CN112652749B - Carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon and preparation method and application thereof - Google Patents
Carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon and preparation method and application thereof Download PDFInfo
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- H01M10/00—Secondary cells; Manufacture thereof
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- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
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Abstract
The invention provides a carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon, and a preparation method and application thereof. The preparation method comprises the following steps: growing vertical graphene on the carbon cloth through PECVD reaction to obtain first carbon cloth; respectively and uniformly dispersing 2-methylimidazole and cobalt nitrate in water to obtain a first solution; adding the first carbon cloth into the first solution, mixing and stirring, reacting for 4-5h to grow Co-MOF, cleaning and drying to obtain second carbon cloth; and annealing the second carbon cloth under the protection of argon to obtain the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene. The sodium ion full cell assembled by the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene can realize good electrochemical performance.
Description
Technical Field
The invention relates to a carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon and a preparation method thereof, belonging to the technical field of alkali metal batteries.
Background
Lithium ion batteries now occupy the vast majority of the energy storage market, and have been commercialized and increasingly popular and developed due to their high energy density and stable safety factor. As is well known, lithium resources are quite scarce and unevenly distributed, and it is predicted that in 2025, the consumption of metallic lithium will exceed 20% of its production. Therefore, it is important to find an alternative alkali metal battery. In the periodic table of elements, sodium is next to the same main group of metal lithium, and since sodium ions cannot store energy in a graphite negative electrode and commercial development of the graphite negative electrode is limited, designing a novel negative electrode material of a sodium ion battery becomes a great importance.
Sodium metal anodes have also recently received much attention, mainly due to their abundance and highest theoretical capacity (1165 mAh/g). However, sodium metal anodes still suffer from three major problems in use: 1. the growth of dendrites is more; 2. coulomb efficiency is low; 3. the volume effect is large. Therefore, it is urgent to design a current collector capable of suppressing the growth of dendrites, suppressing the volume effect, and improving the coulombic efficiency.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a synthesis method and application of a carbon cloth current collector with uniformly distributed cobalt particles and vertical graphene growing thereon.
In order to solve the above technical problems, an object of the present invention is to provide a sodium ion energy storage device with high coulombic efficiency and stable cycle performance.
In order to achieve the above object, the present invention firstly provides a method for preparing a carbon cloth with vertical graphene grown thereon, in which cobalt particles are uniformly distributed, wherein the method comprises the following steps:
growing vertical graphene on the carbon cloth through PECVD reaction to obtain first carbon cloth;
respectively and uniformly dispersing 2-methylimidazole and cobalt nitrate in water to obtain a first solution;
adding the first carbon cloth into the first solution, mixing and stirring, reacting for 4-5h to grow Co-MOF, cleaning and drying to obtain second carbon cloth;
and annealing the second carbon cloth under the protection of argon to obtain the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene.
The carbon cloth with the uniformly distributed cobalt particles and the vertical graphene grows on the carbon cloth, the cobalt particles are uniformly distributed, and the vertical graphene grows and is uniformly distributed; the method is used for sodium metal cathode protection of a sodium ion energy storage device and has the advantages of uniform sodium metal deposition and less dendritic crystal growth. The carbon cloth has good conductivity and mechanical stability, direct melting of sodium is facilitated, volume expansion caused by sodium metal deposition stripping can be well relieved by the vertical graphene structure, a large number of deposition sites are brought to sodium metal deposition due to uniform distribution of cobalt particles, uniform deposition of sodium metal is promoted, and good electrochemical performance of the finally assembled sodium ion full cell is achieved.
The preparation method of the carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon specifically comprises the following steps:
(a) placing carbon cloth in a CVD furnace, vacuumizing, introducing argon and methane, growing vertical graphene at the temperature of 500-plus-600 ℃ by PECVD to obtain first carbon cloth, respectively and uniformly dispersing 2-methylimidazole and cobalt nitrate in water, and mixing to obtain a first solution;
(b) putting the first carbon cloth into the first solution, magnetically stirring, reacting for 4-5h to perform Co-MOF growth, taking out, cleaning and drying to obtain a second carbon cloth; and placing the second carbon cloth in a tubular furnace, and annealing under the protection of argon to obtain the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene.
In a specific embodiment of the invention, the PECVD reaction is carried out by disposing the carbon in a CVD furnace, introducing 100-150sccm argon gas and 10-20sccm methane, vacuumizing to below 3Pa, and growing the vertical graphene for 0.5-1h at a heating rate of 1-20 ℃/min to 500-600 ℃.
