CN111973491B - Oily hair cosmetic - Google Patents
Oily hair cosmetic Download PDFInfo
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- CN111973491B CN111973491B CN202010155635.4A CN202010155635A CN111973491B CN 111973491 B CN111973491 B CN 111973491B CN 202010155635 A CN202010155635 A CN 202010155635A CN 111973491 B CN111973491 B CN 111973491B
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- hair
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- oil
- hair cosmetic
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- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000005063 tetradecenyl group Chemical group C(=CCCCCCCCCCCCC)* 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 229940098385 triisostearin Drugs 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229940117972 triolein Drugs 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Abstract
Disclosed is an oily hair cosmetic which can impart a dry feel, hair-gathering properties, and hair luster to hair. [ MEANS FOR solving PROBLEMS ] an oily hair cosmetic comprising component (A): a silicone compound having a viscosity of 1000 to 3000 mPa.s at 25 ℃ and a component (B): vegetable oil and/or fatty acid triglyceride, and component (C): octyl polymethylsiloxane, the content of the component (A) is 0.3 to 5.0% by mass, the content of the component (B) is 7.0 to 50.0% by mass, and the content of the component (C) is 5.0 to 50.0% by mass.
Description
Technical Field
The present invention relates to an oily hair cosmetic.
Background
As a hair cosmetic for supplementing oil to hair and providing gloss, smoothness, etc., an oily hair cosmetic, i.e., hair oil, containing a liquid oily component as a main component is used. As such hair oils, for example, hair oils disclosed in patent document 1 are available.
Prior art literature
Patent literature
Patent document 1: japanese patent laid-open No. 2007-269726
Disclosure of Invention
Problems to be solved by the invention
As a conventional oily hair cosmetic, it is known that a high hair-gathering property is imparted to hair by blending a vegetable oil, and a glossy finish is obtained. In addition, it is also known that a dry touch feeling (dry touch feeling) with good finger passing property is imparted to hair by blending silicone having a high polymerization degree, and a light finish feeling is obtained.
Oily hair cosmetics that achieve high hair-gathering properties often have tackiness and a much heavier finish. On the other hand, oily hair cosmetics that give a dry feel are generally less returnable. Therefore, the high gathering property and the dry feel are characteristics of both lawyers, and the problem of achieving both of these characteristics is not known.
Furthermore, silicones with a high degree of polymerization are particularly poor in compatibility with vegetable oils, and oily hair cosmetics for which they have been used have not been obtained so far.
In view of the above, an object of the present invention is to provide an oily hair cosmetic capable of imparting a dry feel, hair-gathering properties, and hair luster to hair.
Means for solving the problems
As a result of intensive studies to achieve the above object, the present inventors have found that an oily hair cosmetic containing component (a): a silicone compound having a viscosity of 1000 to 3000 mPa.s at 25 ℃ and a component (B): vegetable oil and/or fatty acid triglyceride, and component (C): the content of the components (A) to (C) is within a specific range. The present invention has been completed based on these technical ideas.
Specifically, the present invention provides an oily hair cosmetic comprising the following component (A), the following component (B) and the following component (C), wherein the content of the component (A) is 0.3 to 5.0% by mass, the content of the component (B) is 7.0 to 50.0% by mass, and the content of the component (C) is 5.0 to 50.0% by mass.
Component (A): silicone compound having a viscosity of 1000 to 3000 mPa.s at 25 DEG C
Component (B): vegetable oil and/or fatty acid triglyceride
Component (C): octyl polymethylsiloxane
The oily hair cosmetic preferably further comprises the following component (D), and the content of the component (D) is 0.1 to 20.0 mass%.
Component (D): isononyl isononanoate and/or tridecyl isononanoate
The oily hair cosmetic preferably further comprises the following component (E), and the content of the component (E) is 0.1 to 30.0 mass%.
Component (E): phenyl modified silicones
The oily hair cosmetic preferably further comprises the following component (F), and the content of the component (F) is 3.0 to 80.0 mass%.
