CN111809292A - Flame-retardant fabric for furniture and preparation process - Google Patents
Flame-retardant fabric for furniture and preparation process Download PDFInfo
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- CN111809292A CN111809292A CN202010657157.7A CN202010657157A CN111809292A CN 111809292 A CN111809292 A CN 111809292A CN 202010657157 A CN202010657157 A CN 202010657157A CN 111809292 A CN111809292 A CN 111809292A
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- Prior art keywords
- fibers
- flame
- retardant
- fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 111
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 95
- 239000003063 flame retardant Substances 0.000 title claims abstract description 94
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000000835 fiber Substances 0.000 claims abstract description 131
- 229920000728 polyester Polymers 0.000 claims abstract description 30
- 210000002268 wool Anatomy 0.000 claims abstract description 30
- 229920006282 Phenolic fiber Polymers 0.000 claims abstract description 28
- 239000004952 Polyamide Substances 0.000 claims abstract description 28
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 28
- 229920002647 polyamide Polymers 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 26
- 239000012796 inorganic flame retardant Substances 0.000 claims abstract description 22
- 238000007598 dipping method Methods 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims description 59
- 230000008018 melting Effects 0.000 claims description 32
- 238000002844 melting Methods 0.000 claims description 32
- 238000010438 heat treatment Methods 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 30
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 20
- 238000005303 weighing Methods 0.000 claims description 15
- 238000009941 weaving Methods 0.000 claims description 14
- 229920000877 Melamine resin Polymers 0.000 claims description 10
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 10
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 10
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 10
- 239000000347 magnesium hydroxide Substances 0.000 claims description 10
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 10
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 238000004804 winding Methods 0.000 claims description 10
- 238000009987 spinning Methods 0.000 claims description 6
- CEAZRRDELHUEMR-URQXQFDESA-N Gentamicin Chemical compound O1[C@H](C(C)NC)CC[C@@H](N)[C@H]1O[C@H]1[C@H](O)[C@@H](O[C@@H]2[C@@H]([C@@H](NC)[C@@](C)(O)CO2)O)[C@H](N)C[C@@H]1N CEAZRRDELHUEMR-URQXQFDESA-N 0.000 claims description 5
- 229930182566 Gentamicin Natural products 0.000 claims description 5
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 5
- 230000000844 anti-bacterial effect Effects 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 5
- 229960002518 gentamicin Drugs 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 238000002074 melt spinning Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 238000002485 combustion reaction Methods 0.000 abstract description 7
- 239000002759 woven fabric Substances 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 3
- 231100000989 no adverse effect Toxicity 0.000 abstract 1
- 239000012466 permeate Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000004753 textile Substances 0.000 description 21
- 239000000203 mixture Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- AZFKQCNGMSSWDS-UHFFFAOYSA-N MCPA-thioethyl Chemical compound CCSC(=O)COC1=CC=C(Cl)C=C1C AZFKQCNGMSSWDS-UHFFFAOYSA-N 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 230000002411 adverse Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/08—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
- D06M13/364—Cyanuric acid; Isocyanuric acid; Derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Woven Fabrics (AREA)
Abstract
The invention discloses a flame-retardant fabric for furniture and a preparation process thereof, the flame-retardant fabric comprises polyester fiber, polyacrylonitrile fiber, phenolic fiber, polyamide fiber and artificial wool fiber, because two silk threads of a woven fabric have different combustion capacities, flame can not spread after combustion, so that a flame-retardant effect is achieved, meanwhile, the woven fabric is immersed in an inorganic flame retardant, is baked by using a dipping baking method, is immersed in an organic flame retardant, is baked by using the dipping baking method, so that the inorganic flame retardant and the organic flame retardant respectively permeate into the fabric, and are fused into the fabric fiber by using a high-temperature baking mode, so that the flame-retardant effect is achieved, and the added flame retardant is safe and harmless to a human body, has a wide application range, has no adverse effect on the original strength, elasticity and whiteness of the fiber, and has good hand feeling, wearability and durability, effectively improves the grade of the product and the economic benefit.
Description
Technical Field
The invention relates to the technical field of flame-retardant fabrics, in particular to a flame-retardant fabric for furniture and a preparation process thereof.
