CN112624803A - Production process of ceramic tile with low-gloss anti-slip granular ceramic surface material - Google Patents
Production process of ceramic tile with low-gloss anti-slip granular ceramic surface material Download PDFInfo
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- CN112624803A CN112624803A CN202011618990.7A CN202011618990A CN112624803A CN 112624803 A CN112624803 A CN 112624803A CN 202011618990 A CN202011618990 A CN 202011618990A CN 112624803 A CN112624803 A CN 112624803A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
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Abstract
The invention discloses a production process of a ceramic tile with a low-gloss anti-skid granular ceramic surface material, which comprises the following steps: 1) preparing a ceramic blank; 2) preparing overglaze; 3) preparing low-gloss anti-skid particles; 4) production of low-gloss antiskid particle ceramic tiles: firstly, spraying the overglaze on a ceramic blank by a high-pressure spray gun, and then completely drying by an oven; secondly, printing ink-jet patterns on the dried ceramic blank after the ceramic blank is cooled to room temperature; thirdly, weighing the low-gloss anti-slip particles obtained in the step 3) according to the weight percentage, adding glue according to the weight percentage, uniformly mixing, and spraying the mixture on the ceramic blank body obtained in the step two by using a high-pressure spray gun; fourthly, drying the ceramic body obtained in the third step in drying equipment; fifthly, placing the brick ceramic blank obtained in the step IV into a natural gas roller kiln to be fired, and finally obtaining a finished product. The invention is applied to ceramic tile production, has the characteristics of simple process, high yield and high production efficiency, has stronger universality and can be popularized in the industry.
Description
Technical Field
The invention relates to a production process of a ceramic tile with a low-gloss anti-skid granular ceramic surface material.
Background
The glazed tile is a glazed tile with the surface being fired at high temperature and high pressure, and the glazed tile consists of two parts, namely a soil blank and a glazed surface. Glazed tiles used in the prior art have certain non-slip property, but have low non-slip coefficient and poor safety. And the existing glazed tile has higher glossiness, stronger light pollution, inconvenient cleaning and poor use effect.
Disclosure of Invention
The invention aims to provide a production process of ceramic tiles with low-gloss anti-skidding granular ceramic surface materials, which is applied to ceramic tile production, has the characteristics of simple manufacturing process, high yield and high production efficiency, has stronger universality and can be popularized in the industry.
The technical scheme of the invention is that the production process of the ceramic tile with the low-gloss anti-skid granular ceramic surface material comprises the following steps:
1) preparation of a ceramic body: pressing the sintered blank powder with low water absorption of less than 0.5 percent into a ceramic blank by using a Kodak 4800C press;
2) and (3) preparing overglaze: selecting feldspar, soil, quartz and zirconium silicate as raw materials, mixing the raw materials in proportion, putting the mixture into a 1000CC ceramic ball milling tank, adding 40% of water, and putting the mixture into a belt type ball mill for ball milling to obtain overglaze powder;
3) preparation of low-gloss anti-slip particles:
a, frit preparation: feldspar, soil, quartz, zinc, barium carbonate and alumina are selected as raw materials, mixed uniformly by a mixer according to a certain proportion, put into a frit tank kiln for melting, the melting temperature is 1500 ℃, the melted high-temperature liquid flows into water to be water-quenched into conformal semitransparent particles with the diameter of 1-5mm, and dried to obtain the frit, the drying temperature is 120-;
b, preparing low-glossiness anti-skid particles: b, screening the frit by using a 270-mesh standard screen and a 400-mesh standard screen respectively, selecting semitransparent fine particles which meet the requirements of 270-400 meshes, c removing iron, d packaging, and obtaining low-glossiness anti-skid particles;
4) production of low-gloss antiskid particle ceramic tiles:
firstly, the glaze is prepared into the specific gravity of 1.55g/cm in a 100ml specific gravity bottle3Spraying the ceramic blank with the weight of 220 plus 60 g and 240g on a high-pressure spray gun with the caliber of 0.65mm, and completely drying by using an oven;
secondly, printing ink-jet patterns on the dried ceramic blank after the ceramic blank is cooled to room temperature, and printing by using a ceramic digital ink-jet printer, wherein the ink has blue, brown, beige, yellow and black colors;
③ weighing 100 percent of the low-gloss anti-skid particles obtained in the step 3) according to the weight percentage, adding 100 percent of glue water according to the weight percentage, and uniformly mixing, wherein the specific gravity of the mixture is 1.4g/cm3Spraying the mixture on the ceramic blank by using a high-pressure spray gun with the caliber of 2.5mm, wherein the using weight of the mixture is 40-50 g;
fourthly, drying the ceramic body obtained in the third step in drying equipment;
fifthly, placing the ceramic green body of the brick obtained in the step IV into a natural gas roller kiln for sintering, and finally obtaining the ceramic brick with the low-glossiness anti-skid granular ceramic surface material.
