CN112442699A - Surface cleaning agent - Google Patents
Surface cleaning agent Download PDFInfo
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- CN112442699A CN112442699A CN201910805723.1A CN201910805723A CN112442699A CN 112442699 A CN112442699 A CN 112442699A CN 201910805723 A CN201910805723 A CN 201910805723A CN 112442699 A CN112442699 A CN 112442699A
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- Prior art keywords
- surface cleaning
- cleaning agent
- sodium
- water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/12—Light metals
- C23G1/125—Light metals aluminium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/362—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also zinc cations
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the technical field of chemical cleaning agents, and particularly relates to a surface cleaning agent. The paint consists of the following components in percentage by weight: 10-15% of phosphating solution; 6-25% of an aluminum ion complexing agent; foaming anionic surfactant: 1.5-8.5%; 1-12% of a nonionic surfactant; the balance being water. Compared with the prior art, the surface cleaning agent disclosed by the invention has the advantages that the aluminum ion complexing agent, the foaming surfactant and the phosphide are added, so that the surface cleaning speed of the aluminum alloy is greatly increased, the problems of whitening and yellowing of the surface in the traditional chemical cleaning process are solved, and the original gloss of the surface of the aluminum alloy can be recovered.
Description
Technical Field
The invention belongs to the technical field of chemical cleaning agents, and particularly relates to a surface cleaning agent.
Background
Aluminum alloys have been widely used in the aerospace, automotive, mechanical manufacturing, marine and chemical industries due to their advantages of low density, high strength, strong corrosion resistance, good processability and easy regeneration, and have become the most widely used non-ferrous metal structural materials. However, the surface of the aluminum alloy product is easily polluted by various oil stains and dust in the manufacturing and using processes, and yellow spots, oil stain stains and tarnish are generated by oxidation, so that the aluminum alloy product needs to be cleaned regularly. In the related art, cleaning is performed by a chemical method of wiping with a soda solution, but reaction products such as sodium metaaluminate and aluminum hydroxide remaining after cleaning are attached to the surface to whiten the surface, and meanwhile, acid washing and alkali washing can damage an oxidation protection film on the surface of the aluminum alloy, so that a galvanic cell is formed among various metal ions on the surface of the aluminum alloy, and further corrosion, oxidation and yellowing occur, and the appearance of the aluminum alloy is affected.
Therefore, there is a need to provide a new surface cleaning agent to solve the above technical problems.
Disclosure of Invention
The invention aims to provide a surface cleaning agent with good cleaning effect.
The invention provides a surface cleaning agent, which comprises the following components in percentage by weight:
10-15% of phosphating solution;
6-25% of an aluminum ion complexing agent;
foaming anionic surfactant: 1.5-8.5%;
1-12% of a nonionic surfactant;
the balance being water.
Preferably, the paint comprises the following components in percentage by weight:
15% of phosphating solution;
10% of aluminum ion complexing agent;
foaming anionic surfactant: 6 percent;
nonionic surfactant, 6%;
the balance being water.
Preferably, the paint comprises the following components in percentage by weight:
10% of phosphating solution;
25% of aluminum ion complexing agent;
foaming anionic surfactant: 1.5 percent;
nonionic surfactant, 12%;
the balance being water.
Preferably, the paint comprises the following components in percentage by weight:
12.5 percent of phosphating solution;
15.5 percent of aluminum ion complexing agent;
foaming anionic surfactant: 8.5 percent;
nonionic surfactant, 6.5%;
the balance being water.
Preferably, the phosphating solution comprises: phosphoric acid, sodium dihydrogen phosphate, zinc chlorate, sodium nitrate, sodium fluoride and water,
preferably, the aluminum ion complexing agent is a polydentate ligand containing N, O, F atoms.
Preferably, the aluminum ion complexing agent comprises: one or more of ethylene diamine tetraacetic acid, iminodisuccinic acid, cyclohexanediamine tetraacetic acid, diethylamine pentanic acid, ethylene glycol and triethanolamine.
Preferably, the foaming surfactant is one or more of sodium dodecyl benzene sulfonate, sodium dodecyl sulfate and C10-C18 sodium fatty acid.
Preferably, the nonionic surfactant is one or more of nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, sorbitan trioleate, propylene glycol fatty acid ester and polyoxyethylene oleyl ether.
Preferably, the phosphating solution comprises the following components in percentage by weight:
30% of phosphoric acid;
sodium dihydrogen phosphate, 10%;
8 percent of zinc chlorate;
8% of sodium nitrate;
2% of sodium fluoride;
and 42% of water.