Component (F): volatile oil
ADVANTAGEOUS EFFECTS OF INVENTION
The oily hair cosmetic of the present invention can impart a dry feel, a hair-gathering property, and a hair luster to hair.
Detailed Description
The oily hair cosmetic of the present invention comprises at least a silicone compound having a viscosity of 1000 to 3000 mpa·s at 25 ℃; vegetable oils and/or fatty acid triglycerides; octyl polymethylsiloxane. In the present specification, a silicone compound having a viscosity of 1000 to 3000 mpa·s at 25 ℃ may be referred to as "component (a)", a vegetable oil and/or a fatty acid triglyceride may be referred to as "component (B)", and an octyl polymethylsiloxane may be referred to as "component (C)".
The oily hair cosmetic of the present invention preferably further comprises isononyl isononanoate and/or tridecyl isononanoate, and further preferably comprises a phenyl-modified silicone. In addition, volatile oils are preferably included. In the present specification, isononyl isononanoate and/or tridecyl isononanoate may be referred to as "component (D)", phenyl-modified silicone as "component (E)", and volatile oil as "component (F)".
That is, the oily hair cosmetic of the present invention contains at least component (a), component (B) and component (C). The oily hair cosmetic of the present invention may contain components other than the above components (a) to (C), for example, component (D), component (E), component (F) and components other than the components (a) to (F). The oily hair cosmetic of the present invention may contain only one component, for example, component (a), component (B), component (C), component (D), component (E), component (F), and other components, or may contain two or more components.
[ component (A) ]
The component (A) is a silicone compound having a viscosity of 1000 to 3000 mPas at 25 ℃. The oily hair cosmetic of the present invention can impart a dry feel to hair by blending the component (a). The component (A) may be used alone or in combination of two or more.
From the viewpoint of exhibiting the above-mentioned effects, the viscosity of the component (A) at 25℃is 1000 to 3000 mPas, preferably 1200 to 3000 mPas.
Examples of the component (a) include dimethiconol, dimethylpolysiloxane, and modified silicone. The dimethiconol refers to a material in which terminal methyl groups of dimethylpolysiloxane are replaced with hydroxyl groups. Examples of the modified silicone include polyether-modified silicone, amino-modified silicone, carboxyl-modified silicone, fatty acid-modified silicone, alcohol-modified silicone, fatty alcohol-modified silicone, epoxy-modified silicone, fluorine-modified silicone, and alkyl-modified silicone. As the modified silicone, amino-modified dimethylpolysiloxane is preferable.
Examples of commercially available polydimethylsiloxanols as component (A) include trade names "XF49-C2020", trade names "XF49-C2499", trade names "XF49-C2520", trade names "XF49-C4470", trade names "XF49-C2497", trade names "XF49-C4996", and trade names "XF49-C2070" (all manufactured by Momentive Performance Materials). Examples of commercial products of the dimethylpolysiloxane of the component (A) include trade names "XF49-811", trade names "XF49-813", trade names "XF49-D1747", trade names "XF49-B2317", and trade names "XF49-B1747" (all manufactured by Momentive Performance Materials).
The content of the component (a) in the oily hair cosmetic of the present invention is 0.3 to 5.0% by mass, preferably 0.4 to 4.0% by mass, and more preferably 0.5 to 3.0% by mass, relative to 100% by mass of the oily hair cosmetic of the present invention. When the content is 0.3 mass% or more, a dry feel can be imparted to hair. When the content exceeds 5.0% by mass, the hair cosmetic is insoluble in oily hair cosmetics and cannot be stably blended. The content ratio of the component (a) is the total content ratio of all the components (a) in the oily hair cosmetic of the present invention.
[ component (B) ]
Component (B) is vegetable oil and/or fatty acid triglyceride. By blending the component (B), the oily hair cosmetic of the present invention can impart high hair-gathering properties to hair. Further, the gloss exhibited by the blending component (C) can be further improved. The component (B) may be used alone or in combination of two or more.
Examples of the vegetable oil include macadamia nut oil, eucalyptus oil, coconut oil, avocado oil, safflower oil, olive oil, palm kernel oil, macadamia nut oil, shea butter (Shea butter), cocoa butter, almond oil, sunflower oil, rose fruit oil, olive squalane, camellia oil, kiwi seed oil, camellia oil, almond oil, sesame oil, soybean oil, jojoba oil, castor oil, hazelnut oil, meadowfoam oil, peppermint oil, mousse nut oil, carrot oil, lavender oil, squalane, satin rose wax, beancurd flower wax, square flower wax, camellia oil, crambe seed oil, and hydrogenated products thereof (e.g., hydrogenated castor oil, hydrogenated jojoba oil, hydrogenated palm oil, hydrogenated avocado oil, hydrogenated soybean oil).
The fatty acid triglyceride is preferably a fatty acid triglyceride having 6 to 22 carbon atoms, which is 1 or more constituent fatty acids.
Examples of the fatty acid triglycerides include tri-2-ethylhexanoic acid glyceride, tricaprylin, tricapran glyceride, triundecanoic acid glyceride, tristearin, triisostearin, tripalmitin glyceride, triundecanoic acid glyceride, tri-2-heptylundecanoic acid glyceride, tribenzylic acid glyceride, tripyritic acid glyceride, trilaurin glyceride, triolein, tripalmitin glyceride, triacetyl hydroxystearin glyceride, triacetyl ricinoleic acid glyceride, trihydroxy glyceryl stearate, tricaprylin/capric acid glyceride, tricaprylin/capric acid/myristic acid/stearic acid glyceride, tricaprylin/capric acid/lauric acid glyceride, tricaprylin/capric acid/linoleic acid glyceride, tricaprylin fatty acid glyceride, triglycerin fatty acid/fatty acid glyceride, triglycidyl fatty acid glyceride (C18-capric acid fatty acid glyceride, triglycidyl fatty acid glyceride, fatty acid glyceride (12-fatty acid triglyceride, and triglycidyl fatty acid glyceride (12-fatty acid glyceride), hydrogenated tri-fatty acid (C12-18) glycerides, tri-fatty acid (C12-20) glycerides, tri-fatty acid (C18-36) glycerides, tri-branched fatty acid (C10-40) glycerides, tri-branched fatty acid (C12-31) glycerides, (hydrogenated rosin/diisostearic acid) glycerides, tri (palm oil fatty acid/palm kernel oil fatty acid/olive oil fatty acid/rapeseed oil fatty acid) glycerides, tri (castor fatty acid/olive fatty acid) glycerides, tri (behenic acid/isostearic acid/eicosanoic) glycerides, tri (mink oil fatty acid/palmitic acid) glycerides, and the like.
The content of the component (B) in the oily hair cosmetic of the present invention is 7.0 to 50.0% by mass, preferably 12.0 to 45.0% by mass, more preferably 12.0 to 40.0% by mass, and even more preferably 12.0 to 30.0% by mass, relative to 100% by mass of the oily hair cosmetic of the present invention. By setting the content to 7.0 mass% or more, hair can be provided with hair-gathering properties. In addition, gloss can be improved. By setting the content to 50.0 mass% or less, the tackiness after coating can be suppressed. In addition, the compatibility of the component (a) can be improved. The content ratio of the component (B) is the total content ratio of all the components (B) in the oily hair cosmetic of the present invention.
[ component (C) ]
Component (C) is octyl polymethylsiloxane. By blending component (C), the compatibility of component (a) and component (B) can be promoted, and the oily hair cosmetic of the present invention can impart luster to hair. The component (C) may be used alone or in combination of two or more.
Octyl polymethylsiloxane is one type of alkyl-modified polysiloxane, and is a polysiloxane that contains, as silicon atoms constituting the main chain of the polysiloxane, silicon atoms to which octyl groups (n-octyl groups) are bonded within the polysiloxane chain. Component (C) is a compound denoted by the INCI name as "CAPRYLYL METHICONE". The component (C) is preferably a compound represented by the following formula (1).
[ chemical formula 1 ]
Examples of the commercial products of the component (C) include a product under the trade name "SILSOFT 034" (manufactured by Momentive Performance Materials Co., ltd.), a product under the trade name "FZ-3196", and a product under the trade name "SS-3408" (manufactured by Dow Toray Co., ltd.).
The content of the component (C) in the oily hair cosmetic of the present invention is 5.0 to 50.0% by mass, preferably 7.0 to 40.0% by mass, and more preferably 10.0 to 30.0% by mass, relative to 100% by mass of the oily hair cosmetic of the present invention. When the content is less than 5.0% by mass, the component (A) and the component (B) are not sufficiently compatible, and the stability of the preparation is poor. In addition, by 5.0 mass% or more, sufficient gloss can be imparted to hair. When the content exceeds 50.0 mass%, it is difficult to impart high furcation. The content ratio of the component (C) is the total content ratio of all the components (C) in the oily hair cosmetic of the present invention.
[ component (D) ]
Component (D) is isononyl isononanoate and/or tridecyl isononanoate. By compounding the component (D), the compatibility between the component (a) and the component (B) can be further improved. The component (D) may be used alone or in combination of two or more.
The content of the component (D) in the oily hair cosmetic of the present invention is not particularly limited, but is preferably 0.1 to 20.0% by mass, more preferably 0.5 to 15.0% by mass, and even more preferably 3.0 to 15.0% by mass, based on 100% by mass of the oily hair cosmetic of the present invention. When the content is 0.1 mass% or more, the compatibility of the component (A) and the component (B) is further improved. When the content is 20.0 mass% or less, the feel of the coated hair is further reduced and the feel of the hair is improved. (D) The content ratio of (D) is the total content ratio of all components (D) in the oily hair cosmetic of the present invention.
[ component (E) ]
Component (E) is a phenyl-modified silicone. By compounding the component (E), the compatibility between the component (A) and the component (B) can be further improved. In addition, the gloss can be further improved. The component (E) may be used alone or in combination of two or more.
Phenyl-modified silicone is a methylphenyl polysiloxane containing, as silicon atoms constituting the main chain of the polysiloxane, silicon atoms to which phenyl groups are bonded and silicon atoms to which methyl groups are bonded, within the polysiloxane chain. The component (E) may be a compound denoted by INCI name "DIPHENYLSILOXY PHENYL TRIMETHICONE", a compound denoted by "TRIMETHYLSILOXYPHENYL DIMETHICONE", a compound denoted by "DIPHENYL DIMETHICONE", or the like.
Component (E) is preferably liquid at 25 ℃. The viscosity of the component (E) at 25℃is preferably 10000 mPas or less (for example, 0.1 to 10000 mPas), more preferably 2000 mPas or less.
The content of the component (E) in the oily hair cosmetic of the present invention is not particularly limited, but is preferably 0.1 to 30.0% by mass, more preferably 0.5 to 20.0% by mass, and still more preferably 1.0 to 10.0% by mass, based on 100% by mass of the oily hair cosmetic of the present invention. When the content is 0.1 mass% or more, the compatibility of the component (A) and the component (B) is further improved. In addition, the gloss can be further improved. When the content is 30.0 mass% or less, the tackiness can be further suppressed. The content ratio of the component (E) is the total content ratio of all the components (E) in the oily hair cosmetic of the present invention.
[ component (F): volatile oil ]
Component (F) is an oil (oil component) having volatility at 25 ℃. The boiling point of the component (F) is, for example, 250℃or lower, preferably 230℃or lower. Component (F) can dissolve other components to apply to hair and volatilize after application. The component (F) does not include the component (C) and the component (E). The component (F) may be used alone or in combination of two or more.
Examples of the component (F) include cyclic silicone oil, methyl trimethicone, ethyl trisiloxane, hydrocarbon oil, and dimethylpolysiloxane having a viscosity of 0.1 to 2.0 mPas at 25 ℃. Examples of the cyclic silicone oil include methyl cyclopolysiloxane, octamethyl cyclotetrasiloxane, decamethyl cyclopentasiloxane, and dodecamethyl cyclohexasiloxane. Examples of the hydrocarbon oil include isoparaffins, light mobile isoparaffins, hydrogenated polyisobutene, hydrogenated (tetradecenyl/methylpentadecene), and isododecane.
The content of the component (F) in the oily hair cosmetic of the present invention is not particularly limited, but is preferably 3.0 to 80.0 mass%, more preferably 5.0 to 70.0 mass%, and even more preferably 15.0 to 50.0 mass% with respect to 100 mass% of the oily hair cosmetic of the present invention, in view of exhibiting a function as a base for dissolving other components. The content ratio of the component (F) is the total content ratio of all the components (F) in the oily hair cosmetic of the present invention.
[ other Components ]
The oily hair cosmetic of the present invention may contain components (other components) other than the above components (a) to (F) within a range that does not hinder the object of the present invention. The other components are not particularly limited, and examples thereof include components commonly used in cosmetics and quasi drugs. Specifically, examples thereof include: lower alcohols such as ethanol; a polyol; oily components (other oily components) other than the components (a) to (F); nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, and the like; thickening agents such as carboxyvinyl polymer, acrylic acid/alkyl methacrylate copolymer, hydroxymethyl cellulose, hydroxypropyl methylcellulose, and xanthan gum; a humectant; a germicide; a pearlizing agent; antiinflammatory agents such as glycyrrhizic acid and its salts; cooling agents such as menthol; phosphoric acid and its salts, citric acid and its salts, lactic acid and its salts, sodium hydroxide, triethanolamine and other pH regulator; a perfume; an ultraviolet absorber; an antioxidant; chelating agents (Chelating agents); a film-forming polymer compound such as polyvinylpyrrolidone; powder of kaolin, silica, talc, etc.; a pigment; a pigment; vitamins; amino acids; an astringent; a whitening agent; an animal and plant extract; an acid; alkali, and the like.
Examples of the other oily component include waxes other than the components (a) to (F), hydrocarbon oils, ester oils, silicone oils, higher alcohols, higher fatty acids, and the like. By blending the above-mentioned other oily components, the properties of the composition, the feel at the time of application, moisture retention, and the like can be appropriately adjusted.
The content of water in the oily hair cosmetic of the present invention is not particularly limited, but is preferably 3.0% by mass or less, more preferably 1.5% by mass or less, based on 100% by mass of the oily hair cosmetic of the present invention.
The oily hair cosmetic of the present invention is not particularly limited, and can be produced by a known or conventional method. For example, the above components may be mixed and stirred with a homomixer, impeller mixer, or the like.
The oily hair cosmetic of the present invention is so-called hair oil. Examples of the oily hair cosmetic of the present invention include leave-in hair conditioners and hair styling agents. The oily hair cosmetic of the present invention is used for the following purposes: the aim of arranging the hair by inhibiting the hair from spreading; the purpose of providing shine to hair; the aim of providing a dry feel to the hair; the aim of improving the finger passing property of hair; protecting hair from heat of a hair dryer or hair iron, etc.
The method of using the oily hair cosmetic of the present invention is not particularly limited, and examples thereof include the following methods. (i) After washing hair and drying with a towel, an appropriate amount of the oily hair cosmetic of the present invention is applied to the hair in whole or in part, and dried with a blower or the like. (ii) The oily hair cosmetic of the present invention is applied to dry hair or slightly wet hair in an appropriate amount in whole or in part, and the hair is finished by using a hair iron or the like as needed. The oily hair cosmetic of the present invention may be used in combination with other hair styling agents to style hair.
In the oily hair cosmetic of the present invention, a silicone compound [ component (a) ] having a viscosity of 1000 to 3000 mpa·s at 25 ℃ and a vegetable oil and/or a fatty acid triglyceride [ component (B) ] are used as oily components in specific proportions. In general, the compatibility of the component (a) and the component (B) is poor, and it is difficult to sufficiently exhibit the respective functions only by mixing them. In contrast, in the present invention, by blending octyl polymethylsiloxane [ component (C) ] in a specific ratio, the compatibility of component (A) and component (B) is drastically improved. Thus, the oily hair cosmetic of the present invention can exert both the effect of the component (a) of imparting a dry feel to hair and the effect of the component (B) of imparting a hair-gathering property, and it is presumed that the refractive index of the hair cosmetic is increased by further blending the component (C), but sufficient gloss can be imparted to hair.
Examples
Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to these examples. The blending amount described in the table is the blending amount of each component (i.e., the blending amount of the active ingredient in each raw material, the pure ingredient), and unless otherwise specified, the blending amount is expressed as "mass%.
Examples 1 to 21 and comparative examples 1 to 7
Each hair cosmetic of examples and comparative examples was prepared by a conventional method using each component (components (a) to (F) and the like) described in the table.
The main components described in the table are as follows.
< component (A) >
High-polymerization dimethylpolysiloxane (about 1800 ten thousand mPa.s): trade name "XF49-811", manufactured by Momentive Performance Materials company, viscosity at 25℃of about 1800 ten thousand mPa.s
High-polymerization dimethylpolysiloxane (about 1300 thousand mPa.s): trade name "XF49-B1747", manufactured by Momentive Performance Materials company, viscosity at 25℃of about 1300 ten thousand mPa.s
High-polymerization polydimethyl siloxane alcohol (about 1800 ten thousand mpa·s): trade name "XF49-C2020", manufactured by Momentive Performance Materials company, viscosity at 25℃of about 1800 ten thousand mPa.s
< component (C) >
Octyl polymethylsiloxane a: trade name "SILSOFT 034", manufactured by Momentive Performance Materials Co
Octyl polymethylsiloxane B: trade names "SS-3408", dow Toray co., ltd
< component (E) >
Methyl phenyl polysiloxane: trade name "KF-56", manufactured by Xinyue chemical industry Co., ltd
Trimethylsiloxyphenyl trimethicone a: trade names "BELSIL PDM20", wacker Asahikasei Silicone Co., ltd
Trimethylsiloxyphenyl trimethicone B: trade names "BELSIL PDM1000", wacker Asahikasei Silicone Co., ltd
< other ingredients >
Polydimethylsiloxane (350 mPas): trade names "DOWSIL SH200C-FLUID 350cs", dow Toray Co., ltd. Manufactured, viscosity 350 mPa.s at 25 ℃
Mineral oil a: trade name "liquid Paraffin No.380", manufactured by Sanremo Industrial Co., ltd
Mineral oil B: trade name "CARNATION #70", manufactured by Sonneborn Inc
Amino terminal polydimethylsiloxane: trade names "SS-3551", dow Toray co., ltd
Bis (hydroxy/methoxy) amino terminal polydimethylsiloxane: trade names "AP-8087Fluid", dow Toray Co., ltd
(evaluation)
The hair cosmetics obtained in examples and comparative examples were evaluated as follows. The evaluation results are shown in the table. For the samples having poor stability of the preparation, no other evaluation was performed. Evaluation was performed by 3 panelists.
(1) Dry feel
After bleaching the hair tresses (hair tresses having a length of 30cm, a weight of 10g, and a complete cuticle) with hydrogen peroxide and ammonia, the hair tresses were rinsed with shampoo, applied with conditioner and rinsed. Further, the resultant was dried with a blower to prepare a sample hair bundle ("sample hair bundle before coating").
Approximately 0.3g of each of the hair cosmetics obtained in examples and comparative examples was uniformly applied to the sample hair bundle before the application, and dried with a blower for 3 minutes to prepare a hair bundle coated with the hair cosmetics ("sample hair bundle after the application").
The sample hair tresses before and after coating were passed through the fingers from the upper part to the lower part of the hair tresses, and whether or not the fingers were caught or not was checked.
[ criterion ]
O (good): the feel to which the finger was caught was significantly reduced as compared with the test piece hair tresses before coating, and the finger passability was good.
X (bad): the feel of the finger caught was the same as that of the test piece hair tress before coating, or the feel was stronger than that of the test piece hair tress before coating.
(2) Hair-gathering property and luster
After the evaluation of (1), the applied sample hair tresses were visually observed, and the hair-gathering property and gloss were determined according to the following criteria.
