CN112111775B - Rapid oxidation treatment system for lead - Google Patents

Rapid oxidation treatment system for lead Download PDF

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Publication number
CN112111775B
CN112111775B CN202010821477.1A CN202010821477A CN112111775B CN 112111775 B CN112111775 B CN 112111775B CN 202010821477 A CN202010821477 A CN 202010821477A CN 112111775 B CN112111775 B CN 112111775B
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insulating
barrel
thick bamboo
insulating inner
post
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CN112111775A (en
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陈圆元
王盛明
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Zhixing Shanghai Hardware Co ltd
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Zhixing Shanghai Hardware Co ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/34Anodisation of metals or alloys not provided for in groups C25D11/04 - C25D11/32
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/82Recycling of waste of electrical or electronic equipment [WEEE]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating Apparatus (AREA)

Abstract

The application relates to a wire rapid oxidation treatment system, which comprises an insulating inner cylinder arranged horizontally, wherein two symmetrical conductive semi-rings which are coaxial with the insulating inner cylinder are fixedly connected to the inner circumferential surface of the insulating inner cylinder, and a gap is formed between the two conductive semi-rings; the two conductive semi-rings are fixedly connected with a plurality of cathode semi-ring plates and anode semi-ring plates on the sides close to each other, two ends of the insulating inner cylinder are connected with insulating taper sleeves coaxial with the insulating inner cylinder, the taper tops of the insulating taper sleeves are arranged towards the sides close to each other, the taper tops of the insulating taper sleeves are fixedly connected with insulating elastic sealing sheets, and elastic holes capable of being enlarged along with elastic deformation of the insulating elastic sealing sheets are formed in the middle of the insulating elastic sealing sheets; the peripheral surface of the insulating inner cylinder is fixedly connected with a liquid inlet pipe. This application has and avoids external foreign matter to fall into the oxidation inslot, guarantees the effect of the oxidation treatment of work piece.

Description

Rapid oxidation treatment system for lead
Technical Field
The application relates to the field of metal material surface treatment, in particular to a wire rapid oxidation treatment system.
Background
The existing wire generally adopts copper or copper alloy as a conducting medium, and for high-power electric equipment, copper and copper alloy wires with long service life and large diameter are required, and in order to improve the corrosion resistance of the copper and copper alloy wires or meet the special decoration requirements of the surfaces of the copper and copper alloy wires, an anodic oxidation treatment process is also required to be carried out on the copper and copper alloy wires, generally, after the anodic oxidation treatment for a long time, the surfaces of the copper and copper alloy can form an oxide or complex compact film layer with colors from dark black to light green and the like.
According to the referenced application publication numbers: CN102254638A, which is a chinese patent of invention, discloses a production system for performing anodic oxidation low-voltage insulation treatment after annealing a copper-clad aluminum wire, comprising a pretreatment tank arranged behind an original production line for pretreating the copper-clad aluminum wire, a reinforced anodic oxidation tank arranged behind the pretreatment tank for oxidizing the surface of the copper-clad aluminum wire, a hot air device arranged behind the reinforced anodic oxidation tank for drying the surface of the copper-clad aluminum wire, a sealing device arranged behind the hot air device for coating an insulating material on the dried copper-clad aluminum wire, a drying device connected to the rear end of the sealing device, and a take-up device arranged behind the drying device for winding and packaging the copper-clad aluminum wire.
In view of the above-mentioned related arts, the inventor believes that there exists a problem that the oxidation tank adopts an open structure during the anodic oxidation process, the workpiece is subjected to immersion oxidation, and external pollutants easily drop into the oxidation tank, which affects the oxidation of the workpiece in the oxidation tank.
Disclosure of Invention
In order to avoid external foreign matter to fall into the oxidation inslot, guarantee the oxidation treatment of work piece, this application provides a quick oxidation treatment system of wire.
The application provides a quick oxidation treatment system of wire adopts following technical scheme:
a wire rapid oxidation treatment system comprises an insulating inner cylinder which is horizontally arranged, wherein the inner peripheral surface of the insulating inner cylinder is fixedly connected with two symmetrically arranged conductive semi-rings which are coaxial with the insulating inner cylinder, and a gap is arranged between the two conductive semi-rings; the two conductive semi-rings are fixedly connected with a plurality of cathode semi-ring plates and anode semi-ring plates on the sides close to each other, two ends of the insulating inner cylinder are connected with insulating taper sleeves coaxial with the insulating inner cylinder, the taper tops of the insulating taper sleeves are arranged towards the sides close to each other, the taper tops of the insulating taper sleeves are fixedly connected with insulating elastic sealing sheets, and elastic holes capable of being enlarged along with elastic deformation of the insulating elastic sealing sheets are formed in the middle of the insulating elastic sealing sheets; the peripheral surface of the insulating inner cylinder is fixedly connected with a liquid inlet pipe.
Through adopting the above technical scheme, during the use, insert the insulating taper sleeve of insulating inner tube one end with the one end of thick copper line, make the tip of thick copper line push open the elasticity hole of insulating elastic sealing piece, and insert to insulating inner tube in, it is ejecting again from the elasticity hole of the elastic sealing piece of another insulating taper sleeve, pour into the insulating inner tube with electrolyte into from the feed liquor pipe this moment, switch on respectively two electrically conductive semi-rings, cooperate electrolyte through positive pole semi-ring board and negative pole semi-ring board interact, can realize the oxidation treatment to thick copper line surface, then slowly drag thick copper line, can realize the continuous oxidation treatment of thick copper line, and because the elastic hole of the insulating elastic sealing piece of adoption can tightly hoop thick copper line, avoid electrolyte to spill, external foreign matter also can't enter in the insulating inner tube, the oxidation quality of thick copper line has been guaranteed.
