acetaldehyde in the wastewater is 1:1, the hydrogen peroxide reacts with the acetaldehyde in the liquid-phase product 2 at the normal pressure, the reaction temperature is 15 ℃, the reaction time is 10 hours, acetic acid is generated, the liquid is converted into the liquid-phase product 3, the liquid-phase product 3 is heated to 60 ℃ in a heating system with condensation reflux and lasts for 10 hours, so that the excessive hydrogen peroxide in the wastewater is completely decomposed, then the liquid-phase product 3 is conveyed into an acetic acid production system, and the acetic acid in the liquid-phase product 3 is separated through the acetic acid production system.
Example 2
A process for treating acetic acid production wastewater comprises the following steps:
s1, adding 30 wt% of aqueous hydrogen peroxide solution into acetic acid production wastewater, wherein the molar equivalent ratio of hydrogen peroxide to iodine in the wastewater is 2: 1, reacting the hydrogen peroxide with iodine ions in the wastewater to generate iodine simple substance, and reacting at the normal pressure at the reaction temperature of 30 ℃ for 20 min;
s2, performing gravity filtration or reduced pressure filtration on the mixture after the reaction in the step S1, separating solid iodine elementary substance generated by the reaction from the wastewater, and obtaining liquid-phase product 1 as the residual liquid;
s3, adding activated carbon powder into the liquid-phase product 1 treated in the step S2, wherein the mass ratio of the added activated carbon to the iodine remained in the liquid-phase product 1 is 1: 500;
s4, performing gravity filtration or reduced pressure filtration on the liquid-phase product 1 treated in the step S3 to separate out activated carbon, wherein the residual liquid is a liquid-phase product 2;
s5, adding 40 wt% of aqueous hydrogen peroxide into the liquid-phase product 2 treated in the step S4, wherein the molar equivalent ratio of hydrogen peroxide to acetaldehyde in the wastewater is 1: 3, the hydrogen peroxide reacts with the acetaldehyde in the liquid-phase product 2 at normal pressure, the reaction temperature is 30 ℃, the reaction time is 5 hours, acetic acid is generated, the liquid is converted into the liquid-phase product 3, the liquid-phase product 3 is heated to 80 ℃ in a heating system with condensation reflux and lasts for 0.5 hour, so that the excessive hydrogen peroxide in the wastewater is completely decomposed, then the liquid-phase product 3 is conveyed into an acetic acid production system, and the acetic acid in the liquid-phase product 3 is separated through the acetic acid production system.
Example 3
A process for treating acetic acid production wastewater comprises the following steps:
s1, adding 40 wt% of aqueous hydrogen peroxide solution into acetic acid production wastewater, wherein the molar equivalent ratio of hydrogen peroxide to iodine in the wastewater is 3:1, reacting the hydrogen peroxide with iodine ions in the wastewater to generate iodine simple substance, and reacting at the normal pressure at the reaction temperature of 60 ℃ for 5 min;
s2, filtering the mixture after the reaction in the step S1, separating solid iodine elementary substance generated by the reaction from the wastewater, and taking the residual liquid as a liquid-phase product 1;
s3, adding activated carbon powder into the liquid-phase product 1 treated in the step S2, wherein the mass ratio of the added activated carbon to the iodine remained in the liquid-phase product 1 is 1: 100;
s4, filtering the liquid-phase product 1 treated in the step S3, separating out activated carbon in the liquid-phase product, and obtaining a residual liquid which is a liquid-phase product 2;
s5, adding 30 wt% of aqueous hydrogen peroxide into the liquid-phase product 2 treated in the step S4, wherein the molar equivalent ratio of hydrogen peroxide to acetaldehyde in the wastewater is 1:5, the hydrogen peroxide reacts with the acetaldehyde in the liquid-phase product 2 at normal pressure, the reaction temperature is 80 ℃, the reaction time is 0.5h, acetic acid is generated, the liquid is converted into the liquid-phase product 3, the liquid-phase product 3 is conveyed into an acetic acid production system, and the acetic acid in the liquid-phase product 3 is separated through the acetic acid production system.
As shown in fig. 2, through experiments, in step 4 of examples 1 to 3 of the present invention, activated carbon powder can not only filter iodine in the liquid-phase product 1, but also perform adsorption and decoloration on the liquid-phase product 1, so that the liquid-phase product 2 obtained after the treatment becomes a clarified liquid, and the iodine content in the liquid-phase product 2 is detected by using starch, and the experimental results show that the iodine recovery rate in the liquid-phase product 2 can reach more than 99%, and the residual iodine content in the liquid-phase product 2 reaches less than 100 ppm. The liquid-phase product 3 treated in the step S5 is detected, and the experimental result shows that the conversion rate of acetaldehyde into acetic acid can reach more than 85%.
