CN112796145B - Moss scented cigarette paper, its preparation method and use - Google Patents
Moss scented cigarette paper, its preparation method and use Download PDFInfo
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- CN112796145B CN112796145B CN202110145265.0A CN202110145265A CN112796145B CN 112796145 B CN112796145 B CN 112796145B CN 202110145265 A CN202110145265 A CN 202110145265A CN 112796145 B CN112796145 B CN 112796145B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/02—Head boxes of Fourdrinier machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F3/00—Press section of machines for making continuous webs of paper
- D21F3/02—Wet presses
- D21F3/10—Suction rolls, e.g. couch rolls
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F5/00—Dryer section of machines for making continuous webs of paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/02—Material of vegetable origin
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention discloses a preparation method of moss scented cigarette paper, which takes finished moss scented cigarette paper as a reference and comprises the following components in parts by mass: fiber: 55-70 parts of filler: 30-45 parts of a combustion improver: 0.5-1 part of characteristic spice and 0.5-1.5 parts of special spice; the preparation method of the moss scented cigarette paper comprises the steps of pulping, forming, embossing, drying, soaking in a combustion improver, drying and rewinding, characteristic fragrance coating, drying, winding, slitting, packaging and the like. The invention also discloses the moss faint scent cigarette paper prepared by the preparation method and application of the moss faint scent cigarette paper in improving the characteristic cigarette fragrance of side-stream smoke and improving the smoking quality of mainstream smoke.
Description
Technical Field
The invention belongs to the technical field of tobacco, and particularly relates to moss faint scent cigarette paper, a preparation method thereof and application of the moss faint scent cigarette paper in endowing sidestream characteristic cigarette fragrance and improving mainstream smoke suction quality.
Background
The common cigarette paper, namely cigarette coil paper, is an important material for forming cigarette products and mainly plays a role in wrapping tobacco shreds. Meanwhile, because the cigarette paper participates in cigarette combustion, the cigarette paper has important influence on the sensory quality of cigarette smoking, the release amount of mainstream smoke and side stream and the like.
The common cigarette paper mainly comprises plant fibers, inorganic filler in the structure of the plant fibers and a combustion regulator. Common plant fibers comprise wood pulp fibers and hemp pulp fibers, and the using amount of the common plant fibers is 65-75% of the mass of the cigarette paper. The inorganic filler is mainly calcium carbonate, and the dosage of the inorganic filler is usually 25 to 35 percent of the mass of the cigarette paper. The burn modifier is typically a metal salt of an organic acid, which is added after paper formation, typically in an amount of 0.5% to 3.0% by mass of the wrapper.
The cigarette paper is one of the main auxiliary materials of the cigarette, and compared with the forming paper and the tipping paper, the most important difference is that the cigarette paper participates in the combustion of the whole cigarette. The wood pulp fiber and the hemp pulp fiber contained in the common cigarette paper can generate wood smell in the burning process of the cigarette, and have certain negative influence on the sensory quality of the cigarette. Therefore, optimizing and improving the performance of the cigarette paper, enabling the cigarette paper to play a positive role in the combustion process, reducing the negative influence of the cigarette paper in the combustion process and being the key for improving the quality and the performance of the cigarette paper. In recent years, with the pursuit of cigarette enterprises on differentiation and individuation of cigarette products, stable aroma substances are added into cigarette paper, so that the cigarette paper has special aroma, or the sensory comfort of cigarette smoking is improved, and the cigarette paper is an important direction for innovation and quality improvement of the cigarette paper. When the aromatized and flavored cigarette paper is combusted, the aroma components in the aromatized and flavored cigarette paper are released to become a part of the mainstream smoke of the cigarette, and the function of adjusting and modifying the smoke can be realized.
To achieve this effect, some exploration practices exist in the industry. The patent CN201510810210.1 is an aloe cigarette paper and a preparation method thereof, wherein, the aloe and the cigarette paper raw material wood pulp fiber are mixed to be pulped, papermaking and cut into the cigarette paper. In patent CN201410251024.4, a manner of adding tobacco oil-impregnated powder by sizing is adopted to add spice into the cigarette paper. Patent CN201710366803.2 starts from selection of new flavors and application parts, and adds latent flavor to the front end of cigarette by dip coating, spray coating or stamping to prepare a cigarette product with prominent chewing flavor.
