CN112500196A - Ceramic tile with stereoscopic gem particle feeling glaze and preparation method thereof - Google Patents
Ceramic tile with stereoscopic gem particle feeling glaze and preparation method thereof Download PDFInfo
- Publication number
- CN112500196A CN112500196A CN202011337575.4A CN202011337575A CN112500196A CN 112500196 A CN112500196 A CN 112500196A CN 202011337575 A CN202011337575 A CN 202011337575A CN 112500196 A CN112500196 A CN 112500196A
- Authority
- CN
- China
- Prior art keywords
- glaze
- gem
- particle
- dry
- ceramic tile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a ceramic tile with a glaze surface with three-dimensional gem particle sense and a preparation method thereof. The preparation method comprises the following steps: applying a cover glaze on the surface of the blank and carrying out ink-jet printing on a pattern; applying dry grain glaze on the surface of the blank after the pattern is printed by ink jet; the dry particle glaze comprises, by weight, 45-65 parts of transparent dry particle glaze powder and 10-20 parts of gem leftover materials; finally, the ceramic tile with the glaze surface with the stereoscopic gem particle sense is formed by sintering. The invention realizes the glaze effect of three-dimensional gem particle sense by using the color gem leftover material, the added color gem leftover material and the transparent glaze have better fusion property, the defects of air holes and the like can not occur, the color can stably exist in the firing process, the color diffusion can not occur, and the firing process of the kiln can not be influenced or has less influence.
Description
Technical Field
The invention belongs to the field of architectural ceramics, and particularly relates to a ceramic tile with a stereoscopic gem particle feeling glaze surface and a preparation method thereof.
Background
Building ceramic tiles are widely used for home decoration as a decorative material with excellent performance. The ink-jet printing technology gives ceramic colors, however, the wide application of the ink-jet printing technology also leads to the increasingly serious homogenization of ceramic products, and personalized products are difficult to appear. In addition, the inkjet printed pattern decoration is a two-dimensional plane decoration. Granular crystal flowers are separated out from the glaze in a crystallization mode, and the ceramic tile with the three-dimensional glaze feeling can be prepared by matching with ink-jet printing patterns. However, the crystallization has high requirements on the temperature system of the kiln, and the expansion coefficients of different crystallization frits are different, so that the glaze surface cracks due to different expansion coefficients when different crystallization frits are mixed for use. It has also been reported that a mixture of colored frit and transparent frit is used to form a three-dimensional glaze effect, but the colored frit itself is added with a colorant to form a color dot on the basis of the transparent frit, so that the colorant in the colored frit diffuses at high temperature, which results in no granular effect, and even poor overall plate effect. Moreover, the traditional pigment is synthesized through a high-temperature solid-phase reaction, and the mixing of molecular levels is not realized in the synthesis process, so that the color is poor after the pigment is crushed and refined, and the coloring effect of colored particles is further limited.
Disclosure of Invention
Aiming at the problems brought forward by the background technology, the invention realizes the glaze effect of three-dimensional gem particle sense by using the color gem leftover material, the added color gem leftover material and the transparent glaze have better fusion performance, the defects of air holes and the like can not occur, the color can stably exist in the firing process, the color diffusion can not occur, and the firing process of the kiln can not be influenced or has less influence.
In a first aspect, the invention provides a method for preparing a ceramic tile with a glaze surface with a stereoscopic gem particle sense. The preparation method comprises the following steps:
applying a cover glaze on the surface of the blank and carrying out ink-jet printing on a pattern;
applying dry grain glaze on the surface of the blank after the pattern is printed by ink jet; the dry particle glaze comprises, by weight, 45-65 parts of transparent dry particle glaze powder and 10-20 parts of gem leftover materials;
finally, the ceramic tile with the glaze surface with the stereoscopic gem particle sense is formed by sintering.
Preferably, the specific gravity of the dry granular glaze is 1.6-1.9 g/cm3. The specific gravity of the gem leftover is larger, and is generally 4.0-4.1 g/cm3. In the dry grain glaze, the weight part of the gem leftover materials is not more than 20 parts, otherwise, the gem leftover materials and the dry grain glaze slip have larger specific gravity difference, which can cause the settlement of gem particles to cause the concave pits, the bubbles and the like on the glaze surface. The weight portion of the transparent dry grain glaze powder in the dry grain glaze is not less than 45, otherwise, the color difference and the color mark appear on the brick surface because the transparent dry grain glaze powder is too little.
