CN112340989A - Dry particle glaze ceramic tile and preparation method thereof - Google Patents

Dry particle glaze ceramic tile and preparation method thereof Download PDF

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Publication number
CN112340989A
CN112340989A CN202011239384.4A CN202011239384A CN112340989A CN 112340989 A CN112340989 A CN 112340989A CN 202011239384 A CN202011239384 A CN 202011239384A CN 112340989 A CN112340989 A CN 112340989A
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dry
glaze
parts
overglaze
grain
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CN112340989B (en
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杜希希
周青
王春
王爱芳
杨浩勇
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Guangdong Dongwei New Material Co ltd
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Dongguan Weimei Decoration Materials Co ltd
Dongguan City Wonderful Ceramics Industrial Park Co Ltd
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    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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Abstract

The invention discloses a dry particle glazed ceramic tile and a preparation method thereof, wherein the preparation method of the dry particle glazed ceramic tile comprises the following steps: A. pressing and molding the blank, and drying the blank in a drying kiln to obtain a porcelain brick blank; B. applying dry grain glaze on the surface of the porcelain tile blank to obtain a dry grain glaze layer; C. performing glaze decoration on the surface of the dry particle glaze layer to obtain a glaze decoration layer; D. applying a protective glaze on the overglaze decorative layer to obtain a protective glaze layer; E. and putting the ceramic tile into a kiln for firing and forming to obtain the dry grain glazed ceramic tile. By directly applying the dry grain overglaze on the surface of the porcelain tile blank, compared with the prior art in which the ground glaze (overglaze) is applied firstly for pattern decoration, and then the dry grain is applied, the ground glaze process and the dry grain process are directly combined, the preparation method of the porcelain tile is simplified, the production cost of the porcelain tile is reduced, and the stability and the product qualification rate of the porcelain tile are improved.

Description

Dry particle glaze ceramic tile and preparation method thereof
Technical Field
The invention relates to the field of ceramic production, in particular to a dry particle glazed ceramic tile and a preparation method thereof.
Background
At present, in the aspect of ceramic tile glaze decoration, with the wide application of various new technologies and new processes, various functional inks, special frit dry particles, a silk screen roller ink-jet technology are combined and mixed, and the like, so that the glaze decoration effect is greatly changed. In addition, with the increasing safety awareness of people, the application of various anti-skid glazes and anti-skid dry particles is quite common. In the process of producing and applying dry particle decoration technology, the most widely used decoration technology at present is that a procedure of spraying dry particles or spraying dry particles is added before the glazed tile enters a firing kiln, and dry particle applying equipment is required to be added, so that the production cost of the dry particle glazed ceramic tile is improved, and the product percent of pass is reduced.
Accordingly, the prior art has shortcomings and drawbacks that require further improvement and development.
Disclosure of Invention
In view of the defects of the prior art, the invention aims to provide a dry particle glazed ceramic tile and a preparation method thereof, and aims to solve the problems of high cost and low qualified rate of the dry particle glazed ceramic tile and the preparation method thereof in the prior art.
In order to solve the technical problems, the invention provides the following technical scheme: a method for preparing a dry particle glazed porcelain tile, comprising:
A. pressing and molding the blank, and drying the blank in a drying kiln to obtain a porcelain brick blank;
B. applying dry grain glaze on the surface of the porcelain tile blank to obtain a dry grain glaze layer;
C. performing glaze decoration on the surface of the dry particle glaze layer to obtain a glaze decoration layer;
D. applying a protective glaze on the overglaze decorative layer to obtain a protective glaze layer;
E. and putting the ceramic tile into a kiln for firing and forming to obtain the dry grain glazed ceramic tile.
Further, the dry material of the dry grain glaze comprises the following raw materials in parts by weight:
53 parts of dry overglaze and 47 parts of dry particles;
wherein the dry overglaze material comprises the following components in parts by weight: 3 parts of barium carbonate, 54 parts of zirconium silicate, 1 part of calcined talc, 30 parts of silica fume, 4 parts of kaolin and 9 parts of quartz;
the chemical composition of the dry granules comprises the following components in percentage by mass: SiO 22 55.32％、Al2O3 14.86％、Fe2O30.06％、CaO 9.82％、MgO 2.08％、BaO 2.12％、K2O 3.46％、Na2O 1.10％、ZnO 9.23％、B2O31.09% and 0.86% of loss on ignition.
