CN111929924A - Goggles suitable for all-weather wearing and preparation method thereof - Google Patents

Goggles suitable for all-weather wearing and preparation method thereof Download PDF

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CN111929924A
CN111929924A CN202011003328.0A CN202011003328A CN111929924A CN 111929924 A CN111929924 A CN 111929924A CN 202011003328 A CN202011003328 A CN 202011003328A CN 111929924 A CN111929924 A CN 111929924A
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film layer
reflection film
substrate
layer
goggles
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李振声
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    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/10Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
    • G02C7/108Colouring materials
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/113Anti-reflection coatings using inorganic layer materials only
    • G02B1/115Multilayers
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Ophthalmology & Optometry (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Eyeglasses (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Optical Elements (AREA)

Abstract

The goggles comprise a high-reflection film layer and an anti-reflection and anti-reflection film layer, wherein the high-reflection film layer is positioned on the surface, far away from eyes, of a substrate, and the anti-reflection and anti-reflection film layer is positioned on the surface, close to the eyes, of the substrate. The preparation method comprises the following steps: preparing a substrate; respectively forming hard coatings on two surfaces of the substrate by adopting a dip-coating thermosetting process; forming the high-reflection film layer and the anti-reflection film layer on the substrate by adopting a vacuum electronic coating process; and plating a hydrophobic oil-repellent layer on the surface of the high-reflection film layer and the surface of the anti-reflection film layer by adopting a vacuum electronic coating process. The goggles can make the golfer clearly see the height fluctuation, the grass line and the gradient of the green.