Preferably, the melting temperature of the transparent dry particle glaze powder is 1100-1200 ℃.
Preferably, the chemical composition of the transparent dry particle glaze powder comprises: by mass percent, SiO2：40～45％，Al2O3: 14 to 18%, alkaline earth metal oxide: 19 to 25%, alkali metal oxide: 4-8%.
Preferably, the melting starting temperature of the gem leftover materials is 1200-1300 ℃.
Preferably, the gemstone scraps are sapphire and/or ruby. More preferably, the chemical composition of the gemstone scraps comprises: by mass percentage, Al2O3：95～99.9％，CrO3：1～5％，Fe2O3：0.01～0.05％。
The kinds of precious stones are many, such as pearls, emeralds, pearls, lapis, opals, etc. However, the chemical compositions of different kinds of gemstones are different, for example, the chemical composition of pearl includes calcium carbonate, magnesium carbonate, calcium phosphate, alumina, iron oxide and organic matter. However, the introduction of the chemical composition can affect the high-temperature performance and effect of the ceramic glaze. The invention adopts sapphire and ruby, has single and stable components, belongs to eight elements of ceramic raw materials, has stable structure, is not easy to react at high temperature, and can keep the decoration effect of the ceramic. Therefore, the components of the gem leftover materials are preferably high-temperature elements, the reaction cannot occur in the firing process, and the gem leftover materials cannot contain elements harmful to the glaze, such as boron, fluorine and the like, and the structure of the gem leftover materials is stable.
Preferably, the glazing amount of the dry granular glaze is 1000-1200 g/m2. The low glazing amount of the dry particle glaze may cause poor fusion flatness of the gem particle material and the glaze material. Too high an amount of dry glaze particles will result in material waste and increased costs. In addition, the thickness of the glaze layer is too thick due to excessive application of dry granular glaze, bubbles are difficult to discharge at high temperature to generate bubbles, and more pores appear after polishing, so that the glaze effect is influenced.
Preferably, the glazing mode of the dry granular glaze is glaze pouring. The glaze spraying mode is not suitable for the technical scheme of the invention because the glaze spraying effect is not uniform due to the gravity of dry particle glaze, and the glaze spraying nozzle is easy to be blocked by the gem leftover materials to influence the brick surface effect, and the glaze spraying efficiency is low, so that the cost is increased. The above problems can be well avoided by adopting glaze pouring.
Preferably, the dry particle glaze further comprises 80-100 parts by weight of a dry particle suspending agent. The dry particle suspending agent is used for fixing dry particles, so that the glaze is prevented from being blown away by hot air of a kiln in the firing process due to poor dry particle glaze fluidity and adhesive force. In addition, the suspension property of the dry granular glaze can be increased, the occurrence of precipitation is reduced, and the glaze slip is more uniform.
The particle size of the gem leftover is preferably controlled to be 60-100 meshes. The particle size of the gemstone offcuts is tightly controlled. The gem leftover belongs to a high-temperature material, and the combination of the gem leftover and the glaze layer is not good due to too large grain diameter. Moreover, the gemstone scraps with large particle size can cause the agglomeration caused by insufficient dispersion of gemstone particles in the glazing process, resulting in uneven glazing, and consequently, glaze defects such as ripples. Too large a particle size will also exacerbate the settling of the gemstone particles. Moreover, when the brick surface is polished, the large particles of the polishing abrasive block easily bring out all or most of the gem leftover materials, and gem pits appear on the brick surface. The particle size of the gem leftover is too small, the decorative effect is not good enough, and a good stereoscopic gem particle feeling glaze surface cannot be generated.
Preferably, the maximum firing temperature is 1150-1210 ℃, and the firing period is 55-65 minutes.
Preferably, the specific gravity of the overglaze is 1.50-1.53 g/cm3The glazing amount is 500-550 g/m2。
In a second aspect, the invention also provides a ceramic tile with a stereoscopic glaze-like gem particle feeling, which is obtained by the preparation method.
Detailed Description
The present invention is further illustrated by the following examples, which are to be understood as merely illustrative of, and not restrictive on, the present invention. Unless otherwise specified, each percentage means a mass percentage.
The preparation method of the ceramic tile with the glaze surface with the stereoscopic gem particle feeling is exemplified as follows.
