CN112552569A - Preparation method of modified latex and friction power generation functional gloves - Google Patents
Preparation method of modified latex and friction power generation functional gloves Download PDFInfo
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- CN112552569A CN112552569A CN202011363691.3A CN202011363691A CN112552569A CN 112552569 A CN112552569 A CN 112552569A CN 202011363691 A CN202011363691 A CN 202011363691A CN 112552569 A CN112552569 A CN 112552569A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
- C08L13/02—Latex
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/02—Direct processing of dispersions, e.g. latex, to articles
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02N—ELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
- H02N1/00—Electrostatic generators or motors using a solid moving electrostatic charge carrier
- H02N1/04—Friction generators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2313/00—Characterised by the use of rubbers containing carboxyl groups
- C08J2313/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
Abstract
The preparation method of the modified latex and friction power generation functional glove comprises the following components in parts by weight: 100-110 parts of carboxylic butyronitrile latex, 1-2 parts of potassium hydroxide, 1-1.5 parts of sulfur, 1.5-3 parts of zinc oxide, 1-2 parts of titanium dioxide, 0.01-0.03 part of dispersing agent, 10-20 parts of microsphere friction power generation effect powder and 3-8 parts of sodium polyacrylate. The preparation method of the friction power generation functional glove comprises the steps of preheating a glove core, dipping the glove core in modified latex, pre-vulcanizing at 65-85 ℃ for 60-90min, soaking and washing at 40-50 ℃ for 40-60min, and vulcanizing at 95-115 ℃ for 60-90 min. The beneficial effects are that: the glove dipping latex is added with miscellaneous piezoelectric induction crystal dispersion powder, and the latex is blended and modified.
Description
Technical Field
The invention belongs to the technical field of glove production, and particularly relates to a method for preparing a modified latex glove with a friction power generation function.
Background
In daily life, people are often troubled by static electricity generated by mutual friction of different materials, so people adopt various methods to avoid the generation of the static electricity. However, there is a microsphere electric generator which can convert energy such as friction energy, acoustic energy, light wave energy, etc. generated in industrial production and daily life of people into electric energy. In the internal sub-circuit structure of the friction microsphere generator, based on the coupling effect of friction effect and static balance, charge induction can be generated between two friction materials with different electrical properties, so that the two friction materials have equal quantity of electricity with different signs, and a potential difference is formed between the two materials; and electrons in the external circuit of the generator flow between the electrodes under the action of the potential difference. Since this generator is a very promising energy harvesting device, its application in the field of rubber protective gloves has wide space in view of its ability to harvest multiple energies in the surrounding environment and simultaneously convert them into electrical energy, but there is currently little research on this.
Disclosure of Invention
In order to solve the problems, the invention adopts the following technical scheme:
the modified latex comprises the following components in parts by weight:
100 portions of carboxylated nitrile latex and 110 portions of carboxylated nitrile latex,
1-2 parts of potassium hydroxide, namely,
1 to 1.5 portions of sulfur,
1.5 to 3 parts of zinc oxide,
1-2 parts of titanium dioxide powder,
0.01 to 0.03 portion of dispersant,
10-20 parts of microsphere triboelectric effect powder,
3-8 parts of sodium polyacrylate.
One mode comprises the following components in parts by weight:
100 parts of carboxylic acrylonitrile-butadiene latex,
1 part of potassium hydroxide, namely potassium hydroxide,
0.8 part of sulfur, namely,
2 parts of zinc oxide, namely zinc oxide,
0.5 to 1.2 portions of accelerant,
2 parts of titanium dioxide, namely 2 parts of titanium dioxide,
0.02 part of a dispersant, namely,
20 parts of microsphere friction power generation effect powder,
0.8 to 1.8 portions of anti-aging agent,
1-2 parts of black pigment,
5 parts of sodium polyacrylate.
In one mode, the microsphere triboelectricity generation effect powder comprises the following components in parts by weight:
1 to 10 portions of zinc metastannate crystal,
80-90 parts of polydimethylsiloxane,
1-10 parts of nano silver powder.
In one mode, the microsphere triboelectricity generation effect powder comprises the following components in parts by weight:
2 parts of zinc metastannate crystal powder,
90 parts of dimethyl silicone Polymer (PDMS),
and 8 parts of nano silver powder.
In one mode, the preparation method of the microsphere triboelectric generation effect powder comprises the following steps,
mixing zinc metastannate crystal powder, nano silver powder and polydimethylsiloxane;
the mixture was evacuated and heated to 50 ℃;
stirring and drying the mixture;
and (5) obtaining the microsphere triboelectricity generation effect powder after drying.
In one mode, the modified latex is prepared by the following steps,
mixing the raw materials, controlling the viscosity at 1500-,
and adding the prepared latex into a vacuumizing device for defoaming treatment.
