CN112826007A - Device and method for removing heavy metals by propolis mixed liquid - Google Patents

Device and method for removing heavy metals by propolis mixed liquid Download PDF

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Publication number
CN112826007A
CN112826007A CN202110114249.5A CN202110114249A CN112826007A CN 112826007 A CN112826007 A CN 112826007A CN 202110114249 A CN202110114249 A CN 202110114249A CN 112826007 A CN112826007 A CN 112826007A
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China
Prior art keywords
propolis
heavy metal
mixed solution
vibration
vibration device
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CN202110114249.5A
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Chinese (zh)
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孙长生
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BEIJING AGRICULTURAL TECHNOLOGY YIJIAN BEE PRODUCTS RESEARCH INSTITUTE
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BEIJING AGRICULTURAL TECHNOLOGY YIJIAN BEE PRODUCTS RESEARCH INSTITUTE
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Priority to CN202110114249.5A priority Critical patent/CN112826007A/en
Publication of CN112826007A publication Critical patent/CN112826007A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/21Removal of unwanted matter, e.g. deodorisation or detoxification by heating without chemical treatment, e.g. steam treatment, cooking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/28Mechanical auxiliary equipment for acceleration of sedimentation, e.g. by vibrators or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/30Control equipment

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

The invention relates to the technical field of propolis processing, in particular to a device and a method for removing heavy metals from propolis mixed liquor; the device for removing the heavy metal from the propolis mixed liquid comprises a settling tank, wherein a heavy metal settling area is arranged below the settling tank, a plurality of discharge ports which are arranged up and down are arranged on the side surface of the heavy metal settling area, supporting legs are arranged below the settling tank, and a vibration device which is a first vibration device is arranged on the settling tank; the method for removing heavy metal from propolis mixed solution comprises vibrating propolis ethanol mixed solution in a propolis mixed solution heavy metal removing device for the first time, standing for the first time, and separating to remove the mixed solution containing heavy metal. Has the advantages of good heavy metal discharging effect and high heavy metal discharging efficiency.