And pressing and forming the blank by using the blank powder. The chemical composition of the green body powder is not limited, and the conventional green body powder can be adopted. For example, the chemical composition of the green body powder may include: by mass percent, SiO2：60～65％、Al2O3：20～25％、K2O：1～4％、Na2O: 2-4%, loss on ignition: 1 to 5 percent.
And drying the green body. The drying time can be 1-1.5 h. Controlling the water content of the dried blank to be 0.1-0.5 wt%.
And applying surface glaze on the surface of the blank. The overglaze has the functions of covering the blank ground color flaws and enabling the color development effect of the ink-jet printed patterns to be better.
The chemical composition of the overglaze is not limited, and the overglaze composition conventional in the field can be adopted. The chemical composition of the overglaze may include: by mass percent, SiO2：60～68％、Al2O3: 20-24%, alkaline earth metal oxide: 0 to 1%, alkali metal oxide: 4 to 9% of ZrO2: 3.2-9.6%, loss on ignition: 1.3 to 1.7 percent. As an example, the chemical composition of the overglaze comprises: by mass percent, SiO2：60～68％、Al2O3：20～24％、CaO：0.3～0.6％、MgO：0.1～0.3％、K2O：1.5～2.5％、Na2O：3～4％、ZrO2: 3.2-9.6%, loss on ignition: 1.3 to 1.7 percent.
The glazing mode of the overglaze can be glaze spraying. The glazing process of the overglaze has little influence on the appearance of the effect of the gem particles. In some embodiments, the overglaze has a specific gravity of 1.50 to 1.53g/cm3The glazing amount is 500-550 g/m2。
And (4) carrying out ink-jet printing on the surface of the blank body after the overglaze is applied. And drying the blank after the pattern is printed by ink jet. The drying time may be 5 min.
And preparing dry grain glaze. The dry glaze particles may include transparent dry glaze powder, gemstone leftovers, and dry suspending agents. The "dry particle suspension" may also be referred to as "stamp-pad ink" or "glue". The stamp-pad ink has the function of enabling dry grain glaze to be better attached to the surface of the brick and reducing the defects of the glaze surface. Generally, the mass ratio of the total amount of the transparent dry-grain glaze powder and the gem leftover materials to the dry-grain suspending agent is preferably controlled to be 1: 1-1.5. In some embodiments, the dry particulate glaze may include: according to parts by weight, 45-65 parts of transparent dry grain glaze powder, 10-20 parts of gem leftover materials and 80-100 parts of dry grain suspending agents.
Preferably, the mass ratio of the transparent dry-grain glaze powder to the gem leftover material can be 2: 1-4.5: 1. the mass ratio is controlled in the range, so that the enough consumption of the gem leftover materials can be ensured to obtain excellent glaze decoration effect, and the defects of color difference, color marks and the like caused by lower consumption of the transparent dry grain glaze powder can be avoided. In some embodiments, the chemical composition of the transparent dry glaze powder may include: by mass percent, SiO2：40～45％，Al2O3：14～18％，CaO：3.5～4.5％，MgO：2.5～4％，BaO：14.5～16％，ZnO：3～3.8％，K2O：2.1～3.5％，Na2O：2.5～3.5％。
The gem leftover material can be ruby or sapphire leftover material. The main component of ruby is alumina, which is red in color because the ruby is formed by doping the alumina lattice with chromium oxide due to geological motion. The main component of sapphire is also alumina, which appears blue because the alumina lattice is doped with titanium oxide. Sapphire and ruby are colored by doping with impurity ions into alumina crystal lattices, so that the color generation effect does not change with the change of the particle size. The natural sapphire leftover materials in the nature can exist stably at high temperature, color diffusion cannot occur, and the stereoscopic impression after sintering is strong. And the cost of the red sapphire leftover material is lower, the processing and the use are convenient, and the industrial production is easy to realize.
The particle size of the gem leftover material particles can be 60-100 meshes.