At present, cigarette paper used in the industry is flavored mainly in a pulping and pulping process or is added by spraying at a specific position. These methods have the following disadvantages: 1. in the production process of cigarettes, the temperature in the drying link can reach 100 ℃, and partial spices volatilize and dissipate, so that the quality stability of the flavored cigarette paper is influenced, and the problems of high production cost, poor product stability and the like are caused. 2. In the storage process of the flavored cigarette paper or the circulation process after the cigarette is made, the oxidation and deterioration of partial components and the like can occur. 3. The flavoring purpose of the prior art cigarette paper is to adjust or enhance the sensory effect of the tobacco aroma of the mainstream smoke, without concern for the sensory effects of sidestream smoke aroma. And the enhancement of the sensory effect of the cigarette aroma of the side-stream smoke can bring pleasant smell to surrounding non-smoking people, thereby creating a better environment for the non-smoking people.
The invention is provided for solving the problems and developing the aromatized and flavored cigarette paper.
Disclosure of Invention
The invention aims to solve the problems that cigarette paper aroma source substances are not stable enough to influence the quality stability of cigarette paper in the prior art and the cigarette aroma of sidestream smoke is not concerned. The moss-fragrant cigarette paper provided by the invention has characteristic side-stream cigarette fragrance, and the cigarette fragrance of mainstream smoke has a function of coordinating with the original fragrance of tobacco, so that the comfort of smoking sense of the cigarette is improved. The preparation method of the moss scented cigarette paper is simple, and the obtained cigarette paper is stable in quality and controllable in cost.
The technical scheme of the invention is as follows:
the invention discloses a preparation method of moss scented cigarette paper, which takes finished moss scented cigarette paper as a reference and comprises the following components in parts by mass: fiber: 55-70 parts of filler: 30-45 parts of a combustion improver: 0.5-1 part of characteristic spice and 0.5-1.5 parts of special spice; the preparation method of the moss scented cigarette paper comprises the following steps:
(1) circularly pulping the fibers, and then fully mixing the obtained fiber pulp with the filler which is made into pulp in advance to make pulp to obtain mixed pulp;
(2) forming the mixed slurry obtained in the step (1) on a wire section of a head box of a long-wire paper machine, and introducing the semi-wet paper web into a pressing section of the paper machine through a vacuum paper-leading roll after the paper web is formed to be dehydrated to obtain the semi-wet paper web with certain humidity;
(3) impressing the semi-wet paper web obtained in the step (2) between the stainless steel roller printed with the ribs and the back pressure rubber roller, so that the ribs on the stainless steel roller are transferred to the semi-wet paper web;
(4) introducing the rib-printed semi-wet paper web obtained in the step (3) into a pre-drying and drying treatment, and drying the paper web to a paper web with the dryness of about 85-90 wt%;
(5) introducing the paper web obtained in the step (4) into a wet glue pressing part through a paper guide roll, and soaking the two sides of the paper web with a solution of a combustion improver to obtain the paper web soaked by the combustion improver;
(6) drying the paper web soaked by the combustion improver obtained in the step (5), and rewinding to obtain a paper web roll;
(7) placing the paper web roll obtained in the step (6) on a coating device, and coating by using a coating liquid containing characteristic perfume to obtain a paper web coated with perfume;
(8) and (5) drying, rolling, slitting and packaging the paper web coated with the spices obtained in the step (7) to obtain the fragrant moss cigarette paper.
Preferably, the characterizing fragrance is: two or more of orcinol glucoside, fructus Jujubae tincture, tree moss absolute oil/tree moss extract, oak moss absolute oil, and Yunnan tobacco extract.
