CN111849287A - Organic coating with invisible effect - Google Patents
Organic coating with invisible effect Download PDFInfo
- Publication number
- CN111849287A CN111849287A CN202010766476.1A CN202010766476A CN111849287A CN 111849287 A CN111849287 A CN 111849287A CN 202010766476 A CN202010766476 A CN 202010766476A CN 111849287 A CN111849287 A CN 111849287A
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- China
- Prior art keywords
- coating
- fluorescent ink
- organic coating
- ultraviolet fluorescent
- ultraviolet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an organic coating with a stealth effect, which comprises a substrate, wherein an ultraviolet fluorescent ink pattern is arranged on the substrate, and a transparent coating is covered on the ultraviolet fluorescent ink pattern. The organic coating system can completely hide the contents drawn by the ultraviolet fluorescent ink under visible light, and ensure that the contents of the patterns drawn by the ultraviolet fluorescent ink have good reading effect under the irradiation of ultraviolet light. In addition, the coating system can provide protection on physical and chemical properties and optical properties for the ultraviolet fluorescent ink.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to an organic coating with a stealth effect.
Background
At present, the mainstream 'invisible Ink' in the market is colorless and transparent ultraviolet fluorescent Ink (UltravioletFluorescent Ink). The ultraviolet fluorescent ink is widely applied to base materials with permeability and low glossiness and has a good hiding effect under visible light, such as paper, packing materials, ceramics and other base materials. However, when the substrate material has no high permeability and a certain glossiness, such as resin coating, oil-based paint coating and metal, the hiding effect of the ultraviolet fluorescent ink under visible light is not good. In addition, the ultraviolet fluorescent ink has no alkali resistance, detergent resistance and organic solvent resistance, and the conservation of the service life of the ultraviolet fluorescent ink exposed in the air is estimated to be 2 years. Can not meet the requirements of performance and service life of some high-grade products.
Disclosure of Invention
In view of the above, the present invention is directed to provide an organic coating with a hiding effect, which can improve the poor hiding effect of the uv fluorescent ink under visible light when the uv fluorescent ink is on the surface of an impermeable base material, and provide a certain protection for the drawn pattern.
In order to achieve the purpose, the technical scheme of the invention is realized as follows:
an organic coating with a stealth effect comprises a substrate, wherein an ultraviolet fluorescent ink pattern is arranged on the substrate, and a transparent coating is covered on the ultraviolet fluorescent ink pattern.
In some embodiments, the substrate comprises an acrylic coating.
In some embodiments, the lower part of the acrylic resin coating is sequentially provided with a common oil-based colored paint, black epoxy resin base powder and an aluminum matrix from outside to inside.
In some embodiments, the pattern comprises a pattern made of uv fluorescent ink.
In some embodiments, the clear coat layer comprises an acrylic solid powder coating.
In some embodiments, the pattern comprises a QR two-dimensional code.
In some embodiments, the QR two-dimensional code comprises a dot-matrix QR two-dimensional code.
In some embodiments, the uv fluorescent ink includes a fluorescent agent and a transparent resin.
Compared with the prior art, the organic coating with the invisible effect has the following advantages:
(1) on the premise of ensuring that the drawn contents of the ultraviolet ink can be read normally under the irradiation of ultraviolet rays, the drawn contents are completely invisible under the sunlight.
(2) The coating system can isolate the drawn contents of the ultraviolet ink from the external conditions, avoid the exchange or reaction of the contents and external substances, and provide protection on physicochemical properties for the contents.
(3) The ultraviolet absorbent in the acrylic transparent resin powder can slow down the photoaging rate of ultraviolet rays in sunlight to the ultraviolet fluorescent ink, and provides protection on optical properties for the ultraviolet fluorescent ink.
(4) The acrylic transparent resin coating used by the coating system is a common outer coating in the automobile industry, has good impact resistance and abrasion resistance, and can meet the international requirement on the paint film performance of automobiles. The use of acrylic transparent resin as the cover layer for the uv fluorescent ink can introduce new appearance effects for the automotive market. Hidden anti-counterfeiting information can be attached to the visible area on the front surface of the automobile hub.