[ criterion for judging hair-gathering Property ]
O (good): the hair bundle is not unfolded downwards, the hair bundle is integrally gathered, and then the front end part of the hair bundle is gathered.
Delta (usable): the hair bundle is not unfolded downwards, the hair bundle is integrally gathered, but the front end part of the hair bundle is slightly not gathered.
X (bad): the hair bundle is obviously unfolded downwards as a whole.
[ criterion for determining gloss ]
O (good): when the light irradiates the hair, the hair has a luster of reflecting the glaring light.
X (bad): no gloss or, although glossy, no glaring light is reflected when the light strikes the hair.
(3) Formulation stability
The properties of each hair cosmetic obtained in examples and comparative examples (after 3 days of preparation) were visually observed, and the hair cosmetic was evaluated according to the following criteria.
[ criterion for judging stability of preparation ]
O (good): without separation, is uniform.
X (bad): separation and non-uniformity are observed
The oily hair cosmetic (example) of the present invention was evaluated as excellent in formulation stability, dry feel, returnability, and gloss. On the other hand, when the component (a) was not blended (comparative example 1) and when a silicone compound having a viscosity of less than 1000 ten thousand mpa·s at 25 ℃ was blended instead of the component (a) (comparative example 2), the dry feel was poor. In addition, when the blending amount of the component (a) is large (comparative example 3), the stability of the preparation is poor. In the case where the component (B) was not blended (comparative example 4) and in the case where the component (B) was not blended and the amount of isononyl isononanoate was increased (comparative example 5), the furcation was poor. In comparative example 5, the dry feel was poor, and the applied test piece had a rough feel and a poor touch. When the component (a) and the component (C) are not blended (comparative example 6), the dry feel and gloss are poor. When the component (C) is not blended (comparative example 7), the stability of the preparation is poor.
Further, the following shows examples of the formulation of the oily hair cosmetic of the present invention.
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Claims (4)
1. An oily hair cosmetic comprising (A) 0.3 to 5.0% by mass of (B) 12.0 to 50.0% by mass of (C) 10.0 to 30.0% by mass of (C),
component (A): a silicone compound having a viscosity of 1000 to 3000 mPa.s at 25 ℃;
component (B): vegetable oils and/or fatty acid triglycerides;
component (C): octyl polymethylsiloxane.
2. The oily hair cosmetic according to claim 1, further comprising a component (D) in an amount of 0.1 to 20.0% by mass,
component (D): isononyl isononanoate and/or tridecyl isononanoate.
3. The oily hair cosmetic according to claim 1 or 2, further comprising a component (E) contained in an amount of 0.1 to 30.0% by mass,
component (E): phenyl-modified silicones.
4. The oily hair cosmetic according to any one of claim 1 to 3, further comprising a component (F) contained in an amount of 3.0 to 80.0% by mass,
component (F): volatile oils.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
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| JP2019097696 | 2019-05-24 | ||
| JP2019-097696 | 2019-05-24 | ||
| JP2020-002844 | 2020-01-10 | ||
| JP2020002844A JP7335171B2 (en) | 2019-05-24 | 2020-01-10 | oily hair cosmetics |
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| CN111973491A CN111973491A (en) | 2020-11-24 |
| CN111973491B true CN111973491B (en) | 2024-02-02 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20150050387A (en) * | 2013-10-29 | 2015-05-08 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Aqueous dispersion of silicone rubber particle, silicone rubber particle, and cosmetics |
| JP2017137250A (en) * | 2016-02-02 | 2017-08-10 | 株式会社アリミノ | Hairdressing composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP4584340B2 (en) * | 2009-04-27 | 2010-11-17 | 株式会社資生堂 | Oil-in-water emulsified hair cosmetic |
| JP6804420B2 (en) * | 2017-09-28 | 2020-12-23 | 株式会社マンダム | Hair cosmetics |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20150050387A (en) * | 2013-10-29 | 2015-05-08 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Aqueous dispersion of silicone rubber particle, silicone rubber particle, and cosmetics |
| JP2017137250A (en) * | 2016-02-02 | 2017-08-10 | 株式会社アリミノ | Hairdressing composition |
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