CN112119526A

CN112119526A - Solid-state battery, battery module, and method for charging solid-state battery

Info

Publication number: CN112119526A
Application number: CN201980032049.6A
Authority: CN
Inventors: 志村重辅; 青木则之; 加藤友裕
Original assignee: Murata Manufacturing Co Ltd
Current assignee: Murata Manufacturing Co Ltd
Priority date: 2018-05-15
Filing date: 2019-05-08
Publication date: 2020-12-22
Also published as: US20210066771A1; JPWO2019220981A1; WO2019220981A1

Abstract

A solid-state battery is provided with: a battery element including a positive electrode layer and a negative electrode layer that are alternately laminated with a solid electrolyte layer interposed therebetween; a positive electrode terminal attached to the battery element so as to be electrically connected to the positive electrode layer and electrically separated from the negative electrode layer; a negative electrode terminal attached to the battery element so as to be electrically connected to the negative electrode layer and electrically separated from the positive electrode layer; an insulating covering member that covers the battery element such that the positive electrode terminal and the negative electrode terminal are led out; and a heat receiving member mounted to the covering member so as to be electrically separated from the positive electrode terminal and the negative electrode terminal, respectively, and having a thermal conductivity higher than that of the covering member.

Description

Solid-state battery, battery module, and method for charging solid-state battery

Technical Field

The present technology relates to a solid-state battery including a positive electrode layer, a negative electrode layer, and a solid electrolyte layer, a charging method therefor, and a battery module using the solid-state battery.

Background

Various electronic devices such as cellular phones are widely used, and miniaturization, weight reduction, and long life of the electronic devices are strongly desired. Accordingly, as a power source, development of a battery that can be repeatedly used (can be charged and discharged) has been actively performed.

As the battery, a solid-state battery (solid-state battery) using a solid-state electrolyte (solid electrolyte) has attracted attention instead of a liquid-state battery using a liquid-state electrolyte (electrolytic solution). This is because the solid-state battery does not have a problem of liquid leakage that is unique to a liquid-based battery.

The solid-state battery includes a positive electrode layer, a negative electrode layer, and a solid electrolyte layer. Since the structure of the solid-state battery has a large influence on the charging characteristics, various studies have been made on the structure of the solid-state battery.

Specifically, in order to rapidly charge the solid-state battery, a heating mechanism (heating element) is provided on the outer surface or inside the solid-state battery (see, for example, patent document 1).

Prior art documents

Patent document

Patent document 1: japanese unexamined patent publication Hei 04-010366

Disclosure of Invention

Although various studies have been made on the structure of the solid-state battery, the charge characteristics of the solid-state battery are still insufficient, and therefore, there is still room for improvement. In this case, particularly, the urgent desire for the above-described quick charging has an ever-increasing tendency, and therefore, it is important to easily realize the quick charging.

The present technology has been made in view of the above problems, and an object thereof is to provide a solid-state battery, a charging method thereof, and a battery module, which can easily improve charging characteristics.

A solid-state battery according to an embodiment of the present technology includes: a battery element including a positive electrode layer and a negative electrode layer that are alternately laminated with a solid electrolyte layer interposed therebetween; a positive electrode terminal attached to the battery element so as to be electrically connected to the positive electrode layer and electrically separated from the negative electrode layer; a negative electrode terminal attached to the battery element so as to be electrically connected to the negative electrode layer and electrically separated from the positive electrode layer; an insulating covering member that covers the battery element so that the positive electrode terminal and the negative electrode terminal are led out, respectively; and a heat receiving member mounted to the covering member so as to be electrically separated from the positive electrode terminal and the negative electrode terminal, respectively, and having a thermal conductivity higher than that of the covering member.

A battery module according to an embodiment of the present technology includes: a support; a solid-state battery disposed on the support; a heat source disposed on the support at a position different from a position at which the solid-state battery is disposed; and a heat transfer member disposed on the support body and thermally connecting the solid-state battery and the heat source to each other, the solid-state battery having the same configuration as that of the solid-state battery according to the embodiment of the present technology.

A method of charging a solid-state battery according to an embodiment of the present technology is a method as follows: the solid-state battery is heated, the temperature of the solid-state battery is measured, whether the temperature of the solid-state battery reaches a predetermined temperature is determined, and when the temperature of the solid-state battery reaches the predetermined temperature, the solid-state battery is charged.

Another method of charging a solid-state battery according to an embodiment of the present technology is a method as follows: the method includes heating a solid-state battery, measuring a heating time of the solid-state battery, determining whether the heating time of the solid-state battery reaches a predetermined heating time, and charging the solid-state battery when the heating time of the solid-state battery reaches the predetermined heating time.

Another method of charging a solid-state battery according to an embodiment of the present technology is a method as follows: the method includes charging a solid-state battery, calculating a charging rate of the solid-state battery, determining whether the charging rate of the solid-state battery reaches a predetermined charging rate, and heating the solid-state battery when the charging rate of the solid-state battery reaches the predetermined charging rate.

Another method of charging a solid-state battery according to an embodiment of the present technology is a method as follows: the method includes charging the solid-state battery, measuring a voltage of the solid-state battery, determining whether the voltage of the solid-state battery reaches a predetermined voltage, and heating the solid-state battery when the voltage of the solid-state battery reaches the predetermined voltage.

According to the solid-state battery of one embodiment of the present technology, the heat receiving member is attached to the covering member so as to be electrically separated from the positive electrode terminal and the negative electrode terminal, respectively, and the heat conductivity of the heat receiving member is higher than the heat conductivity of the covering member, so that the charging characteristics of the battery module using the solid-state battery can be easily improved.

According to the battery module of one embodiment of the present technology, the solid-state battery and the heat source are disposed on the support, and the solid-state battery and the heat source are thermally connected to each other through the heat transfer member, so that the charging characteristics can be easily improved.

According to the method of charging a solid-state battery according to an embodiment of the present technology, after heating the solid-state battery, the solid-state battery is charged based on the temperature of the solid-state battery, or the solid-state battery is charged based on the heating time of the solid-state battery, and therefore, the charging characteristics can be easily improved.

According to another method of charging a solid-state battery according to an embodiment of the present technology, after the solid-state battery is charged, the solid-state battery is heated based on the charging rate of the solid-state battery, or the solid-state battery is charged based on the voltage of the solid-state battery, and therefore, the charging characteristics can be easily improved.

Note that the effect of the present technology is not necessarily limited to the effect described here, and may be any of a series of effects related to the present technology described later.

Drawings

Fig. 1 is a plan view showing a structure of a battery module according to an embodiment of the present technology.

Fig. 2 is a plan view showing the structure of the solid-state battery shown in fig. 1.

Fig. 3 is a plan view showing another configuration of the solid-state battery shown in fig. 1.

Fig. 4 is a sectional view showing the configuration of the solid-state battery along the line 1A-1A shown in fig. 1.

Fig. 5 is a block diagram illustrating the configuration of the battery module shown in fig. 1.

Fig. 6 is a flowchart for explaining the operation of the battery module according to the embodiment of the present technology.

Fig. 7A is a plan view for explaining a manufacturing process of a battery module according to an embodiment of the present technology.

Fig. 7B is a sectional view illustrating the configuration of the battery module taken along 7A-7A shown in fig. 7A.

Fig. 8A is a plan view for explaining a manufacturing process of the battery module subsequent to fig. 7A.

Fig. 8B is a sectional view illustrating the configuration of the battery module taken along line 8A-8A shown in fig. 8A.

Fig. 9A is a plan view for explaining a manufacturing process of the battery module subsequent to fig. 8A.

Fig. 9B is a sectional view illustrating the configuration of the battery module taken along 9A-9A shown in fig. 9A.

Fig. 10A is a plan view for explaining a manufacturing process of the battery module subsequent to fig. 9A.

Fig. 10B is a sectional view illustrating the configuration of the battery module taken along line 10A-10A shown in fig. 10A.

Fig. 11A is a plan view for explaining a manufacturing process of the battery module subsequent to fig. 10A.

Fig. 11B is a sectional view illustrating the configuration of the battery module taken along line 11A-11A shown in fig. 11A.

Fig. 12 is a cross-sectional view showing the structure of a solid-state battery according to modification 2.

Fig. 13 is a flowchart for explaining the operation of the battery module according to modification 3.

Fig. 14 is a flowchart for explaining the operation of the battery module according to modification 4.

Fig. 15 is a flowchart for explaining the operation of the battery module according to modification 5.

Fig. 16 is a plan view showing the structure of a battery module according to modification 6.

Detailed Description

An embodiment of the present technology will be described in detail below with reference to the drawings. Note that the order of description is as follows.

1. Battery module (solid battery)

1-1. integral formation

1-2. constitution of solid-state Battery

1-3. block structure

1-4 action (charging method of solid battery)

1-5. method of manufacture

1-6. action and Effect

2. Modification example

3. Use of battery module (solid battery)

<1. Battery Module (solid State Battery) >

A battery module according to an embodiment of the present technology will be described.

Note that the solid-state battery according to an embodiment of the present technology is a part (a component) of the battery module described here, and therefore, the following description is given together with the solid-state battery.

This battery module includes a solid-state battery 200 (see fig. 2 to 4) described later, and is used as a power source in various applications. The solid-state battery 200 is a battery using a solid electrolyte, and is a so-called all-solid-state battery. In the solid-state battery 200, the battery capacity is obtained by utilizing the intercalation phenomenon of the electrode reaction substance and the deintercalation phenomenon of the electrode reaction substance.

The electrode reactant is a substance involved in an electrode reaction (so-called charge-discharge reaction). The kind of the electrode reaction substance is not particularly limited, and examples thereof include alkali metals. Next, for example, a case where the electrode reaction material is lithium will be described.