Drawings
The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate an embodiment of the invention and, together with the description, serve to explain the invention and not to limit the invention.
FIG. 1 is a schematic diagram of an organic coating with invisible effect before spraying transparent solid powder coating.
FIG. 2 is a schematic diagram of a sprayed transparent solid powder coating of an organic coating with a stealth effect according to the present invention.
Description of reference numerals:
11-ultraviolet fluorescent ink pattern; 12-acrylic resin coating; 13-common oily color paint; 14-black epoxy resin base powder; a 15-aluminum matrix; 20-acrylic transparent resin coating.
Detailed Description
It should be noted that the embodiments and features of the embodiments may be combined with each other without conflict.
The technical solutions of the present invention will be described clearly and completely with reference to the accompanying drawings and embodiments, and it is to be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The organic coating having the stealth effect according to the embodiment of the present invention is described below with reference to fig. 1 to 2 in combination with the embodiment.
The principle of the present technical solution firstly needs to discuss why the ultraviolet fluorescent ink can be observed by naked eyes in the visible light energy. Taking fig. 1 as an example, the coating layers are, from outside to inside: an ultraviolet fluorescent ink pattern 11; an acrylic resin coating layer 12; common oily color paint 13; black epoxy resin base powder 14; an aluminum substrate 15. The ultraviolet fluorescent ink pattern 11 is sprayed on the acrylic transparent resin coating 12 of the full-coating system by a dot matrix ink-jet printer, and the schematic diagram of poor invisible effect is shown.
The acrylic resin coating 12 is used as a base material to which the ultraviolet fluorescent ink pattern 11 is attached, and the drawn pattern is a dot-matrix sprayed QR two-dimensional Code (Quick Response Code). The acrylic resin coating 12 has high glossiness and is not easy to permeate, and the ultraviolet fluorescent ink 11 lattice can be attached to the substrate in a hill shape. The reason why the ultraviolet fluorescent ink two-dimensional code can be observed by naked eyes under visible light is well explained in the figure 1: high gloss surfaces can be specularly reflected. When ultraviolet fluorescent ink dot matrix hilly shape is attached to the surface of the ultraviolet fluorescent ink dot matrix, the angle of light reflected by the dot matrix is different from the angle of a mirror surface of a high-glossiness surface, so that the dot matrix part is slightly dim. Therefore, the content sprayed by the ultraviolet fluorescent ink can be observed under visible light. In addition, the transparency of the uv fluorescent ink is limited, and a pale white trace of the uv fluorescent ink can be observed on the material of the metal substrate.
When a new acrylic clear resin coating 20 is coated on the uv fluorescent ink pattern 11 coating after spraying the acrylic clear resin coating 20 on the uv fluorescent ink pattern 11 coating, a new specular reflection plane can be established. The condition that the drawn contents of the ultraviolet fluorescent ink pattern 11 are observed by naked eyes due to different light reflection angles is avoided. The active ingredient of the uv fluorescent ink pattern 11 is mainly transparent resin, which functions as a carrier of the fluorescent agent and enhances the ink adhesion. The active ingredients of the uv fluorescent ink pattern 11 have transparency similar to that of the acrylic transparent resin coating. The acrylic transparent resin 20 can well cover the pale trace generated by the uv fluorescent ink 11. The acrylic transparent resin coating 12 itself has good resistance to organic solvents, alkali and abrasion. The acrylic clear resin coating 20 covers the uv fluorescent ink coating to isolate it from external conditions and provide good protection for its physical and chemical properties. The acrylic resin itself is easily deteriorated by irradiation of ultraviolet rays. Therefore, an ultraviolet absorber is generally added to the acrylic solid powder coating. For example, 2- (2-2H-benzotriazole) -6- (1-methyl-1-phenyl) ethyl-4- (1, 1,3, 3-tetramethylbutyl) phenol. Therefore, the acrylic transparent resin coating layer 20 can absorb most of the ultraviolet rays of the sunlight under the daily conditions, thereby slowing down the photoaging rate of the ultraviolet fluorescent ink. The effective life of the fluorescent powder is prolonged, and the observation effect of the fluorescent powder under a 365nm ultraviolet light source can be ensured.
In some embodiments, an organic coating with a stealth effect includes a substrate having a pattern of ultraviolet fluorescent ink disposed thereon, the pattern being covered with a transparent solid powder coating. The substrate comprises a metal substrate or an acrylic resin coating, the pattern comprises a pattern made of ultraviolet fluorescent ink, the pattern comprises a QR two-dimensional code, and the QR two-dimensional code comprises a dot-matrix QR two-dimensional code. The solid powder coating comprises an acrylic resin solid powder coating. The ultraviolet fluorescent ink comprises a fluorescent agent and a transparent resin.
In some embodiments, in the first step, a full-coating template is taken, the coating system of which is the acrylic resin coating 12 in fig. 1; common oily color paint 13 and black epoxy resin base powder 14. And secondly, spraying various patterns such as two-dimensional codes, logos and the like on the surface of the sample plate by using an ultraviolet fluorescent ink 11 dot-matrix code spraying machine. And thirdly, placing the sprayed sample plate under electrostatic spraying equipment, and spraying acrylic transparent resin powder. And fourthly, feeding the sample plate into an oven to melt, level and solidify the acrylic resin. Resulting in the coating structure shown in fig. 2.
Compared with the prior art, the organic coating with the invisible effect has the following advantages:
(1) on the premise of ensuring that the drawn contents of the ultraviolet ink can be read normally under the irradiation of ultraviolet rays, the drawn contents are completely invisible under the sunlight.
(2) The coating system can isolate the drawn contents of the ultraviolet ink from the external conditions, avoid the exchange or reaction of the contents and external substances, and provide protection on physicochemical properties for the contents.
(3) The ultraviolet absorbent in the acrylic transparent resin powder can slow down the photoaging rate of ultraviolet rays in sunlight to the ultraviolet fluorescent ink, and provides protection on optical properties for the ultraviolet fluorescent ink.
(4) The acrylic transparent resin coating used by the coating system is a common outer coating in the automobile industry, has good impact resistance and abrasion resistance, and can meet the international requirement on the paint film performance of automobiles. The use of acrylic transparent resin as the cover layer for the uv fluorescent ink can introduce new appearance effects for the automotive market. Hidden anti-counterfeiting information can be attached to the visible area on the front surface of the automobile hub.
The die replacing device is simple in structure, convenient to operate, time-saving and labor-saving, and solves the problem of low die replacing efficiency caused by the fact that no special spinning machine die replacing device is available. The device can be used for quickly positioning and installing the die in the die replacement process of the spinning machine, and can finish the die replacement work of all the spinning machines by one person alone, so that the labor intensity of personnel in the die replacement process is obviously reduced, the die replacement efficiency is improved, the waste of the personnel in the die replacement process is reduced, and the potential safety hazard of using a forklift to operate in a narrow space is avoided.
In the description of the present invention, it is to be understood that the terms "central", "longitudinal", "lateral", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", etc., indicate orientations or positional relationships based on those shown in the drawings, and are used only for convenience in describing the present invention and for simplicity in description, and do not indicate or imply that the referenced devices or elements must have a particular orientation, be constructed and operated in a particular orientation, and thus, are not to be considered as limiting the scope of the present invention.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the present invention, "a plurality" means at least two, e.g., two, three, etc., unless specifically limited otherwise.
In the present invention, unless otherwise expressly stated or limited, the terms "mounted," "connected," "secured," and the like are to be construed broadly and can, for example, be fixedly connected, detachably connected, or integrally formed; can be mechanically connected, electrically connected or can communicate with each other; either directly or indirectly through intervening media, either internally or in any other relationship. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
The present invention is not limited to the above preferred embodiments, and any modifications, equivalent substitutions, improvements, etc. within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (8)
1. The organic coating with the invisible effect is characterized by comprising a substrate, wherein an ultraviolet fluorescent ink pattern (11) is arranged on the substrate, and a transparent coating is covered on the ultraviolet fluorescent ink pattern (11).
