CN112626630A - Preparation method and application of two-dimensional nano titanium carbide-based conductive paste - Google Patents
Preparation method and application of two-dimensional nano titanium carbide-based conductive paste Download PDFInfo
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- CN112626630A CN112626630A CN202011512691.5A CN202011512691A CN112626630A CN 112626630 A CN112626630 A CN 112626630A CN 202011512691 A CN202011512691 A CN 202011512691A CN 112626630 A CN112626630 A CN 112626630A
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- titanium carbide
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
Abstract
The invention relates to a preparation method and application of conductive slurry based on two-dimensional nano titanium carbide. Dissolving lithium fluoride in hydrochloric acid, adding titanium aluminum carbide, dispersing the obtained precipitate phase in absolute ethyl alcohol, performing ultrasonic treatment, dispersing in deionized water to obtain a dispersion liquid, performing centrifugal treatment to obtain an upper-layer titanium carbide dispersion liquid, adding a settling agent, standing to obtain a precipitate product, dispersing in a substrate solvent, and adding a dispersing auxiliary agent to obtain the two-dimensional nano titanium carbide conductive paste. The invention adopts an etching method to prepare two-dimensional nano titanium carbide nano sheets, can efficiently prepare nano titanium carbide conductive slurry through sedimentation separation, has good dispersion stability, conductivity and antistatic property, can be applied to the manufacture of conductive wires and the printing of flexible circuits, and realizes good conductivity and antistatic property of base materials.
Description
Technical Field
The invention belongs to the technical field of material preparation and application, and relates to a titanium carbide preparation method and application to textile fibers.
Background
The emerging 2D inorganic nano material Michelene (MXene) has good conductivity and hydrophilicity, and a precursor MAX (M) thereofn+1AXn) The phase ceramic is a ternary layered compound. (M is a transition metal element; A represents an element of Si or Al; X represents an element of C or N; and N is 1 to 3). Mxene has a chemical formula of Mn+1XnTXAnd T represents-OH, -F, = O and other groups on the surface of the material. Gogotsi et al first used a hydrofluoric acid solution to selectively etch the MAX phase (Ti) in 20113AlCl2) Al atomic layer to obtain ultrathin two-dimensional nano material Ti3C2TX(MXene) with graphene-like properties, monolayer thickness below 1 nm. In 2014, Ghidiu and the like use LiF and HCl to prepare Mxene, the reaction conditions are mild, a large amount of single-layer Mxene can be generated, and the method is widely adopted. Ti3C2TxThe MXene is the most widely researched MXene at present, and has wide application potential in the fields of catalyst carriers, energy storage, biochemical sensors, electromagnetic wave shielding and absorption, composite material modification and the like. Ti3C2TXDue to its high young's modulus and mechanical properties, it is used as reinforcement in composite materials, and also due to its excellent electrical conductivity, it is used to improve the electrical properties of composite materials.
Wearable electronic equipment gradually becomes the trend of life, and textiles can be manufactured into an electric conduction sensing device due to good flexibility and wearability, so that the electric conduction sensing device can capture and identify human body movement and physiological states. Conductive textiles are an important way to achieve wearing only.
The synthetic fiber is easy to generate static electricity due to poor hygroscopicity, static charge is easier to accumulate in a low-humidity environment, the accumulation of the static charge is easy to cause discomfort to people in the use of textiles, and dust is easy to adsorb, so that the use effect and experience are directly influenced. At present, three methods for improving the conductivity of the fiber and accelerating the leakage of the charge exist. The method 1 can adopt the methods of blending, interweaving or inlaying of antistatic fiber, conductive fiber and common synthetic fiber to improve the conductive capability of the fiber aggregate and overcome the electrostatic interference; in the method 2, from the material science point of view, the key of the antistatic technology of the textile lies in the research and application technology of the novel conductive fiber with low resistance, long acting and universality; method 3 is the antistatic finishing of the textile, and the key point is to select a proper antistatic finishing agent. The nanometer material can be combined with textile fiber by virtue of the advantages of stability, low (non) toxicity and the like, and plays the specific functionality of the nanometer material.
Disclosure of Invention
The invention provides a preparation method of a high-efficiency nanometer two-dimensional material with good dispersion stability, conductivity and antistatic property aiming at the problems of conductivity and antistatic property existing when the existing synthetic fiber is applied to wearable electronic equipment.