Description

Goggles suitable for all-weather wearing and preparation method thereof
Technical Field
The invention relates to the field of goggles, in particular to goggles suitable for being worn by a golfer all the time, and relates to a preparation method of the goggles.
Background
Existing sun protection eyewear generally provides only 100% UV400 protection, about 30-50% blue light resistance, and dimming of light. Other sunglasses specifically designed for golf are only suitable for use with specific light sources, such as: some light transmittance is only 10-15%, the lens is only suitable for being used in violent sunlight, and the light source can not be less than 6000 lumens; on the contrary, some light transmittance is up to 40%, only applicable to cloudy days, and the light source can not exceed 4000 lumens; some of the selected colors are bright, so that the emotion of the player is excited within 4 to 5 hours in the court, thereby not only influencing the exertion of the skill of the player, but also increasing the fatigue after the competition. Polariscope is also a popular type of sunglasses, but it is only suitable for waterborne activities and the lenses have a feeling of distance disparity.
Disclosure of Invention
It is a first object of the present invention to provide goggles adapted for all weather wear that enable a golfer to see the undulations, grass lines and slopes of a green.
A second object of the invention is to increase visual comfort.
A third object of the invention is to further improve the hardness and wear resistance of the lens.
A fourth object of the present invention is to further make the surface of the goggle less prone to adhesion of water drops, fingerprints, oil stains, and the like.
A fifth object of the present invention is to provide a method of manufacturing goggles.
In order to achieve the first purpose, the goggles provided by the invention comprise a high-reflection film layer and an anti-reflection film layer, wherein the high-reflection film layer is positioned on the surface of the substrate far away from the eyes, and the anti-reflection film layer is positioned on the surface of the substrate near the eyes.
On one hand, the anti-reflection film layer is arranged on the surface of the substrate close to eyes, so that light from the back can directly penetrate through the lens, and the light is prevented from being reflected by the lens to enter the eyes; on the other hand, the high-reflection film layer is arranged on the surface of the substrate far away from the eyes, so that most of reflected light which makes objects and images fuzzy can be isolated, and the two reflected light layers are combined, so that the problem of poor vision caused by reflecting light with multiple angles and different reflection rates due to the fact that the surface of the object is not an absolute plane is solved, a wearer can see the objects more clearly and three-dimensionally, and a golfer can see the high-low fluctuation, the grass marks and the gradient of the green clearly. Meanwhile, the high-reflection film layer and the anti-reflection film layer are combined, so that the light transmittance of the lens is 27% -29%, and a light source with ground reflection ranging from 10 lumens to 100000 lumens does not influence the vision, and the lens is suitable for being worn all the day long.
Preferably, the high-reflection film layer comprises a plurality of silicon dioxide layers and a plurality of titanium pentoxide layers, the overall thickness is between 1 and 3 micrometers, more preferably 2 micrometers, and the silicon dioxide layers and the titanium pentoxide layers are alternately arranged; the antireflection film layer comprises a plurality of silicon dioxide layers and a plurality of titanium pentoxide layers, the whole thickness of the antireflection film layer is between 0.7 and 0.9 microns, more preferably 0.8 micron, and the silicon dioxide layers and the titanium pentoxide layers are alternately arranged. The high-reflection film layer with the thickness can separate 80% of irregular reflection, so that the object distance is more real and three-dimensional, and the visual effect is better. The anti-reflection film layer makes the reflectivity less than 1%.
To achieve the second object, the substrate in the above goggles is configured such that the substrate includes the following components: resins, yellow pigments, green pigments, blue pigments, violet pigments, and orange pigments.
Preferably, the substrate further comprises a light wave absorbent including a first light wave absorbent for absorbing 580nm light waves and a second light wave absorbent for absorbing 490nm light waves.
Preferably, the contents of the respective components constituting the base sheet are as follows by weight:
Figure BDA0002695066560000021
Figure BDA0002695066560000031
by the configuration of the substrate color, the visual comfort level is increased, so that a player feels on a natural grassland after wearing the sole, the mood is pleasant, and the swing technology is more favorably developed. Can prevent 100% UV400 and 88% UV430, and better protect eyes.
In order to achieve the third object, a hard coating for improving the hardness and wear resistance of the surface of the substrate is further disposed between the high reflection film layer and the substrate of the goggles, and between the anti-reflection film layer and the substrate.
In order to achieve the fourth purpose, a hydrophobic oil-repellent layer is further arranged on the surface of the high-reflection film layer and the surface of the anti-reflection film layer of the goggles.
To achieve the fifth objective, the present invention provides a method for manufacturing goggles, comprising the following steps:
step one, preparing a substrate;
weighing the following raw materials in parts by weight: 1000 parts of resin, 0.010859 parts of first light wave absorbent, 0.010859 parts of second light wave absorbent, 0.038998 parts of yellow pigment, 0.041715 parts of green pigment, 0.014272 parts of blue pigment, 0.024569 parts of purple pigment and 0.0021 part of orange pigment, wherein the wavelength of the first light wave is 580nm, and the wavelength of the second light wave is 490 nm;
uniformly stirring the raw materials, performing injection molding, and then sequentially cleaning, strengthening and drying to obtain a substrate;
step two, adopting a dip-coating thermosetting process to respectively form hard coatings on two surfaces of the substrate;
step three, adopting a vacuum electronic coating process to alternately coat a silicon dioxide layer and a titanium pentoxide layer on the surface far away from eyes to form a high-reflection film layer with the thickness of 2 microns; alternately plating a silicon dioxide layer and a titanium pentoxide layer on the surface close to eyes to form an antireflection film layer with the thickness of 0.8 micrometer;