Further, the wet material of the dry grain glaze comprises the following raw materials in parts by weight:
30 parts of dry overglaze material, 26 parts of dry particles and 44 parts of suspending agent;
wherein the dry overglaze material comprises the following components in parts by weight: 3 parts of barium carbonate, 54 parts of zirconium silicate, 1 part of calcined talc, 30 parts of silica fume, 4 parts of kaolin and 9 parts of quartz;
the chemical composition of the dry granules comprises the following components in percentage by mass: SiO 22 55.32％、Al2O314.86％、Fe2O30.06％、CaO 9.82％、MgO 2.08％、BaO 2.12％、K2O3.46％、Na2O 1.10％、ZnO 9.23％、B2O31.09% and 0.86% of loss on ignition.
Further, the chemical composition of the dry particle glaze comprises, by mass:
SiO2 47.05％、Al2O3 8.82％、Fe2O3 0.12％、CaO 13.06％、MgO 0.85％、BaO 4.21％、K2O 1.50％、Na2O 2.09％、ZnO 3.64％、B2O30.56 percent, ZrO 17.07 percent and loss on ignition 1.03 percent.
Further, the processing method of the dry particle glaze comprises the following steps:
weighing 30 parts of dry overglaze material according to the weight percentage, adding a suspending agent, and performing ball milling to obtain dry overglaze material glaze slurry;
weighing 26 parts of dry particles according to the weight fraction, adding a suspending agent, and uniformly mixing to obtain dry particle glaze slurry;
uniformly mixing the dry overglaze slip and the dry particle slip according to the ratio of 1:1-1:1.1 to obtain dry particle overglaze;
wherein, the dry surface material in the dry surface glaze slip comprises the following dry surface material: suspending agent is 1: 0.6; dry particles in the dry particle glaze slurry: 1:1 of suspending agent; the fineness of the glaze slurry of the dry grain overglaze is 100-150 meshes.
Further, the billet chemical composition meter comprises:
SiO2 67％～69％、Al2O3 17％～19％、Fe2O3 0.9％～1.4％、CaO 0.2％～0.5％、MgO 1.0％～1.5％、K2O 2.1％～2.7％、Na22.2 to 2.7 percent of O and 4.9 to 5.4 percent of loss on ignition;
and B, drying at the temperature of 80-100 ℃ for 60min in the step A.
Further, the specific gravity of the glaze slip of the dry grain overglaze in the step B is 1.75 +/-0.02;
the glazing amount of the dry particle glaze ranges from 580 to 710g/m2；
The flow rate of the dry grain overglaze is 20-30 s.
Further, the specific gravity of the glaze slip of the protective glaze in the step D is 1.25-1.35, and the glazing amount of the protective glaze is 150-280 g/m2The glaze spraying pressure of the protective glaze is 3-5 kgf/cm2。
Furthermore, the firing temperature when the material is placed into a kiln to be fired and molded in the step E is 60min, and the maximum firing temperature is 1240 ℃.
In order to solve the above technical problems, the present invention provides another technical solution as follows: a dry particle glazed ceramic tile, wherein the dry particle glazed ceramic tile is prepared by the preparation method of the dry particle glazed ceramic tile;
wherein, the dry particle glazed porcelain tile sequentially comprises from bottom to top: a porcelain tile body, a dry grain glaze layer, a surface glaze decorative layer and a protective glaze layer.
Has the advantages that: the invention provides a dry particle glazed ceramic tile and a preparation method thereof, wherein the preparation method of the dry particle glazed ceramic tile comprises the following steps: A. pressing and molding the blank, and drying the blank in a drying kiln to obtain a porcelain brick blank; B. applying dry grain glaze on the surface of the porcelain tile blank to obtain a dry grain glaze layer; C. performing glaze decoration on the surface of the dry particle glaze layer to obtain a glaze decoration layer; D. applying a protective glaze on the overglaze decorative layer to obtain a protective glaze layer; E. and putting the ceramic tile into a kiln for firing and forming to obtain the dry grain glazed ceramic tile. It can be understood that the dry grain overglaze is directly applied to the surface of the porcelain tile blank, and then compared with the prior art that the ground glaze (overglaze) is applied firstly for pattern decoration, then the dry grain is applied, and the ground glaze process and the dry grain process are directly combined, the preparation method of the porcelain tile is simplified, the production cost of the porcelain tile is reduced, and the stability and the product qualification rate of the porcelain tile are improved.
Drawings
FIG. 1 is a schematic flow chart of a method for preparing a dry-particle glazed porcelain tile provided in the present invention;
FIG. 2 is a schematic perspective view of a dry-grain glazed ceramic tile provided in the present invention;
description of reference numerals:
11. a porcelain tile body; 13. a dry grain glaze layer; 14. a glaze decoration layer; 15. and protecting the glaze layer.
Detailed Description
The invention provides a dry particle glazed porcelain tile and a preparation method thereof, and the invention is further described in detail below in order to make the purpose, technical scheme and effect of the invention clearer and more clear. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
At present, in the aspect of ceramic tile glaze decoration, with the wide application of various new technologies and new processes, various functional inks, special frit dry particles, a silk screen roller ink-jet technology are combined and mixed, and the like, so that the glaze decoration effect is greatly changed. In addition, with the increasing safety awareness of people, the application of various anti-skid glazes and anti-skid dry particles is quite common. In the process of producing and applying dry particle decoration technology, the most widely used decoration technology at present is that a procedure of spraying dry particles or spraying dry particles is added before the glazed tile enters a firing kiln, and dry particle applying equipment is required to be added, so that the production cost of the dry particle glazed ceramic tile is improved, and the product percent of pass is reduced. Based on the problems of high cost and low qualification rate of the dry grain glazed ceramic tile and the preparation method thereof in the prior art, the invention provides the dry grain glazed ceramic tile and the preparation method thereof.
Referring to fig. 1, the present invention provides a method for preparing a dry-particle glazed ceramic tile, which particularly comprises:
s11, pressing and forming the blank, and drying the blank in a drying kiln to obtain a porcelain tile green body;
step S12, applying dry grain overglaze on the surface of the porcelain tile blank to obtain a dry grain overglaze layer;
step S13, performing glaze decoration on the surface of the dry particle glaze layer to obtain a glaze decoration layer;
step S14, applying protective glaze on the overglaze decoration layer to obtain a protective glaze layer;
and step S15, firing and forming in a kiln to obtain the dry particle glazed porcelain tile.
It can be understood that the dry grain overglaze is directly applied to the surface of the porcelain tile blank, and then compared with the prior art that the ground glaze (overglaze) is applied firstly for pattern decoration, then the dry grain is applied, and the ground glaze process and the dry grain process are directly combined, the preparation method of the porcelain tile is simplified, the production cost of the porcelain tile is reduced, and the stability and the product qualification rate of the porcelain tile are improved.
Further, the dry material of the dry grain glaze comprises the following raw materials in parts by weight:
53 parts of dry overglaze and 47 parts of dry particles;
wherein the dry overglaze material comprises the following components in parts by weight: 3 parts of barium carbonate, 54 parts of zirconium silicate, 1 part of calcined talc, 30 parts of silica fume, 4 parts of kaolin and 9 parts of quartz;
the chemical composition of the dry granules comprises the following components in percentage by mass: SiO 22 55.32％、Al2O3 14.86％、Fe2O30.06％、CaO 9.82％、MgO 2.08％、BaO 2.12％、K2O 3.46％、Na2O 1.10％、ZnO 9.23％、B2O31.09% and 0.86% of loss on ignition.
It can be understood that the dry grain overglaze in the preparation method of the dry grain glazed ceramic tile provided by the invention comprises an overglaze component and a dry grain component, so that the overglaze and the dry grain are directly integrated in the same step, the preparation method of the ceramic tile is simplified, and the guarantee is provided for reducing the production cost of the ceramic tile, and improving the stability and the product qualification rate of the ceramic tile.
Further, the wet material of the dry grain glaze comprises the following raw materials in parts by weight:
30 parts of dry overglaze material, 26 parts of dry particles and 44 parts of suspending agent;
wherein the dry overglaze material comprises the following components in parts by weight: 3 parts of barium carbonate, 54 parts of zirconium silicate, 1 part of calcined talc, 30 parts of silica fume, 4 parts of kaolin and 9 parts of quartz;
the chemical composition of the dry granules comprises the following components in percentage by mass: SiO 22 55.32％、Al2O3 14.86％、Fe2O30.06％、CaO 9.82％、MgO 2.08％、BaO 2.12％、K2O 3.46％、Na2O 1.10％、ZnO 9.23％、B2O31.09 percent and the ignition loss is 0.86 percent;
wherein the suspending agent is a commonly used agent in the field; specifically, the suspending agent comprises 1% of polyoxyethylene octyl phenol ether, 1% of 2-amino-2-methyl-1-propanol, 1% of a mixture of 5-chloro-2-methyl-3 (2H) isothiazolone and 2-methyl-3 (2H) isothiazolone, 1% of magnesium nitrate, 1% of magnesium chloride and 95% of water.
Further, the chemical composition of the dry particle glaze comprises, by mass:
SiO2 47.05％、Al2O3 8.82％、Fe2O3 0.12％、CaO 13.06％、MgO 0.85％、BaO 4.21％、K2O 1.50％、Na2O 2.09％、ZnO 3.64％、B2O30.56 percent, ZrO 17.07 percent and loss on ignition 1.03 percent.
Further, the processing method of the dry particle glaze comprises the following steps:
weighing 30 parts of dry overglaze material according to the weight percentage, adding a suspending agent, and performing ball milling to obtain dry overglaze material glaze slurry;
weighing 26 parts of dry particles according to the weight fraction, adding a suspending agent, and uniformly mixing to obtain dry particle glaze slurry;
uniformly mixing the dry overglaze slip and the dry particle slip according to the ratio of 1:1-1:1.1 to obtain dry particle overglaze;
wherein, the dry surface material in the dry surface glaze slip comprises the following dry surface material: suspending agent is 1: 0.6; dry particles in the dry particle glaze slurry: 1:1 of suspending agent; the fineness of the glaze slurry of the dry grain overglaze is 100-150 meshes.
It can be understood that the dry overglaze needs to be subjected to ball milling, a suspending agent needs to be added during the ball milling, and the dry overglaze in the dry overglaze slip is controlled to have the following characteristics: adding 18 parts of suspending agent when the suspending agent is 1: 0.6; and the dry particles can be directly and uniformly mixed with the suspending agent, and the dry particles in the overglaze dry material glaze slurry are controlled: adding 26 parts of suspending agent into the suspension agent in a ratio of 1: 1; that is, when preparing the dry grain overglaze, the dry overglaze material and the dry grains are respectively mixed with the suspending agent, and then the mixed glaze slip is converged to obtain the dry grain overglaze; when the surface glaze dry material glaze slip and the dry particle glaze slip are mixed, the surface glaze dry material glaze slip is preferably as follows: dry grain glaze slip is 1: 1; it can be understood that the adding proportion of the dry particles in the dry particle overglaze and the dry material of the overglaze can be finely adjusted, and when the dry particle overglaze ceramic tile with dense glaze dry particle texture, granular texture and strong antiskid effect is required to be obtained, the content of the dry particles is required to be increased; when the dry glazed porcelain tile with slight dry grain texture and anti-slip effect needs to be obtained, the content of the dry glaze needs to be increased.
Further, the billet chemical composition meter comprises:
SiO2 67％～69％、Al2O3 17％～19％、Fe2O3 0.9％～1.4％、CaO 0.2％～0.5％、MgO 1.0％～1.5％、K2O 2.1％～2.7％、Na22.2 to 2.7 percent of O and 4.9 to 5.4 percent of loss on ignition;
the drying temperature in the step S11 is 80-100 ℃, and the drying time is 60 min.
Further, the specific gravity of the glaze slip of the dry grain overglaze in the step S12 is 1.75 +/-0.02;
the glazing amount of the dry particle glaze ranges from 580 to 710g/m2；
The flow rate of the dry grain overglaze is 20-30 s.
Further, the specific gravity of the glaze slip of the protective glaze in the step S14 is 1.25-1.35, and the glazing amount of the protective glaze is 150-280 g/m2The glaze spraying pressure of the protective glaze is 3-5 kgf/cm2。
Further, in the step S15, the firing temperature when the molded product is fired in a kiln is 60min, and the maximum firing temperature is 1240 ℃.
Referring to fig. 2, the present invention provides a dry grain glazed ceramic tile, which is prepared by the preparation method of the dry grain glazed ceramic tile of the present invention; wherein, the dry particle glazed porcelain tile sequentially comprises from bottom to top: a porcelain tile blank 11, a dry grain glaze layer 13, a surface glaze decorative layer 14 and a protective glaze layer 15.
It can be understood that the dry grain overglaze is directly applied to the surface of the porcelain tile blank, and then compared with the prior art that the ground glaze (overglaze) is applied firstly for pattern decoration, then the dry grain is applied, and the ground glaze process and the dry grain process are directly combined, the preparation method of the porcelain tile is simplified, the production cost of the porcelain tile is reduced, and the stability and the product qualification rate of the porcelain tile are improved.
The present invention will be described in further detail with reference to specific examples.
The first embodiment is as follows:
the invention provides a preparation method of a dry particle glazed porcelain tile, which particularly comprises the following steps:
s11, pressing and forming the blank, and drying the blank in a drying kiln to obtain a porcelain tile green body;
step S12, applying dry grain overglaze on the surface of the porcelain tile blank to obtain a dry grain overglaze layer;
step S13, performing glaze decoration on the surface of the dry particle glaze layer to obtain a glaze decoration layer;
step S14, applying protective glaze on the overglaze decoration layer to obtain a protective glaze layer;
and step S15, firing and forming in a kiln to obtain the dry particle glazed porcelain tile.
The dry material of the dry grain glaze comprises the following raw materials in parts by weight:
53 parts of dry overglaze and 47 parts of dry particles;
wherein the dry overglaze material comprises the following components in parts by weight: 3 parts of barium carbonate, 54 parts of zirconium silicate, 1 part of calcined talc, 30 parts of silica fume, 4 parts of kaolin and 9 parts of quartz;
the chemical composition of the dry granules comprises the following components in percentage by mass: SiO 22 55.32％、Al2O3 14.86％、Fe2O30.06％、CaO 9.82％、MgO 2.08％、BaO 2.12％、K2O 3.46％、Na2O 1.10％、ZnO 9.23％、B2O31.09% and 0.86% of loss on ignition.
Further, the billet chemical composition meter comprises:
SiO2 67％～69％、Al2O3 17％～19％、Fe2O3 0.9％～1.4％、CaO 0.2％～0.5％、MgO 1.0％～1.5％、K2O 2.1％～2.7％、Na22.2 to 2.7 percent of O and 4.9 to 5.4 percent of loss on ignition;
the drying temperature in the step S11 is 80-100 ℃, and the drying time is 60 min.
Further, the specific gravity of the glaze slip of the dry grain overglaze in the step S12 is 1.75 +/-0.02;
the glazing amount of the dry particle glaze ranges from 580 to 710g/m2；
The flow rate of the dry grain overglaze is 20-30 s.
Further, the specific gravity of the glaze slip of the protective glaze in the step S14 is 1.25-1.35, and the glazing amount of the protective glaze is 150-280 g/m2The glaze spraying pressure of the protective glaze is 3-5 kgf/cm2。
Further, in the step S15, the firing temperature when the molded product is fired in a kiln is 60min, and the maximum firing temperature is 1240 ℃.
It is understood that by applying a dry-grained overglaze directly on the surface of the green ceramic tile, the dry-grained overglaze comprises both an overglaze component and a dry-grained component; compared with the prior art that the ground glaze (overglaze) is firstly applied to carry out pattern decoration, then the dry particles are applied, and the ground glaze process and the dry particle process are directly combined, the preparation method of the porcelain tile is simplified, the production cost of the porcelain tile is reduced, and the stability and the product qualification of the porcelain tile are improved.
Example two:
the embodiment also provides a preparation method of the dry particle glazed ceramic tile, which is different from the first embodiment in that:
the wet material of the dry grain glaze comprises the following raw materials in parts by weight:
30 parts of dry overglaze material, 26 parts of dry particles and 44 parts of suspending agent;
wherein the dry overglaze material comprises the following components in parts by weight: 3 parts of barium carbonate, 54 parts of zirconium silicate, 1 part of calcined talc, 30 parts of silica fume, 4 parts of kaolin and 9 parts of quartz;
the chemical composition of the dry granules comprises the following components in percentage by mass: SiO 22 55.32％、Al2O3 14.86％、Fe2O30.06％、CaO 9.82％、MgO 2.08％、BaO 2.12％、K2O 3.46％、Na2O 1.10％、ZnO 9.23％、B2O31.09% and 0.86% of loss on ignition.
Example three: the embodiment also provides a preparation method of the dry particle glazed ceramic tile, which is different from the first embodiment in that:
the dry material of the dry grain glaze comprises the following raw materials in parts by weight:
1.5 parts of barium carbonate, 28 parts of zirconium silicate, 0.5 part of calcined talc, 16 parts of silica lime, 2 parts of kaolin, 5 parts of quartz and 47 parts of dry particles;
wherein the chemical composition of the dry granules comprises the following components in percentage by mass: SiO 22 55.32％、Al2O3 14.86％、Fe2O3 0.06％、CaO 9.82％、MgO 2.08％、BaO 2.12％、K2O 3.46％、Na2O 1.10％、ZnO 9.23％、B2O31.09% and 0.86% of loss on ignition.
Example four:
the embodiment also provides a preparation method of the dry particle glazed porcelain tile, which is different from the second embodiment in that:
the processing method of the dry grain overglaze comprises the following steps:
weighing 30 parts of dry overglaze material according to the weight percentage, adding a suspending agent, and performing ball milling to obtain dry overglaze material glaze slurry;
weighing 26 parts of dry particles according to the weight fraction, adding a suspending agent, and uniformly mixing to obtain dry particle glaze slurry;
uniformly mixing the dry overglaze slip and the dry particle slip according to the ratio of 1:1 to obtain dry particle overglaze;
wherein, the dry surface material in the dry surface glaze slip comprises the following dry surface material: suspending agent is 1: 0.6; dry particles in the dry particle glaze slurry: 1:1 of suspending agent; the fineness of the glaze slip of the dry grain glaze is 100 meshes.
It can be understood that the dry overglaze needs to be subjected to ball milling, a suspending agent needs to be added during the ball milling, and the dry overglaze in the dry overglaze slip is controlled to have the following characteristics: adding 18 parts of suspending agent when the suspending agent is 1: 0.6; and the dry particles can be directly and uniformly mixed with the suspending agent, and the dry particles in the overglaze dry material glaze slurry are controlled: adding 26 parts of suspending agent into the suspension agent in a ratio of 1: 1; that is, when preparing the dry grain overglaze, the dry overglaze material and the dry grains are respectively mixed with the suspending agent, and then the mixed glaze slip is converged to obtain the dry grain overglaze; the porcelain tile obtained in the embodiment has slightly dry grain glaze texture and slightly anti-skid effect.
Example five:
the embodiment also provides a preparation method of the dry particle glazed porcelain tile, which is different from the second embodiment in that:
the processing method of the dry grain overglaze comprises the following steps:
weighing 30 parts of dry overglaze material according to the weight percentage, adding a suspending agent, and performing ball milling to obtain dry overglaze material glaze slurry;
weighing 26 parts of dry particles according to the weight fraction, adding a suspending agent, and uniformly mixing to obtain dry particle glaze slurry;
uniformly mixing the dry overglaze slip and the dry particle slip according to the ratio of 1:1.1 to obtain dry particle overglaze;
wherein, the dry surface material in the dry surface glaze slip comprises the following dry surface material: suspending agent is 1: 0.6; dry particles in the dry particle glaze slurry: 1:1 of suspending agent; the fineness of the glaze slip of the dry grain overglaze is 150 meshes.
It can be understood that the dry overglaze needs to be subjected to ball milling, a suspending agent needs to be added during the ball milling, and the dry overglaze in the dry overglaze slip is controlled to have the following characteristics: adding 18 parts of suspending agent when the suspending agent is 1: 0.6; and the dry particles can be directly and uniformly mixed with the suspending agent, and the dry particles in the overglaze dry material glaze slurry are controlled: adding 26 parts of suspending agent into the suspension agent in a ratio of 1: 1; that is, when preparing the dry grain overglaze, the dry overglaze material and the dry grains are respectively mixed with the suspending agent, and then the mixed glaze slip is converged to obtain the dry grain overglaze; when the surface glaze dry material glaze slip and the dry particle glaze slip are mixed, the surface glaze dry material glaze slip is preferably as follows: dry grain glaze slip is 1: 1; it can be understood that the adding proportion of the dry particles in the dry particle overglaze and the dry overglaze material can be finely adjusted, the dry particle glazed porcelain tile obtained in the embodiment has dense texture of the dry particles, and the dry particle glazed porcelain tile has granular feel and strong anti-skid effect.
Example six:
the embodiment also provides a preparation method of the dry particle glazed ceramic tile, which is different from the first embodiment in that:
the chemical composition of the dry particle glaze comprises the following components in percentage by mass:
SiO2 47.05％、Al2O3 8.82％、Fe2O3 0.12％、CaO 13.06％、MgO 0.85％、BaO 4.21％、K2O 1.50％、Na2O 2.09％、ZnO 3.64％、B2O30.56 percent, ZrO 17.07 percent and loss on ignition 1.03 percent.
Example seven:
the embodiment also provides a preparation method of the dry particle glazed ceramic tile, which is different from the first embodiment in that:
the billet chemical composition meter comprises:
SiO2 69％、Al2O3 19％、Fe2O3 0.9％、CaO 0.2％、MgO 1.5％、K2O 2.6％、Na22.2 percent of O and 4.9 percent of loss on ignition;
the drying temperature in the step S11 is 80 ℃, and the drying time is 60 min.
Example eight:
the embodiment also provides a preparation method of the dry particle glazed ceramic tile, which is different from the first embodiment in that:
the billet chemical composition meter comprises:
SiO2 67％、Al2O3 18.8％、Fe2O3 1.4％、CaO 0.5％、MgO 1.5％、K2O 2.7％、Na2o2.7% and loss on ignition 5.4%;
the drying temperature in the step S11 is 100 ℃, and the drying time is 60 min.
Example nine:
the embodiment also provides a preparation method of the dry particle glazed ceramic tile, which is different from the first embodiment in that:
the glaze slip specific gravity of the dry grain overglaze in the step S11 is 1.73;
the glazing amount of the dry particle glaze is 580g/m2；
The flow rate of the dry grain overglaze is 20 s;
the glaze slip specific gravity of the protective glaze in the step S12 is 1.25, and the glazing amount of the protective glaze is 150g/m2The glaze spraying pressure of the protective glaze is 3kgf/cm2。
Example ten:
the embodiment also provides a preparation method of the dry particle glazed ceramic tile, which is different from the first embodiment in that:
the glaze slip specific gravity of the dry grain overglaze in the step S11 is 1.77;
the glazing amount of the dry particle glaze is 710g/m2；
The flow rate of the dry grain overglaze is 30 s;
the glaze slip specific gravity of the protective glaze in the step S12 is 1.35, and the glazing amount of the protective glaze is 280g/m2The glaze spraying pressure of the protective glaze is 5kgf/cm2。
Example eleven:
the embodiment also provides a dry particle glazed ceramic tile, which is prepared by the preparation method of the dry particle glazed ceramic tile; wherein, the dry particle glazed porcelain tile sequentially comprises from bottom to top: a porcelain tile body, a dry grain glaze layer, a surface glaze decorative layer and a protective glaze layer.
It can be understood that the dry grain overglaze is directly applied to the surface of the porcelain tile blank, and then compared with the prior art that the ground glaze (overglaze) is applied firstly for pattern decoration, then the dry grain is applied, and the ground glaze process and the dry grain process are directly combined, the preparation method of the porcelain tile is simplified, the production cost of the porcelain tile is reduced, and the stability and the product qualification rate of the porcelain tile are improved.
In summary, the invention provides a dry particle glazed ceramic tile and a preparation method thereof, and the preparation method of the dry particle glazed ceramic tile comprises the following steps: A. pressing and molding the blank, and drying the blank in a drying kiln to obtain a porcelain brick blank; B. applying dry grain glaze on the surface of the porcelain tile blank to obtain a dry grain glaze layer; C. performing glaze decoration on the surface of the dry particle glaze layer to obtain a glaze decoration layer; D. applying a protective glaze on the overglaze decorative layer to obtain a protective glaze layer; E. and putting the ceramic tile into a kiln for firing and forming to obtain the dry grain glazed ceramic tile. It can be understood that the dry grain overglaze is directly applied to the surface of the porcelain tile blank, and then compared with the prior art that the ground glaze (overglaze) is applied firstly for pattern decoration, then the dry grain is applied, and the ground glaze process and the dry grain process are directly combined, the preparation method of the porcelain tile is simplified, the production cost of the porcelain tile is reduced, and the stability and the product qualification rate of the porcelain tile are improved.
It is to be understood that the invention is not limited to the examples described above, but that modifications and variations may be effected thereto by those of ordinary skill in the art in light of the foregoing description, and that all such modifications and variations are intended to be within the scope of the invention as defined by the appended claims.

Claims (10)

1. A preparation method of dry particle glazed porcelain tiles is characterized by comprising the following steps:
A. pressing and molding the blank, and drying the blank in a drying kiln to obtain a porcelain brick blank;
B. applying dry grain glaze on the surface of the porcelain tile blank to obtain a dry grain glaze layer;
C. performing glaze decoration on the surface of the dry particle glaze layer to obtain a glaze decoration layer;
D. applying a protective glaze on the overglaze decorative layer to obtain a protective glaze layer;
E. and putting the ceramic tile into a kiln for firing and forming to obtain the dry grain glazed ceramic tile.
2. The method for preparing the dry particle glazed ceramic tile according to claim 1, wherein the dry particle glaze comprises the following raw materials in parts by weight:
53 parts of dry overglaze and 47 parts of dry particles;
wherein the dry overglaze material comprises the following components in parts by weight: 3 parts of barium carbonate, 54 parts of zirconium silicate, 1 part of calcined talc, 30 parts of silica fume, 4 parts of kaolin and 9 parts of quartz;
the chemical composition of the dry granules comprises the following components in percentage by mass: SiO 22 55.32％、Al2O314.86％、Fe2O30.06％、CaO 9.82％、MgO 2.08％、BaO 2.12％、K2O 3.46％、Na2O 1.10％、ZnO 9.23％、B2O31.09% and 0.86% of loss on ignition.
3. The method for preparing the dry particle glazed ceramic tile according to claim 1, wherein the wet material of the dry particle glaze comprises the following raw materials in parts by weight:
30 parts of dry overglaze material, 26 parts of dry particles and 44 parts of suspending agent;
wherein the dry overglaze material comprises the following components in parts by weight: 3 parts of barium carbonate, 54 parts of zirconium silicate, 1 part of calcined talc, 30 parts of silica fume, 4 parts of kaolin and 9 parts of quartz;
the chemical composition of the dry granules comprises the following components in percentage by mass: SiO 22 55.32％、Al2O314.86％、Fe2O30.06％、CaO 9.82％、MgO 2.08％、BaO 2.12％、K2O 3.46％、Na2O 1.10％、ZnO 9.23％、B2O31.09% and 0.86% of loss on ignition.
4. The method for preparing the dry particle glazed ceramic tile according to claim 1, wherein the chemical composition of the dry particle overglaze comprises the following components in percentage by mass:
SiO2 47.05％、Al2O3 8.82％、Fe2O3 0.12％、CaO 13.06％、MgO 0.85％、BaO 4.21％、K2O 1.50％、Na2O 2.09％、ZnO 3.64％、B2O30.56 percent, ZrO 17.07 percent and loss on ignition 1.03 percent.
5. The method for preparing the dry grain glazed ceramic tile according to claim 3, wherein the processing method of the dry grain overglaze comprises the following steps:
weighing 30 parts of dry overglaze material according to the weight percentage, adding a suspending agent, and performing ball milling to obtain dry overglaze material glaze slurry;
weighing 26 parts of dry particles according to the weight fraction, adding a suspending agent, and uniformly mixing to obtain dry particle glaze slurry;
uniformly mixing the dry overglaze slip and the dry particle slip according to the ratio of 1:1-1:1.1 to obtain dry particle overglaze;
wherein, the dry surface material in the dry surface glaze slip comprises the following dry surface material: suspending agent is 1: 0.6; dry particles in the dry particle glaze slurry: 1:1 of suspending agent; the fineness of the glaze slurry of the dry grain overglaze is 100-150 meshes.
6. The method of claim 1, wherein the blank chemical composition comprises:
SiO2 67％～69％、Al2O3 17％～19％、Fe2O3 0.9％～1.4％、CaO 0.2％～0.5％、MgO 1.0％～1.5％、K2O 2.1％～2.7％、Na22.2 to 2.7 percent of O and 4.9 to 5.4 percent of loss on ignition;
and B, drying at the temperature of 80-100 ℃ for 60min in the step A.
7. The method for producing a dry-grain glazed porcelain tile according to claim 1,
the specific gravity of the glaze slip of the dry grain overglaze in the step B is 1.75 +/-0.02;
the glazing amount of the dry particle glaze ranges from 580 to 710g/m2；
The flow rate of the dry grain overglaze is 20-30 s.
8. The method for producing a dry-grain glazed porcelain tile according to claim 1,
the specific gravity of the glaze slip of the protective glaze in the step D is 1.25-1.35, and the glazing amount of the protective glaze is 150-280 g/m2The glaze spraying pressure of the protective glaze is 3-5 kgf/cm2。
9. The method for producing a dry-grain glazed porcelain tile according to claim 1,
and E, firing temperature in the kiln for firing and forming is 60min, and the maximum firing temperature is 1240 ℃.
10. A dry-grained vitreous enamel brick, characterized in that it is obtained by the process for the preparation of a dry-grained vitreous enamel brick according to any one of claims 1 to 9;
wherein, the dry particle glazed porcelain tile sequentially comprises from bottom to top: a porcelain tile body, a dry grain glaze layer, a surface glaze decorative layer and a protective glaze layer.
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