In a preferred embodiment of the invention, the overglaze in the step 2) is prepared from the following raw materials in percentage by weight: 40-50% of feldspar, 10-25% of soil, 10-20% of quartz and 10-15% of zirconium silicate.
In a preferred embodiment of the invention, the specific gravity of the ball-milled fineness in the step 2) is 1.80 +/-0.05 g/cm3And the fineness after drying meets the requirement that the residue of a 325-mesh sieve is less than 1 percent.
In a preferred embodiment of the present invention, the frit in the preparation of the frit in step 3) is prepared by weighing the following raw materials in percentage by weight: 40-50% of feldspar, 10-25% of soil, 10-20% of quartz, 5-8% of zinc, 5-10% of barium carbonate and 3-5% of aluminum oxide.
In a preferred embodiment of the present invention, the drying time of the oven in the (r) of the step 4) is 20min, and the temperature of the oven is 120 ℃.
In a preferred embodiment of the present invention, the drying temperature of the drying equipment in the fourth step 4) is 120 ℃, and the drying time is 30-40 min.
In a preferred embodiment of the invention, the maximum firing temperature of the kiln in the fifth step 4) is 1190-1210 ℃, the firing time is 1h, and the sintering temperature is 1180-1210 ℃.
The invention relates to a production process of a ceramic tile with a low-gloss anti-slip granular ceramic surface material, which is applied to the production of the ceramic tile, has the characteristics of simple process, high yield and high production efficiency, has stronger universality and can be popularized in the industry.
Detailed Description
The following detailed description of the preferred embodiments of the present invention is provided to enable those skilled in the art to more readily understand the advantages and features of the present invention, and to clearly and unequivocally define the scope of the present invention.
The invention relates to a production process of a ceramic tile with a low-gloss anti-skid granular ceramic surface material, which comprises the following steps:
1) preparation of a ceramic body: pressing the sintered blank powder with low water absorption of less than 0.5 percent into a ceramic blank by using a Kodak 4800C press;
2) and (3) preparing overglaze: feldspar, soil, quartz and zirconium silicate are selected as raw materials, and the raw materials are weighed according to the following weight percentage: 40-50% of feldspar, 10-25% of soil, 10-20% of quartz and 10-15% of zirconium silicate, which are mixed according to a certain proportion, put into a 1000CC ceramic ball milling tank, added with 40% of water and put into a belt ball mill for ball milling, and the fineness specific gravity after ball milling is 1.80 +/-0.05 g/cm3After drying, the fineness meets the requirement that the residue of a 325-mesh sieve is less than 1 percent, and overglaze powder is obtained;
3) preparation of low-gloss anti-slip particles:
a, frit preparation: feldspar, soil, quartz, zinc, barium carbonate and alumina are selected as raw materials, and the raw materials are weighed according to the following weight percentage: 40-50% of feldspar, 10-25% of soil, 10-20% of quartz, 5-8% of zinc, 5-10% of barium carbonate and 3-5% of alumina, uniformly mixing the components by a mixer in proportion, putting the mixture into a frit tank kiln for smelting at 1500 ℃, allowing the molten high-temperature liquid to flow into water to be quenched into conformal semitransparent particles with the diameter of 1-5mm, and drying the particles to obtain a frit, wherein the drying temperature is 120 ℃ and 180 ℃, and the drying time is 40-70 min;
b, preparing low-glossiness anti-skid particles: b, screening the frit by using a 270-mesh standard screen and a 400-mesh standard screen respectively, selecting semitransparent fine particles which meet the requirements of 270-400 meshes, c removing iron, d packaging, and obtaining low-glossiness anti-skid particles;