Preferably, the characteristic perfume quality composition is: (A) 0.5-1 part of tree moss extract, 0.05-0.2 part of oak moss absolute and 0.2-1.0 part of Yunnan tobacco extract; or (B) orcinol glucoside 0.2-0.5, tree moss absolute oil 0.2-0.5, and Chinese date tincture 0.5-1.0; or (C) tree moss extract 0.5-1, and mogroside 0.5-1.0; or (D) tree moss absolute 0.2-0.5, oak moss absolute 0.05-0.2, and fructus Jujubae tincture 0.5-1.0.
Preferably, the preparation method of the coating liquid containing the characteristic perfume in the step (7) is as follows: dissolving the characteristic perfume into a solvent containing 40-70wt% of ethanol, adding 0.5-2wt% of glyceryl triacetate as a cosolvent, and mixing to completely dissolve the characteristic perfume to obtain the coating liquid containing the characteristic perfume. The effective coating rate (applied mass fraction) of the characteristic spice in the coating liquid on the cigarette paper is 0.5-1.5 percent, namely the characteristic spice is 0.5-1.5 percent of the finished moss fragrant cigarette paper by weight based on the finished moss fragrant cigarette paper.
Preferably, the filler is light calcium carbonate; the combustion improver is organic acid metal salt;
preferably, the organic acid metal salt is one or a combination of two or more of potassium citrate, potassium malate, potassium lactate and potassium acetate.
Preferably, the drying temperature of step (6) is 80-120 ℃.
Preferably, the drying temperature of step (8) is 70-90 ℃.
The second aspect of the invention discloses the moss scented cigarette paper prepared by the preparation method.
Preferably, the quantitative amount of the moss scented cigarette paper is 25-45g/cm 2 And the air permeability is 30-100 Kelas tower.
The third aspect of the invention discloses application of the moss faint scent cigarette paper in improving the sensory effect of the cigarette fragrance of side-stream smoke.
The invention has the beneficial effects that:
1. the moss scented cigarette paper provided by the invention adopts a perfuming mode of secondary coating, and solves the problems of unstable spice and unobvious style characteristics in the cigarette paper.
2. The flavoring raw materials selected by the moss-fragrant cigarette paper are heat-stable, have the function of coordinating with the original fragrance of tobacco, can be used for blending fragrance which highlights different cigarette style characteristics, and improve the smoking sensory comfort. The flavoring raw materials selected by the invention include orcinol glucoside, jujube tincture, tree moss absolute oil/tree moss extract, oak moss absolute oil and Yunnan tobacco extract, any two or more of which can be designed and selected according to the style characteristics of cigarettes, and the flavoring raw materials can be flexibly applied and matched with corresponding flavors.
3. According to the invention, characteristic components such as the moss melanin and the like are detected in the pyrolysis product of the moss fragrant cigarette paper by using the selected perfuming raw materials, so that main stream smoke and side stream smoke have characteristic fragrance, the brand recognition degree can be improved, and the product homogenization phenomenon is avoided.
4. The moss-fragrant cigarette paper can improve the sensory effect of cigarette fragrance of side-stream smoke. Compared with the common cigarette paper control sample, the main side flow smoke components of the moss scented cigarette paper disclosed by the invention are greatly changed, and particularly, the quantitative result of the moss melanin in the side flow smoke is greater than the detection value in the main flow smoke. When the cigarette filter tip is used for smoking cigarette finished products, the characteristic aroma of side-stream smoke can bring pleasant smell to surrounding non-smoking people, and a better environment is created for the non-smoking people.
5. Compared with the traditional cigarette flavoring mode, the flavoring mode of the moss-fragrant cigarette paper is more controllable and more uniform; the selected characteristic fragrance does not depend on the leaf group formula, and the difficulty of leaf group and spice formula is reduced. The quality of products processed in different places of cigarette brands is better guaranteed; meanwhile, the use value of low-grade tobacco leaves is improved, and the dependence of high-grade cigarettes on high-price hemp pulp cigarette paper is reduced.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described below with reference to specific embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention. The experimental methods in the following examples, which are not specified under specific conditions, are generally performed under conventional conditions. Unless otherwise indicated, the percentages and parts are by mass.
