CN112521860A - Multifunctional primer with consolidation and permeability - Google Patents
Multifunctional primer with consolidation and permeability Download PDFInfo
- Publication number
- CN112521860A CN112521860A CN202011318481.2A CN202011318481A CN112521860A CN 112521860 A CN112521860 A CN 112521860A CN 202011318481 A CN202011318481 A CN 202011318481A CN 112521860 A CN112521860 A CN 112521860A
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- Prior art keywords
- permeability
- consolidation
- primer
- multifunctional primer
- putty
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a multifunctional primer with consolidation and permeability, which consists of the following raw materials: the invention can be applied to the engineering of dams, tunnels, bridges, civil buildings and the like, has controllable permeability and controllable mechanical property on cement base layers and putty, can well permeate into pores of concrete and putty layers by self, and can be cured and crosslinked in situ, so that a coating is formed on the surface of the primer, a root-planting type consolidation reinforcing layer is formed in a structural layer, good adhesion is provided for the interlayer, and the primer has excellent permeability resistance and salt-overtaking resistance and alkaline performance.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to a multifunctional primer with consolidation and permeability.
Background
Most of putty layers for buildings are loose and low in strength, meanwhile, concrete has a porous structure, water and ions can permeate into the interior of the putty layers through the pores of the putty layers to corrode the putty layers, the service life of the buildings and the service life of finish paint are directly affected, and the loosening of base layers is one of the main reasons for causing quality defects of paint films.
Most of the building primers in the current market adopt acrylic polymers produced by common processes as film-forming substances, and the emulsion has poor permeability and no consolidation, so that a good base reinforcing effect cannot be achieved
Concrete is also a brittle material, and under the action of stress, the concrete is easy to crack and lose efficacy, so that huge economic loss and serious potential safety hazard are caused. Therefore, concrete protection is an important problem related to the national civilization and industrial construction, and the development of high-performance concrete protection materials is an important direction for prolonging the service life of concrete; therefore, how to add a reinforcing layer on the concrete to form a putty layer with effective protection function is a difficult problem.
Disclosure of Invention
Technical problem to be solved
In order to solve the problems in the prior art, the invention provides the multifunctional primer with the consolidation and permeability performance, which can be applied to the engineering of dams, tunnels, bridges, civil buildings and the like, has controllable permeability and controllable mechanical property on cement bases and putty, can well self-permeate into pores of concrete and putty layers, is cured and crosslinked in situ, forms a coating on the surface of the primer, forms a root-planting consolidation reinforcing layer in a structural layer, provides good adhesion for the layers, and has excellent permeability resistance and salt-overtaking resistance.
(II) technical scheme
In order to achieve the purpose, the invention adopts the main technical scheme that:
the multifunctional primer with the consolidation and permeability performance comprises the following raw materials in percentage by weight:
further, the defoaming agent is silicone.
Further, the solid content of the hyperbranched emulsion is more than 60%, and the initial viscosity is less than 10mPa & s.
Further, the thickener is a nonionic thickener.
(III) advantageous effects
The invention has the beneficial effects that: the hyperbranched emulsion is the highly branched three-dimensional macromolecule which is the most different from the traditional emulsion polymerization, the hyperbranched polymer has a plurality of branching points, molecular chains are not easy to tangle, the viscosity is not changed along with the increase of molecular weight, and the hyperbranched emulsion has rich terminal functional groups, is easy to modify and modify, and is beneficial to synthesizing various functional materials.
Drawings
FIG. 1 is a schematic diagram of the molecular formula of the hyperbranched emulsion of the invention.
Detailed Description
For the purpose of better explaining the present invention and to facilitate understanding, the present invention will be described in detail by way of specific embodiments with reference to the accompanying drawings.
The multifunctional primer with the consolidation and permeability performance comprises the following raw materials in percentage by weight:
further, the defoaming agent is silicone.
Further, the solid content of the hyperbranched emulsion is more than 60%, and the initial viscosity is less than 10mPa & s.
Further, the thickener is a nonionic thickener.
As shown in figure 1, the hyperbranched emulsion is used, the biggest difference between the hyperbranched emulsion and the traditional emulsion polymerization is that the hyperbranched polymer is a highly branched three-dimensional macromolecule, the hyperbranched polymer has a plurality of branching points, molecular chains are not easy to tangle, the viscosity is not changed along with the increase of molecular weight, and the hyperbranched polymer has rich terminal functional groups, is easy to modify and is beneficial to synthesizing various functional materials.
The nonionic wetting agent added in the invention is any one of Emulsogen LCN 407 and DOW TRITON @ CF-10 of Craine.
The antifoam agent of the invention is selected from the group consisting of cotinineNXZ, CorningA10, KeningA36 and/or Dispelair CF 246 of Blackbook.
The preservative of the present invention is selected from Kathon of Rohm and HaasTMLXE, Rocima of Rohm and HaasTM361. ROZONE OF ROMOHASTM2000.
The film forming aid in the invention is TEAXAL of Istman.
The hyperbranched emulsion is one of HBP WE1051A and HyPer CPP of Wuhan hyperbranched emulsion GmbH.
Thickening in the inventionThe agent is selected from ACRYSOL 2020NPR of Rohm and Haas, ACRYSOL RM-8W of Rohm and PasteurLR 8990, basfAt least one of PU 75.