The following table is a calculation table of the income of each ton of acetic acid production wastewater treated by the acetic acid production wastewater treatment process of the invention:
as can be seen from the above table, the acetic acid wastewater treatment process of the invention can obtain 396.22 yuan per ton of acetic acid wastewater, and if 10 ten thousand tons of wastewater rich in iodine and acetaldehyde are treated for an acetic acid manufacturing plant every year, 3962.2 ten thousand yuan can be obtained.
Through the embodiments, it can be seen that, the acetic acid wastewater treatment process of the invention can greatly reduce the wastewater treatment cost, recycle iodine and acetaldehyde in the wastewater, generate a large amount of economic benefits, and simultaneously, remove acetaldehyde in the wastewater, ensure that the discharged wastewater is more environment-friendly and safer, and avoid environmental pollution.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (10)
1. A process for treating acetic acid production wastewater is characterized by comprising the following steps:
s1, adding aqueous hydrogen peroxide into acetic acid production wastewater, wherein the molar equivalent ratio of hydrogen peroxide to iodine in the wastewater is 1: 1-3: 1, and reacting the hydrogen peroxide with iodine ions in the wastewater to generate an iodine simple substance;
s2, filtering the mixture after the reaction in the step S1, separating solid iodine elementary substance generated by the reaction from the wastewater, and taking the residual liquid as a liquid-phase product 1;
s3, adding activated carbon powder into the liquid-phase product 1 treated in the step S2, wherein the mass ratio of the added activated carbon to the iodine remained in the liquid-phase product 1 is 1: 1000-1: 100;
s4, filtering the liquid-phase product 1 treated in the step S3, separating out activated carbon in the liquid-phase product, and obtaining a residual liquid which is a liquid-phase product 2;
s5, adding aqueous hydrogen peroxide into the liquid-phase product 2 treated in the step S4, wherein the molar equivalent ratio of hydrogen peroxide to acetaldehyde in the wastewater is 1: 1-5: 1, reacting the hydrogen peroxide with the acetaldehyde in the liquid-phase product 2 to generate acetic acid, converting the liquid into a liquid-phase product 3, and conveying the liquid-phase product 3 to an acetic acid production system for separating the acetic acid.
2. The acetic acid production wastewater treatment process according to claim 1, characterized in that: in step S1, the reaction is carried out under normal pressure, and the reaction temperature is 15-60 ℃.
3. The acetic acid production wastewater treatment process according to claim 1, characterized in that: in step S1, the reaction time is 5-60 min.
4. The acetic acid production wastewater treatment process according to claim 3, characterized in that: in step S5, the reaction is carried out under normal pressure, and the reaction temperature is 15-80 ℃.
5. The acetic acid production wastewater treatment process according to claim 1, characterized in that: in step S5, the reaction time is 0.5-10 h.
6. The acetic acid production wastewater treatment process according to claim 1, characterized in that: in step S5, after the reaction of hydrogen peroxide and acetaldehyde is completed, the waste water is heated to 60-80 ℃ in a system with condensing reflux for 0.5-10h, so that the redundant hydrogen peroxide in the waste water is completely decomposed.
7. The acetic acid production wastewater treatment process according to claim 1, characterized in that: in steps S2 and S4, the wastewater is filtered by gravity filtration or reduced pressure filtration.
8. The acetic acid production wastewater treatment process according to claim 1, characterized in that: after the treatment of step S4, the iodine content in the liquid-phase product 2 is detected by starch, the iodine recovery rate in the liquid-phase product 2 reaches more than 99%, and the residual iodine content in the liquid-phase product 2 is less than 100 ppm.
9. The acetic acid production wastewater treatment process according to claim 1, characterized in that: after the treatment of step S5, the conversion rate of acetaldehyde in the liquid-phase product 2 into acetic acid is 85% or more.