Note that, with respect to a specific example (a plurality of options regarding materials, forming methods, and the like) of an example described below as appropriate, only one type may be adopted, and two or more types may be combined with each other.

<1-1. Overall construction >

Fig. 1 shows a planar configuration of a battery module. However, in fig. 1, the illustration of the solid-state battery 200 is simplified.

For example, as shown in fig. 1, the battery module includes a solid-state battery 200, a heater 300, a wiring 400, and a heat transfer wire 500 on a base 100. In fig. 1, the solid-state battery 200 and the heater 300 are shaded, respectively.

[ base body 100]

The base 100 is a support for supporting the solid-state battery 200, the heater 300, and the like. The base 100 is, for example, a so-called printed board. Therefore, for example, the solid-state battery 200, the heater 300, the wiring 400, and the heat transmission wire 500 are mounted on one surface of the base 100 by surface mounting technology.

[ solid-state Battery ]

The solid-state battery 200 is a main part of the battery module (so-called power source) and is disposed on the substrate 100. As will be described later, the solid-state battery 200 includes a heat receiving pad 250 (see fig. 2 to 4) for receiving heat generated by the heater 300. Note that the detailed configuration of the solid-state battery 200 will be described later (see fig. 2 to 4).

[ Heater ]

The heater 300 is a heating source that heats the solid-state battery 200. The heater 300 is provided on the substrate 100 separately from the solid-state battery 200, that is, is disposed on the substrate 100 at a position different from the position where the solid-state battery 200 is disposed.

In particular, the heater 300 generates heat by itself, and heats the solid-state battery 200 by the heat generated when it generates heat. The heater 300 includes a heater such as a chip resistor (chip resistor) or a Positive Temperature Coefficient (PTC) thermistor. This is because the heater 300 can be easily attached to the base 100, and the heater 300 can sufficiently heat the solid-state battery 200.

The chip resistor is an electronic component (heat generating resistor) that generates heat by a resistor. Specifically, the chip resistor is, for example, a surface-mount high-power chip resistor. The PTC thermistor is an electronic component (heat generating resistor) that generates heat by utilizing the characteristic of an increase in resistance at a certain temperature or higher. Specifically, the PTC thermistor is, for example, a POSISTOR (registered trademark) FTP series (micro heater) manufactured by mitania corporation.

[ Wiring ]

The wiring 400 is a current-carrying member (electrical wiring) for carrying out current carrying to the solid-state battery 200, and is disposed on the substrate 100. The wiring 400 is made of a conductive material such as copper, for example.

Specifically, the battery module includes two wires 400 (positive electrode wire 401 and negative electrode wire 402) for operating the solid-state battery 200, for example. The positive electrode wiring 401 and the negative electrode wiring 402 are separated from each other in the X-axis direction, for example, and extend in the X-axis direction. Positive electrode wiring 401 is connected to positive electrode terminal 220 (positive electrode terminal surface 220M) described later in solid-state battery 200, for example. The negative electrode wiring 402 is connected to, for example, a negative electrode terminal 230 (negative electrode terminal surface 230M) described later in the solid-state battery 200 (see fig. 3 and 4).

[ Heat transfer line ]

The heat radiation wire 500 is a heat transfer member for thermally connecting the solid-state battery 200 and the heater 300 to each other, and is disposed on the base 100. The structure of the heat conductive wire 500 is not particularly limited as long as it has thermal conductivity.

Here, the heat transfer wire 500 functions as, for example, a heat transfer member that transfers heat generated in the heater 300 to the solid-state battery 200, and also functions as an energizing member (electrical wiring) that energizes the heater 300. This is because the heat transmission line 500 also serves as an electric wiring for conducting electricity to the heater 300, and thus it is not necessary to provide an electric wiring for conducting electricity separately from the heat transmission line 500. This is because the heat conductive wire 500 can be easily attached to the base 100 together with the solid-state battery 200 and the heater 300.

Specifically, the battery module includes, for example, two heat transmission lines 500 (a positive heat transmission line 501 and a negative heat transmission line 502). The positive electrode heat transfer line 501 and the negative electrode heat transfer line 502 are separated from each other in the X axis direction, for example, and extend in the Y axis direction.

The positive electrode heat transfer wire 501 functions as an electric wire for supplying electricity to the heater 300, and is connected to a positive electrode, not shown, of the heater 300. The negative electrode heat transfer wire 502 functions as an electrical wiring for conducting electricity to the heater 300, and is connected to a negative electrode, not shown, of the heater 300.

The positive electrode heat transfer wire 501 is connected to a heat receiving pad 251 (heat receiving surface 251M) of the solid-state battery 200, which will be described later, in order to transfer heat generated by the heater 300 to the solid-state battery 200. The negative heat transfer wire 502 is connected to a heat receiving pad 252 (heat receiving surface 252M) described later in the solid-state battery 200 (see fig. 2 to 4) in order to transfer heat generated by the heater 300 to the solid-state battery 200.

That is, the positive electrode heat transfer wire 501 and the negative electrode heat transfer wire 502 are used to energize the heater 300 and transfer heat generated in the heater 300 to the solid-state battery 200. Thus, the heater 300 can heat the solid-state battery 200 via the positive and negative

heat transmission wires

501 and 502 and the

heat receiving pads

251 and 252.

Note that each of the positive electrode heat transfer line 501 and the negative electrode heat transfer line 502 may include, for example, a conductive material such as solder in addition to an electric wiring such as a copper wire. The conductive material such as solder is used, for example, to fix the positive electrode heat transfer wire 501 and the negative electrode heat transfer wire 502 to the base 200, and to connect the positive electrode heat transfer wire 501 and the negative electrode heat transfer wire 502 to the solid-state battery 200 (heat receiving pads 251 and 252).

<1-2 > construction of solid-state Battery

Fig. 2 and 3 each show a planar configuration of the solid-state battery 200 shown in fig. 1, and fig. 4 shows a sectional configuration of the solid-state battery 200 along the line 1A-1A shown in fig. 1.

However, fig. 2 shows a state in which the solid-state battery 200 is viewed from above (the side on which the heat receiving pad 250 is not arranged), and fig. 3 shows a state in which the solid-state battery 200 is viewed from below (the side on which the heat receiving pad 250 is arranged).

For example, as shown in fig. 2 to 4, the solid-state battery 200 includes a laminate 210, a positive electrode terminal 220, a negative electrode terminal 230, a cover 240, and a heat receiving pad 250. The positive terminal 220, the negative terminal 230, and the heat receiving pad 250 are each shaded in fig. 2 and 3, respectively.

[ laminate ]

The laminate 210 is a battery element including a positive electrode layer 211, a negative electrode layer 212, and a solid electrolyte layer 213. The laminate 210 is disposed between the positive electrode terminal 220 and the negative electrode terminal 230, and includes a plurality of layers laminated in a direction (Z-axis direction) intersecting a direction (X-axis direction) in which the positive electrode terminal 220 and the negative electrode terminal 230 face each other. The plurality of layers are, for example, a positive electrode layer 211, a negative electrode layer 212, a solid electrolyte layer 213, a positive electrode separation layer 214, and a negative electrode separation layer 215.

Specifically, the laminate 210 has, for example, a laminate structure in which

positive electrode layers

211 and 214, and

negative electrode layers

212 and 215 are alternately laminated with solid electrolyte layers 213 interposed therebetween in the Z-axis direction. Therefore, the positive electrode layer 211 and the positive electrode separation layer 214, and the negative electrode layer 212 and the negative electrode separation layer 215 are separated from each other through the solid electrolyte layer 213. Here, for example, the lowermost layer in the stacked structure is the negative electrode layer 212 and the negative electrode separation layer 215, and the uppermost layer in the stacked structure is the negative electrode layer 212 and the negative electrode separation layer 215.

The number of stacked layers (the number of positive electrode layers 211, negative electrode layers 212, and solid electrolyte layers 213) of the stacked body 210 is not particularly limited. Fig. 4 shows a case where the number of positive electrode layers 211 is two, the number of negative electrode layers 212 is three, and the number of solid electrolyte layers 13 is four, for example, to simplify the illustration.

Note that the stacked body 210 may include, for example, other layers than the above-described series of layers. Other layers are for example protective layers etc. The protective layer is, for example, the lowermost layer in the stacked body 210 and the uppermost layer in the stacked body 210.

(Positive electrode layer)

The positive electrode layer 211 is electrically connected to the positive electrode terminal 220 and electrically separated from the negative electrode terminal 230 via the positive electrode separation layer 214.

The positive electrode layer 211 has a laminated structure in which a positive electrode current collecting layer and a positive electrode active material layer are laminated in the Z-axis direction, for example. In this case, for example, one positive electrode current collecting layer and one positive electrode active material layer may be laminated with each other, or two positive electrode active material layers may be laminated with one positive electrode current collecting layer interposed therebetween.

The positive electrode current collecting layer includes, for example, a conductive material such as a carbon material or a metal material, and may further include a binder, a solid electrolyte, and the like. The positive electrode active material layer includes, for example, a positive electrode active material capable of lithium intercalation and lithium deintercalation, and may further include a binder, a conductive agent, a solid electrolyte, and the like. The positive electrode active material is, for example, a lithium compound such as a composite oxide containing lithium as a constituent element, a phosphoric acid compound containing lithium as a constituent element, or the like. Note that the solid electrolyte has, for example, the same configuration as the solid electrolyte included in the solid electrolyte layer 213.

(negative electrode layer)

Negative electrode layer 212 is electrically connected to negative electrode terminal 230, and is electrically separated from positive electrode terminal 220 via negative electrode separation layer 215.