And drying the glaze particles on the surface of the blank after ink-jet printing. In some embodiments, the chemical composition of the dry particulate glaze may include: by mass percent, SiO2：40～45％，Al2O3：14～18％，CaO：3.5～4.5％，MgO：2.5～4％，BaO：14.5～16％，ZnO：3～3.8％，K2O：2.1～3.5％，Na2O：2.5～3.5％。
The bell jar can be used for pouring glaze. In some embodiments, the dry particle glaze has a specific gravity of 1.6-1.9 g/cm3The glazing amount is 1000-1200 g/m2. The thick shower is adopted to ensure that the gem leftover particles are more uniformly distributed in the glaze layer, the fired glaze layer is transparent, and the gem particle particles exist in the glaze layer in a particle form by the thick glaze layer, so that a more three-dimensional brick surface effect is obtained. Preferably, the specific gravity of the dry granular glaze is 1.8-1.89 g/cm3。
And drying after the glaze pouring is finished, and firing in a kiln. Controlling the highest firing temperature to 1150-1210 ℃, firing time to 55-65 min, and taking out of the kiln to obtain a finished product.
It will be appreciated that the effect of the invention may also be achieved by adding gem stone leftover particles to the frit to produce dry frit pellets. In particular, in order to realize the three-dimensional property of glaze layer pattern decoration, the process of glue dry particles can be used for positioning the gem particles, thereby achieving a new decoration effect.
The present invention will be described in detail by way of examples. It is also to be understood that the following examples are illustrative of the present invention and are not to be construed as limiting the scope of the invention, and that certain insubstantial modifications and adaptations of the invention by those skilled in the art may be made in light of the above teachings. The specific process parameters and the like of the following examples are also only one example of suitable ranges, i.e., those skilled in the art can select the appropriate ranges through the description herein, and are not limited to the specific values exemplified below.
Example 1
(1) And pressing and molding the blank powder to form a blank.
(2) And drying the green body. The drying time is 1h, and the water content of the dried ceramic body is 0.3 wt%.
(3) And applying surface glaze on the surface of the dried blank. The overglaze comprises the following chemical components: by mass percent, SiO2：64％、Al2O3：22％、CaO：0.45％、MgO：0.2％、K2O：2.0％、Na2O：3.5％、ZrO2: 6.5%, loss on ignition: 1.5 percent. The specific gravity of the overglaze is 1.52g/cm3The glazing amount is 500g/m2。
(4) And (4) printing a pattern on the surface of the blank in an ink jet mode.
(5) And drying the blank body after the pattern is printed by ink jet for 3 min.
(6) And preparing dry grain glaze. The dry particle glaze comprises: 45 parts of transparent dry grain glaze powder, 20 parts of gem leftover materials and 80 parts of stamp-pad ink. The chemical composition of the transparent dry particle glaze powder comprises: by mass percent, SiO2：42.5％，Al2O3：16％，CaO：4.0％，MgO：3.25％，BaO：15％，ZnO：3.5％，K2O：3.0％，Na2O: 2.8 percent. The chemical composition of the gem leftover material comprises: by mass percentage, Al2O3：98％，CrO3：1.95％，Fe2O3: 0.05 percent. The particle size of the gem leftover is 100 meshes.
(7) And drying the grain glaze on the surface of the blank after the pattern is printed by ink jet. The specific gravity of the dry granular glaze is 1.8g/cm3The glazing amount is 1000g/m2。
(8) And drying the green body after the glaze particles are sprayed and dried, and firing. The highest firing temperature is 1150-1210 ℃, the firing time is 55-65 min, and the ceramic tile with the glaze surface with the stereoscopic gem particle sense is obtained after the ceramic tile is taken out of the kiln.
Example 2
(1) And pressing and molding the blank powder to form a blank.
(2) And drying the green body. The drying time is 1.5h, and the water content of the dried ceramic body is 0.1 wt%.
(3) And applying surface glaze on the surface of the dried blank. The overglaze comprises the following chemical components: by mass percent, SiO2：60％、Al2O3：20％、CaO：0.3％、MgO：0.1％、K2O：1.5％、Na2O：3％、ZrO2: 3.2%, loss on ignition: 1.3 percent. The specific gravity of the overglaze is 1.50g/cm3The glazing amount is 550g/m2。
(4) And (4) printing a pattern on the surface of the blank in an ink jet mode.
(5) And drying the blank body after the pattern is printed by ink jet for 3 min.