Description

Device and method for removing heavy metals by propolis mixed liquid
Technical Field
The invention relates to the technical field of propolis processing, in particular to a device for removing heavy metals from propolis mixed liquor and a method for removing heavy metals from the propolis mixed liquor.
Background
The purification process of propolis is as follows: (1) pulverizing propolis to obtain propolis powder; (2) mixing propolis powder with ethanol to obtain propolis ethanol mixed solution; (3) filtering the propolis mixed solution to obtain pure propolis ethanol solution; (4) recovering ethanol from the pure propolis ethanol solution to obtain pure propolis.
In the purification process, the original propolis, the propolis mixed solution and the pure propolis ethanol solution contain some heavy metals, and the removal of the heavy metals is a necessary condition for producing high-quality propolis.
Most of the raw propolis ethanol mixed liquor is removed at the stage, and the used equipment is a device for removing heavy metals from the propolis mixed liquor.
In the patent document with the publication number of CN204426590U and the application number of 201420838611.9, which is named as a height-adjustable propolis standing lead-removing settling tank, the height-adjustable propolis standing lead-removing settling tank comprises a settling tank, wherein the settling tank is provided with a standing lead-removing settling area, a lead-removing pipe and a lead-removing interface, the lower part of the settling tank is the standing lead-removing settling area, the standing lead-removing settling area is provided with a plurality of lead-removing interfaces, and the lead-removing interfaces are connected with the lead-removing pipe. The propolis can effectively precipitate heavy metals such as lead, and propolis with high heavy metal content at the bottom can be removed after standing and precipitating; the device for removing the heavy metals from the propolis mixed liquid has the defect of poor effect of removing the heavy metals, and cannot meet the requirement of producing high-quality propolis.
Disclosure of Invention
The invention aims to overcome the defects and provide a device and a method for removing heavy metals by propolis mixed liquor, wherein the device and the method have good heavy metal removing effect and high heavy metal removing efficiency.
The device for removing heavy metal from propolis mixed liquid adopts the technical scheme that: propolis mixes liquid and gets rid of heavy metal device, including the gunbarrel, the gunbarrel below be heavy metal settling zone, have a plurality of discharge ports that set up from top to bottom in heavy metal settling zone side, the gunbarrel below have landing leg, characterized by: and the vibration device is arranged on the settling tank and is a first vibration device, the frequency of the first vibration device is 10-15 Hz, and the amplitude of the vibration device is 1-1.5 mm.
Preferably, the method comprises the following steps: the frequency of the first vibration device is 13 hz, and the amplitude of the first vibration device is 1.2 mm.
Preferably, the method comprises the following steps: and the second vibration device is arranged on the settling tank and has the frequency of 20-25 Hz and the amplitude of 0.8-1 mm.
Preferably, the method comprises the following steps: the frequency of the second vibration device is 18 Hz, and the amplitude of the first vibration device is 0.9 mm.
Preferably, a damping spring is further mounted in the middle of the supporting leg.
Preferably, a heating pipeline is arranged around the settling tank.
Preferably, a transparent window is further installed around the settling tank.
The method for removing heavy metals by using the propolis mixed solution adopts the technical scheme that: the method for removing heavy metal from propolis mixed solution comprises the steps of vibrating the propolis ethanol mixed solution for the first time in a propolis mixed solution heavy metal removing device, standing for the first time, and separating and discharging the propolis mixed solution containing heavy metal to obtain the propolis mixed solution without heavy metal.
Preferably: the frequency of the first vibration is 10-15 Hz, the amplitude of the vibration device is 1-1.5 mm, and the first rest time is 150-200 minutes of standing.
Preferably, the method comprises the following steps: the first vibration frequency was 13 hz and the second vibration amplitude was 1.2 mm.
Preferably, the method comprises the following steps: the vibration device is characterized in that the vibration device also has secondary vibration and secondary standing after primary vibration and primary standing, the frequency of the second vibration device is 20-25 Hz, the amplitude of the vibration device is 0.8-1 mm, and the secondary standing time is 150-200 minutes.
Preferably, in the process of the first heavy metal sedimentation and/or the second heavy metal sedimentation, the propolis mixed solution is kept at the temperature of 60-70 ℃.
Preferably, the method comprises the following steps: and in the process of the first heavy metal sedimentation and/or the second heavy metal sedimentation, the propolis mixed solution is kept at the temperature of 65 ℃.
The invention has the beneficial effects that: the device and the method for removing the heavy metal by the propolis mixed liquid have the advantages of good effect of removing the heavy metal and high efficiency of removing the heavy metal.
Drawings
FIG. 1 is a schematic view of the device for removing heavy metals from propolis mixed solution according to the present invention.