The negative electrode layer 212 has a laminated structure in which a negative electrode current collecting layer and a negative electrode active material layer are laminated in the Z-axis direction, for example. In this case, for example, one negative electrode current collector layer and one negative electrode active material layer may be stacked on each other, or two negative electrode active material layers may be stacked on each other with one negative electrode current collector layer interposed therebetween.

The negative electrode current collecting layer includes, for example, a conductive material such as a carbon material or a metal material, and may further include a binder, a solid electrolyte, and the like. The negative electrode active material layer includes, for example, a negative electrode active material capable of lithium intercalation and lithium deintercalation, and may further include a binder, a conductive agent, a solid electrolyte, and the like. Examples of the negative electrode active material include carbon materials, metal materials, and lithium compounds. The carbon material is, for example, graphite or the like. The metal-based material is, for example, a material including silicon as a constituent element. The lithium compound is, for example, a composite oxide including lithium as a constituent element. Note that the solid electrolyte has, for example, the same configuration as the solid electrolyte included in the solid electrolyte layer 213.

(solid electrolyte layer)

The solid electrolyte layer 213 is a medium for transferring lithium between the positive electrode layer 211 and the negative electrode layer 212, and is electrically connected to the positive electrode terminal 220 and the negative electrode terminal 230, respectively. The solid electrolyte layer 213 includes a solid electrolyte, and may further include a binder or the like. Examples of the solid electrolyte include crystalline solid electrolytes and glass ceramic solid electrolytes.

(cathode separation layer and cathode separation layer)

The positive electrode separation layer 214 and the negative electrode separation layer 215 have the same structure as the solid electrolyte layer 213, for example.

[ Positive electrode terminal and negative electrode terminal ]

Positive electrode terminal 220 is attached to one side surface (the side on which negative electrode separation layer 215 is disposed) of stacked body 210, and is electrically connected to positive electrode layer 211. The positive electrode terminal 220 is made of a conductive material such as silver, and has a thermal conductivity of C3.

Note that the positive electrode terminal 220 extends in the Z-axis direction along one side surface of the stacked body 210, for example, and is then bent outward in the X-axis direction. Therefore, the portion of the positive electrode terminal 220 bent outward has, for example, a positive electrode terminal surface 220M along a predetermined surface (XY plane). Positive terminal surface 220M is a connection surface to be connected to positive wiring 401, and has an area S3.

The negative electrode terminal 230 is attached to the other side surface (the side on which the positive electrode separation layer 214 is disposed) of the stacked body 210, and is separated from the positive electrode terminal 220. Thus, the negative electrode terminal 230 is electrically connected to the negative electrode layer 212. The negative terminal 230 is made of, for example, the same material as the material forming the positive terminal 220, and has thermal conductivity C4.

Note that the negative electrode terminal 230 extends in the Z-axis direction along, for example, the other side surface of the stacked body 210, and is then bent outward in the X-axis direction (in the direction opposite to the direction in which the positive electrode terminal 220 is bent). Therefore, the bent portion of the negative terminal 230 has a negative terminal surface 230M along the XY plane, for example. The negative electrode terminal surface 230M is a connection surface to be connected to the negative electrode wiring 402, and has an area S4.

[ covering layer ]

The cover layer 240 is a covering member that covers the periphery of the laminate 210 in order to physically and chemically protect the laminate 210. However, a part of each of the positive electrode terminal 220 and the negative electrode terminal 230 is led out from the inside of the cover 240 to the outside. That is, the cover 240 covers the stacked body 210 so that the positive electrode terminal 220 and the negative electrode terminal 230 are led out.

The cover layer 240 is made of an insulating polymer material such as epoxy resin, and thus has insulation properties. However, the cover layer 240 may have a multilayer structure in which two or more layers are laminated from the inside toward the outside, for example. In this case, for example, two or more layers may be separated from each other with the barrier layer interposed therebetween.

The thermal conductivity of the cover layer 240 is not particularly limited, and among them, as low a thermal conductivity as possible is preferable. This is because, when heat is transferred from the heat receiving pad 250 to the laminated body 210, the heat is easily maintained in the laminated body 210, and therefore, the laminated body 210 is easily heated efficiently. In this case, the cover layer 240 may have a plurality of bubbles (voids) therein in order to improve the heat retaining property of the cover layer 240.

The color of the cover layer 240 is not particularly limited, and among them, a color having a small emissivity is preferable. This is because the heat is easily maintained in the stacked body 210, and therefore the stacked body 210 is easily heated efficiently. Specifically, as for the color of the cover layer 240, a light color is preferable to a dark color, and more specifically, white is preferable to black.

Accordingly, the surface shape of the cover layer 240 is preferably as smooth as possible. This is because, as described above, the emissivity becomes small, and it becomes difficult to radiate heat from the inside to the outside of the cover layer 240. Specifically, the surface of the cover layer 240 is preferably smoothed as compared with the surface textured finish.

[ heated cushion ]

The heat receiving pad 250 is a heat receiving member that receives heat transmitted from the heater 300 via the heat transmitting wire 500, and is attached to the stacked body 210. Thereby, the heat receiving pad 250 receives heat supplied from the heater 300, and heats the stacked body 210 with the heat.

The heat receiving pad 250 is separated from the positive and

negative terminals

220 and 230, respectively, to be electrically separated from the positive and

negative terminals

220 and 230, respectively. However, as described above, the heat receiving pad 250 is thermally connected to the stacked body 210 to heat the stacked body 210, and particularly has a thermal conductivity C higher than the thermal conductivity C5 of the cover layer 240. This is because more heat is received by the heated pad 250 than is released from the cover layer 240. Thus, the laminated body 210 is easily and efficiently heated by the heat received by the heat receiving pad 250.

The heat receiving pad 250 is attached to the cover layer 240, more specifically, to the lower surface of the cover layer 240 (the surface on which the positive electrode terminal 220 and the negative electrode terminal 230 are bent). The heat receiving pad 250 is embedded in the cover layer 240 so as to be partially exposed, and is separated from the stacked body 210 via the cover layer 240. Thus, the exposed portion of the heat receiving pad 250 has an exposed surface (heat receiving surface) 250M along the XY plane, and the heat receiving surface 250M has an area S.

The material for forming the heat receiving pad 250 is not particularly limited as long as it has thermal conductivity (the thermal conductivity C described above). Therefore, the heat receiving pad 250 may have conductivity and may have insulation.

When the heat receiving pad 250 has conductivity, the positive electrode terminal 220, the negative electrode terminal 230, and the heat receiving pad 250 may be collectively formed using a conductive frame 700 in a manufacturing process of the solid-state battery 200, as will be described later. In this case, since the conductive heat receiving pad 250 is separated from the laminated body 210 via the insulating cover layer 240, even if the heat receiving pad 250 has conductivity, the laminated body 210 is not easily affected by the heat receiving pad 250.

When the heat receiving pad 250 has insulation, the heat receiving pad 250 is electrically separated from the positive terminal 220 and the negative terminal 230, respectively. Therefore, accidental short-circuiting of the solid-state battery 200 due to the presence of the heated pad 250 is less likely to occur.

The conductive heat receiving pad 250 includes, for example, conductive materials such as copper, aluminum, and various alloys. The type of alloy is not particularly limited, and examples thereof include a nickel-iron alloy (42 alloy). Among them, the conductive material is preferably a low thermal expansion alloy such as a nickel-iron alloy (42 alloy). This is because the thermal expansion coefficient of the low thermal expansion alloy is as low as that of the ceramic, and therefore the heat receiving pad 250 is less likely to thermally expand.

Note that the solder wettability of the conductive heated pad 250 is preferably high. This is because, when the heat receiving pad 250 is connected to the heat transfer wire 500 by solder, the surface of the heat receiving pad 250 and the surface of the heat transfer wire 500 are covered with solder without a gap therebetween. Thus, the heat receiving pad 250 and the heat transmission line 500 are easily brought into close contact with each other, and therefore, the heat receiving pad 250 is easily and efficiently receives heat via the heat transmission line 500.

The solder wettability can be determined by a method prescribed in JIS J8615, JIS H8618, ISO 2093, and the like, for example. With regard to the solder wettability described here, the high solder wettability means that the heat receiving surface 250M of the heat receiving pad 250 is determined to be "wettable" based on the criterion in the above-described determination method. Specifically, when the heat receiving surface 250M of the heat receiving pad 250 is immersed in a solder bath (at a temperature of 250 ℃ ± 5 ℃) for 3 seconds, the solder is uniformly attached to the heat receiving surface 250M, and it is determined that "wettability" is present.

Note that, when the determination is "non-wettability" based on the determination criterion in the above-described determination method, for example, a series of cases described below is employed. First, projections, black spots, and the like appear on the heat receiving surface 250M to which the solder is attached. Second, the solder in the form of a scale is scattered and peeled off in the bending test performed by the heat receiving pad 250. Third, the solder is not attached to the heat receiving surface 250M, and the heat receiving surface 250M is exposed.

The insulating heat receiving pad 250 includes an insulating material such as alumina (alumina), aluminum nitride, silicon carbide, or mica. The thermal expansion coefficient of the insulating material is preferably sufficiently low as that of the conductive material.

Here, for example, as described above, heat is transmitted from the heater 300 to the heat receiving pad 250 via the two heat transmission lines 500 (the positive heat transmission line 501 and the negative heat transmission line 502). In this case, the solid-state battery 200 is provided with, for example, two heat receiving pads 250(251, 252). The heated pad 251 has a thermal conductivity C (C1), while the heated pad 252 has a thermal conductivity C (C2). Thus, the thermal conductivity C1 of the heated pad 251 is higher than the thermal conductivity C5 of the cover layer 240. In addition, the thermal conductivity C2 of the heated pad 252 is higher than the thermal conductivity C5 of the cover layer 240.