In one embodiment of the invention, the molar mass ratio of 2-methylimidazole to cobalt nitrate is 6-8: 1.
In one embodiment of the invention, the annealing treatment is calcination for 2.5-3.5h at a temperature rise rate of 1-20 ℃/min to 750 ℃ -850 ℃.
The invention also provides the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene growing thereon, which is prepared by the preparation method of the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene growing thereon.
The carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon can be applied to sodium ion energy storage devices.
The invention also provides a sodium ion energy storage device which comprises a component made of the carbon cloth which is uniformly distributed with the cobalt particles and is grown with the vertical graphene. The sodium ion energy storage device comprises a sodium metal symmetric battery and a sodium ion full battery.
The sodium metal symmetric battery containing the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene is prepared by the following steps:
(1) preparing a pole piece: and melting the sodium block into a liquid state at 200 ℃, immersing the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene in the liquid sodium, and cooling the carbon cloth after the liquid sodium is adsorbed on the carbon cloth pole piece for later use.
(2) The sodium metal symmetric battery is assembled by sequentially arranging a positive electrode shell, carbon cloth which is uniformly distributed with cobalt particles of sodium on melting and is provided with vertical graphene, a glass fiber diaphragm, carbon cloth which is uniformly distributed with cobalt particles of sodium on melting and is provided with vertical graphene, a gasket, an elastic sheet and a negative electrode shell.
The sodium ion full cell containing the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene is prepared by the following steps:
(1) preparing a positive pole piece: dispersing 9mmol of sodium hydroxide, 6mmol of ammonium metavanadate, 9mmol of ammonium dihydrogen phosphate and 5mmol of citric acid in deionized water, and stirring in an oil bath for one hour at 80 ℃ to obtain dark blue gel; then drying the mixture in vacuum at 40 ℃ for 12 hours; and finally annealing in an argon atmosphere, wherein the annealing is carried out for 3h at 400 ℃, then for 8h at 700 ℃, and the heating rate is 5 ℃ per minute, so that the sodium vanadium phosphate NVP is obtained finally. And (3) mixing the active substance NVP, the conductive agent super p and the binder PVDF in a mass ratio of 90:5:5, stirring, coating on an aluminum foil, and drying for later use.
(2) The sodium ion full-cell is assembled by the order of a positive electrode shell, carbon cloth (negative plate) with vertical graphene growing and uniformly distributed fused sodium-loaded cobalt particles, a glass fiber diaphragm, a vanadium sodium phosphate pole piece (positive plate), a gasket, an elastic sheet and a negative electrode shell.
According to the preparation method of the carbon cloth with the vertical graphene growing on the cobalt particles uniformly distributed, the vertical graphene grows on the carbon cloth through a chemical vapor deposition method, then Co-MOF grows on the surface of the carbon cloth through a wet chemical method, and the carbon cloth is annealed and carbonized in an argon atmosphere, so that the vertical graphene on the surface of the prepared carbon cloth is obvious in structure, the cobalt particles are uniformly distributed, and nitrogen-doped carbon is introduced; the carbon cloth with the three-dimensional network structure and the uniformly distributed cobalt particles and the vertical graphene is applied to the sodium ion energy storage device, and has the advantages of high energy density, high safety and the like. The three-dimensional structure of the carbon cloth and the vertical structure of the surface graphene are beneficial to reducing the problem of dendrite and relieving the volume effect brought by the process of sodium intercalation; meanwhile, the cobalt particles with uniform surfaces can reduce local large current, provide more nucleation sites, induce uniform deposition of sodium and inhibit growth of dendritic crystals; in addition, nitrogen-doped carbon introduced by the MOF can promote the adsorption and deposition of sodium, reduce the generation of 'dead' sodium, improve the coulombic efficiency and enhance the cycle stability.
Drawings
Fig. 1 is an SEM image of a carbon cloth grown with vertical graphene in which cobalt particles are uniformly distributed in example 1: (a) a synthetic flow chart of carbon cloth Co @ CC/VG with uniformly distributed cobalt particles and vertical graphene; (b) scanning electron microscope images of the high-power lower carbon cloth CC; (c) a scanning electron microscope image of the carbon cloth CC/VG with vertical graphene growing under high power; (d) a scanning electron microscope image of carbon cloth Co @ CC/VG with vertical graphene growing and with uniformly distributed long cobalt particles at high power; (e) d partial enlarged view of figure.