(6) And preparing dry grain glaze. The dry particle glaze comprises: 50 parts of transparent dry grain glaze powder, 16 parts of gem leftover materials and 85 parts of stamp-pad ink. The chemical composition of the transparent dry particle glaze powder comprises: by mass percent, SiO2：45％，Al2O3：18％，CaO：4.5％，MgO：4％，BaO：16％，ZnO：3.8％，K2O：3.5％，Na2O: 3.5 percent. The chemical composition of the gem leftover material comprises: by mass percentage, Al2O3：98％，CrO3：1.95％，Fe2O3: 0.05 percent. The particle size of the gem leftover is 100 meshes.
(7) And drying the grain glaze on the surface of the blank after the pattern is printed by ink jet. The specific gravity of the dry granular glaze is 1.6g/cm3The glazing amount is 1200g/m2。
(8) And drying the green body after the glaze particles are sprayed and dried, and firing. The highest firing temperature is 1150-1210 ℃, the firing time is 55-65 min, and the ceramic tile with the glaze surface with the stereoscopic gem particle sense is obtained after the ceramic tile is taken out of the kiln.
Example 3
(1) And pressing and molding the blank powder to form a blank.
(2) And drying the green body. The drying time is 1h, and the water content of the dried ceramic body is 0.3 wt%.
(3) And applying surface glaze on the surface of the dried blank. The overglaze comprises the following chemical components: by mass percent, SiO2：68％、Al2O3：24％、CaO：0.6％、MgO：0.3％、K2O：2.5％、Na2O：4％、ZrO2: 9.6%, loss on ignition: 1.7 percent. The specific gravity of the overglaze is 1.52g/cm3The glazing amount is 530g/m2。
(4) And (4) printing a pattern on the surface of the blank in an ink jet mode.
(5) And drying the blank body after the pattern is printed by ink jet for 3 min.
(6) And preparing dry grain glaze. The dry particle glaze comprises: 60 parts of transparent dry grain glaze powder, 15 parts of gem leftover materials and 90 parts of stamp-pad ink. The chemical composition of the transparent dry particle glaze powder can comprise: by mass percent, SiO2：40％，Al2O3：14％，CaO：3.5％，MgO：.5％，BaO：14.5％，ZnO：3％，K2O：2.1％，Na2O: 2.5 percent. The chemical composition of the gem leftover material comprises: by mass percentage, Al2O3：98％，CrO3：1.95％，Fe2O3: 0.05 percent. The particle size of the gem leftover is 100 meshes.
(7) And drying the grain glaze on the surface of the blank after the pattern is printed by ink jet. The specific gravity of the dry granular glaze is 1.89g/cm3The glazing amount is 1100g/m2。
(8) And drying the green body after the glaze particles are sprayed and dried, and firing. The highest firing temperature is 1150-1210 ℃, the firing time is 55-65 min, and the ceramic tile with the glaze surface with the stereoscopic gem particle sense is obtained after the ceramic tile is taken out of the kiln.
Claims (9)
1. A preparation method of a ceramic tile with a stereoscopic gem particle feeling glaze surface is characterized by comprising the following steps:
applying a cover glaze on the surface of the blank and carrying out ink-jet printing on a pattern;
applying dry grain glaze on the surface of the blank after the pattern is printed by ink jet; the dry particle glaze comprises, by weight, 45-65 parts of transparent dry particle glaze powder and 10-20 parts of gem leftover materials;
finally, the ceramic tile with the glaze surface with the stereoscopic gem particle sense is formed by sintering.
2. The method according to claim 1, wherein the transparent dry glaze powder has a melting start temperature of 1100 to 1200 ℃; preferably, the chemical composition of the transparent dry particle glaze powder comprises: by mass percent, SiO2：40～45%，Al2O3: 14 to 18%, alkaline earth metal oxide: 19 to 25%, alkali metal oxide: 4-8%.
3. The method according to claim 1 or 2, wherein the starting melting temperature of the gemstone scraps is 1200 to 1300 ℃; preferably, the gem leftover materials are sapphire and/or ruby; more preferably, the chemical composition of the gemstone scraps comprises: by mass percentage, Al2O3：95～99.9%，CrO3：1～5%，Fe2O3：0.01～0.05%。
4. The preparation method according to any one of claims 1 to 3, wherein the dry particle glaze has a specific gravity of 1.6 to 1.9g/cm3The glazing amount is 1000-1200 g/m2。
5. The preparation method according to any one of claims 1 to 4, characterized in that the dry particle glaze is applied by spraying glaze.
6. The method according to any one of claims 1 to 5, wherein the particle size of the gemstone scraps is 60 to 100 meshes.