The

heat receiving pads

251 and 252 are separated from each other, for example, in the X-axis direction and extend in the same direction as the extending direction (Y-axis direction) of each of the positive and negative

heat transfer lines

501 and 502. The width W (dimension in the X-axis direction) and the length L (dimension in the Y-axis direction) of each of the

heat receiving pads

251 and 252 are not particularly limited, and can be set arbitrarily.

The heat receiving pad 251 is disposed at a position corresponding to the positive electrode heat transfer line 501, for example, and is connected to the positive electrode heat transfer line 501. The heat receiving pad 252 is disposed at a position corresponding to the negative electrode heat radiation line 502, for example, and is connected to the negative electrode heat radiation line 502. Thereby, heat generated in the heater 300 is transferred to the heat receiving pad 251 via the positive heat transfer line 501, and is transferred to the heat receiving pad 252 via the negative heat transfer line 502.

Note that, as described above, the heat receiving pad 251 is partially exposed from the cover layer 240, and therefore, the exposed portion of the heat receiving pad 251 has the heat receiving surface 251M along the XY plane. The heat receiving surface 251M is a connection surface connected to the positive electrode heat transfer wire 501, and has an area S1.

As described above, the heat receiving pad 252 is partially exposed from the cover layer 240, and thus, the exposed portion of the heat receiving pad 252 has the heat receiving surface 252M along the XY plane. The heat receiving surface 252M is a connection surface connected to the negative electrode heat transfer line 502, and has an area S2.

Here, in order to easily heat the stacked body 210 by heat transmitted from the heater 300 to the heat receiving pad 250(251, 252) through the heat transmission line 500 (the positive heat transmission line 501 and the negative heat transmission line 502), the physical properties of the heat receiving pad 250 preferably satisfy the following conditions.

The thermal conductivity C1 of the first, heated pad 251 is, for example, at least the thermal conductivity C3 of the positive electrode terminal 220 and at least the thermal conductivity C4 of the negative electrode terminal 230. Similarly, the thermal conductivity C2 of the heated pad 252 is, for example, at least the thermal conductivity C3 of the positive electrode terminal 220 and at least the thermal conductivity C4 of the negative electrode terminal 230. This is because the heat received by each of the

heat receiving pads

251, 252 is ensured. This makes it easy to efficiently heat the stacked body 210 with the heat received by the

heat receiving pads

251 and 252.

Among them, the thermal conductivity C1 is preferably higher than the thermal conductivity C3, and preferably higher than the thermal conductivity C4. Likewise, the thermal conductivity C2 is preferably higher than the thermal conductivity C3 and higher than the thermal conductivity C4. This is because the heat received by each of the

heat receiving pads

251, 252 is greater than the heat released from each of the positive terminal 220 and the negative terminal 230. This makes it easy to heat the stacked body 210 more efficiently by the heat received by the

heat receiving pads

251 and 252.

Second, the area S of the heat receiving surface 250M of the heat receiving pad 250, i.e., the sum of the area S1 of the heat receiving surface 251M of the heat receiving pad 251 and the area S of the heat receiving surface 252M of the heat receiving pad 252 (S1 + S2), for example, is larger than the sum of the area S3 of the positive electrode terminal surface 220M of the positive electrode terminal 220 and the area S4 of the negative electrode terminal surface 230M of the negative electrode terminal 230 (S3 + S4). This is because the area (heat receiving area) in which heat is received by each of the

heat receiving pads

251 and 252 is larger than the area (heat radiation area) in which heat is radiated from each of the positive electrode terminal 220 and the negative electrode terminal 230. This makes it easy to efficiently heat the stacked body 210 with the heat received by the

heat receiving pads

251 and 252.

Note that the three-dimensional shapes of the

heat receiving pads

251 and 252 are not particularly limited. Here, for example, as shown in fig. 4, the heat receiving pad 251 extends in the X-axis direction, and one end portion and the other end portion of the heat receiving pad 251 in the X-axis direction are bent toward the stacked body 210. The three-dimensional shape of the heat receiving pad 252 is, for example, the same as the three-dimensional shape of the heat receiving pad 251 described above.

However, one end portion and the other end portion of the heat receiving pad 251 may not be bent toward the stacked body 210, for example. That is, the heat receiving pad 251 may extend in the X-axis direction in an unfolded manner, for example. The same applies to the heat receiving pad 252, for example.

Note that it is preferable that the thermally conductive paste exists between the heated pad 250(251, 252) and the heat transfer wire 500. This is because the heated pad 250 and the heat transfer wire 500 are closely attached to each other without a gap by the thermally conductive paste. Accordingly, the heat conduction state between the heat receiving pad 250 and the heat transfer wire 500 is not easily hindered by the air mixing or the like, and therefore, the heat receiving pad 250 easily receives heat by the heat transfer wire 500.

When the conductive heat receiving pad 250 is used, for example, one or two or more of solder, metal paste, and the like can be used as the heat conductive paste. When the insulating heat receiving pad 250 is used, for example, silicon oil including particles of alumina, aluminum nitride, silicon carbide, mica, or the like can be used as the heat conductive paste.

<1-3. Block Structure >

Fig. 5 illustrates a block structure of the battery module shown in fig. 1. Fig. 5 also shows a part of the components of the battery module described above.

For example, as shown in fig. 5, the battery module includes a control unit 601, a power supply 602, a voltage/current adjustment unit 603, a switch 604, and a temperature measurement element 605 in addition to the solid-state battery 200, the heater 300, the wiring 400 (the positive electrode wiring 401 and the negative electrode wiring 402), and the heat transfer wire 500 (the positive electrode heat transfer wire 501 and the negative electrode heat transfer wire 502).

The power supply 602 is connected to the solid-state battery 200 through, for example, a voltage/current adjustment unit 603, and is connected to the heater 300 through a switch 604. The solid-state battery 200 is connected to the controller 601 via, for example, a temperature measuring element 605.

[ control section ]

The control unit 601 controls the operation of the entire battery module. The control unit 501 is an integrated circuit including electronic components such as a Central Processing Unit (CPU), a memory, an input/output port, and a timer. Specifically, the controller 601 controls the charging operation of the solid-state battery 200 by the voltage/current adjuster 603, and switches the operation of the heater 300 by the switch 604.

[ Power supply ]

The power supply 602 is used to charge the solid-state battery 200 and to operate (generate heat) the heater 300. The power supply 602 includes a constant voltage power supply such as an AC adapter.

[ Voltage/Current adjustment section ]

The voltage/current adjustment unit 603 controls the charging operation of the solid-state battery 200, and particularly controls the constant-current charging operation (CC) and the constant-voltage charging operation (CV). The voltage/current adjustment unit 603 is, for example, an integrated circuit for controlling CC/CV charging.

Note that, in fig. 5, the control section 601 and the voltage/current adjustment section 603 are separated from each other, but for example, the control section 601 and the voltage/current adjustment section 603 may be integrated with each other. That is, for example, the control section 601 may also function as the voltage/current adjustment section 603 without using the voltage/current adjustment section 603.

[ switch ]

The switch 604 switches the operation (on/off) of the heater 300. The switch 604 includes a switching element such as a Field Effect Transistor (FET), for example.

[ temperature measuring element ]

The temperature measuring element 605 measures the temperature T of the solid-state battery 200, and outputs the measurement result of the temperature T to the control unit 601. The temperature measuring element 605 includes, for example, a temperature sensor such as a thermistor. The location where the temperature measuring element 60 is provided is not particularly limited as long as it can measure the temperature T of the solid-state battery 200. Here, the temperature measuring element 605 is provided, for example, on the lower surface (the surface on the side where the heat receiving pad 250 is arranged) of the solid-state battery 200 in a region where the heat receiving pad 250 does not exist.

<1-4. actions (method for charging solid State Battery) >

Fig. 6 shows a flow related to the operation of the battery module shown in fig. 1 to 5. Here, the operation of charging the solid-state battery 200 will be described by describing the flow of the operation of the control unit 601 that controls the operation of the entire battery module. The step numbers in parentheses described below correspond to the step numbers shown in fig. 6.

Note that the method of charging the solid-state battery according to the embodiment of the present technology is realized by the operation of the battery module described here, and therefore, the method of charging the solid-state battery will be collectively described below.

In the battery module before the series of operations described below (initial state), for example, the solid-state battery 200 is not yet heated by the heater 300, and therefore the temperature T of the solid-state battery 200 is lower than the target temperature TA.

In this battery module, first, the switch 604 is connected, and the power supply 602 and the heater 600 are connected to each other via the switch 604. Thereby, the heater 300 is operated by the power supply 602 (step S11), and the solid-state battery 200 is heated by the heater 300 (step S12). In this case, when the heater 300 operates, the heater 300 generates heat. Thus, the heat generated in the heater 300 is transmitted to the heat receiving pads 250(251, 252) via the heat transmission line 500 (the positive electrode heat transmission line 501 and the negative electrode heat transmission line 502), and the stacked body 210 is heated by the

heat receiving pads

251, 252.

Then, after the heater 300 is operated, the temperature T of the solid-state battery 200 is measured by the temperature measuring element 605 (step S13). In this case, the temperature T is measured at predetermined intervals, for example, by a timer.

Then, based on the measurement result of the temperature T, it is determined whether the temperature T reaches the target temperature TA (step S14). The target temperature TA is stored in the memory, for example.