Preferably, the outside rigid coupling of insulating inner tube has the insulating urceolus that sets up with insulating inner tube coaxial line, the both ends that correspond insulating inner tube in the insulating urceolus all are connected with the fender lid, two the fender lid is close to one side each other and is connected with the both ends of insulating inner tube, insulating urceolus with form well cavity between the insulating inner tube, the insulating inner tube downside corresponds and has all seted up the hole that leaks between insulating taper sleeve and the fender lid, the axis position department that the fender lid corresponds insulating inner tube has seted up the through-hole.
Through adopting above-mentioned technical scheme, when a small amount of electrolyte flowed from the elasticity hole of insulating elasticity gasket, electrolyte will directly flow to the insulating inner tube part between insulating taper sleeve and the fender lid, then directly flows to the cavity intracavity along the hole that leaks, avoids electrolyte to flow to the external world.
Preferably, one end of the insulating outer barrel is connected with a post-treatment barrel which is coaxial with the insulating outer barrel, a first arc-shaped liquid cavity which is coaxial with the post-treatment barrel is formed in the barrel wall of the post-treatment barrel, the central angle of the first arc-shaped liquid cavity is larger than 180 degrees and smaller than 360 degrees, a plurality of liquid spraying pipes which are communicated with the first arc-shaped liquid cavity and face the position of the axis of the post-treatment barrel are fixedly connected to the inner side of the post-treatment barrel by taking the axis of the post-treatment barrel as the center, a second arc-shaped liquid cavity which is coaxial with the first arc-shaped liquid cavity is formed in the lower portion of the inner wall of the post-treatment barrel, and a plurality of liquid discharging holes which are communicated with the second arc-shaped liquid cavity are formed in the bottom surface of the post-treatment barrel.
Through adopting above-mentioned technical scheme, after the oxidation treatment of thick copper line process anode, when getting into the aftertreatment section of thick bamboo, can be through injecting the cleaning solution to arc liquid cavity one in, make the cleaning solution pass through the spray tube and spray thick copper line to accomplish the cleanness of thick copper line, and the waste liquid of clean production will arrange to two internal storages of arc liquid cavity through the outage.
Preferably, an annular air cavity II is formed in one side, away from the retaining cover, of the arc-shaped liquid cavity I, corresponding to the inner wall of the post-treatment barrel, a plurality of air injection pipes II are fixedly connected to the position, corresponding to the annular air cavity II, of the inner wall of the post-treatment barrel, and are fixedly connected to the axis of the post-treatment barrel as the center, the air injection pipes II face to the axis position of the post-treatment barrel, and the nozzles of the air injection pipes II are obliquely arranged towards the direction of the retaining cover.
Through adopting above-mentioned technical scheme, after the thick copper line is through the cleanness of hydrojet pipe, continue the conveying along with the thick copper line, two air injection pipes simultaneously spray the surface to the thick copper line of the air in the annular air cavity two, because two orientation of air injection pipe keep off the lid direction, consequently can be close to the direction injection that keeps off the lid with the cleaning solution trend on thick copper line surface, and then make the surface of the thick copper line through two positions of annular air cavity not being stained with the water droplet, make thick copper line surface keep dry.
Preferably, the inner wall of the post-treatment barrel is conical, and the end, with a smaller aperture, of the inner wall of the post-treatment barrel is far away from the insulating outer barrel.
Through adopting above-mentioned technical scheme, the inner tube wall that adopts the aftertreatment section of thick bamboo is the toper, and the cleaning solution that falls to aftertreatment section of thick bamboo bottom surface will directly fall to the outage position along the conical surface of the inner tube wall of cleaning solution, and the collection of the cleaning solution of being convenient for avoids the cleaning solution to fall to jet-propelled pipe two in.
Preferably, the one end that insulating urceolus was kept away from to the aftertreatment section of thick bamboo is connected with the package paint cylinder with aftertreatment section of thick bamboo coaxial line, be provided with the heating chamber of lacquer layer in the package paint cylinder, the one end that the package paint cylinder corresponds the lacquer layer heating chamber and is close to the aftertreatment section of thick bamboo is connected with the feeding taper sleeve with a package paint cylinder coaxial line, the other end that the package paint cylinder corresponds the lacquer layer heating chamber is connected with the ejection of compact and keeps off the ring, the charging hole has been seted up at the conical top of feeding taper sleeve, the ejection of compact keeps off and sets up the discharge opening with the feeding hole coaxial line on the ring, the feeding hole aperture is less than the discharge opening aperture, the outer peripheral face rigid coupling of package paint cylinder has heating device, the outer peripheral face rigid coupling of package paint cylinder has can be to the continuous reinforced blevile of material in the package paint cylinder.
By adopting the technical scheme, along with the continuous conveying of thick copper wires, one end of each thick copper wire enters the paint layer heating cavity from the feeding hole of the feeding taper sleeve of the paint coating barrel, meanwhile, raw materials of an insulating paint layer are conveyed into the paint coating barrel through the material pushing device, the raw materials are heated to thick liquid through the heating device, at the moment, thick paint coating is hung on the peripheral surface of the thick copper wire along with the conveying of the thick copper wire until the thick copper wire is conveyed out from the discharging hole, at the moment, paint coating is realized on the peripheral surface of the thick copper wire, the diameter of a copper wire after paint coating is identical to that of the discharging baffle ring, in addition, as the heating device is arranged on the outer side of the paint coating barrel, the paint coating barrel is connected with the post-processing barrel, the heat of the paint coating barrel can be transmitted to the post-processing barrel and further transmitted into the annular air cavity, the heating of the air in the annular air cavity II is realized, so that the air in the air injection pipe II is sprayed out, the surface drying effect of the thick copper wire is enhanced, the preheating is realized, and the insulating hot air is prevented from affecting the insulating outer barrel.