In one mode, the raw material mixing comprises the following specific steps: mixing carboxylic butyronitrile latex, potassium hydroxide, sulfur, zinc oxide, an accelerant, titanium dioxide and a dispersing agent to form a latex system,
adding the micro-sphere friction power generation effect powder, stirring,
adding sodium polyacrylate for thickening.
A method for preparing a glove with a friction power generation function,
the glove core is preheated, and then the glove core is preheated,
dipping the mixture into the modified latex in the preamble,
pre-vulcanizing at 65-85 deg.C for 60-90min,
soaking and washing at 40-50 deg.C for 40-60min,
vulcanizing at 95-115 deg.C for 60-90 min.
The invention has the beneficial effects that:
the glove dipping latex is added with miscellaneous piezoelectric induction crystal dispersion powder, and the latex is blended and modified. Various energy forms are wasted along with human activities in daily life, and even certain damage is caused to work in special environments, such as electrostatic effect. The device can collect relevant energy from the human activity process at any time and any place and convert the relevant energy into beneficial electric energy.
Detailed Description
The invention will be further illustrated with reference to specific embodiments:
the modified latex comprises the following components in parts by weight:
100 portions of carboxylated nitrile latex and 110 portions of carboxylated nitrile latex,
1-2 parts of potassium hydroxide, namely,
1 to 1.5 portions of sulfur,
1.5 to 3 parts of zinc oxide,
1-2 parts of titanium dioxide powder,
0.01 to 0.03 portion of dispersant,
10-20 parts of microsphere triboelectric effect powder,
3-8 parts of sodium polyacrylate.
Comprises the following components in parts by weight:
100 parts of carboxylic acrylonitrile-butadiene latex,
1 part of potassium hydroxide, namely potassium hydroxide,
0.8 part of sulfur, namely,
2 parts of zinc oxide, namely zinc oxide,
0.5 to 1.2 portions of accelerant,
2 parts of titanium dioxide, namely 2 parts of titanium dioxide,
0.02 part of a dispersant, namely,
20 parts of microsphere friction power generation effect powder,
0.8 to 1.8 portions of anti-aging agent,
1-2 parts of black pigment,
5 parts of sodium polyacrylate.
The microsphere friction power generation effect powder comprises the following components in parts by weight:
1 to 10 portions of zinc metastannate crystal,
80-90 parts of polydimethylsiloxane,
1-10 parts of nano silver powder.
The microsphere friction power generation effect powder comprises the following components in parts by weight:
2 parts of zinc metastannate crystal powder,
90 parts of dimethyl silicone Polymer (PDMS),
and 8 parts of nano silver powder.
The preparation method of the microsphere triboelectricity generation effect powder comprises the following steps,
mixing zinc metastannate crystal powder, nano silver powder and polydimethylsiloxane;
the mixture was evacuated and heated to 50 ℃;
stirring and drying the mixture;
and (5) obtaining the microsphere triboelectricity generation effect powder after drying.
The preparation method of the modified latex comprises the following steps of,
mixing the raw materials, controlling the viscosity at 1500-,
and adding the prepared latex into a vacuumizing device for defoaming treatment.
The raw material mixing method comprises the following specific steps: mixing carboxylic butyronitrile latex, potassium hydroxide, sulfur, zinc oxide, an accelerant, titanium dioxide and a dispersing agent to form a latex system,
adding the micro-sphere friction power generation effect powder, stirring,
adding sodium polyacrylate for thickening.
The method for preparing the glove with the friction power generation function comprises the following steps
The glove core is preheated, and then the glove core is preheated,
dipping the mixture into the modified latex in the preamble,
pre-vulcanizing at 65-85 deg.C for 60-90min,
soaking and washing at 40-50 deg.C for 40-60min,
vulcanizing at 95-115 deg.C for 60-90 min.
Example 1
The formula of the microsphere friction power generation effect powder modified latex comprises the following raw materials in parts by weight: 100 parts of carboxylic butyronitrile latex, 1 part of KOH, 0.8 part of sulfur, 3.0 parts of zinc oxide, 1.0 part of accelerator, 2.0 parts of titanium dioxide, 0.02 part of dispersant, 20 parts of microsphere friction power generation effect powder, 0.8 part of anti-aging agent, 2 parts of black pigment and 5 parts of sodium polyacrylate.
(1) ZnSnO32 parts of (zinc metastannate) crystal powder, 90 parts of PDMS (polydimethylsiloxane) and 8 parts of nano silver powder are mixed;
(2) the mixture was evacuated and heated to 50 ℃;
(3) stirring and drying the mixture;
(4) and (5) obtaining the microsphere triboelectricity generation effect powder after drying.