When the temperature T has not reached the target temperature TA (no in step S14), it is determined that the temperature T has not increased to such an extent that the charging of the solid-state battery 200 can be started, and the operation returns to the operation of measuring the temperature T (step S13). In this case, after the temperature T is measured again at the next measurement timing (step S13), the temperature T is determined again (step S14). Thus, the operation of measuring the temperature T (step S13) and the operation of determining the temperature T (step S14) are repeated until the temperature T reaches the target temperature TA.

On the other hand, when the temperature T reaches the target temperature TA (yes in step S14), it is determined that the temperature T has increased to such an extent that the charging of the solid-state battery 200 can be started, and the charging of the solid-state battery 200 is started by the power supply 602 and the voltage/current adjustment unit 603 (step S15). In this case, for example, the solid-state battery 200 is charged at a constant current (constant current charging) until the voltage reaches a predetermined value (upper limit voltage), and then the solid-state battery 200 is charged at the voltage (constant voltage charging) until the current reaches a predetermined value (lower limit current). In the charging process of the solid-state battery 200, lithium is released from the positive electrode layer 211, and the lithium is inserted into the negative electrode layer 212 through the solid electrolyte layer 213.

Here, the target temperature TA is a temperature at which the time required for charging the solid-state battery 200 can be shortened as compared with the time required for charging the solid-state battery 200 at normal temperature (23 ℃), and is a temperature higher than the normal temperature. The specific target temperature TA is not particularly limited as long as it is a temperature at which the solid-state battery 200 needs to be heated, and is, for example, 40 ℃. However, if the temperature of the solid-state battery 200 is too high, the characteristics and the like of the solid electrolyte layer 213 may be degraded, and therefore, the target temperature TA is preferably 60 ℃.

Then, it is determined whether the charging of the solid-state battery 200 is completed (step S16). In this case, for example, the determination operation of the completion of charging is repeated at predetermined time intervals by a timer.

Here, for example, the voltage/current adjustment unit 603 measures the current during constant voltage charging, and checks whether or not the current reaches the lower limit current, thereby determining whether or not charging is completed. Specifically, when the current at the time of constant voltage charging has not reached the lower limit current, it is determined that the charging of the solid-state battery 200 is not completed, and when the current at the time of constant voltage charging has reached the lower limit current, it is determined that the charging of the solid-state battery 200 has been completed.

When the charging of the solid-state battery 200 is not completed (no in step S16), the determination of completion of charging is performed again at the next determination timing (step S16). On the other hand, when the charging of the solid-state battery 200 is completed (yes in step S16), the charging of the solid-state battery 200 is ended by the voltage current adjustment part 603 (step S17).

Finally, the switch 604 is cut, thereby separating the power supply 602 and the heater 300 from each other through the switch 604. Thereby, the heater 300 is stopped (step S18). In this case, the heating of the stacked body 210 using the

heat receiving pads

251 and 252 is completed because the heat generation of the heater 300 is stopped.

Thereby, the solid-state battery 200 is charged (constant-voltage constant-current charging), and the charging operation of the solid-state battery 200 is completed.

<1-5 > production method >

Fig. 7A to 11A show planar configurations corresponding to fig. 2, respectively, for explaining the manufacturing process of the battery module shown in fig. 1 to 4. Fig. 7B to 11B show cross-sectional configurations corresponding to fig. 4, respectively, for explaining the manufacturing process of the battery module shown in fig. 1 to 4.

That is, a cross section along 7A-7A shown in FIG. 7A, a cross section along 8A-8A shown in FIG. 8B, a cross section along 9A-9A shown in FIG. 9A, a cross section along 10A-10A shown in FIG. 10B, and a cross section along 11A-11A shown in FIG. 11A are shown in FIG. 7B, respectively.

[ method for producing solid-State Battery ]

Next, a method for manufacturing the solid-state electric element 200, which is a main part of the battery module shown in fig. 1 to 4, will be described. In fig. 9B to 11B, the cross-sectional structure of the laminate 210 is illustrated to simplify the illustration.

To manufacture the solid-state battery 200, first, as shown in fig. 7A and 7B, a frame 700 is prepared. The frame 700 is a support for manufacturing a battery module, and is a precursor that ultimately becomes a part of the battery module (the positive electrode terminal 220, the negative electrode terminal 230, and the heat receiving pad 250). In fig. 7A and fig. 8A to 10A described later, a frame 700 is hatched.

Specifically, the frame 700 is a plate-shaped member having, for example, three openings 700K1, 700K2, and 700K3, and includes a frame portion 710, a pair of protruding

portions

720 and 730, and a pair of crossing

portions

740 and 750.

The frame 710 is a support frame that supports the pair of protruding

portions

720 and 730 and the pair of crossing

portions

740 and 750.

The pair of protruding

portions

720 and 730 are separated from each other in the X-axis direction by a pair of crossing

portions

740 and 750. The protruding portion 720 is connected to the frame portion 710 on one side (right side) in the X axis direction, for example, and protrudes inward from the frame portion 710. The protruding portion 730 is coupled to the frame portion 710 on the other side (left side) in the X axis direction, for example, and protrudes inward from the frame portion 710. Therefore, the protruding

portions

720 and 730 extend in the X-axis direction, for example, and protrude in the direction of approaching each other.

The protruding portion 720 includes, for example, a bent portion 720P bent in a subsequent step as a leading end portion in the protruding direction. Similarly, the protruding portion 730 includes, for example, a bent portion 730P bent in a subsequent step as a leading end portion in the protruding direction. In fig. 7A, broken lines are indicated at positions where the protruding

portions

720 and 730 are bent in the subsequent process.

The pair of crossing

portions

740 and 750 are separated from each other in the X-axis direction. The crossing portion 740 is disposed closer to the protrusion 730 than to the protrusion 720, for example, and the crossing portion 750 is disposed closer to the protrusion 720 than to the protrusion 730, for example. For example, the crossing portion 740 is connected to the frame portion 710 at one end side (upper side) in the Y axis direction, and is connected to the frame portion 710 at the other end side (lower side) in the Y axis direction. For example, one end side of the crossing portion 750 in the Y axis direction is connected to the frame portion 710, and the other end side thereof in the Y axis direction is connected to the frame portion 710. Therefore, the crossing

portions

740 and 750 extend in the Y-axis direction, respectively, for example.

The crossing portion 740 includes, for example, a pair of bent portions 740P bent in a subsequent step as a pair of protruding portions protruding toward both sides (X-axis direction) at a central portion in the extending direction (Y-axis direction). Similarly, the crossing portion 750 includes, for example, a pair of bent portions 750P bent in a subsequent step as a pair of protruding portions protruding toward both sides (X-axis direction) at a central portion in the extending direction (Y-axis direction). In fig. 7A, the positions where the crossing

portions

740 and 750 are bent in the subsequent process are indicated by broken lines.

Thus, the opening 700K1 is surrounded by the frame 710, the protruding portion 720, and the crossing portion 750, for example. The opening 700K2 is surrounded by the frame 710, the protruding portion 730, and the crossing portion 740, for example. The opening 700K3 is surrounded by the frame 710 and the crossing

portions

740 and 750, for example.

Note that the frame 700 includes, for example, the same material as the formation material of the heated pads 250(251, 252). Here, the frame 700 includes, for example, a nickel-iron alloy (42 alloy), and thus has conductivity. The solid-state battery 200 is manufactured by using the frame 700 so that the positive electrode terminal 220, the negative electrode terminal 230, and the heat receiving pad 250(251, 252) are formed of a common material, respectively, as described later.

Then, as shown in fig. 8A and 8B, the

projections

720 and 730 and the crossing

portions

740 and 750 are partially bent in a common direction.

Specifically, bent portion 720P of protruding portion 720 is bent to the near side, and bent portion 730P of protruding portion 730 is bent to the near side. Further, a pair of bent portions 740P of transverse portion 740 are bent toward the near side, respectively, and a pair of bent portions 750P of transverse portion 750 are bent toward the near side, respectively. The near side is a side located further forward than the paper surface of fig. 8A, and is an upper side in fig. 8B. Note that in fig. 8A, the thicknesses of the protruding portions 720 and 730 (

bent portions

720P and 730P) and the crossing portions 740 and 750 (

bent portions

740P and 750P) are not shown.

Then, as shown in fig. 9A and 9B, a laminated body 210 is formed above the frame 700, more specifically, on the side where the protruding

portions

720 and 730 and the crossing

portions

740 and 750 are bent, respectively.

Here, a detailed description of the manufacturing process of the laminate 210 is omitted, and when the laminate 210 is formed, for example, as shown in fig. 4, the positive electrode layer 211 and the positive electrode separator 214 are alternately laminated with the negative electrode layer 212 and the negative electrode separator 215 via the solid electrolyte layer 213. In this case, for example, a so-called green sheet method is employed.

In particular, when the stacked body 210 is formed, the stacked body 210 is disposed between the protruding portions 720 and 730 (the

bent portions

720P and 730P), and the stacked body 210 is connected to the

bent portions

720P and 730P, respectively. More specifically, the positive electrode layer 211 is connected to the bent portion 720P and separated from the bent portion 730P via the positive electrode separation layer 214. The negative electrode layer 212 is connected to the bent portion 730P, and is separated from the bent portion 720P via the negative electrode separation layer 215.

When the laminate 210 is formed, the laminate 210 is disposed above each of the crossing

portions

740 and 750, and the laminate 210 is separated from the crossing

portions

740 and 750.

Then, as shown in fig. 10A and 10B, a cover layer 240 is formed so as to cover the periphery of the stacked body 210. In forming the cover layer 240, for example, a solution in which a material (insulating polymer material) for forming the cover layer 240 is dissolved in an organic solvent is supplied to the periphery of the laminate 210, and then the solution is dried. In this case, the solution may be applied to the laminate 210, or the laminate 210 may be immersed in the solution.