Example 1
A moss scented cigarette paper takes a finished moss scented cigarette paper as a reference and comprises the following components in parts by mass: fiber: 60 parts of filler light calcium carbonate: 37 parts, combustion improver potassium citrate, potassium malate, potassium lactate and/or potassium acetate: 1 part, and 1.5 parts of a characteristic spice; the preparation method of the moss scented cigarette paper comprises the following steps: (1) circularly pulping the fibers, and then fully mixing the fiber pulp with the previously prepared pulpy calcium carbonate to make the mixture into mixed pulp; (2) forming the mixed slurry obtained in the step (1) through a head box of a fourdrinier paper machine on a wire section, and introducing the semi-wet paper web into a pressing section of the paper machine through a vacuum paper-leading roller after the paper web is formed to be dehydrated to obtain the semi-wet paper web with certain humidity; (3) impressing the semi-wet paper web obtained in the step (2) between a stainless steel roller printed with ribs and a back pressure rubber roller to transfer the ribs on the stainless steel roller to the semi-wet paper web; (4) introducing the ribbed semi-moist paper web obtained in step (3) into a pre-drying and drying treatment to dry the paper web to a dryness of about 85 wt%; (5) introducing the paper web obtained in the step (4) into a wet glue pressing part through a paper guide roll, and soaking the two sides of the paper web with an aqueous solution of a combustion improver potassium citrate to obtain the paper web soaked by the combustion improver potassium citrate; (6) drying and rewinding the paper web soaked by the combustion improver potassium citrate in the step (5) at 100 ℃ to obtain a paper web roll; (7) placing the paper web roll obtained in the step (6) on a coating device, and coating by using a coating liquid containing characteristic perfume to obtain a paper web coated with perfume; (8) and (4) drying the paper web coated with the spice obtained in the step (7) at 80 ℃, rolling, slitting and packaging to obtain the moss fragrant cigarette paper. Wherein the characteristic perfume is as follows: two or more of orcinol glucoside, fructus Jujubae tincture, tree moss absolute, tree moss extract, oak moss absolute, and Yunnan tobacco extract.
In the embodiment, a characteristic spice formula (A) including 1.0 part by mass of tree moss extract, 0.2 part by mass of oak moss absolute and Yunnan tobacco extract0.8. The preparation method of the coating liquid comprises the following steps: dissolving the perfume into a solvent containing ethanol of 70wt%, adding 1.0wt% of glyceryl triacetate as a cosolvent, and mixing to completely dissolve the characteristic perfume to obtain the coating liquid containing the characteristic perfume. The obtained cigarette paper has a gram weight of 35 g/m 2 Air permeability is 60 Kelas Tower (CU).
Example 2
The difference from the example 1 is that the formula of the spice (in parts by mass) is as follows (B), orcinol glucoside is 0.2, tree moss absolute is 0.2, and Chinese date tincture is 0.5. The obtained cigarette paper has a gram weight of 30g/m 2 And the air permeability is 50CU.
Example 3
The difference from the example 1 is that the formula of the spice (in parts by mass) is as follows (C), namely tree moss extract 0.5, and mogroside 1.0. The gram weight of the obtained cigarette paper is 40 g/m 2 The air permeability was 70CU.
Example 4
The difference from the example 1 is that the formula (parts by weight) of the perfume is as follows (D), 0.2 of tree moss absolute, 0.1 of oak moss absolute and 0.5 of Chinese date tincture. The gram weight of the obtained cigarette paper is 33 g/m 2 And the air permeability is 60CU.
Example 5: testing
The moss scented cigarette paper and the control sample common cigarette paper of example 1 were wrapped with tobacco shreds respectively and rolled into cigarettes for analysis and test. The same applies except for the different cigarette papers.
The analysis method comprises the following steps: method for analyzing smoke components of cigarettes by adopting pyrolysis analysis
(I) pyrolysis analysis method
The pyrolysis experiment was carried out with reference to YQ/T-79 2016 tobacco additive thermal cracking specification, which is described in detail below:
(1) Pyrolysis conditions
Pyrolysis temperature-rising program: the initial temperature was 50 ℃ and was raised at 30 ℃/s to set pyrolysis temperatures of 300 ℃, 600 ℃ and 900 ℃ for 5 s each.
Pyrolysis atmosphere: 9 (V/V) oxygen/nitrogen mixture gas.
Gas flow rate: 70 mL/min.
Pyrolysis apparatus valve box temperature: 280. DEG C.
Pyrolysis apparatus transmission line temperature: 280. DEG C.
Cold trap trapping temperature: -60 ℃.
Cold trap sample introduction conditions: the temperature is increased from-60 ℃ to 280 ℃ within 5 min.
A cold trap system: silicon oxide glass wool approximately 2cm long was loaded from both ends to the center of the stainless steel tube.
(2) GC-MS conditions
The chromatographic column is an elastic quartz capillary column; the stationary phase is 5% of phenyl-95% of methyl polysiloxane; the specification is [60m (length) × 0.25mm (inner diameter) × 1.0 μm (film thickness) ];
carrier gas flow, 1.5mL/min;
the split ratio is 100;
heating to 50 deg.C for 4 min, heating to 200 deg.C at a rate of 4 deg.C/min, heating to 280 deg.C at a rate of 10 deg.C/min, and maintaining for 15 min;
mass spectrometry transmission line temperature: 280. DEG C;
ion source temperature, 230 ℃;
the temperature of the quadrupole rods is 150 ℃;
the mass scanning range is 29-450 amu;
(3) Data processing
Peak area correction was performed using sample mass and qualitative search was performed using the NIST 2014 mass spectral library.
(II) flue gas analysis method
(A) Instruments and reagents
Cerulean SM405-SV model sidestream smoking machines; agilent 6890-5973 gas chromatography-mass spectrometer; buchi R-210 type rotary evaporator.
Elastic quartz capillary chromatographic column: DB-5MS 30m 0.25mm 0.25 μm.
Methanol, dichloromethane, deuterated benzene and phenethylacetate are all chromatographically pure.
(B) Collecting and pretreating side stream smoke total particulate matter
Before the cigarette experiment, the cigarettes are balanced for 48 hours under the conditions of (22 +/-1) DEG C and relative humidity (60 +/-2)% and then are sorted by weight and suction resistance to pick out uniform test cigarettes.
Smoking cigarettes with SM405-SV type sidestream smoking machine, and the specific method refers to YC/T185-2004. Each glass fiber filter sheet collects 3 cigarette side stream smoke.
The fishtail cover is taken down, 20mL of methanol is taken, and the fishtail cover is cleaned by sucking with a dropper. The methanol solution was collected in a 100mL Erlenmeyer flask. The collected methanol solution was subjected to vacuum (55 ℃ C., 300 mbar) and an internal standard solution was added and directly analyzed by GC/MS.
(C) Collection and pretreatment of total particulate matter in mainstream smoke
a. Flue gas trapping
The sample cigarette is balanced in the environment of (22 plus or minus 1) DEG C and relative humidity (60 plus or minus 2)% for 48h, and cigarettes of (average mass plus or minus 0.015) g and (average suction resistance plus or minus 49) Pa are selected as test samples.
Smoking cigarettes with a linear smoking machine, smoking 10 cigarettes in each group, trapping particulate matters of mainstream smoke of the cigarettes by using a Cambridge filter disc with the diameter of 44 mm, connecting two serially connected absorption bottles behind the trap, wherein each absorption bottle contains 10mL of methanol solution, and trapping gas-phase components of the mainstream smoke under the condition of low temperature (dry ice/isopropanol bath).
b. Analysis of the particle phase component
Putting a Cambridge filter for trapping particulate matters of 10 cigarettes in a 4mL sample bottle, adding 3mL dichloromethane extractant, accurately adding 100 mu L internal standard solution (2 mg/mL), sealing, performing ultrasonic extraction for 30 min, taking extract, filtering through a 0.45 mu m microporous filter membrane, performing GC-MS analysis on the filtrate, and Selecting Ion Monitoring (SIM) to perform quantitative analysis and detection on target components.