and step four, plating a hydrophobic oil-repellent layer on the surface of the high-reflection film layer and the surface of the anti-reflection film layer by adopting a vacuum electronic coating process.
In the above goggles manufacturing method, preferably, the following steps are sequentially included in the vacuum electronic plating process: ultrasonic cleaning, electrostatic gun cleaning, baking in oven, coating film on frame, vacuum pumping to 7.0 × 10-5Pa, cleaning and roughening with an ion gun, and continuing to evacuate to 3.5X 10-5Pa, coating the film by working of an electron gun.
Compared with the prior art, the invention has at least the following beneficial effects:
is suitable for all-weather wearing. The light transmittance is 27% -29%, and the light source with the ground reflection between 10 lumens and 100000 lumens does not affect the vision.
The lens can be directly penetrated by the light from the rear, and the poor vision caused by the reflection of light with multi-angle and different reflection rate can be isolated due to the non-absolute plane of the surface of the object, so that the wearer can see the object more clearly and stereoscopically, and the golf can clearly see the fluctuation, the grass lines and the gradient of the putting green.
The visual comfort level is increased, so that the wearer feels on the natural grassland and the mood is relaxed.
Drawings
FIG. 1 is a schematic diagram of the components of an embodiment of eyewear;
reference numerals: 1. a substrate; 2. hardening the layer; 3. a highly reflective film layer; 4. an anti-reflection film layer; 5. hydrophobic and oil-phobic layer.
Detailed Description
The invention is further illustrated with reference to the following figures and examples.
Referring to fig. 1, the goggles comprise a high-reflection film layer and an antireflection film layer, wherein the high-reflection film layer is positioned on the surface, far away from eyes, of a substrate, and the antireflection film layer is positioned on the surface, close to the eyes, of the substrate. Hard coatings for improving the hardness and the wear resistance of the surface of the substrate are further arranged between the high-reflection film layer and the substrate and between the anti-reflection film layer and the substrate. And the surfaces of the high-reflection film layer and the anti-reflection film layer are also provided with hydrophobic oil-repellent layers.
Wherein, the high reflection film layer is composed of silicon dioxide layers and titanium pentoxide layers which are alternately arranged, and the whole thickness is 2 microns. The anti-reflection film layer is also composed of silicon dioxide layers and titanium pentoxide layers which are alternately arranged, and the whole thickness is 0.8 microns. In the embodiment of fig. 1, starting from the substrate, the highly reflective film layer is formed by the following steps: silicon dioxide layer, titanium oxide layer, silicon dioxide layer. Starting from a substrate, the antireflection film layer sequentially comprises the following components: silicon dioxide layer, titanium trioxide layer, silicon dioxide layer.
Wherein the substrate comprises the following components: resin, yellow (code 8416) pigment, green (code 9002) pigment, blue (code 634) pigment, violet (code 4401) pigment and orange (code 8404) pigment. Also comprises a first light wave absorbent for absorbing 580nm light wave and a second light wave absorbent for absorbing 490nm light wave. The resin is preferably polycarbonate (polycarbonates). The contents of the components constituting the base sheet by weight are as follows:
Figure BDA0002695066560000051
the hard coating is an optical material for improving the hardness and abrasion resistance of the lens surface. The material of the hard coating is preferably HC-3800 material produced by Japanese fine works, and the main component is organosilicon.
The hydrophobic and oleophobic layer is used for endowing the surface of the lens with super-hydrophobic and oleophobic performances, and adopts fluorine modified high-molecular nano material containing active siloxane groups. The hydrophobic oil-repellent layer is preferably made of Korean EnSH-HT material.
The first light wave absorbent is used for absorbing 580nm light waves. The first light wave absorbent is preferably 580nm light wave absorbent of Lanxess, Germany, and the main component is macromolecular phthalocyanine compound.
The second light wave absorbent is used for absorbing 490nm light waves. The second light wave absorbent is preferably 490nm light wave absorbent of Lanxess, Germany, and the main component is macromolecular azo nickel metal compound.
The preparation method of the goggles comprises the following steps:
step one, preparing a substrate;
weighing the raw materials in parts by weight;
uniformly stirring the raw materials, performing injection molding at 280-290 ℃, ultrasonically cleaning with pure water at 60 ℃, strengthening at room temperature of 18 ℃, liquid temperature of 15 ℃ and humidity of no more than 45%, pre-drying at 70 ℃ for 20-30 minutes, and drying at 120 ℃ for 3 hours to obtain a substrate;
step two, adopting a dip-coating thermosetting process to respectively form hard coatings on two surfaces of the substrate;
step three, adopting a vacuum electronic coating process, and alternately coating a silicon dioxide layer and a titanium pentoxide layer on the surface of the substrate treated in the step two, which is far away from eyes to form a high-reflection film layer with the thickness of 2 microns; alternately plating a silicon dioxide layer and a titanium pentoxide layer on the surface close to eyes to form an antireflection film layer with the thickness of 0.8 micrometer;
and step four, plating a hydrophobic oil-repellent layer on the surface of the high-reflection film layer and the surface of the anti-reflection film layer by adopting a vacuum electronic coating process.
Wherein, in the vacuum electronic coating process, the lens is firstly cleaned by ultrasound, then cleaned by an electrostatic gun, transferred into an oven for drying, then placed in a coating frame in order, placed in a vacuum chamber, and vacuumized to 7.0 multiplied by 10-5When Pa, the ion gun starts to work, and the surface of the lens is cleaned and roughened; then continuing to vacuumize to 3.5 multiplied by 10-5And when Pa is needed, the electron gun works and alternately plates the silicon dioxide layer and the titanium pentoxide layer.
The present invention has been described in detail with reference to the specific embodiments, and the detailed description is only for the purpose of helping those skilled in the art understand the present invention, and is not to be construed as limiting the scope of the present invention. Various modifications, equivalent changes, etc. made by those skilled in the art under the spirit of the present invention shall be included in the protection scope of the present invention.