4) production of low-gloss antiskid particle ceramic tiles:
firstly, the glaze is prepared into the specific gravity of 1.55g/cm in a 100ml specific gravity bottle3Spraying the ceramic blank with the weight of 220 plus 60 g on a 60-60 cm ceramic blank by using a high-pressure spray gun with the caliber of 0.65mm, and then completely drying the ceramic blank by using an oven, wherein the drying time is 20min and the temperature of the oven is 120 ℃;
secondly, printing ink-jet patterns on the dried ceramic blank after the ceramic blank is cooled to room temperature, and printing by using a ceramic digital ink-jet printer, wherein the ink has blue, brown, beige, yellow and black colors;
③ weighing 100 percent of the low-gloss anti-skid particles obtained in the step 3) according to the weight percentage, adding 100 percent of glue water according to the weight percentage, and uniformly mixing, wherein the specific gravity of the mixture is 1.4g/cm3Spraying the mixture on the ceramic blank by using a high-pressure spray gun with the caliber of 2.5mm, wherein the using weight of the mixture is 40-50 g;
fourthly, drying the ceramic body in the third step in drying equipment, wherein the drying temperature is 120 ℃, and the drying time is 30-40 min;
fifthly, placing the brick ceramic blank obtained in the step IV into a natural gas roller kiln for sintering, wherein the maximum sintering temperature of the kiln is 1190-1210 ℃, the sintering time is 1h, and the sintering temperature is 1180-1210 ℃, and finally obtaining the ceramic brick with the low-gloss anti-skid granular ceramic surface material.
Example one
Pressing the sintered blank powder with low water absorption of less than 0.5 percent into a ceramic blank by using a Kodak 4800C press; weighing 50% of feldspar, 20% of soil, 15% of quartz and 15% of zirconium silicate according to the weight percentage to prepare overglaze, mixing the overglaze according to the weight percentage, putting the mixture into a 1000CC ceramic ball milling tank, adding 40% of water, putting the mixture into a belt type ball mill for ball milling, wherein the fineness specific gravity after ball milling is 1.80 +/-0.05 g/cm3The fineness after drying meets the requirement of a 325-mesh sieveThe rest is less than 1 percent, and overglaze powder is obtained; 42 percent of feldspar, 22 percent of soil, 16 percent of quartz, 7 percent of zinc, 8 percent of barium carbonate and 5 percent of alumina are weighed according to the weight percentage to prepare frit, the frit is uniformly mixed by a mixer according to the proportion, and then is put into a frit tank kiln for melting, the melting temperature is 1500 ℃, the melted high-temperature liquid flows into water to be water-quenched into conformal semitransparent particles with the diameter of 1-3mm, the particles are dried to obtain the frit, the drying temperature is 140 ℃, and the drying time is 60 min; putting the dried frit into a double-roller crusher for crushing, sieving by using a 270-mesh standard sieve and a 400-mesh standard sieve respectively, selecting semitransparent fine particles meeting the requirements of 270-400 meshes, removing iron, and packaging to obtain low-glossiness anti-skid particles; the overglaze is mixed in a 100ml pycnometer to adjust the specific gravity to 1.55g/cm3Spraying the ceramic blank with the weight of 225g on a 60 x 60cm ceramic blank by using a high-pressure spray gun with the caliber of the spray gun of 0.65mm, and then completely drying the ceramic blank by using an oven, wherein the drying time is 20min and the oven temperature is 120 ℃; after cooling the dried ceramic blank to room temperature, printing an ink-jet pattern, and printing by using a ceramic digital ink-jet