A preparation method of a friction power generation functional glove comprises the following steps:
preparing latex according to the proportion, and controlling the viscosity at 2500 mps;
adding the prepared latex into a vacuumizing device for defoaming;
preheating the selected carbon wire inner container on the hand mold sleeve for 30min at 70 ℃;
dipping latex, and homogenizing for 240s at 40 ℃;
pre-sulfurizing (85 deg.C for 90min), soaking and washing (50 deg.C for 60min), and sulfurizing (115 deg.C for 90 min);
and demolding to obtain the glove product.
For the mobile phone power, a power storage battery can be arranged.
Example 2
The formula of the microsphere friction power generation effect powder modified latex comprises the following raw materials in parts by weight: 80 parts of carboxylic butyronitrile latex, 20 parts of carboxylic butylbenzene latex, 1 part of KOH, 0.8 part of sulfur, 3.0 parts of zinc oxide, 1.0 part of accelerator, 2.0 parts of titanium dioxide, 0.02 part of dispersant, 20 parts of microsphere friction power generation effect powder, 0.8 part of anti-aging agent, 2 parts of black pigment and 5 parts of sodium polyacrylate.
(1) ZnSnO32 parts of (zinc metastannate) crystal powder, PDMS (polydimethylsiloxane silica)Alkane) 90 parts and nano silver powder 8 parts;
(2) the mixture was evacuated and heated to 50 ℃;
(3) stirring and drying the mixture;
(4) and (5) obtaining the microsphere triboelectricity generation effect powder after drying.
A preparation method of a microsphere friction power generation functional glove comprises the following steps:
preparing latex according to the proportion, and controlling the viscosity at 1500 mps;
adding the prepared latex into a vacuumizing device for defoaming;
a carbon wire inner container is selected on the hand mold sleeve, and the hand mold sleeve is preheated for 20min in an oven at 70 ℃;
dipping latex, and homogenizing at 40 ℃ for 180 s;
pre-sulfurizing (65 deg.C for 60min), soaking and washing (40 deg.C for 40min), and sulfurizing (95 deg.C for 90 min);
and demolding to obtain the glove product.
Example 3
The formula of the microsphere friction power generation effect powder modified latex comprises the following raw materials in parts by weight: 80 parts of carboxylic butyronitrile latex, 20 parts of carboxylic butylbenzene latex, 1 part of KOH, 0.8 part of sulfur, 3.0 parts of zinc oxide, 1.0 part of accelerator, 2.0 parts of titanium dioxide, 0.02 part of dispersant, 20 parts of microsphere friction power generation effect powder, 0.8 part of anti-aging agent, 2 parts of black pigment and 5 parts of sodium polyacrylate.
(1) ZnSnO32 parts of (zinc metastannate) crystal powder, 90 parts of PDMS (polydimethylsiloxane) and 8 parts of nano silver powder are mixed;
(2) the mixture was evacuated and heated to 50 ℃;
(3) stirring and drying the mixture;
(4) and (5) obtaining the microsphere triboelectricity generation effect powder after drying.
A preparation method of a microsphere friction power generation functional glove comprises the following steps:
preparing latex according to the proportion, and controlling the viscosity to be 3500 mps;
adding the prepared latex into a vacuumizing device for defoaming;
a selected steel wire on the hand mold sleeve covers the inner container, and the inner container is preheated in an oven for 25in at 70 ℃;
dipping latex, and homogenizing for 200s at 40 ℃;
pre-vulcanizing (70 deg.C for 60-90min), soaking and washing (45 deg.C for 45min), and vulcanizing (100 deg.C for 90 min);
and demolding to obtain the glove product.
The glove can collect related energy from the human activity process at any time and any place and convert the related energy into beneficial electric energy, and the glove has a good power generation effect.
It will be apparent to those skilled in the art that various modifications may be made to the above embodiments without departing from the general spirit and concept of the invention. All falling within the scope of protection of the present invention. The protection scheme of the invention is subject to the appended claims.
Claims (8)
1. Modified latex, characterized in that: comprises the following components in parts by weight:
100 portions of carboxylated nitrile latex and 110 portions of carboxylated nitrile latex,
1-2 parts of potassium hydroxide, namely,
1 to 1.5 portions of sulfur,
1.5 to 3 parts of zinc oxide,
1-2 parts of titanium dioxide powder,
0.01 to 0.03 portion of dispersant,
10-20 parts of microsphere triboelectric effect powder,
3-8 parts of sodium polyacrylate.