Preferably, the feeding end of the inner cylinder is connected with a pretreatment cylinder which is coaxial with the insulating inner cylinder, a first annular air cavity is formed in the wall of the pretreatment cylinder, a plurality of first air nozzles communicated with the first annular air cavity are fixedly connected to the position, corresponding to the first annular air cavity, of the inner wall of the pretreatment cylinder, and the nozzles of the first air nozzles are obliquely arranged towards the axial position of the pretreatment cylinder and towards the direction far away from the insulating inner cylinder.
Through adopting above-mentioned technical scheme, before the thick copper line got into insulating inner tube, jet-propelled pipe one can be with the gas injection of annular air cavity one to the thick copper line on to clean the thick copper line, and because jet-propelled pipe one's spout orientation keeps away from insulating inner tube direction slope setting, can all spray the foreign matter to the direction of keeping away from insulating inner tube, the cleanness on surface when guaranteeing the thick copper line and getting into insulating inner tube.
Preferably, a plurality of supports are fixedly connected to the inner peripheral surface of the pretreatment barrel, the end portions of the supports are rotatably connected with straightening wheels, and straightening channels coaxial with the insulating inner barrel are formed between the adjacent sides of the straightening wheels.
Through adopting above-mentioned technical scheme, after the thick copper line gets into a preliminary treatment section of thick bamboo, can at first accomplish the straightening to the thick copper line through the straightening passageway that a plurality of straightener roller formed, guarantee the straightness accuracy of thick copper line, guarantee that the thick copper line can get into in the insulating inner tube.
Preferably, the pushing device comprises a feeding pipe vertically and fixedly connected to the paint coating barrel, a spiral feeding roller is rotationally connected in the feeding pipe, and a filling pipe is fixedly connected to one side of the upper end of the feeding pipe.
Through adopting above-mentioned technical scheme, in the during operation, drop into the filler pipe with the raw materials, through the continuous rotation of spiral feed roller, can be with the continuous paint layer heating intracavity that delivers to a package lacquer section of thick bamboo of material and promote the material extrusion in the paint layer heating intracavity.
In summary, the present application includes at least one of the following beneficial technical effects:
1. when the device is used, one end of a thick copper wire is inserted into the insulating taper sleeve at one end of the insulating inner cylinder, the end part of the thick copper wire pushes the elastic hole of the insulating elastic sealing sheet open and is inserted into the insulating inner cylinder, and then the thick copper wire is pushed out from the elastic hole of the elastic sealing sheet of the other insulating taper sleeve;
2. after the thick copper wire is subjected to anodic oxidation treatment and enters the post-treatment barrel, cleaning liquid can be injected into the arc-shaped liquid cavity I, the cleaning liquid can be sprayed to the thick copper wire through the liquid spraying pipe, so that the thick copper wire is cleaned, waste liquid generated by cleaning is discharged into the arc-shaped liquid cavity II through the liquid discharge holes and stored, after the thick copper wire is cleaned through the liquid spraying pipe, the thick copper wire is continuously conveyed along with the thick copper wire, meanwhile, the air in the arc-shaped liquid cavity II is sprayed to the surface of the thick copper wire through the air spraying pipe II, and the cleaning liquid on the surface of the thick copper wire can be sprayed in the direction close to the blocking cover due to the fact that the air spraying pipe II faces the direction of the blocking cover, so that the surface of the thick copper wire passing through the arc-shaped liquid cavity II is not stained with water drops, and the surface of the thick copper wire is kept dry;
3. the method comprises the following steps that one end of a thick copper wire enters a paint layer heating cavity from a feeding hole of a feeding taper sleeve of an enamel coating cylinder along with continuous conveying of the thick copper wire, meanwhile, raw materials of an insulating paint layer are conveyed into the enamel coating cylinder through a material pushing device, the raw materials are heated to thick liquid through a heating device, at the moment, thick enamel coating is hung on the peripheral surface of the thick copper wire along with conveying of the thick copper wire until the thick copper wire is conveyed out from a discharging hole, at the moment, enamel coating is achieved on the peripheral surface of the thick copper wire, the diameter of a copper wire after enamel coating is the same as that of a discharging hole of a discharging baffle ring, in addition, a heating device is arranged outside the enamel coating cylinder, the enamel coating cylinder is connected with a post-treatment cylinder, heat of the enamel coating cylinder can be transmitted to the post-treatment cylinder and further transmitted into an annular air cavity II, heating of air in the annular air cavity II is achieved, hot air is sprayed out from an air injection pipe II, the surface drying effect of the thick copper wire is enhanced, preheating is achieved, and then, and further, and the insulating air cavity of the insulating outer cylinder and the insulating outer cylinder is prevented from being affected by the post-treatment cylinder.
Drawings
FIG. 1 is a schematic view of the overall structure of a rapid oxidation treatment system for conductive wires according to the present invention.
FIG. 2 is a schematic view of the pretreatment cartridge of the present application.
FIG. 3 is a schematic view of the structure of the oxidation treatment cartridge of the present application.
Figure 4 is a schematic view of the construction of the return pipe of the present application.
Fig. 5 is an enlarged schematic view of a portion a of fig. 3.
FIG. 6 is a schematic structural view of a post-treatment cartridge according to the present application.
FIG. 7 is a schematic structural view of the second arcuate liquid chamber of the present application.
FIG. 8 is a schematic view of the construction of a paint cartridge according to the present application.