10. The acetic acid production wastewater treatment process according to claim 1, characterized in that: in steps S1 and S5, the concentration of the aqueous hydrogen peroxide solution is 30 to 40 wt%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110122699.9A CN112919678B (en) | 2021-01-29 | 2021-01-29 | Acetic acid production wastewater treatment process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110122699.9A CN112919678B (en) | 2021-01-29 | 2021-01-29 | Acetic acid production wastewater treatment process |
Publications (2)
Publication Number | Publication Date |
---|---|
CN112919678A true CN112919678A (en) | 2021-06-08 |
CN112919678B CN112919678B (en) | 2023-04-18 |
Family
ID=76168347
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202110122699.9A Active CN112919678B (en) | 2021-01-29 | 2021-01-29 | Acetic acid production wastewater treatment process |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112919678B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113636687A (en) * | 2021-09-14 | 2021-11-12 | 江苏集萃托普索清洁能源研发有限公司 | Resource utilization process for high-value chemicals in acetic acid plant wastewater |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5175362A (en) * | 1991-05-29 | 1992-12-29 | Eastman Kodak Company | Recovery of acetyl values from ethylidene diacetate |
WO1994010083A1 (en) * | 1992-10-30 | 1994-05-11 | Schering Aktiengesellschaft | Method of recovering iodine from iodated organic compounds |
JPH0920698A (en) * | 1995-07-05 | 1997-01-21 | Kobe Steel Ltd | Production of organic compound showing affinity to hydrophilic medium |
CN1523001A (en) * | 2003-09-05 | 2004-08-25 | 上海吴泾化工有限公司 | Acetic acid purification process |
CN1634843A (en) * | 2004-10-15 | 2005-07-06 | 上海吴泾化工有限公司 | Acetic acid refining method for improving acetic acid potassium permanganate test time |
CN105948305A (en) * | 2016-05-12 | 2016-09-21 | 同济大学 | Method for reducing generation of I-DBPs (iodinated disinfection by-products) through chemical pre-oxidation |
CN110194501A (en) * | 2019-04-30 | 2019-09-03 | 凯莱英医药化学(阜新)技术有限公司 | From the continuous process and continuous device for recycling iodide in waste water containing iodine |
-
2021
- 2021-01-29 CN CN202110122699.9A patent/CN112919678B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5175362A (en) * | 1991-05-29 | 1992-12-29 | Eastman Kodak Company | Recovery of acetyl values from ethylidene diacetate |
WO1994010083A1 (en) * | 1992-10-30 | 1994-05-11 | Schering Aktiengesellschaft | Method of recovering iodine from iodated organic compounds |
JPH0920698A (en) * | 1995-07-05 | 1997-01-21 | Kobe Steel Ltd | Production of organic compound showing affinity to hydrophilic medium |
CN1523001A (en) * | 2003-09-05 | 2004-08-25 | 上海吴泾化工有限公司 | Acetic acid purification process |
CN1634843A (en) * | 2004-10-15 | 2005-07-06 | 上海吴泾化工有限公司 | Acetic acid refining method for improving acetic acid potassium permanganate test time |
CN105948305A (en) * | 2016-05-12 | 2016-09-21 | 同济大学 | Method for reducing generation of I-DBPs (iodinated disinfection by-products) through chemical pre-oxidation |
CN110194501A (en) * | 2019-04-30 | 2019-09-03 | 凯莱英医药化学(阜新)技术有限公司 | From the continuous process and continuous device for recycling iodide in waste water containing iodine |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113636687A (en) * | 2021-09-14 | 2021-11-12 | 江苏集萃托普索清洁能源研发有限公司 | Resource utilization process for high-value chemicals in acetic acid plant wastewater |
WO2023040003A1 (en) * | 2021-09-14 | 2023-03-23 | 江苏集萃托普索清洁能源研发有限公司 | Process for recycling high-value chemicals in acetic acid plant wastewater |
Also Published As
Publication number | Publication date |
---|---|
CN112919678B (en) | 2023-04-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102417263B (en) | Method for processing wastewater from nitrochlorobenzene production | |
CN214399818U (en) | Device for purifying hydrogen chloride by calcium chloride method containing impurity dilute hydrochloric acid | |
CN105692996A (en) | Novel process for treating industrial wastewater with benzyl alcohol | |
CN111573640A (en) | Method and system for producing high-purity nitric acid by recovering fluorine-containing dilute nitric acid waste liquid | |
CN112919678B (en) | Acetic acid production wastewater treatment process | |
CN114588650A (en) | Combined hydrochloric acid resolving process | |
CN110590034A (en) | Process treatment method for lithium iron wastewater of lithium battery anode material | |
CN102417265B (en) | Method for effectively removing organic matters in wastewater from nitrochlorobenzene production | |
CN113860995B (en) | Recovery treatment process and treatment device for waste liquid produced in production of acetochlor | |
CN216303678U (en) | Recovery processing device for waste liquid generated in acetochlor production | |
CN1307109C (en) | Method for recovering aromatic carboxylic acid in waste water | |
CN111233191B (en) | Method for treating wastewater generated in process of preparing epoxy chloropropane by epoxidation of chloropropene | |
CN107200680B (en) | Pressure swing distillation separation method of phenol wastewater | |
CN110845651B (en) | Process for improving bromine utilization rate in brominated butyl rubber | |
CN113548960A (en) | Purification method of food-grade benzoic acid | |
CN109369339B (en) | Method for treating waste p-toluenesulfonic acid iron n-butanol solution | |
CN111254289A (en) | Method for recovering rhodium from rhodium-containing waste liquid | |
WO2023040003A1 (en) | Process for recycling high-value chemicals in acetic acid plant wastewater | |
CN109503336B (en) | Equipment and method for treating unqualified DMMn material | |
CN109467501B (en) | Process and device for refining acetic acid and regenerating entrainer in polyvinyl alcohol mother liquor recovery unit | |
CN102617354B (en) | Refining process of o-nitrophenol | |
CN111454449B (en) | Method for recycling solvent system for synthesizing PPTA | |
CN102126943A (en) | Recycling and separating process of heavy component residual liquid in carbonylation production process of acetic acid | |
CN115636722A (en) | Method for preparing ethylene glycol | |
CN101928825A (en) | Gold wet-process purification method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |