CN111995902A - Solvent type toughened glass ink diluent and preparation method thereof - Google Patents
Solvent type toughened glass ink diluent and preparation method thereof Download PDFInfo
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- CN111995902A CN111995902A CN202010940536.7A CN202010940536A CN111995902A CN 111995902 A CN111995902 A CN 111995902A CN 202010940536 A CN202010940536 A CN 202010940536A CN 111995902 A CN111995902 A CN 111995902A
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- solvent
- diluent
- toughened glass
- glass ink
- boiling point
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- 239000002904 solvent Substances 0.000 title claims abstract description 58
- 239000003085 diluting agent Substances 0.000 title claims abstract description 43
- 239000005341 toughened glass Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 5
- 238000009835 boiling Methods 0.000 claims description 26
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 21
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 21
- 229940116411 terpineol Drugs 0.000 claims description 21
- 239000002966 varnish Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 7
- 239000002318 adhesion promoter Substances 0.000 claims description 6
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 5
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 239000003350 kerosene Substances 0.000 claims description 5
- 230000010355 oscillation Effects 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 claims description 3
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 claims description 3
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 claims description 3
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 claims description 3
- 230000004907 flux Effects 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000002798 polar solvent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000011521 glass Substances 0.000 abstract description 12
- 239000012895 dilution Substances 0.000 abstract description 4
- 238000010790 dilution Methods 0.000 abstract description 4
- 239000006260 foam Substances 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 230000002401 inhibitory effect Effects 0.000 abstract description 3
- 238000003889 chemical engineering Methods 0.000 abstract description 2
- 239000012847 fine chemical Substances 0.000 abstract description 2
- 239000000976 ink Substances 0.000 description 45
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000004819 Drying adhesive Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000013035 low temperature curing Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a solvent type toughened glass ink diluent, which belongs to the field of fine chemical engineering and comprises the following raw material components in percentage by weight: the invention also discloses a preparation method of the solvent type toughened glass ink diluent, wherein the diluent prepared by the method has small smell, good compatibility with high-temperature sintered glass ink of various solvent systems, proper volatilization speed, good leveling property and extremely high dilution efficiency, can improve the drying adhesion of the ink, has defoaming and foam inhibiting effects on the ink, and can be widely applied to the diluent of the solvent type high-temperature sintered glass ink on the market.
Description
Technical Field
The invention belongs to the field of fine chemical engineering, and particularly relates to a solvent type toughened glass ink diluent and a preparation method thereof.
Background
In the case of glass, ceramic and other objects which can be subjected to high temperature treatment, the decoration of the surface is usually carried out by means of high temperature sintering of inorganic pigment coating and low temperature curing of organic coating. In contrast, the high-temperature sintered coating has better compatibility and adhesive force, lasting decorative effect and wide adaptability to the environment. At present, most of the ink used in the glass printing industry is prepared by mixing oil-soluble resin dissolved by organic solvent with pigment and other auxiliary agents. The toughened glass ink is usually high in viscosity in order to have good storability before use, and when the toughened glass ink is used, the toughened glass ink needs to be diluted by using a corresponding diluent. However, at present, because the solvents used by various ink manufacturers for producing the ink are different, the glass manufacturers must use the matched diluent for printing well when using the ink, otherwise, the disadvantages of leveling, pinholes, bubbles and the like can be generated, the universality of the diluents of various families is not strong, and the solvent type diluents generally have the problem of large odor, thereby causing great harm to people and environment.
In order to improve the disadvantages of the current solvent-based diluents and reduce the harm to people and the environment, various ink companies are also actively conducting research. However, since the introduction of a general-purpose diluent is not favorable for the sale of the ink at home from the viewpoint of economic benefits, no general-purpose diluent is available on the market at present.
Disclosure of Invention
Aiming at the problems in the prior art, the invention aims to provide a method for manufacturing natural-color handbag paper, and the diluent prepared by the method has the advantages of small smell, good compatibility with high-temperature sintered glass ink of various flux systems, proper volatilization speed, good leveling property, extremely high dilution efficiency, capability of improving the drying adhesion of the ink, defoaming and foam inhibition effects on the ink and capability of being generally applicable to the diluent of solvent type high-temperature sintered glass ink in the market.
In order to realize the purpose, the invention adopts the technical scheme that:
a solvent type toughened glass ink diluent comprises the following raw material components in percentage by weight: 30-50% of high-boiling point medium-low polarity solvent, 20-40% of medium-boiling point medium-low polarity solvent and 20-40% of terpineol system varnish.
Furthermore, the raw material composition also comprises 0-5% of auxiliary agent.
Further, the high-boiling point medium-low polar solvent is one or two of terpineol with a boiling point of more than 200 ℃, high-boiling point kerosene, a 200# solvent, diethylene glycol butyl ether acetate, diethylene glycol ethyl ether acetate, diethylene glycol butyl ether and tripropylene glycol methyl ether.
Further, the medium-boiling point low-polarity solvent is one or two of dipropylene glycol methyl ether, 100# solvent, ethylene glycol ethyl ether acetate and propylene glycol methyl ether acetate with the boiling point within the range of 100-200 ℃.
Further, the terpineol system varnish is a transparent mixed solution with resin and taking terpineol as a main fusing agent.
Further, the auxiliary agent is one or more of a dispersing agent, a leveling agent and an adhesion promoter.
A preparation method of a solvent type toughened glass ink diluent specifically comprises the following steps:
step 1: mixing and stirring the high-boiling point medium-low polarity solvent, the medium-boiling point medium-low polarity solvent and the terpineol system varnish according to the weight percentage, and adding the auxiliary agent during stirring until uniform transparent liquid is formed;
step 2: and (3) carrying out ultrasonic oscillation on the transparent liquid obtained by the treatment in the step (1) for 40-60min, and finally standing to obtain the diluent.
Further, the standing time of the step 2 is 55-70 min.
The invention has the beneficial effects that: (1) the diluent prepared by the invention has small smell, good compatibility with high-temperature sintered glass printing ink of various flux systems, proper volatilization speed, good leveling property and extremely high dilution efficiency, can reduce the using amount of the diluent, can improve the drying adhesive force of the printing ink, has defoaming and foam inhibiting effects on the printing ink, and can be generally applicable to the diluent of solvent type high-temperature sintered glass printing ink in the market;
(2) in the prior art, if a large amount of fast-volatilization solvents are used, the viscosity of the ink can be greatly increased, the fluidity is reduced, the leveling of the ink film is seriously influenced, and an orange peel phenomenon is easily generated; if a large amount of solvent with slow volatilization (high boiling point) is used, the ink can be dried slowly, and the ink film is sticky, soft, fluid and thick at the edge; therefore, the invention adopts two solvents with high boiling point and medium boiling point to jointly adjust the volatilization speed of the solvent in the printing ink to achieve balance, and the adding proportion of the two solvents is respectively 30-50 percent and 20-40 percent, thereby not causing the phenomenon of too fast volatilization of the solvent and too low volatility, having good leveling property, and adjusting the types of the solvents in various solvent type glass printing inks to achieve proper degree;
(3) the invention adopts terpineol system ink mixing oil, wherein the terpineol can improve the binding force between the ink resin and the printing stock interface, thereby improving the drying adhesive force of the ink; the adhesion promoter in the adopted auxiliary agent not only promotes the adhesion of the ink, but also increases the surface tension of the ink, so that the adhesion and the leveling property are simultaneously improved, and bubbles are not easy to generate.
Detailed Description
For a better understanding of the present invention, embodiments of the present invention are described in detail below with reference to examples, but those skilled in the art will understand that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention.
In the following embodiments, the high-boiling point medium-low polar solvent is one or two of terpineol with a boiling point of more than 200 ℃, high-boiling point kerosene, 200# solvent, diethylene glycol butyl ether acetate, diethylene glycol ethyl ether acetate, diethylene glycol butyl ether and tripropylene glycol methyl ether; the medium-boiling point low-polarity solvent is one or two of dipropylene glycol methyl ether, 100# solvent, ethylene glycol ethyl ether acetate and propylene glycol methyl ether acetate with the boiling point within the range of 100-200 ℃; the terpineol system varnish is a transparent mixed solution with resin and taking terpineol as a main fusing agent; the auxiliary agent is one or more of a dispersing agent, a flatting agent and an adhesion promoter.
Example 1:
a solvent type toughened glass ink diluent comprises the following raw material components in percentage by weight: 30% of high-boiling-point kerosene, 30% of dipropylene glycol methyl ether, 38% of terpineol system varnish and 2% of dispersant.
A preparation method of a solvent type toughened glass ink diluent specifically comprises the following steps:
step 1: mixing and stirring the high-boiling-point kerosene, the dipropylene glycol methyl ether and the terpineol system varnish according to the weight percentage, and adding a dispersing agent during stirring until a uniform transparent liquid is formed;
step 2: and (3) carrying out ultrasonic oscillation on the transparent liquid obtained by the treatment in the step (1) for 40min, and finally standing for 70min to obtain the diluent.
Example 2:
a solvent type toughened glass ink diluent comprises the following raw material components in percentage by weight: 35% of 200# solvent, 40% of propylene glycol methyl ether acetate, 20% of terpineol system varnish and 5% of adhesion promoter.
A preparation method of a solvent type toughened glass ink diluent specifically comprises the following steps:
step 1: mixing and stirring the 200# solvent, the propylene glycol methyl ether acetate and the terpineol system varnish according to the weight percentage, and adding the adhesion promoter during stirring until a uniform transparent liquid is formed;
step 2: and (3) carrying out ultrasonic oscillation on the transparent liquid obtained by the treatment in the step (1) for 60min, and finally standing for 55min to obtain the diluent.