printer, wherein the ink is black; weighing 100 percent of low-gloss anti-skid particles according to the weight percentage, adding 100 percent of glue according to the weight percentage, and uniformly mixing, wherein the specific gravity of the mixture is 1.4g/cm3Spraying the mixture on a ceramic blank after ink jetting by using a high-pressure spray gun with the caliber of 2.5mm, wherein the using weight of the mixture is 42 g; then, drying the ceramic body in drying equipment at the drying temperature of 120 ℃ for 32 min; and placing the obtained ceramic green body of the brick into a natural gas roller kiln for sintering, wherein the maximum sintering temperature of the kiln is 1200 ℃, the sintering time is 1h, and the sintering temperature is 1190 ℃, and finally obtaining the ceramic brick with the low-gloss anti-skid granular ceramic surface material.
Example two
Pressing the sintered blank powder with low water absorption of less than 0.5 percent into a ceramic blank by using a Kodak 4800C press; weighing 45% of feldspar, 25% of soil, 20% of quartz and 10% of zirconium silicate according to the weight percentage to prepare overglaze, mixing the overglaze according to the weight percentage, putting the mixture into a 1000CC ceramic ball milling tank, adding 40% of water, putting the mixture into a belt type ball mill for ball milling, wherein the fineness specific gravity after ball milling is 1.80 +/-0.05 g/cm3After drying, the fineness meets the requirement that the residue of a 325-mesh sieve is less than 1 percent, and overglaze powder is obtained; weighing 50% of feldspar, 15% of soil, 15% of quartz, 6% of zinc and 10% of barium carbonate according to the weight percentagePreparing fusion cakes by 4 percent of alumina, uniformly mixing the fusion cakes by a mixer in proportion, putting the fusion cakes into a fusion cake tank kiln for fusion at the fusion temperature of 1500 ℃, allowing the fused high-temperature liquid to flow into water to be quenched into conformal semitransparent particles with the diameter of 2-5mm, and drying the particles at the drying temperature of 170 ℃ for 50min to obtain the fusion cakes; putting the dried frit into a double-roller crusher for crushing, sieving by using a 270-mesh standard sieve and a 400-mesh standard sieve respectively, selecting semitransparent fine particles meeting the requirements of 270-400 meshes, removing iron, and packaging to obtain low-glossiness anti-skid particles; the overglaze is mixed in a 100ml pycnometer to adjust the specific gravity to 1.55g/cm3Spraying the ceramic blank with the weight of 235g on a 60 x 60cm ceramic blank by using a high-pressure spray gun with the caliber of the spray gun of 0.65mm, and then completely drying the ceramic blank by using an oven, wherein the drying time is 20min, and the temperature of the oven is 120 ℃; after cooling the dried ceramic blank to room temperature, printing an ink-jet pattern, and printing by using a ceramic digital ink-jet printer, wherein the color of the ink is blue; weighing 100 percent of low-gloss anti-skid particles according to the weight percentage, adding 100 percent of glue according to the weight percentage, and uniformly mixing, wherein the specific gravity of the mixture is 1.4g/cm3Spraying the mixture on a ceramic blank after ink jetting by using a high-pressure spray gun with the caliber of 2.5mm, wherein the using weight of the mixture is 48 g; then, drying the ceramic body in drying equipment at the drying temperature of 120 ℃ for 38 min; and placing the obtained ceramic green body of the brick into a natural gas roller kiln for sintering, wherein the maximum sintering temperature of the kiln is 1210 ℃, the sintering time is 1h, and the sintering temperature is 1200 ℃, and finally obtaining the ceramic brick with the low-glossiness anti-slip granular ceramic surface material.