Fig. 2 is a diagram of electrochemical properties of carbon cloth with uniformly distributed cobalt particles and vertical graphene grown thereon, which is applied to a sodium metal symmetric battery after sodium melting, prepared in example 1:
(a) sodium metal symmetric cells of example 1, comparative examples 1-2 were at 1mAh cm-2Loading amount of (a), and an overpotential contrast diagram under different current densities; (b) sodium metal couple of example 1, comparative examples 1-3The battery is weighed at 1mAh cm-2Load amount of (1 mA cm)-2Comparative plot of current density overpotential and cycle time.
Fig. 3 is a graph of electrochemical performance assembled into a sodium ion full cell in example 1: (a) the sodium ion full battery charge-discharge curve chart of the embodiment 1 with Co @ CC/VG molten sodium as the negative electrode and vanadium sodium phosphate as the positive electrode; (b) the full cell rate graph of sodium ions with Co @ CC/VG molten sodium as the negative electrode and vanadium sodium phosphate as the positive electrode in example 1; (c) sodium ion full cell 0.2A g in example 1 and comparative examples 1 to 3-1Capacity at current versus graph.
Detailed Description
Example 1
The embodiment provides a synthesis method of a carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon, which comprises the following steps:
(a) placing carbon in a CVD furnace, vacuumizing, introducing 100sccm argon and 10sccm methane, growing vertical graphene under the conditions of 500-600 ℃ by 80w PECVD to obtain first carbon cloth, respectively and uniformly dispersing 0.493g of 2-methylimidazole and 0.218g of cobalt nitrate in 20ml of water, and mixing to obtain a first solution;
(b) putting the first carbon cloth into the first solution, magnetically stirring, reacting for 4-5h to perform Co-MOF growth, taking out, washing with deionized water, and drying to obtain a second carbon cloth; and (3) placing the second carbon cloth in a tubular furnace, and annealing under the protection of argon to obtain the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene (firstly, firing at 400 ℃ for 3h, then firing at 700 ℃ for 8h, and heating at the speed of 5 ℃ per minute).
The application of the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene growing on the carbon cloth in the sodium metal symmetrical battery comprises the following steps:
(1) preparing a pole piece: and melting the sodium block into a liquid state at 200 ℃, immersing the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene in 0.2mg of liquid sodium, and cooling the carbon cloth after the liquid sodium is fully adsorbed on the carbon cloth pole piece for later use.
(2) The sodium metal symmetric battery is assembled by sequentially arranging a positive electrode shell, carbon cloth which is uniformly distributed with cobalt particles of sodium on melting and is provided with vertical graphene, a glass fiber diaphragm, carbon cloth which is uniformly distributed with cobalt particles of sodium on melting and is provided with vertical graphene, a gasket, an elastic sheet and a negative electrode shell.
The application of the carbon cloth with the uniformly distributed cobalt particles and the vertical graphene growing on the carbon cloth in the sodium-ion full cell comprises the following steps of:
(1) preparing a positive pole piece: dispersing 9mmol of sodium hydroxide, 6mmol of ammonium metavanadate, 9mmol of ammonium dihydrogen phosphate and 5mmol of citric acid in deionized water, and stirring in an oil bath at 80 ℃ for one hour to obtain dark blue gel; then it was dried under vacuum at 40 ℃ for 12 hours; and finally annealing in an argon atmosphere, wherein the annealing is carried out for 3h at 400 ℃, then for 8h at 700 ℃, and the heating rate is 5 ℃ per minute, so that the sodium vanadium phosphate NVP is obtained finally. And (3) mixing the active substance NVP, the conductive agent super p and the binder PVDF in a mass ratio of 90:5:5, stirring, coating on an aluminum foil, and drying for later use.
(2) The sodium ion full-cell is assembled by the order of a positive electrode shell, carbon cloth (negative plate) with vertical graphene growing and uniformly distributed fused sodium-loaded cobalt particles, a glass fiber diaphragm, a vanadium sodium phosphate pole piece (positive plate), a gasket, an elastic sheet and a negative electrode shell.
Example 2
The embodiment provides a synthesis method and application of a carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon, which are basically the same as those in embodiment 1, and are different only in that: in step (a), 0.175g of cobalt nitrate was added.
Example 3
The embodiment provides a synthesis method and application of a carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon, which are basically the same as those in embodiment 1, and are different only in that: in step (a), the amount of cobalt nitrate added was 0.262 g.
Example 4
The embodiment provides a synthesis method and application of a carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon, which are basically the same as those in embodiment 1, and are different only in that: in the step (a), the respective dispersion solvents for 2-methylimidazole and cobalt nitrate were 10 ml.
Example 5
The embodiment provides a synthesis method and application of a carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon, which are basically the same as those in embodiment 1, and are different only in that: in the step (a), the respective dispersion solvents for 2-methylimidazole and cobalt nitrate were 30 ml.