Example 3:
a solvent type toughened glass ink diluent comprises the following raw material components in percentage by weight: 50% of diethylene glycol butyl ether, 20% of propylene glycol methyl ether acetate, 25% of terpineol system ink adjusting oil and 5% of flatting agent.
A preparation method of a solvent type toughened glass ink diluent specifically comprises the following steps:
step 1: mixing and stirring the diethylene glycol butyl ether, the propylene glycol methyl ether acetate and the terpineol system varnish according to the weight percentage, and adding the leveling agent during stirring until uniform and transparent liquid is formed;
step 2: and (3) carrying out ultrasonic oscillation on the transparent liquid obtained by the treatment in the step (1) for 50min, and finally standing for 65min to obtain the diluent.
The diluent prepared in the above example is applied to solvent type toughened glass ink, and the obtained ink is subjected to technical index detection, and the detection results are shown in table 1.
TABLE 1
TABLE 2
As can be seen from tables 1 and 2, the diluent prepared by the method disclosed by the invention has the advantages of small smell, good compatibility with various solvent system high-temperature sintered glass inks, appropriate volatilization speed, good leveling property and extremely high dilution efficiency, can improve the drying adhesion of the ink, has defoaming and foam inhibiting effects on the ink, and can be widely applied to the diluent of solvent type high-temperature sintered glass inks in the market.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above-described embodiments. Those skilled in the art should appreciate that many modifications and variations are possible in light of the above teaching without departing from the scope of the invention.
Claims (8)
1. The solvent type toughened glass ink diluent is characterized by comprising the following raw material components in percentage by weight: 30-50% of high-boiling point medium-low polarity solvent, 20-40% of medium-boiling point medium-low polarity solvent and 20-40% of terpineol system varnish.
2. The solvent-based toughened glass ink diluent as claimed in claim 1, wherein the raw material composition further comprises 0-5% of an auxiliary agent.
3. The solvent-based toughened glass ink diluent as claimed in claim 1, wherein the high-boiling point medium-low polar solvent is one or two of terpineol, high-boiling point kerosene, 200# solvent, diethylene glycol butyl ether acetate, diethylene glycol ethyl ether acetate, diethylene glycol butyl ether and tripropylene glycol methyl ether, the boiling point of which is 200 ℃ or higher.
4. The solvent-based toughened glass ink diluent as claimed in claim 1, wherein the medium-boiling point low-polarity solvent is one or two of dipropylene glycol methyl ether, 100# solvent, ethylene glycol ethyl ether acetate, propylene glycol methyl ether acetate with boiling points in the range of 100-200 ℃.
5. The solvent-based toughened glass ink diluent as claimed in claim 1, wherein said terpineol system varnish is a transparent mixed solution with resin and using terpineol as main flux.
6. The solvent-based toughened glass ink diluent as claimed in claim 2, wherein the auxiliary agent is one or more of a dispersant, a leveling agent and an adhesion promoter.
7. The preparation method of the solvent-based tempered glass ink diluent as claimed in claims 1-6, which is characterized by comprising the following steps:
step 1: mixing and stirring the high-boiling point medium-low polarity solvent, the medium-boiling point medium-low polarity solvent and the terpineol system varnish according to the weight percentage, and adding the auxiliary agent during stirring until uniform transparent liquid is formed;
step 2: and (3) carrying out ultrasonic oscillation on the transparent liquid obtained by the treatment in the step (1) for 40-60min, and finally standing to obtain the diluent.
8. The method for preparing the solvent-based toughened glass ink diluent as claimed in claim 7, wherein the standing time of step 2 is 55-70 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010940536.7A CN111995902A (en) | 2020-09-09 | 2020-09-09 | Solvent type toughened glass ink diluent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010940536.7A CN111995902A (en) | 2020-09-09 | 2020-09-09 | Solvent type toughened glass ink diluent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111995902A true CN111995902A (en) | 2020-11-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010940536.7A Pending CN111995902A (en) | 2020-09-09 | 2020-09-09 | Solvent type toughened glass ink diluent and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN111995902A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113416444A (en) * | 2021-08-05 | 2021-09-21 | 江苏冠军科技集团股份有限公司 | High-flash-point environment-friendly diluent and preparation method and application thereof |
| WO2024104498A1 (en) * | 2023-08-16 | 2024-05-23 | 黄山市晶特美新材料有限公司 | New solvent-type varnish for glass frit, and preparation method therefor |
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2020
- 2020-09-09 CN CN202010940536.7A patent/CN111995902A/en active Pending
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113416444A (en) * | 2021-08-05 | 2021-09-21 | 江苏冠军科技集团股份有限公司 | High-flash-point environment-friendly diluent and preparation method and application thereof |
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Application publication date: 20201127 |