2. The modified latex according to claim 1, wherein: comprises the following components in parts by weight:
100 parts of carboxylic acrylonitrile-butadiene latex,
1 part of potassium hydroxide, namely potassium hydroxide,
0.8 part of sulfur, namely,
2 parts of zinc oxide, namely zinc oxide,
0.5 to 1.2 portions of accelerant,
2 parts of titanium dioxide, namely 2 parts of titanium dioxide,
0.02 part of a dispersant, namely,
20 parts of microsphere friction power generation effect powder,
0.8 to 1.8 portions of anti-aging agent,
1-2 parts of black pigment,
5 parts of sodium polyacrylate.
3. The modified latex according to claim 1, wherein: the microsphere friction power generation effect powder comprises the following components in parts by weight:
1 to 10 portions of zinc metastannate crystal,
80-90 parts of polydimethylsiloxane,
1-10 parts of nano silver powder.
4. The modified latex according to claim 3, wherein: the microsphere friction power generation effect powder comprises the following components in parts by weight:
2 parts of zinc metastannate crystal powder,
90 parts of dimethyl silicone Polymer (PDMS),
and 8 parts of nano silver powder.
5. The modified latex according to claim 3, wherein: the preparation method of the microsphere triboelectricity generation effect powder comprises the following steps,
mixing zinc metastannate crystal powder, nano silver powder and polydimethylsiloxane;
the mixture was evacuated and heated to 50 ℃;
stirring and drying the mixture;
and (5) obtaining the microsphere triboelectricity generation effect powder after drying.
6. The modified latex according to claim 1, wherein: the preparation method of the modified latex comprises the following steps of,
mixing the raw materials, controlling the viscosity at 1500-,
and adding the prepared latex into a vacuumizing device for defoaming treatment.
7. The modified latex according to claim 6, wherein: the raw material mixing method comprises the following specific steps: mixing carboxylic butyronitrile latex, potassium hydroxide, sulfur, zinc oxide, an accelerant, titanium dioxide and a dispersing agent to form a latex system,
adding the micro-sphere friction power generation effect powder, stirring,
adding sodium polyacrylate for thickening.
8. The preparation method of the friction power generation functional glove is characterized by comprising the following steps: comprises that
The glove core is preheated, and then the glove core is preheated,
dipping the modified latex of any one of claims 1 to 5,
pre-vulcanizing at 65-85 deg.C for 60-90min,
soaking and washing at 40-50 deg.C for 40-60min,
vulcanizing at 95-115 deg.C for 60-90 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN202011363691.3A CN112552569A (en) | 2020-11-27 | 2020-11-27 | Preparation method of modified latex and friction power generation functional gloves |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202011363691.3A CN112552569A (en) | 2020-11-27 | 2020-11-27 | Preparation method of modified latex and friction power generation functional gloves |
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| CN112552569A true CN112552569A (en) | 2021-03-26 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003096417A (en) * | 2001-09-27 | 2003-04-03 | Teraoka Seisakusho:Kk | Flame-retardant adhesive cloth tape |
| WO2014139346A1 (en) * | 2013-03-12 | 2014-09-18 | 国家纳米科学中心 | Sliding frictional nano generator and power generation method |
| CN204670447U (en) * | 2015-04-22 | 2015-09-30 | 纳米新能源（唐山）有限责任公司 | Based on the sterilizing gloves of triboelectricity |
| US20150349664A1 (en) * | 2013-01-28 | 2015-12-03 | Peking University | Single friction surface triboelectric microgenerator and method of manufacturing the same |
| CN108976534A (en) * | 2018-07-10 | 2018-12-11 | 南通腾拓手套有限公司 | A kind of safety and industrial gloves and its manufacture craft of the ultra-thin anti-skidding skin care of butyronitrile |
-
2020
- 2020-11-27 CN CN202011363691.3A patent/CN112552569A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003096417A (en) * | 2001-09-27 | 2003-04-03 | Teraoka Seisakusho:Kk | Flame-retardant adhesive cloth tape |
| US20150349664A1 (en) * | 2013-01-28 | 2015-12-03 | Peking University | Single friction surface triboelectric microgenerator and method of manufacturing the same |
| WO2014139346A1 (en) * | 2013-03-12 | 2014-09-18 | 国家纳米科学中心 | Sliding frictional nano generator and power generation method |
| CN204670447U (en) * | 2015-04-22 | 2015-09-30 | 纳米新能源（唐山）有限责任公司 | Based on the sterilizing gloves of triboelectricity |
| CN108976534A (en) * | 2018-07-10 | 2018-12-11 | 南通腾拓手套有限公司 | A kind of safety and industrial gloves and its manufacture craft of the ultra-thin anti-skidding skin care of butyronitrile |
Non-Patent Citations (1)
| Title |
|---|
| 王果: "基于ZnSO3@PDMS介电复合膜的摩擦电纳米发电机的研究", 《中国优秀博硕士学位论文全文数据库（硕士） 工程科技II辑》 * |
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