Example 1
Weighing 34.4 parts of water according to 100 parts by weight, and sequentially adding the nonionic wetting agent PE-100 at the rotating speed of 300-600 rpm: 0.25 part, 1.0 part of propylene glycol and defoaming agentNXZ: 0.5 part, dispersed for 5 minutes; sequentially adding a film forming additive TEAXNAL at the rotating speed of 600-1000 rpm: 3 portions of preservative KathonTMLXE: 0.2 part, dispersing for 5 minutes, and then adding the hyperbranched emulsion HBP WE 1051A: 60 portions of defoaming agentA10: 0.2 parts of thickener ACRYSOL RM-8W: 0.45 part, dispersed for 5 minutes; sampling and inspecting quality; filtering and packaging after the product is qualified.
Example 2
Weighing 19.4 parts of water by weight according to 100 parts of water by weight, and sequentially adding a nonionic wetting agent PE-100: 0.25 part, 1.0 part of propylene glycol and defoaming agentNXZ: 0.5 part, dispersed for 5 minutes; sequentially adding a film forming additive TEAXNAL at the rotating speed of 600-1000 rpm: 3 portions of preservative KathonTMLXE: 0.2 part, dispersing for 5 minutes, and then adding the hyperbranched emulsion HBP WE 1051A: 75 portions of defoaming agentA10: 0.2 parts of thickener ACRYSOL RM-8W: 0.45 part, dispersed for 5 minutes; sampling and inspecting quality;filtering and packaging after the product is qualified.
Specific properties of examples 1 and 2 are shown in table 1:
TABLE 1
As can be seen from Table 1, the coating film property test data of examples 1 and 2 meet the JG/210-.
The above description is only a preferred embodiment of the present invention, and all equivalent changes and modifications made in accordance with the claims of the present invention should be covered by the present invention.
Claims (4)
2. the multifunctional primer with consolidated permeability according to claim 1, wherein the defoamer is of silicone type.
3. The multifunctional primer with consolidated permeability according to claim 1, wherein the hyperbranched emulsion has a solid content of more than 60% and an initial viscosity of less than 10 mPa-s.
4. The multifunctional primer with consolidated permeability according to claim 1, wherein the thickener is a nonionic thickener.
Priority Applications (1)
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CN202011318481.2A CN112521860A (en) | 2020-11-23 | 2020-11-23 | Multifunctional primer with consolidation and permeability |
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CN202011318481.2A CN112521860A (en) | 2020-11-23 | 2020-11-23 | Multifunctional primer with consolidation and permeability |
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CN112521860A true CN112521860A (en) | 2021-03-19 |
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CN202011318481.2A Pending CN112521860A (en) | 2020-11-23 | 2020-11-23 | Multifunctional primer with consolidation and permeability |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2016111A1 (en) * | 2006-05-09 | 2009-01-21 | Evonik Degussa GmbH | Hyper-branched polyurethanes method for production and use thereof |
CN108753174A (en) * | 2018-06-21 | 2018-11-06 | 广东高登刷新科技有限责任公司 | High osmosis consolidates wall alkali-resistant sealing primer |
CN109651925A (en) * | 2018-12-19 | 2019-04-19 | 成都新柯力化工科技有限公司 | A kind of hydrophobic osmosis type coating and preparation method for building concrete surface |
CN110343450A (en) * | 2019-08-09 | 2019-10-18 | 黄石乐佳化学材料有限公司 | It is a kind of water-soluble to penetrate into consolidation type macromolecule composite water-proof paint and its preparation method and application |
CN111454645A (en) * | 2020-05-19 | 2020-07-28 | 重庆天壹交通工程有限公司 | Waterproof agent and application method thereof |
CN111718654A (en) * | 2020-07-28 | 2020-09-29 | 三棵树涂料股份有限公司 | Reaction type seal primer with super-strong salt-efflorescence-resistant performance and preparation method thereof |
-
2020
- 2020-11-23 CN CN202011318481.2A patent/CN112521860A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2016111A1 (en) * | 2006-05-09 | 2009-01-21 | Evonik Degussa GmbH | Hyper-branched polyurethanes method for production and use thereof |
CN108753174A (en) * | 2018-06-21 | 2018-11-06 | 广东高登刷新科技有限责任公司 | High osmosis consolidates wall alkali-resistant sealing primer |
CN109651925A (en) * | 2018-12-19 | 2019-04-19 | 成都新柯力化工科技有限公司 | A kind of hydrophobic osmosis type coating and preparation method for building concrete surface |
CN110343450A (en) * | 2019-08-09 | 2019-10-18 | 黄石乐佳化学材料有限公司 | It is a kind of water-soluble to penetrate into consolidation type macromolecule composite water-proof paint and its preparation method and application |
CN111454645A (en) * | 2020-05-19 | 2020-07-28 | 重庆天壹交通工程有限公司 | Waterproof agent and application method thereof |
CN111718654A (en) * | 2020-07-28 | 2020-09-29 | 三棵树涂料股份有限公司 | Reaction type seal primer with super-strong salt-efflorescence-resistant performance and preparation method thereof |
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Application publication date: 20210319 |