Description of reference numerals: 1. a pretreatment cartridge; 11. a support; 111. a straightening wheel; 12. a first annular air cavity; 121. an air inlet pipe; 122. a first gas injection pipe; 2. an oxidation treatment cylinder; 21. an insulating inner cylinder; 211. insulating taper sleeves; 212. an insulating elastic sealing sheet; 213. an elastic hole; 214. a water leakage hole; 22. an insulating outer cylinder; 221. a blocking cover; 222. a through hole; 23. a conductive half ring; 231. an anode half-ring plate; 232. a cathode half ring plate; 233. a liquid permeable hole; 234. a receiving groove; 235. floating the steel balls; 24. a liquid inlet pipe; 241. a liquid storage barrel; 242. a control valve; 25. a hollow cavity; 26. a liquid discharge pipe; 261. a liquid storage barrel; 27. a return pipe; 271. a reflux pump; 3. a post-treatment cylinder; 31. a first arc-shaped liquid cavity; 311. cleaning the liquid pipe; 312. a liquid spraying pipe; 32. an arc-shaped liquid cavity II; 321. a drain hole; 322. a waste liquid pipe; 323. a regulating valve; 33. a second annular air cavity; 331. a gas supply pipe; 332. a second gas injection pipe; 4. coating an enamel cylinder; 41. a paint layer heating cavity; 42. a heating device; 43. feeding taper sleeves; 431. a feed port; 44. a discharging baffle ring; 441. a discharge hole; 45. a cooling fan; 46. a material pushing device; 461. a feed pipe; 462. a screw feed roller; 463. a drive motor; 464. a filler tube.
Detailed Description
The present application is described in further detail below with reference to the attached drawings.
The embodiment of the application discloses a wire rapid oxidation treatment system.
Referring to fig. 1, a quick oxidation treatment system for wires comprises a pretreatment cylinder 1, an oxidation treatment cylinder 2, a post-treatment cylinder 3 and an enamel-covered cylinder 4 which are arranged in sequence, wherein the axes of the pretreatment cylinder 1, the oxidation treatment cylinder 2, the post-treatment cylinder 3 and the enamel-covered cylinder 4 are all horizontally arranged and are positioned on the same straight line. When the device works, a traction device can be adopted to carry out traction transmission on the conducting wires transmitted out of the paint-coated cylinder 4, so that the crude copper wires sequentially pass through the pretreatment cylinder 1 to complete cleaning pretreatment; the oxidation treatment is completed through an oxidation treatment cylinder 2; cleaning after oxidation treatment is completed again through the post-treatment cylinder 3; and finishing the enameling of the coarse copper wire by an enameling barrel 4 to finally form the copper wire.
Referring to fig. 2, a plurality of brackets 11 are fixed to the inner circumferential surface of the pretreatment tank 1, a straightening wheel 111 is rotatably connected to an end of each bracket 11, and a straightening channel coaxial with the insulating inner tank 21 is formed between the adjacent sides of the plurality of straightening wheels 111. The barrel wall of the pretreatment barrel 1 is internally provided with a first annular air cavity 12, the outer wall of the pretreatment barrel 1 is fixedly connected with an air inlet pipe 121 communicated with the first annular air cavity 12, the air inlet pipe 121 can be connected with external air injection equipment, the inner wall of the pretreatment barrel 1 is uniformly and fixedly connected with a first air injection pipe 122 communicated with the first annular air cavity 12, the nozzle of each first air injection pipe 122 faces to the axis position of the pretreatment barrel 1, and the nozzle of each first air injection pipe 122 faces to the direction inclined away from the oxidation treatment barrel 2. After the thick copper line gets into a pretreatment canister 1, can at first accomplish the aligning to the thick copper line through the straightening passageway that a plurality of straightener roller 111 formed, guarantee the straightness accuracy of thick copper line, and simultaneously, the intake pipe 121 of cyclic annular air cavity one 12 is connected through external gas injection equipment, the gaseous injection of cyclic annular air cavity one 12 to thick copper line is gone up to rethread jet-propelled pipe one 122, thereby clean thick copper line, and because the spout orientation of jet-propelled pipe one 122 sets up towards the direction slope of keeping away from oxidation treatment canister 2, can all spray the foreign matter to the direction of keeping away from oxidation treatment canister 2, guarantee the cleanness on surface when thick copper line gets into oxidation treatment canister 2.
Referring to fig. 3 and 4, the oxidation treatment cylinder 2 includes an insulating inner cylinder 21 and an insulating outer cylinder 22 sleeved outside the insulating inner cylinder 21, and axes of the insulating inner cylinder 21 and the insulating outer cylinder 22 are in the same straight line.
The two ends of the insulating inner cylinder 21 are both connected with insulating taper sleeves 211 through bolts, the insulating taper sleeves 211 and the insulating inner cylinder 21 are arranged coaxially, and the conical tops of the two insulating taper sleeves 211 face to one side close to each other. The conic node of two insulating taper sleeves 211 all is rigid coupling to have insulating elasticity gasket 212, two insulating elasticity gasket 212 all offer elastic hole 213 (refer to fig. 5) corresponding insulating inner tube 21's axis position department, elastic hole 213 contracts to the encapsulated situation because of insulating elasticity gasket 212's effect under the normality, when thick copper line inserts elastic hole 213 from an elasticity gasket, elastic hole 213 can open because of its self elasticity, make thick copper line insert, then, along with the continuation motion of thick copper line, the tip of thick copper line will be ejecting by the elastic hole 213 of another elasticity gasket.