Background
The burning of the textile is an important factor causing fire and causing fire spread, effectively reducing the occurrence of the fire, and defending and resisting the fire are hot problems concerned by countries in the world for a long time. Along with the rapid development of the domestic urbanization, high-rise buildings and underground buildings are increased year by year, the fire hazard is frequent, the fire extinguishing difficulty is increased, the development of flame-retardant textiles is promoted to a new height, although the flame-retardant textile materials are applied in China, the flame-retardant textile materials are mainly used for special operations, such as firefighter protective clothing, welding work clothing, military protective clothing and the like, the flame-retardant textiles are rarely related to furniture textiles, the furniture textiles divide cloth into four types, namely pure woven textiles, blended textiles and interwoven textiles according to the yarn raw materials forming the textiles, the furniture textiles are characterized by soft hand feeling, rich patterns, mellow lines and novel modeling, the textiles used in the domestic soft furniture textiles are mainly natural textiles, artificial textiles and blended textiles, the characteristics of the textiles and the textiles used for developing the furniture textiles with the flame-retardant function on the basis of proper cost performance are the subject of research, along with the improvement of living levels, most people live in high-rise or super high-rise buildings and put forward higher requirements on the occurrence of fire prevention, so that the design and development of textile materials with good wearability and flame retardant effects of no melting and dripping, no toxicity, low smoke and the like become hot points of research, the mechanism of the flame retardant materials mainly prevents fibers from being thermally decomposed, inhibits or dilutes combustible gas through heat absorption, covering protection, gas dilution, condensed phase flame retardance, gas phase flame retardance, surface effect or melting and dripping effect of particles and the like, and isolates the connection between the thermal environment and the air so as to achieve the flame retardant effect, at present, the most widely used flame retardant process of the furniture fabric is a flame retardant adding method and a mixed spinning method, the two methods are different in use method and required materials, the adopted flame retardant adding method is to add the flame retardant into the fabric, baking is carried out after the flame retardant is added, and high temperature is utilized to promote the flame retardant to be blended into fabric fibers, so that the fabric can achieve the flame-retardant purpose.
Disclosure of Invention
The invention aims to provide a flame-retardant fabric for furniture and a preparation process thereof, wherein a composite fabric is obtained by weaving two different fiber mixture silk yarns, and due to the different combustion capacities of the two silk yarns, flame cannot spread after the two silk yarns are combusted, so that the flame-retardant effect is achieved.
In order to achieve the purpose, the invention provides the following technical scheme:
the flame-retardant fabric for furniture comprises the following components in parts by weight: 5-20 components of polyester fiber, 12 components of polyacrylonitrile fiber, 20 components of phenolic fiber, 6 components of polyamide fiber and 6-20 components of artificial wool fiber.
Preferably, the composition comprises the following components in parts by weight: 5-component polyester fibers, 12-component polyacrylonitrile fibers, 20-component phenolic fibers, 6-component polyamide fibers and 20-component artificial wool fibers.
Preferably, the composition comprises the following components in parts by weight: 20-component polyester fibers, 12-component polyacrylonitrile fibers, 20-component phenolic fibers, 6-component polyamide fibers and 6-component artificial wool fibers.
Preferably, the composition comprises the following components in parts by weight: 10-component polyester fibers, 12-component polyacrylonitrile fibers, 20-component phenolic fibers, 6-component polyamide fibers and 10-component artificial wool fibers.
The invention provides another technical scheme: a preparation process of flame-retardant fabric for furniture comprises the following steps:
the method comprises the following steps: preparing two groups of heating and melting equipment, and respectively weighing polyester fibers, polyacrylonitrile fibers, phenolic fibers, polyamide fibers and artificial wool fibers of corresponding components according to the amount;
step two: adding polyester fibers and polyacrylonitrile fibers into a first group of heating and melting equipment, heating and melting the polyester fibers and the polyacrylonitrile fibers under a stirring state, adding phenolic fibers, polyamide fibers and artificial wool fibers into a second group of heating and melting equipment, and heating and melting the phenolic fibers, the polyamide fibers and the artificial wool fibers under a stirring state;
step three: respectively adding the melts in the two groups of heating and melting equipment into a melt spinning machine for spinning operation, winding and recovering the silk threads by using a winding drum, and then drying the silk threads in a high-temperature environment;
step four: respectively installing two groups of different silk threads in silk thread weaving equipment, weaving the composite fabric, and sequentially carrying out antibacterial modification treatment on the obtained woven composite fabric by using gentamicin and octadecylamine;
step five: and immersing the woven composite fabric into a flame retardant, and drying the composite fabric by using a dipping and baking method to obtain the flame-retardant fabric.
Preferably, the dip baking method comprises the steps of:
step one, zero one: firstly, immersing the composite fabric in an inorganic flame retardant until the whole composite fabric is wetted by the inorganic flame retardant;
step one, zero and two: taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying;
step one, zero and three: immersing the dried fabric in the organic flame retardant until the whole composite fabric is wetted by the organic flame retardant;
step one, zero and four: and taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying.
Preferably, the preparation of the flame retardant comprises the following steps:
step two, zero and one: weighing 15 components of antimony trioxide, 5 components of magnesium hydroxide and 5 components of aluminum hydroxide;
step two, zero two: sequentially pouring antimony trioxide, magnesium hydroxide and aluminum hydroxide into mixing and stirring equipment, and stirring at constant temperature to obtain an inorganic flame retardant;
step two, zero and three: weighing 8 components of melamine, 8 components of melamine cyanurate and 4 components of organic synergist mixed resin;
step two, zero and four: sequentially pouring melamine, melamine cyanurate and organic synergist mixed resin into mixing and stirring equipment, and stirring at constant temperature to obtain an organic flame retardant;
step two, zero and five: and respectively extracting and storing the inorganic flame retardant and the organic flame retardant by using an extraction and storage device.
Compared with the prior art, the invention has the beneficial effects that:
the invention provides a flame-retardant fabric for furniture and a preparation process thereof, wherein a composite fabric is obtained by weaving two different fiber mixture silk threads, three flame-retardant fabrics with high pulling resistance, high softness and comfort and the combination of the pulling resistance and the softness are respectively woven by changing the content of fibers in the two silk threads, and the two silk threads of the woven fabric have different combustion capacities, so that flame cannot spread after combustion, thereby achieving the flame-retardant effect The application range is wide, the original strength, elasticity and whiteness of the fiber are not adversely affected, and the fiber has good hand feeling, wearability and durability, so that the grade of the product is effectively improved, and the economic benefit is improved.
Drawings
FIG. 1 is a flow chart of a preparation process of the flame-retardant fabric for furniture;
FIG. 2 is a flow chart of the steps of the immersion baking process of the present invention;
FIG. 3 is a flow chart of the preparation of the flame retardant of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the flame-retardant fabric for furniture comprises the following components in parts by weight: the flame-retardant fabric comprises 5 components of polyester fibers, 12 components of polyacrylonitrile fibers, 20 components of phenolic fibers, 6 components of polyamide fibers and 20 components of artificial wool fibers, wherein the content of the artificial wool fibers is increased, and the content of the polyester fibers is reduced, so that the woven flame-retardant fabric is high in softness and comfort, but low in anti-pulling capacity.
Referring to fig. 1, in order to better show the process flow of the flame retardant fabric for furniture, the embodiment provides a preparation process of the flame retardant fabric for furniture, which includes the following steps:
the method comprises the following steps: preparing two groups of heating and melting equipment, and respectively weighing polyester fibers, polyacrylonitrile fibers, phenolic fibers, polyamide fibers and artificial wool fibers of corresponding components according to the amount;
step two: adding polyester fibers and polyacrylonitrile fibers into a first group of heating and melting equipment, heating and melting the polyester fibers and the polyacrylonitrile fibers under a stirring state, adding phenolic fibers, polyamide fibers and artificial wool fibers into a second group of heating and melting equipment, and heating and melting the phenolic fibers, the polyamide fibers and the artificial wool fibers under a stirring state;
step three: respectively adding the melts in the two groups of heating and melting equipment into a melt spinning machine for spinning operation, winding and recovering the silk threads by using a winding drum, and then drying the silk threads in a high-temperature environment;
step four: respectively installing two groups of different silk threads in silk thread weaving equipment, weaving the composite fabric, and sequentially carrying out antibacterial modification treatment on the obtained woven composite fabric by using gentamicin and octadecylamine;
step five: and immersing the woven composite fabric into a flame retardant, and drying the composite fabric by using a dipping and baking method to obtain the flame-retardant fabric.
Referring to fig. 2, the immersion baking method includes the following steps:
step one, zero one: firstly, immersing the composite fabric in an inorganic flame retardant until the whole composite fabric is wetted by the inorganic flame retardant;
step one, zero and two: taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying;
step one, zero and three: immersing the dried fabric in the organic flame retardant until the whole composite fabric is wetted by the organic flame retardant;
step one, zero and four: and taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying.
Referring to fig. 3, the preparation of the flame retardant comprises the following steps:
step two, zero and one: weighing 15 components of antimony trioxide, 5 components of magnesium hydroxide and 5 components of aluminum hydroxide;
step two, zero two: sequentially pouring antimony trioxide, magnesium hydroxide and aluminum hydroxide into mixing and stirring equipment, and stirring at constant temperature to obtain an inorganic flame retardant;
step two, zero and three: weighing 8 components of melamine, 8 components of melamine cyanurate and 4 components of organic synergist mixed resin;
step two, zero and four: sequentially pouring melamine, melamine cyanurate and organic synergist mixed resin into mixing and stirring equipment, and stirring at constant temperature to obtain an organic flame retardant;
step two, zero and five: and respectively extracting and storing the inorganic flame retardant and the organic flame retardant by using an extraction and storage device.
Example two:
the flame-retardant fabric for furniture comprises the following components in parts by weight: 20 components of polyester fiber, 12 components of polyacrylonitrile fiber, 20 components of phenolic fiber, 6 components of polyamide fiber and 6 components of artificial wool fiber, the content of the artificial wool fiber is reduced, and the content of the polyester fiber is increased, so that the anti-pulling and anti-impact performance of the woven flame-retardant fabric is improved, but the softness and the comfort degree are reduced.
Referring to fig. 1, in order to better show the process flow of the flame retardant fabric for furniture, the embodiment provides a preparation process of the flame retardant fabric for furniture, which includes the following steps:
the method comprises the following steps: preparing two groups of heating and melting equipment, and respectively weighing polyester fibers, polyacrylonitrile fibers, phenolic fibers, polyamide fibers and artificial wool fibers of corresponding components according to the amount;
step two: adding polyester fibers and polyacrylonitrile fibers into a first group of heating and melting equipment, heating and melting the polyester fibers and the polyacrylonitrile fibers under a stirring state, adding phenolic fibers, polyamide fibers and artificial wool fibers into a second group of heating and melting equipment, and heating and melting the phenolic fibers, the polyamide fibers and the artificial wool fibers under a stirring state;
step three: respectively adding the melts in the two groups of heating and melting equipment into a melt spinning machine for spinning operation, winding and recovering the silk threads by using a winding drum, and then drying the silk threads in a high-temperature environment;
step four: respectively installing two groups of different silk threads in silk thread weaving equipment, weaving the composite fabric, and sequentially carrying out antibacterial modification treatment on the obtained woven composite fabric by using gentamicin and octadecylamine;
step five: and immersing the woven composite fabric into a flame retardant, and drying the composite fabric by using a dipping and baking method to obtain the flame-retardant fabric.
Referring to fig. 2, the immersion baking method includes the following steps:
step one, zero one: firstly, immersing the composite fabric in an inorganic flame retardant until the whole composite fabric is wetted by the inorganic flame retardant;
step one, zero and two: taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying;
step one, zero and three: immersing the dried fabric in the organic flame retardant until the whole composite fabric is wetted by the organic flame retardant;
step one, zero and four: and taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying.
Referring to fig. 3, the preparation of the flame retardant comprises the following steps:
step two, zero and one: weighing 15 components of antimony trioxide, 5 components of magnesium hydroxide and 5 components of aluminum hydroxide;
step two, zero two: sequentially pouring antimony trioxide, magnesium hydroxide and aluminum hydroxide into mixing and stirring equipment, and stirring at constant temperature to obtain an inorganic flame retardant;
step two, zero and three: weighing 8 components of melamine, 8 components of melamine cyanurate and 4 components of organic synergist mixed resin;
step two, zero and four: sequentially pouring melamine, melamine cyanurate and organic synergist mixed resin into mixing and stirring equipment, and stirring at constant temperature to obtain an organic flame retardant;
step two, zero and five: and respectively extracting and storing the inorganic flame retardant and the organic flame retardant by using an extraction and storage device.