7. The production method according to any one of claims 1 to 6, wherein the maximum firing temperature is 1150 to 1210 ℃ and the firing period is 55 to 65 minutes.
8. The method according to any one of claims 1 to 7, wherein the overglaze has a specific gravity of 1.50 to 1.53g/cm3The glazing amount is 500-550 g/m2。
9. Ceramic tile with a stereoscopic gem particle feel glaze obtained by the method of production according to any one of claims 1 to 8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011337575.4A CN112500196B (en) | 2020-11-25 | 2020-11-25 | Ceramic tile with stereoscopic gem particle feeling glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011337575.4A CN112500196B (en) | 2020-11-25 | 2020-11-25 | Ceramic tile with stereoscopic gem particle feeling glaze and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112500196A true CN112500196A (en) | 2021-03-16 |
| CN112500196B CN112500196B (en) | 2022-05-06 |
Family
ID=74959277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011337575.4A Active CN112500196B (en) | 2020-11-25 | 2020-11-25 | Ceramic tile with stereoscopic gem particle feeling glaze and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112500196B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113955942A (en) * | 2021-12-22 | 2022-01-21 | 广东简一(集团)陶瓷有限公司 | High-hardness glaze and preparation method thereof |
| CN114057397A (en) * | 2021-10-25 | 2022-02-18 | 蒙娜丽莎集团股份有限公司 | Micro-light treatment method for surface of fine dry particle rock plate |
| CN114213013A (en) * | 2021-12-06 | 2022-03-22 | 蒙娜丽莎集团股份有限公司 | Flash dry grain glaze, flash dry grain polished ceramic plate and preparation method thereof |
| CN114230326A (en) * | 2021-12-13 | 2022-03-25 | 新明珠集团股份有限公司 | Semi-transparent ceramic tile and preparation method thereof |
| CN114907147A (en) * | 2022-04-19 | 2022-08-16 | 四川利弘陶瓷有限公司 | Processing technology of magic spar ceramic |
| WO2022205988A1 (en) * | 2021-03-31 | 2022-10-06 | 蒙娜丽莎集团股份有限公司 | Ceramic slab having colored jade effect and preparation method therefor |
| CN115583844A (en) * | 2021-10-21 | 2023-01-10 | 蒙娜丽莎集团股份有限公司 | Dark-engraved decorative dry-grain fully-polished ceramic tile and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105924134A (en) * | 2016-04-25 | 2016-09-07 | 广东宏宇新型材料有限公司 | Resource-saving glazed tile with pearlescent and color-variable effect and preparation method thereof |
| CN108129027A (en) * | 2018-01-30 | 2018-06-08 | 广东宏海陶瓷实业发展有限公司 | There are the crystallization glazed tile of friable mica effect, parent glaze and preparation method thereof in surface |
| CN110451802A (en) * | 2019-08-15 | 2019-11-15 | 蒙娜丽莎集团股份有限公司 | A kind of mica sheet decorative porcelain glazed tile and preparation method thereof |
-
2020
- 2020-11-25 CN CN202011337575.4A patent/CN112500196B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105924134A (en) * | 2016-04-25 | 2016-09-07 | 广东宏宇新型材料有限公司 | Resource-saving glazed tile with pearlescent and color-variable effect and preparation method thereof |
| CN108129027A (en) * | 2018-01-30 | 2018-06-08 | 广东宏海陶瓷实业发展有限公司 | There are the crystallization glazed tile of friable mica effect, parent glaze and preparation method thereof in surface |
| CN110451802A (en) * | 2019-08-15 | 2019-11-15 | 蒙娜丽莎集团股份有限公司 | A kind of mica sheet decorative porcelain glazed tile and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨琇明 主编: "《结晶学及晶体光学》", 31 July 2018, 中国地质大学出版社 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022205988A1 (en) * | 2021-03-31 | 2022-10-06 | 蒙娜丽莎集团股份有限公司 | Ceramic slab having colored jade effect and preparation method therefor |
| CN115583844A (en) * | 2021-10-21 | 2023-01-10 | 蒙娜丽莎集团股份有限公司 | Dark-engraved decorative dry-grain fully-polished ceramic tile and preparation method thereof |
| CN115583844B (en) * | 2021-10-21 | 2023-08-11 | 蒙娜丽莎集团股份有限公司 | Full-polished ceramic tile with concealed carving decoration dry grains and preparation method thereof |
| CN114057397A (en) * | 2021-10-25 | 2022-02-18 | 蒙娜丽莎集团股份有限公司 | Micro-light treatment method for surface of fine dry particle rock plate |