Compared with the prior art, the surface cleaning agent disclosed by the invention has the advantages that the aluminum ion complexing agent, the foaming surfactant and the phosphide are added, so that the surface cleaning speed of the aluminum alloy is greatly increased, the problems of whitening and yellowing of the surface in the traditional chemical cleaning process are solved, and the original gloss of the surface of the aluminum alloy can be recovered.
Detailed Description
The present invention will be further described with reference to the following embodiments.
Example 1
A surface cleaning agent comprises the following components in percentage by weight:
10% of phosphating solution;
6% of aluminum ion complexing agent;
foaming anionic surfactant: 1.5 percent;
nonionic surfactant, 1%;
the balance being water.
The phosphating solution comprises: phosphoric acid, sodium dihydrogen phosphate, zinc chlorate, sodium nitrate, sodium fluoride and water;
the phosphating solution comprises the following components in percentage by weight:
30% of phosphoric acid;
sodium dihydrogen phosphate, 10%;
8 percent of zinc chlorate;
8% of sodium nitrate;
2% of sodium fluoride;
and 42% of water.
The aluminum ion complexing agent is a composition of ethylene diamine tetraacetic acid and iminodisuccinic acid.
The foaming surfactant is sodium dodecyl benzene sulfonate.
The nonionic surfactant is: sorbitan trioleate, propylene glycol fatty acid ester and polyoxyethylene oleyl ether.
Description of the effects: the surface cleaning agent prepared by the components is sprayed or brushed on the surface of the aluminum alloy to realize the cleaning function, the cleaning can be finished after the cleaning agent is contacted with the surface of the aluminum alloy for 5s, a large amount of bubbles are generated in the cleaning process as a normal phenomenon, the residual liquid is wiped off by using a cleaning cloth, the surface of the cleaned aluminum alloy is not whitish or yellow, and the natural color of the aluminum alloy can be kept for a long time.
Example 2
A surface cleaning agent comprises the following components in percentage by weight:
15% of phosphating solution;
25% of aluminum ion complexing agent;
foaming anionic surfactant: 8.5 percent;
nonionic surfactant, 12%;
the balance being water.
The phosphating solution comprises: phosphoric acid, sodium dihydrogen phosphate, zinc chlorate, sodium nitrate, sodium fluoride and water;
the phosphating solution comprises the following components in percentage by weight:
phosphoric acid, 28%;
sodium dihydrogen phosphate, 11%;
8 percent of zinc chlorate;
9% of sodium nitrate;
2% of sodium fluoride;
and 42% of water.
The aluminum ion complexing agent is a composition of iminodisuccinic acid, cyclohexanediamine tetraacetic acid and diethylamine pentanic acid.
The foaming surfactant is a composition of sodium dodecyl sulfate and C18 sodium fatty acid.
The nonionic surfactant is a composition of octyl phenol polyoxyethylene ether and propylene glycol fatty acid ester.
Description of the effects: the surface cleaning agent prepared by the components is sprayed or brushed on the surface of the aluminum alloy to realize the cleaning function, the cleaning can be finished after the cleaning agent is contacted with the surface of the aluminum alloy for 3s, a large amount of bubbles are generated in the cleaning process as a normal phenomenon, the residual liquid is wiped off by using a cleaning cloth, the surface of the cleaned aluminum alloy is not whitish or yellow, and the natural color of the aluminum alloy can be kept for a long time.
Example 3
A surface cleaning agent comprises the following components in percentage by weight:
15% of phosphating solution;
10% of aluminum ion complexing agent;
foaming anionic surfactant: 6 percent;
nonionic surfactant, 6%;
the balance being water.
The phosphating solution comprises: phosphoric acid, sodium dihydrogen phosphate, zinc chlorate, sodium nitrate, sodium fluoride and water;
the phosphating solution comprises the following components in percentage by weight:
phosphoric acid, 31%;
sodium dihydrogen phosphate, 11%;
9 percent of zinc chlorate;
9% of sodium nitrate;
3% of sodium fluoride;
water, 37%.
The aluminum ion complexing agent comprises: ethylenediaminetetraacetic acid, iminodisuccinic acid, cyclohexanediaminetetraacetic acid, diethylaminepentanic acid, and ethylene glycol.
The foaming surfactant is a composition of sodium dodecyl benzene sulfonate, sodium dodecyl sulfonate and sodium dodecyl sulfate.
The nonionic surfactant is a composition of nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, sorbitan trioleate, propylene glycol fatty acid ester and polyoxyethylene oleyl ether.
Description of the effects: the surface cleaning agent prepared by the components is sprayed or brushed on the surface of the aluminum alloy to realize the cleaning function, the cleaning can be finished after the cleaning agent is contacted with the surface of the aluminum alloy for 4s, a large amount of bubbles are generated in the cleaning process as a normal phenomenon, the residual liquid is wiped off by using a cleaning cloth, the surface of the cleaned aluminum alloy is not whitish or yellow, and the natural color of the aluminum alloy can be kept for a long time.
Example 4
A surface cleaning agent comprises the following components in percentage by weight:
10% of phosphating solution;
25% of aluminum ion complexing agent;
foaming anionic surfactant: 1.5 percent;
nonionic surfactant, 12%;
the balance being water.
The phosphating solution comprises: phosphoric acid, sodium dihydrogen phosphate, zinc chlorate, sodium nitrate, sodium fluoride and water;
the phosphating solution comprises the following components in percentage by weight:
30% of phosphoric acid;
sodium dihydrogen phosphate, 9%;
9 percent of zinc chlorate;
9% of sodium nitrate;
2% of sodium fluoride;
and (4) water, 41%.
The aluminum ion complexing agent is cyclohexanediamine tetraacetic acid.
The foaming surfactant is sodium dodecyl sulfate.
The nonionic surfactant is polyoxyethylene oleyl ether.
Description of the effects: the surface cleaning agent prepared by the components is sprayed or brushed on the surface of the aluminum alloy to realize the cleaning function, the cleaning can be finished after the cleaning agent is contacted with the surface of the aluminum alloy for 4s, a large amount of bubbles are generated in the cleaning process as a normal phenomenon, the residual liquid is wiped off by using a cleaning cloth, the surface of the cleaned aluminum alloy is not whitish or yellow, and the natural color of the aluminum alloy can be kept for a long time.
Example 5
A surface cleaning agent comprises the following components in percentage by weight:
12.5 percent of phosphating solution;
15.5 percent of aluminum ion complexing agent;
foaming anionic surfactant: 8.5 percent;
nonionic surfactant, 6.5%;
the balance being water.
The phosphating solution comprises: phosphoric acid, sodium dihydrogen phosphate, zinc chlorate, sodium nitrate, sodium fluoride and water;
the phosphating solution comprises the following components in percentage by weight:
29% of phosphoric acid;
sodium dihydrogen phosphate, 9%;
7 percent of zinc chlorate;
7% of sodium nitrate;
1% of sodium fluoride;
and 47% of water.
The aluminum ion complexing agent comprises: a combination of cyclohexanediaminetetraacetic acid and diethylaminepentanic acid.
The foaming surfactant is a composition of sodium dodecyl sulfate and sodium dodecyl sulfate.
The nonionic surfactant is a composition of nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, sorbitan trioleate and propylene glycol fatty acid ester.
Description of the effects: the surface cleaning agent prepared by the components is sprayed or brushed on the surface of the aluminum alloy to realize the cleaning function, the cleaning can be finished after the cleaning agent is contacted with the surface of the aluminum alloy for 4s, a large amount of bubbles are generated in the cleaning process as a normal phenomenon, the residual liquid is wiped off by using a cleaning cloth, the surface of the cleaned aluminum alloy is not whitish or yellow, and the natural color of the aluminum alloy can be kept for a long time.
In the above embodiment, the phosphating solution mainly serves to form a dense phosphating film on the surface of the aluminum alloy after removing stains and oxide films, thereby preventing the surface from being oxidized and discolored. The aluminum ion complexing agent can quickly convert aluminum ions generated by the reaction of the aluminum alloy and phosphoric acid into a stable aluminum ion complex, and the cleaning speed of the surface of the aluminum alloy is accelerated in the aspect of chemical kinetics; meanwhile, aluminum ions are prevented from being converted into aluminum hydroxide and sodium meta-chlorate, so that the surface of the aluminum alloy is prevented from being whitened. Foaming anionic surfactant action: on one hand, stains on the surface of the aluminum alloy are cleaned, on the other hand, the mass transfer process of the phosphating reaction and the complexing reaction is accelerated through foaming, and the cleaning speed is increased. The nonionic surfactant is mainly used for enhancing and supplementing the capability of the foaming surfactant in cleaning stains on the surface of the aluminum alloy.
Compared with the prior art, the surface cleaning agent disclosed by the invention has the advantages that the aluminum ion complexing agent, the foaming surfactant and the phosphide are added, so that the surface cleaning speed of the aluminum alloy is greatly increased, the problems of whitening and yellowing of the surface in the traditional chemical cleaning process are solved, and the original gloss of the surface of the aluminum alloy can be recovered.
While the foregoing is directed to embodiments of the present invention, it will be understood by those skilled in the art that various changes may be made without departing from the spirit and scope of the invention.
Claims (10)
1. The surface cleaning agent is characterized by comprising the following components in percentage by weight:
10-15% of phosphating solution;
6-25% of an aluminum ion complexing agent;
foaming anionic surfactant: 1.5-8.5%;
1-12% of a nonionic surfactant;
the balance being water.
2. The surface cleaning agent according to claim 1, which comprises the following components in percentage by weight:
15% of phosphating solution;
10% of aluminum ion complexing agent;
foaming anionic surfactant: 6 percent;
nonionic surfactant, 6%;
the balance being water.
3. The surface cleaning agent according to claim 1, which comprises the following components in percentage by weight:
10% of phosphating solution;
25% of aluminum ion complexing agent;
foaming anionic surfactant: 1.5 percent;
nonionic surfactant, 12%;
the balance being water.
4. The surface cleaning agent according to claim 1, which comprises the following components in percentage by weight:
12.5 percent of phosphating solution;
15.5 percent of aluminum ion complexing agent;
foaming anionic surfactant: 8.5 percent;
nonionic surfactant, 6.5%;
the balance being water.
5. The surface cleaning agent according to any one of claims 1 to 4, wherein the phosphating solution comprises: phosphoric acid, sodium dihydrogen phosphate, zinc chlorate, sodium nitrate, sodium fluoride and water.
6. The surface cleaning agent according to any one of claims 1 to 4, wherein the aluminum ion complexing agent is a polydentate ligand containing N, O, F atoms.
7. The surface cleaning agent according to any one of claims 1 to 4, wherein the aluminum ion complexing agent comprises: one or more of ethylene diamine tetraacetic acid, iminodisuccinic acid, cyclohexanediamine tetraacetic acid, diethylamine pentanic acid, ethylene glycol and triethanolamine.
8. The surface cleaning agent according to any one of claims 1 to 4, wherein the foaming surfactant is one or more of sodium dodecylbenzene sulfonate, sodium dodecyl sulfate, and sodium C10-C18 fatty acid.
9. The surface cleaning agent according to any one of claims 1 to 4, wherein the nonionic surfactant is one or more selected from nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, sorbitan trioleate, propylene glycol fatty acid ester and polyoxyethylene oleyl ether.
10. The surface cleaning agent according to any one of claims 1 to 4, wherein the phosphating solution comprises the following components in percentage by weight:
30% of phosphoric acid;
sodium dihydrogen phosphate, 10%;
8 percent of zinc chlorate;
8% of sodium nitrate;
2% of sodium fluoride;
and 42% of water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910805723.1A CN112442699A (en) | 2019-08-29 | 2019-08-29 | Surface cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910805723.1A CN112442699A (en) | 2019-08-29 | 2019-08-29 | Surface cleaning agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112442699A true CN112442699A (en) | 2021-03-05 |
Family
ID=74741185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910805723.1A Pending CN112442699A (en) | 2019-08-29 | 2019-08-29 | Surface cleaning agent |
Country Status (1)
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1665957A (en) * | 2002-07-10 | 2005-09-07 | 坎梅陶尔股份有限公司 | Method for coating metallic surfaces |
| CN101307440A (en) * | 2008-07-11 | 2008-11-19 | 上海瑞尔实业有限公司 | Phosphating liquid sharing for aluminum alloy and ferrous metal |
| CN103388153A (en) * | 2013-07-26 | 2013-11-13 | 上海金兆节能科技有限公司 | Environment-friendly rustproof cleaning agent |
| CN104195577A (en) * | 2014-09-15 | 2014-12-10 | 陈建宝 | High-efficient metal cleaner |
| CN109280912A (en) * | 2018-10-24 | 2019-01-29 | 江苏理工学院 | A kind of aluminum alloy surface processing phosphating solution and method for bonderizing |
-
2019
- 2019-08-29 CN CN201910805723.1A patent/CN112442699A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1665957A (en) * | 2002-07-10 | 2005-09-07 | 坎梅陶尔股份有限公司 | Method for coating metallic surfaces |
| CN101307440A (en) * | 2008-07-11 | 2008-11-19 | 上海瑞尔实业有限公司 | Phosphating liquid sharing for aluminum alloy and ferrous metal |
| CN103388153A (en) * | 2013-07-26 | 2013-11-13 | 上海金兆节能科技有限公司 | Environment-friendly rustproof cleaning agent |
| CN104195577A (en) * | 2014-09-15 | 2014-12-10 | 陈建宝 | High-efficient metal cleaner |
| CN109280912A (en) * | 2018-10-24 | 2019-01-29 | 江苏理工学院 | A kind of aluminum alloy surface processing phosphating solution and method for bonderizing |
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Application publication date: 20210305 |