Two pairs of symmetrically arranged conductive half rings 23 are fixedly connected to the upper and lower sides of the inner peripheral surface of the insulating inner cylinder 21, the sides of the two conductive half rings 23 away from each other are fixedly connected to wires extending out of the insulating inner cylinder 21 and the insulating outer cylinder 22 for connecting external power equipment (which is not described in detail in the prior art), the axes of the two conductive half rings 23 and the axis of the insulating inner cylinder 21 are in the same straight line, and a gap is formed between the two conductive half rings 23, so that the two conductive half rings 23 are not in direct contact. One side of a conductive half ring 23 close to another conductive half ring 23 is fixedly connected with a plurality of anode semi-ring plates 231, one side of another conductive half ring 23 close to the anode semi-ring plates 231 is fixedly connected with a plurality of cathode semi-ring plates 232, the plurality of anode semi-ring plates 231 and the plurality of cathode semi-ring plates 232 are uniformly arranged along the axis direction of the insulating inner cylinder 21, the axis directions of the anode semi-ring plates 231 and the cathode semi-ring plates 232 are the same as the axis direction of the insulating inner cylinder 21, and a plurality of liquid penetrating holes 233 are formed in the surfaces of the anode semi-ring plates 231 and the cathode semi-ring plates 232. During operation, the electrolyte can be injected into the insulating inner cylinder 21 through the liquid inlet pipe 24, the anode half-ring plate 231 and the cathode half-ring plate 232 can be electrified through the conductive half rings 23, and the electrolyte can flow conveniently through the gap between the two conductive half rings 23 and the liquid permeating holes 233 on the surfaces of the anode half-ring plate 231 and the cathode half-ring plate 232.
The side of the anode half-ring plate 231 close to the cathode half-ring plate 232 is also provided with a semicircular receiving groove 234 (refer to fig. 5), the corresponding receiving grooves 234 are spliced with each other to form a receiving hole for passing a copper wire, and the bottom surface of the receiving groove 234 is embedded with a plurality of floating steel balls 235. The upper side of the peripheral surface of the insulating inner cylinder 21 is further fixedly connected with a liquid inlet pipe 24, the lower end of the liquid inlet pipe 24 is communicated with the inside of the insulating inner cylinder 21, the upper end of the liquid inlet pipe 24 extends out of the outer side wall of the insulating outer cylinder 22 and is fixedly connected with a liquid storage barrel 241, and the middle part of the liquid inlet pipe 24 is fixedly connected with a control valve 242. After the thick copper wire is inserted into the insulating inner cylinder 21, the thick copper wire is conveyed in a bearing hole formed by the bearing grooves 234 along the anode semi-ring plate 231 and the cathode semi-ring plate 232, the floating steel balls 235 are abutted to the peripheral surface of the thick copper wire and are convenient for pushing the thick copper wire, then the electrolyte is injected through the liquid inlet pipe 24 and the two conductive semi-rings 23 are electrified, so that the anode semi-ring plate 231 and the cathode semi-ring plate 232 are electrified, the thick copper wire is oxidized by matching the electrolyte, and the thick copper wire is prevented from leaking because the elastic hole 213 of the adopted insulating elastic sealing sheet 212 can tightly hoop the thick copper wire, and external foreign matters can not enter the insulating inner cylinder 21.
The two ends of the insulating inner cylinder 21 in the insulating outer cylinder 22 are all connected with the retaining covers 221 through bolts, the axial line positions of the retaining covers 221 corresponding to the insulating inner cylinder 21 are all provided with through holes 222, the retaining covers 221 close to the pretreatment cylinder 1 are connected with the pretreatment cylinder 1 through bolts, the two retaining covers 221 are close to one side and are connected with the two ends of the insulating inner cylinder 21, a hollow cavity 25 is formed between the inner wall of the insulating outer cylinder 22 and the outer wall of the insulating inner cylinder 21, the lower side of the insulating inner cylinder 21 is provided with water leakage holes 214 corresponding to the positions between the insulating conical sleeve 211 and the retaining covers 221, the water leakage holes 214 are communicated with the hollow cavity 25, the bottom surface of the insulating outer cylinder 22 is fixedly connected with a liquid discharge pipe 26, the upper end of the liquid discharge pipe 26 is communicated with the hollow cavity 25, the lower end of the liquid discharge pipe 26 is fixedly connected with a liquid storage barrel 261, a return pipe 27 is fixedly connected between the liquid storage barrel 261 and the liquid storage barrel 241, and a return pump 271 is fixedly connected with the middle part of the return pipe 27. After the crude copper wire is processed from the pretreatment cylinder 1, the crude copper wire is directly inserted into the insulating outer cylinder 22 from the through hole 222 in the middle of the blocking cover 221, and then is inserted into the insulating inner cylinder 21 through the elastic hole 213 of the insulating elastic sealing plate at the top of the insulating taper sleeve 211, when a small amount of electrolyte flows out from the elastic hole 213 of the insulating elastic sealing plate 212, the electrolyte directly flows to the insulating inner cylinder 21 between the insulating taper sleeve 211 and the blocking cover 221, then directly flows into the hollow cavity 25 along the water leakage hole 214, and flows into the liquid storage barrel 261 from the liquid discharge pipe 26, when the electrolyte in the liquid storage barrel 261 is too much, the reflux pump 271 can be started to send the electrolyte in the liquid storage barrel 261 to the liquid storage barrel 241, and the reflux utilization of the electrolyte is realized.