Example three:
the flame-retardant fabric for furniture comprises the following components in parts by weight: the softness and comfort of the polyester fiber containing 10 components, the polyacrylonitrile fiber containing 12 components, the phenolic fiber containing 20 components, the polyamide fiber containing 6 components and the artificial wool fiber containing 10 components are remarkably improved, and the polyester fiber containing 10 components, the polyacrylonitrile fiber containing 12 components, the phenolic fiber containing 20 components, the polyamide fiber containing 6 components and the artificial wool fiber containing 10 components are ensured to have the anti-pulling capability.
Referring to fig. 1, in order to better show the process flow of the flame retardant fabric for furniture, the embodiment provides a preparation process of the flame retardant fabric for furniture, which includes the following steps:
the method comprises the following steps: preparing two groups of heating and melting equipment, and respectively weighing polyester fibers, polyacrylonitrile fibers, phenolic fibers, polyamide fibers and artificial wool fibers of corresponding components according to the amount;
step two: adding polyester fibers and polyacrylonitrile fibers into a first group of heating and melting equipment, heating and melting the polyester fibers and the polyacrylonitrile fibers under a stirring state, adding phenolic fibers, polyamide fibers and artificial wool fibers into a second group of heating and melting equipment, and heating and melting the phenolic fibers, the polyamide fibers and the artificial wool fibers under a stirring state;
step three: respectively adding the melts in the two groups of heating and melting equipment into a melt spinning machine for spinning operation, winding and recovering the silk threads by using a winding drum, and then drying the silk threads in a high-temperature environment;
step four: respectively installing two groups of different silk threads in silk thread weaving equipment, weaving the composite fabric, and sequentially carrying out antibacterial modification treatment on the obtained woven composite fabric by using gentamicin and octadecylamine;
step five: and immersing the woven composite fabric into a flame retardant, and drying the composite fabric by using a dipping and baking method to obtain the flame-retardant fabric.
Referring to fig. 2, the immersion baking method includes the following steps:
step one, zero one: firstly, immersing the composite fabric in an inorganic flame retardant until the whole composite fabric is wetted by the inorganic flame retardant;
step one, zero and two: taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying;
step one, zero and three: immersing the dried fabric in the organic flame retardant until the whole composite fabric is wetted by the organic flame retardant;
step one, zero and four: and taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying.
Referring to fig. 3, the preparation of the flame retardant comprises the following steps:
step two, zero and one: weighing 15 components of antimony trioxide, 5 components of magnesium hydroxide and 5 components of aluminum hydroxide;
step two, zero two: sequentially pouring antimony trioxide, magnesium hydroxide and aluminum hydroxide into mixing and stirring equipment, and stirring at constant temperature to obtain an inorganic flame retardant;
step two, zero and three: weighing 8 components of melamine, 8 components of melamine cyanurate and 4 components of organic synergist mixed resin;
step two, zero and four: sequentially pouring melamine, melamine cyanurate and organic synergist mixed resin into mixing and stirring equipment, and stirring at constant temperature to obtain an organic flame retardant;
step two, zero and five: and respectively extracting and storing the inorganic flame retardant and the organic flame retardant by using an extraction and storage device.
The working principle of the invention is as follows: the invention relates to a flame-retardant fabric for furniture and a preparation process thereof, wherein two different fiber mixture silk yarns are used for weaving to obtain a composite fabric, three flame-retardant fabrics with high anti-pulling capacity, high softness and comfort level and the coexistence of the anti-pulling capacity and the softness comfort level are respectively woven by changing the content of fibers in the two silk yarns, and the flame cannot spread after the two silk yarns of the woven fabric are combusted due to different combustion capacities, so that the flame-retardant effect is achieved.
In summary, the following steps: the invention relates to a flame-retardant fabric for furniture and a preparation process thereof, wherein a composite fabric is obtained by weaving two different fiber mixture silk threads, three flame-retardant fabrics with high anti-pulling capacity, high softness, high comfort level and both anti-pulling capacity and softness comfort level are respectively woven by changing the content of fibers in the two silk threads, and the flame cannot spread after the two silk threads of the woven fabric are combusted due to different combustion capacities, so that the flame retardant effect is achieved The application range is wide, the original strength, elasticity and whiteness of the fiber are not adversely affected, and the fiber has good hand feeling, wearability and durability, so that the grade of the product is effectively improved, and the economic benefit is improved.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be able to cover the technical solutions and the inventive concepts of the present invention within the technical scope of the present invention.
Claims (7)
1. The flame-retardant fabric for furniture is characterized by comprising the following components in parts by weight: 5-20 components of polyester fiber, 12 components of polyacrylonitrile fiber, 20 components of phenolic fiber, 6 components of polyamide fiber and 6-20 components of artificial wool fiber.
2. The flame-retardant fabric for furniture as claimed in claim 1, which comprises the following components in parts by weight: 5-component polyester fibers, 12-component polyacrylonitrile fibers, 20-component phenolic fibers, 6-component polyamide fibers and 20-component artificial wool fibers.
3. The flame-retardant fabric for furniture as claimed in claim 1, which comprises the following components in parts by weight: 20-component polyester fibers, 12-component polyacrylonitrile fibers, 20-component phenolic fibers, 6-component polyamide fibers and 6-component artificial wool fibers.
4. The flame-retardant fabric for furniture as claimed in claim 1, which comprises the following components in parts by weight: 10-component polyester fibers, 12-component polyacrylonitrile fibers, 20-component phenolic fibers, 6-component polyamide fibers and 10-component artificial wool fibers.
5. The preparation process of the flame-retardant fabric for furniture according to claim 1, characterized by comprising the following steps:
s1: preparing two groups of heating and melting equipment, and respectively weighing polyester fibers, polyacrylonitrile fibers, phenolic fibers, polyamide fibers and artificial wool fibers of corresponding components according to the amount;
s2: adding polyester fibers and polyacrylonitrile fibers into a first group of heating and melting equipment, heating and melting the polyester fibers and the polyacrylonitrile fibers under a stirring state, adding phenolic fibers, polyamide fibers and artificial wool fibers into a second group of heating and melting equipment, and heating and melting the phenolic fibers, the polyamide fibers and the artificial wool fibers under a stirring state;
s3: respectively adding the melts in the two groups of heating and melting equipment into a melt spinning machine for spinning operation, winding and recovering the silk threads by using a winding drum, and then drying the silk threads in a high-temperature environment;
s4: respectively installing two groups of different silk threads in silk thread weaving equipment, weaving the composite fabric, and sequentially carrying out antibacterial modification treatment on the obtained woven composite fabric by using gentamicin and octadecylamine;
s5: and immersing the woven composite fabric into a flame retardant, and drying the composite fabric by using a dipping and baking method to obtain the flame-retardant fabric.
6. The process for preparing the flame-retardant fabric for furniture according to claim 5, wherein the dip baking method comprises the following steps:
s101: firstly, immersing the composite fabric in an inorganic flame retardant until the whole composite fabric is wetted by the inorganic flame retardant;
s102: taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying;
s103: immersing the dried fabric in the organic flame retardant until the whole composite fabric is wetted by the organic flame retardant;
s104: and taking out the composite fabric, and placing the composite fabric in a high-temperature environment for baking and drying.
7. The preparation process of the flame-retardant fabric for furniture according to claim 6, wherein the preparation of the flame retardant comprises the following steps:
s201: weighing 15 components of antimony trioxide, 5 components of magnesium hydroxide and 5 components of aluminum hydroxide;
s202: sequentially pouring antimony trioxide, magnesium hydroxide and aluminum hydroxide into mixing and stirring equipment, and stirring at constant temperature to obtain an inorganic flame retardant;
s203: weighing 8 components of melamine, 8 components of melamine cyanurate and 4 components of organic synergist mixed resin;
s204: sequentially pouring melamine, melamine cyanurate and organic synergist mixed resin into mixing and stirring equipment, and stirring at constant temperature to obtain an organic flame retardant;
s205: and respectively extracting and storing the inorganic flame retardant and the organic flame retardant by using an extraction and storage device.
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