FIG. 2 is a graph showing the relationship between temperature, vibration and standing time in the process of removing heavy metals from the propolis mixed solution of the present invention.
Wherein, the device comprises a settling tank 1, a settling tank 2, a heavy metal settling zone 3, a discharge port 4, a supporting leg 5, a first vibration device 6, a second vibration device 7, a damping spring 8, a heating pipeline 9 and a transparent window.
Detailed Description
The invention is further described below with reference to the figures and examples.
As shown in fig. 1, the device for removing heavy metal from propolis mixed liquid comprises a precipitation tank 1, a heavy metal precipitation zone 2 is arranged below the precipitation tank, a plurality of discharge ports 3 are arranged on the side surface of the heavy metal precipitation zone, and support legs 4 are arranged below the precipitation tank, and is characterized in that: and the vibration device is arranged on the settling tank and is a first vibration device 5, the frequency of the first vibration device is 10-15 Hz, and the amplitude of the vibration device is 1-1.5 mm.
The device is arranged in such a way, the propolis mixed liquid can make the material containing heavy metal precipitate and descend in vibration, can precipitate and gather in a heavy metal precipitation area as soon as possible, then the discharge port is opened, the propolis mixed liquid containing more heavy metal is discharged, and the propolis without heavy metal (purer) is obtained, so that the aim of the invention is fulfilled.
Preferably, the method comprises the following steps: the frequency of the first vibration device is 13 hz, and the amplitude of the first vibration device is 1.2 mm.
By the arrangement, the propolis containing larger and more heavy metals is more suitable for reduction.
And the vibration device is arranged on the settling tank and is a second vibration device 6, the frequency of the second vibration device is 20-25 Hz, and the amplitude of the vibration device is 0.8-1 mm.
This device sets up like this, can realize starting the second vibrating device when using the second vibrating device, the amplitude of second vibrating device is less to the frequency is higher, and easier and contain the less propolis granule of heavy metal and form resonance for the sediment of this part propolis reaches better promotion its sediment.
Preferably, the method comprises the following steps: the frequency of the second vibration device is 23 Hz, and the amplitude of the first vibration device is 0.9 mm.
By the arrangement, the propolis containing larger and more heavy metals is more suitable for reduction.
Preferably, a damping spring 7 is further installed in the middle of the supporting leg.
This can reduce the spread of vibration to the surroundings.
Preferably, a heating pipeline 8 is arranged around the settling tank.
This device sets up like this, can realize the heating to the gunbarrel, makes propolis mixed liquid operation under suitable temperature to reach the effect of better detach heavy metal, for example keep the gunbarrel temperature to be 60 ~ 70 ℃.
Preferably, a transparent window 9 is also arranged around the sedimentation tank.
Preferably, the device also comprises a control device, wherein the control device is connected with the first vibration device and the second vibration device, and the control device is used for starting the first vibration device for 60-80 minutes and then standing for 150-200 minutes; then starting a second vibration device, wherein the control device is that the second vibration device is started for 60-80 minutes and then stands for 150-200 minutes;
preferably, the control device is further connected with a heating pipeline, and the control device enables the heating pipeline to be heated to 60-70 ℃ and keeps warm.
Example 1
Standing the propolis mixed solution for 24 hr to obtain propolis (preferably propolis) with heavy metal removed, and measuring to obtain propolis containing heavy metal 45 ppm.
Example 2
Vibrating the propolis ethanol mixed solution in a propolis mixed solution heavy metal removal device, wherein the vibration frequency is 10-15 Hz, the vibration amplitude of the vibration device is 1-1.5 mm, standing for 150-200 minutes, separating and discharging the propolis mixed solution containing heavy metals to obtain pure propolis mixed solution, and measuring the content of the heavy metals to be 30-35 ppm.
Example 3
The propolis mixed solution in the embodiment 2 is subjected to vibration and standing for the first precipitation, and then subjected to secondary precipitation after the first precipitation is completed, wherein the secondary precipitation time is 60-80 minutes, and then standing for 150-200 minutes, the frequency of a secondary heavy metal precipitation vibration device is 20-25 Hz, the amplitude of the vibration device is 0.8-1 mm, and the content of heavy metal is 25-30 ppm.
Example 4
The above examples 2 and 3 are repeated, and the content of heavy metals is reduced by keeping the propolis mixture stable at 60-70 deg.C.
Example 5
The above examples 2 and 3 are repeated, and the propolis mixture is kept stable at 65 deg.C, so that the content of heavy metals is reduced, and the quality of propolis can be ensured.
The above description is only an embodiment of the present invention, but the structural features of the present invention are not limited thereto, and any changes or modifications within the field of the present invention by those skilled in the art are covered within the scope of the present invention.