Referring to fig. 6 and 7, the post-treatment cylinder 3 is bolted to the insulating outer cylinder 22, the inner wall of the post-treatment cylinder 3 is tapered, and the end of the post-treatment cylinder 3 having a larger diameter is close to the oxidation treatment cylinder 2. Arc-shaped liquid cavity one 31 coaxial with aftertreatment section of thick bamboo 3 is seted up in the section of thick bamboo wall of aftertreatment section of thick bamboo 3, the central angle of arc-shaped liquid cavity one 31 is greater than 180 and is less than 360, the global upside rigid coupling of aftertreatment section of thick bamboo 3 has clean liquid pipe 311, external water supply equipment (this is no longer repeated for prior art) can be connected to clean liquid pipe 311, the inboard of aftertreatment section of thick bamboo 3 uses its axis to have a plurality of spray tubes 312 that communicate with arc-shaped liquid cavity one 31 as the even rigid coupling in center, the spout of spray tubes 312 sets up towards the axis position department of aftertreatment section of thick bamboo 3, arc-shaped liquid cavity two 32 coaxial with arc-shaped liquid cavity one 31 is seted up to the lower part in the section of thick bamboo wall of aftertreatment section of thick bamboo 3, a plurality of outage 321 that communicate with arc-shaped liquid cavity two 32 are still seted up to the bottom surface of aftertreatment section of thick bamboo 3. A waste liquid pipe 322 is fixedly connected to the lower side of the peripheral surface of the post-treatment cylinder 3, and the upper end of the waste liquid pipe 322 is communicated with the second arc-shaped liquid cavity 32. A regulating valve 323 is fixedly connected at the middle part of the waste liquid pipe 322; after the thick copper line is handled through anodic oxidation, when getting into aftertreatment section of thick bamboo 3, can be through injecting the cleaning solution in arc liquid cavity 31, make the cleaning solution pass through spray tube 312 and spray the thick copper line, thereby accomplish the cleanness of thick copper line, be the toper owing to the inner tube wall that adopts aftertreatment section of thick bamboo 3, the cleaning solution that falls to the 3 bottom surfaces of aftertreatment section of thick bamboo will directly fall to the outage 321 position along the conical surface of the inner tube wall of cleaning solution, then arrange to two 32 in the arc liquid cavity through the outage 321, finally discharge through waste liquid pipe 322.
The one end that keeps away from oxidation treatment section of thick bamboo 2 that corresponds cyclic annular air cavity 12 in the section of thick bamboo wall of aftertreatment section of thick bamboo 3 has seted up two 33 of cyclic annular air cavity, the peripheral rigid coupling of outer wall of aftertreatment section of thick bamboo 3 has air supply pipe 331, air supply pipe 331 one end and two 33 intercommunications of cyclic annular air cavity, and its other end can be connected external air supply equipment (no longer repeated here for prior art) the axis of a post-treatment section of thick bamboo 3 that the position that the inner wall of aftertreatment section of thick bamboo 3 corresponds two 33 of cyclic annular air cavity has two 332 of a plurality of gas nozzles for central rigid coupling, two 332 of gas nozzles all face the axis position department of aftertreatment section of thick bamboo 3, and the gas nozzle of two 332 of gas nozzles all sets up towards keeping off the slope of lid 221 direction. After the blister copper wire is cleaned by the liquid spraying pipe 312, the blister copper wire is conveyed along with the blister copper wire, meanwhile, the second air spraying pipes 332 spray air in the second annular air cavity 33 to the surface of the blister copper wire, and since the second air spraying pipes 332 face the direction of the blocking cover 221, the cleaning liquid on the surface of the blister copper wire can be sprayed towards the direction close to the blocking cover 221, so that the surface of the blister copper wire passing through the second annular air cavity 33 is not stained with water drops, and the surface of the blister copper wire is kept dry.
Referring to fig. 8, one end of the enameling cylinder 4, which is close to the post-processing cylinder 3, is bolted to the post-processing cylinder 3, a paint layer heating chamber 41 is arranged in the enameling cylinder 4, a heating device 42 is fixedly connected to the outer peripheral surface of the enameling cylinder 4, the heating device 42 adopts a spiral heating coil fixed to the outer peripheral surface of the enameling cylinder 4, the spiral heating coil is an electric heating coil (which is not described in detail in the prior art), one end of the enameling cylinder 4, which corresponds to the paint layer heating chamber 41, which is close to the post-processing cylinder 3, is bolted to a feeding taper sleeve 43 which is coaxial with the enameling cylinder 4, the other end of the enameling cylinder 4, which corresponds to the paint layer heating chamber 41, is bolted to a discharging baffle ring 44, a feeding hole 431 is formed in the taper top of the feeding taper sleeve 43, a discharging hole 441 which is coaxial with the feeding hole 431 is formed in the middle of the discharging baffle ring 44, the aperture of the feeding hole 431 is smaller than the aperture of the discharging hole 441, the aperture of the feeding hole 431 is the same as the diameter of the thick copper wire, and one end, which corresponds to the discharging baffle ring 44, which is far away from the paint layer heating chamber 41, which is fixedly connected to the enameling cylinder 4, is uniformly provided with a plurality of cooling fans 45. A plurality of cooling fans 45 are each capable of blowing air toward the axial position of the paint-packing canister 4.
The outer peripheral face rigid coupling of package paint section of thick bamboo 4 has pushing equipment 46, pushing equipment 46 includes vertical rigid coupling in package paint section of thick bamboo 4 global upside and with the feeding pipe 461 of lacquer layer heating chamber 41 intercommunication, the feeding pipe 461 internal rotation is connected with the spiral feed roller 462 with the feeding pipe 461 coaxial line, and the one end rigid coupling that the feeding pipe 461 is kept away from package paint section of thick bamboo 4 has can drive spiral feed roller 462 pivoted driving motor 463, the upper end one side rigid coupling of feeding pipe 461 has the filler tube 464 with the feeding pipe 461 intercommunication.
Following the continuous transmission of the thick copper wire, one end of the thick copper wire enters the paint layer heating cavity 41 from the feeding hole 431 of the feeding taper sleeve 43 of the enamelling cylinder 4, meanwhile, during operation, the raw materials are put into the filler pipe 464, the materials can be continuously conveyed into the paint layer heating cavity 41 of the enamelling cylinder 4 and pushed out of the paint layer heating cavity 41 through the continuous rotation of the spiral feeding roller 462, the enamelling cylinder 4 is heated through the spiral heating coil, so that the raw materials are heated to thick liquid, at the moment, thick enamelling paint is hung on the peripheral surface of the thick copper wire along with the transmission of the thick copper wire until the thick copper wire is transmitted out through the discharge hole 441, at the moment, the peripheral surface of the thick copper wire is enamelled, the enamelling cylinder 4 is connected with the post-processing cylinder 3, the heat of the enamelling cylinder 4 can be transmitted to the post-processing cylinder 3, and then transmitted to the discharge hole 441 of the discharge baffle ring 44, in addition, a heating device 42 is arranged outside the enamelling cylinder 4, the enamelling cylinder 4 is connected with the post-processing cylinder 3, so that the heat of the arc-shaped insulating liquid air cavity 22 in the two insulating cylinder 22 is heated to realize the secondary air cavity, and the secondary insulating liquid preheating effect of the insulating cylinder 22, and further, and the secondary insulating liquid is realized by the air cavity 22, and the insulating liquid, and the outer cylinder 22.