Claims (9)

1. The goggles are characterized by comprising a high-reflection film layer and an anti-reflection film layer, wherein the high-reflection film layer is positioned on the surface, far away from eyes, of a substrate, and the anti-reflection film layer is positioned on the surface, close to the eyes, of the substrate.
2. Eyewear according to claim 1, wherein the substrate comprises the following components: resins, yellow pigments, green pigments, blue pigments, violet pigments, and orange pigments.
3. The goggle of claim 2 wherein the substrate further comprises a light wave absorber comprising a first light wave absorber for absorbing 580nm light waves and a second light wave absorber for absorbing 490nm light waves.
4. Goggles as claimed in claim 3, characterized in that the contents of the components constituting said substrate are, by weight:
Figure FDA0002695066550000011
5. the goggles as claimed in claim 1, wherein hard coatings for improving the hardness and abrasion resistance of the surface of the substrate are further provided between the high-reflection film layer and the substrate and between the antireflection film layer and the substrate.
6. Eyewear in accordance with claim 1,
the high-reflection film layer comprises a plurality of silicon dioxide layers and a plurality of titanium pentoxide layers, the overall thickness of the high-reflection film layer is between 1 and 3 micrometers, and the silicon dioxide layers and the titanium pentoxide layers are alternately arranged;
the antireflection film layer comprises a plurality of silicon dioxide layers and a plurality of titanium pentoxide layers, the whole thickness is between 0.7 and 0.9 microns, and the silicon dioxide layers and the titanium pentoxide layers are alternately arranged.
7. The goggles as claimed in claim 1, wherein the surface of said high-reflection film layer and the surface of said antireflection film layer are further provided with hydrophobic and oleophobic layers.
8. A method for making goggles, comprising the steps of:
step one, preparing a substrate;
weighing the following raw materials in parts by weight: 1000 parts of resin, 0.010859 parts of first light wave absorbent, 0.010859 parts of second light wave absorbent, 0.038998 parts of yellow pigment, 0.041715 parts of green pigment, 0.014272 parts of blue pigment, 0.024569 parts of purple pigment and 0.0021 part of orange pigment, wherein the wavelength of the first light wave is 580nm, and the wavelength of the second light wave is 490 nm;
uniformly stirring the raw materials, performing injection molding, and then sequentially cleaning, strengthening and drying to obtain a substrate;
step two, adopting a dip-coating thermosetting process to respectively form hard coatings on two surfaces of the substrate;
step three, adopting a vacuum electronic coating process to alternately coat a silicon dioxide layer and a titanium pentoxide layer on the surface far away from eyes to form a high-reflection film layer with the thickness of 1-3 microns; alternately plating a silicon dioxide layer and a titanium pentoxide layer on the surface close to eyes to form an antireflection film layer with the thickness of 0.7-0.9 micrometer;
and step four, plating a hydrophobic oil-repellent layer on the surface of the high-reflection film layer and the surface of the anti-reflection film layer by adopting a vacuum electronic coating process.
9. The method of claim 8 wherein the vacuum electro-deposition process comprises the following steps in sequence: ultrasonic cleaning, electrostatic gun cleaning, baking in oven, coating film on frame, vacuum pumping to 7.0 × 10-5Pa, cleaning and roughening with an ion gun, and continuing to evacuate to 3.5X 10-5Pa, coating the film by working of an electron gun.
CN202011003328.0A 2020-09-22 2020-09-22 Goggles suitable for all-weather wearing and preparation method thereof Pending CN111929924A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112609161A (en) * 2020-11-20 2021-04-06 厦门腾诺光学科技有限公司 Preparation method of seawater corrosion resistant coated lens
CN113667166A (en) * 2021-08-23 2021-11-19 江苏全真光学科技股份有限公司 High-contrast high-definition lens and preparation method thereof
US11464678B1 (en) * 2022-04-03 2022-10-11 Chun Sing Lee Goggle lens suitable for golfers to wear all-weather and method of manufacturing the same
WO2022252038A1 (en) * 2021-05-31 2022-12-08 李振声 All-weather high-definition lens suitable for golf and preparation method therefor