2. The organic coating with stealth effect according to claim 1, characterized in that said substrate comprises an acrylic resin coating (12).
3. The organic coating with invisible effect according to claim 2, characterized in that a common oil-based color paint (13), a black epoxy resin base powder (14) and an aluminum matrix (15) are further arranged on the lower portion of the acrylic resin coating (12) from outside to inside.
4. The organic coating with invisible effect of claim 1, wherein the pattern comprises a pattern made of ultraviolet fluorescent ink.
5. The organic coating with stealth effect according to claim 1, characterized in that said clear coat comprises an acrylic solid powder coating (20).
6. The organic coating with invisible effect of claim 4, wherein the pattern comprises a QR two-dimensional code.
7. The organic coating with invisible effects of claim 6, wherein the QR two-dimensional code comprises a dot-matrix QR two-dimensional code.
8. The organic coating with invisible effect of claim 7, wherein the ultraviolet fluorescent ink comprises a fluorescent agent and a transparent resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010766476.1A CN111849287A (en) | 2020-08-03 | 2020-08-03 | Organic coating with invisible effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010766476.1A CN111849287A (en) | 2020-08-03 | 2020-08-03 | Organic coating with invisible effect |
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| Publication Number | Publication Date |
|---|---|
| CN111849287A true CN111849287A (en) | 2020-10-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010766476.1A Pending CN111849287A (en) | 2020-08-03 | 2020-08-03 | Organic coating with invisible effect |
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| CN (1) | CN111849287A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112406343A (en) * | 2020-11-30 | 2021-02-26 | 中信戴卡股份有限公司 | Code making method for improving recognition rate of fluorescent two-dimensional code |
| CN114605869A (en) * | 2022-03-22 | 2022-06-10 | 德硅(上海)新材料科技有限公司 | Inorganic fluorescent material composition, decorative film with anti-counterfeiting effect and preparation method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104494533A (en) * | 2014-11-19 | 2015-04-08 | 上海电机学院 | Motor vehicle license plate and anti-fake method thereof |
| CN106043938A (en) * | 2016-07-29 | 2016-10-26 | 北京赛腾标识***股份公司 | Cover suitable for product tracing and application method of cover |
| CN106423805A (en) * | 2016-11-28 | 2017-02-22 | 中信戴卡股份有限公司 | Aluminum alloy surface coating and method for forming coating |
| CN106945446A (en) * | 2017-02-28 | 2017-07-14 | 中信戴卡股份有限公司 | It is a kind of to be used for the method in aluminum alloy surface bat printing pattern |
| CN213388474U (en) * | 2020-08-03 | 2021-06-08 | 中信戴卡股份有限公司 | Organic coating with invisible effect |
-
2020
- 2020-08-03 CN CN202010766476.1A patent/CN111849287A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104494533A (en) * | 2014-11-19 | 2015-04-08 | 上海电机学院 | Motor vehicle license plate and anti-fake method thereof |
| CN106043938A (en) * | 2016-07-29 | 2016-10-26 | 北京赛腾标识***股份公司 | Cover suitable for product tracing and application method of cover |
| CN106423805A (en) * | 2016-11-28 | 2017-02-22 | 中信戴卡股份有限公司 | Aluminum alloy surface coating and method for forming coating |
| CN106945446A (en) * | 2017-02-28 | 2017-07-14 | 中信戴卡股份有限公司 | It is a kind of to be used for the method in aluminum alloy surface bat printing pattern |
| CN213388474U (en) * | 2020-08-03 | 2021-06-08 | 中信戴卡股份有限公司 | Organic coating with invisible effect |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112406343A (en) * | 2020-11-30 | 2021-02-26 | 中信戴卡股份有限公司 | Code making method for improving recognition rate of fluorescent two-dimensional code |
| CN114605869A (en) * | 2022-03-22 | 2022-06-10 | 德硅(上海)新材料科技有限公司 | Inorganic fluorescent material composition, decorative film with anti-counterfeiting effect and preparation method |
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