In particular, when the cover layer 240 is formed, the

projections

720 and 730 are partially led out from the inside of the cover layer 240 to the outside, and the crossing

portions

740 and 750 are separated from the laminate 210 with a part of the cover layer 240 interposed therebetween.

Note that a cutting line CL indicated by a one-dot chain line in fig. 10A shows a position where the frame 700 is cut in a subsequent process.

Finally, after the frame 700 is cut along the cutting line CL shown in fig. 10A, the frame 700 is removed. Thereby, as shown in fig. 11A and 11B, the solid-state battery 200 is completed. The detailed structure of the solid-state battery 200 is shown in fig. 1 to 4.

In this case, as can be seen from fig. 10A, 10B, 11A, and 11B, the positive electrode terminal 220 is formed by the cut protruding portion 720, and the negative electrode terminal 230 is formed by the cut protruding portion 730. Further, the heated pad 251 is formed by the cut across portion 740, and the heated pad 252 is formed by the cut across portion 750. Thereby, the positive electrode terminal 220, the negative electrode terminal 230, and the heat receiving pad 250(251, 252) are formed together.

[ method for producing Battery Module ]

Note that, when manufacturing a battery module, for example, as shown in fig. 1, the solid-state battery 200, the heater 300, the wiring 400 (the positive electrode wiring 401 and the negative electrode wiring 402), and the heat transmission line 500 (the positive electrode heat transmission line 501 and the negative electrode heat transmission line 502) are mounted on the surface of the base 100 by a conventional surface mounting technique.

<1-6 > Effect and Effect

According to this battery module, the solid-state battery 200 and the heater 300 are disposed on the base 100, and the solid-state battery 200 and the heater 300 are thermally connected to each other by the heat radiation wire 500 (the positive heat radiation wire 501 and the negative heat radiation wire 502). In the solid-state battery 200, the insulating cover layer 240 covers the stacked body 210 so that the positive electrode terminal 220 and the negative electrode terminal 230 are led out, respectively, and the heat receiving pads 250(251, 252) are attached to the cover layer 240 so as to be electrically separated from the positive electrode terminal 220 and the negative electrode terminal 230, respectively. The thermal conductivity C (C1, C2) of the heated pad 250 is higher than the thermal conductivity C5 of the cover layer 240.

In this case, heat generated in the heater 300 is transferred to the heat receiving pad 250 through the heat transfer line 500, and thus the stacked body 210 is heated by the heat transferred to the heat receiving pad 250. As a result, the solid-state battery 200 is charged in a state where the stacked body 210 is heated, and therefore, the solid-state battery 200 is charged in a shorter time than when the solid-state battery 200 is charged in a state where the stacked body 210 is not heated.

In particular, when the stacked body 210 is heated by the heat receiving pad 250, the heat conductivity C of the heat receiving pad 250 is higher than the heat conductivity C5 of the cover layer 240, and therefore, more heat is received by the heat receiving pad 250 attached to the cover layer 240 than is released from the cover layer 240 of the stacked body 210. Thereby, the stacked body 210 is easily heated efficiently, and therefore, the solid-state battery 200 can be charged in a shorter time.

Further, by providing the heater 300 as a heat source separately from the solid-state battery 200, the stacked body 210 can be heated by the heat receiving pad 250 having a simple configuration only by introducing the heat receiving pad 250 into the solid-state battery 200. In this case, since it is not necessary to introduce a complicated heat source into the solid-state battery 200 and to introduce a complicated heat transfer mechanism for thermally connecting the heat source to the solid-state battery 200, the solid-state battery 200 having the heating mechanism of the stacked body 210 can be easily constructed.

Further, since the solid-state battery 200, the heater 300, and the heat transmission wire 500 are easily attached to the base 100 by using the surface mounting technique, the heating mechanism of the solid-state battery 200 using the heater 300 and the heat transmission wire 500 is easily constructed.

Therefore, the solid-state battery 200 can be charged in a short time by simply changing the configuration of the solid-state battery 200 and introducing the heat receiving pad 250, and therefore, the charging characteristics of the battery module can be easily improved. In this case, the solid-state battery 200 can be charged in a short time by a simple configuration change, and therefore, the time required for charging the solid-state battery 200 can be reduced at low cost.

In particular, if the thermal conductivity C1 of the heat receiving pad 251 is greater than or equal to the thermal conductivity C3 of the positive terminal 220 and greater than or equal to the thermal conductivity C4 of the negative terminal 230, the heat received by the heat receiving pad 251 will be ensured. Therefore, the stacked body 210 is easily heated efficiently, and a higher effect can be obtained. The same effect and effect can be obtained when the thermal conductivity C2 of the heat receiving pad 252 is equal to or higher than the thermal conductivity C3 of the positive electrode terminal 220 and equal to or higher than the thermal conductivity C4 of the negative electrode terminal 230.

Further, if the area S of the heat receiving surface 250M, i.e., the sum of the area S1 of the heat receiving surface 251M and the area S2 of the heat receiving surface 252M (S1 + S2) is greater than the sum of the area S3 of the positive terminal surface 220M and the area S4 of the negative terminal surface 230M (S3 + S4), the heat receiving area of the

heat receiving pads

251, 252 is greater than the heat dissipation area of the positive terminal 220 and the negative terminal 230. Therefore, the stacked body 210 is easily heated efficiently, and therefore, higher effects can be obtained.

In addition, if the heat receiving pad 250 has insulation, the heat receiving pad 250 is electrically separated from each of the positive and

negative terminals

220 and 230. Therefore, unexpected short-circuiting of the solid-state battery 200 is less likely to occur, and higher effects can be obtained.

Further, if the heat receiving pad 250 has conductivity, the heat receiving pad 250 is electrically separated from the laminate 210 via the insulating cover layer 240. Therefore, the stacked body 210 is less susceptible to electrical influence, and higher effects can be obtained. In this case, in particular, in the manufacturing process of the solid-state battery 200, the positive electrode terminal 220, the negative electrode terminal 230, and the heat receiving pad 250 are collectively formed using the conductive frame 700, and therefore, the solid-state battery 200 can be easily manufactured.

Further, if the heater 300 includes a chip resistor or the like, the heater 300 can be easily mounted to the base 100, and the heater 300 can sufficiently heat the solid-state battery 200, so that a higher effect can be obtained.

Further, if the heat transfer wire 500 is an electric wiring for conducting electricity to the heater 300, it is not necessary to provide an electric wiring for conducting electricity separately from the heat transfer wire 500, and the heat transfer wire 500 can be easily attached to the base 100 together with the solid-state battery 200 and the heater 300. Therefore, the heat transfer wire 500 functioning as a heat transfer path and a conductive path is easily introduced into the battery module, and the structure of the battery module is further simplified, so that a higher effect can be obtained. In this case, in particular, as described above, the solid-state battery 200, the heater 300, and the heat conductive wire 500 can be mounted on the base body 100 by the surface mounting technique, and therefore, the battery module can be manufactured at low cost.

In the solid-state battery 200 mounted on the battery module, the insulating cover layer 240 covers the stacked body 210 so that the positive electrode terminal 220 and the negative electrode terminal 230 are led out, and the heat receiving pad 250 is attached to the cover layer 240 so as to be electrically separated from each of the positive electrode terminal 220 and the negative electrode terminal 230, and the thermal conductivity C of the heat receiving pad 250 is higher than the thermal conductivity C5 of the cover layer 240. In this case, for the reasons described above with respect to the battery module, the charging time of the solid-state battery 200 can be shortened only by a simple configuration change of introducing the heat receiving pad 250. Therefore, the charging characteristics of the battery module using the solid-state battery 200 can be easily improved. The operations and effects related to the solid-state battery 200 other than this are the same as those related to the battery module.

Further, according to the charging method of the solid-state battery 200, the solid-state battery 200 is heated, and the temperature T of the solid-state battery 200 is measured, after which the charging of the solid-state battery 200 is started when the temperature T reaches the target temperature TA. In this case, as described above, the solid-state battery 200 is charged in a state where the stacked body 210 is heated, and therefore, the solid-state battery 200 is charged in a short time. Therefore, the charging characteristics of the battery module using the solid-state battery 200 can be easily improved.

<2. modification >

The structure of the battery module (solid-state battery 200) can be appropriately modified. Note that any two or more of the configuration and operation of the battery module (solid-state battery 200) described above and the series of configurations (modifications) of the battery module (solid-state battery 200) described below may be combined with each other.

[ modification 1]

In fig. 1 to 4, the secondary battery includes two heat receiving pads 250(251, 252), but the number of the heat receiving pads 250 is not particularly limited. Therefore, the secondary battery may be provided with only one heat receiving pad 250, or may be provided with three or more heat receiving pads 250.

When the secondary battery includes one heat receiving pad 250, for example, the heat receiving pad 250 may be connected to one of the positive electrode heat transfer line 501 and the negative electrode heat transfer line 502. When the secondary battery includes three or more heat receiving pads 250, two of the three or more heat receiving pads 250 may be connected to the positive electrode heat transfer wire 501 and the negative electrode heat transfer wire 502, and an additional heat transfer wire may be additionally provided to connect the remaining one or more heat receiving pads 250 to the heater 300. The additional heat transfer wire has the same configuration as the positive electrode heat transfer wire 501 and the negative electrode heat transfer wire 502, for example.

In these cases, too, the same effect can be obtained because the stacked body 210 is heated by one or three or more heat receiving pads 250.

[ modification 2]

In fig. 4, the heated pad 250 is separated from the stack 210 by the cover layer 240. However, for example, as shown in fig. 12 corresponding to fig. 4, if the heat receiving pad 250 has an insulating property, the heat receiving pad 250 may be adjacent to the laminated body 210.