The glaze with the effect of the matt and anti-slip particles produced by the production process has the following advantages on the premise of no roughness:
strong slip resistance: the slip resistance is far better than that of the common glazed tile, the slip resistance coefficient can reach R11-R12, the ceramic tile is used in bathrooms, outdoor public places and the like, and has better safety compared with the common ceramic tile due to excellent slip resistance;
easy cleaning: the common cleaning agent can clean the fabric;
low gloss: the brightness index is 2-5, and the reflected light pollution is reduced.
The invention relates to a production process of a ceramic tile with a low-gloss anti-slip granular ceramic surface material, which is applied to the production of the ceramic tile, has the characteristics of simple process, high yield and high production efficiency, has stronger universality and can be popularized in the industry.
The above description is only an embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that can be made by those skilled in the art without inventive work within the technical scope of the present invention are included in the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope defined by the claims.
Claims (7)
1. A production process of ceramic tiles with low-gloss anti-skid granular ceramic surface materials is characterized by comprising the following steps of: the method comprises the following steps:
1) preparation of a ceramic body: pressing the sintered blank powder with low water absorption of less than 0.5 percent into a ceramic blank by using a Kodak 4800C press;
2) and (3) preparing overglaze: selecting feldspar, soil, quartz and zirconium silicate as raw materials, mixing the raw materials in proportion, putting the mixture into a 1000CC ceramic ball milling tank, adding 40% of water, and putting the mixture into a belt type ball mill for ball milling to obtain overglaze powder;
3) preparation of low-gloss anti-slip particles:
a, frit preparation: feldspar, soil, quartz, zinc, barium carbonate and alumina are selected as raw materials, mixed uniformly by a mixer according to a certain proportion, put into a frit tank kiln for melting, the melting temperature is 1500 ℃, the melted high-temperature liquid flows into water to be water-quenched into conformal semitransparent particles with the diameter of 1-5mm, and dried to obtain the frit, the drying temperature is 120-;
b, preparing low-glossiness anti-skid particles: b, screening the frit by using a 270-mesh standard screen and a 400-mesh standard screen respectively, selecting semitransparent fine particles which meet the requirements of 270-400 meshes, c removing iron, d packaging, and obtaining low-glossiness anti-skid particles;
4) production of low-gloss antiskid particle ceramic tiles:
firstly, the glaze is prepared into the specific gravity of 1.55g/cm in a 100ml specific gravity bottle3Using a high pressure with a spray gun bore of 0.65mmSpraying the spray gun on a 60 × 60cm ceramic blank, wherein the weight is 220-;
secondly, printing ink-jet patterns on the dried ceramic blank after the ceramic blank is cooled to room temperature, and printing by using a ceramic digital ink-jet printer, wherein the ink has blue, brown, beige, yellow and black colors;
③ weighing 100 percent of the low-gloss anti-skid particles obtained in the step 3) according to the weight percentage, adding 100 percent of glue water according to the weight percentage, and uniformly mixing, wherein the specific gravity of the mixture is 1.4g/cm3Spraying the mixture on the ceramic blank by using a high-pressure spray gun with the caliber of 2.5mm, wherein the using weight of the mixture is 40-50 g;
fourthly, drying the ceramic body obtained in the third step in drying equipment;
fifthly, placing the ceramic green body of the brick obtained in the step IV into a natural gas roller kiln for sintering, and finally obtaining the ceramic brick with the low-glossiness anti-skid granular ceramic surface material.
2. The process for the production of ceramic tiles with low gloss non-slip particulate ceramic surface material as claimed in claim 1, wherein: the overglaze in the step 2) is prepared from the following raw materials in percentage by weight: 40-50% of feldspar, 10-25% of soil, 10-20% of quartz and 10-15% of zirconium silicate.