The implementation principle of the rapid oxidation treatment system for the conducting wire in the embodiment of the application is as follows: during operation, firstly, one end of a thick copper wire sequentially penetrates through the pretreatment cylinder 1, the oxidation treatment cylinder 2, the post-treatment cylinder 3 and the paint-coating cylinder 4, one end of the thick copper wire extending out of the paint-coating cylinder 4 is drawn through an external drawing device, and then the equipment is formally operated.
After the thick copper line gets into a pretreatment canister 1, can at first accomplish the aligning to the thick copper line through the straightening passageway that a plurality of straightener roller 111 formed, guarantee the straightness accuracy of thick copper line, and simultaneously, the intake pipe 121 of cyclic annular air cavity one 12 is connected through external gas injection equipment, the gaseous injection of cyclic annular air cavity one 12 to thick copper line is gone up to rethread jet-propelled pipe one 122, thereby clean thick copper line, and because the spout orientation of jet-propelled pipe one 122 sets up towards the direction slope of keeping away from oxidation treatment canister 2, can all spray the foreign matter to the direction of keeping away from oxidation treatment canister 2, guarantee the cleanness on surface when thick copper line gets into oxidation treatment canister 2.
After the thick copper wire is inserted into the insulating inner cylinder 21, the thick copper wire is conveyed in a bearing hole formed by the bearing grooves 234 along the anode semi-ring plate 231 and the cathode semi-ring plate 232, the floating steel balls 235 are abutted to the peripheral surface of the thick copper wire and are convenient for pushing the thick copper wire, then the electrolyte is injected through the liquid inlet pipe 24 and the two conductive semi-rings 23 are electrified, so that the anode semi-ring plate 231 and the cathode semi-ring plate 232 are electrified, the thick copper wire is oxidized by matching the electrolyte, and the thick copper wire is prevented from leaking because the elastic hole 213 of the adopted insulating elastic sealing sheet 212 can tightly hoop the thick copper wire, and external foreign matters can not enter the insulating inner cylinder 21.
After the thick copper line is through anodic oxidation treatment, when getting into aftertreatment section of thick bamboo 3, can be through injecting the cleaning solution in the arc liquid cavity 31, make the cleaning solution pass through spray tube 312 and spray the thick copper line, thereby accomplish the cleanness of thick copper line, after the thick copper line passes through spray tube 312's cleanness, continue the conveying along with the thick copper line, simultaneously two 332 of jet-propelled pipe spray the surface to the thick copper line with the air injection in two 32 of arc liquid cavity, because two 332 of jet-propelled pipe keep off the lid 221 direction towards, consequently, can spray the cleaning solution trend on thick copper line surface near the direction that keeps off lid 221, and then make the surface of the thick copper line through two 32 positions of arc liquid cavity not be stained with the water droplet, make thick copper line surface keep dry.
Then, the thick copper line gets into lacquer layer heating chamber 41 by the feed port 431 of the feeding taper sleeve 43 of a package lacquer section of thick bamboo 4, and simultaneously, in operation, drop into the filler 464 with the raw materials, through the continuous rotation of spiral feed roller 462, can send the material to in the lacquer layer heating chamber 41 of a package lacquer section of thick bamboo 4 and promote the material in the lacquer layer heating chamber 41 and extrude constantly, and heat a package lacquer section of thick bamboo 4 through spiral heating coil, thereby heat the raw materials to thick form liquid, at this moment, thick form copper line global will hang the package lacquer of thick form along with its conveying, until the thick copper line conveys out by discharge opening 441, at this moment, form the package lacquer on the outer peripheral face of thick copper line, rethread a plurality of cooling blower 45's air-blast cooling, can realize the solidification of package lacquer layer, the copper wire diameter that the package lacquer was accomplished is the same with the discharge opening 441 diameter of ejection of compact baffle ring 44.
The above embodiments are preferred embodiments of the present application, and the protection scope of the present application is not limited by the above embodiments, so: all equivalent changes made according to the structure, shape and principle of the present application shall be covered by the protection scope of the present application.

Claims (9)

1. A wire rapid oxidation treatment system is characterized in that: the insulating device comprises an insulating inner cylinder (21) which is horizontally arranged, wherein two conductive semi-rings (23) which are symmetrically arranged and have the same axis with the insulating inner cylinder (21) are fixedly connected to the inner peripheral surface of the insulating inner cylinder (21), and a gap is formed between the two conductive semi-rings (23); one sides of the two conductive semi-rings (23) close to each other are fixedly connected with a plurality of cathode semi-ring plates (232) and anode semi-ring plates (231) respectively, two ends of the insulating inner cylinder (21) are connected with insulating taper sleeves (211) coaxial with the insulating inner cylinder (21), the conical tops of the insulating taper sleeves (211) are arranged towards one sides close to each other, the conical tops of the insulating taper sleeves (211) are fixedly connected with insulating elastic sealing pieces (212), and the middle parts of the insulating elastic sealing pieces (212) are provided with elastic holes (213) capable of expanding along with the elastic deformation of the insulating elastic sealing pieces; the peripheral surface of the insulating inner cylinder (21) is fixedly connected with a liquid inlet pipe (24).