In this case, the same effect can be obtained because the laminated body 210 is also heated by the heat receiving pad 250. In this case, in particular, since the heat receiving pad 250 is close to the laminated body 210, heat is easily transferred from the heat receiving pad 250 to the laminated body 210. Therefore, the stacked body 210 is easily heated by the heat receiving pad 250.

[ modification 3]

In fig. 5 and 6, the battery module includes a temperature measuring device 605, and the charging of the solid-state battery 200 is started when the temperature T of the solid-state battery 200 reaches a target temperature TA based on the measurement result of the temperature T of the solid-state battery 200 measured by the temperature measuring device 605.

However, the logic for determining whether or not the solid-state battery 200 has reached the desired heating state if the solid-state battery 200 is started to be charged when the solid-state battery 200 has been heated to reach the desired heating state is not particularly limited.

Specifically, for example, as shown in fig. 13 corresponding to fig. 6, the charging of the solid-state battery 200 may be started based on the measurement result of the heating time P of the solid-state battery 200 measured by the timer. In this case, for example, the battery module may not include the temperature measuring element 605.

The specific operation of the battery module is as described below. However, in the following description, the description will be simplified with respect to the description of the same action as that already described in fig. 6. The step numbers in parentheses described below correspond to the step numbers shown in fig. 13.

In this battery module, first, the heater 300 is operated (step S21) to heat the solid-state battery 200 (step S22). Then, the heating time (elapsed time after the start of heating) P of the solid-state battery 200 is measured by a timer (step S23). Then, it is determined whether or not the heating time P reaches the target heating time PA based on the measurement result of the heating time P (step S24). The target heating time PA is stored in the memory, for example.

When the heating time P has not reached the target heating time PA (no in step S24), it is determined that the heating time has not elapsed to such an extent that the charging of the solid-state battery 200 can be started, and the operation returns to the measurement operation of the heating time P (step S23). In this case, the heating time P is measured again at the next measurement timing (step S23), and the measurement operation of the heating time P (step S23) and the determination operation of the heating time P (step S24) are repeated until the heating time P reaches the target heating time PA.

On the other hand, when the heating time P reaches the target heating time PA (yes in step S24), it is determined that the heating time has elapsed to such an extent that the charging of the solid-state battery 200 can be started, and the charging of the solid-state battery 200 is started (step S25).

Here, the target heating time PA is a time for heating the solid-state battery 200 to a temperature that can shorten the time required for charging the solid-state battery 200 compared to when the solid-state battery 200 is charged at normal temperature (23 ℃), and can be set arbitrarily according to conditions such as the heating temperature.

Then, it is determined whether the charging of the solid-state battery 200 is completed (step S26). When the charging of the solid-state battery 200 is not completed (no in step S26), the determination of completion of charging is performed again at the next determination timing (step S26), and when the charging of the solid-state battery 200 is completed (yes in step S26), the charging of the solid-state battery 200 is ended (step S27).

Finally, the heater 300 is stopped (step S28). Thereby, the solid-state battery 200 is charged, and the charging operation of the solid-state battery 200 is completed.

In this case, the solid-state battery 200 is heated, the heating time P of the solid-state battery 200 is measured, and then the charging of the solid-state battery 200 is started when the heating time P reaches the target heating time PA. Therefore, since the solid-state battery 200 is charged in a state where the stacked body 210 is heated, the same effect can be obtained.

[ modification 4]

In fig. 6 and 13, after the solid-state battery 200 is heated by the heater 300, when the temperature T and the heating time P satisfy predetermined conditions, respectively, the charging of the solid-state battery 200 is started. However, for example, as shown in fig. 14 corresponding to fig. 6 and 13, after the charging of the solid-state battery 200 is started, the heater 300 may be used to heat the solid-state battery 200 when the charging rate R of the solid-state battery 200 satisfies a predetermined condition.

The specific operation of the battery module is as described below. However, in the following description, the description will be simplified with respect to the description of the same action as that already described in fig. 6. The step numbers in parentheses described below correspond to the step numbers shown in fig. 14.

In this battery module, first, charging of the solid-state battery 200 is started (step S31). Then, the voltage/current adjustment unit 603 calculates the charging rate R of the solid-state battery 200 (step S32). In this case, the charging rate R is calculated by dividing the integrated current after the start of charging, which is measured by the voltage/current adjustment unit 603, by the capacity of the solid-state battery 200. That is, the charging rate R is calculated based on a calculation formula of charging rate R being the integrated current after the start of charging/the capacity of the solid-state battery 200.

Then, based on the calculation result of the charging rate R, it is determined whether the charging rate R reaches the target charging rate RA (step S33). The target charging rate RA is stored in the memory, for example.

Here, the target charging rate RA is a charging rate at which the charging time of the solid-state battery 200 needs to be shortened compared to when the solid-state battery 200 is charged at normal temperature (23 ℃). Specifically, in the charging process of the solid-state battery 200, generally, when the charging rate is equal to or higher than a certain value, that is, when the late stage of charging is reached, the charging rate tends to be significantly slow. Therefore, even if the solid-state battery 200 is not heated in the entire charging process in order to effectively shorten the charging time of the solid-state battery 200, if the solid-state battery 200 is heated in the later stage of charging in which the charging rate tends to be significantly slow, the time required for charging the solid-state battery 200 can be effectively shortened in the later stage of charging. Therefore, since the charging time is significantly increased in a state where the solid-state battery 200 is not heated, the target charging rate RA is the charging rate in the late charging period in which the charging time needs to be significantly reduced by heating the solid-state battery 200. As described above, the specific target charging rate RA is not particularly limited as long as it is a charging rate in the late stage of charging, and is, for example, 80% or more.

When the charging rate R has not reached the target charging rate RA (no in step S33), it is determined that the charging process has not reached the late stage of charging in which heating of the solid-state battery 200 is required, and the operation returns to the operation of calculating the charging rate R (step S32). In this case, the charging rate R is calculated again at the next calculation timing (step S32), and the calculation operation of the charging rate R (step S32) and the determination operation of the charging rate R (step S33) are repeated until the charging rate R reaches the target charging rate RA.

On the other hand, when the charging rate R reaches the target charging rate RA (yes in step S33), it is determined that the charging process reaches the late stage of charging in which heating of the solid-state battery 200 is necessary. Thereby, the heater 300 is operated (step S34), and the solid-state battery 200 is heated (step S35).

Then, it is determined whether the charging of the solid-state battery 200 is completed (step S36). When the charging of the solid-state battery 200 is not completed (no in step S36), the determination of completion of charging is performed again at the next determination timing (step S36), and when the charging of the solid-state battery 200 is completed (yes in step S36), the charging of the solid-state battery 200 is ended (step S37).

Finally, the heater 300 is stopped (step S38). Thereby, the solid-state battery 200 is charged, and thus the charging operation of the solid-state battery 200 is completed.

In this case, the charging of the solid-state battery 200 is started, the charging rate R of the solid-state battery 200 is calculated, and then the solid-state battery 200 is heated when the charging rate R reaches the target charging rate RA. Therefore, since the solid-state battery 200 is charged in a state where the stacked body 210 is heated, the same effect can be obtained.

As a result, in particular, the laminate 210 is heated only in the later stage of charging in which the charging rate is significantly reduced, and the time for heating the laminate 210 is shortened as compared with the time when the laminate 210 is formed in the entire charging process (fig. 6 and 13). Therefore, deterioration of the stacked body 210 (material for forming each layer such as the solid electrolyte layer 213) due to heating is suppressed, and the amount of energy consumption required for the heating operation of the heater 300 is reduced, whereby higher effects can be obtained. In particular, since the deterioration of the laminate 210 is suppressed, the charging speed is also suppressed from being lowered due to the deterioration of the laminate 210.

[ modification 5]

For example, as shown in fig. 15 corresponding to fig. 14, after the charging of the solid-state battery 200 is started, the solid-state battery 200 may be heated by the heater 300 when the voltage V of the solid-state battery 200 satisfies a predetermined condition.

The specific operation of the battery module is as described below. However, in the following description, the description will be simplified with respect to the description of the same action as that already described in fig. 6. The step numbers in parentheses described below correspond to the step numbers shown in fig. 15.

In this battery module, first, charging of the solid-state battery 200 is started (step S41). Then, the voltage V of the solid-state battery 200 is measured by the voltage current adjustment unit 603 (step S42).

Then, based on the measurement result of the voltage V, it is determined whether the voltage V reaches the target voltage VA (step S43). The target voltage VA is a voltage corresponding to the target charging rate RA (see fig. 14), that is, a voltage at the late stage of charging, and is stored in the memory, for example. The specific target voltage VA is not particularly limited as long as it is a voltage at the late stage of charging. For example, if the positive electrode active material is lithium cobaltate (LiCoO) in terms of the amount of the positive electrode active material₂) On the other hand, when the negative electrode active material is graphite, the target voltage VA is, for example, 4.1V or more.

When the voltage V does not reach the target voltage VA (no in step S43), it is determined that the charging process has not reached the late stage of charging in which heating of the solid-state battery 200 is required, and the operation returns to the operation of measuring the voltage V (step S42). In this case, the voltage V is calculated again at the next measurement timing (step S42), and the calculation operation of the voltage V (step S42) and the determination operation of the voltage V (step S43) are repeated until the voltage V reaches the target voltage VA.

On the other hand, when the voltage V reaches the target voltage VA (yes in step S43), it is determined that the charging process has reached the late stage of charging in which heating of the solid-state battery 200 is necessary. Thereby, the heater 300 is operated (step S44), and the solid-state battery 200 is heated (step S45).