Example 6
The embodiment provides a synthesis method and application of a carbon cloth with uniformly distributed cobalt particles and vertical graphene growing thereon, which are basically the same as those in embodiment 1, and are different only in that: in the application of the sodium metal symmetrical battery and the sodium ion full battery, the sodium fused on the carbon cloth is 0.4 mg.
Comparative example 1
The comparative example provides a synthesis method of a carbon cloth with vertical graphene, which is basically the same as that in example 1, and the application of the carbon cloth with vertical graphene in a sodium metal symmetric battery and a sodium ion full battery is completely the same as that in example 1, except that: in the step (a), after the vertical graphene grows, no Co particles grow on the surface of the vertical graphene, namely the surface of the vertical graphene is CC/VG.
Comparative example 2
The comparative example directly uses commercial carbon cloth, and the application of the carbon cloth in the sodium metal symmetric battery and the sodium ion full battery is completely the same as that in the example 1, namely CC.
Comparative example 3
In the comparative example, sodium foil was used as it is, and the application of sodium foil to the sodium metal symmetric cell and the sodium ion full cell was completely the same as in example 1, i.e., Na.
Comparative example 4
The comparative example provides a method for synthesizing carbon cloth with uniformly distributed cobalt particles and vertical graphene, which is basically the same as that in example 1, and the application of the carbon cloth with uniformly distributed cobalt particles and vertical graphene in a sodium metal symmetric battery and a sodium ion full battery is completely the same as that in example 1, except that: the amount of cobalt nitrate added in step (a) was 0.1 g.
Comparative example 5
The comparative example provides a method for synthesizing carbon cloth with uniformly distributed cobalt particles and vertical graphene, which is basically the same as that in example 1, and the application of the carbon cloth with uniformly distributed cobalt particles and vertical graphene in a sodium metal symmetric battery and a sodium ion full battery is completely the same as that in example 1, except that: the amount of cobalt nitrate added in step (a) was 0.3 g.
Comparative example 6
The comparative example provides a method for synthesizing carbon cloth with uniformly distributed cobalt particles and vertical graphene, which is basically the same as that in example 1, and the application of the carbon cloth with uniformly distributed cobalt particles and vertical graphene in a sodium metal symmetric battery and a sodium ion full battery is completely the same as that in example 1, except that: in the step (a), 5ml of the dispersion solvent for 2-methylimidazole and cobalt nitrate was used.
Comparative example 7
The comparative example provides a method for synthesizing carbon cloth with uniformly distributed cobalt particles and vertical graphene, which is basically the same as that in example 1, and the application of the carbon cloth with uniformly distributed cobalt particles and vertical graphene in a sodium metal symmetric battery and a sodium ion full battery is completely the same as that in example 1, except that: in the step (a), the respective dispersion solvents for 2-methylimidazole and cobalt nitrate were 40 ml.
Comparative example 8
The comparative example provides a sodium ion full cell system of NNMO// Na @ carbon felt.
Comparative example 9
This comparative example provides a sodium ion full cell system of NNM// Na @ rGa.
Comparative example 10
The comparative example provides a sodium ion full cell with NVP// Na @ Na2S-CTP。
Comparative example 11
This comparative example provides a sodium ion full cell with the system NVP @ C-rGO// Na @ rGO/CNT.
The data of examples 1 to 6 and comparative examples 1 to 11 were tested according to the blue system test, and the obtained data are shown in table 1.
TABLE 1
From the synthesis flow chart of fig. 1(a), it can be seen that the carbon cloth is grown with vertical graphene through the CVD process, then Co-MOF is grown on the surface of the carbon cloth, and the carbon cloth with vertical graphene grown and with uniformly distributed cobalt particles is obtained through annealing.
It can be seen from examples 1-3 and comparative examples 4-5 that the addition amount of cobalt nitrate needs to be kept in a proper range, and example 1 is the most proper addition amount, and too much or too little of cobalt nitrate affects the sodium metal symmetric battery and the sodium ion full battery because the amount of the organic ligand 2-methylimidazole is kept constant, and in the case that the organic ligand is kept constant, the metal ion donor needs to be matched with the organic ligand, otherwise incomplete reaction is caused, so that the cobalt particle growth is not uniform, the sodium dendrite growth cannot be well inhibited, and finally the electrochemical performance is attenuated.