The technical scheme for realizing the aim of the invention is to provide a preparation method based on two-dimensional nano titanium carbide conductive slurry, which comprises the following steps:
(1) dissolving lithium fluoride in hydrochloric acid according to the mass concentration of 5-10%;
(2) adding titanium aluminum carbide into the solution obtained in the step (1) according to the mass concentration of 1-5%, and stirring for 18-36 hours at the temperature of 35-45 ℃ to obtain a precipitate phase;
(3) dispersing the precipitate obtained in the step (2) in absolute ethyl alcohol according to the mass concentration of 1-5%, performing ultrasonic treatment for 1-3 hours, performing centrifugal treatment on the precipitate, dispersing the precipitate in deionized water according to the mass concentration of 1-5%, and performing ultrasonic treatment for 30-60 min to obtain a dispersion liquid;
(4) centrifuging the dispersion liquid obtained in the step (3) for 6-36 hours at the temperature of 90-250 ℃ and the rotating speed of 3500 rpm to obtain the titanium carbide dispersion liquid on the upper layer;
(5) adding a settling agent into the titanium carbide dispersion liquid obtained in the step (4), and standing to obtain a precipitation product;
(6) and (3) dispersing the precipitation product obtained in the step (5) in a base material solvent according to the mass concentration of 1-10%, adding a dispersing aid, and uniformly dispersing to obtain the two-dimensional nano titanium carbide conductive paste.
In the technical scheme, the settling agent is one or more of ethanol, copper acetate and ammonium bicarbonate; the base material solvent is one or more of ethylene glycol, polyethylene glycol, 1, 3 propylene glycol, glycerol, polyacrylamide and polyacrylate; the dispersing auxiliary agent is one or more of polyvinylpyrrolidone, dodecyl trimethyl ammonium chloride, sodium dodecyl sulfate and a silane coupling agent KH560, and the mass ratio of the dispersing auxiliary agent to the titanium carbide is 1-10%; the mass ratio of the settling agent ethanol to the titanium carbide dispersion liquid is 1: 1; the mass ratio of the settling agent copper acetate, the ammonium bicarbonate and the titanium carbide dispersion liquid is 0.1-1 per mill.
The technical scheme of the invention also comprises the application of the conductive paste based on the two-dimensional nano titanium carbide, which is obtained by the preparation method, and the conductive paste is added into a base material and used for manufacturing conductive wires with conductive and antistatic properties and printed flexible circuits.
Compared with the prior art, the invention has the beneficial effects that: the efficient preparation method and the application of the two-dimensional titanium carbide conductive paste are provided, the efficient preparation of the nano two-dimensional material is realized, the material has good conductivity and dispersibility, and the conductive paste can be prepared to be added into a corresponding base material, so that the base material has good conductivity and antistatic performance.
Drawings
Fig. 1 is a transmission electron microscope image of a titanium carbide nanosheet prepared in example 1 of the present invention.
Fig. 2 is an X-ray diffraction pattern of a titanium carbide nanosheet prepared in example 1 of the present invention.
Fig. 3 is an X-ray photoelectron spectrum of the titanium carbide nanosheet prepared in example 1 of the present invention.
Detailed Description
The technical solution of the present invention is further described with reference to the accompanying drawings and specific embodiments.
Example 1
Accurately weighing 13 g of lithium fluoride, adding the lithium fluoride into a polytetrafluoroethylene beaker filled with 200ml of hydrochloric acid (9M), and slowly adding 10 g of titanium aluminum carbide powder within ten minutes after the lithium fluoride is fully dissolved; the beaker was sealed and stirred at 40 ℃ for 18 h. The precipitate was centrifuged, washed with water to a pH of > 5 and dispersed in 200mL of absolute ethanol. And performing centrifugal separation after ultrasonic treatment for 1 h. The precipitate was dispersed in 1L of deionized water and sonicated for 30 min. Centrifuging at 3500 rpm for 5 min to obtain upper layer titanium carbide less layer dispersion. Adding 0.2 g of ammonium bicarbonate into the titanium carbide dispersion, stirring, standing, centrifuging, collecting precipitate, and washing with ethanol. 5 g of the precipitate is added into 100 mL of glycerol, then 0.2 g of polyvinylpyrrolidone is added, and the mixture is stirred for 3 hours to be well dispersed, so that the nano titanium carbide conductive slurry is obtained.
Referring to the attached drawing 1, a transmission electron microscope image of the few-layer titanium carbide nanosheet prepared in the embodiment shows that the morphology of the titanium carbide nanosheet is visible.
Referring to fig. 2, the X-ray diffraction pattern of the titanium carbide prepared in this example is shown to be consistent with the literature XRD data.
Referring to fig. 3, an X-ray photoelectron spectrum of the titanium carbide prepared in this example shows that the valence of Ti indicates that the prepared product is titanium carbide.