| CN114213013A (en) * | 2021-12-06 | 2022-03-22 | 蒙娜丽莎集团股份有限公司 | Flash dry grain glaze, flash dry grain polished ceramic plate and preparation method thereof |
| CN114213013B (en) * | 2021-12-06 | 2023-03-17 | 蒙娜丽莎集团股份有限公司 | Flash dry grain glaze, flash dry grain polished ceramic plate and preparation method thereof |
| CN114230326A (en) * | 2021-12-13 | 2022-03-25 | 新明珠集团股份有限公司 | Semi-transparent ceramic tile and preparation method thereof |
| CN114230326B (en) * | 2021-12-13 | 2022-07-22 | 新明珠集团股份有限公司 | Semi-transparent ceramic tile and preparation method thereof |
| CN113955942A (en) * | 2021-12-22 | 2022-01-21 | 广东简一(集团)陶瓷有限公司 | High-hardness glaze and preparation method thereof |
| CN113955942B (en) * | 2021-12-22 | 2022-03-15 | 广东简一(集团)陶瓷有限公司 | High-hardness glaze and preparation method thereof |
| CN114907147A (en) * | 2022-04-19 | 2022-08-16 | 四川利弘陶瓷有限公司 | Processing technology of magic spar ceramic |
Also Published As
| Publication number | Publication date |
|---|---|
| CN112500196B (en) | 2022-05-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112500196B (en) | Ceramic tile with stereoscopic gem particle feeling glaze and preparation method thereof | |
| CN106518029B (en) | A kind of marble Ceramic Tiles preparation method with metallic luster recess texture | |
| CN110776256B (en) | White radial crystal flower dry grain glaze, light-transmitting ceramic tile and preparation method thereof | |
| CN110759641B (en) | Crystal flower dry grain glaze and positioning crystal flower ceramic tile prepared from crystal flower dry grain glaze | |
| CN110845227B (en) | Positioning crystal-patterned light-transmitting ceramic tile and preparation method thereof | |
| CN105777089B (en) | A kind of transparent brick and preparation method thereof | |
| CN110357668A (en) | A kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments | |
| CN112456802B (en) | Giant crystal particles capable of forming crystal flowers, dry particle combination, particles for ceramics, ceramics and preparation method of ceramics | |
| CN104829268A (en) | Glaze for fast-fired crystal glaze ceramic tile, and preparation method and applications of ceramic tile | |
| CN110835234B (en) | Colored chrysanthemum-shaped crystal flower glaze, chrysanthemum-shaped crystal flower light-transmitting ceramic tile and preparation method thereof | |
| CN107266023B (en) | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method | |
| CN104140297A (en) | Glaze and preparation of embossment phantom glazed brick | |
| CN110903033B (en) | Crystal nucleating agent and positioning crystal pattern ceramic tile prepared by using same | |
| CN114276121B (en) | Ceramic tile with starlight stereoscopic effect and preparation method thereof | |
| CN108484114B (en) | Glazed ceramic tile with high-content polishing waste and preparation method thereof | |
| CN112142328A (en) | Manufacturing method of ceramic chip with fine die texture | |
| CN114573340B (en) | Zirconia-based metal texture crystal drilling material, ceramic tile and preparation method thereof | |
| CN110845252B (en) | Special blank large-particle combined digital cloth archaized brick and preparation method thereof | |
| CN110903080B (en) | Special blank large particle combined digital cloth ink-jet infiltration polished brick and preparation method thereof | |
| CN115180982A (en) | Simulated micro-cement ceramic tile and preparation method thereof | |
| CN110862230B (en) | Dry ice crack nucleating agent particles, ice crack crystal flower light-transmitting ceramic tile and preparation method thereof | |
| CN111807702A (en) | Method for manufacturing glazed tile with glazed three-dimensional effect | |
| CN116969778A (en) | Wrinkled veined matte double-layer reactive glaze for artistic ceramic and preparation method thereof | |
| CN115466056A (en) | Colored frit dry particles and ceramic tile decorated by same | |
| CN114014542B (en) | Concave-convex texture foamed ceramic heat-insulating board and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |