CN112175695A - Metal soft film antirust oil - Google Patents

Metal soft film antirust oil Download PDF

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Publication number
CN112175695A
CN112175695A CN201910597312.8A CN201910597312A CN112175695A CN 112175695 A CN112175695 A CN 112175695A CN 201910597312 A CN201910597312 A CN 201910597312A CN 112175695 A CN112175695 A CN 112175695A
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CN
China
Prior art keywords
parts
oil
soft film
metal soft
kerosene
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Pending
Application number
CN201910597312.8A
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Chinese (zh)
Inventor
王方斌
计敏
杜晓青
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Shiyan Shuangqi Technology Co ltd
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Shiyan Shuangqi Technology Co ltd
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Priority to CN201910597312.8A priority Critical patent/CN112175695A/en
Publication of CN112175695A publication Critical patent/CN112175695A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/24—Epoxidised acids; Ester derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/285—Esters of aromatic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/102—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/064—Thiourea type compounds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a metal soft film anti-rust oil which comprises the following components in parts by mass: 70-80 parts of kerosene, 10-20 parts of transformer oil, 3-5 parts of zinc naphthenate, 1-2 parts of dioctyl phthalate, 2-3 parts of N-oleoyl sarcosine octadecylamine salt, 1-2 parts of 1-hydroxybenzotriazole, 0.6-1 part of tetramethylammonium hydroxide, 2-3 parts of epoxy cotton seed butyl oleate, 1-2 parts of propylene glycol adipate polyester, 1-2 parts of allyl thiourea, 3-4 parts of calcium petroleum sulfonate, 3-5 parts of dodecenyl succinic acid half ester, 1-2 parts of tall oil and 5-6 parts of anti-stripping mechanical oil, and relates to the technical field of anti-rust oil. The metal soft film antirust oil has good water absorption performance and sweat replacement performance, can quickly replace residual moisture on a workpiece, has soft surface oil film, is not easy to discolor and soften, has strong antistatic corrosion performance, good weather resistance, strong ultraviolet aging resistance, stable film coating, difficult oxidation, good protection effect on various metal workpieces and strong universality.

Description

Metal soft film antirust oil
Technical Field
The invention relates to the technical field of anti-rust oil, in particular to metal soft film anti-rust oil.
Background
Antirust oil; the rust-inhibiting oil is an oil solvent with red brown appearance and rust-inhibiting function, which comprises an oil-soluble corrosion inhibitor, base oil, an auxiliary additive and the like, and can be divided into fingerprint removal type rust-inhibiting oil, water dilution type rust-inhibiting oil, solvent dilution type rust-inhibiting oil, dual-purpose oil for rust-inhibiting lubrication, sealed storage rust-inhibiting oil, displacement type rust-inhibiting oil, thin-layer oil, rust-inhibiting grease, gas phase rust-inhibiting oil and the like according to performance and application, wherein the commonly used corrosion inhibitors in the rust-inhibiting oil comprise alkaline earth metal salts of fatty acid or naphthenic acid, lead naphthenate, zinc naphthenate, petroleum sodium sulfonate, barium petroleum sulfonate, calcium petroleum sulfonate, tallow diamine trioleate, rosin amine and the like.
The existing metal soft film antirust oil is easy to discolor, soften, resist static corrosion, resist ultraviolet aging and oxidize, and is not suitable for wide popularization and application.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides the metal soft film antirust oil, which solves the problems that the existing metal soft film antirust oil is easy to discolor, soften, resist static corrosion and strong ultraviolet aging resistance and is easy to oxidize.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: the metal soft film anti-rust oil comprises the following components in parts by mass: 70-80 parts of kerosene, 10-20 parts of transformer oil, 3-5 parts of zinc naphthenate, 1-2 parts of dioctyl phthalate, 2-3 parts of N-oleoyl sarcosine octadecylamine salt, 1-2 parts of 1-hydroxybenzotriazole, 0.6-1 part of tetramethylammonium hydroxide, 2-3 parts of epoxy cotton seed butyl oleate, 1-2 parts of propylene glycol adipate polyester, 1-2 parts of allyl thiourea, 3-4 parts of calcium petroleum sulfonate, 3-5 parts of dodecenyl succinic acid half ester, 1-2 parts of tall oil and 5-6 parts of anti-stripping mechanical oil.
Preferably, the kerosene is jet fuel.
Preferably, the zinc naphthenate contains 5 to 7 percent of zinc.
Preferably, the anti-stripping mechanical oil consists of 2 parts of polyethylene glycol monomethyl ether, 0.1 part of 2, 6-di-tert-butyl-4-methylphenol, 4 parts of rosin, 1 part of urethane acrylate, 3 parts of lanthanum nitrate, 90 parts of mechanical oil, 6 parts of zinc dihydrogen phosphate, 40 parts of 28% ammonia water, 20 parts of deionized water and 0.1 part of a silane coupling agent.
Preferably, the metal soft film rust preventive oil comprises the following components in parts by mass: 70 parts of kerosene, 10 parts of transformer oil, 3 parts of zinc naphthenate, 1 part of dioctyl phthalate, 2 parts of N-oleoyl sarcosine octadecylamine salt, 1 part of 1-hydroxybenzotriazole, 0.6 part of tetramethylammonium hydroxide, 2 parts of epoxy cotton butyl oleate, 1 part of propylene glycol adipate polyester, 1 part of allylthiourea, 3 parts of calcium petroleum sulfonate, 3 parts of dodecenylsuccinic acid half-ester, 1 part of tall oil and 5 parts of anti-stripping mechanical oil.
Preferably, the metal soft film rust preventive oil comprises the following components in parts by mass: 80 parts of kerosene, 20 parts of transformer oil, 5 parts of zinc naphthenate, 2 parts of dioctyl phthalate, 3 parts of N-oleoyl sarcosine octadecylamine salt, 2 parts of 1-hydroxybenzotriazole, 1 part of tetramethyl ammonium hydroxide, 3 parts of epoxy cotton butyl oleate, 2 parts of propylene glycol adipate polyester, 2 parts of allyl thiourea, 4 parts of calcium petroleum sulfonate, 5 parts of dodecenyl succinic acid half ester, 2 parts of tall oil and 6 parts of anti-stripping mechanical oil.
(III) advantageous effects
The invention has the following beneficial effects:
the metal soft film antirust oil has good water absorption performance and sweat replacement performance, can quickly replace residual moisture on a workpiece, has soft surface oil film, is not easy to discolor and soften, has strong antistatic corrosion performance, good weather resistance, strong ultraviolet aging resistance, stable film coating, difficult oxidation, good protection effect on various metal workpieces and strong universality.
It is not necessary for any product that embodies the invention to achieve all of the above-described advantages simultaneously.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below.
The embodiment of the invention provides a technical scheme that: the metal soft film anti-rust oil comprises the following components in parts by mass: 70-80 parts of kerosene, 10-20 parts of transformer oil, 3-5 parts of zinc naphthenate, 1-2 parts of dioctyl phthalate, 2-3 parts of N-oleoyl sarcosine octadecylamine salt, 1-2 parts of 1-hydroxybenzotriazole, 0.6-1 part of tetramethylammonium hydroxide, 2-3 parts of epoxy cotton seed butyl oleate, 1-2 parts of propylene glycol adipate polyester, 1-2 parts of allyl thiourea, 3-4 parts of calcium petroleum sulfonate, 3-5 parts of dodecenyl succinic acid half ester, 1-2 parts of tall oil and 5-6 parts of anti-stripping mechanical oil.
The kerosene is aviation kerosene or dewaxing kerosene, and can be adjusted according to actual use conditions.
The zinc naphthenate contains 5-7% of zinc.
The anti-stripping mechanical oil is composed of 2 parts of polyethylene glycol monomethyl ether, 0.1 part of 2, 6-di-tert-butyl-4-methylphenol, 4 parts of rosin, 1 part of urethane acrylate, 3 parts of lanthanum nitrate, 90 parts of mechanical oil, 6 parts of zinc dihydrogen phosphate, 40 parts of 28% ammonia water, 20 parts of deionized water and 0.1 part of a silane coupling agent.
The metal soft film antirust oil comprises the following components in parts by mass: 70 parts of kerosene, 10 parts of transformer oil, 3 parts of zinc naphthenate, 1 part of dioctyl phthalate, 2 parts of N-oleoyl sarcosine octadecylamine salt, 1 part of 1-hydroxybenzotriazole, 0.6 part of tetramethylammonium hydroxide, 2 parts of epoxy cotton butyl oleate, 1 part of propylene glycol adipate polyester, 1 part of allylthiourea, 3 parts of calcium petroleum sulfonate, 3 parts of dodecenylsuccinic acid half-ester, 1 part of tall oil and 5 parts of anti-stripping mechanical oil.
Second embodiment
The metal soft film antirust oil comprises the following components in parts by mass: 80 parts of kerosene, 20 parts of transformer oil, 5 parts of zinc naphthenate, 2 parts of dioctyl phthalate, 3 parts of N-oleoyl sarcosine octadecylamine salt, 2 parts of 1-hydroxybenzotriazole, 1 part of tetramethyl ammonium hydroxide, 3 parts of epoxy cotton butyl oleate, 2 parts of propylene glycol adipate polyester, 2 parts of allyl thiourea, 4 parts of calcium petroleum sulfonate, 5 parts of dodecenyl succinic acid half ester, 2 parts of tall oil and 6 parts of anti-stripping mechanical oil.
Third embodiment
The metal soft film antirust oil comprises the following components in parts by mass: 75 parts of kerosene, 15 parts of transformer oil, 4 parts of zinc naphthenate, 1.5 parts of dioctyl phthalate, 2.5 parts of N-oleoyl sarcosine octadecylamine salt, 1 part of 1-hydroxybenzotriazole, 0.8 part of tetramethylammonium hydroxide, 2 parts of epoxy cotton seed butyl oleate, 1.5 parts of propylene adipate polyester, 1 part of allyl thiourea, 3.5 parts of calcium petroleum sulfonate, 4 parts of dodecenyl succinic acid half ester, 4.5 parts of tall oil and 5.5 parts of anti-stripping mechanical oil.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof.

Claims (6)

1. A metal soft film antirust oil is characterized in that: the metal soft film antirust oil comprises the following components in parts by mass: 70-80 parts of kerosene, 10-20 parts of transformer oil, 3-5 parts of zinc naphthenate, 1-2 parts of dioctyl phthalate, 2-3 parts of N-oleoyl sarcosine octadecylamine salt, 1-2 parts of 1-hydroxybenzotriazole, 0.6-1 part of tetramethylammonium hydroxide, 2-3 parts of epoxy cotton seed butyl oleate, 1-2 parts of propylene glycol adipate polyester, 1-2 parts of allyl thiourea, 3-4 parts of calcium petroleum sulfonate, 3-5 parts of dodecenyl succinic acid half ester, 1-2 parts of tall oil and 5-6 parts of anti-stripping mechanical oil.
2. The metal soft film rust preventive oil as claimed in claim 1, wherein: the kerosene is aviation kerosene.
3. The metal soft film rust preventive oil as claimed in claim 1, wherein: the zinc naphthenate contains 5-7% of zinc.
4. The metal soft film rust preventive oil as claimed in claim 1, wherein: the anti-stripping mechanical oil is composed of 2 parts of polyethylene glycol monomethyl ether, 0.1 part of 2, 6-di-tert-butyl-4-methylphenol, 4 parts of rosin, 1 part of urethane acrylate, 3 parts of lanthanum nitrate, 90 parts of mechanical oil, 6 parts of zinc dihydrogen phosphate, 40 parts of 28% ammonia water, 20 parts of deionized water and 0.1 part of a silane coupling agent.
5. The metal soft film rust preventive oil as claimed in claim 1, wherein: the metal soft film antirust oil comprises the following components in parts by mass: 70 parts of kerosene, 10 parts of transformer oil, 3 parts of zinc naphthenate, 1 part of dioctyl phthalate, 2 parts of N-oleoyl sarcosine octadecylamine salt, 1 part of 1-hydroxybenzotriazole, 0.6 part of tetramethylammonium hydroxide, 2 parts of epoxy cotton butyl oleate, 1 part of propylene glycol adipate polyester, 1 part of allylthiourea, 3 parts of calcium petroleum sulfonate, 3 parts of dodecenylsuccinic acid half-ester, 1 part of tall oil and 5 parts of anti-stripping mechanical oil.
6. The metal soft film rust preventive oil as claimed in claim 1, wherein: the metal soft film antirust oil comprises the following components in parts by mass: 80 parts of kerosene, 20 parts of transformer oil, 5 parts of zinc naphthenate, 2 parts of dioctyl phthalate, 3 parts of N-oleoyl sarcosine octadecylamine salt, 2 parts of 1-hydroxybenzotriazole, 1 part of tetramethyl ammonium hydroxide, 3 parts of epoxy cotton butyl oleate, 2 parts of propylene glycol adipate polyester, 2 parts of allyl thiourea, 4 parts of calcium petroleum sulfonate, 5 parts of dodecenyl succinic acid half ester, 2 parts of tall oil and 6 parts of anti-stripping mechanical oil.
CN201910597312.8A 2019-07-04 2019-07-04 Metal soft film antirust oil Pending CN112175695A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910597312.8A CN112175695A (en) 2019-07-04 2019-07-04 Metal soft film antirust oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910597312.8A CN112175695A (en) 2019-07-04 2019-07-04 Metal soft film antirust oil

Publications (1)

Publication Number Publication Date
CN112175695A true CN112175695A (en) 2021-01-05

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Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115678636A (en) * 2021-07-29 2023-02-03 中国石油天然气股份有限公司 Corrosion inhibitor and preparation method and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115678636A (en) * 2021-07-29 2023-02-03 中国石油天然气股份有限公司 Corrosion inhibitor and preparation method and application thereof
CN115678636B (en) * 2021-07-29 2024-05-28 中国石油天然气股份有限公司 Corrosion inhibitor and preparation method and application thereof

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