2. The system of claim 1, wherein: the outside rigid coupling of insulating inner tube (21) has insulating urceolus (22) that sets up with insulating inner tube (21) coaxial line, the both ends that correspond insulating inner tube (21) in insulating urceolus (22) all are connected with and keep off lid (221), two keep off lid (221) and be close to one side each other and be connected with the both ends of insulating inner tube (21), insulating urceolus (22) with cavity (25) in forming between insulating inner tube (21), insulating inner tube (21) downside corresponds insulating taper sleeve (211) and keeps off and all seted up between lid (221) hole of leaking (214), keep off the axial position department that lid (221) correspond insulating inner tube (21) and seted up through-hole (222).
3. The system of claim 2, wherein: one end of the insulating outer barrel (22) is connected with a post-treatment barrel (3) which is coaxial with the insulating outer barrel (22), a first arc-shaped liquid cavity (31) which is coaxial with the post-treatment barrel (3) is formed in the barrel wall of the post-treatment barrel (3), the central angle of the first arc-shaped liquid cavity (31) is larger than 180 degrees and smaller than 360 degrees, a plurality of liquid spraying pipes (312) which are communicated with the first arc-shaped liquid cavity (31) and face the axis position of the post-treatment barrel (3) are fixedly connected to the inner side of the post-treatment barrel (3) by taking the axis of the post-treatment barrel as the center, a second arc-shaped liquid cavity (32) which is coaxial with the first arc-shaped liquid cavity (31) is formed in the lower portion of the barrel wall of the post-treatment barrel (3), and a plurality of liquid discharging holes (321) which are communicated with the second arc-shaped liquid cavity (32) are formed in the bottom surface of the post-treatment barrel (3).
4. The system for rapid oxidation treatment of conductive wires according to claim 3, wherein: the one side that keeps away from fender lid (221) corresponding arc liquid chamber one (31) in the section of thick bamboo wall of aftertreatment section of thick bamboo (3) has seted up cyclic annular air cavity two (33), the axis of aftertreatment section of thick bamboo (3) is fixed with a plurality of jet-propelled pipes two (332) for the center after the position that aftertreatment section of thick bamboo (3) inner wall corresponds cyclic annular air cavity two (33), jet-propelled pipe two (332) all face the axis position department of aftertreatment section of thick bamboo (3), and the spout of jet-propelled pipe two (332) all sets up towards keeping off lid (221) direction slope.
5. The system of claim 4, wherein: the inner wall of the post-treatment barrel (3) is conical, and the end, with smaller aperture, of the inner wall of the post-treatment barrel (3) is far away from the insulating outer barrel (22).
6. The system of claim 3, wherein: the one end that insulating urceolus (22) was kept away from to aftertreatment section of thick bamboo (3) is connected with a packet of paint drum (4) with aftertreatment section of thick bamboo (3) coaxial line, be provided with lacquer layer heating chamber (41) in a packet of paint drum (4), the one end that packet of paint drum (4) corresponds lacquer layer heating chamber (41) and is close to aftertreatment section of thick bamboo (3) is connected with feeding taper sleeve (43) with a packet of paint drum (4) coaxial line, the other end that packet of paint drum (4) corresponds lacquer layer heating chamber (41) is connected with ejection of compact fender ring (44), feeding hole (431) have been seted up at the conical top of feeding taper sleeve (43), ejection of compact fender ring (44) is last to set up discharge opening (441) with feeding hole (431) coaxial line, feeding hole (431) aperture is less than discharge opening (441) aperture, the rigid coupling of packet of paint drum (4) has heating device (42), the rigid coupling of packet of paint drum (4) has can be to continuous reinforced pushing equipment (46) in packet of paint drum (4).
7. The system of claim 3, wherein: the feed end of insulating inner tube (21) is connected with a preliminary treatment section of thick bamboo (1) that sets up with insulating inner tube (21) coaxial line, annular air cavity (12) have been seted up in the section of thick bamboo wall of preliminary treatment section of thick bamboo (1), the position rigid coupling that the inner wall of preliminary treatment section of thick bamboo (1) corresponds annular air cavity (12) has the air jet pipe (122) of a plurality of intercommunication annular air cavities (12), the spout of air jet pipe (122) is towards the axis position department of preliminary treatment section of thick bamboo (1) and is kept away from insulating inner tube (21) direction slope setting towards the orientation.
8. The system for rapid oxidation treatment of conductive wires according to claim 7, wherein: the inner peripheral surface of the pretreatment barrel (1) is fixedly connected with a plurality of supports (11), the end parts of the supports (11) are rotatably connected with straightening wheels (111), and straightening channels coaxial with the insulating inner barrel (21) are formed between the sides, close to each other, of the straightening wheels (111).
9. The system of claim 6, wherein: the material pushing device (46) comprises a feeding pipe (461) vertically and fixedly connected to the paint-coating barrel (4), a spiral feeding roller (462) is rotationally connected to the feeding pipe (461), and a filling pipe (464) is fixedly connected to one side of the upper end of the feeding pipe (461).
CN202010821477.1A 2020-08-15 2020-08-15 Rapid oxidation treatment system for lead Active CN112111775B (en)

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CN114197007A (en) * 2021-05-18 2022-03-18 西比里电机技术(苏州)有限公司 Conductor wire thermoelectric chemical oxidation treatment device

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CN103413632A (en) * 2013-09-02 2013-11-27 丹阳利华电子有限公司 Surface oxidation resistant treatment device for copper-cladding aluminum bimetallic composite wire
CN206902264U (en) * 2017-06-03 2018-01-19 深圳市宜诺自动化设备有限公司 A kind of aluminium foil continuous oxidation equipment with anode conducting device

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DE10342512B3 (en) * 2003-09-12 2004-10-28 Atotech Deutschland Gmbh Device for the electrolytic treatment of electrically conducting structures on strip-like material used in chip cards, price signs or ID cards comprises an arrangement consisting of contact electrodes and an electrolysis region
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