It can be seen from examples 1, 4 to 5 and 6 to 7 that the amount of solvent water added cannot be too small, and it can be seen from comparative example 6 that when the amount of water added is too small, a large deterioration in electrochemical performance occurs. Further, the amount of water should not be too large, and 20ml is the most preferable amount in example 1. This is because when water is added too much, the solute is diluted and the Co-MOF grown on the carbon cloth becomes less, thereby reducing nucleation sites for sodium deposition, resulting in the growth of sodium dendrites; when the water is too little, the carbon cloth can not be uniformly soaked into the solution, so that the uneven growth of Co-MOF is caused, and finally the poor electrochemical performance is caused.
As can be seen from examples 1 and 6, when the amount of sodium fused onto the carbon cloth is too large, the electrochemical performance is poor, because when the amount of sodium is too large, the three-dimensional porous structure of the carbon cloth is filled with the excessive amount of sodium, and the volume effect of sodium during deposition and peeling is not alleviated.
As can be seen from example 1 and comparative example 1, the electrochemical performance is improved by the growth of cobalt particles, because the presence of cobalt particles provides more deposition sites for the deposition of sodium, and the more deposition sites can effectively reduce the growth of sodium dendrites.
As can be seen from comparative examples 1 and 2, the growth of the vertical graphene improves electrochemical performance because the three-dimensional structure of the vertical graphene can effectively inhibit the growth of sodium dendrite.
From example 1 and comparative example 3, it can be seen that our structural design greatly improves the electrochemical performance of sodium metal symmetric cells and sodium ion full cells.
As can be seen from fig. 1(b), the vertical graphene is uniformly coated on the carbon cloth fiber after being grown, and the vertical structure can effectively alleviate the volume effect of sodium in the deposition and stripping process; as can be seen from fig. 1(c), fig. 1(d) and fig. 1(e), the cobalt particles in example 1 grow uniformly, and these cobalt particles can provide a large number of uniform nucleation sites for sodium nucleation, thereby reducing dendrite generation, which is demonstrated by the good electrochemical performance of fig. 2(a) and fig. 2 (b).
The carbon cloth with uniformly distributed cobalt particles and vertical graphene growing is applied to sodium ion full batteries and has the highest capacity under the same current. Fig. 3(a) is a charge-discharge curve of a carbon cloth with vertically-grown graphene, in which cobalt particles are uniformly distributed at different currents, after melting sodium, the carbon cloth serves as a negative electrode, and vanadium sodium phosphate serves as a positive electrode, and the charge-discharge curve shows that a platform for charging and discharging vanadium sodium phosphate can be embodied under a large current, and the excellent rate performance of the full battery is embodied. FIG. 3(b) is a graph of the capacity of FIG. 3(a) at 1A g-1Under high current, the full battery can still maintain 56mAh g-1The capacity of (c). FIG. 3(c) compares example 1 to comparative examples 1-3 at 0.2A g-1The capacity under current plot, from which it can be seen that the capacity of example 1 is the highest, the cycle of example 1 is more stable than comparative examples 2-3.
The above embodiments are merely illustrative of the technical ideas and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the contents of the present invention and implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.
Claims (4)
1. A preparation method of carbon cloth with uniformly distributed cobalt particles and vertical graphene growth is applied to a sodium metal symmetric battery and a sodium ion full battery, and is characterized by comprising the following steps:
arranging carbon in a CVD furnace, vacuumizing, introducing 100sccm argon and 10sccm methane, and growing vertical graphene at 500-600 ℃ by 80w PECVD to obtain first carbon cloth;
respectively and uniformly dispersing 0.493g of 2-methylimidazole and 0.218g of cobalt nitrate in 20ml of water, and mixing to obtain a first solution;
putting the first carbon cloth into the first solution, magnetically stirring, reacting for 4-5h to perform Co-MOF growth, taking out, washing with deionized water, and drying to obtain a second carbon cloth;
placing the second carbon cloth in a tubular furnace, and annealing under the protection of argon to obtain carbon cloth with uniformly distributed cobalt particles and vertical graphene; the annealing is to burn at 400 ℃ for 3h and then at 700 ℃ for 8h, and the heating rate is 5 ℃ per minute.
2. The carbon cloth with the vertical graphene growing thereon and the uniformly distributed cobalt particles is prepared by the preparation method of the carbon cloth with the vertical graphene growing thereon and the uniformly distributed cobalt particles according to claim 1.
3. A sodium ion energy storage device comprising a component made of the carbon cloth of claim 2 in which the cobalt particles are uniformly distributed and in which vertical graphene grows.
4. The sodium ion energy storage device of claim 3, wherein the sodium ion energy storage device comprises a sodium metal symmetric cell, a sodium ion full cell.
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