CN111909801A - Low-foam deoiling concentrated surfactant composition - Google Patents
Low-foam deoiling concentrated surfactant composition Download PDFInfo
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- CN111909801A CN111909801A CN202010907494.7A CN202010907494A CN111909801A CN 111909801 A CN111909801 A CN 111909801A CN 202010907494 A CN202010907494 A CN 202010907494A CN 111909801 A CN111909801 A CN 111909801A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Abstract
The invention provides a low-foam deoiling concentrated surfactant composition which comprises the following components in parts by weight: 30-40 parts of polyoxyethylene fatty alcohol ether, 15-20 parts of polyoxyethylene oleate, 5-10 parts of sodium lauroyl sarcosinate, 5-8 parts of deoiling component, 3-7 parts of sodium alginate, 1-2 parts of flavonoid-containing plant extract, 1-5 parts of suspending agent, 1-2 parts of essence and 1-8 parts of water; the deoiling component consists of a sulfonate surfactant, an alkyl polyglycoside surfactant and citric acid. The concentrated surfactant composition has excellent cleaning capacity, less foam, high deoiling capacity and low material cost.
Description
Technical Field
The invention relates to the technical field of surfactants, in particular to a low-foam deoiling concentrated surfactant composition.
Background
The surfactant is a substance which can obviously reduce the interfacial tension when the addition amount is small, and the molecule of the surfactant has a unique structure: one end is a hydrophilic polar group and the other end is a lipophilic non-polar group, also known as an amphipathic molecule. Can spontaneously form stable and orderly arranged association structures such as micelles, lyotropic liquid crystals, microemulsions, vesicles, vermicular micelles, microemulsion gels and the like in a solution. Widely applied to various aspects of human production and life, commonly known as industrial monosodium glutamate.
However, surfactants generally have foaming properties which contribute to their application in the fields of daily chemicals such as toothpaste, bath foam, laundry detergent, shampoo, etc., but in many industrial fields, particularly in the field of high-tech material development, or in zero-emission industrial production of water recycling, such foams cause fatal damage, leading to problems of poor application properties of materials, or interruption of production and processing of materials due to foam, or water pollution of production processes of materials due to foam, aggravating wastewater treatment burden, etc. In order to reduce foams generated in the use of the surfactant, industrial product manufacturers using the surfactant often add various types of defoaming agents, so that the industrial production cost is increased, the self biodegradability of the defoaming agent is poor, the defoaming agent is accumulated in zero-emission circulating water for a long time, and the COD (chemical oxygen demand) and BOD (biochemical oxygen demand) in the water are increased, so that the difficulty and the cost of later-stage water treatment are increased.
In addition, the common surfactant has the problem of insufficient degreasing property, and has poor degreasing effect on petroleum and the like. Therefore, a need exists for a surfactant composition that has less lather and greater oil removal.
Disclosure of Invention
In view of the above problems, the present invention provides a low-foam degreasing concentrated surfactant composition having excellent cleaning ability, less foam, high degreasing ability, and low material cost.
In order to achieve the purpose, the invention is solved by the following technical scheme:
a low-foam degreasing concentrated surfactant composition comprises the following components in parts by weight: 30-40 parts of polyoxyethylene fatty alcohol ether, 15-20 parts of polyoxyethylene oleate, 5-10 parts of sodium lauroyl sarcosinate, 5-8 parts of deoiling component, 3-7 parts of sodium alginate, 1-2 parts of flavonoid-containing plant extract, 1-5 parts of suspending agent, 1-2 parts of essence and 1-8 parts of water;
the deoiling component consists of a sulfonate surfactant, an alkyl polyglycoside surfactant and citric acid.
Specifically, the deoiling component is prepared from a sulfonate surfactant, an alkyl polyglycoside surfactant and citric acid according to a mass ratio of 10-15: 5-10: 1.
Specifically, the sulfonate surfactant is one selected from C10-C18 alkylbenzene sulfonic acids.
Specifically, the alkyl polyglycoside surfactant is one selected from C8-C16 alkyl polyglycoside.
Specifically, the plant extract containing flavonoids is selected from one of folium Ginkgo extract, lemon peel extract, mandarin orange peel extract, tartary buckwheat leaf extract, and folium crataegi extract.
Specifically, the suspending agent is acrylate copolymer.
The invention has the beneficial effects that:
firstly, the concentrated surfactant composition provided by the invention takes polyoxyethylene fatty alcohol ether, polyoxyethylene oleate and sodium lauroyl sarcosinate as main cleaning components, and has excellent cleaning capability on dirt after being compounded and used;
secondly, the degreasing component consisting of a sulfonate surfactant, an alkyl polyglycoside surfactant and citric acid is added, so that the degreasing agent can effectively remove oil stains and has high degreasing efficiency;
thirdly, sodium alginate is added, the sodium alginate forms gel when meeting water in a concentrated solution system, and a film layer is formed on the surface of the composition, so that the essence in the composition can be effectively prevented from being lost;
fourthly, plant extracts containing flavonoid compounds are also added, and the plant extracts containing the flavonoid compounds have excellent characteristics of oxidation resistance, bacteria resistance and the like.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments in order to provide a further understanding of the nature and technical means of the invention, as well as the specific objects and functions attained by the invention.
Example 1
A low-foam degreasing concentrated surfactant composition comprises the following components in parts by weight: 35 parts of polyoxyethylene fatty alcohol ether, 15 parts of polyoxyethylene oleate, 10 parts of sodium lauroyl sarcosinate, 6 parts of deoiling component, 5 parts of sodium alginate, 1 part of plant extract containing flavonoid compounds, 2 parts of suspending agent, 1 part of essence and 4 parts of water; the deoiling component is prepared from dodecyl benzene sulfonic acid, dodecyl polyglycoside and citric acid according to the mass ratio of 10: 5: 1.