The nano titanium carbide conductive paste prepared by the embodiment can be added in the spinning of synthetic fiber master batches or directly printed on textiles to obtain conductive and antistatic fibers and textiles; or the chemical fiber is applied to the manufacture of conductive wires and flexible circuits to realize good conductive and antistatic performances of the chemical fiber.
Example 2
Accurately weighing 16 g of lithium fluoride, adding the lithium fluoride into a polytetrafluoroethylene beaker filled with 200ml of hydrochloric acid (9M), and slowly adding 10 g of titanium aluminum carbide powder within ten minutes after the lithium fluoride is fully dissolved; the beaker was sealed and stirred at 45 ℃ for 24 h. The precipitate was centrifuged, washed with water to a pH of > 5 and dispersed in 200mL of absolute ethanol. And performing centrifugal separation after ultrasonic treatment for 1 h. The precipitate was dispersed in 1L of deionized water and sonicated for 30 min. Centrifuging at 3500 rpm for 5 min to obtain upper layer titanium carbide less layer dispersion. 0.2 g of copper acetate monohydrate was added to the titanium carbide dispersion, stirred, allowed to stand, centrifuged, and the precipitate was collected and washed with ethanol. And adding 5 g of precipitate into 100-50 mL of polyacrylate, stirring for 3h to disperse the precipitate well, wherein the obtained nano titanium carbide conductive slurry can be applied to the manufacture of conductive wires and flexible circuits, and the good conductive and antistatic properties of chemical fibers are realized.
Example 3
Accurately weighing 10 g of lithium fluoride, adding the lithium fluoride into a polytetrafluoroethylene beaker filled with 200ml of hydrochloric acid (9M), and slowly adding 10 g of titanium aluminum carbide powder within ten minutes after the lithium fluoride is fully dissolved; the beaker was sealed and stirred at 35 ℃ for 36 h. The precipitate was centrifuged, washed with water to a pH of > 5 and dispersed in 200mL of absolute ethanol. And performing centrifugal separation after ultrasonic treatment for 1 h. The precipitate was dispersed in 1L of deionized water and sonicated for 30 min. Centrifuging at 3500 rpm for 5 min to obtain upper layer titanium carbide less layer dispersion. Adding 1L of absolute ethyl alcohol into the titanium carbide dispersion liquid, stirring, standing, centrifuging, and collecting precipitates. And adding 5 g of precipitate into 50 mL of glycol, then adding 0.5 g of silane coupling agent KH560, stirring for 3h to disperse the precipitate well, wherein the obtained nano titanium carbide conductive slurry can be applied to the manufacture of conductive wires and flexible circuits, and the good conductive and antistatic properties of chemical fibers are realized.
Example 4
Accurately weighing 10 g of lithium fluoride, adding the lithium fluoride into a polytetrafluoroethylene beaker filled with 200ml of hydrochloric acid (9M), and slowly adding 10 g of titanium aluminum carbide powder within ten minutes after the lithium fluoride is fully dissolved; the beaker was sealed and stirred at 35 ℃ for 18 h. The precipitate was centrifuged, washed with water to a pH of > 5 and dispersed in 200mL of absolute ethanol. And performing centrifugal separation after ultrasonic treatment for 1 h. The precipitate was dispersed in 1L of deionized water and sonicated for 30 min. Centrifuging at 3500 rpm for 5 min to obtain upper layer titanium carbide less layer dispersion. Adding 0.1 g of ammonium bicarbonate into the titanium carbide dispersion, stirring, standing, centrifuging, collecting precipitate, and washing with ethanol. And adding 5 g of precipitate into 500 mL of 1, 3-propanediol, then adding 0.1 g of dodecyl trimethyl ammonium chloride, stirring for 3h to ensure that the precipitate is well dispersed, and obtaining the nano titanium carbide conductive slurry which can be applied to the manufacture of conductive wires and flexible circuits to realize good conductive and antistatic properties of chemical fibers.