Claims (10)

1. Propolis mixes liquid and gets rid of heavy metal device, including the gunbarrel, the gunbarrel below be heavy metal settling zone, have a plurality of discharge ports that set up from top to bottom in the heavy metal side, the gunbarrel below have landing leg, characterized by: and the vibration device is arranged on the settling tank and is a first vibration device, the frequency of the first vibration device is 10-15 Hz, and the amplitude of the vibration device is 1-1.5 mm.
2. The device for removing heavy metals from propolis mixed solution according to claim 1, which is characterized in that: the frequency of the first vibration device is 13 hz, and the amplitude of the first vibration device is 1.2 mm.
3. The device for removing heavy metals from propolis mixed solution according to claim 1 or 2, which is characterized in that: and the second vibration device is arranged on the settling tank and has the frequency of 20-25 Hz and the amplitude of 0.8-1 mm.
4. The device for removing heavy metals from propolis mixed solution according to claim 1 or 2, which is characterized in that: the frequency of the second vibration device is 23 Hz, and the amplitude of the first vibration device is 0.9 mm; a damping spring is also arranged in the middle of the supporting leg; and transparent windows are also arranged around the settling tank.
5. The device for removing heavy metals from propolis mixed solution according to claim 1 or 2, which is characterized in that: and a heating pipeline is arranged around the settling tank.
6. The method for removing heavy metal from propolis mixed solution comprises vibrating propolis ethanol mixed solution in a propolis mixed solution heavy metal removing device for the first time, standing for the first time, and separating to remove the mixed solution containing heavy metal.
7. The method for removing heavy metals with the propolis mixture solution as claimed in claim 6, wherein: the frequency of the first vibration is 10-15 Hz, the amplitude of the vibration device is 1-1.5 mm, and the first rest time is 150-200 minutes of standing.
8. The method for removing heavy metals with the propolis mixture solution as claimed in claim 7, wherein: the vibration frequency of the second vibration is 23 Hz, the amplitude of the second vibration is 1.2 mm, and the second standing time is 150-200 minutes of standing.
9. The method for removing heavy metals with the propolis mixture solution as claimed in claim 8, wherein: and in the process of primary heavy metal sedimentation and/or secondary heavy metal sedimentation, the temperature of the propolis mixed solution is kept at 60-70 ℃.
10. The method for removing heavy metals with the propolis mixture solution as claimed in claim 8, wherein: and in the process of the first heavy metal sedimentation and/or the second heavy metal sedimentation, the propolis mixed solution is kept at the temperature of 65 ℃.
CN202110114249.5A 2021-01-28 2021-01-28 Device and method for removing heavy metals by propolis mixed liquid Pending CN112826007A (en)

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CN202110114249.5A CN112826007A (en) 2021-01-28 2021-01-28 Device and method for removing heavy metals by propolis mixed liquid

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Application Number Priority Date Filing Date Title
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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1720817A (en) * 2003-12-25 2006-01-18 南昌大学 Combination use of absorption and ion exchange for removing lead from propolis
CN1868312A (en) * 2005-05-25 2006-11-29 南京老山药业股份有限公司 Process of high speed centrifugal removing lead from bee-glue
CN101061834A (en) * 2006-04-29 2007-10-31 北京知蜂堂蜂产品有限公司 Method of distilling and purifying of propolis and special equipment thereof
CN103549249A (en) * 2013-10-11 2014-02-05 吕明 Purification technology for propolis
CN103876013A (en) * 2012-12-21 2014-06-25 吕艳 Purification method of propolis
CN203723367U (en) * 2014-01-21 2014-07-23 上海冠生园蜂制品有限公司 Impurity separating device
CN204426590U (en) * 2014-12-24 2015-07-01 南京老山药业股份有限公司 Height adjustable propolis leaves standstill deleading settling tank
CN206910892U (en) * 2017-05-13 2018-01-23 河南福美生物科技有限公司 A kind of beeswax separator
CN108294270A (en) * 2018-03-03 2018-07-20 贵阳学院 A kind of extraction process of propolis

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1720817A (en) * 2003-12-25 2006-01-18 南昌大学 Combination use of absorption and ion exchange for removing lead from propolis
CN1868312A (en) * 2005-05-25 2006-11-29 南京老山药业股份有限公司 Process of high speed centrifugal removing lead from bee-glue
CN101061834A (en) * 2006-04-29 2007-10-31 北京知蜂堂蜂产品有限公司 Method of distilling and purifying of propolis and special equipment thereof
CN103876013A (en) * 2012-12-21 2014-06-25 吕艳 Purification method of propolis
CN103549249A (en) * 2013-10-11 2014-02-05 吕明 Purification technology for propolis
CN203723367U (en) * 2014-01-21 2014-07-23 上海冠生园蜂制品有限公司 Impurity separating device
CN204426590U (en) * 2014-12-24 2015-07-01 南京老山药业股份有限公司 Height adjustable propolis leaves standstill deleading settling tank
CN206910892U (en) * 2017-05-13 2018-01-23 河南福美生物科技有限公司 A kind of beeswax separator
CN108294270A (en) * 2018-03-03 2018-07-20 贵阳学院 A kind of extraction process of propolis

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Address after: 100192 3-38, 3 / F, 26 Houtun South Road, Haidian District, Beijing

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Address before: 461500 yijianfeng product research institute, east of future road, Weiwu Road industrial cluster, Changge City, Xuchang City, Henan Province

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Application publication date: 20210525