c. Gas phase composition analysis
After smoking the cigarettes, respectively smoking the absorption tubes in the two absorption bottles for 5 times by using an ear washing ball for cleaning, accurately adding 100 mu L of internal standard solution into each absorption bottle, uniformly stirring, and uniformly mixing 1mL of solution in each absorption bottle for GC/MS analysis. The internal standard solution is a double internal standard solution of deuterated benzene and phenethylacetate. The DB-624 column method uses deuterated benzene as an internal standard, and the DB-5MS column method uses phenethyl acetate as an internal standard.
d. Chromatography mass spectrometry
Taking a gas particle phase sample in duplicate, and respectively carrying out sample injection analysis on DB-5MS and DB-624 columns, wherein the specific chromatographic mass spectrometry analysis conditions are as follows: DB-5MS (60 m × 1.0 μm × 0.25 mm) method:
temperature programming: heating from 60 deg.C to 250 deg.C at a rate of 2 deg.C/min, heating to 290 deg.C at a rate of 5 deg.C/min, and maintaining for 20 min; sample injection amount: 1 mu L of the solution; sample inlet temperature: 290 ℃; the split ratio is as follows: 10:1; carrier gas: he, flow rate: 1.5mL/min; transmission line temperature: 290 ℃; an ionization mode: EI; ion source temperature: 230. DEG C; ionization energy: 70eV; quadrupole rod temperature: 150 ℃; mass spectrometry mass scan range: 26 to 400 amu; a monitoring mode: a full scan mode and a selective ion scan mode.
Timing events: CH2Cl2, 0min detector open; 5min detector is closed; the detector is turned on for 6 min; CH3OH, 0min detector is opened; 4 min detector is closed; 5:00 The min detector is turned on.
DB-624 (60 m × 1.4 μm × 0.25 mm) method:
temperature programming: keeping the temperature at 40 ℃ for 30 min, then heating to 160 ℃ at the speed of 2 ℃/min, keeping the temperature for 1 min, heating to 240 ℃ at the speed of 5 ℃/min, and keeping the temperature for 10 min; sample introduction amount: 1 mu L of the solution; sample inlet temperature: 220 ℃; the split ratio is as follows: 10:1; carrier gas: he, flow rate: 1.0mL/min, transmission line temperature: 240 ℃; an ionization mode: EI; ion source temperature: 230 ℃; ionization energy: 70eV; temperature of the quadrupole rods: 150 ℃; mass spectrometry mass scan range: 20 to 350amu; and (3) monitoring mode: a full scan mode and a selective ion scan mode.
Timing events: dichloromethane, 0min detector open; 12; 13 min detector on; methanol, 0min detector open; 11, 70 min detector is closed; 13 min detector was turned on.
The detection results are as follows:
the pyrolysis results of the moss scented cigarette paper at different temperatures are shown in table 1 below.
As can be seen from Table 1, at 300 ℃, triacetin was detected in the pyrolysis product of the moss scented cigarette paper, and no other components were detected. The added perfume is shown to volatilize little at 300 ℃, and the detected glyceryl triacetate is taken as a perfuming cosolvent. At 600 ℃ and 900 ℃, lichenin monomethyl ether and orcinol are detected in the pyrolysis products of the moss scented cigarette paper besides the triacetin. The orcinol monomethyl ether and orcinol are characteristic components of the oak moss, which shows that the moss faint scent cigarette paper can release the characteristic components of spices during high-temperature pyrolysis. According to the peak area, the area of orcinol and orcinol monomethyl ether in the pyrolysis product at 900 ℃ is lower than that of the peak area at 600 ℃, which shows that other thermal reactions can occur between orcinol and orcinol monomethyl ether during the high-temperature pyrolysis at 900 ℃, and the release amount is reduced.
The differences of pyrolysis products of the moss faint scent cigarette paper and the control sample common cigarette paper at 300 ℃, 600 ℃ and 900 ℃ are respectively compared.
As can be seen from Table 2, at 300 ℃ the cigarette paper with faint scent of moss was detected as triacetin, and the control sample was detected as no volatile component.