Then, it is determined whether the charging of the solid-state battery 200 is completed (step S46). When the charging of the solid-state battery 200 is not completed (no in step S46), the determination of completion of charging is performed again at the next determination timing (step S46), and when the charging of the solid-state battery 200 is completed (yes in step S46), the charging of the solid-state battery 200 is ended (step S47).

Finally, the heater 300 is stopped (step S48). Thereby, the solid-state battery 200 is charged, and thus the charging operation of the solid-state battery 200 is completed.

In this case, the charging of the solid-state battery 200 is started, and the voltage V of the solid-state battery 200 is measured, after which the solid-state battery 200 is heated when the voltage V reaches the target voltage VA. Therefore, the solid-state battery 200 is charged in a state where the stacked body 210 is heated, and the same effect can be obtained.

In this case as well, since the laminated body 210 is heated only in the later stage of charging in which the charging speed is significantly reduced, deterioration of the laminated body 210 due to heating is suppressed and the amount of energy consumed by the heater 300 is reduced, as in the case of determination based on the charging rate R (fig. 14).

[ modification 6]

In fig. 1, the battery module includes one solid-state battery 200 and one heater 300, but the number of the solid-state battery 200 and the number of the heaters 300 are not particularly limited, and may be two or more.

Specifically, for example, as shown in fig. 16 corresponding to fig. 1, the battery module may include two solid-state batteries 200(201, 202). This battery module includes, for example, two solid-

state batteries

201 and 202, and a positive electrode wiring 403 and a negative electrode wiring 404, and has the same configuration as the battery module shown in fig. 1 except that the positive electrode heat transfer wire 501 and the negative electrode heat transfer wire 502 have different extension ranges. In fig. 16, solid-

state batteries

201 and 202 are shaded, respectively.

The solid-

state batteries

201 and 202 are separated from each other, for example, in the Y-axis direction with the heater 300 interposed therebetween. The structures of the solid-

state batteries

201 and 202 are shown in fig. 1 to 4, for example.

In the solid-state battery 201, for example, the positive electrode terminal 220 is connected to a positive electrode wiring 401, and the negative electrode terminal 230 is connected to a negative electrode wiring 402. In the solid-state battery 202, for example, the positive electrode terminal 220 is connected to the positive electrode wiring 403, and the negative electrode terminal 230 is connected to the negative electrode wiring 404. The positive electrode wiring 403 and the negative electrode wiring 404 have the same configuration as the positive electrode wiring 401 and the negative electrode wiring 402, for example.

The positive electrode heat transfer line 501 and the negative electrode heat transfer line 502 extend from the solid-state battery 201 to the solid-state battery 202 via the heater 300. Thus, in the solid-state battery 201, the heat receiving pad 251 is connected to the positive electrode heat transfer wire 501, and the heat receiving pad 252 is connected to the negative electrode heat transfer wire 502. In the solid battery 202, the heat receiving pad 251 is connected to the positive heat transmission line 501, and the heat receiving pad 252 is connected to the negative heat transmission line 502.

In the battery module, when the heater 300 generates heat, the heat generated in the heater 300 is transmitted to the solid-state battery 201 (heat receiving pads 251, 252) through the positive electrode heat transmission line 501 and the negative electrode heat transmission line 502, and is transmitted to the solid-state battery 202 (heat receiving pads 251, 252) through the positive electrode heat transmission line 501 and the negative electrode heat transmission line 502. Thus, in the solid-state battery 201, the stacked body 210 is heated by the

heat receiving pads

251 and 252, and in the solid-state battery 202, the stacked body 210 is also heated by the

heat receiving pads

251 and 252.

In this case, the battery module includes a plurality of solid-state batteries 200 (here, two solid-state batteries 201 and 202), and the heater 300 is thermally connected to the plurality of solid-state batteries 200 via the heat radiation wires 500 (the positive electrode heat radiation wire 501 and the negative electrode heat radiation wire 502). Thereby, the solid-state battery 200 (the stacked body 210) is heated by the heat receiving pad 250, and the same effect can be obtained.

In particular, since one heater 300 is shared by a plurality of solid-state batteries 200, the plurality of solid-state batteries 200 are heated by the one heater 300. Thus, it is not necessary to employ a plurality of heaters 300 in order to heat a plurality of solid batteries 200, thereby reducing the required number of heaters 300. Therefore, the plurality of solid-state batteries 200 can be charged while suppressing the mounting area of the heater 300 and the like on the base 100, and a higher effect can be obtained. In particular, since only one heater 300 is required, the structure of the battery module can be simplified, and an increase in cost can be suppressed.

<3. use of Battery Module (solid Battery) >

The use of the battery module is not particularly limited. Note that, since the solid-state battery 200 is one constituent element of the battery module as described above, the following description will be made together with the application of the solid-state battery 200.

The application of the battery module is not particularly limited as long as the battery module can be used as a machine, equipment, appliance, device, system (an assembly of a plurality of pieces of equipment and the like) or the like such as a power source for driving and a power storage source for storing electric power. The battery module used as a power source may be either a main power source or an auxiliary power source. The main power source is a power source that is preferentially used regardless of the presence of other power sources. The auxiliary power supply may be a power supply used instead of the main power supply, or may be a power supply switched from the main power supply as needed. In the case of using a battery module as the auxiliary power supply, the kind of the main power supply is not limited to the battery module.

The battery module is used, for example, as follows: electronic devices (including portable electronic devices) such as video cameras, digital still cameras, mobile phones, notebook computers, cordless phones, stereo headphones, portable radios, portable televisions, and portable information terminals; portable living appliances such as electric shavers; storage devices such as a standby power supply and a memory card; electric tools such as electric drills and electric saws; a battery pack mounted as a detachable power supply on a notebook computer or the like; medical electronic devices such as pacemakers and hearing aids; electric vehicles such as electric vehicles (including hybrid vehicles); a power storage system such as a household battery system for storing electric power in advance for emergency. Of course, the battery module may be used for other applications than the above-described applications.

The present technology has been described above with reference to one embodiment, but aspects of the present technology are not limited to those described in one embodiment, and various modifications are possible. Specifically, although the solid-state battery using lithium as an electrode reactant has been described, the solid-state battery may be a solid-state battery using an electrode reactant other than lithium.

Note that the effects described in this specification are merely examples, and thus the effects of the present technology are not limited to the effects described in this specification. Therefore, other effects can be obtained also with the present technology.

Claims

1. A solid-state battery is provided with:

a battery element including a positive electrode layer and a negative electrode layer that are alternately laminated with a solid electrolyte layer interposed therebetween;

a positive electrode terminal attached to the battery element so as to be electrically connected to the positive electrode layer and electrically separated from the negative electrode layer;

a negative electrode terminal attached to the battery element so as to be electrically connected to the negative electrode layer and electrically separated from the positive electrode layer;

an insulating covering member that covers the battery element so that the positive electrode terminal and the negative electrode terminal are led out, respectively; and

a heat receiving member mounted to the covering member so as to be electrically separated from the positive electrode terminal and the negative electrode terminal, respectively, and having a thermal conductivity higher than that of the covering member.

2. The solid-state battery according to claim 1,

the heat conductivity of the heat receiving member is equal to or higher than the heat conductivity of the positive electrode terminal and equal to or higher than the heat conductivity of the negative electrode terminal.

3. The solid-state battery according to claim 1 or 2,

the heat receiving unit has a heat receiving surface along a prescribed surface,

the positive terminal has a positive terminal surface along the predetermined surface,

the negative terminal has a negative terminal surface along the predetermined surface,

the area of the heating surface is larger than the sum of the area of the positive terminal surface and the area of the negative terminal surface.

4. The solid-state battery according to any one of claims 1 to 3,

the heat receiving member has an insulating property.

5. The solid-state battery according to any one of claims 1 to 3,

the heat receiving member has conductivity.

6. A battery module is provided with:

a support;

the solid-state battery according to any one of claims 1 to 5, disposed on the support;

a heat source disposed on the support body at a position different from a position at which the solid-state battery is disposed; and

and a heat transfer member disposed on the support body and thermally connecting the solid-state battery and the heat source to each other.

7. The battery module of claim 6,

the heating source includes at least one of a chip resistor and a positive temperature coefficient thermistor.

8. The battery module according to claim 6 or 7,

the heat transfer member is an electric wiring for energizing the heating source.

9. The battery module according to any one of claims 6 to 8,

the battery module is provided with a plurality of the solid-state batteries,

the heating source is thermally connected to the plurality of solid batteries through the heat transfer member.

10. A charging method of a solid-state battery, in which charging method,

the solid-state battery is heated up,

the temperature of the solid-state battery is measured,

and determines whether or not the temperature of the solid-state battery reaches a prescribed temperature,

and charging the solid-state battery when the temperature of the solid-state battery reaches the predetermined temperature.

11. A charging method of a solid-state battery, in which charging method,

the solid-state battery is heated up,

the heating time of the solid-state battery is measured,

and determines whether or not the heating time of the solid-state battery reaches a predetermined heating time,

and charging the solid-state battery when the heating time of the solid-state battery reaches the predetermined heating time.

12. A charging method of a solid-state battery, in which charging method,

the solid-state battery is charged with electricity,

the charging rate of the solid-state battery is calculated,

and determines whether or not the charging rate of the solid-state battery reaches a prescribed charging rate,

heating the solid-state battery when the charging rate of the solid-state battery reaches the predetermined charging rate.

13. A charging method of a solid-state battery, in which charging method,

the solid-state battery is charged with electricity,

the voltage of the solid-state battery is measured,

and determines whether or not the voltage of the solid-state battery reaches a prescribed voltage,

heating the solid-state battery when the voltage of the solid-state battery reaches the predetermined voltage.