Example 5
Accurately weighing 13 g of lithium fluoride, adding the lithium fluoride into a polytetrafluoroethylene beaker filled with 200ml of hydrochloric acid (9M), and slowly adding 10 g of titanium aluminum carbide powder within ten minutes after the lithium fluoride is fully dissolved; the beaker was sealed and stirred at 35 ℃ for 18 h. The precipitate was centrifuged, washed with water to a pH of > 5 and dispersed in 200mL of absolute ethanol. And performing centrifugal separation after ultrasonic treatment for 1 h. The precipitate was dispersed in 1L of deionized water and sonicated for 30 min. Centrifuging at 3500 rpm for 5 min to obtain upper layer titanium carbide less layer dispersion. Adding 1 g of ammonium bicarbonate into the titanium carbide dispersion liquid, stirring, standing, centrifuging, collecting precipitate, and washing with ethanol. And adding 5 g of precipitate into ethylene glycol, then adding 0.1 g of polyvinylpyrrolidone, stirring for 3h to ensure that the precipitate is well dispersed, and obtaining the nano titanium carbide conductive slurry which can be applied to the manufacture of conductive wires and flexible circuits to realize good conductive and antistatic properties of chemical fibers.
Claims (6)
1. A preparation method based on two-dimensional nano titanium carbide conductive paste is characterized by comprising the following steps:
(1) dissolving lithium fluoride in hydrochloric acid according to the mass concentration of 5-10%;
(2) adding titanium aluminum carbide into the solution obtained in the step (1) according to the mass concentration of 1-5%, and stirring for 18-36 hours at the temperature of 35-45 ℃ to obtain a precipitate phase;
(3) dispersing the precipitate obtained in the step (2) in absolute ethyl alcohol according to the mass concentration of 1-5%, performing ultrasonic treatment for 1-3 hours, performing centrifugal treatment on the precipitate, dispersing the precipitate in deionized water according to the mass concentration of 1-5%, and performing ultrasonic treatment for 30-60 min to obtain a dispersion liquid;
(4) centrifuging the dispersion liquid obtained in the step (3) for 6-36 hours at the temperature of 90-250 ℃ and the rotating speed of 3500 rpm to obtain the titanium carbide dispersion liquid on the upper layer;
(5) adding a settling agent into the titanium carbide dispersion liquid obtained in the step (4), and standing to obtain a precipitation product;
(6) and (3) dispersing the precipitation product obtained in the step (5) in a base material solvent according to the mass concentration of 1-10%, adding a dispersing aid, and uniformly dispersing to obtain the two-dimensional nano titanium carbide conductive paste.
2. The preparation method of the two-dimensional nano titanium carbide-based conductive paste according to claim 1, characterized by comprising the following steps: the settling agent is one or more of ethanol, copper acetate and ammonium bicarbonate.
3. The preparation method of the two-dimensional nano titanium carbide-based conductive paste according to claim 1, characterized by comprising the following steps: the base material solvent is one or more of ethylene glycol, polyethylene glycol, 1, 3 propylene glycol, glycerol, polyacrylamide and polyacrylate.
4. The preparation method of the two-dimensional nano titanium carbide-based conductive paste according to claim 1, characterized by comprising the following steps: the dispersing aid is one or more of polyvinylpyrrolidone, dodecyl trimethyl ammonium chloride, sodium dodecyl sulfate and a silane coupling agent KH560, and the mass ratio of the dispersing aid to the titanium carbide is 1-10%.
5. The preparation method of the two-dimensional nano titanium carbide-based conductive paste according to claim 2, characterized by comprising the following steps: the mass ratio of the settling agent ethanol to the titanium carbide dispersion liquid is 1: 1; the mass ratio of the settling agent copper acetate, the ammonium bicarbonate and the titanium carbide dispersion liquid is 0.1-1 per mill.