3. The process for the production of ceramic tiles with low gloss non-slip particulate ceramic surface material as claimed in claim 1, wherein: the fineness and the specific gravity of the ball-milled product in the step 2) are 1.80 +/-0.05 g/cm3And the fineness after drying meets the requirement that the residue of a 325-mesh sieve is less than 1 percent.
4. The process for the production of ceramic tiles with low gloss non-slip particulate ceramic surface material as claimed in claim 1, wherein: the frit in the frit preparation of step 3) is prepared by weighing the following raw materials in percentage by weight: 40-50% of feldspar, 10-25% of soil, 10-20% of quartz, 5-8% of zinc, 5-10% of barium carbonate and 3-5% of aluminum oxide.
5. The process for the production of ceramic tiles with low gloss non-slip particulate ceramic surface material as claimed in claim 1, wherein: the drying time of the drying oven in the step 4) is 20min, and the temperature of the drying oven is 120 ℃.
6. The process for the production of ceramic tiles with low gloss non-slip particulate ceramic surface material as claimed in claim 1, wherein: the drying temperature of the drying equipment in the step 4) is 120 ℃, and the drying time is 30-40 min.
7. The process for the production of ceramic tiles with low gloss non-slip particulate ceramic surface material as claimed in claim 1, wherein: the maximum firing temperature of the kiln in the fifth step 4) is 1190-1210 ℃, the firing time is 1h, and the firing temperature is 1180-.
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Citations (6)
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JPH05105559A (en) * | 1991-10-22 | 1993-04-27 | Inax Corp | Antislip tile and its production |
CN108178514A (en) * | 2018-01-19 | 2018-06-19 | 佛山科学技术学院 | A kind of building ceramic tiles gentle eye protection matting glaze and its preparation process |
CN109227901A (en) * | 2018-10-10 | 2019-01-18 | 东莞市唯美陶瓷工业园有限公司 | Can simultaneously a variety of dry-particle ceramic tiles of charity, preparation method and its control method |
CN111087253A (en) * | 2019-12-19 | 2020-05-01 | 卡罗比亚(中国)高新材料有限公司 | Decoration process on low-water-absorption ceramic surface |
CN111116235A (en) * | 2019-12-30 | 2020-05-08 | 肇庆乐华陶瓷洁具有限公司 | Fine dry particle ceramic tile, preparation method thereof and fine dry particle glaze |
WO2020233032A1 (en) * | 2019-05-17 | 2020-11-26 | 蒙娜丽莎集团股份有限公司 | Dry granule ceramic tile from wet-method slurry spraying processing and preparation method therefor |
-
2020
- 2020-12-31 CN CN202011618990.7A patent/CN112624803A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05105559A (en) * | 1991-10-22 | 1993-04-27 | Inax Corp | Antislip tile and its production |
CN108178514A (en) * | 2018-01-19 | 2018-06-19 | 佛山科学技术学院 | A kind of building ceramic tiles gentle eye protection matting glaze and its preparation process |
CN109227901A (en) * | 2018-10-10 | 2019-01-18 | 东莞市唯美陶瓷工业园有限公司 | Can simultaneously a variety of dry-particle ceramic tiles of charity, preparation method and its control method |
WO2020233032A1 (en) * | 2019-05-17 | 2020-11-26 | 蒙娜丽莎集团股份有限公司 | Dry granule ceramic tile from wet-method slurry spraying processing and preparation method therefor |
CN111087253A (en) * | 2019-12-19 | 2020-05-01 | 卡罗比亚(中国)高新材料有限公司 | Decoration process on low-water-absorption ceramic surface |
CN111116235A (en) * | 2019-12-30 | 2020-05-08 | 肇庆乐华陶瓷洁具有限公司 | Fine dry particle ceramic tile, preparation method thereof and fine dry particle glaze |
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Application publication date: 20210409 |