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2718611Y (en) * 2004-05-18 2005-08-17 温州众生科技有限公司 Protective goggles lens for blue-lightproof driving
CN104280792A (en) * 2013-07-03 2015-01-14 上海舒曼光学有限公司 Spectacle lens antireflection film layer and manufacturing method thereof
CN208314363U (en) * 2018-06-28 2019-01-01 江苏万新光学有限公司 A kind of resin lens suitable for driving
CN208654467U (en) * 2018-11-16 2019-03-26 江苏万新光学有限公司 A kind of anti-blue light resin lens
CN110703363A (en) * 2019-10-24 2020-01-17 明灏科技(北京)有限公司 Lens coating processing technology, lens and computer storage medium
CN212364751U (en) * 2020-09-22 2021-01-15 李振声 Goggles suitable for all-weather wearing

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2718611Y (en) * 2004-05-18 2005-08-17 温州众生科技有限公司 Protective goggles lens for blue-lightproof driving
CN104280792A (en) * 2013-07-03 2015-01-14 上海舒曼光学有限公司 Spectacle lens antireflection film layer and manufacturing method thereof
CN208314363U (en) * 2018-06-28 2019-01-01 江苏万新光学有限公司 A kind of resin lens suitable for driving
CN208654467U (en) * 2018-11-16 2019-03-26 江苏万新光学有限公司 A kind of anti-blue light resin lens
CN110703363A (en) * 2019-10-24 2020-01-17 明灏科技(北京)有限公司 Lens coating processing technology, lens and computer storage medium
CN212364751U (en) * 2020-09-22 2021-01-15 李振声 Goggles suitable for all-weather wearing

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112609161A (en) * 2020-11-20 2021-04-06 厦门腾诺光学科技有限公司 Preparation method of seawater corrosion resistant coated lens
WO2022252038A1 (en) * 2021-05-31 2022-12-08 李振声 All-weather high-definition lens suitable for golf and preparation method therefor
CN113667166A (en) * 2021-08-23 2021-11-19 江苏全真光学科技股份有限公司 High-contrast high-definition lens and preparation method thereof
US11464678B1 (en) * 2022-04-03 2022-10-11 Chun Sing Lee Goggle lens suitable for golfers to wear all-weather and method of manufacturing the same

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Application publication date: 20201113