As can be seen from Table 3, compared with the control sample, the moss faint scent cigarette paper contains 3 more compounds in 600 ℃ pyrolysis products, namely lichen diphenol monomethyl ether, orcinol and glyceryl triacetate; wherein lichen diphenol monomethyl ether and orcinol are characteristic components of tree moss, and glyceryl triacetate is a perfuming cosolvent.
In addition, other pyrolysis products of the moss scented cigarette paper are different from those of the moss scented cigarette paper. The release amount of 3-hydroxybenzaldehyde, 2, 3-pentanedione, butanedialdehyde, butyrolactone, acetoin, 2 (5H) -furanone, propionic acid, formic acid, 3-methyl-2-cyclopentene-1-one, 2, 3-dimethyl-2-cyclopentene-1-one and the like in the pyrolysis product of the moss scented cigarette paper is high, while the release amount of 1, 4.
As can be seen from Table 4, compared with the control sample, the 900 ℃ pyrolysis product of the moss scented cigarette paper also contains 3 more compounds, namely lichen diphenol monomethyl ether, orcinol and triacetin. Wherein lichenin monomethyl ether and orcinol are characteristic components of tree moss, and glyceryl triacetate is perfuming cosolvent.
Other pyrolysis products of the moss scented cigarette paper are also different from the control. The release amount of components such as 1-hydroxyacetone, formic acid, 2, 3-dihydroxybenzaldehyde, 2, 3-pentanedione, hydroxyacetaldehyde, 3-hydroxybenzaldehyde, p-diphenol, 2-hydroxybutyrolactone, 2-hydroxy-3, 4-dimethyl-2-cyclopentene-1-one, acetoin, 2-pentanone, butanedialdehyde and the like in the paper pyrolysis products in the moss-scented cigarette is high; and the release amounts of 2-methylphenol, p-xylene, 1,4, 3, 6-dianhydro-glucopyranose, 2, 3-dihydro-1-indanone, 3-methylphenol, cyclopentanone, 4-methyl-5H-furan-2-one, etc. are low.
The flue gas analysis results were as follows:
(1) Sidestream smoke increasing composition
The sidestream smoke add-on composition is given in table 5 below. It mainly contains the marked components of oak moss, such as moss melanin.
Sidestream smoke reduction composition:
sidestream smoke has fewer components to reduce, see table 6 below. Mainly include 2-methyl-6-propylphenol, methyl linoleate 2, 5-furan-dicarbaldehyde, methyl 3-furancarboxylate, 4-cyclopentene-1, 3-dione, 4-hydroxybenzaldehyde, 5-hydroxymethylfurfural, 4-methylbenzaldehyde and the like.
(2) Increased composition of mainstream smoke
The increased composition of mainstream smoke is shown in table 7 below. Mainly contains melanoidin, 2, 3-dihydroxy-propionic acid, 5-methyl-3H-furan-2-one, 2-furancarbinol, glycolic acid, linolenic acid, butyrolactone and other components.
Reduced mainstream smoke composition:
the constituents of the mainstream smoke that are reduced are shown in Table 8 below, and mainly include 2-carbonyl propionic acid, pyrrole, gulonolactone, hydroxy butanone, pyrazine, 2, 5-dimethyl-1, 4-benzenediol, 2, 4-dihydroxy-2, 5-dimethyl-3-dihydro-furan-3-one toluene, 2-methyl-6-propylphenol, 2-hydroxy-2-cyclopenten-1-one, isopentyl cyanide, and the like.