6. The application of the conductive paste based on the two-dimensional nano titanium carbide obtained by the preparation method of the claim 1 is added into a base material and used for manufacturing conductive wires and printed flexible circuits with conductive and antistatic properties.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114318852A (en) * | 2022-01-07 | 2022-04-12 | 苏州大学 | Intelligent fireproof textile based on nano composite material and preparation method thereof |
| CN114606652A (en) * | 2022-02-17 | 2022-06-10 | 苏州美森无纺科技有限公司 | Photo-thermal regulation and control type efficient oil adsorption wiping cloth and preparation method thereof |
| CN114773858A (en) * | 2022-03-30 | 2022-07-22 | 华南理工大学 | Flame-retardant tracking-resistant silicone rubber composition and preparation method and application thereof |
| CN117071104A (en) * | 2023-09-27 | 2023-11-17 | 吴江市兴业纺织有限公司 | Antistatic textile fabric and preparation method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105734953A (en) * | 2016-02-23 | 2016-07-06 | 崔铉泽 | Light-absorbing and heat-emitting composition and preparation method of fabric containing same |
| CN107887588A (en) * | 2017-11-08 | 2018-04-06 | 黑龙江科技大学 | A kind of preparation method and application of nano-sulfur particles/two-dimensional layer carbonization titanium composite material |
| CN108557822A (en) * | 2018-08-02 | 2018-09-21 | 合肥学院 | A kind of preparation method of surface organic modification titanium carbide nanometer sheet |
| CN109167066A (en) * | 2018-09-03 | 2019-01-08 | 济南大学 | A kind of preparation method of few layer titanium carbide growth in situ nitrogen-doped carbon nanometer pipe three-dimensional composite material |
| CN110534741A (en) * | 2019-09-06 | 2019-12-03 | 浙江大学 | A kind of fast preparation method and application of few layer MXenes |
| CN110606998A (en) * | 2019-09-25 | 2019-12-24 | 合肥学院 | MXene/natural rubber flexible composite film and preparation method thereof |
| CN110773213A (en) * | 2019-11-11 | 2020-02-11 | 福州大学 | One-dimensional cadmium sulfide/two-dimensional titanium carbide composite photocatalyst and preparation method and application thereof |
| CN111118889A (en) * | 2019-12-06 | 2020-05-08 | 广东工业大学 | Multifunctional flexible sensing fiber membrane and preparation method and application thereof |
| CN111223587A (en) * | 2020-01-16 | 2020-06-02 | 南开大学 | Dendritic layered self-assembled flexible conductive film and preparation method thereof |
| CN111573676A (en) * | 2020-06-18 | 2020-08-25 | 济南大学 | Preparation method of one-dimensional titanium carbide nano coil |
-
2020
- 2020-12-20 CN CN202011512691.5A patent/CN112626630A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105734953A (en) * | 2016-02-23 | 2016-07-06 | 崔铉泽 | Light-absorbing and heat-emitting composition and preparation method of fabric containing same |
| CN107887588A (en) * | 2017-11-08 | 2018-04-06 | 黑龙江科技大学 | A kind of preparation method and application of nano-sulfur particles/two-dimensional layer carbonization titanium composite material |
| CN108557822A (en) * | 2018-08-02 | 2018-09-21 | 合肥学院 | A kind of preparation method of surface organic modification titanium carbide nanometer sheet |
| CN109167066A (en) * | 2018-09-03 | 2019-01-08 | 济南大学 | A kind of preparation method of few layer titanium carbide growth in situ nitrogen-doped carbon nanometer pipe three-dimensional composite material |
| CN110534741A (en) * | 2019-09-06 | 2019-12-03 | 浙江大学 | A kind of fast preparation method and application of few layer MXenes |
| CN110606998A (en) * | 2019-09-25 | 2019-12-24 | 合肥学院 | MXene/natural rubber flexible composite film and preparation method thereof |
| CN110773213A (en) * | 2019-11-11 | 2020-02-11 | 福州大学 | One-dimensional cadmium sulfide/two-dimensional titanium carbide composite photocatalyst and preparation method and application thereof |
| CN111118889A (en) * | 2019-12-06 | 2020-05-08 | 广东工业大学 | Multifunctional flexible sensing fiber membrane and preparation method and application thereof |
| CN111223587A (en) * | 2020-01-16 | 2020-06-02 | 南开大学 | Dendritic layered self-assembled flexible conductive film and preparation method thereof |
| CN111573676A (en) * | 2020-06-18 | 2020-08-25 | 济南大学 | Preparation method of one-dimensional titanium carbide nano coil |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114318852A (en) * | 2022-01-07 | 2022-04-12 | 苏州大学 | Intelligent fireproof textile based on nano composite material and preparation method thereof |
| CN114318852B (en) * | 2022-01-07 | 2023-11-10 | 苏州大学 | Intelligent fireproof textile based on nanocomposite and preparation method thereof |
| CN114606652A (en) * | 2022-02-17 | 2022-06-10 | 苏州美森无纺科技有限公司 | Photo-thermal regulation and control type efficient oil adsorption wiping cloth and preparation method thereof |
| CN114606652B (en) * | 2022-02-17 | 2023-07-21 | 苏州美森无纺科技有限公司 | Photo-thermal regulation type efficient oil adsorption wiping cloth and preparation method thereof |
| CN114773858A (en) * | 2022-03-30 | 2022-07-22 | 华南理工大学 | Flame-retardant tracking-resistant silicone rubber composition and preparation method and application thereof |
| CN114773858B (en) * | 2022-03-30 | 2023-05-23 | 华南理工大学 | Flame-retardant tracking-resistant silicone rubber composition and preparation method and application thereof |
| CN117071104A (en) * | 2023-09-27 | 2023-11-17 | 吴江市兴业纺织有限公司 | Antistatic textile fabric and preparation method thereof |
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