And (3) testing: the foam height at 25 ℃ was measured using 5g of the above composition, and the detergency of the composition was measured by a method described in "measurement of detergency and circulating washing performance of detergent for clothing" GB/T13174-2008, and the record is as shown in table 1 below.
Example 2
A low-foam degreasing concentrated surfactant composition comprises the following components in parts by weight: 30 parts of polyoxyethylene fatty alcohol ether, 20 parts of polyoxyethylene oleate, 10 parts of sodium lauroyl sarcosinate, 6 parts of deoiling component, 5 parts of sodium alginate, 1 part of plant extract containing flavonoid compounds, 2 parts of suspending agent, 1 part of essence and 5 parts of water;
the deoiling component is prepared from dodecyl benzene sulfonic acid, dodecyl polyglycoside and citric acid according to the mass ratio of 10: 5: 1.
And (3) testing: the foam height at 25 ℃ was measured using 5g of the above composition, and the detergency of the composition was measured by a method described in "measurement of detergency and circulating washing performance of detergent for clothing" GB/T13174-2008, and the record is as shown in table 1 below.
Comparative example 1
5g of a common commercially available AES concentrate was measured for foam height at 25 ℃ and the detergency of the common commercially available AES concentrate was measured by the test method of GB/T13174-2008. determination of detergency and circular detergency for clothes, and the record is as shown in Table 1 below.
TABLE 1 test results
| Example 1 | Example 2 | Comparative example 1 | |
| Stain removal value | 1.9 | 1.7 | 1.4 |
| Height/cm of foam | 2.1 | 1.8 | 4.3 |
It was tested that examples 1, 2, using the surfactant composition of the present application, had a much higher stain removal value and a significantly lower foam height than the conventional commercially available AES concentrate of comparative example 1.
The above examples only show 2 embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (6)
1. The low-foam deoiling concentrated surfactant composition is characterized by comprising the following components in parts by weight: 30-40 parts of polyoxyethylene fatty alcohol ether, 15-20 parts of polyoxyethylene oleate, 5-10 parts of sodium lauroyl sarcosinate, 5-8 parts of deoiling component, 3-7 parts of sodium alginate, 1-2 parts of flavonoid-containing plant extract, 1-5 parts of suspending agent, 1-2 parts of essence and 1-8 parts of water;
the deoiling component consists of a sulfonate surfactant, an alkyl polyglycoside surfactant and citric acid.
2. The low-foam degreasing concentrated surfactant composition according to claim 1, wherein the degreasing component is prepared from a sulfonate surfactant, an alkyl polyglycoside surfactant and citric acid in a mass ratio of 10-15: 5-10: 1.
3. A low foaming degreasing concentrated surfactant composition as claimed in claim 2 wherein said sulfonate surfactant is selected from the group consisting of C10-C18 alkyl benzene sulfonic acids.
4. The low foam degreasing concentrated surfactant composition of claim 2, wherein the alkyl polyglycoside surfactant is selected from the group consisting of C8-C16 alkyl polyglycosides.
5. The low foaming deoiling concentrated surfactant composition as claimed in claim 1, wherein said flavonoid containing plant extract is selected from one of ginkgo biloba extract, lemon peel extract, citrus peel extract, tartary buckwheat leaf extract, hawthorn leaf extract.
6. The low foam degreasing concentrated surfactant composition of claim 1 wherein the suspending agent is an acrylate copolymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010907494.7A CN111909801A (en) | 2020-09-02 | 2020-09-02 | Low-foam deoiling concentrated surfactant composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010907494.7A CN111909801A (en) | 2020-09-02 | 2020-09-02 | Low-foam deoiling concentrated surfactant composition |
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| Publication Number | Publication Date |
|---|---|
| CN111909801A true CN111909801A (en) | 2020-11-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010907494.7A Pending CN111909801A (en) | 2020-09-02 | 2020-09-02 | Low-foam deoiling concentrated surfactant composition |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491084A (en) * | 2001-02-16 | 2004-04-21 | Encapsulated flavor and/or fragrance composition | |
| CN101596428A (en) * | 2009-07-08 | 2009-12-09 | 工合聚能(天津)石油精化科技发展有限公司 | A kind of molecular compound surfactant and preparation method thereof |
| CN105985869A (en) * | 2015-02-02 | 2016-10-05 | 上海净安化工科技有限公司 | Concentrated multifunctional detergent |
| CN106753861A (en) * | 2016-11-24 | 2017-05-31 | 嘉兴德扬生物科技有限公司 | A kind of Closestool cleanser of antibacterial lasting and preparation method thereof |
| CN111518633A (en) * | 2020-05-22 | 2020-08-11 | 四川君和环保股份有限公司 | Oil sludge cleaning agent and preparation method thereof |
-
2020
- 2020-09-02 CN CN202010907494.7A patent/CN111909801A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491084A (en) * | 2001-02-16 | 2004-04-21 | Encapsulated flavor and/or fragrance composition | |
| CN101596428A (en) * | 2009-07-08 | 2009-12-09 | 工合聚能(天津)石油精化科技发展有限公司 | A kind of molecular compound surfactant and preparation method thereof |
| CN105985869A (en) * | 2015-02-02 | 2016-10-05 | 上海净安化工科技有限公司 | Concentrated multifunctional detergent |
| CN106753861A (en) * | 2016-11-24 | 2017-05-31 | 嘉兴德扬生物科技有限公司 | A kind of Closestool cleanser of antibacterial lasting and preparation method thereof |
| CN111518633A (en) * | 2020-05-22 | 2020-08-11 | 四川君和环保股份有限公司 | Oil sludge cleaning agent and preparation method thereof |
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Application publication date: 20201110 |