According to the tests, characteristic components such as the moss melanin and the like are detected in the pyrolysis product of the moss scent cigarette paper, the smoke components of the main side stream and the side stream are greatly changed, and the proportion of the moss melanin in the smoke of the main side stream and the smoke of the side stream is 1. Therefore, the sidestream smoke of the moss scented cigarette paper can obviously feel green and fragrant smell, costustoot, paste smell and the like brought by the characteristic components of the tree moss, and the sensory intensity is even stronger than that of the mainstream smoke; these flavors in the sidestream smoke can impart a pleasant smell to surrounding non-smoking persons, creating a better environment for the non-smoking persons.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are given by way of illustration of the principles of the present invention, but that various changes and modifications may be made without departing from the spirit and scope of the invention, and such changes and modifications are within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (10)
1. The preparation method of the moss scented cigarette paper is characterized in that the finished moss scented cigarette paper is taken as a reference and comprises the following components in parts by mass: fiber: 55-70 parts of filler: 30-45 parts of a combustion improver: 0.5-1 part of characteristic perfume 0.5-1.5 parts; the preparation method of the moss scented cigarette paper comprises the following steps:
(1) circularly pulping the fibers, and then fully mixing the obtained fiber slurry with the filler which is made into slurry in advance to make the slurry into mixed slurry;
(2) forming the mixed slurry obtained in the step (1) on a wire section of a head box of a long-wire paper machine, and introducing the semi-wet paper web into a pressing section of the paper machine through a vacuum paper-leading roll after the paper web is formed to be dehydrated to obtain the semi-wet paper web with certain humidity;
(3) impressing the semi-wet paper web obtained in the step (2) between a stainless steel roller printed with ribs and a back pressure rubber roller to transfer the ribs on the stainless steel roller to the semi-wet paper web;
(4) introducing the ribbed semi-wet paper web obtained in step (3) into a pre-drying and drying treatment to dry the paper web to a dryness of 85-90 wt%;
(5) introducing the paper web obtained in the step (4) into a wet glue pressing part through a paper guide roller, and soaking the two sides of the paper web with a solution of a combustion improver to obtain the paper web soaked by the combustion improver;
(6) drying the paper web soaked by the combustion improver obtained in the step (5), and rewinding to obtain a paper web roll;
(7) placing the paper web roll obtained in the step (6) on a coating device, and coating by using a coating liquid containing characteristic perfume to obtain a paper web coated with perfume;
(8) and (4) drying, rolling, slitting and packaging the paper web coated with the spice obtained in the step (6) to obtain the fragrant moss cigarette paper.
2. The method of claim 1, wherein the characterizing flavor is: two or more of orcinol glucoside, fructus Jujubae tincture, tree moss absolute oil/tree moss extract, oak moss absolute oil, and Yunnan tobacco extract.
3. The method of claim 2, wherein the characteristic flavor profile is: (A) Tree moss extract 0.5-1, oak moss absolute 0.05-0.2, and Yunnan tobacco extract 0.2-1.0; or (B) orcinol glucoside 0.2-0.5, tree moss absolute oil 0.2-0.5, and Chinese date tincture 0.5-1.0; or (C) tree moss extract 0.5-1, and mogroside 0.5-1.0; or (D) tree moss absolute 0.2-0.5, oak moss absolute 0.05-0.2, and fructus Jujubae tincture 0.5-1.0.
4. The method according to claim 1, wherein the characteristic flavor-containing coating liquid of step (7) is prepared by: dissolving the characteristic perfume into a solvent containing 40-70wt% of ethanol, adding 0.5-2wt% of glyceryl triacetate as a cosolvent, and mixing to completely dissolve the characteristic perfume to obtain the coating liquid containing the characteristic perfume.
5. The method according to claim 1, wherein the filler is light calcium carbonate; the combustion improver is organic acid metal salt; the organic acid metal salt is one or the combination of more than two of potassium citrate, potassium malate, potassium lactate and potassium acetate.
6. The production method according to claim 1, wherein the drying temperature in the step (6) is 80 to 120 ℃.
7. The method according to claim 1, wherein the drying temperature in the step (8) is 70 to 90 ℃.
8. A moss scented cigarette paper prepared by the preparation method according to any one of claims 1 to 7.
9. The moss scented cigarette paper of claim 8, wherein the quantitative amount of the moss scented cigarette paper is 25-45g/cm 2 And the air permeability is 30-100 Kelas tower.
10. Use of the moss scented cigarette paper of claim 8 to enhance the sensory effect of the smoke notes of sidestream smoke.
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